JP2005212489A - Manufacturing method of article having pattern-like anti-fogging effect - Google Patents

Manufacturing method of article having pattern-like anti-fogging effect Download PDF

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JP2005212489A
JP2005212489A JP2005075952A JP2005075952A JP2005212489A JP 2005212489 A JP2005212489 A JP 2005212489A JP 2005075952 A JP2005075952 A JP 2005075952A JP 2005075952 A JP2005075952 A JP 2005075952A JP 2005212489 A JP2005212489 A JP 2005212489A
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article
pattern
film
transparent
antifogging
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Shigeki Nomura
茂樹 野村
Toshiharu Otsuka
敏治 大塚
Takashi Sawara
敬 佐原
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of an article having an anti-fogging effect in the shape of a pattern, which can give a high design quality, by utilizing changes in temperature and humidity, for a transparent article whose inside can be seen through, such as glass and a transparent plastic used for a window and show window, a show case and a glass tumbler or for a reflexive article having a high surface brightness such as a mirror. <P>SOLUTION: The manufacturing method of the article having the anti-fogging effect in the shape of a pattern comprises pasting in the shape of a pattern a film having an anti-fogging effect on a surface of the transparent article through which the light passes or the reflexive article on which the light reflects. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、パターン状に防曇効果を有する物品の製造方法に関し、更に詳しくは窓やショーウインドウ等に用いられるガラスや透明プラスチック、ショーケースやガラスコップ等の内部が透視できる透視性物品或いは鏡その他表面輝度の高い反射性物品に、温湿度の変化を利用して高い意匠性を付与し得るパターン状に防曇効果を有する物品の製造方法に関する。 The present invention relates to a method of manufacturing an article having an antifogging effect in a pattern, and more specifically, a transparent article or mirror that can be seen through the inside of glass, transparent plastic, showcases, glass cups, and the like used for windows and show windows. The present invention also relates to a method for manufacturing an article having an antifogging effect in a pattern that can impart high designability to a reflective article having a high surface luminance by utilizing changes in temperature and humidity.

多湿な環境や温度差が大きい環境において、透視性を要求される窓、ショーウインドウ、ショーケース等の物品や反射性を要求される鏡等の物品は、結露によって曇り、内部が透視できなくなったり、映像を確認できなくなったりするので、従来から、種々の曇り防止手段が講ぜられている。 In humid environments or environments with large temperature differences, items such as windows, show windows, and showcases that require transparency, and mirrors that require reflectivity may become cloudy due to condensation, making it impossible to see through the interior. Since the video cannot be confirmed, various anti-fogging means have been conventionally taken.

上記の如く、これらの透視性物品或いは反射性物品は、その物品の有する透視性或いは反射性がこれらの物品自身の基本的な性能である場合が多く、気中の水蒸気の結露による透過光の乱反射の発生、即ち、曇りの発生は、これらの物品において大きな欠点になる場合が多い。 As described above, in these transparent articles or reflective articles, the transparency or reflectivity of the articles is often the basic performance of these articles themselves, and transmitted light due to condensation of water vapor in the air is often present. The occurrence of diffuse reflection, i.e., cloudiness, is often a major drawback in these articles.

これらの曇り防止の一般的な手段としては、例えば、これらの透視性物品等に微弱な電流を流して加温して曇りを防止する方法、発熱体を透視性物品近傍に配置し、その熱によって曇りを防止する方法、透視性物品表面近傍に強制的に空気の流れを作って曇りを防止する方法或いはこれらを併用した方法等がある。上記の方法はいずれも、予めこれらの物品を防曇に適した構造にしておく必要があり、一般的には高価なものとなる。 As a general means for preventing these fogging, for example, a method of passing a weak current through these transparent articles to heat them to prevent fogging, a heating element is arranged in the vicinity of the transparent articles, and the heat There are a method for preventing fogging, a method for forcibly creating an air flow in the vicinity of the surface of the transparent article to prevent fogging, or a method using these in combination. In any of the above methods, it is necessary to make these articles in a structure suitable for anti-fogging in advance, which is generally expensive.

更に、これらの透視性物品等に微弱な電流を流して加温する方法、発熱体を用いて近傍より加温する方法は、いずれも漏電防止のため特に厳重な注意を払い、安全な構造を採る必要があり、且つ、ランニングコストがかかるので経済的な方法とはいえない。 Furthermore, the method of heating by passing a weak current through these transparent articles, etc., and the method of heating from the vicinity using a heating element pay special attention to prevent leakage, and have a safe structure. It is not an economical method because it needs to be adopted and the running cost is high.

一方、簡易な方法として、防曇効果を有する塗料を噴霧塗布(例えば、RP東プラ社製、商品名「くもらないスプレー」等)等で塗布する方法や防曇性を有するフィルムをこれら物品に貼着する方法も採られているが、これらの方法は、いずれも防曇効果の寿命が短く、適用範囲は極めて限られたものとなる。 On the other hand, as a simple method, a paint having an anti-fogging effect is applied by spray coating (for example, product name “Mokudashi Spray” manufactured by RP Topura Co., Ltd.) or the like, or a film having anti-fogging properties is applied to these articles. Although the method of sticking is also taken, all of these methods have a short life of the anti-fogging effect, and the application range is extremely limited.

又、物品表面に防曇性の塗料を直接塗布して曇りを防止する方法も採られている。これらの防曇性被膜や防曇性物品の製造方法として、例えば、特許文献1に、親水性のポリビニルアルコールをシランカップリング剤等の架橋剤で架橋して耐水性や表面硬度を高め、良好な接着性を付与し得るとする防曇性被膜が開示され、特許文献2に、比較的親水性を有するポリオール変性メラミン樹脂に界面活性剤を添加した防曇性物品が開示されている。 In addition, a method of preventing fogging by directly applying an antifogging paint to the surface of the article is also employed. As a method for producing these antifogging films and antifogging articles, for example, in Patent Document 1, hydrophilic polyvinyl alcohol is cross-linked with a cross-linking agent such as a silane coupling agent to improve water resistance and surface hardness. An antifogging film capable of imparting excellent adhesiveness is disclosed, and Patent Document 2 discloses an antifogging article obtained by adding a surfactant to a polyol-modified melamine resin having a relatively hydrophilic property.

しかし、上記のいずれの方法も、透視性物品や反射性物品の全面にわったって防曇効果が発揮される。即ち、結露による曇りは物品の性能を低下させるだけのものであるという認識に立った技術であって、結露によって生ずる曇りを積極的に利用して、当該物品の意匠性をより向上させようとする意図は全くない。
特開平3−181586号公報 特開昭56−159231号公報
However, any of the above methods exhibits an antifogging effect over the entire surface of the transparent article or the reflective article. In other words, it is a technology based on the recognition that fogging due to condensation only lowers the performance of an article, and actively uses the fogging caused by condensation to further improve the design of the article. There is no intention to do.
Japanese Patent Laid-Open No. 3-181586 JP 56-159231 A

本発明は、叙上の事実に鑑みなされたものであって、その目的とするところは、結露によって生ずる曇りを積極的に利用して文字や図柄等のパターンが浮きでる意匠性の高いパターン状に防曇効果を有する物品の製造方法を提供することにある。 The present invention has been made in view of the above facts, and the object of the present invention is to provide a pattern with a high design property in which patterns such as letters and designs are lifted by positively using cloudiness caused by condensation. Another object of the present invention is to provide a method for producing an article having an antifogging effect.

本発明は、光が透過する透視性物品或いは光が反射する反射性物品の表面に、防曇性を有するフィルムをパターン状に貼付するパターン状に防曇効果を有する物品の製造方法である。
以下に本発明を詳述する。
The present invention is a method for producing an article having an antifogging effect in a pattern in which a film having antifogging properties is pasted on the surface of a transparent article that transmits light or a reflective article that reflects light.
The present invention is described in detail below.

上記光が透過する透視性物品としては、特に限定されるものではなく、例えば、窓ガラス、間仕切り等の光線を採り入れ、或いは該物品を透過して見ることができるもの、冷凍ショーケース、コップ、瓶、額、包装材料等の内蔵物を透視するもの、トランスペアレンシーシート等の透過光自体を使用するもの等であって、その材質は、ガラス、その他の透光性の無機材料、プラスチックス、その他の透光性の有機材料等の可視光線を透過し得るものが挙げられる。ここで可視光線とは、可視光線の総てである必要はなく、その一部の可視光線を透過し得るものであってもよい。 The transparent article through which the light passes is not particularly limited, and for example, a window glass, a light such as a partition, or the like that can be seen through the article, a frozen showcase, a cup, Those that see through the built-in items such as bottles, forehead, and packaging materials, those that use transmitted light itself such as transparency sheets, etc., the material is glass, other light-transmitting inorganic materials, plastics, Other materials that can transmit visible light, such as a light-transmitting organic material, can be used. Here, the visible light does not need to be all visible light, and may be a part of which visible light can be transmitted.

上記光が反射する反射性物品としては、特に限定されるものではなく、例えば、代表的に鏡が挙げられるが、その他研磨され光沢のある金属、ガラス、金属蒸着されたプラスチックス等、結露による曇りの存在が目視により確認し得るものが挙げられる。 The reflective article that reflects the light is not particularly limited. For example, a typical example is a mirror, but other polished and glossy metals, glass, metal-deposited plastics, and the like are caused by condensation. The thing which can confirm the presence of cloudiness visually is mentioned.

上記パターンとは、表示や装飾効果を目的とする文字や図柄等を指す。 The pattern refers to characters, designs and the like for display and decoration effects.

上記防曇性を有するフィルムとしては、特に限定されるものではないが、例えば、セロハン等の親水性セルロース系フィルム、ポリエチレン、ポリプロピレン、塩化ビニル樹脂、ポリエチレンテレフタレート等の合成樹脂に各々界面活性剤を添加したフィルム、上記合成樹脂フィルムに塗布型の防曇処理剤を塗布したフィルム等が挙げられる。これらの防曇性を有するフィルムとして市販されているものは、例えば、大日本印刷社製、商品名「ミランパ」、RP東プラ社製、商品名「くもらないフィルム」、ソニーケミカル社製、商品名「ボードンフィルム」、理研ビニル工業社製、商品名「RIVEX−AF」、日本板硝子社製、商品名「ペルコートAF」、FILM SPECIALITIES社製、商品名「VISTEX」等が挙げられる。 The antifogging film is not particularly limited. For example, a hydrophilic cellulose film such as cellophane, a synthetic resin such as polyethylene, polypropylene, vinyl chloride resin, and polyethylene terephthalate is used with a surfactant. Examples thereof include an added film and a film obtained by applying a coating-type antifogging agent to the synthetic resin film. Those commercially available as films having anti-fogging properties include, for example, products manufactured by Dai Nippon Printing Co., Ltd., trade names “Mirampa”, RP Topura Co., Ltd., trade names “Kumadai Film”, products manufactured by Sony Chemical Co., Ltd. Name “Bordon Film”, manufactured by Riken Vinyl Industry Co., Ltd., trade name “RIVEX-AF”, manufactured by Nippon Sheet Glass Co., Ltd., trade name “Pelcoat AF”, manufactured by FILM SPECIALITIES, trade name “VISTEX”, and the like.

上記防曇性を有するフィルムをパターン状に裁断する手段としては、特に限定されるものではないが、例えば、特に粘着シートを任意の形状にカットするカッティングマシン(積水化学工業社製、商品名「セキスイカッティングマシン920F型」等)が好適に用いられる。又、上記防曇性を有するフィルムにパターン状に切れ目を入れておき、該防曇性を有するフィルムを透視性物品或いは反射性物品の表面に貼付後、上記フィルムの不要部分のみを剥離して除去する如くなされていてもよい。 The means for cutting the film having antifogging properties into a pattern is not particularly limited. For example, a cutting machine that cuts the adhesive sheet into an arbitrary shape (Sekisui Chemical Co., Ltd., trade name “ Sekisui cutting machine 920F type "or the like is preferably used. In addition, a pattern is cut in the antifogging film, and after the antifogging film is pasted on the surface of a transparent article or a reflective article, only unnecessary portions of the film are peeled off. It may be made to remove.

上記防曇性を有するフィルムを上記透視性物品或いは反射性物品の表面に貼付する手段は、特に限定されるものではないが、例えば、接着剤で貼付されてもよく、又、上記防曇性を有するフィルムの裏面に予め粘着剤層を設けておき、被着面に押圧して貼付されてもよく、上記透視性物品或いは反射性物品の表面と上記防曇性を有するフィルムの裏面間に両面粘着テープを介在させて貼付されてもよい。 A means for attaching the antifogging film to the surface of the transparent article or the reflective article is not particularly limited, and may be attached with an adhesive, for example. A pressure-sensitive adhesive layer may be provided in advance on the back surface of the film having, and may be pressed and stuck to the adherend surface, between the surface of the transparent article or reflective article and the back surface of the film having antifogging properties. It may be affixed with a double-sided adhesive tape interposed.

上記防曇性を有するフィルムが、予め粘着剤層が設けられてなる場合、該防曇性を有するフィルムをパターン状に裁断した後、裏面に積層された粘着剤層を表面に露出させて、被
着体である透視性物品或いは反射性物品の表面に綺麗に貼付するために用いられる通称アプリケションテープに一旦仮着し、これを上記透視性物品或いは反射性物品の表面に転写した後、アプリケションテープのみを剥離して貼付されてもよい。
When the film having antifogging property is provided with an adhesive layer in advance, after cutting the film having antifogging property into a pattern, the adhesive layer laminated on the back surface is exposed on the surface, Once temporarily attached to a so-called application tape that is used to cleanly adhere to the surface of a transparent article or a reflective article, which is an adherend, and transfer it to the surface of the transparent article or reflective article, Only the application tape may be peeled off and attached.

本発明のパターン状に防曇効果を有する物品の製造方法は、叙上の如く構成されているので、透明な防曇性を有するフィルムを用いた場合、結露によって上記物品の表面が曇った場合のみ目的とする文字や図柄等のパターンが浮きでる極めて意匠性の高い物品を、極めて簡単な方法によって得ることができる。 Since the method for producing an article having an antifogging effect in the pattern of the present invention is configured as described above, when a transparent film having an antifogging property is used, the surface of the article is fogged due to condensation. It is possible to obtain an article with extremely high designability, in which a pattern such as a target character or design is floating, by an extremely simple method.

以下に実施例を掲げて本発明を更に詳しく説明するが、本発明はこれら実施例のみに限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.

(実施例1)
防曇フィルム(RP東プラ社製、商品名「くもらないフィルム」)をカッティングマシン(積水化学工業社製、商品名「セキスイカッティングマシン920F型」)で30ポイントの文字「A」をカットし、マーキングフィルム転写用シート(積水化学工業社製、商品名「セキスイアプリケーションテープ#555」)に仮着し、建築用透明ガラス(旭硝子社製)に貼付し、マーキングフィルム転写用シートを剥離してパターン状に防曇効果を有する物品を得た。
(Example 1)
Cut the 30-point letter “A” with an anti-fogging film (RP Topura Co., Ltd., trade name “cloudy film”) with a cutting machine (Sekisui Chemical Co., Ltd., trade name “Sekisui Cutting Machine 920F type”), Temporarily attach to a marking film transfer sheet (Sekisui Chemical Co., Ltd., trade name “Sekisui Application Tape # 555”), affix it to transparent glass for construction (Asahi Glass Co., Ltd.), peel off the marking film transfer sheet, and pattern An article having an antifogging effect was obtained.

得られたパターン状に防曇効果を有する物品を、温度23℃、湿度50%RHの室内に放置した後、呼気を吹きかけたところ、印刷文字「A」の部分だけが曇らず、浮き出して視認でき、該部を通して反対面を透視できた。 The obtained pattern-shaped article having an anti-fogging effect is left in a room at a temperature of 23 ° C. and a humidity of 50% RH and then exhaled. And the opposite surface could be seen through.

本発明のパターン状に防曇効果を有する物品の製造方法は、いずれも極めて簡便な手段によって、結露によって目的とする文字や図柄等のパターンが浮きでる極めて意匠性の高い、パターン状に防曇効果を有する物品を製造することができる。
しかも、上記パターンが装飾効果を目的とする文字や図柄等である場合には、光や温湿度等の環境を適宜変化させることにより、一層装飾効果を高めることができる。
The method for producing an article having an anti-fogging effect in a pattern according to the present invention is extremely anti-fogging in a pattern having a very high design, in which a desired pattern of characters, designs, etc. is floated by condensation by extremely simple means. An article having an effect can be manufactured.
In addition, when the pattern is a character, a design, or the like for the purpose of decoration, the decoration effect can be further enhanced by appropriately changing the environment such as light, temperature and humidity.

Claims (1)

光が透過する透視性物品或いは光が反射する反射性物品の表面に、防曇性を有するフィルムをパターン状に貼付することを特徴とするパターン状に防曇効果を有する物品の製造方法。 A method for producing an article having an antifogging effect in a pattern, wherein a film having an antifogging property is attached to the surface of a transparent article that transmits light or a reflective article that reflects light.
JP2005075952A 2005-03-16 2005-03-16 Manufacturing method of article having pattern-like anti-fogging effect Withdrawn JP2005212489A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
JP2005075952A JP2005212489A (en) 2005-03-16 2005-03-16 Manufacturing method of article having pattern-like anti-fogging effect

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JP22531396A Division JP3673335B2 (en) 1996-08-27 1996-08-27   Method for manufacturing article having antifogging effect in pattern shape

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