JP3031357B1 - Sandwich molded products containing recycled materials - Google Patents

Sandwich molded products containing recycled materials

Info

Publication number
JP3031357B1
JP3031357B1 JP28392598A JP28392598A JP3031357B1 JP 3031357 B1 JP3031357 B1 JP 3031357B1 JP 28392598 A JP28392598 A JP 28392598A JP 28392598 A JP28392598 A JP 28392598A JP 3031357 B1 JP3031357 B1 JP 3031357B1
Authority
JP
Japan
Prior art keywords
recycled
core
core material
resin
sandwich
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP28392598A
Other languages
Japanese (ja)
Other versions
JP2000108124A (en
Inventor
恂一 松浦
正彦 大塚
利喜弘 岡本
英明 島田
保治 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP28392598A priority Critical patent/JP3031357B1/en
Application granted granted Critical
Publication of JP3031357B1 publication Critical patent/JP3031357B1/en
Publication of JP2000108124A publication Critical patent/JP2000108124A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Laminated Bodies (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

【要約】 【課題】 成形品中の再生材の含有率を高くすること、
及びその成形品を再度同種の製品の再生材として再利用
を可能にすることを目的とする。 【解決手段】 芯材と該芯材の全表面を被覆する表面材
とからなるサンドイッチ成形品において、表面材と芯材
の両方に再生材を含有し、表面材と芯材の樹脂が同種の
樹脂で構成されるサンドイッチ成形品。
Abstract: [PROBLEMS] To increase the content of recycled materials in a molded article;
Another object of the present invention is to enable the molded article to be reused as a recycled material of the same product. SOLUTION: In a sandwich molded product comprising a core material and a surface material covering the entire surface of the core material, a regenerated material is contained in both the surface material and the core material, and the resin of the surface material and the resin of the core material are the same. Sandwich molded product composed of resin.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】再生材を製品へ再利用するた
めに、再生材を未使用材に混合するに際して、(1)再
生材中の異物や物性上の問題から再生材の含有率を高め
ることが困難にもかかわらず含有率を高めたい、(2)
成形品を再度同種の製品に再使用したい、これら(1)
(2)の期待が併せて求められる場合に本発明は有用で
ある。
BACKGROUND OF THE INVENTION In order to recycle a recycled material into a product, when mixing the recycled material with an unused material, (1) increase the content of the recycled material due to foreign matter in the recycled material and problems in physical properties. Want to increase the content despite difficulties, (2)
Want to reuse molded articles for similar products again.
The present invention is useful when the expectation (2) is also required.

【0002】このような目的に使用する場合であれば特
に製品の種類は問わないが、電気電子機器の部品は難燃
性の規格を満足する必要があり、再使用するには樹脂の
種類のみならず難燃剤の種類を同種にすることが規格取
得を容易にする要件であり、このような製品への使用が
特に有用である。
[0002] If used for such purposes, the type of product is not particularly limited, but the parts of electrical and electronic equipment must satisfy the flame retardancy standard. Rather, it is a requirement to make it easier to obtain standards by making the types of flame retardants the same, and use in such products is particularly useful.

【0003】[0003]

【従来の技術】サンドイッチ成形及び同成形品は公知で
あり、サンドイッチ成形を有効に実施するための金型技
術や成形技術について多くの報告がある。またサンドイ
ッチ成形品についても自動車部品、家電製品等各種の製
品へのサンドイッチ成形の適用が試みられている。サン
ドイッチ成形を適用する目的は芯材に電磁シールド材や
発泡材など特定の機能を有する材料を使用して、製品の
外観や物性はあまり変えずに特定の機能を賦与すること
があげられる。再生材は品質上欠点がある場合が多い
これを芯材へ使用し、表面材には新しい材料を使用して
外観上問題のない製品を得ることも一般に知られた考え
方である。
2. Description of the Related Art Sandwich molding and molded articles are known, and there are many reports on mold techniques and molding techniques for effectively performing sandwich molding. As for sandwich molded products, application of sandwich molding to various products such as automobile parts and home electric appliances has been attempted. The purpose of applying the sandwich molding is to use a material having a specific function such as an electromagnetic shielding material or a foam material as a core material, and to impart a specific function without significantly changing the appearance and physical properties of the product. Recycled materials often have defects in quality, but it is a generally known idea to use this as a core material and to use a new material as a surface material to obtain a product having no problem in appearance.

【0004】従来の考え方は前項に述べたように再生材
を芯材として使用するものである。即ち再生材は一般に
使用後の製品から得られるので、付着した汚れの除去が
問題であり、もしサンドイッチ成形によって、これを芯
材にのみ使用し、表面材には新しい材料を使用すれば、
仮に汚れがあってもこれを内部に隠し表面は新しい材料
のみから成形した成形品と何ら変わらない成形品が得ら
れる。
[0004] The conventional idea is to use a recycled material as a core material as described in the preceding section. In other words, since recycled materials are generally obtained from products after use, removal of adhered dirt is a problem.If sandwich molding is used only for the core material and if a new material is used for the surface material,
Even if there is dirt, it can be hidden inside and a molded article whose surface is no different from a molded article molded from only a new material can be obtained.

【0005】更に極端に言えば、芯材として、表面材と
色の異なる材料、他の製品からの材料、異物を含む材料
など成形さえできれば使用可能である。
[0005] In a more extreme case, as the core material, a material different in color from the surface material, a material from another product, a material containing foreign matter, etc. can be used as long as it can be molded.

【0006】[0006]

【発明が解決しようとする課題】 しかしこのような成形
品を再度回収使用しようとしても、低品質の成形品への
使用やサーマルリサイクルする以外は困難な場合が多
い。また電気電子機器の場合には難燃性の規格の取得が
必要な場合があり、表面材や芯材に含まれる樹脂や難燃
剤の種類や含有量を制御する必要があるので、従来知ら
れているサンドイッチ成形に再生材を使用する概念のみ
では、該成形品を再度同じ製品の成形品に使用すること
は困難である。
If you try again recovered using However, such a molded article [0006], the case except that the use and thermal recycling to low-quality molded articles difficult in many cases. In the case of electrical and electronic equipment, it may be necessary to obtain flame retardancy standards, and it is necessary to control the type and content of the resin and flame retardant contained in the surface material and core material. It is difficult to use the molded product again for a molded product of the same product only with the concept of using a recycled material for sandwich molding.

【0007】[0007]

【課題を解決するための手段】本発明の特徴は、表面材
にも再生材を使用し、成形品全体に占める再生材の含有
率を従来の芯材のみに再生材を使用する場合に比べて高
くすると同時に、表面材と芯材に再生材の含有率は異な
っても良いが、それ以外は同種の樹脂を使用し、再度同
種の製品にマテリアルリサイクルすることが容易な成形
品を提供する点にある。
The feature of the present invention is that the recycled material is used also for the surface material, and the content of the recycled material in the whole molded product is reduced as compared with the case where the recycled material is used only for the conventional core material. At the same time, the content of the recycled material may be different between the surface material and the core material, but other than that, the same type of resin is used, and a molded product that is easy to material-recycle again to the same type of product is provided. On the point.

【0008】ここで同種の樹脂とは樹脂の種類のみなら
ず、難燃剤の種類も同じで、できれば色調も同じ系統の
材料を意味する。このような材料を表面材、芯材に使用
すれば成形品を破砕、洗滌後、少しの色材、難燃剤等の
追加、さらに未使用の樹脂との混練りにより物性、難燃
性、色調がもとの樹脂銘柄と殆ど変わらない(本発明で
はこれを同種の樹脂と表現する)再生材含有ペレットを
調製して再度同種の製品の成形品に使用することができ
る。
Here, the same kind of resin means not only the kind of the resin but also the kind of the flame retardant, and preferably the same kind of material having the same color tone. If such a material is used for the surface material and the core material, the molded product is crushed and washed, then a small amount of a coloring material, a flame retardant, etc. are added, and further, the physical properties, flame retardancy, color tone are obtained by kneading with an unused resin. It is possible to prepare a recycled material-containing pellet which is almost the same as the original resin brand (in the present invention, this is referred to as a resin of the same kind) and use it again for a molded article of the same kind of product.

【0009】近年、環境問題で廃製品の処理が社会問題
となっていて、サーマルリサイクルとしてエネルギーと
しての利用やマテリアルリサイクルとして材料として再
利用することが必要になっている。
In recent years, disposal of waste products has become a social problem due to environmental problems, and it has become necessary to use it as energy for thermal recycling and to reuse it as a material for material recycling.

【0010】マテリアルリサイクルについては、品質が
低くてもよい他の製品へ利用する方法もあるが、できれ
ば同じ製品に再使用することが望まれる。同じ製品に再
利用するには、材料の汚れの無さや、物性の低下の無い
ことが求められる。
[0010] As for material recycling, there is a method of using it for other products whose quality may be low, but it is desirable to reuse it for the same product if possible. In order to reuse the same product, it is required that the material is free from contamination and that the physical properties do not deteriorate.

【0011】特に電気電子機器は、米国のUL難燃規格
が必要な場合が多く、使用するプラスチック筐体に再生
材を使用する場合には樹脂の種類のみならず、難燃剤等
の添加剤の種類についても一定である必要がある。
In particular, electric and electronic equipment often requires the UL flame retardant standard of the United States. When a recycled material is used for a plastic casing to be used, not only the type of resin but also additives such as a flame retardant are used. The type also needs to be constant.

【0012】再生材を再使用するに際して、使用後の廃
製品から選別、破砕、洗滌、乾燥等の後処理を経て得た
再生材ペレットに汚れや物性の問題がなければそのまま
成形して製品に再使用できるが、多くの場合汚れの除去
が不十分で、半分以上の未使用の新しい材料に再生材を
部分的に混合して使用することが必要であり、再生材の
含有率を高めることが難しい。
When the recycled material is reused, if the recycled material pellets obtained through post-processing such as sorting, crushing, washing, and drying from the used waste product are free from dirt and physical properties, they are directly formed into products. It can be reused, but in many cases the dirt is not sufficiently removed, and it is necessary to partially mix the recycled material with at least half of the unused new material. Is difficult.

【0013】このような場合にサンドイッチ成形法によ
れば、成形品の表面層には未使用の新しい材料との混合
材料を使用し、コア層(芯の部分)には100%の再生
材そのものを使用して再生材の使用比率を高めることが
できる。
In such a case, according to the sandwich molding method, a mixed material with an unused new material is used for a surface layer of a molded article, and a 100% recycled material itself is used for a core layer (core portion). Can be used to increase the usage ratio of the recycled material.

【0014】さらに表面層(この部分の材料を表面材と
言う)とコア層(この部分の材料を芯材と言う)に、再
生材の含有率(再生材と未使用の新しい材料の混合物中
の再生材の百分率)のみが異なり、樹脂の種類、難燃剤
等の種類は同じ材料(同種の材料と言う)を使用すれ
ば、成形品を使用後に後処理して得た再生材は既にその
製品の材料として申請しているUL難燃規格の成分に合
致し、そのまま再度リサイクルして同じ製品に使用する
ことができる。
Further, the surface layer (the material in this portion is referred to as a surface material) and the core layer (the material in this portion is referred to as a core material) are provided with a content ratio of a recycled material (in a mixture of the recycled material and an unused new material). Only the percentage of recycled material) and the same type of resin, flame retardant, etc. (the same type of material) can be used. The material conforms to the UL flame retardant standard that has been applied as a material of the product, and can be recycled as it is and used for the same product.

【0015】本発明の主旨は芯材と該芯材の全表面を被
覆する表面材からなるサンドイッチ成形品において、芯
材と表面材がともに再生材を含有し、再生材の含有率の
みが異なる同種の樹脂を使用して、再生材の含有率の向
上と再度マテリアルリサイクルすることを狙いとする成
形品を提供する点にある。
The gist of the present invention is that in a sandwich molded article comprising a core material and a surface material covering the entire surface of the core material, both the core material and the surface material contain recycled materials, and only the content ratio of the recycled materials differs. It is an object of the present invention to provide a molded article that aims to increase the content of a recycled material and recycle the material again by using the same kind of resin.

【0016】[0016]

【発明の実施の形態】以下本発明を更に具体的に説明す
る。本発明のサンドイッチ成形品の表面材及び芯材の樹
脂の種類は特に限定しないが、ポリエチレン、ポリプロ
ピレンなどのポリオレフィン、ゴム成分などによるポリ
オレフィンの耐衝撃性改質材料、ポリ塩化ビニル、ポリ
スチレン、衝撃性改良ポリスチレン、アクリロニトリル
−スチレン共重合体、アクリロニトリル−スチレン−ブ
タジエン共重合体(ABS樹脂)、ポリカーボネート、
ポリカーボネート−ABS樹脂のアロイポリマー、ポリ
カーボネート−ポリスチレンのアロイポリマー、ポリカ
ーボネート−ポリエステルのアロイポリマー、ポリカー
ボネート−ポリアミドのアロイポリマー、変性ポリフェ
ニレンエーテル樹脂、同ポリスチレンとの混合物、ナイ
ロンなどのポリアミド、ポリアミドを含むアロイポリマ
ー、ポリオキシメチレン、ポリエチレンテレフタレー
ト、ポリブチレンテレフタレート、各種の液晶ポリマー
などが挙げられる。望ましい樹脂は高衝撃性ポリスチレ
ン、ABS樹脂、変性PPO、ポリカーボネート、ポリ
カーボネート−ABS樹脂アロイポリマー、ポリカーボ
ネート−ポリスチレンアロイポリマーなど電気電子機器
の筐体に通常使用される材料である。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described more specifically. The type of the resin of the surface material and the core material of the sandwich molded product of the present invention is not particularly limited, but polyolefins such as polyethylene and polypropylene, impact resistance modifying materials of polyolefins by rubber components, polyvinyl chloride, polystyrene, impact resistance Improved polystyrene, acrylonitrile-styrene copolymer, acrylonitrile-styrene-butadiene copolymer (ABS resin), polycarbonate,
Polycarbonate-ABS resin alloy polymer, Polycarbonate-Polystyrene alloy polymer, Polycarbonate-Polyester alloy polymer, Polycarbonate-Polyamide alloy polymer, Modified polyphenylene ether resin, Mixture with the same polystyrene, Polyamide such as nylon, Alloy polymer containing polyamide , Polyoxymethylene, polyethylene terephthalate, polybutylene terephthalate, various liquid crystal polymers, and the like. Desirable resins are high-impact polystyrene, ABS resin, modified PPO, polycarbonate, polycarbonate-ABS resin alloy polymer, polycarbonate-polystyrene alloy polymer, and other materials normally used for the housing of electric and electronic equipment.

【0017】本発明に使用される樹脂は、米国UL(ア
ンダーライターズラボラトリーズ)難燃規格のUL94
HB、UL94V−2、UL94V−1、UL94V−
0、UL945V等いづれの段階の材料でもよい。
The resin used in the present invention is a UL94 (Underwriters Laboratories) flame retardant standard of the United States.
HB, UL94V-2, UL94V-1, UL94V-
0, UL945V, or any other material.

【0018】難燃化材料の場合、材料中に含まれる難燃
剤を特に限定しないが、三光出版社刊「やさしいプラス
チック配合剤」社団法人日本合成樹脂技術協会監修、1
2、13頁記載の臭素系、塩素系、燐系、無機系の難燃
剤、また本文献には記載がないがシリコーン系の難燃剤
が例示される。勿論難燃剤を含まない樹脂、色材、無機
フィラー、ガラス繊維、炭素繊維、その他の難燃剤以外
の添加剤を含有する樹脂も本発明の材料に含まれる。
In the case of the flame retardant material, the flame retardant contained in the material is not particularly limited, but it is supervised by Sanko Shuppan Co., Ltd.
Brominated, chlorine-based, phosphorus-based and inorganic flame retardants described on pages 2 and 13 and silicone-based flame retardants which are not described in this document are exemplified. Of course, the material of the present invention also includes resins containing no flame retardant, coloring materials, inorganic fillers, glass fibers, carbon fibers, and other additives containing additives other than flame retardants.

【0019】本発明で使用される樹脂は、芯材と表面材
のそれぞれについて、新しい材料との混合物の場合に
は、再生材と新しい材料が同種の樹脂であることを特徴
とする。ここで言う同種とは、非難燃の樹脂同志を混合
する場合及び非難燃の樹脂と難燃樹脂を混合する場合は
樹脂の種類が同じであることを、難燃化樹脂同志を混合
する場合は難燃剤の種類も同じ材料を意味する。
The resin used in the present invention is characterized in that, in the case of a mixture of a core material and a surface material with a new material, the recycled material and the new material are the same type of resin. The same kind here means that when mixing non-flame-retardant resins and when mixing non-flame-retardant resin and flame-retardant resin, the type of resin is the same, and when mixing flame-retardant resins, The type of flame retardant means the same material.

【0020】さらに、芯材と表面材も同種の材料を使用
するが、ここでの同種の意味も前記と同じである。即ち
芯材と表面材の両方が非難燃樹脂の場合及び一方が難燃
樹脂の場合は樹脂の種類のみが同じことを意味し、両方
が難燃樹脂の場合は樹脂の種類と難燃剤の種類が共に同
じことを意味する。但し、再生材の含有量は同じでも良
いが通常は芯材と表面材で異なり、芯材中の再生材の含
有率の方が高い。 [芯材と表面材の割合]芯材と表面材の割合は特に限定
しないが、通常は芯材と表面材の合計を100重量部と
するとき、芯材が10重量部乃至40重量部である。成
形品の肉厚が大きい場合には、芯材を多く封入できるの
で芯材の割合を40重量部より大きくできるが、一方表
面材の割合が小さくなり、極端な場合には何も表面層に
再生材を使用しなくても、芯材だけで再生材の含有率を
大きくできるので、表面材には汚れに心配のない未使用
の新しい材料を使用する方が汚れ等の問題がなくて有利
である。
Further, the same material is used for the core material and the surface material, and the same meaning here is the same as described above. That is, when both the core material and the surface material are non-flame-retardant resins and when one is a flame-retardant resin, it means that only the type of resin is the same, and when both are flame-retardant resins, the type of resin and the type of flame retardant Mean the same thing. However, the content of the recycled material may be the same, but usually differs between the core material and the surface material, and the content of the recycled material in the core material is higher. [Ratio of core material and surface material] The ratio of the core material and the surface material is not particularly limited, but usually, when the total of the core material and the surface material is 100 parts by weight, the core material is 10 to 40 parts by weight. is there. When the thickness of the molded product is large, the core material can be encapsulated in a large amount, so that the ratio of the core material can be larger than 40 parts by weight. On the other hand, the ratio of the surface material becomes small. Even without using recycled materials, the content of recycled materials can be increased only by the core material, so it is more advantageous to use unused new materials that do not have to worry about dirt on the surface material because there is no problem such as dirt It is.

【0021】また芯材の割合が10重量部より小さい場
合にはサンドイッチ成形する意義は小さく、再生材を1
0重量%含有する材料を通常の射出成型で成形する場合
と比べて再生材の含有率は大差ない。以上の理由で通常
芯材の割合は10重量部乃至40重量部となるが、電気
電子製品の筐体のように肉厚が3mm程度の場合には芯
材の割合はほぼこの範囲に相当する。 [芯材中の再生材の割合]芯材中の再生材の割合は30
重量%乃至100重量%である。再生材の含有率を大き
くするためには100重量%が望ましいが、成形品を再
度マテリアルリサイクルするために色の調製、難燃剤の
追加、特に難燃規格UL94HBの再生材を難燃化して
使用する場合には数十%の薬剤の添加、物性補強のため
の新しい材料の添加などが必要な場合があり、30重量
%乃至100重量%を範囲とする。 [表面材中の再生材の割合]表面材中の再生材の割合は
5重量%乃至50重量%である。表面材中に50重量%
より多くの再生材を含有させても汚れ等の問題がない材
料であれば、通常の射出成形でも成形品中の再生材の含
有率を大きくすることができサンドイッチ成形を採用し
なくてもよい。また表面材中の再生材の割合が5重量%
より少ない場合は成形品中の再生材含有率を大きくする
ために表面層にわざわざ再生材を使用するより、新しい
材料を使用する方が汚れ等の問題が無くて良い。従って
5重量%乃至50重量%を範囲とする。 [成形方法]本発明の成形品は、プラスチックの分野に
おいてサンドイッチ成形として通常実施されている成形
方法によって成形することができる。
When the ratio of the core material is less than 10 parts by weight, the significance of sandwich molding is small, and
The content of the recycled material is not much different from the case where the material containing 0% by weight is molded by ordinary injection molding. For the above reasons, the ratio of the core material is usually 10 to 40 parts by weight, but when the wall thickness is about 3 mm as in the case of electric and electronic products, the ratio of the core material substantially corresponds to this range. . [Rate of recycled material in core material] The ratio of recycled material in the core material is 30.
% By weight to 100% by weight. To increase the content of recycled materials, 100% by weight is desirable. However, in order to recycle the molded product again, the color is adjusted and a flame retardant is added. In some cases, it may be necessary to add several tens of percent of a drug or a new material for reinforcing physical properties, and the range is 30% to 100% by weight. [Ratio of Recycled Material in Surface Material] The ratio of the recycled material in the surface material is 5% by weight to 50% by weight. 50% by weight in the surface material
If the material does not have a problem such as contamination even if a larger amount of recycled material is contained, the content of the recycled material in the molded product can be increased even by ordinary injection molding, and it is not necessary to adopt sandwich molding. . 5% by weight of recycled material in the surface material
When the amount is smaller, the use of a new material is less likely to cause problems such as dirt than the use of a recycled material in the surface layer in order to increase the content of the recycled material in the molded article. Therefore, the range is 5% by weight to 50% by weight. [Molding method] The molded article of the present invention can be molded by a molding method usually carried out as sandwich molding in the field of plastics.

【0022】図1に示すように、サンドイッチ成形方法
は、はじめに表面層の材料(表面材2)を注入口4より
注入し、続いてコア層の材料(芯材1)を注入口4より
注入して射出し、最後に注入口4から少量の表面層の材
料を射出する。このサンドイッチ成形方法については、
例えば「合成樹脂」Vol.39,No.9(1993
年9月号)17頁,21頁に記載されている。
As shown in FIG. 1, in the sandwich molding method, first, the material of the surface layer (surface material 2) is supplied from the injection port 4.
After the injection , the material of the core layer (core material 1) is injected and injected from the injection port 4, and finally a small amount of the material of the surface layer is injected from the injection port 4. About this sandwich molding method,
For example, “Synthetic resin” Vol. 39, no. 9 (1993
September issue), page 17, page 21.

【0023】以下、先ず実施した材料の調製方法を述
べ、続いて参考例、実施例、比較例によって本発明を詳
しく説明するが、本発明の範囲はこれらの実施例の内容
に限定されるものではない。なお、材料のUL難燃規格
は、UL94を省略し、成形品の肉厚を示す1/12″
(1/12インチ)を加えて、1/12″HB、1/1
2″V−0と記載する。 [材料の調製(1)]日本電気(株)製デスクトップパ
ソコンの特定機種の廃製品を集め、その中から難燃化ポ
リスチレン(米国のUL難燃規格1/12″V−0品)
を材料とするディスプレイの筐体を選別して、それらに
付着する紙ラベル、金属ラベル等の異種材料を除いた。
Hereinafter, the method of preparing the materials will be described first, and then the present invention will be described in detail with reference examples, examples, and comparative examples. However, the scope of the present invention is limited to the contents of these examples. is not. In addition, the UL flame-retardant standard of the material omits UL94, and indicates 1/12 ″ indicating the thickness of the molded product.
(1/12 inch) and add 1/12 "HB, 1/1
2 "V-0. [Preparation of material (1)] Waste products of a specific type of desktop personal computer manufactured by NEC Corporation were collected, and flame retarded polystyrene (U.S. UL flame retardant standard 1 / 12 "V-0 product)
The display casings made of the above materials were sorted out, and different kinds of materials such as paper labels and metal labels attached to them were removed.

【0024】更にこれらを破砕、洗滌して後、混練り機
で調色、ペレット化し、UL難燃規格1/12″V−0
の白い再生材ペレットを得た。この再生材ペレットを材
料A100とする。これは色材等の少量の新たな添加物
を除けば、再生材100%からなる材料である。材料A
100の試験片を作成し、異物観察及び物性測定を行っ
た結果、該材料の汚れは、試験片の表面積0.1m2 当
たりの黒い異物(半径100μm以上)の個数は3個と
評価され、またアイゾット衝撃強度(ASTMD25
6)は8.5kgf・cm/cm2 であった。 [材料の調製(2)]日本電気(株)製デスクトップパ
ソコンの廃製品の中からポリスチレン製のキーボードの
裏板及びフロントマスク(パソコン本体の筐体前部のプ
ラスチック製のカバー)を集めた。
Further, these are crushed and washed, and then toned and pelletized with a kneading machine, and UL Flame Retardant Standard 1/12 "V-0.
White recycled pellets were obtained. This recycled material pellet is referred to as a material A100. This is a material composed of 100% recycled material, except for a small amount of new additives such as coloring materials. Material A
As a result of preparing 100 test pieces and observing the foreign substances and measuring the physical properties, the number of black foreign substances (radius of 100 μm or more) per 0.1 m 2 of the surface area of the test pieces was evaluated as three. Izod impact strength (ASTMD25
6) was 8.5 kgf · cm / cm 2. [Preparation of Material (2)] A back plate of a polystyrene keyboard and a front mask (a plastic cover at the front of the casing of the personal computer main body) were collected from waste products of a desktop personal computer manufactured by NEC Corporation.

【0025】これらは米国のUL難燃規格1/12″H
B品の非難燃材料であり、材料メーカー数社のポリスチ
レンをそれぞれ使用した製品が含まれていた。
These are U.S. UL flame retardant standards 1/12 "H
It was a non-flame-retardant material of Product B, and included products using polystyrene from several material manufacturers.

【0026】これらから、紙ラベル、金属ラベル、ゴム
材、アクリル材などの異種材料からなる付き物を除き、
破砕、洗滌後、廃製品の難燃化ポリスチレンと同じ難燃
剤、及び色材を添加し、混練り機によりUL難燃規格1
/12″V−0の白い再生材ペレットにした。この再生
材ペレットを材料B100とする。
From these, excluding attached materials made of dissimilar materials such as paper labels, metal labels, rubber materials and acrylic materials,
After crushing and washing, add the same flame retardant and colorant as the flame retardant polystyrene of the waste product, and use a kneading machine to UL Flame Retardant Standard 1
/ 12 "V-0 white recycled material pellets. The recycled material pellets are referred to as material B100.

【0027】これは新たに添加した難燃剤及び色材等の
添加物を除けば、再生材100%からなる材料である。
材料B100の試験片を作成し、異物観察及び物性測定
を行った結果、該材料の汚れは、試験片の表面積0.1
m2 当たりの黒い異物(半径100μm以上)の個数は
10個と評価され、またアイゾット衝撃強度(ASTM
D256)は3.5kgf・cm/cm2 であった。 [材料の調製(3)]キーボードの裏板及びフロントマ
スクから異種材料からなる付き物を除き、破砕後、洗滌
工程を省く以外は材料の調整(2)と同様に調製し、U
L難燃規格1/12″V−0の白い再生材ペレットを得
た。この再生材ペレットを材料C100とする。これも
添加物を除けば、再生材100%からなる材料である。
材料C100の試験片を作成し、異物観察及び物性測定
を行った結果、該材料の汚れは、試験片の表面積0.1
m2 当たりの黒い異物(半径100μm以上)の個数は
100個と評価され、またアイゾット衝撃強度(AST
MD256)は3.5kgf・cm/cm2 であった。 [材料の調製(4)]材料の調整(1)において、混練
り機で再生材ペレットを調製するときに、未使用の新し
いUL難燃規格1/12″V−0のポリスチレン67重
量部を、破砕、洗滌した廃製品からの材料33重量部と
混合し、再生材を33重量%含むUL難燃規格1/1
2″V−0の白い再生材ペレットを得た。
This is a material composed of 100% recycled material except for additives such as newly added flame retardants and coloring materials.
As a result of preparing a test piece of the material B100 and observing the foreign substance and measuring the physical properties, the contamination of the material was 0.1% in the surface area of the test piece.
The number of black foreign substances (radius 100 μm or more) per m 2 was estimated to be 10, and Izod impact strength (ASTM)
D256) was 3.5 kgf · cm / cm 2. [Preparation of material (3)] The material was prepared in the same manner as in the preparation of material (2) except that the backing plate and the front mask of the keyboard were freed of the adhering material made of a different material, crushed, and the washing step was omitted.
A white recycled material pellet having an L flame retardancy standard of 1/12 ″ V-0 was obtained. This recycled material pellet is referred to as a material C100. This material is also made of 100% recycled material except for additives.
As a result of preparing a test piece of the material C100 and observing foreign matters and measuring physical properties, the stain on the material was 0.1% in the surface area of the test piece.
The number of black foreign substances (radius of 100 μm or more) per m 2 was evaluated as 100, and the Izod impact strength (AST
MD256) was 3.5 kgf · cm / cm 2. [Preparation of material (4)] In preparation of material (1) , when preparing regenerated material pellets with a kneading machine, 67 parts by weight of a new unused UL flame-retardant standard 1/12 "V-0 polystyrene was used. , Crushed, washed and mixed with 33 parts by weight of material from waste products, containing UL materials containing 33% by weight of UL flame retardant standard 1/1
2 "V-0 white recycled material pellets were obtained.

【0028】この再生材ペレットを材料A033とす
る。材料A033の試験片を作成し、異物観察及び物性
測定を行った結果、該材料の汚れは、試験片の表面積
0.1m2 当たりの黒い異物(半径100μm以上)の
個数は1個と評価され、またアイゾット衝撃強度(AS
TMD256)は9.5kgf・cm/cm2 であっ
た。[材料の調製(5)]材料の調整(2)において混
練り機で再生材ペレットを調製するときに、未使用の新
しいUL難燃規格1/12″V−0のポリスチレン90
重量部を、破砕、洗滌した廃製品からの材料10重量部
に混合し、10重量%より少し少ない約9%の再生材を
含むUL難燃規格1/12″V−0の白い再生材ペレッ
トを得た。
This recycled material pellet is referred to as material A033. As a result of preparing a test piece of the material A033 and observing the foreign substances and measuring the physical properties, the number of black foreign substances (radius of 100 μm or more) per 0.1 m 2 of the surface area of the test piece was evaluated as one, In addition, Izod impact strength (AS
TMD256) was 9.5 kgf · cm / cm2. [Preparation of Material (5)] When preparing regenerated material pellets by a kneader in the preparation of material (2) , a new unused UL flame-retardant standard 1/12 ″ V-0 polystyrene 90 is used.
Parts by weight are mixed with 10 parts by weight of the material from the crushed and washed waste products, and UL flame-retardant standard 1/12 "V-0 white recycled material pellets containing about 9% recycled material slightly less than 10% by weight I got

【0029】この再生材ペレットを材料B009とす
る。材料B009の試験片を作成し、異物観察及び物性
測定を行った結果、該材料の汚れは、試験片の表面積
0.1m2 当たりの黒い異物(半径100μm以上)の
個数は1個と評価され、またアイゾット衝撃強度(AS
TMD256)は9kgf・cm/cm2 であった。 [未使用の新しい材料]比較のため、未使用の新しい材
料の汚れの無さと物性を知る必要があり、ポリスチレン
(UL難燃規格1/12″V−0)について測定した。
ポリスチレン(UL難燃規格1/12″V−0)の表面
の汚れの無さの程度は、0.1m2 当たりの黒い異物の
無さで評価して0乃至1個であり、最大許容できても1
個程度と推定される。またアイゾット衝撃強度は10k
gf・cm/cm2 であった。 [参考例1 サンドイッチ成形(1)][材料の調製
(4)]によって説明した材料A033(白色)を表面
材として、また[材料の調製(1)]によって説明した
材料A100を黒く着色(サンドイッチ成形で技術上重
要な点は、芯材の比率を高めつつ成形品の表面に芯材が
露出することを避けることであり、芯材が表面に露出し
たときに判定し易くするために着色した)した材料を芯
材として使用した。
This recycled material pellet is referred to as material B009. As a result of preparing a test piece of material B009 and observing foreign substances and measuring physical properties, the number of black foreign substances (radius 100 μm or more) per surface area of 0.1 m 2 of the test piece was evaluated as one as to contamination of the material. In addition, Izod impact strength (AS
TMD256) was 9 kgf · cm / cm2. [Unused new material] For comparison, it is necessary to know the cleanness and physical properties of the unused new material, and the measurement was performed on polystyrene (UL flame-retardant standard 1/12 "V-0).
The degree of no contamination on the surface of polystyrene (UL flame-retardant standard 1/12 "V-0) is 0 to 1 when evaluated based on the absence of black foreign matter per 0.1 m @ 2, which is the maximum allowable. Also one
It is estimated to be about one. Izod impact strength is 10k
gf · cm / cm 2. [Reference Example 1 Sandwich molding (1)] The material A033 (white) described in [Preparation of material (4)] is used as a surface material, and the material A100 described in [Preparation of material (1)] is colored black (sandwich). A technically important point in molding is to avoid exposing the core material on the surface of the molded product while increasing the ratio of the core material, and colored to make it easier to determine when the core material is exposed on the surface. ) Was used as the core material.

【0030】型締め力360トンのサンドイッチ成形機
を使用し、デスクトップ型パソコン本体のフロントカバ
ー(大凡の寸法は400×150mm、主要部分の厚み
は約2.5mm)を成形した。
Using a sandwich molding machine with a clamping force of 360 tons, a front cover (approximate dimensions: 400 × 150 mm, main part thickness: about 2.5 mm) of the desktop personal computer was molded.

【0031】芯材用のノズルと表面材用のノズルの移動
量からサンドイッチ成形品中の芯材と表面材の比率を求
め、芯材、表面材それぞれに含まれる再生材の割合(材
料の調製の実施例の各項に記載した)から成形品中に含
まれる再生材の割合を計算した。成形条件を変えて、芯
材が表面に露出しないで成形可能な芯材の割合を検討し
た結果、30%であった。 [実施例1 サンドイッチ成形(2)]参考例1に記載
したと同様に[材料の調製(4)]によって説明した材
料A033を表面材として、また[材料の調製(1)]
によって説明した材料A100を芯材として使用した。
The ratio between the core material and the surface material in the sandwich molded product is determined from the movement amount of the core material nozzle and the surface material nozzle, and the ratio of the recycled material contained in each of the core material and the surface material (preparation of material) Was described in each section of the Examples), the proportion of the recycled material contained in the molded article was calculated. As a result of examining the ratio of the core material that can be molded without exposing the core material to the surface by changing the molding conditions, it was 30%. [Example 1 Sandwich molding (2)] In the same manner as described in Reference example 1, material A033 described in [Preparation of material (4)] was used as a surface material, and [Preparation of material (1)].
A100 described above was used as the core material.

【0032】但し色調は[材料の調製(1)]及び[材
料の調製(4)]に述べたように白色の材料を使用し
た。型締め力360トンのサンドイッチ成形機を使用
し、デスクトップ型パソコン本体のフロントカバー(大
凡の寸法は400×150mm、主要部分の厚みは約
2.5mm)を成形した。
However, as for the color tone, a white material was used as described in [Material Preparation (1)] and [Material Preparation (4)]. Using a sandwich molding machine with a clamping force of 360 tons, a front cover (approximate dimensions of 400 × 150 mm, thickness of main part of about 2.5 mm) of the desktop personal computer body was molded.

【0033】芯材用のノズルと表面材用のノズルの移動
量からサンドイッチ成形品中の芯材と表面材の比率を求
め、芯材、表面材それぞれに含まれる再生材の割合
([材料の調製]の各項に記載した)から成形品中に含
まれる再生材の割合を計算した。
The ratio of the core material to the surface material in the sandwich molded product is obtained from the movement amount of the core material nozzle and the surface material nozzle, and the ratio of the recycled material contained in each of the core material and the surface material ([[material Preparation]), the percentage of recycled material contained in the molded article was calculated.

【0034】参考例1のように芯材の割合が30%のサ
ンドイッチ成形品が得られ、表面の汚れは未使用の新し
い材料を使用して通常の射出成形をした場合と比較して
特に問題がない成形品であった。芯材、表面材それぞれ
に含まれる再生材の割合([材料の調製(1)]及び
[材料の調製(4)]に記載した)から成形品中に含ま
れる再生材の割合を計算したところ、該サンドイッチ成
形品中の再生材の含有率は約53%(表面層中:表面材
中再生材含有率33%×表面層の割合70%即ち23
%、コア層中:芯材中再生材含有率100%×コア層の
割合30%即ち30%、合計で53%)であった。
A sandwich molded product having a core material ratio of 30% as in Reference Example 1 was obtained, and the stain on the surface was particularly problematic as compared with the case where normal injection molding was performed using an unused new material. There was no molded product. The ratio of the recycled material contained in the molded article was calculated from the ratio of the recycled material contained in each of the core material and the surface material (described in [Material Preparation (1)] and [Material Preparation (4)]). The content of the recycled material in the sandwich molded article is about 53% (in the surface layer: the content of the recycled material in the surface material is 33% × the ratio of the surface layer is 70%, that is, 23%).
%, In the core layer: the content of the recycled material in the core material was 100% × the ratio of the core layer was 30%, that is, 30%, that is, 53% in total).

【0035】本サンドイッチ成形品中の異物を推定する
に、[材料の調製(1)]に記載した異物の個数が3個
の材料が30%、[材料の調製(4)]に記載した異物
の個数が1個の材料が70%からなり、未使用の新しい
材料に劣るとは言え充分にきれいであり、またアイゾッ
ト衝撃強度は8.5kgf・cm/cm2 の材料30%
と、9.5kgf・cm/cm2 の材料70%からな
り、同じ製品への再使用が充分に可能である。 [比較例1 サンドイッチ成形(3)]表面材に[未使
用の新しい材料]に記載した材料を使用する以外は実施
例1と同様に成形し、サンドイッチ成形品を得た。再生
材の含有率は30%であった。 [比較例2 通常の射出成形(1)][材料の調製
(4)]に記載した材料A033を使用して、型締め力
350トンの射出成形機、及び実施例1で使用した金型
を使用し、フロントマスクを成形した。本成形品中の再
生材の含有率は[材料の調製(4)]に記載した材料中
の再生材含有率から推定されるように、33%であっ
た。 [参考例2 サンドイッチ成形(4)][材料の調製
(5)]の材料B009(白色)を表面材として、また
[材料の調製(2)]の材料B100を黒く着色した材
料を芯材として使用した。型締め力550トンのサンド
イッチ成形機を使用し、デスクトップ型パソコン本体の
フロントカバー(大凡の寸法は400×150mm、主
要部分の厚みは約2.5mm)を成形した。芯材用のノ
ズルと表面材用のノズルの移動量からサンドイッチ成形
品中の芯材と表面材の比率を求め、芯材、表面材それぞ
れに含まれる再生材の割合([材料の調製]の各項に記
載した)から成形品中に含まれる再生材の割合を計算し
た。
In order to estimate the foreign matter in the sandwich molded article, 30% of the material has three foreign substances described in [Preparation of material (1)] and 30% of the foreign matter described in [Preparation of material (4)]. Is 70% of a single material, which is inferior to an unused new material, and is sufficiently clean, and has an Izod impact strength of 8.5 kgf.cm/cm@2 of a 30% material.
And 9.5 kgf · cm / cm 2 of 70% of the material, and can be sufficiently reused for the same product. Implementation but using materials described in the Comparative Example 1 sandwich molding (3) New materials unused] the surface material
Molding was performed in the same manner as in Example 1 to obtain a sandwich molded product. The content of the recycled material was 30%. [Comparative Example 2 Ordinary Injection Molding (1)] Using the material A033 described in [Preparation of Material (4)], an injection molding machine with a mold clamping force of 350 tons and the mold used in Example 1 were used. Used to form a front mask. The content of the recycled material in the molded article was 33% as estimated from the content of the recycled material in the material described in [Preparation of Material (4)]. [Reference Example 2 Sandwich molding (4)] Using material B009 (white) of [Preparation of material (5)] as a surface material, and using material B100 of [Preparation of material (2)] colored black as a core material used. Using a sandwich molding machine with a mold clamping force of 550 tons, a front cover (approximate dimensions: 400 × 150 mm, main part thickness: about 2.5 mm) of the desktop personal computer body was molded. The ratio between the core material and the surface material in the sandwich molded product is calculated from the movement amount of the core material nozzle and the surface material nozzle, and the ratio of the recycled material contained in each of the core material and the surface material ([preparation of material] (Described in each section), the ratio of recycled materials contained in the molded article was calculated.

【0036】成形条件を変えて、芯材が表面に露出しな
いで成形可能な芯材の割合を検討した結果、25%であ
った。 [実施例2 サンドイッチ成形(5)]参考例2の記載
と同様に、[材料の調製(5)]の材料B009を表面
材として、また[材料の調製(2)]の材料B100を
芯材として使用した。但し色調は[材料の調製(2)]
及び[材料の調製(5)]に述べたように白色の材料を
使用した。型締め力550トンのサンドイッチ成形機を
使用し、デスクトップ型パソコン本体のフロントカバー
(大凡の寸法は400×150mm、主要部分の厚みは
約2.5mm)を成形した。
The ratio of the core material that can be molded without exposing the core material to the surface was examined by changing the molding conditions. As a result, the ratio was 25%. [Example 2 Sandwich molding (5)] In the same manner as described in Reference example 2, material B009 of [Preparation of material (5)] was used as a surface material, and material B100 of [Preparation of material (2)] was used as a core material. Used as However, the color tone is [Material preparation (2)]
And a white material as described in [Preparation of Material (5)]. Using a sandwich molding machine with a mold clamping force of 550 tons, a front cover (approximate dimensions: 400 × 150 mm, main part thickness: about 2.5 mm) of the desktop personal computer body was molded.

【0037】芯材用のノズルと表面材用のノズルの移動
量からサンドイッチ成形品中の芯材と表面材の比率を求
め、芯材、表面材それぞれに含まれる再生材の割合
([材料の調製]の各項に記載した)から成形品中に含
まれる再生材の割合を計算した。参考例2のように芯材
の割合が25%のサンドイッチ成形品が得られ、表面の
汚れは未使用の新しい材料を使用して通常の射出成形を
した場合と比較して特に問題がない成形品であった。
The ratio between the core material and the surface material in the sandwich molded product is determined from the movement amount of the core material nozzle and the surface material nozzle, and the ratio of the recycled material contained in each of the core material and the surface material ([[material Preparation]), the percentage of recycled material contained in the molded article was calculated. As in Reference Example 2, a sandwich molded product having a core material ratio of 25% was obtained, and surface contamination was not particularly problematic as compared with a case where normal injection molding was performed using an unused new material. It was a product.

【0038】芯材、表面材それぞれに含まれる再生材の
割合([材料の調製(2)]及び[材料の調製(5)]
に記載した)から成形品中に含まれる再生材の割合を計
算したところ、該サンドイッチ成形品中の再生材の含有
率は約32%(表面層中:表面材中再生材含有率9%×
表面層の割合75%即ち7%、コア層中:芯材中再生材
含有率100%×コア層の割合25%即ち25%、合計
で32%)であった。
The ratio of the recycled material contained in each of the core material and the surface material ([Preparation of material (2)] and [Preparation of material (5)])
), The content of the recycled material in the sandwich molded product was about 32% (in the surface layer: 9% of the recycled material content in the surface material).
The ratio of the surface layer was 75%, ie, 7%, and in the core layer: the content of the recycled material in the core material was 100% × the ratio of the core layer was 25%, ie, 25%, for a total of 32%.

【0039】本サンドイッチ成形品中の異物を推定する
に、[材料の調製(2)]に記載した異物の個数が10
個の材料が25%、[材料の調製(5)]に記載した異
物の個数が1個の材料が75%からなり、未使用の新し
い材料に劣るがきれいであり、またアイゾット衝撃強度
は3.5kgf・cm/cm2 の材料25%と、9kg
f・cm/cm2 の材料75%からなり、同じ製品への
再使用が充分に可能であると推定される。 [比較例3 サンドイッチ成形(6)]表面材に[未使
用の新しい材料]に記載した材料を使用する以外は実施
例2と同様に成形し、サンドイッチ成形品を得た。再生
材の含有率は25%であった。 [比較例4 通常の射出成形(2)][材料の調製
(5)]に記載した材料B009を使用して、型締め力
350トンの射出成形機、及び実施例2で使用した金型
を使用し、フロントマスクを成形した。本成形品中の再
生材の含有率は[材料の調製(5)]に記載した再生材
含有率から推定されるように、9%であった。 [比較例5 サンドイッチ成形(7)]芯材に[材料の
調製(2)]の材料B100の代わりに、[材料の調製
(3)]の材料C100を使用する他は実施例2と同様
に実施しフロントマスクを成形した。実施例2のように
芯材の割合が25%のサンドイッチ成形品が得られ、表
面は未使用の新しい材料を使用して通常の射出成形をし
た場合と比較して特に問題がない成形品であった。
In order to estimate foreign matter in the sandwich molded product, the number of foreign matter described in [Preparation of material (2)] was 10
The material is 25%, and the number of foreign substances described in [Preparation of material (5)] is 75%. The material is inferior to the unused new material, but the Izod impact strength is 3%. 2.5 kgf.cm/cm2 material 25% and 9 kg
It is assumed that it is composed of 75% of the material of f · cm / cm 2 and can be sufficiently reused in the same product. [Comparative Example 3 Sandwich molding (6)] A sandwich molded product was obtained in the same manner as in Example 2 except that the material described in [Unused new material] was used as the surface material. The content of the recycled material was 25%. [Comparative Example 4 Normal Injection Molding (2)] Using the material B009 described in [Preparation of Material (5)], an injection molding machine with a clamping force of 350 tons and a mold used in Example 2 were used. Used to form a front mask. The content of the recycled material in the molded article was 9% as estimated from the content of the recycled material described in [Preparation of Material (5)]. [ Comparative Example 5 Sandwich molding (7)] In the same manner as in Example 2 except that the material C100 of [Preparation of material (3)] was used instead of the material B100 of [Preparation of material (2)] for the core material. This was performed to form a front mask. As in Example 2, a sandwich molded product having a core material ratio of 25% was obtained, and the surface was a molded product having no particular problem as compared with a case where ordinary new materials were used for injection molding. there were.

【0040】但し、本サンドイッチ成形品中の異物を推
定するに、[材料の調製(3)]に記載した異物の個数
が100個の材料が25%、[材料の調製(5)]に記
載した異物の個数が1個の材料が75%からなり、同じ
製品への再使用には問題がある。芯材、表面材それぞれ
に含まれる再生材の割合([材料の調製(3)]及び
[材料の調製(5)]に記載した)から成形品中に含ま
れる再生材の割合を計算したところ、該サンドイッチ成
形品中の再生材の含有率は約32%(表面層中:表面材
中再生材含有率9%×表面層の割合75%即ち7%、コ
ア層中:芯材中再生材含有率100%×コア層の割合2
5%即ち25%、合計で32%)であり、再度同じ製品
に再生材として使用するには問題があるものの、比較例
3及び比較例4と比較して、再生材の含有率は高く、表
面がきれいな成形品が得られた。
However, in order to estimate the foreign matter in the present sandwich molded product, 25% of the material having 100 foreign matters described in [Preparation of material (3)] was described in [Preparation of material (5)]. 75% of the material contains one foreign matter, and there is a problem in reusing the same foreign material. The ratio of the recycled material contained in the molded article was calculated from the ratio of the recycled material contained in each of the core material and the surface material (described in [Material Preparation (3)] and [Material Preparation (5)]). The content of the recycled material in the sandwich molded article is about 32% (in the surface layer: the content of the recycled material in the surface material is 9% × the ratio of the surface layer is 75%, ie, 7%; in the core layer: the recycled material in the core material) Content 100% x core layer ratio 2
5%, that is, 25%, and a total of 32%). Although there is a problem in using the same product again as a recycled material, the content of the recycled material is higher than those in Comparative Examples 3 and 4. A molded product with a clean surface was obtained.

【0041】[0041]

【発明の効果】以上説明したように本発明の成形物は、 (1)再生材を使用しても表面がきれいな成形品を提供
する。
As described above, the molded article of the present invention provides (1) a molded article having a clean surface even when a recycled material is used.

【0042】(2)通常の射出成形の成形品に比べて多
くの再生材を含有させることができる。
(2) A larger amount of recycled material can be contained as compared with ordinary injection molded articles.

【0043】(3)芯材と表面材に同種の樹脂(樹脂の
種類、難燃剤の種類等)を使用することにより、成形品
を再度同じ製品にマテリアルリサイクルできる製品を提
供する。
(3) By using the same type of resin (the type of resin, the type of flame retardant, etc.) for the core material and the surface material, it is possible to provide a product whose molded product can be recycled to the same product again.

【0044】(4)肉厚が3mm以下の成形品について
も、上記の効果を得ることができる。
(4) The above-mentioned effects can be obtained even for a molded product having a thickness of 3 mm or less.

【0045】(5)従って電気・電子機器の筐体への再
生材の使用についても有効である。
(5) Therefore, the use of recycled materials for the housing of electric / electronic equipment is also effective.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明のサンドイッチ成形品の実施の形態を示
す断面図である。
FIG. 1 is a sectional view showing an embodiment of a sandwich molded product of the present invention.

【符号の説明】[Explanation of symbols]

1 芯材 2 表面材 4 注入口 5 成形型 DESCRIPTION OF SYMBOLS 1 Core material 2 Surface material 4 Injection port 5 Mold

───────────────────────────────────────────────────── フロントページの続き (72)発明者 島田 英明 東京都港区芝五丁目7番1号 日本電気 株式会社内 (72)発明者 佐藤 保治 東京都港区芝五丁目7番1号 日本電気 株式会社内 (56)参考文献 特開 平8−276538(JP,A) 特開 平10−202694(JP,A) 特開 平8−118418(JP,A) 特開 平9−131759(JP,A) 特開 平9−131760(JP,A) 特開 平9−108084(JP,A) (58)調査した分野(Int.Cl.7,DB名) B32B 1/00 - 35/00 B29C 45/00 - 45/84 B29C 49/00 - 49/80 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Hideaki Shimada 5-7-1 Shiba, Minato-ku, Tokyo NEC Corporation (72) Inventor Yoji Sato 5-7-1 Shiba, Minato-ku, Tokyo NEC (56) References JP-A 8-276538 (JP, A) JP-A 10-202694 (JP, A) JP-A 8-118418 (JP, A) JP-A 9-131759 (JP, A) A) JP-A-9-131760 (JP, A) JP-A-9-108084 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B32B 1/00-35/00 B29C 45 / 00-45/84 B29C 49/00-49/80

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 芯材と該芯材の全表面を被覆する表面材
とからなるサンドイッチ成形品において、表面材と芯材
が共に再生材を含有し、再生材の含有率のみが異なる同
種の樹脂であり、表面材中に5重量%乃至50重量%、
芯材中に表面材中より多い割合で再生材を含有し、 表面材と芯材の合計を100重量部とするとき、芯材の
割合が10重量部乃至40重量部であり、芯材中の汚れ
を、表面積0.1平方メートル当たりの半径100μm
以上の大きさの異物の数で10個以下にし、 成形品の大部分の肉厚が3mm以下の筐体の成形品であ
ることを特徴とする サンドイッチ成形品。
1. A sandwich molded article comprising a core material and a surface material covering the entire surface of the core material, wherein both the surface material and the core material contain a recycled material, and the same type of material is different only in the content of the recycled material. Resin, and 5 to 50% by weight in the surface material;
When the recycled material is contained in the core material at a higher ratio than the surface material, and the total of the surface material and the core material is 100 parts by weight,
The ratio is 10 to 40 parts by weight, and the contamination in the core material is
With a radius of 100 μm per 0.1 square meter of surface area
The number of foreign substances having the above size is set to 10 or less, and the thickness of most of the molded article is 3 mm or less.
A sandwich molded product characterized by being capable of being sandwiched.
【請求項2】 表面材に含まれる再生材の百分率が、5
重量%乃至40重量%、芯材中に含まれる再生材の百分
率が70重量%乃至100重量%である請求項1記載の
サンドイッチ成形品。
2. The percentage of recycled material contained in the surface material is 5%.
The sandwich molded article according to claim 1, wherein the weight percentage of the recycled material contained in the core material is 70% to 100% by weight.
【請求項3】 芯材と表面材の両方が非難燃樹脂の場合
及び一方が難燃樹脂の場合、樹脂の種類のみが同じで、
芯材と表面材の両方が難燃樹脂の場合、難燃剤の種類が
ともに同一である請求項1又は請求項2のサンドイッチ
成形品。
3. When both the core material and the surface material are non-flame-retardant resins.
And if one is a flame retardant resin, only the type of resin is the same,
If both the core material and the surface material are flame retardant resins, the type of flame retardant
The sandwich molded article according to claim 1 or 2, which are the same .
JP28392598A 1998-10-06 1998-10-06 Sandwich molded products containing recycled materials Expired - Fee Related JP3031357B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28392598A JP3031357B1 (en) 1998-10-06 1998-10-06 Sandwich molded products containing recycled materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28392598A JP3031357B1 (en) 1998-10-06 1998-10-06 Sandwich molded products containing recycled materials

Publications (2)

Publication Number Publication Date
JP3031357B1 true JP3031357B1 (en) 2000-04-10
JP2000108124A JP2000108124A (en) 2000-04-18

Family

ID=17671995

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28392598A Expired - Fee Related JP3031357B1 (en) 1998-10-06 1998-10-06 Sandwich molded products containing recycled materials

Country Status (1)

Country Link
JP (1) JP3031357B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004160985A (en) * 2002-10-23 2004-06-10 Sekisui Chem Co Ltd Sandwich injection-molded product

Also Published As

Publication number Publication date
JP2000108124A (en) 2000-04-18

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