JP2005145077A - Decorative laminate - Google Patents

Decorative laminate Download PDF

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JP2005145077A
JP2005145077A JP2005017646A JP2005017646A JP2005145077A JP 2005145077 A JP2005145077 A JP 2005145077A JP 2005017646 A JP2005017646 A JP 2005017646A JP 2005017646 A JP2005017646 A JP 2005017646A JP 2005145077 A JP2005145077 A JP 2005145077A
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decorative
sheet
paper
synthetic resin
adhesive
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Noboru Wakabayashi
昇 若林
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a decorative laminate prevented from undergoing deformation due to moisture absorption/releasing under open air during storage or long term use, and easily processed with a fireproof, odorless and low priced adhesive like an emulsion adhesive on application. <P>SOLUTION: The laminate is composed by laminating a decorative sheet 2 on one side, and a chartaceous sheet 4 on the other side, of a ligneous substrate 3; wherein the chartaceous sheet 4 comprises two tissue papers 41 and 43 of a basis weight of 25 to 40 g/m<SP>2</SP>and being bonded through an extrusion coating layer 42 of a thermoplastic synthetic resin. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、各種家具類や建築内装材等の表面材として用いられる、外気の湿度や水分により反りが生じることのない化粧板に関するものである。   The present invention relates to a decorative board that is used as a surface material for various furniture and building interior materials, etc., and does not warp due to the humidity and moisture of the outside air.

従来、合板、MDF(中密度木質系ファイバーボード)、ハードボード、パーチクルボード等の吸湿或いは吸水、又は、放湿により含水率が変わり易い、所謂、木質系基材の片面に、熱硬化性樹脂含浸紙、熱可塑性樹脂シート等の化粧シートを積層、固着して化粧被覆層を形成せしめてなる化粧板が知られており、装飾用建築用板、家具類の表面装飾板等種々の用途に用いられているが、化粧シート貼着時の接着剤の乾燥の度合い、また、保管中或いは長期間の使用に際して湿気の影響を受けて狂いを生ずることがある。即ち、上記木質系基材の含水率が、その外気条件下における木質系基材の平衡含水率より小さい場合には、該化粧板の化粧シートを積層、固着してない面から吸湿或いは吸水して裏面側を膨張させる傾向があり、また、反対に木質系基材の含水率が、その外気条件下における木質系基材の平衡含水率より大きい場合には、放湿して収縮させる傾向があるのに対し、表面側には一般に化粧被覆層が施されているため表面側からの吸放湿は殆どなされない。従って化粧板の表面側と裏面側との膨張率、又は収縮率が異なり、図2のような反りを生じその結果商品価値が損なわれると共に使用に際して接着を困難にする。また、フラッシュ構造のドア、引き戸、間仕切り等に加工した場合、図2(ロ)のような表面板を凸とする反りが発生し、表面材の化粧板が芯材と剥離するという問題があった。   Conventionally, the moisture content of plywood, MDF (medium density wood fiber board), hard board, particle board, etc., moisture content or water content is easily changed by moisture release, so-called wood-based substrate impregnated with thermosetting resin A decorative board is known in which a decorative coating layer is formed by laminating and fixing decorative sheets such as paper and thermoplastic resin sheets, and is used for various purposes such as decorative architectural boards and furniture surface decorative boards. However, the degree of drying of the adhesive when sticking the decorative sheet, and the influence of moisture during storage or long-term use may cause a malfunction. That is, when the moisture content of the wooden base material is smaller than the equilibrium moisture content of the wooden base material under the outside air condition, the decorative sheet of the decorative board is laminated and absorbs moisture or water from the non-adhered surface. If the moisture content of the wooden substrate is higher than the equilibrium moisture content of the wooden substrate under the outside air condition, the moisture tends to be released and contracted. On the other hand, since a decorative coating layer is generally applied to the surface side, moisture absorption / release from the surface side is hardly performed. Therefore, the expansion rate or contraction rate of the front surface side and the back surface side of the decorative board is different, causing warping as shown in FIG. 2, resulting in a loss of commercial value and difficulty in bonding in use. In addition, when processed into a flash-structured door, sliding door, partition, etc., there is a problem that the surface plate as shown in FIG. It was.

このような欠点を解消しようとして、表面に化粧シートを貼付けた化粧板の裏面側に、化粧板の裏面からの吸湿、放湿による木質系基板の含水率の変化を防ぐ方法として、例えば、塗料を塗装したもの、塩化ビニル、ポリエチレン、ポリプロピレン等の合成樹脂フイルムを貼合せたもの、また紙と合成樹脂の2層からなるシートを貼合せたものが知られている。   In order to eliminate such disadvantages, as a method for preventing moisture change from the back side of the decorative board on the back side of the decorative board with a decorative sheet pasted on the surface, moisture content change of the wooden substrate due to moisture release, for example, paint There are known materials coated with synthetic resin films such as vinyl chloride, polyethylene and polypropylene, and materials laminated with two layers of paper and synthetic resin.

しかしながら、上記の塗料を塗装したものは、合板、MDF等木質系基材の表面の塗料の吸い込みが強く、また表面の平滑度が悪いために均一な防湿、防水層を形成することが難しいという欠陥があり、塩化ビニル、ポリエチレン、ポリプロピレン等の合成樹脂フイルムを貼合せたものの場合、フイルムコストが高く、更に、貼合せに溶剤型の接着剤を用いねばならないため、火気に対して安全で、臭気がないエマルジョン型接着剤を用いることが出来ず、価格的にも高価になりがちである。紙と合成樹脂の2層からなるシートの場合は、該シートがカールし易く、木質系基材への貼付け作業が困難である等の問題があった。   However, it is difficult to form a uniform moisture-proof and waterproof layer in the case where the above-mentioned paint is applied, because the paint on the surface of the wood base material such as plywood or MDF is strongly sucked and the smoothness of the surface is poor. If there is a defect and the synthetic resin film such as vinyl chloride, polyethylene, polypropylene is laminated, the film cost is high, and furthermore, a solvent-type adhesive must be used for the lamination, so it is safe against fire, An emulsion type adhesive having no odor cannot be used and tends to be expensive in price. In the case of a sheet composed of two layers of paper and synthetic resin, there are problems such as the sheet being easily curled and difficult to affix to a wooden base material.

本発明はかかる問題点に鑑みてなされたものであって、その目的とするところは、保管中或いは長期間の使用に際して、外気による吸湿、放湿等による板反り現象を起こさず、また、施工にあたっても、エマルジョン型接着剤のような火気に対して安全で、臭気がない、価格的にも安価な接着剤で容易に加工の出来る化粧板を提供することにある。   The present invention has been made in view of such problems, and the object of the present invention is to prevent plate warping due to moisture absorption, moisture release, etc. due to outside air during storage or long-term use. At the same time, it is an object to provide a decorative board that is safe against fire such as an emulsion type adhesive, has no odor, and can be easily processed with an inexpensive adhesive.

上記目的を達成するために、本発明の化粧板は、木質系基材の一方の面に化粧シートを積層し、他方の面に、2枚の秤量25〜40g/m2の薄葉紙を熱可塑性合成樹脂の押出しコート層を介して接着してなる紙質系シートが積層されていることを特徴とするものである。 In order to achieve the above object, the decorative board of the present invention has a decorative sheet laminated on one side of a wooden base material, and two sheets of thin paper having a weight of 25 to 40 g / m 2 are thermoplastic on the other side. It is characterized in that paper-based sheets that are bonded through a synthetic resin extrusion coating layer are laminated.

そして、前記熱可塑性合成樹脂の押出しコート層がポリオレフィン系樹脂であることがより好ましいものである。   And it is more preferable that the extrusion coating layer of the thermoplastic synthetic resin is a polyolefin resin.

本発明の化粧板は、化粧合板の裏面に2枚の薄葉紙を熱可塑性合成樹脂の押出しコート層を介して接着してなる紙質系シートを防湿層として貼合せた構成としているので、化粧合板の裏面からの水分や湿度は熱可塑性合成樹脂層によって遮断されるために、反りの発生が防止される。   The decorative board of the present invention has a constitution in which a paper-based sheet obtained by adhering two thin paper sheets to the back surface of the decorative plywood through an extrusion coating layer of a thermoplastic synthetic resin is bonded as a moisture-proof layer. Since moisture and humidity from the back surface are blocked by the thermoplastic synthetic resin layer, warpage is prevented from occurring.

また、化粧板の裏面に貼着される防湿層は、熱可塑性合成樹脂層を芯層としてその表裏に薄葉紙が積層一体化されてなる3層構造よりなるため、芯層の熱可塑性合成樹脂層による防湿効果に加えて、表裏面における薄葉紙が化粧板裏面および後加工施工面に対し、火気に対して安全で、臭気がない、価格的にも安価なエマルジョン型接着剤を使用して良好な接着強度を発揮する。更に、フラッシュ構造のドア、引き戸、間仕切り等への化粧板の貼付け作業も容易に行われ、品質的にも安定な製品が得られた。   In addition, the moisture-proof layer attached to the back surface of the decorative board has a three-layer structure in which a thermoplastic synthetic resin layer is used as a core layer and thin papers are laminated and integrated on the front and back. Therefore, the thermoplastic synthetic resin layer of the core layer In addition to the moisture-proofing effect, the thin paper on the front and back sides is good for the back side of the decorative board and the post-processed surface by using an emulsion-type adhesive that is safe against fire, has no odor, and is inexpensive. Demonstrate adhesive strength. Furthermore, the decorative plate can be easily pasted onto flash doors, sliding doors, partitions, etc., and a stable product can be obtained.

以下、実施の形態について図面を参照して説明する。図1は本発明の化粧板の積層構成を示す断面図であり、1は化粧板、2は化粧シート、3は木質系基材、4は紙質系シート、41、43は薄葉紙、42は熱可塑性合成樹脂層、5は接着剤層をそれぞれ表している。   Hereinafter, embodiments will be described with reference to the drawings. FIG. 1 is a cross-sectional view showing a laminated structure of a decorative board according to the present invention, wherein 1 is a decorative board, 2 is a decorative sheet, 3 is a wood-based substrate, 4 is a paper-based sheet, 41 and 43 are thin papers, and 42 is heat. Plastic synthetic resin layers and 5 represent adhesive layers, respectively.

これらの図から分かるように、化粧板1の構成としては、図1に示すように、2枚の薄葉紙41、43が熱可塑性合成樹脂の押出しコート層42を介して接着された紙質系シート4、接着剤層5、木質系基材3、接着剤層5および化粧シート2が下から順に積層された構成からなる。本発明の化粧板1の特徴は、防湿層として、2枚の薄葉紙41、43を熱可塑性合成樹脂の押出しコート層42を介して接着してなる紙質系シート4を化粧板1の裏面に接着剤層5を介して設けている点にある。   As can be seen from these drawings, the decorative board 1 has a configuration in which a sheet-like sheet 4 in which two thin paper sheets 41 and 43 are bonded via an extruded coat layer 42 of a thermoplastic synthetic resin as shown in FIG. The adhesive layer 5, the woody base material 3, the adhesive layer 5, and the decorative sheet 2 are laminated in order from the bottom. A feature of the decorative board 1 of the present invention is that a paper sheet 4 formed by adhering two thin paper sheets 41 and 43 through a thermoplastic synthetic resin extrusion coating layer 42 is adhered to the back surface of the decorative board 1 as a moisture-proof layer. It exists in providing through the agent layer 5.

木質系化粧板の防湿層として作用する紙質系シート4に使用される薄葉紙41、43としては、秤量25〜40g/m2の建材用プリント用紙、純白紙、あるいは合成樹脂を混抄させて層間強度を強化させた薄葉紙(いわゆる強化プリント紙)等が使用され、25〜35g/m2の厚さのものが好適であり、ラミネートするもう一枚の薄葉紙とは、もちろん同種でも異種でもよい。 The thin papers 41 and 43 used for the paper-based sheet 4 acting as a moisture-proof layer of the wood-based decorative board are interlayer paper strengths by mixing a printed paper for building materials having a weight of 25 to 40 g / m 2 , pure white paper, or synthetic resin. A thin paper (so-called reinforced printing paper) reinforced with a thickness of 25 to 35 g / m 2 is suitable. Of course, the other thin paper to be laminated may be the same or different.

紙質系シート4を構成する2枚の薄葉紙41、43を接着するための熱可塑性合成樹脂層42は、結果として木質系基材が反らない程度の耐水性を備えていればよく、水溶性樹脂以外は原則的に使用可能である。好ましい例としてポリエチレン、ポリプロピレン、エチレン−酢酸ビニル共重合体等のポリオレフィン系樹脂が挙げられる。熱可塑性合成樹脂層42の厚みとしては、1〜50μm程度である。   The thermoplastic synthetic resin layer 42 for bonding the two thin papers 41 and 43 constituting the paper-based sheet 4 only needs to have water resistance so that the wood-based base material does not warp as a result. Other than resin, it can be used in principle. Preferable examples include polyolefin resins such as polyethylene, polypropylene, and ethylene-vinyl acetate copolymer. The thickness of the thermoplastic synthetic resin layer 42 is about 1 to 50 μm.

紙質系シート4を作るには、薄葉紙41、43と熱可塑性合成樹脂42のフイルムを接着剤を使うか、あるいは使わずに熱などで貼合せる方法、2枚の薄葉紙41、43にエクストルージョンラミネート法により熱可塑性合成樹脂42の層を溶融押出しと同時にラミネートする方法があり、貼合せ方法は熱可塑性合成樹脂42の種類によって適したものを選択する。本発明のように、薄葉紙41、熱可塑性合成樹脂42および薄葉紙43の3つの層にするときには、エクストルージョンラミネート法により一度に3つの層を貼合せると、工程が少なくて済み、更に、本発明のように、ポリエチレン、ポリプロピレンおよびエチレン−酢酸ビニル共重合体等のポリオレフィン系樹脂を熱可塑性合成樹脂として使用するときには、エクストルージョンラミネート法により熱可塑性合成樹脂を溶融押出しと同時にラミネートする方法が適した方法である。   To make a paper-based sheet 4, a method of laminating thin paper 41, 43 and a thermoplastic synthetic resin 42 with adhesive or using heat without using an adhesive, extrusion lamination to two thin papers 41, 43 There is a method of laminating a layer of the thermoplastic synthetic resin 42 by melt extrusion at the same time, and a laminating method is selected according to the kind of the thermoplastic synthetic resin 42. When the three layers of the thin paper 41, the thermoplastic synthetic resin 42 and the thin paper 43 are formed as in the present invention, the number of steps can be reduced by laminating the three layers at once by the extrusion laminating method. When using polyolefin-based resins such as polyethylene, polypropylene and ethylene-vinyl acetate copolymer as thermoplastic synthetic resins, the method of laminating the thermoplastic synthetic resin simultaneously with melt extrusion by the extrusion laminating method is suitable. Is the method.

木質系基材3の代表的なものは合板であるが、水分が浸透して困るものであれば、同様の構造にすることにより問題が解消するから、ここでは、木質系基材3としては、そのようなものも一切含むものとし、合板以外に、例えば、木の皮、集成木材、パーチクルボード、MDF、ハードボードそのほかの各種ファイバーボードなどが挙げられる。   A typical example of the wood-based substrate 3 is plywood, but if it is difficult for moisture to permeate, the problem is solved by adopting a similar structure. In addition to plywood, examples include wood bark, laminated timber, particle board, MDF, hard board, and other various fiber boards.

紙質系シート4と木質系基材3の貼付けには一般的な接着剤、例えば、酢酸ビニル樹脂系、エチレン/ビニルアセテート樹脂系、尿素樹脂系、ウレタン樹脂系等のエマルジョン型接着剤が火気に対して安全で、臭気もなく価格的にも安価なため好ましく用いられる。 Common adhesives such as vinyl acetate resin, ethylene / vinyl acetate resin, urea resin, urethane resin, etc., are used for affixing the paper-based sheet 4 and the wood-based substrate 3 to the fire. It is preferably used because it is safe, odorless and inexpensive.

このような3層構造のものを用いることにより、木質系基材3における裏面層への水分の吸放出が芯層の熱可塑性合成樹脂層42によって防止されると共に、熱可塑性合成樹脂層42の表裏面に薄葉紙41、43が存在することで木質系基材3裏面への接着剤による接着強度が良好となるため、一般的なラミネータ装置により簡単に貼着することが出来る。又、施工下地への接着剤塗布により十分に下地面との接着強度を得ることができる。   By using such a three-layer structure, moisture absorption / release to the back surface layer of the woody base material 3 is prevented by the thermoplastic synthetic resin layer 42 of the core layer, and the thermoplastic synthetic resin layer 42 Since the thin papers 41 and 43 are present on the front and back surfaces, the adhesive strength of the adhesive to the back surface of the wood-based substrate 3 is improved, so that it can be easily attached with a general laminator device. Moreover, sufficient adhesive strength with the ground surface can be obtained by applying the adhesive to the ground surface.

上記の如く、本発明では、防湿層として作用する紙質系シートの両表面が薄葉紙で構成されているので、木質系基材又は施工面との接着に、安価で、安全なエマルジョン型接着剤を用いて容易に積層することが出来る。   As described above, in the present invention, since both surfaces of the paper-based sheet that acts as a moisture-proof layer are composed of thin paper, an inexpensive and safe emulsion-type adhesive is used for bonding to a wooden substrate or construction surface. And can be easily stacked.

本発明の実施例を以下説明する。   Examples of the present invention will be described below.

〔実施例1〕
秤量30g/m2の紙間強化紙にTダイ押出機から20μmの厚さにポリエチレンフイルムを押出しコーティングし、同時にもう一枚の薄葉紙、秤量30g/m2の紙間強化紙をラミネートし、チルロールで冷却して薄葉紙2層よりなる紙質系シートを調製した。次いで、2.0mm厚みの合板に厚み80μmの塩化ビニル化粧シートを酢酸ビニル系接着剤を接着剤塗布量80g/m2で貼合せた化粧合板を用意した。次いで、前記化粧合板の裏面に上記で得られた紙質系シートをエマルジョン型酢酸ビニル系接着剤を用いて貼合せ防湿層を有する化粧合板を得た。次いで上記防湿層を有する化粧合板を温度25℃、湿度70%の雰囲気中にて1週間放置して取り出して見たが、何ら異常は認められなかった。
[Example 1]
A polyethylene film is extruded and coated to a thickness of 20 μm from a T-die extruder on a 30 g / m 2 inter-paper reinforced paper, and another sheet of paper and a 30 g / m 2 inter-paper reinforced paper are laminated at the same time, and a chill roll Was cooled to prepare a paper-based sheet comprising two layers of thin paper. Next, a decorative plywood was prepared by bonding a vinyl chloride adhesive sheet with a vinyl chloride adhesive at an adhesive application amount of 80 g / m 2 to a 2.0 mm thick plywood. Next, a decorative plywood having a moisture-proof layer was obtained by laminating the paper-based sheet obtained above on the back surface of the decorative plywood using an emulsion-type vinyl acetate adhesive. Next, the decorative plywood having the above moisture-proof layer was left to stand for one week in an atmosphere at a temperature of 25 ° C. and a humidity of 70%, and no abnormality was found.

〔比較例1〕
上記実施例において塩化ビニル化粧シートを貼合せた化粧合板に裏面に紙質系基材を貼付けせずに実施例と同様に温度25℃、湿度70%の雰囲気中にて1週間放置して取り出して見た所、30mm以上の凸反りを発生し、実用不能の化粧合板になった。
[Comparative Example 1]
In the above example, without attaching a paper-based base material to the back surface of the decorative plywood laminated with the vinyl chloride decorative sheet, the sample was left to stand for 1 week in an atmosphere at a temperature of 25 ° C. and a humidity of 70%. Apparently, a convex warp of 30 mm or more occurred, and it became an impractical decorative plywood.

本発明の化粧板の積層構成を示す断面図である。It is sectional drawing which shows the laminated structure of the decorative board of this invention. 従来品の斜視図である。It is a perspective view of a conventional product.

符号の説明Explanation of symbols

1 化粧板
2 化粧シート
3 木質系基材
4 紙質系シート
41、43 薄葉紙
42 熱可塑性合成樹脂層
5 接着剤層
DESCRIPTION OF SYMBOLS 1 Decorative board 2 Decorative sheet 3 Woody base material 4 Paper-based sheet 41, 43 Thin paper 42 Thermoplastic synthetic resin layer 5 Adhesive layer

Claims (2)

木質系基材の一方の面に化粧シートを積層し、他方の面に、2枚の秤量25〜40g/m2の薄葉紙を熱可塑性合成樹脂の押出しコート層を介して接着してなる紙質系シートが積層されていることを特徴とする化粧板。 A paper-based system in which a decorative sheet is laminated on one surface of a wood-based substrate, and two thin papers weighing 25 to 40 g / m 2 are bonded to the other surface via an extruded coating layer of a thermoplastic synthetic resin. A decorative board in which sheets are laminated. 前記熱可塑性合成樹脂の押出しコート層がポリオレフィン系樹脂であることを特徴とする請求項1記載の化粧板。
The decorative board according to claim 1, wherein the extrusion coating layer of the thermoplastic synthetic resin is a polyolefin resin.
JP2005017646A 2005-01-26 2005-01-26 Decorative laminate Pending JP2005145077A (en)

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JP2005017646A JP2005145077A (en) 2005-01-26 2005-01-26 Decorative laminate

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JP2005017646A JP2005145077A (en) 2005-01-26 2005-01-26 Decorative laminate

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP7206644A Division JPH0929919A (en) 1995-07-20 1995-07-20 Decorative panel

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5731571A (en) * 1980-08-05 1982-02-20 Dainippon Printing Co Ltd Decorative material
JPH01118541U (en) * 1988-02-05 1989-08-10
JPH03118634U (en) * 1990-03-22 1991-12-06
JPH06280376A (en) * 1993-03-26 1994-10-04 Noda Corp Building plate
JPH07232305A (en) * 1993-12-28 1995-09-05 Mitsui Mokuzai Kogyo Kk Moisture-resistant composite plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5731571A (en) * 1980-08-05 1982-02-20 Dainippon Printing Co Ltd Decorative material
JPH01118541U (en) * 1988-02-05 1989-08-10
JPH03118634U (en) * 1990-03-22 1991-12-06
JPH06280376A (en) * 1993-03-26 1994-10-04 Noda Corp Building plate
JPH07232305A (en) * 1993-12-28 1995-09-05 Mitsui Mokuzai Kogyo Kk Moisture-resistant composite plate

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