JP2005288928A - Molded object with improved physical strength by dual layer molding - Google Patents

Molded object with improved physical strength by dual layer molding Download PDF

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JP2005288928A
JP2005288928A JP2004108680A JP2004108680A JP2005288928A JP 2005288928 A JP2005288928 A JP 2005288928A JP 2004108680 A JP2004108680 A JP 2004108680A JP 2004108680 A JP2004108680 A JP 2004108680A JP 2005288928 A JP2005288928 A JP 2005288928A
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resin
resin material
molded product
layer
molded object
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Isao Hagiwara
萩原  勲
Sumire Kubota
すみれ 久保田
Hiroshi Saeki
大志 佐伯
Toshikazu Hirasawa
利和 平澤
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Canon Inc
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Canon Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To secure physical strength of a molded object in recycling a regenerated resin as a finished product. <P>SOLUTION: The molded object obtained by recycling the regenerated resin has one of the surface layers which is formed of a thermoplastic resin material and the other surface layer which is formed of a ground resin material as it is obtained by grinding the molded object processed using the thermoplastic resin material. Thus the molded object is dual-layered so that its mechanical strength and flame retardancy are improved. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、再生樹脂を製品へ再利用するにあたり、成形品の物性強度に関するものである。   The present invention relates to the physical property strength of a molded product when recycled resin is reused in a product.

特に、一方の表層部を熱可塑性樹脂材料で形成し、また他の層部を熱可塑性樹脂材料で成形加工した成形品を粉砕し再生された材料で形成された二層成形構造の成形品に関する。   In particular, the present invention relates to a molded article having a two-layer molded structure formed of a material obtained by pulverizing a molded product in which one surface layer portion is formed of a thermoplastic resin material and the other layer portion is molded using a thermoplastic resin material. .

又、本発明は、前記熱可塑性樹脂材料の成形品を粉砕処理して、該粉砕した樹脂材料のまま射出成形加工の樹脂原料とする技術に関する。   The present invention also relates to a technique for pulverizing a molded article of the thermoplastic resin material and using the pulverized resin material as a resin raw material for injection molding.

さらに本発明は、複写機、プリンターなどの画像形成装置、ファクシミリ、コンピュータなどの情報通信機器、家庭電化機器等に使用されているプラスチック樹脂材料のリサイクル技術に関する。   The present invention further relates to a technology for recycling plastic resin materials used in image forming apparatuses such as copying machines and printers, information communication equipment such as facsimile machines and computers, and home appliances.

市場から回収された製品は、従来は分解され焼却または埋め立てにより処理されて来た。   Products collected from the market have traditionally been decomposed and processed by incineration or landfill.

また、環境問題が意識されるようになると、これらのプラスチック部品を粉砕リペレット化して未使用樹脂材料同等レベルにする技術等により再利用が行われている。すなわち、これらの材料に対するリサイクル方法として、成形品を粉砕、洗浄、再ペレット化を行った後、未使用樹脂材料(バージンペレット)と上記の使用済みの樹脂材料とを一定の割合で混合して物性を回復する処置を講じて使用する方法が提案されている。また、2種類の樹脂材料を成形用金型のキャビテイに射出してコア層を構成する樹脂成形部分と、スキン層を構成する樹脂成形部分とから成るサンドイッチ構造の射出成形法に代表されるような多層構造を利用した再生方法がある。   In addition, when environmental problems become conscious, these plastic parts are reused by a technique of pulverizing and re-pelletizing them to the same level as unused resin materials. That is, as a recycling method for these materials, after molding products are pulverized, washed, and re-pelletized, unused resin materials (virgin pellets) and the above-mentioned used resin materials are mixed in a certain ratio. A method for taking measures to recover physical properties has been proposed. In addition, it is represented by an injection molding method having a sandwich structure composed of a resin molding part constituting a core layer and a resin molding part constituting a skin layer by injecting two kinds of resin materials into a cavity of a molding die. There is a reproduction method using a multi-layer structure.

再生樹脂を利用したこれらの技術については、特許文献1、特許文献2、特許文献3、特許文献4等ある。また、機械強度に関しては、特許文献5等がある。しかし、現状ではこれらの再生法では再生材の使用率が30%程度と低く、再生材を一つの成形品に多量に使用することは出来ない。また、機械強度についても、充分な強度が明確に確保されていない。一方、再生材100%の成形品では、複写機、プリンター、ファクシミリ等の、画像形成機器、情報通信機器の構成部品である、外装品、筐体、機構部品に対し充分な強度が確保されていない。
特開2002−86491号公報 特開平5−301222号公報 特開平5−147036号公報 特開2000−108124号公報 特開2002−347186号公報
As for these techniques using recycled resin, there are Patent Document 1, Patent Document 2, Patent Document 3, Patent Document 4, and the like. Moreover, there exists patent document 5 etc. regarding mechanical strength. However, under these current recycling methods, the usage rate of the recycled material is as low as about 30%, and the recycled material cannot be used in a large amount in one molded product. In addition, sufficient mechanical strength is not clearly ensured. On the other hand, molded products made of 100% recycled material have sufficient strength for exterior parts, casings, and mechanical parts that are components of image forming equipment and information communication equipment such as copying machines, printers, and facsimiles. Absent.
JP 2002-86491 A Japanese Patent Laid-Open No. 5-301222 Japanese Patent Laid-Open No. 5-147036 JP 2000-108124 A JP 2002-347186 A

本発明の課題は再生材を使用して上記の問題の解決の糸口とする場合の、部品強度の低下対策にある。   The subject of this invention exists in the countermeasure against a fall of component intensity | strength when using a recycled material as a clue of the solution of said problem.

すなわち、本発明の課題の1つは、再生材を使用した成形品の二層成形による強度改善を提案することにある。   That is, one of the objects of the present invention is to propose strength improvement by two-layer molding of a molded product using a recycled material.

又、本発明の課題の他の1つは、再利用する樹脂成形品を粉砕処理した材料のまま使用することにより再利用する樹脂材料の熱履歴による物性劣化を避けると共に更に二層成形による強度改善を提案する。   Further, another object of the present invention is to avoid deterioration of physical properties due to the heat history of the resin material to be reused by using the resin molded product to be reused as a pulverized material, and to further improve the strength by two-layer molding. Suggest improvements.

これらは、前記した複写機、プリンター、ファクシミリ等の、画像形成機器、情報通信機器の構成部品である、外装品、筐体、機構部品などの平板構造から構成している。   These are composed of flat plate structures such as exterior parts, casings, and mechanical parts, which are constituent parts of image forming apparatuses and information communication apparatuses such as the above-described copying machines, printers, and facsimiles.

そして、このような筐体部は機械的強度を保証する必要があるが、100%の再生材を使用すると、再生材の物性値の劣化による前記機能部の機能保証を得ることが困難であった。   Such a casing portion needs to guarantee mechanical strength. However, when 100% recycled material is used, it is difficult to obtain functional guarantee of the functional unit due to deterioration of physical property values of the recycled material. It was.

本発明は上記課題を解決するために、一方の表層と他の層から成る二層構造の樹脂成形品であって、前記他の層の一部を構成する樹脂材料は熱可塑性樹脂材料を成形加工した成形品を粉砕した粉砕樹脂材料のまま用い、前記表層を構成する樹脂材料はバージン材料で成形加工したことを特徴とした二層構造による樹脂成形品の強度改善を提案する。   In order to solve the above-mentioned problems, the present invention is a resin-molded product having a two-layer structure composed of one surface layer and another layer, and the resin material constituting a part of the other layer is formed from a thermoplastic resin material. We propose to improve the strength of a resin molded product with a two-layer structure in which the processed molded product is used as a pulverized resin material and the resin material constituting the surface layer is molded with a virgin material.

上記発明には、前記樹脂成形品が事務機器、電気機器、情報通信機器等の外装部品、筐体部品又は構成部品であることを特徴とした二層構造の樹脂成形品の態様がある。   In the above-mentioned invention, there is an embodiment of a resin molded product having a two-layer structure, wherein the resin molded product is an exterior part, a casing part or a component part of office equipment, electrical equipment, information communication equipment and the like.

更に、前記他の層の一部を構成する樹脂材料の原料は事務機器の外装品または事務機器の筐体、構成部品の樹脂成形品を粉砕加工処理した樹脂材料であることを特徴とした二層構造の樹脂成形品の態様がある。   Further, the raw material of the resin material constituting a part of the other layer is a resin material obtained by pulverizing and processing office equipment exterior parts or office equipment casings and resin moldings of constituent parts. There is an embodiment of a resin molded product having a layer structure.

又、本発明の他の1つは、一方の表層を構成する樹脂材料とその他の層を構成する樹脂材料を成形用金型に夫々射出した二層構造の樹脂成形品であって、前記その他の層の一部を構成する樹脂材料は熱可塑性樹脂材料を成形加工した樹脂成形品を粉砕加工し、粉砕した樹脂材料の大きさを所定の大きさに基準設定した樹脂材料を使用するようにしたことを特徴とした二層構造による樹脂成形品の強度改善を提案する。   Another aspect of the present invention is a resin molded product having a two-layer structure in which a resin material constituting one surface layer and a resin material constituting the other layer are respectively injected into a molding die. As the resin material that constitutes a part of the layer, a resin molded product obtained by molding a thermoplastic resin material is pulverized, and a resin material in which the size of the pulverized resin material is set to a predetermined size is used. We propose to improve the strength of resin molded products by the two-layer structure.

前記二層構造の樹脂成形品は画像形成装置の外装部品または筐体部品、構成部品であることを特徴とする。   The two-layered resin molded product is an exterior part, a casing part, or a component part of an image forming apparatus.

更に本発明の他の1つは、一方の表層とその他の層から成る二層構造の樹脂成形品であって、前記その他の層の一部を構成する樹脂材料は熱可塑性樹脂材料を成形加工した成形品を粉砕した粉砕樹脂材料を用い、前記表層を構成する樹脂材料はバージン材料で成形するとともに、前記表層を構成する樹脂材料は前記粉砕加工した樹脂材料と同種の樹脂材料を使用して成形加工したことを特徴とした二層構造による樹脂成形品の強度改善を提案する。   Furthermore, another one of the present invention is a two-layered resin molded product composed of one surface layer and another layer, and the resin material constituting a part of the other layer is formed by molding a thermoplastic resin material. Using the pulverized resin material obtained by pulverizing the molded product, the resin material constituting the surface layer is molded with a virgin material, and the resin material constituting the surface layer is the same type of resin material as the pulverized resin material. We propose to improve the strength of resin molded products with a two-layer structure characterized by molding.

更に、本発明の他の1つは、前記熱可塑性樹脂材料をPC+ABS樹脂材料とすることを特徴とした二層構造による樹脂成形品の強度改善を提案する。   Furthermore, another one of the present invention proposes improvement of the strength of a resin molded product by a two-layer structure characterized in that the thermoplastic resin material is a PC + ABS resin material.

本発明に拠れば、表層とその他の層から成る二層構造の樹脂成形品であって、前記その他の層の一部を構成する樹脂材料は熱可塑性樹脂材料を成形加工した成形品を粉砕したままの粉砕樹脂材料を用い、前記少なくとも一方の表層を構成する樹脂材料はバージン材料を使用して成形加工したことを特徴とした二層構造の樹脂成形品により、熱履歴による物性劣化をおさえ、再生材の使用率が高く、更にリペレット工程を経ない低コストで成形品の強度アップを図ることができた。   According to the present invention, a resin molded product having a two-layer structure composed of a surface layer and other layers, wherein the resin material constituting a part of the other layers is a molded product obtained by molding a thermoplastic resin material. The resin material of the two-layer structure is characterized in that the resin material constituting the at least one surface layer is molded using a virgin material, and the physical property deterioration due to thermal history is suppressed. The usage rate of the recycled material was high, and the strength of the molded product could be increased at a low cost without going through the repellet process.

又、前記樹脂成形品は事務機器、電気機器、情報通信機器等の外装部品または筐体部品とすることにより環境問題への解決点を提案できた。   Further, the resin molded product can be proposed as a solution to environmental problems by using exterior parts or casing parts of office equipment, electrical equipment, information communication equipment, and the like.

(実施例)
以下の実施例1〜2、比較例1〜2に対し、評価方法は以下のとおりである。
(Example)
The evaluation methods are as follows for the following Examples 1-2 and Comparative Examples 1-2.

シャルピー衝撃試験:JISK7111に順じた測定。   Charpy impact test: Measurement according to JISK7111.

難燃試験UL94燃焼試験に順じた試験。   Flame retardant test A test that complies with UL94 combustion test.

PC−ABSバージン樹脂で積層厚1mを一方の表面とし、PC+ABSリサイクル粉砕樹脂で積層厚2mmを他方の表面とした計3mm厚からなる二層成形品(図1)   PC-ABS virgin resin with a laminate thickness of 1m on one surface and PC + ABS recycled pulverized resin with a laminate thickness of 2mm on the other surface, a two-layer molded product (3mm in total) (Figure 1)

PC+ABSバージン樹脂で積層厚1mを一方の表面とし、PC+ABSリサイクル樹脂で積層厚2mmを他方の表面とした計3mm厚からなる二層成形品(図1)
(比較例1)
PC+ABSリサイクル粉砕樹脂積層厚3mmからなる成形品
(比較例2)
PC+ABSリサイクル樹脂積層厚3mmからなる成形品
PC + ABS virgin resin with a laminate thickness of 1m on one surface and PC + ABS recycled resin with a laminate thickness of 2mm on the other surface, a two-layer molded product (3mm in total) (Figure 1)
(Comparative Example 1)
Molded product consisting of 3mm thick PC + ABS recycled crushed resin (Comparative Example 2)
Molded product consisting of 3mm thick PC + ABS recycled resin

Figure 2005288928
Figure 2005288928

PC+ABSリサイクル樹脂で積層厚2mmを他方の表面とした計3mm厚からなる二層成形品A two-layer molded product with a total thickness of 3mm with PC + ABS recycled resin and a laminated thickness of 2mm on the other surface

Claims (3)

再生樹脂を再利用した成形品で、一方の表層部を熱可塑性樹脂材料で形成し、また他の層部を熱可塑性樹脂材料で成形加工した成形品を粉砕した粉砕樹脂材料のままで二層成形する事による機械強度及び耐難燃性を改善させた成形品。   A molded product made from recycled resin, with one surface layer made of a thermoplastic resin material and the other layer molded with a thermoplastic resin material. Molded product with improved mechanical strength and flame resistance. 再生樹脂を再利用した成形品で、一方の表層部を熱可塑性樹脂材料で形成し、また他の層部を熱可塑性樹脂材料のリサイクル材で二層成形する事による機械強度及び耐難燃性を改善させた成形品。   A molded product made from recycled resin, with one surface layer formed from a thermoplastic resin material and the other layer formed from two layers of thermoplastic resin recycled material to provide mechanical strength and flame resistance. Improved molded product. 請求項1〜2に記載した熱可塑性樹脂材料がPC+ABSであることを特徴とする二層成形品。   A two-layer molded article, wherein the thermoplastic resin material according to claim 1 or 2 is PC + ABS.
JP2004108680A 2004-04-01 2004-04-01 Molded object with improved physical strength by dual layer molding Withdrawn JP2005288928A (en)

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