JP2005239558A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
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- JP2005239558A JP2005239558A JP2004047389A JP2004047389A JP2005239558A JP 2005239558 A JP2005239558 A JP 2005239558A JP 2004047389 A JP2004047389 A JP 2004047389A JP 2004047389 A JP2004047389 A JP 2004047389A JP 2005239558 A JP2005239558 A JP 2005239558A
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- Prior art keywords
- manufactured
- feeling
- product name
- extract
- hair
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- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000003599 detergent Substances 0.000 title claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 22
- 229920000642 polymer Polymers 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 22
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 8
- 239000005017 polysaccharide Substances 0.000 claims abstract description 8
- 150000004676 glycans Chemical class 0.000 claims abstract description 7
- VLJXNZIHIIROLJ-UHFFFAOYSA-N trimethyl-(5-methyl-4-oxohex-5-enyl)azanium Chemical class CC(=C)C(=O)CCC[N+](C)(C)C VLJXNZIHIIROLJ-UHFFFAOYSA-N 0.000 claims description 5
- 210000004209 hair Anatomy 0.000 abstract description 16
- 239000002932 luster Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 22
- 239000000284 extract Substances 0.000 description 21
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 18
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 239000002453 shampoo Substances 0.000 description 13
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 12
- 238000005187 foaming Methods 0.000 description 12
- -1 galactomannan polysaccharide Chemical class 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229920006322 acrylamide copolymer Polymers 0.000 description 7
- 239000002280 amphoteric surfactant Substances 0.000 description 7
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000005639 Lauric acid Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- OIFLLGNCLZLPAF-UHFFFAOYSA-M trimethyl-(5-methyl-4-oxohex-5-enyl)azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)CCC[N+](C)(C)C OIFLLGNCLZLPAF-UHFFFAOYSA-M 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 244000131522 Citrus pyriformis Species 0.000 description 4
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 4
- 244000288377 Saxifraga stolonifera Species 0.000 description 4
- 235000002953 Saxifraga stolonifera Nutrition 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- 235000021360 Myristic acid Nutrition 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- 244000250129 Trigonella foenum graecum Species 0.000 description 3
- 235000001484 Trigonella foenum graecum Nutrition 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- JIATYBYHEXWFRC-UHFFFAOYSA-L calcium;silver;(4-aminophenyl)sulfonyl-(5-methoxypyrimidin-2-yl)azanide;3-[(2,4-dihydroxy-3,3-dimethylbutanoyl)amino]propanoate Chemical compound [Ca+2].[Ag+].OCC(C)(C)C(O)C(=O)NCCC([O-])=O.OCC(C)(C)C(O)C(=O)NCCC([O-])=O.N1=CC(OC)=CN=C1[N-]S(=O)(=O)C1=CC=C(N)C=C1 JIATYBYHEXWFRC-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 235000001019 trigonella foenum-graecum Nutrition 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- IDYLOZGOBLTKMM-UHFFFAOYSA-N 14-(14-hydroxytetradecoxy)tetradecan-1-ol Chemical compound OCCCCCCCCCCCCCCOCCCCCCCCCCCCCCO IDYLOZGOBLTKMM-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 239000004166 Lanolin Chemical class 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- 244000044822 Simmondsia californica Species 0.000 description 2
- 235000004433 Simmondsia californica Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 229940008396 carrot extract Drugs 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 229930195712 glutamate Natural products 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- KTCCLEVCNRHWQL-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)CNCCC(O)=O KTCCLEVCNRHWQL-UHFFFAOYSA-N 0.000 description 1
- NBDYSLCMCUDINP-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCC(O)=O NBDYSLCMCUDINP-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 235000011696 French rose Nutrition 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000181025 Rosa gallica Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical class NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229940072117 fennel extract Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940038487 grape extract Drugs 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001965 increasing effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、洗浄剤組成物に関し、詳しくは、洗浄性に優れ、洗浄時にはクリーミィでありながらかつボリュームのある泡が得られ、使用後の肌や髪につやを与え、みずみずしさ（うるおい感）を保つことができ、かつ長期間の連用によってもべたつき感が生じず、良好な仕上り感が得られる洗浄剤組成物に関するものである。 The present invention relates to a cleaning composition, and in particular, it has excellent cleaning properties, and a creamy and voluminous foam is obtained at the time of cleaning, which gives gloss to the skin and hair after use, and is refreshing (moisturizing feeling) The present invention relates to a detergent composition that can maintain a good finish and does not give a sticky feeling even when used for a long period of time, and provides a good finish feeling.
近年、ヘアシャンプーやボディシャンプー、洗顔料等の洗浄剤は、本来の目的である洗浄性に加えて、豊かな起泡性、クリーミーな泡質、すすぎ性、そして使用後になめらかになるなどの仕上がり感が求められている。増泡や泡質調製については従来から、アニオン性界面活性剤、両性界面活性剤等の洗浄基剤と組み合わせて、ラウリン酸モノエタノールアミドやヤシ油脂肪酸ジエタノールアミドなどの高級脂肪酸アルカノールアミドが広く用いられている（例えば、非特許文献１参照）。また、仕上がり感の調整剤として、特定の油分やポリマー類を配合するなどの試みが行われてきた（例えば、特許文献１〜５参照）。 In recent years, detergents such as hair shampoos, body shampoos, and facial cleansers have a rich foaming property, creamy foam quality, rinsing properties, and a smooth finish after use, in addition to the original cleaning properties. A feeling is required. Conventionally, higher fatty acid alkanolamides such as lauric acid monoethanolamide and coconut oil fatty acid diethanolamide have been widely used in combination with detergent bases such as anionic surfactants and amphoteric surfactants for foaming and foam preparation. (See, for example, Non-Patent Document 1). In addition, attempts have been made to blend specific oils and polymers as a finishing feeling regulator (see, for example, Patent Documents 1 to 5).
しかしながら、従来の仕上り感調整剤を配合した場合には、泡立ちや泡質が低下する、すすぎ時の感触が低下する（ぬるつき感やきしみ感を生じる）、長期間の連用によりべたつき感を生じる、油分やポリマーの皮膜が皮膚表面に残留することにより髪や肌のツヤを失うなどの問題があった。高級脂肪酸ジエタノールアミドを配合しても油分などによる泡立ちや泡質の低下は避けられず、これを改良するために高級脂肪酸ジエタノールアミドを多量に配合した場合には、すすぎ性や仕上がり感に悪影響を及ぼすなどの問題があった。また、高級脂肪酸モノエタノールアミド等を用いた場合、低温で結晶が析出する場合があった。 However, when a conventional finish feeling modifier is blended, foaming and foam quality are lowered, the feeling at the time of rinsing is lowered (causes a feeling of stickiness and squeaking), and a sticky feeling is produced by prolonged use. There are problems such as loss of hair and skin gloss due to the oil or polymer film remaining on the skin surface. Even if higher fatty acid diethanolamide is added, bubbling due to oil or the like and deterioration of the foam quality cannot be avoided.If a higher amount of higher fatty acid diethanolamide is added in order to improve this, it will adversely affect the rinsing properties and finish feeling. There were problems such as effects. Further, when higher fatty acid monoethanolamide or the like was used, crystals sometimes precipitated at a low temperature.
上記事情において、本発明の目的とするところは、洗浄性に優れ、洗浄時にはクリーミィでありながらかつボリュームのある泡が得られ、使用後の肌や髪につやを与え、みずみずしさ（うるおい感）を保つことができ、かつ長期間の連用によってもべたつき感が生じず、良好な仕上り感が得られる洗浄剤組成物を提供することにある。 In the above circumstances, the object of the present invention is to provide excellent cleanability, creamy and voluminous foam at the time of cleaning, and give gloss to the skin and hair after use, freshness (moisture feeling) It is an object of the present invention to provide a cleaning composition that can maintain a good finish and does not give a sticky feeling even when used for a long period of time, and provides a good finish feeling.
本発明者等は、本発明の目的を達成するために鋭意研究した結果、特定のポリマーを組み合わせて界面活性剤を含有する洗浄剤組成物に配合すると上記欠点が改善されることを見出し、本発明を完成した。 As a result of intensive studies to achieve the object of the present invention, the present inventors have found that the above-mentioned drawbacks can be improved by combining a specific polymer with a detergent composition containing a surfactant. Completed the invention.
すなわち、本発明の請求項１は、（Ａ）メタクリルプロピルトリメチルアンモニウム誘導ポリマーと、（Ｂ）ジメチルジアリルアンモニウム誘導ポリマーと、（Ｃ）カチオン化多糖類と、（Ｄ）界面活性剤とを、含有することを特徴とする洗浄剤組成物である。本発明の請求項２は、（Ａ）、（Ｂ）、（Ｃ）の含有量が、（Ａ）＋（Ｂ）＋（Ｃ）＝０．０５〜２．０質量％（以下％と略す。）、かつ質量比が、（（Ａ）＋（Ｂ））：（Ｃ）＝１０：１〜１：１０であることを特徴とする請求項１に記載の洗浄剤組成物である。 That is, claim 1 of the present invention contains (A) a methacrylpropyltrimethylammonium derivative polymer, (B) a dimethyldiallylammonium derivative polymer, (C) a cationized polysaccharide, and (D) a surfactant. It is the cleaning composition characterized by doing. According to claim 2 of the present invention, the contents of (A), (B), and (C) are (A) + (B) + (C) = 0.05 to 2.0% by mass (hereinafter abbreviated as%). .), And the mass ratio is ((A) + (B)) :( C) = 10: 1 to 1:10.
本発明によって、洗浄性に優れ、洗浄時にはクリーミィでありながらかつボリュームのある泡が得られ、使用後の肌や髪につやを与え、みずみずしさ（うるおい感）を保つことができ、かつ長期間の連用によってもべたつき感が生じず、良好な仕上り感が得られる洗浄剤組成物を提供することができる。 According to the present invention, it is excellent in cleanability, can produce creamy and voluminous foam at the time of cleaning, can give skin and hair after use, can keep freshness (moisture feeling), and can be used for a long time Thus, it is possible to provide a cleaning composition that does not give a sticky feeling even when used continuously, and can provide a good finished feeling.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明における（Ａ）メタクリルプロピルトリメチルアンモニウム誘導ポリマーは、メタクリルプロピルトリメチルアンモニウムの構造をモノマー単位の一つとして有するポリマーであり、アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・メチルアクリレート共重合体（商品名：ＭＥＲＱＵＡＴ ２００１［ナルコ社製］など）が好ましく用いられる。これらのメタクリルプロピルトリメチルアンモニウム誘導ポリマーは１種又は２種以上を組み合わせて用いることができる。 The (A) methacrylpropyltrimethylammonium derivative polymer in the present invention is a polymer having a methacrylpropyltrimethylammonium structure as one of the monomer units, and an acrylic acid / methacrylpropyltrimethylammonium chloride / methyl acrylate copolymer (trade name: MERQUAT 2001 (manufactured by Nalco) and the like are preferably used. These methacrylpropyltrimethylammonium derived polymers can be used alone or in combination of two or more.
本発明における（Ｂ）ジメチルジアリルアンモニウム誘導ポリマーは、ジメチルジアリルアンモニウムの構造をモノマー単位の一つとして有するポリマーであり、塩化ジメチルジアリルアンモニウム重合体（商品名：ＭＥＲＱＵＡＴ １００（ナルコ社製）など）、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体（商品名：ＭＥＲＱＵＡＴ
５５０、２２００（ナルコ社製）など）、アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（商品名：ＭＥＲＱＵＡＴ ２８０、２９５（ナルコ社製）など）、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（商品名：ＭＥＲＱＵＡＴ ＰＬＵＳ ３３３０、３３３１（ナルコ社製）など）などが挙げられ、好ましくは塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体が用いられる。これらのジメチルジアリルアンモニウム誘導ポリマーは１種又は２種以上を組み合わせて用いることができる。
The (B) dimethyldiallylammonium derivative polymer in the present invention is a polymer having a dimethyldiallylammonium structure as one of the monomer units, and is a dimethyldiallylammonium chloride polymer (trade name: MERQUAT 100 (manufactured by Nalco), etc.) Dimethyldiallylammonium chloride-acrylamide copolymer (trade name: MERQUAT
550, 2200 (Nalco), etc.), acrylic acid / dimethyldiallylammonium chloride copolymer (trade name: MERQUAT 280, 295 (Nalco), etc.), acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer ( Trade name: MERQUAT PLUS 3330, 3331 (manufactured by Nalco) and the like, and dimethyldiallylammonium chloride-acrylamide copolymer is preferably used. These dimethyldiallylammonium derived polymers can be used alone or in combination of two or more.
本発明における（Ｃ）カチオン化多糖類は、多糖類をカチオン化したものであれば、特に限定されないが、多糖類としてセルロース、又はガラクトースとマンノースを構造単位とするガラクトマンナン系多糖類のものを用いることが望ましい。特に望ましくは、カチオン化セルロース（商品名：ポリマーＪＲ−４００［ＵＣＣ社製］、レオガードＧ［ライオン社製］、カチナールＨＣ−２００、カチナールＬＣ−２００［東邦化学工業社製］など）、カチオン化グアーガム（商品名：ジャガーＣ−１７及びＣ−１３−Ｓ［三晶社製］など）、カチオン化フェヌグリークガム（商品名：カチナールＣＦ−１００、カチナールＣＦ−２００［東邦化学工業社製］など）、カチオン化ローカストビーンガム（商品名：カチナールＣＬＢ−１００［東邦化学工業社製］など）、カチオン化タラガム（商品名：カチナールＣＴＲ−１００［東邦化学工業社製］など）が用いられる。これらのカチオン化多糖類は１種又は２種以上を組み合わせて用いることができる。 The (C) cationized polysaccharide in the present invention is not particularly limited as long as it is a cationized polysaccharide. However, as the polysaccharide, cellulose or a galactomannan polysaccharide having galactose and mannose as structural units is used. It is desirable to use it. Particularly preferably, cationized cellulose (trade name: polymer JR-400 [manufactured by UCC Co., Ltd.], Leogard G [manufactured by Lion Co., Ltd.], kachinal HC-200, kachinal LC-200 [manufactured by Toho Chemical Industry Co., Ltd.], etc.), cationization Guar gum (trade names: Jaguar C-17 and C-13-S [manufactured by Sanki Co., Ltd.), etc., cationized fenugreek gum (trade names: kachinal CF-100, kachinal CF-200 [manufactured by Toho Chemical Industry Co., Ltd.], etc.) And cationized locust bean gum (trade name: Katchinal CLB-100 [manufactured by Toho Chemical Industry Co., Ltd.]) and cationized tara gum (trade name: kachinal CTR-100 [manufactured by Toho Chemical Industry Co., Ltd.]). These cationized polysaccharides can be used alone or in combination of two or more.
上記（Ａ）、（Ｂ）、（Ｃ）の各ポリマーは、本発明の組成物中にポリマー分として合計０．０５〜２．０％含有されることが望ましく、さらに望ましくは０．１〜１．０％含有される。ポリマー分が０．０５％より少ないと所望の泡質が得られない場合があり、２．０％を超えて配合されると、仕上がりがべたつくことがある。また、各ポリマーの配合比は質量比で、（（Ａ）＋（Ｂ））：（Ｃ）＝１０：１〜１：１０であることが望ましく、さらに望ましくは５：１〜１：５である。この範囲を外れると、泡質や仕上り感の悪化の原因となる場合がある。 The polymers (A), (B), and (C) are desirably contained in the composition of the present invention in a total amount of 0.05 to 2.0%, more preferably 0.1 to 0.1%. 1.0% contained. If the polymer content is less than 0.05%, the desired foam quality may not be obtained, and if it exceeds 2.0%, the finish may be sticky. The blend ratio of each polymer is preferably ((A) + (B)) :( C) = 10: 1 to 1:10, more preferably 5: 1 to 1: 5 in terms of mass ratio. is there. If it is out of this range, it may cause deterioration of foam quality and finish feeling.
本発明における（Ｄ）界面活性剤はノニオン性、アニオン性、カチオン性、両性、半極性のいずれでもよく、特にアニオン性界面活性剤、両性界面活性剤、半極性界面活性剤、糖系ノニオン系界面活性剤などが洗浄性、起泡性の面から好ましい。 The surfactant (D) in the present invention may be any of nonionic, anionic, cationic, amphoteric, and semipolar, particularly anionic surfactant, amphoteric surfactant, semipolar surfactant, and sugar-based nonionic surfactant. A surfactant or the like is preferable from the viewpoints of detergency and foaming.
好ましい界面活性剤の具体例としては、アニオン性界面活性剤として、脂肪酸石けん、アルキル硫酸塩型界面活性剤、アルキルエーテル硫酸塩型界面活性剤、オレフィンスルホン酸塩型界面活性剤、リン酸エステル型界面活性剤、アルキルエーテルカルボン酸塩型界面活性剤、アミノ酸塩型界面活性剤（サルコシン塩型、β−アラニン塩型、グルタミン酸塩型、アスパラギン酸塩型など）、スルホコハク酸塩型界面活性剤、タウリン型界面活性剤など、両性界面活性剤として、スルホベタイン型両性界面活性剤、アルキルベタイン型両性界面活性剤、アミドプロピルベタイン型両性界面活性剤、イミダゾリニウムベタイン型両性界面活性剤など、半極性界面活性剤として、アミンオキシド型界面活性剤など、糖系ノニオン性界面活性剤として、アルキルグルコシド、糖脂肪酸エステルなどが挙げられる。これらの界面活性剤の親油基としては、直鎖のものでも分岐のものでも、また、一部他の官能基によって修飾されているものでも良く、アシル基またはアルキル基である場合には通常平均炭素数が８〜２２の直鎖または分岐のものが好ましく用いられる。また、これらの界面活性剤は、アルキレンオキシド構造、アミド構造、ヒドロキシル基などを分子中に有していても良い。これらの界面活性剤は、１種または２種以上を混合して用いることができ、通常、洗浄剤組成物中に０．１〜５０質量％（以下、％と記す）配合することが好ましい。 Specific examples of preferable surfactants include fatty acid soaps, alkyl sulfate type surfactants, alkyl ether sulfate type surfactants, olefin sulfonate type surfactants, and phosphate ester types as anionic surfactants. Surfactant, alkyl ether carboxylate type surfactant, amino acid salt type surfactant (sarcosine salt type, β-alanine salt type, glutamate type, aspartate type, etc.), sulfosuccinate type surfactant, As amphoteric surfactants such as taurine type surfactants, sulfobetaine type amphoteric surfactants, alkylbetaine type amphoteric surfactants, amidopropyl betaine type amphoteric surfactants, imidazolinium betaine type amphoteric surfactants, etc. As polar surfactants, amine oxide surfactants, sugar-based nonionic surfactants, etc. Alkyl glucosides, such as sugar fatty acid esters. The lipophilic group of these surfactants may be linear or branched, or may be partially modified with other functional groups, and is usually an acyl group or an alkyl group. A straight chain or branched chain having an average carbon number of 8 to 22 is preferably used. Further, these surfactants may have an alkylene oxide structure, an amide structure, a hydroxyl group, or the like in the molecule. These surfactants can be used singly or in combination of two or more, and it is usually preferable to add 0.1 to 50% by mass (hereinafter referred to as%) in the detergent composition.
本発明の組成物によれば、従来、増泡効果や増粘効果を期待して汎用されている高級脂肪酸ジエタノールアミドを実質的に配合しなくても所望の効果を得ることができ、高級脂肪酸ジエタノールアミドを多量に配合することによるすすぎ性や仕上がり感の欠点を解消することができる。尚、高級脂肪酸ジエタノールアミドを含有する混合原料を添加剤として配合する場合や、他の効果を期待して高級脂肪酸ジエタノールアミドを配合することは、本発明の目的とする性能に影響しない範囲であれば問題ない。尚、実質的に配合しないとは、本発明の組成物中の配合量が１％以下であり、好ましくは０．１％以下、さらに好ましくは０％である。 According to the composition of the present invention, a desired effect can be obtained without substantially blending a higher fatty acid diethanolamide, which has been conventionally used in anticipation of a foam increasing effect and a thickening effect. The disadvantages of rinsing properties and finished feeling due to the incorporation of a large amount of diethanolamide can be eliminated. It should be noted that when blended raw materials containing higher fatty acid diethanolamides are blended as additives, or blending higher fatty acid diethanolamides in anticipation of other effects, it is within a range that does not affect the target performance of the present invention. No problem. Note that substantially not blended means that the blending amount in the composition of the present invention is 1% or less, preferably 0.1% or less, more preferably 0%.
本発明の洗浄剤組成物は所望により、洗浄剤に一般に配合される成分、例えば、各種界面活性剤、高級アルコール、ラノリン誘導体、ポリエチレングリコールの脂肪酸エステル類等の油性成分、プロピレングリコール、グリセリン、ポリエチレングリコール等の保湿成分、脂肪酸エチレングリコール等のパール光沢剤、他の水溶性高分子化合物（ノニオン性、アニオン性などを含む）、動植物由来の抽出物、金属イオン封鎖剤、防腐剤、ｐＨ調整剤、紫外線吸収剤、酸化防止剤、色素及び香料等を適宜配合することができる。 The cleaning composition of the present invention is a component generally blended into the cleaning agent as desired, for example, various surfactants, higher alcohols, lanolin derivatives, oily components such as polyethylene glycol fatty acid esters, propylene glycol, glycerin, polyethylene Moisturizing ingredients such as glycol, pearl brightener such as fatty acid ethylene glycol, other water-soluble polymer compounds (including nonionic and anionic), animal and plant extracts, sequestering agents, preservatives, pH adjusters , Ultraviolet absorbers, antioxidants, pigments, fragrances, and the like can be appropriately blended.
また、本発明の洗浄剤組成物は、頭髪や身体各部の皮膚洗浄剤のいずれにも適用でき、ヘアシャンプー、ボディシャンプー、ハンドソープ、洗顔剤等の身体用洗浄剤として好適に使用できる。また、固形、液体、クリーム状、ジェル状、エアゾールフォーム、ポンプフォーム、スクイズフォーム、ミスト等様々な形態のものとして用いることができ、望ま
しくは液体洗浄料として用いられる。
Moreover, the cleaning composition of the present invention can be applied to any of the hair cleaning agents and the skin cleaning agents for various parts of the body, and can be suitably used as a body cleaning agent such as a hair shampoo, body shampoo, hand soap, and facial cleanser. Further, it can be used in various forms such as solid, liquid, cream, gel, aerosol foam, pump foam, squeeze foam, mist, and preferably used as a liquid cleaning agent.
次に本発明を実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.
ａ）洗浄性試験法
５ｃｍ×５ｃｍのウールモスリン布にラノリン７％及びスダンＩＩＩ ０．００５％のクロロホルム溶液０．４ｍＬを均一に塗布し、乾燥させ、この汚染布を３％の洗浄剤溶液４０ｍＬが入った約１００ｍＬのガラス製シリンダー中に入れ、４０℃の恒温槽中で１５分間振盪し、汚染布を流水中でよく濯ぎ、乾燥させ、反射率を調べ、次式により洗浄率を求めた。
a) Detergency Test Method 0.4 mL of a 7% lanolin and 0.005% Sudan III chloroform solution was uniformly applied to a 5 cm × 5 cm wool muslin fabric, dried, and 40 mL of 3% detergent solution was applied to the contaminated fabric. Was placed in a glass cylinder of about 100 mL, shaken in a constant temperature bath at 40 ° C. for 15 minutes, the contaminated cloth was rinsed thoroughly in running water, dried, the reflectivity was examined, and the washing rate was obtained by the following formula. .
また、評価の基準を次のように設定した。
◎・・・洗浄性優秀 洗浄率８５％以上
○・・・洗浄性良好 洗浄率７０％以上８５％未満
△・・・洗浄性普通 洗浄率５５％以上７０％未満
×・・・洗浄性不良 洗浄率５５％未満
The evaluation criteria were set as follows.
◎ ・ ・ ・ Excellent cleaning performance 85% or higher ○ ・ ・ ・ Good cleaning performance 70% or higher and lower than 85% △ ・ ・ ・ Normal cleaning performance 55% or higher and lower than 70% × ・ ・ ・ Poor cleaning performance Less than 55%
ｂ）使用感・仕上がり感試験法（ハーフヘッド法）
パネル（３０人）が頭髪を左右半々に分け、一方にコントロールとして、下記組成のシャンプーを、他方に試料をそれぞれ塗布し、同時に洗髪した時の泡立ち及び泡質と、毛髪を乾燥させた後の、うるおい感、べたつきのなさ及びツヤ等の仕上がり感を官能評価した。また、洗髪を上記と同様に１日１回行い、３０日間連続使用を行った後の毛髪の仕上がり感（うるおい感、べたつきのなさ及びツヤ）について官能評価を行った。
b) Usability / finish feeling test method (half-head method)
A panel (30 people) divided the hair into left and right halves. As a control, shampoo of the following composition was applied to one side, a sample was applied to the other side, and foaming and foam quality when the hair was washed at the same time, and after drying the hair Sensory evaluation was made on the feeling of moisture, non-stickiness, and finish such as gloss. In addition, the hair was washed once a day in the same manner as described above, and sensory evaluation was performed on the finished feeling (moisture, non-stickiness, and gloss) after 30 days of continuous use.
コントロール （％）
・ポリオキシエチレン（３）ラウリルエーテル硫酸ナトリウム ２０．０
・カチオン化セルロース誘導体
（商品名：ポリマーＪＲ−４００［ＵＣＣ社製］） ０．５
・精製水 残 余
Control (%)
Polyoxyethylene (3) sodium lauryl ether sulfate 20.0
・ Cationized cellulose derivatives
(Product name: Polymer JR-400 [manufactured by UCC]) 0.5
・ Purified water residue
また、評価の基準を次のように設定した。
◎・・・コントロールより良いと答えた人数が１９名以上
○・・・コントロールより良いと答えた人数が１６〜１８名
△・・・コントロールより良いと答えた人数が８〜１５名
×・・・コントロールより良いと答えた人数が７名以下
The evaluation criteria were set as follows.
◎ ・ ・ ・ 19 or more respondents said that it is better than control ○ ・ ・ ・ 16 to 18 respondents said that it was better than control △ ・ ・ ・ 8 to 15 respondents said that it was better than control × ・ ・・ The number of people who answered that it was better than control
実施例１〜１２及び比較例１〜７
表１に記載の配合組成よりなるヘアシャンプーを常法により調製し、泡立ち、泡質、仕上り感（うるおい感、べたつきのなさ及びツヤ）を評価し、その結果を表１に示した。
Examples 1-12 and Comparative Examples 1-7
A hair shampoo having the composition shown in Table 1 was prepared by a conventional method, and foaming, foam quality, and finishing feeling (moisturation, non-stickiness and gloss) were evaluated. The results are shown in Table 1.
表１より明らかなように、本発明の成分を用いた実施例１〜１２のヘアシャンプーはいずれも優れた性能を示していた。 As is clear from Table 1, all the hair shampoos of Examples 1 to 12 using the components of the present invention exhibited excellent performance.
一方、比較例１〜７では、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれかの特性が劣っており、本発明の目的を達成できなかった。 On the other hand, Comparative Examples 1 to 7 were inferior in any of the properties of detergency, foaming, foam quality, and finished feeling (immediately, after continuous use), and the object of the present invention could not be achieved.
実施例１３（ヘアシャンプー）
（％）
・ＰＯＥ（２）ラウリルエーテル硫酸ナトリウム ５．０
・ラウロイル−Ｎ−メチル−β−アラニンナトリウム ５．０
・ラウリン酸アミドプロピルベタイン １０．０
・ラウリン酸モノイソプロパノールアミド １．０
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体液（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） １．０
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） ５．０
・カチオン化セルロース
（商品名：カチナールＨＣ−２００；東邦化学工業社製） ０．２
・カチオン化フェヌグリークガム
（商品名：カチナールＣＦ−１００；東邦化学工業社製） ０．１
・ポリエーテル変性シリコーン
（商品名：ＳＩＬＷＥＴ Ｌ−７００１［日本ユニカー社製］） ５．０
・加水分解コムギ液
（商品名：ＧＬＵＡＤＩＮ Ｗ−２０；コグニス社製） ０．５
・カチオン化ハチミツ誘導体
（商品名：ハニーコート５０［ＡＲＣＨ社製］） ０．１
・ウイキョウ抽出物（商品名：ＮＡＢ Ｆｅｎｎｅｌ
Ｓｅｅｄ Ｅｘｔｒａｃｔ［ＡＲＣＨ社製］） ０．１
・ガリカバラ抽出物（商品名：Ｐｈｙｔｏｆｌｅｕｒ
Ｆｒｅｎｃｈ Ｒｏｓｅ［ＣＲＯＤＡＲＯＭ社製］） ０．１
・トウキンセンカ抽出物（商品名：オーガニック
トウキンセンカ抽出液ＢＧ−５０［香栄興業社製］） ０．１
・ホホバ抽出物（商品名：ホホバリーフエキス［香栄興業社製］） ０．１
・ユキノシタ抽出物
（商品名：ユキノシタ抽出液ＢＧ［丸善製薬社製］） ０．１
・カギイバラノリ抽出物
（商品名：ＢＩＯＳＴＲＵＣＴＵＲＥＲ［ＳＥＣＭＡ社製］） ０．１
・グリセリン ５．０
・ジプロピレングリコール ３．０
・ＥＤＴＡ−２Ｎａ ０．１
・メチルパラベン ０．２
・安息香酸ナトリウム ０．２
・クエン酸 適 量
・香料 適 量
・水 バランス
Example 13 (hair shampoo)
(%)
-POE (2) sodium lauryl ether sulfate 5.0
Lauroyl-N-methyl-β-alanine sodium 5.0
Lauric acid amidopropyl betaine 10.0
・ Lauric acid monoisopropanolamide 1.0
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer liquid (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 1.0
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; made by Nalco) 5.0
・ Cationized cellulose
(Product name: Kachinar HC-200; manufactured by Toho Chemical Industry Co., Ltd.) 0.2
・ Cationized fenugreek gum
(Product name: Kachinar CF-100; manufactured by Toho Chemical Industry Co., Ltd.) 0.1
・ Polyether-modified silicone
(Product name: SILWET L-7001 [manufactured by Nippon Unicar Co., Ltd.]) 5.0
・ Hydrolyzed wheat liquid
(Product name: GLUADIN W-20; manufactured by Cognis) 0.5
・ Cationized honey derivatives
(Product name: Honeycoat 50 [manufactured by ARCH)] 0.1
-Fennel extract (trade name: NAB Fennel
Seed Extract [manufactured by ARCH]] 0.1
・ Galika rose extract (trade name: Phytofullur
French Rose [manufactured by CRODAROM] 0.1
・ Toukanka extract (trade name: Organic
Tokinkinka extract BG-50 [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Jojoba extract (trade name: jojoba leaf extract [manufactured by Koei Kogyo Co., Ltd.]) 0.1
・ Yukinoshita extract
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Kagii Baranori Extract
(Product name: BIOSTRUCTURER [manufactured by SECMA]) 0.1
・ Glycerin 5.0
・ Dipropylene glycol 3.0
・ EDTA-2Na 0.1
・ Methylparaben 0.2
・ Sodium benzoate 0.2
・ Citric acid appropriate amount / fragrance appropriate amount / water balance
上記成分を均一に混合して調製した上記組成のシャンプー（ｐＨ５．５）は、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれにおいても、良好な結果を得た。 The shampoo (pH 5.5) having the above composition prepared by uniformly mixing the above components gave good results in all of the detergency, foaming, foam quality and finish feeling (immediately after and after continuous use).
実施例１４（ヘアシャンプー）
（％）
・ＰＯＥ（２）ラウリルエーテル硫酸ナトリウム ５．０
・ラウリル硫酸トリエタノールアミン ５．０
・ラウロイルメチル−β−アラニンナトリウム １．０
・Ｎ−ラウロイル−Ｎ−カルボキシメチル−Ｎ−
ヒドロキシエチルイミダゾリニウムベタイン液
（商品名：ソフタゾリンＣＬ［川研ファインケミカル社製］） ２．０
・ラウリルジメチルアミノ酢酸ベタイン ５．０
・ラウリン酸モノイソプロパノールアミド １．０
・ＰＯＥセトステアリルヒドロキシミリスチレンエーテル
（商品名：エルファコスＧＴ２８２Ｓ；ライオンアクゾ社製） ０．２
・エチレングリコールジステアレート ２．０
・高分子シリコン水性乳濁液（商品名：ＢＹ２２−０２９
［東レ・ダウ コーニング・シリコーン社製］） ４．０
・加水分解コムギ液
（商品名：プロモイスＷＧ［成和化成社製］） ０．５
・シリル化ペプチド誘導体
（商品名：プロモイスＳ−７００ＳＩＧ［成和化成社製］） ０．５
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体液（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） １．０
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） ２．０
・アクリルアミド・アクリル酸・
塩化ジメチルジアリルアンモニウム共重合体液（約１０％）
（商品名：ＭＥＲＱＵＡＴ ＰＬＵＳ ３３３０［ナルコ社製］） １．０
・カチオン化セルロース誘導体
（商品名：カチナールＬＣ−２００［東邦化学工業社製］） ０．５
・プロピレングリコール ２．０
・レモン果実抽出物（商品名：レモン抽出液ＢＧ［丸善製薬社製］） ０．１
・サボンソウ抽出物
（商品名：サボンソウ抽出液ＢＧ［丸善製薬社製」） ０．０５
・トウキンセンカ抽出物
（商品名：トウキンセンカ抽出液ＢＧ［丸善製薬社製］） ０．１
・ブドウ抽出物 ０．１
・ＥＤＴＡ−２Ｎａ ０．１
・クエン酸 適 量
・パラベン ０．２
・安息香酸ナトリウム ０．３
・香料 適 量
・精製水 残 余
Example 14 (hair shampoo)
(%)
-POE (2) sodium lauryl ether sulfate 5.0
・ Lauryl sulfate triethanolamine 5.0
・ Lauroylmethyl-β-alanine sodium 1.0
N-lauroyl-N-carboxymethyl-N-
Hydroxyethyl imidazolinium betaine solution
(Product name: Softazoline CL [manufactured by Kawaken Fine Chemical Co., Ltd.]) 2.0
・ Lauryldimethylaminoacetic acid betaine 5.0
・ Lauric acid monoisopropanolamide 1.0
・ POE cetostearyl hydroxymyristyl ether
(Product name: Elfacos GT282S; manufactured by Lion Akzo) 0.2
・ Ethylene glycol distearate 2.0
・ Polymer silicone aqueous emulsion (trade name: BY22-029
[Toray Dow Corning Silicone Co., Ltd.]) 4.0
・ Hydrolyzed wheat liquid
(Product name: Promois WG [manufactured by Seiwa Kasei Co., Ltd.]) 0.5
・ Silylated peptide derivatives
(Product name: Promois S-700SIG [Seiwa Kasei Co., Ltd.]) 0.5
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer liquid (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 1.0
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; made by Nalco) 2.0
・ Acrylamide ・ Acrylic acid ・
Dimethyl diallylammonium chloride copolymer liquid (about 10%)
(Product name: MERQUAT PLUS 3330 [manufactured by Nalco]) 1.0
・ Cationized cellulose derivatives
(Product name: Kachinar LC-200 [manufactured by Toho Chemical Industry Co., Ltd.]) 0.5
・ Propylene glycol 2.0
Lemon fruit extract (trade name: Lemon extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Soap extract
(Brand name: Savonso extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.05
・ Toukanka extract
(Brand name: Milky milk extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Grape extract 0.1
・ EDTA-2Na 0.1
・ Citric acid
・ Paraben 0.2
・ Sodium benzoate 0.3
・ Perfume appropriate amount
・ Purified water residue
上記成分を均一に混合して調製した上記組成のシャンプー（ｐＨ６．０）は、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれにおいても、良好な結果を得た。 The shampoo (pH 6.0) having the above composition prepared by uniformly mixing the above components obtained good results in all of the cleaning properties, foaming, foam quality, and finish feeling (immediately after and after continuous use).
実施例１５（ボディシャンプー）
（％）
・ラウリン酸 ９．０
・ミリスチン酸 ６．０
・パルミチン酸 ６．０
・ＰＯＥ（３）ラウリルエーテル硫酸ナトリウム ５．０
・ヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン ５．０
・ラウリン酸アミドプロピルベタイン １．５
・２−アルキル−Ｎ−カルボキシメチル−Ｎ−
ヒドロキシエチルイミダゾリニウムベタイン
（商品名：ソフタゾリンＣＬ−Ｒ；川研ファインケミカル社製） １．０
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） ０．５
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） １．０
・カチオン化フェヌグリークガム
（商品名：カチナールＣＦ−１００；東邦化学工業社製） ０．１
・ジステアリン酸エチレングリコール ２．０
・ヒドロキシプロピルメチルセルロース ０．３
・ＰＯＥセトステアリルヒドロキシミリスチレンエーテル
（商品名：エルファコスＧＴ２８２Ｓ；ライオンアクゾ社製） ０．２
・アルキルグルコシド
（商品名：ＡＰＧ６００；コグニス社製） ２．０
・加水分解コムギ液
（商品名：ＧＬＵＡＤＩＮ Ｗ−２０；コグニス社製） ０．５
・高分子シリコン水性乳濁液（商品名：ＢＹ２２−０２９
［東レ・ダウ コーニング・シリコーン社製］） ２．０
・グリセリン ５．０
・プロピレングリコール ５．０
・ＥＤＴＡ ０．１
・水酸化カリウム 適 量
・香料 適 量
・水 バランス
Example 15 (body shampoo)
(%)
・ Lauric acid 9.0
・ Myristic acid 6.0
・ Palmitic acid 6.0
-POE (3) sodium lauryl ether sulfate 5.0
Palm oil fatty acid acyl glutamate triethanolamine 5.0
・ Lamidate amidopropyl betaine 1.5
2-alkyl-N-carboxymethyl-N-
Hydroxyethyl imidazolinium betaine
(Product name: Softazoline CL-R; manufactured by Kawaken Fine Chemical Co., Ltd.) 1.0
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 0.5
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; manufactured by Nalco) 1.0
・ Cationized fenugreek gum
(Product name: Kachinar CF-100; manufactured by Toho Chemical Industry Co., Ltd.) 0.1
・ Ethylene glycol distearate 2.0
・ Hydroxypropyl methylcellulose 0.3
・ POE cetostearyl hydroxymyristyl ether
(Product name: Elfacos GT282S; manufactured by Lion Akzo) 0.2
・ Alkyl glucoside
(Product name: APG600; manufactured by Cognis) 2.0
・ Hydrolyzed wheat liquid
(Product name: GLUADIN W-20; manufactured by Cognis) 0.5
・ Polymer silicone aqueous emulsion (trade name: BY22-029
[Toray Dow Corning Silicone]] 2.0
・ Glycerin 5.0
・ Propylene glycol 5.0
・ EDTA 0.1
・ Potassium hydroxide appropriate amount / fragrance appropriate amount / water balance
上記成分を均一に混合して調製した上記組成のボディシャンプー（ｐＨ９．０）は、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれにおいても、良好な結果を得た。
The body shampoo (pH 9.0) having the above composition prepared by uniformly mixing the above components obtained good results in all of the cleaning properties, foaming, foam quality, and finish feeling (immediately after and after continuous use).
実施例１６（ハンドソープ）
（％）
・ラウリン酸 １０．０
・ミリスチン酸 ５．０
・パルミチン酸 ７．０
・ＰＯＥ（２）ラウリルエーテル硫酸ナトリウム ８．０
・パーム核油脂肪酸アミドプロピルベタイン ２．５
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体液（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） ０．５
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） ５．０
・カチオン化セルロース
（商品名：カチナールＬＣ−２００；東邦化学工業社製） ０．３
・ジステアリン酸エチレングリコール １．５
・ヒドロキシエチルセルロース ０．３
・レモンエキス
（商品名：レモン抽出液ＢＧ；丸善製薬社製） ０．２
・ニンジンエキス
（商品名：ニンジン抽出液ＢＧ；丸善製薬社製） ０．２
・加水分解シルク液
（商品名：プロモイスシルク−１０００；成和化成社製） １．０
・グリセリン ５．０
・１，３−ブチレングリコール ５．０
・ＥＤＴＡ ０．１
・トリエタノールアミン 適 量
・香料 適 量
・水 バランス
Example 16 (hand soap)
(%)
・ Lauric acid 10.0
・ Myristic acid 5.0
-Palmitic acid 7.0
-POE (2) sodium lauryl ether sulfate 8.0
Palm oil fatty acid amidopropyl betaine 2.5
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer liquid (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 0.5
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; made by Nalco) 5.0
・ Cationized cellulose
(Product name: Kachinar LC-200; manufactured by Toho Chemical Industry Co., Ltd.) 0.3
・ Ethylene glycol distearate 1.5
・ Hydroxyethylcellulose 0.3
・ Lemon extract
(Product name: Lemon extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.2
・ Carrot extract
(Product name: carrot extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.2
・ Hydrolysis silk solution
(Product name: Promois Silk-1000; manufactured by Seiwa Kasei Co., Ltd.) 1.0
・ Glycerin 5.0
1,3-butylene glycol 5.0
・ EDTA 0.1
・ Triethanolamine appropriate amount ・ fragrance appropriate amount ・ water balance
上記成分を均一に混合して調製した上記組成のハンドソープ（ｐＨ８．５）は、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれにおいても、良好な結果を得た。 A hand soap (pH 8.5) having the above composition prepared by uniformly mixing the above components gave good results in all of the cleaning properties, foaming, foam quality, and finish feeling (immediately after and after continuous use).
実施例１７（洗顔料）
（％）
・ラウリン酸 ７．０
・ミリスチン酸 ６．０
・パルミチン酸 ４．０
・ステアリン酸 ２．０
・ＰＯＥ（３）ヤシ油アルキルエーテル硫酸ナトリウム ８．０
・ラウリン酸アミドプロピルベタイン ２．５
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体液（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） １．５
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） ２．０
・アクリルアミド・アクリル酸・
塩化ジメチルジアリルアンモニウム共重合体液（約１０％）
（商品名：ＭＥＲＱＵＡＴ ＰＬＵＳ ３３３０；ナルコ社製） １．０
・カチオン化グアーガム
（商品名：ジャガーＣ−１３−Ｓ；三晶社製） ０．２
・ジステアリン酸エチレングリコール ２．５
・ユキノシタエキス
（商品名：ユキノシタ抽出液ＢＧ；丸善製薬社製） １．０
・海藻抽出物（商品名：カイソウ抽出液；丸善製薬社製） ０．５
・グリセリン ２．０
・１，３−ブチレングリコール １０．０
・ＥＤＴＡ ０．１
・水酸化カリウム 適 量
・香料 適 量
・水 バランス
Example 17 (face wash)
(%)
・ Lauric acid 7.0
・ Myristic acid 6.0
Palmitic acid 4.0
・ Stearic acid 2.0
-POE (3) palm oil sodium alkyl ether sulfate 8.0
・ Lamidate amidopropyl betaine 2.5
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer liquid (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 1.5
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; made by Nalco) 2.0
・ Acrylamide ・ Acrylic acid ・
Dimethyl diallylammonium chloride copolymer liquid (about 10%)
(Product name: MERQUAT PLUS 3330; manufactured by Nalco) 1.0
・ Cationized guar gum
(Product name: Jaguar C-13-S; manufactured by Sankisha) 0.2
・ Ethylene glycol distearate 2.5
・ Yukinoshita Extract
(Product name: Yukinoshita Extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 1.0
・ Seaweed extract (trade name: diatom extract; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.5
・ Glycerin 2.0
・ 1,3-Butylene glycol 10.0
・ EDTA 0.1
・ Potassium hydroxide appropriate amount / fragrance appropriate amount / water balance
上記成分を均一に混合して調製した上記組成の洗顔料（ｐＨ８．８）は、洗浄性、泡立ち、泡質、仕上がり感（直後、連用後）のいずれにおいても、良好な結果を得た。 The facial cleanser (pH 8.8) having the above composition prepared by uniformly mixing the above components gave good results in any of the detergency, foaming, foam quality and finish feeling (immediately after and after continuous use).
尚、上記各処方にて用いた香料は下記のものである。
本発明によって、洗浄性に優れ、洗浄時にはクリーミィでありながらかつボリュームのある泡が得られ、使用後の肌や髪につやを与え、みずみずしさ（うるおい感）を保つことができ、かつ長期間の連用によってもべたつき感が生じない洗浄剤組成物を提供することができる。 According to the present invention, it is excellent in cleanability, can produce creamy and voluminous foam at the time of cleaning, can give skin and hair after use, can keep freshness (moisture feeling), and can be used for a long time Thus, it is possible to provide a cleaning composition that does not give a sticky feeling even when used continuously.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004047389A JP4787469B2 (en) | 2004-02-24 | 2004-02-24 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004047389A JP4787469B2 (en) | 2004-02-24 | 2004-02-24 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005239558A true JP2005239558A (en) | 2005-09-08 |
| JP4787469B2 JP4787469B2 (en) | 2011-10-05 |
Family
ID=35021680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004047389A Expired - Lifetime JP4787469B2 (en) | 2004-02-24 | 2004-02-24 | Cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4787469B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2008038496A1 (en) * | 2006-09-26 | 2010-01-28 | ライオン株式会社 | Shampoo composition |
| JP2010138083A (en) * | 2008-12-10 | 2010-06-24 | Milbon Co Ltd | Shampoo |
| JP2012246270A (en) * | 2011-05-30 | 2012-12-13 | Hoyu Co Ltd | Hair shampoo composition |
| JP2016222670A (en) * | 2015-06-02 | 2016-12-28 | 東邦化学工業株式会社 | Detergent composition |
| JP2017075295A (en) * | 2015-10-15 | 2017-04-20 | ライオン株式会社 | Liquid detergent |
-
2004
- 2004-02-24 JP JP2004047389A patent/JP4787469B2/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2008038496A1 (en) * | 2006-09-26 | 2010-01-28 | ライオン株式会社 | Shampoo composition |
| JP5552742B2 (en) * | 2006-09-26 | 2014-07-16 | ライオン株式会社 | Shampoo composition |
| JP2010138083A (en) * | 2008-12-10 | 2010-06-24 | Milbon Co Ltd | Shampoo |
| JP2012246270A (en) * | 2011-05-30 | 2012-12-13 | Hoyu Co Ltd | Hair shampoo composition |
| JP2016222670A (en) * | 2015-06-02 | 2016-12-28 | 東邦化学工業株式会社 | Detergent composition |
| JP2017075295A (en) * | 2015-10-15 | 2017-04-20 | ライオン株式会社 | Liquid detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4787469B2 (en) | 2011-10-05 |
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