JP2005313642A - 画像形成用の組成物、システム、及び方法 - Google Patents
画像形成用の組成物、システム、及び方法 Download PDFInfo
- Publication number
- JP2005313642A JP2005313642A JP2005127332A JP2005127332A JP2005313642A JP 2005313642 A JP2005313642 A JP 2005313642A JP 2005127332 A JP2005127332 A JP 2005127332A JP 2005127332 A JP2005127332 A JP 2005127332A JP 2005313642 A JP2005313642 A JP 2005313642A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- activator
- dye
- image forming
- dissolved
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 238000003384 imaging method Methods 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title abstract description 4
- 239000012190 activator Substances 0.000 claims abstract description 30
- 239000000758 substrate Substances 0.000 claims description 36
- 238000002844 melting Methods 0.000 claims description 15
- 230000008018 melting Effects 0.000 claims description 15
- 230000005855 radiation Effects 0.000 claims description 10
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- WLTCCDHHWYAMCG-UHFFFAOYSA-N 2-phenylmethoxynaphthalene Chemical compound C=1C=C2C=CC=CC2=CC=1OCC1=CC=CC=C1 WLTCCDHHWYAMCG-UHFFFAOYSA-N 0.000 claims description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 4
- JXBCJUPBVRELNY-UHFFFAOYSA-N [7-(diethylamino)phenothiazin-3-ylidene]-diethylazanium Chemical compound C1=CC(N(CC)CC)=CC2=[S+]C3=CC(N(CC)CC)=CC=C3N=C21 JXBCJUPBVRELNY-UHFFFAOYSA-N 0.000 claims 2
- 235000010290 biphenyl Nutrition 0.000 claims 2
- 239000004305 biphenyl Substances 0.000 claims 2
- 239000002243 precursor Substances 0.000 claims 2
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- 239000000975 dye Substances 0.000 description 45
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- 125000003118 aryl group Chemical group 0.000 description 4
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- 239000000178 monomer Substances 0.000 description 4
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- 238000002835 absorbance Methods 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- JMBUODONIOAHPZ-UHFFFAOYSA-N chembl390388 Chemical compound C1=CC(O)=CC=C1C1=NC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)N1 JMBUODONIOAHPZ-UHFFFAOYSA-N 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000434 metal complex dye Substances 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- FTUYQIPAPWPHNC-UHFFFAOYSA-M sodium;4-[[4-[benzyl(ethyl)amino]phenyl]-[4-[benzyl(ethyl)azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzene-1,3-disulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S([O-])(=O)=O)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 FTUYQIPAPWPHNC-UHFFFAOYSA-M 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
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- GYPMBQZAVBFUIZ-UHFFFAOYSA-N 1,2-dimethoxy-4-methylbenzene Chemical compound COC1=CC=C(C)C=C1OC GYPMBQZAVBFUIZ-UHFFFAOYSA-N 0.000 description 1
- IQKBMBWCUJRFFI-UHFFFAOYSA-N 1-amino-2,3-dihydroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CCCC(N)=C3C(=O)C2=C1 IQKBMBWCUJRFFI-UHFFFAOYSA-N 0.000 description 1
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- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- XUKJDTCEYYOATE-UHFFFAOYSA-N 10h-phenothiazin-1-amine Chemical compound S1C2=CC=CC=C2NC2=C1C=CC=C2N XUKJDTCEYYOATE-UHFFFAOYSA-N 0.000 description 1
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- SQGIIEGQOSBIGJ-UHFFFAOYSA-N 2-[bis[2-(dibutylamino)phenyl]methyl]-n,n-dibutylaniline Chemical compound CCCCN(CCCC)C1=CC=CC=C1C(C=1C(=CC=CC=1)N(CCCC)CCCC)C1=CC=CC=C1N(CCCC)CCCC SQGIIEGQOSBIGJ-UHFFFAOYSA-N 0.000 description 1
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- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- IHXWECHPYNPJRR-UHFFFAOYSA-N 3-hydroxycyclobut-2-en-1-one Chemical group OC1=CC(=O)C1 IHXWECHPYNPJRR-UHFFFAOYSA-N 0.000 description 1
- JDEVVVLLEIZNAL-UHFFFAOYSA-N 4-[[4-(diethylamino)-2-methylphenyl]-[4-(diethylamino)phenyl]methyl]-n,n-diethyl-3-methylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)N(CC)CC)C)C1=CC=C(N(CC)CC)C=C1C JDEVVVLLEIZNAL-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/337—Additives; Binders
- B41M5/3375—Non-macromolecular compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/165—Thermal imaging composition
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- Ink Jet (AREA)
Abstract
それほど強度の高くないエネルギーを適用することで、且つ/又はエネルギーを比較的短時間適用することで、可視マークをより効率的に作り出すことのできる、単一層の発色材料並びにそれを備えた画像形成印刷媒体を提供する。
【解決手段】
本発明の画像形成印刷媒体は、複数の相を有する画像形成組成物(130)を含み、当該画像形成組成物(130)は、アンテナ材料によってエネルギー(110)を吸収する。吸収されたエネルギーによって、活性化剤と発色材料(140)との反応が起こる。
【選択図】図1
Description
本発明は、米国特許出願番号第10/704,993号の一部継続出願である。
以下の説明及び請求の範囲にわたって、特定のシステム成分を指すのに特定の用語を用いる。当業者であれば理解されるように、会社によって、成分の名称は異なる。本明細書は、機能ではなく名称の異なる成分を区別しようとする意はない。以下の説明及び請求の範囲においては、用語「含む(including)」及び「からなる(comprising)」は、非限定的形式で用いられており、従って、「含む、但し限定するものではない」を意味するものと解釈されたい。用語「ロイコ染料」とは、非活性化状態で無色あるいは或る色であり、活性化状態で色を生じるかあるいは変色するところの発色物質である。本明細書で用いるとき、用語「活性化剤」とは、染料と反応して染料の化学構造を変化させ、変色あるいは発色させる物質である。例を示せば、活性化剤には、当該変化を発現させ得るフェノール系化学種又はその他のプロトン供与種を用い得る。用語「アンテナ」とは、任意の放射線吸収化合物を意味し、当該アンテナは、所望の特定の波長のマーキング用放射線を容易に吸収することができる。
110 エネルギー
120 基材
130 画像形成組成物
140 懸濁粒子
Claims (10)
- 画像形成組成物(130)であって、
基質と、
前記基質中に溶解しているアンテナと、
発色剤と、
活性化剤と
を含んで成り、
前記アンテナが、620nm〜680nmの波長の放射線を吸収できるよう適合されており、
前記活性化剤及び前記発色剤のうち一方が、周囲条件で前記基質又は基質前駆体中に溶解することができ、
前記活性化剤及び前記発色剤のうち溶解し得る方が、前記基質中に溶解しており、
前記活性化剤及び前記発色剤のうち他方が、実質的に、基質中に均一に分散している、画像形成組成物。 - 前記アンテナが、1,1’−ジプロピル−3,3,3’,3’−テトラメチルインダジカルボシアニンの塩、1,1’−ジブチル−3,3,3’,3’−テトラメチルインダジカルボシアニンの塩、及び3,7−ビス(ジエチルアミノ)−フェノチアジン−5−イウムの塩から成る群から選択される、請求項1に記載の画像形成組成物。
- 前記発色剤が、ロイコ染料である、請求項1又は2に記載の画像形成組成物。
- 前記発色剤が、融解支援剤と混ぜられている、請求項1〜3の何れか1項に記載の画像形成組成物。
- 前記融解支援剤が、m−テルフェニル、p−ベンジル、ビフェニル、β−ナフトールベンジルエーテル、及び1,2〔ビス(3,4)ジメチルフェニル〕エタンから成る群から選択される、請求項1〜4の何れか1項に記載の画像形成組成物。
- 画像記形成体(100)であって、
基材(120)と、
基質、前記基質中に溶解しているアンテナ、染料、及び活性化剤を含んで成る画像形成組成物(130)と、
を含み、
前記アンテナが、620nm〜680nmの波長の放射線を吸収できるよう適合されており、
前記活性化剤及び前記染料のうち一方が、周囲条件で前記基質又は基質前駆体中に溶解することができ、
前記活性化剤及び前記発色剤のうち溶解し得る方が、前記基質中に溶解しており、
前記活性化剤及び前記発色剤のうち他方が、実質的に、前記基質中に均一に分散している、画像記形成体。 - 前記アンテナが、1,1’−ジプロピル−3,3,3’,3’−テトラメチルインダジカルボシアニンの塩、1,1’−ジブチル−3,3,3’,3’−テトラメチルインダジカルボシアニンの塩、及び3,7−ビス(ジエチルアミノ)−フェノチアジン−5−イウムの塩から成る群から選択される、請求項6に記載の画像形成媒体。
- 前記染料が、ロイコ染料である、請求項6又は7に記載の画像形成媒体。
- 前記染料が、融解支援剤と混ぜられている、請求項6〜8の何れか1項に記載の画像形成媒体。
- 前記融解支援剤が、m−テルフェニル、p−ベンジル、ビフェニル、β−ナフトールベンジルエーテル、及び1,2〔ビス(3,4)ジメチルフェニル〕エタンから成る群から選択される、請求項6〜9の何れか1項に記載の画像形成媒体。
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US20070065749A1 (en) | 2005-09-21 | 2007-03-22 | Vladek Kasperchik | Radiation-markable coatings for printing and imaging |
US20070086308A1 (en) * | 2005-10-13 | 2007-04-19 | Gore Makarand P | Systems and methods for imaging |
US7935471B2 (en) * | 2005-10-20 | 2011-05-03 | Hewlett-Packard Development Company, L.P. | NIR/IR curable coatings for light directed imaging |
US7754413B2 (en) * | 2006-03-10 | 2010-07-13 | Hewlett-Packard Development Company, L.P. | Color forming composition with enhanced image stability |
US20070248918A1 (en) * | 2006-04-25 | 2007-10-25 | Vladek Kasperchik | Compositions, systems and methods for imaging |
US20080020320A1 (en) * | 2006-07-20 | 2008-01-24 | Dorsh Cari L | Color forming composition containing optional sensitizer |
US8293450B2 (en) * | 2006-11-28 | 2012-10-23 | Hewlett-Packard Development Company, L.P. | Laser imaging coating and methods for imaging |
US7892619B2 (en) * | 2006-12-16 | 2011-02-22 | Hewlett-Packard Development Company, L.P. | Coating for optical recording |
US7582408B2 (en) * | 2007-04-27 | 2009-09-01 | Hewlett-Packard Development Company, L.P. | Color forming compositions with a fluoran leuco dye having a latent developer |
WO2009157924A1 (en) | 2008-06-25 | 2009-12-30 | Hewlett-Packard Development Company, L.P. | Image recording media, methods of making image recording media, imaging layers, and methods of making imaging layers |
US8652607B2 (en) * | 2008-06-25 | 2014-02-18 | Hewlett-Packard Development Company, L.P. | Image recording media and imaging layers |
CN105190436A (zh) | 2013-02-27 | 2015-12-23 | 富士胶片株式会社 | 红外线感光性显色组合物、红外线固化性显色组合物、平版印刷版原版和制版方法 |
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