JP2005132786A - Oily dispersion of powder surface-treated with specific acidic ester oil, and cosmetic composition containing the same - Google Patents
Oily dispersion of powder surface-treated with specific acidic ester oil, and cosmetic composition containing the same Download PDFInfo
- Publication number
- JP2005132786A JP2005132786A JP2003372033A JP2003372033A JP2005132786A JP 2005132786 A JP2005132786 A JP 2005132786A JP 2003372033 A JP2003372033 A JP 2003372033A JP 2003372033 A JP2003372033 A JP 2003372033A JP 2005132786 A JP2005132786 A JP 2005132786A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- oil
- powder
- dispersion
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 142
- 239000006185 dispersion Substances 0.000 title claims abstract description 108
- 239000010696 ester oil Substances 0.000 title claims abstract description 79
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 71
- 239000002537 cosmetic Substances 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title description 32
- -1 ester compound Chemical class 0.000 claims abstract description 73
- 239000002253 acid Substances 0.000 claims abstract description 63
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002904 solvent Substances 0.000 claims abstract description 32
- 239000003921 oil Substances 0.000 claims description 35
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 150000001721 carbon Chemical class 0.000 claims description 9
- 239000002612 dispersion medium Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000002723 alicyclic group Chemical group 0.000 claims description 4
- 150000001261 hydroxy acids Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- 239000002245 particle Substances 0.000 abstract description 23
- 238000003860 storage Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 description 38
- 235000014113 dietary fatty acids Nutrition 0.000 description 34
- 239000000194 fatty acid Substances 0.000 description 34
- 229930195729 fatty acid Natural products 0.000 description 34
- 235000019198 oils Nutrition 0.000 description 31
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- 230000015572 biosynthetic process Effects 0.000 description 25
- 238000004519 manufacturing process Methods 0.000 description 25
- 238000003786 synthesis reaction Methods 0.000 description 25
- 150000002148 esters Chemical class 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 23
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 20
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 18
- 238000004381 surface treatment Methods 0.000 description 18
- 239000010419 fine particle Substances 0.000 description 17
- 239000000049 pigment Substances 0.000 description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 16
- 239000004533 oil dispersion Substances 0.000 description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 16
- 239000000539 dimer Substances 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 13
- 229910052719 titanium Inorganic materials 0.000 description 13
- 239000010936 titanium Substances 0.000 description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 230000008859 change Effects 0.000 description 11
- 239000010445 mica Substances 0.000 description 11
- 229910052618 mica group Inorganic materials 0.000 description 11
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 10
- 239000006071 cream Substances 0.000 description 10
- 239000006210 lotion Substances 0.000 description 10
- 239000011787 zinc oxide Substances 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 239000004166 Lanolin Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
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- 239000007788 liquid Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 8
- 239000010410 layer Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- 238000007796 conventional method Methods 0.000 description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 7
- 238000004898 kneading Methods 0.000 description 7
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 6
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
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- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 5
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- 230000000475 sunscreen effect Effects 0.000 description 5
- 239000000516 sunscreening agent Substances 0.000 description 5
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 5
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 229920001202 Inulin Polymers 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 4
- PWATWSYOIIXYMA-UHFFFAOYSA-N Pentylbenzene Chemical compound CCCCCC1=CC=CC=C1 PWATWSYOIIXYMA-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229940024606 amino acid Drugs 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
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- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
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- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
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- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
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- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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Landscapes
- Cosmetics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
本発明は粉体粒子の分散性、分散安定性、貯蔵安定性、使用適性に非常に優れた粉体の新規油性分散体に関するものである。より詳しくは、特定の酸性エステル化合物を含む酸性エステル油により被覆された表面処理粉体とその分散媒として親油性溶媒とを少なくとも含有することを特徴とする粉体の油性分散体、及びこれらを配合した化粧料組成物に関するものである。これら表面処理粉体の油性分散体を使用すると化粧料の製造工程が大幅に省力化でき、またこれらを配合した化粧料は使用感や化粧持ち、製品の経時安定性を大きく向上させる事が出来る。また、この油性分散体は分散安定性が非常に優れているため化粧料のみならずプラスチックの添加剤、インク、塗料、トナー、電子材料等の分野で使用される粉体にも応用できる。 The present invention relates to a novel oily dispersion of powder that is extremely excellent in dispersibility, dispersion stability, storage stability and suitability for use of powder particles. More specifically, an oily dispersion of powder characterized by containing at least a surface-treated powder coated with an acidic ester oil containing a specific acidic ester compound and a lipophilic solvent as a dispersion medium thereof, and The present invention relates to a blended cosmetic composition. When these oil dispersions of surface-treated powders are used, the manufacturing process of cosmetics can be greatly labor-saving, and the cosmetics containing these can greatly improve the feeling of use, makeup, and product stability over time. . Further, since this oil dispersion has very excellent dispersion stability, it can be applied not only to cosmetics but also to powders used in the fields of plastic additives, inks, paints, toners, electronic materials and the like.
近年、粉体を取り扱う産業界では中間材料として粉体を何等かの分散媒に分散安定化させた分散体の必要性が高まっている(例えば、本出願人による特許文献1参照)。その理由としては、作業所内で粉体が飛散し作業者が吸入することによる呼吸障害の可能性があること、作業所周辺の環境保全のため、粉体は微粒子になる程容積が大きくなるため保管スペースをとること、粉体の分散には分散機の選定や分散条件等の技術的な問題が多々あり手間がかかること、更には、安定な粉体の分散体を使用することで作業の効率化が可能なこと、等が挙げられる。 In recent years, there has been an increasing need for a dispersion in which powder is dispersed and stabilized in some dispersion medium as an intermediate material in the industry handling powder (see, for example, Patent Document 1 by the present applicant). The reason for this is that there is a possibility of breathing disturbance due to the scattering of powder in the work place and the worker's inhalation, and the volume of powder becomes larger as the powder becomes finer in order to preserve the environment around the work place. There are many technical problems such as selection of a disperser and dispersion conditions for dispersion of powder, and it takes time and effort, and furthermore, using a stable dispersion of powder It is possible to improve efficiency.
一方、粉体を油性分散体にした場合の欠点としては、粉体の分散安定性が悪く、粉体の沈降や凝集が発生した分散体は、使用時に再分散をしなければならい事が一つの問題である。粉体を油性分散体とする目的は粉体をそのまま原料として取り扱うときの種々の欠点(作業者の粉塵吸入、粉塵回収装置の設置による設備投資、分散の手間、粉体による保管スペース増等)を改善し、粉体の機能を最大限に発揮させるためである。そのために好適な粉体構成或いは分散媒の選択が求められる。油性分散体中の粉体含有量はできるだけ高い程、かつ油性分散体の組成もできるだけ単純な配合(1種類の粉体と1種類の媒体)であることが好ましい。その理由としては、分散体の分散媒の量が多いと処方設計上の自由度が少なくなり、また他の処方への汎用性も悪くなるためである。 On the other hand, when the powder is made into an oily dispersion, the dispersion stability of the powder is poor, and the dispersion in which the powder has settled or agglomerated must be redispersed during use. There are two problems. The purpose of making the powder an oil-based dispersion is the various disadvantages when handling the powder as raw materials as they are (the worker's dust inhalation, capital investment due to the installation of a dust collection device, dispersion effort, increase in storage space due to the powder, etc.) This is to improve the powder and maximize the function of the powder. Therefore, selection of a suitable powder structure or dispersion medium is required. The powder content in the oil dispersion is preferably as high as possible, and the composition of the oil dispersion is preferably as simple as possible (one kind of powder and one kind of medium). The reason is that if the amount of the dispersion medium in the dispersion is large, the degree of freedom in formulation design is reduced, and the versatility to other formulations is also deteriorated.
また、ナノテクノロジーの進歩によりサブミクロン以下の一次粒子径を有する微粒子酸化チタンや微粒子酸化亜鉛等の無機粉体または有機色素は表面処理技術や粉砕または分散の技術の向上により粉末粒子の凝集を少なくすることが可能であるが粉末の嵩は高くなり重量あたりの容積をとるため保管スペースを多く必要とする。また、粉末粒子の再凝集が起こり易く飛散性も高くなり作業性が著しく悪く、粒子の分散と分散安定化が非常に難しいのが現状である。微粒子の分散が不十分であると処方へ配合したとき目的とする紫外線や赤外線の遮蔽効果や色調等が充分に得られないことが多い。また、最近では無機粉体の化粧料への配合量をできるだけ減らして機能を引き出し塗布時または塗布後の粉感軽減を目的とする傾向も有り微粒子粉体のさらなる高分散化とその安定化が望まれている。このため、微粒子粉体を溶媒に分散させた種々の油性分散体とその製法が公開されている。例えば、無機紫外線フィルターが液状紫外線フィルター中に分散されている分散液(例えば、特許文献2参照)や、エステル油をベースとする顔料分散体(例えば、特許文献3参照)が提案されている。さらに、脂肪酸処理された微粒子粉体とアミノ変性シリコーンとシリコーン系分散媒とを含有する分散物(例えば、特許文献4参照)や、口紅用顔料分散液の製造方法とその組成物(例えば、特許文献5参照)が提案されている。しかしながらこれらの分散組成物は高分散と分散安定性を達成するためには分散剤を必須成分として含有する。また、上記特許文献1において、本出願人は分散剤や界面活性剤フリーで処方への汎用が高く、高分散かつ分散安定性の優れた油性分散体を提案したが、この油性分散体はシリコーン系の溶媒以外では粉体の分散性や分散安定性に於いて若干の課題を有している。これらの理由により油性分散体の更なる改良が望まれている。 In addition, with the advancement of nanotechnology, inorganic powders or organic dyes such as fine particle titanium oxide and fine particle zinc oxide having a primary particle size of sub-micron or less reduce powder particle aggregation by improving surface treatment technology and grinding or dispersion technology. However, the bulk of the powder becomes high and requires a lot of storage space to take up the volume per weight. In addition, re-aggregation of powder particles is likely to occur, the scattering property is increased, workability is remarkably deteriorated, and dispersion and stabilization of particles are very difficult at present. When the dispersion of the fine particles is insufficient, the target ultraviolet ray or infrared ray shielding effect and color tone are often not sufficiently obtained when blended into the formulation. Recently, there is a tendency to reduce the blending amount of inorganic powders in cosmetics as much as possible and to reduce the feeling of powder at the time of application or after application. It is desired. For this reason, various oil dispersions in which fine particle powder is dispersed in a solvent and methods for producing the same are disclosed. For example, a dispersion liquid in which an inorganic ultraviolet filter is dispersed in a liquid ultraviolet filter (for example, see Patent Document 2) and a pigment dispersion based on ester oil (for example, see Patent Document 3) have been proposed. Further, a dispersion containing fatty acid-treated fine particle powder, an amino-modified silicone and a silicone-based dispersion medium (see, for example, Patent Document 4), a lipstick pigment dispersion, and a composition thereof (for example, a patent) Document 5) has been proposed. However, these dispersion compositions contain a dispersant as an essential component in order to achieve high dispersion and dispersion stability. Further, in the above-mentioned Patent Document 1, the present applicant has proposed an oil-based dispersion that is free of dispersants and surfactants and is widely used for formulation, and has high dispersion and excellent dispersion stability. This oil-based dispersion is silicone. Other than the solvent of the system, there are some problems in the dispersibility and dispersion stability of the powder. For these reasons, further improvements in oily dispersions are desired.
本発明は、上記種々の問題点を解決し、粉体粒子の分散性、分散安定性、貯蔵安定性、使用適性に優れた分散体を提供することを課題とする。また、本発明の別の課題は、このような優れた分散体を配合することで従来品より優れた粉体の機能を有する化粧料等を提供することにある。 An object of the present invention is to solve the above-mentioned various problems and to provide a dispersion having excellent dispersibility, dispersion stability, storage stability and suitability for use of powder particles. Another object of the present invention is to provide a cosmetic or the like having a powder function superior to conventional products by blending such an excellent dispersion.
そこで本発明者らは、上記問題点を解決するために鋭意研究した結果、特定のエステル油で被覆した表面処理粉体とその分散媒として親油性溶媒とを少なくとも含有する油性分散体が粉体粒子の分散性、分散安定性、貯蔵安定性、及び使用適性に非常に優れ、さらにこれらを配合した化粧料は粉体の機能を最大限引き出すことが可能で製造時の作業性や剤型の経時安定性をも大きく向上させることができることを見出し、本発明を完成した。 Therefore, as a result of intensive studies to solve the above problems, the present inventors have found that an oily dispersion containing at least a surface-treated powder coated with a specific ester oil and a lipophilic solvent as a dispersion medium is a powder. It has excellent particle dispersibility, dispersion stability, storage stability, and suitability for use. Furthermore, cosmetics containing these materials can maximize the functions of the powder, making it possible to improve the workability and dosage form during production. It was found that the stability over time can be greatly improved, and the present invention has been completed.
すなわち、本発明は、酸性エステル油で被覆された表面処理粉体と親油性溶媒との油性分散体であって、前記酸性エステル油が炭素数1〜36の少なくとも1種のアルコールと炭素数1〜36の少なくとも1種のカルボン酸とを反応させて得ることができる総炭素数16以上のエステル化合物を含み、前記酸性エステル油の酸価が15以上であることを特徴とする表面処理粉体の油性分散体を提供する。 That is, the present invention is an oily dispersion of a surface-treated powder coated with an acidic ester oil and a lipophilic solvent, wherein the acidic ester oil has at least one alcohol having 1 to 36 carbon atoms and 1 carbon atom. A surface-treated powder comprising an ester compound having a total carbon number of 16 or more which can be obtained by reacting with at least one carboxylic acid of ~ 36, and wherein the acid value of the acidic ester oil is 15 or more An oily dispersion of is provided.
本発明の好ましい実施形態において、前記酸性エステルのアルコールが、直鎖状炭素、分岐状炭素、飽和炭素、不飽和炭素、脂環式炭素、及び芳香環からなる群より選択される少なくとも1種の炭素鎖を有する1価又は多価アルコールであり、前記酸性エステルのカルボン酸が、直鎖状炭素、分岐状炭素、飽和炭素、不飽和炭素、脂環式炭素、及び芳香環からなる群より選択される少なくとも1種の炭素鎖を有する一塩基酸若しくは多塩基酸、又はそのヒドロキシ酸であることを特徴とする。 In a preferred embodiment of the present invention, the alcohol of the acidic ester is at least one selected from the group consisting of linear carbon, branched carbon, saturated carbon, unsaturated carbon, alicyclic carbon, and aromatic ring. A monovalent or polyhydric alcohol having a carbon chain, wherein the carboxylic acid of the acidic ester is selected from the group consisting of linear carbon, branched carbon, saturated carbon, unsaturated carbon, alicyclic carbon, and aromatic ring It is a monobasic acid or polybasic acid having at least one carbon chain, or a hydroxy acid thereof.
本発明の更に好ましい実施形態において、前記酸性エステル油の酸価が15以上100以下であり、被覆処理される粉体と前記表面処理剤の重量比が100対0.1〜50.0であることを特徴とする。また、前記油性分散体中における前記被覆粉体の含有量が0.1〜95重量%であることが好ましい。 In a further preferred embodiment of the present invention, the acid value of the acidic ester oil is 15 or more and 100 or less, and the weight ratio of the powder to be coated and the surface treatment agent is 100 to 0.1 to 50.0. It is characterized by that. Moreover, it is preferable that content of the said coating powder in the said oil-based dispersion is 0.1 to 95 weight%.
本発明の異なる視点において、上記油性分散体を0.1〜100重量%含むことを特徴とする化粧料が提供される。 In a different aspect of the present invention, there is provided a cosmetic comprising 0.1 to 100% by weight of the above oil dispersion.
本発明の油性分散体は、特定の酸性エステル化合物を含む酸性エステル油により被覆された粉体を含むことにより、粉体粒子の分散性、分散安定性、貯蔵安定性、及び使用適性に非常に優れた性質を示す。これら油性分散体を配合した化粧料は使用感や化粧持ちに優れるとともに製品の経時安定性を大きく向上させる事が出来る。 The oil-based dispersion of the present invention includes a powder coated with an acidic ester oil containing a specific acidic ester compound, thereby greatly improving the dispersibility, dispersion stability, storage stability, and suitability for use of powder particles. Excellent properties. Cosmetics containing these oil-based dispersions are excellent in feeling of use and long-lasting makeup, and can greatly improve the aging stability of the product.
以下本発明の構成について詳述する。本発明で粉体に被覆される酸性エステル油は、炭素数1〜36のアルコールと炭素数1〜36のカルボン酸とを部分エステル化して得られる総炭素数16以上のエステル化合物を含み且つ酸価15以上の酸性エステル油である。 Hereinafter, the configuration of the present invention will be described in detail. The acidic ester oil coated on the powder in the present invention contains an ester compound having a total carbon number of 16 or more obtained by partial esterification of an alcohol having 1 to 36 carbon atoms and a carboxylic acid having 1 to 36 carbon atoms. Acid ester oil having a value of 15 or more.
本発明に用いる炭素数1〜36のアルコールとしては、一価の直鎖アルコールとしてはメタノール、エタノール、プロパノール、ブタノール、ペンタノール、ヘキサノール、ヘプタノール、オクタノール、ノナノール、デカノール、ウンデカノール、ドデカノール(ラウリルアルコール)、トリデカノール、テトラデカノール(ミリスチルアルコール)、ペンタデカノール、ヘキサデカノール(セチルアルコール)、ヘプタデカノール、オクタデカノール(ステアリルアルコール)、ノナデカノール、エイコサノール(アラキルアルコール)、ドコサノール(ベヘニルアルコール)、テトラコサノール、セトステアリルアルコール等がある。一価の分岐アルコールとしては、イソプロピルアルコール、イソブチルアルコール、イソペンチルアルコール、イソヘキサノール、イソヘプタノール、イソオクタノール、ジメチルオクタノール、イソノナノール、イソデカノール、イソウンデカノール、イソドデカノール、イソトリデカノール、イソテトラデカノール、イソペンタデカノール、イソヘキサデカノール(ヘキシルデカノール)、イソヘプタデカノール、イソオクタデカノール(イソステアリルアルコール)、イソノナデカノール、イソエイコサノール(オクチルドデカノール)、2−エチルヘキサノール、2−ブチルオクタノール、2−ヘキシルデカノール、2−オクチルドデカノール、2−デシルテトラデカノール、2−ドデシルヘキサデカノール、2−テトラデシルオクタデカノール、2−ヘキサデシルオクタデカノール、等が挙げられる。一価の不飽和アルコールとしては、ウンデセノール、ラウロレノール、ミリストレノール、パルミトレノール、オレイルアルコール、エラジルアルコール、リノレイルアルコール、リノレニルアルコール、エルシルアルコール、ブラシジルアルコール、アラキジルアルコール、ホホバアルコール等が挙げられる。ステロールとしては、コレステロール、ジヒドロコレステロール、デスモステロール、ラノステロール、ジヒドロラノステロール、アグノステロール、ラトステロール、シトステロール、カンペステロール、スチグマステロール、ブラシカステロール、エルゴステロール、フィトステロール、ラノリンアルコール等がある。2価以上のアルコールとしては、エチレングリコール、プロピレングリコール、トリメチレングリコール、ブタンジオール、ペンタンジオール、ヘキサンジオール、ヘプタンジオール、オクタンジオール、ノナンジオール、デカンジオール、ピナコール、ヒドロベンゾイン、ベンズピナコール、シクロペンタン−1,2−ジオール、シクロヘキサン−1,2−ジオール、シクロヘキサン−1,4−ジオール、ダイマージオール、水添ダイマージオール、ネオペンチルグリコール、グリセリン、トリメチロールプロパン、トリメチロールプロパン縮合物、トリメチロールエタン、ペンタエリスリット、ペンタエリスリット縮合物、ソルビット、グリセリン縮合物、ポリエチレングリコール、ポリプロピレングロコール等が挙げられ、本発明ではこれらを単独、もしくは任意の組み合わせの混合物で使用してもさしつかえない。 The alcohol having 1 to 36 carbon atoms used in the present invention includes methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, undecanol, dodecanol (lauryl alcohol) as a monovalent linear alcohol. , Tridecanol, tetradecanol (myristyl alcohol), pentadecanol, hexadecanol (cetyl alcohol), heptadecanol, octadecanol (stearyl alcohol), nonadecanol, eicosanol (aralkyl alcohol), docosanol (behenyl alcohol), tetra Examples include cosanol and cetostearyl alcohol. Monovalent branched alcohols include isopropyl alcohol, isobutyl alcohol, isopentyl alcohol, isohexanol, isoheptanol, isooctanol, dimethyl octanol, isononanol, isodecanol, isoundecanol, isododecanol, isotridecanol, iso Tetradecanol, isopentadecanol, isohexadecanol (hexyldecanol), isoheptadecanol, isooctadecanol (isostearyl alcohol), isonononadecanol, isoeicosanol (octyldodecanol), 2-ethyl Hexanol, 2-butyloctanol, 2-hexyldecanol, 2-octyldodecanol, 2-decyltetradecanol, 2-dodecylhexadecanol, 2-tetradecyloctyl Decanol, 2-hexadecyl octadecanol, and the like. Monovalent unsaturated alcohols include undecenol, laurolenol, myristolol, palmitolenol, oleyl alcohol, elasyl alcohol, linoleyl alcohol, linolenyl alcohol, erucyl alcohol, brassyl alcohol, arachidyl alcohol, jojoba Alcohol etc. are mentioned. Examples of sterols include cholesterol, dihydrocholesterol, desmosterol, lanosterol, dihydrolanosterol, agnosterol, latosterol, sitosterol, campesterol, stigmasterol, brassicasterol, ergosterol, phytosterol, and lanolin alcohol. Examples of the dihydric or higher alcohol include ethylene glycol, propylene glycol, trimethylene glycol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, pinacol, hydrobenzoin, benzpinacol, cyclopentane- 1,2-diol, cyclohexane-1,2-diol, cyclohexane-1,4-diol, dimer diol, hydrogenated dimer diol, neopentyl glycol, glycerin, trimethylol propane, trimethylol propane condensate, trimethylol ethane, Pentaery slit, pentaerythrit condensate, sorbit, glycerin condensate, polyethylene glycol, polypropylene glycol, etc. No problem even when used in these alone or a mixture of any combination.
本発明に用いる炭素数1〜36のカルボン酸(n=1〜3)としては、飽和、不飽和、ヒドロキシ、芳香族等のいずれも用いる事ができる。例えば、一塩酸(n=1)として、ギ酸、酢酸、プロピオン酸、酪酸、カプロン酸、カプリル酸、カプリン酸、ウンデカン酸、ラウリン酸、トリデカン酸、ミリスチン酸、ペンタデカン酸、パルミチン酸、マルガリン酸、ステアリン酸、ノナデカン酸、アラキジン酸、ベヘン酸、セチロン酸、モンタン酸、メリシン酸等の直鎖脂肪酸、ウンデシレン酸、パルミトオレイン酸、オレイン酸、リノール酸、リノレン酸、アラキドン酸等の不飽和脂肪酸、イソオクチル酸(2−エチルヘキサン酸)、ネオトリデカン酸、イソミリスチン酸、イソパルミチン酸、イソステアリン酸等の分枝脂肪酸、12−ヒドロキシステアリン酸、リシノール酸等のヒドロキシ脂肪酸が挙げられる。多塩基酸(n=2〜3)として、シュウ酸、マロン酸、コハク酸、シクロブタン−1,1−ジカルボン酸、シクロヘキサン−1,2−ジカルボン酸、フェニレン−1,2−ジ酢酸、ジグリコール酸、ジチオグリコール酸、グルタル酸、アジピン酸、ピメリン酸、スベリン酸、アゼライン酸、セバシン酸、ウンデカンジオン酸、ドデカン二酸、エイコサン二酸、オクタコサン二酸、1−,10−デカメチレン二酸、1−,12−ドデカメチレン二酸、1−,15−ペンタデカメチレン二酸、1−,28−オクタコサメチレン二酸、7−エチルオクタデカン二酸、ダイマー酸、水添ダイマー酸等が挙げられる。本発明において「ダイマー酸」とは炭素数11〜22の不飽和脂肪酸の二量化により生成する二塩基酸のことをいう。不飽和二塩基酸としてはフマル酸、マレイン酸、イタコン酸等も挙げられる。ヒドロキシ多塩基酸としては、酒石酸、リンゴ酸、ムチン酸、クエン酸、等が挙げられる。更に、アミノ酸やアシル化されたアミノ酸を用いることもできる。本発明ではこれらを単独、もしくは任意の組み合わせの混合物で使用してもさしつかえない。 As the carboxylic acid having 1 to 36 carbon atoms (n = 1 to 3) used in the present invention, any of saturated, unsaturated, hydroxy, aromatic and the like can be used. For example, as monohydrochloric acid (n = 1), formic acid, acetic acid, propionic acid, butyric acid, caproic acid, caprylic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, Linear fatty acids such as stearic acid, nonadecanoic acid, arachidic acid, behenic acid, cetillonic acid, montanic acid, melicic acid, and unsaturated fatty acids such as undecylenic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid , Branched fatty acids such as isooctylic acid (2-ethylhexanoic acid), neotridecanoic acid, isomyristic acid, isopalmitic acid and isostearic acid, and hydroxy fatty acids such as 12-hydroxystearic acid and ricinoleic acid. As polybasic acids (n = 2 to 3), oxalic acid, malonic acid, succinic acid, cyclobutane-1,1-dicarboxylic acid, cyclohexane-1,2-dicarboxylic acid, phenylene-1,2-diacetic acid, diglycol Acid, dithioglycolic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, eicosanedioic acid, octacosanedioic acid, 1-, 10-decamethylenedioic acid, 1 -, 12-dodecamethylene diacid, 1-, 15-pentadecamethylene diacid, 1-, 28-octacosamethylene diacid, 7-ethyloctadecanedioic acid, dimer acid, hydrogenated dimer acid and the like can be mentioned. In the present invention, “dimer acid” refers to a dibasic acid produced by dimerization of an unsaturated fatty acid having 11 to 22 carbon atoms. Examples of the unsaturated dibasic acid include fumaric acid, maleic acid, itaconic acid and the like. Examples of hydroxypolybasic acids include tartaric acid, malic acid, mucinic acid, citric acid, and the like. Furthermore, amino acids and acylated amino acids can also be used. In the present invention, these may be used alone or in a mixture of any combination.
本発明に使用する酸性エステルは前記アルコールと前記カルボン酸の部分エステルでありエステル化反応によって合成が可能である。エステル化反応は、前記各原料を適当な反応容器に仕込み、酸、アルカリまたは金属触媒の存在下あるいは非存在下、好ましくは該反応に不活性な有機溶媒または/および気体中で150〜200℃にて数時間〜10時間程度まで、副生成する水を除去しながら行う。なお触媒を用いる場合には、反応重量に対し0.001〜1.0%加える。反応終了後、未反応物を含むことがあり、これらを水洗、アルカリ脱酸、シリカゲル等の吸着剤処理等公知の方法で分離除去し、さらに脱色、脱臭処理を施して精製する。このようにして得られる酸性エステル油は常温で液体状または固体状である。本発明で言う酸性エステル油は酸価15以上でかつ総炭素数が16以上のエステル化合物を含むことが好ましい。本発明の表面処理粉体の効果を得る上で、より好ましい酸性エステル油の酸価は15以上、100以下である。このときのエステル油の性状は処理した粉体の親油性溶媒への分散性を考慮すると、常温で液体状、半固体状又は可塑性を有する固体状であるものが好ましい。より好ましくは液体状又は半固体状のもので具体的には融点が70℃以下のものである。 The acidic ester used in the present invention is a partial ester of the alcohol and the carboxylic acid, and can be synthesized by an esterification reaction. In the esterification reaction, the respective raw materials are charged into a suitable reaction vessel, and in the presence or absence of an acid, alkali, or metal catalyst, preferably in an organic solvent or / and gas inert to the reaction, 150 to 200 ° C. For several hours to about 10 hours while removing by-product water. When a catalyst is used, 0.001 to 1.0% is added to the reaction weight. After completion of the reaction, unreacted substances may be contained, and these are separated and removed by a known method such as washing with water, alkaline deoxidation, adsorbent treatment such as silica gel, and further purified by decolorization and deodorization. The acidic ester oil thus obtained is liquid or solid at room temperature. The acidic ester oil referred to in the present invention preferably contains an ester compound having an acid value of 15 or more and a total carbon number of 16 or more. In obtaining the effect of the surface-treated powder of the present invention, the acid value of the acidic ester oil is more preferably 15 or more and 100 or less. The property of the ester oil at this time is preferably a liquid, semi-solid or plastic solid at room temperature in consideration of dispersibility of the treated powder in an oleophilic solvent. More preferably, it is in the form of a liquid or semi-solid, and specifically has a melting point of 70 ° C. or less.
エステル油の酸価が15未満であると粉体基材への吸着性が悪く酸性エステル油が表面処理されず親油性溶媒への分散性が悪い。また、エステル化合物の総炭素数が16未満であると分散安定化に劣り粉体粒子の沈降やハードケーキ化を引き起こしてしまう。なお、本発明の酸性エステル油の酸価は、当業者に公知の方法で測定することができ、例えば、「基準油脂分析試験方法」(日本油化学協会編)に従って測定することができる。 When the acid value of the ester oil is less than 15, the adsorptivity to the powder base material is poor, and the acidic ester oil is not surface-treated and the dispersibility in the lipophilic solvent is poor. Further, if the total number of carbon atoms in the ester compound is less than 16, the dispersion is inferior in stability and causes the powder particles to settle or hard cake. In addition, the acid value of the acidic ester oil of the present invention can be measured by a method known to those skilled in the art, and can be measured, for example, according to “Standard Oil Analysis Test Method” (edited by Japan Oil Chemical Association).
これら総炭素数16以上のエステル化合物を含む、酸価15以上の酸性エステル油の表面処理量は無機粉体基剤の種類やその比表面積により異なるが粉体100重量部に対して0.1〜50重量部である。好ましくは0.3〜35重量部である。これら表面処理するための酸性エステル油は2種以上を混合して被覆処理したものでも構わない。被覆量が0.1重量部より少ないと粉体粒子表面の均一な被覆層が得られず粉体粒子は親油性にならず親油性溶媒への分散性が悪い。50重量部より多いと粉体粒子を凝集させる傾向があり親油性溶媒への分散性や分散安定性は向上しないばかりかまた不経済である。 The surface treatment amount of an acidic ester oil having an acid value of 15 or more, which contains these ester compounds having a total carbon number of 16 or more varies depending on the type of inorganic powder base and its specific surface area, but is 0.1% with respect to 100 parts by weight of the powder. ~ 50 parts by weight. Preferably it is 0.3-35 weight part. These acidic ester oils for surface treatment may be those obtained by coating two or more kinds. When the coating amount is less than 0.1 part by weight, a uniform coating layer on the surface of the powder particles cannot be obtained, and the powder particles are not lipophilic and dispersible in the lipophilic solvent. When the amount is more than 50 parts by weight, the powder particles tend to agglomerate and the dispersibility and dispersion stability in the lipophilic solvent are not improved, and it is uneconomical.
また、三好化成株式会社より「MiBrid Dipersion」の名称ですでに上市されている基本技術を記載している公開公報である特開平2002−80748号記載のB層の表面処理剤としても好適である。A層の処理剤としては反応性オルガノポリシロキサン、アルキルシラン、ポリオレフィン、水添レシチン(塩の形態にあるものを含む。)、N−アシルアミノ酸(塩の形態にあるものを含む。)、脂肪酸(塩の形態にあるものを含む。)及びデキストリン脂肪酸エステル、イヌリン脂肪酸エステルの中から選択される化合物を含有する常温で固体状を有するものである。A層とB層の配合比はA層の処理量<B層の処理量(重量%)でかつA層の処理量は10重量%以下が好ましい。 Moreover, it is also suitable as a surface treatment agent for the B layer described in JP-A-2002-80748, which is an open gazette that describes a basic technology already marketed under the name of “MiBrid Dipersion” by Miyoshi Kasei Co., Ltd. . As the treating agent for the A layer, reactive organopolysiloxane, alkylsilane, polyolefin, hydrogenated lecithin (including those in the form of salts), N-acylamino acids (including those in the form of salts), fatty acids. (Including those in the form of salts) and a compound selected from dextrin fatty acid esters and inulin fatty acid esters and having a solid state at room temperature. The blending ratio of the A layer and the B layer is preferably the processing amount of the A layer <the processing amount (% by weight) of the B layer and the processing amount of the A layer is preferably 10% by weight or less.
さらに、本発明では前記酸性エステル油を粉体の分散剤としても使用できる。具体的には、酸性エステル油で表面処理された粉体と酸性エステル油、そして親油性溶媒との油性分散体、表面処理されていない粉体と酸性エステル油、そして親油性溶媒の配合組み合わせが可能である。 Further, in the present invention, the acidic ester oil can be used as a powder dispersant. Specifically, a combination of a powder surface-treated with acidic ester oil, an acidic ester oil, and an oleophilic solvent, an undispersed powder, an acidic ester oil, and a lipophilic solvent. Is possible.
本発明に用いられる粉体としては、化粧料のみならずプラスチックの添加剤、インキ、塗料、トナー、電子材料等の各分野で使用される粉体が使用可能である。その平均粒子径は、好ましくは3000μm〜0.001μm程度、より好ましくは200μm〜0.005μm程度、最も好ましくは100μm〜0.01μm程度である。また、これら粉体の粒子径の測定方法としては、光学顕微鏡や電子顕微鏡により観察で計測される平均値で求められる。真球状でない粒子に関しては長径、短径、厚み等の合計の平均値より求める事ができる。 As the powder used in the present invention, powders used in various fields such as plastic additives, inks, paints, toners, and electronic materials as well as cosmetics can be used. The average particle diameter is preferably about 3000 μm to 0.001 μm, more preferably about 200 μm to 0.005 μm, and most preferably about 100 μm to 0.01 μm. Moreover, as a measuring method of the particle diameter of these powder, it calculates | requires by the average value measured by observation with an optical microscope or an electron microscope. For particles that are not true spheres, they can be determined from the total average value of the major axis, minor axis, thickness, and the like.
例えば、無機粉体としては、マイカ、セリサイト、タルク、カオリン、合成マイカ、白雲母、金雲母、紅雲母、黒雲母、リチア雲母、炭酸カルシウム、炭酸マグネシウム、リン酸カルシウム、アルミナ、酸化マグネシウム、水酸化アルミニウム、硫酸バリウム、硫酸マグネシウム、ケイ酸、無水ケイ酸、ケイ酸マグネシウム、ケイ酸アルミニウム、ケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸ストロンチウム、炭化ケイ素、タングステン酸金属塩、アルミン酸マグネシウム、メタケイ酸アルミン酸マグネシウム、クロルヒドロキシアルミニウム、クレー、ベントナイト、ゼオライト、スメクタイト、ヒドロキシアパタイト、セラミックパウダー、窒化ホウ素、窒化ボロン、シリカ等の体質顔料が、複合化された特殊な体質顔料としては、三好化成株式会社より発売されているエクセルマイカ、エクセルパール、パウダーラヴィ、SXI−5、SXI−9等が、白色顔料としては、酸化チタン、酸化亜鉛、酸化セリウム等が、着色顔料としては、赤酸化鉄、黄酸化鉄、黒酸化鉄、酸化クロム、水酸化クロム、紺青、群青、無機青色系顔料、カーボンブラック、低次酸化チタン、マンゴバイオレット、コバルトバイオレット、タール色素をレーキ化したもの、天然色素をレーキ化したもの等が、光輝性顔料としては、オキシ塩化ビスマス、雲母チタン、魚鱗箔、合成マイカに酸化チタンを被覆した粉体、日本板硝子株式会社より「メタシャイン」なる商品名で発売されているシリカフレークに酸化チタンを被覆等した粉体、アルミナフレークに酸化スズと酸化チタンを被覆した粉体、アルミニウムフレークに酸化チタンを被覆した粉体、米国エッカート社より発売されているカッパーフレークにシリカを被覆した粉体、ブロンズフレークにシリカを被覆した粉体、アルミニウムフレークにシリカを被覆した粉体等が、平均粒子径0.1μm未満の微粒子粉体としては、微粒子酸化チタン、微粒子酸化亜鉛、微粒子酸化鉄、微粒子酸化セリウム等が、特殊な粒子形状を有するものとしては、バタフライ状硫酸バリウム、花びら状酸化亜鉛、長径が数mmもあるナイロン繊維、その他の粉体としては、三井物産株式会社より「ルミノーバシリーズ」なる商品名で発売されている発光粉体、アルミニウムパウダー、ステンレスパウダー、トルマリン粉末、琥珀パウダー等が挙げられる。 For example, inorganic powders include mica, sericite, talc, kaolin, synthetic mica, muscovite, phlogopite, saucite, biotite, lithia mica, calcium carbonate, magnesium carbonate, calcium phosphate, alumina, magnesium oxide, hydroxide Aluminum, barium sulfate, magnesium sulfate, silicic acid, anhydrous silicic acid, magnesium silicate, aluminum silicate, aluminum magnesium silicate, calcium silicate, barium silicate, strontium silicate, silicon carbide, metal tungstate, aluminate Extensive pigments such as magnesium, magnesium aluminate metasilicate, chlorohydroxyaluminum, clay, bentonite, zeolite, smectite, hydroxyapatite, ceramic powder, boron nitride, boron nitride and silica are combined. Examples of special extender pigments include Excel Mica, Excel Pearl, Powder Ravi, SXI-5, and SXI-9, which are sold by Miyoshi Kasei Co., Ltd., and white pigments such as titanium oxide, zinc oxide, and cerium oxide. However, as coloring pigments, red iron oxide, yellow iron oxide, black iron oxide, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, inorganic blue pigment, carbon black, low-order titanium oxide, mango violet, cobalt violet, tar The pigments raked and the natural pigments raked are brilliant pigments such as bismuth oxychloride, titanium mica, fish scale foil, synthetic mica powder coated with titanium oxide, from Nippon Sheet Glass Co., Ltd. Silica flakes sold under the trade name `` Metashine '' are coated with titanium oxide powder, etc., and alumina flakes are oxidized Powder coated with titanium oxide, powder coated with titanium oxide on aluminum flakes, powder coated with silica on copper flakes sold by Eckert, USA, powder coated with silica on bronze flakes, aluminum flakes As a fine particle powder having an average particle size of less than 0.1 μm, such as fine particle titanium oxide, fine particle zinc oxide, fine particle iron oxide, fine particle cerium oxide, etc. have a special particle shape. Is a butterfly-like barium sulfate, petal-like zinc oxide, nylon fibers with a long diameter of several millimeters, and other powders are luminescent powders sold under the product name “Luminova Series” from Mitsui & Co., Aluminum Examples include powder, stainless steel powder, tourmaline powder, and candy powder.
有機粉体としては、ウールパウダー、ポリアミドパウダー、ポリエステルパウダー、ポリエチレンパウダー、ポリプロピレンパウダー、ポリスチレンパウダー、ポリウレタンパウダー、ベンゾグアナミンパウダー、ポリメチルベンゾグアナミンパウダー、テトラフルオロエチレンパウダー、ポリメチルメタクリレートパウダー、セルロースパウダー、シルクパウダー、シリコーンパウダー、シリコーンゴムパウダー、スチレン・アクリル酸共重合体、ジビニルベンゼン・スチレン共重合体、ビニル樹脂、尿素樹脂、フェノール樹脂、フッ素樹脂、ケイ素樹脂、アクリル樹脂、メラミン樹脂、エポキシ樹脂、ポリカーボネート樹脂等の合成樹脂パウダー、微結晶繊維粉体、澱粉粉末、アシル化リジン粉末、長鎖アルキルリン酸金属塩粉末、金属石鹸粉末、CIピグメントイエロー、CIピグメントオレンジ等が挙げられる。タール色素としては赤色3号、赤色10号、赤色106号、赤色201号、赤色202号、赤色204号、赤色205号、赤色220号、赤色226号、赤色227号、赤色228号、赤色230号、赤色401号、赤色505号、黄色4号、黄色5号、黄色202号、黄色203号、黄色204号、黄色401号、青色1号、青色2号、青色201号、青色404号、緑色3号、緑色201号、緑色204号、緑色205号、橙色201号、橙色203号、橙色204号、橙色206号、橙色207号等;天然色素としては、カルミン、ラッカイン酸、カルサミン、ブラジリン、クロシン等の粉体が挙げられる。 Organic powders include wool powder, polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethyl methacrylate powder, cellulose powder, silk powder , Silicone powder, silicone rubber powder, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin Synthetic resin powder, microcrystalline fiber powder, starch powder, acylated lysine powder, long chain metal alkyl metal salt powder, metal鹸粉 the end, CI Pigment Yellow, CI Pigment Orange, and the like. As the tar pigment, red No. 3, red No. 10, red No. 106, red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 227, red No. 228, red 230 No., red 401, red 505, yellow 4, yellow 5, yellow 202, yellow 203, yellow 204, yellow 401, blue 1, blue 2, blue 201, blue 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc .; natural pigments include carmine, laccaic acid, calsamine, bradylin And powders such as crocin.
また、使用される粉体の形態としても前記複数の混合物、複合体、付着物等、通常化粧料に配合する形態を利用することができる。例えば、必要に応じてこれらの粉体を複合化またはドープ化したものを用いることができる。例としては、ベンガラ等の無機着色顔料を無水ケイ酸で被覆した粉体、ナイロンを白色顔料で被覆した粉体、体質顔料を微粒子白色顔料で被覆した粉体等が挙げられる。 Moreover, the form mix | blended with cosmetics normally, such as said several mixture, a composite_body | complex, a deposit | attachment, etc. can be utilized also as a form of the powder used. For example, a composite or dope of these powders can be used as necessary. Examples include powder coated with an inorganic coloring pigment such as Bengala with silicic anhydride, powder coated with nylon with white pigment, powder coated with extender pigment with fine white pigment, and the like.
本発明で、酸性エステル油を粉体に表面処理する方法としては、カルボン酸をフリー体のまま被覆しても良いしNa、K、並びにBa、Zn、Ca、Mg、Fe、Zr、Co、Al、Ti等の多価金属、アンモニウム、またはモノエタノールアミン、ジエタノールアミン、トリエタノールアミン、2−アミノ−2−メチル−プロパノール、2−アミノ−2−メチル−1,3−プロパンジオール、トリイソプロパノールアミン等の有機アルカノールアミンのオニウムの何れかで処理しても良い。ここでいう処理とはカルボン酸の水素原子を他の金属または有機基で置換した後または置換しながら表面処理することでありこれらに限定されるものではない。具体的には1.ヘンシルミキサーやスーパーミキサー等で酸性エステル油を混合後乾燥する乾式法、2.ニーダーやエクストルーダー等の練合機で混練後乾燥する方法、3.ボールミルやサンドグラインダー等のメカノケミカル型のミルで水や有機溶媒中に粉体を分散させ酸性エステル油を混合した後溶媒を除去して乾燥する方法、4.JETアトマイザーの様な高速気流中で粉体基剤と酸性エステル油を接触させて被覆する方法等がある。ここで言う表面処理方法とは、一般に粉体基剤の表面処理に適用出来る方法であれば良くこれらの方法に限定されるものではない。 In the present invention, as a method for surface-treating the acidic ester oil to the powder, the carboxylic acid may be coated in a free form, or Na, K, and Ba, Zn, Ca, Mg, Fe, Zr, Co, Polyvalent metals such as Al and Ti, ammonium, or monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-propanol, 2-amino-2-methyl-1,3-propanediol, triisopropanolamine Or any of the organic alkanolamine oniums. The term “treatment” as used herein refers to surface treatment after or after substitution of a hydrogen atom of a carboxylic acid with another metal or organic group, and is not limited thereto. Specifically, 1. A dry method in which acidic ester oil is mixed with a Hensyl mixer or a super mixer and then dried. 2. A method of kneading and drying with a kneader such as a kneader or an extruder. 3. A method of dispersing powder in water or an organic solvent using a mechanochemical type mill such as a ball mill or a sand grinder, mixing acidic ester oil, and then removing the solvent and drying. There is a method in which a powder base and acidic ester oil are brought into contact with each other in a high-speed air current such as a JET atomizer. The surface treatment method referred to here is not limited to these methods as long as it is generally applicable to the surface treatment of a powder base.
表面処理される粉体基剤は表面処理剤との親和性や固着性の向上をはかるべく、例えばアルミニウム、カルシウム、マグネシウム、セリウム、ケイ素、ジルコニウム、チタン、亜鉛、鉄、コバルト、マンガン、ニッケルおよびスズの少なくとも1種の酸化物または含水酸化物で被覆されていても構わない。さらにこれら粉体基材は表面処理の相乗効果をはかるべくあらかじめシリコーン化合物による表面処理、アシル化アミノ酸による表面処理、脂肪酸による表面処理、フッ素化合物による表面処理、レシチンによる表面処理、ポリエチレンによる表面処理、アルキルシランによる表面処理、アルキルチタネートによる表面処理、セラミドによる表面処理、デキストリン脂肪酸エステル、イヌリン脂肪酸エステルによる表面処理等の公知の表面処理剤で処理された粉体でも構わない。 The surface of the powder base to be surface treated is improved in compatibility with the surface treatment agent and adhesion, for example, aluminum, calcium, magnesium, cerium, silicon, zirconium, titanium, zinc, iron, cobalt, manganese, nickel and It may be coated with at least one oxide or hydrated oxide of tin. In addition, these powder base materials are pretreated with a silicone compound, surface treatment with an acylated amino acid, surface treatment with a fatty acid, surface treatment with a fluorine compound, surface treatment with lecithin, surface treatment with polyethylene, It may be a powder treated with a known surface treatment agent such as a surface treatment with alkylsilane, a surface treatment with alkyl titanate, a surface treatment with ceramide, a surface treatment with dextrin fatty acid ester or inulin fatty acid ester.
本発明において油性分散体の分散媒としては、親油性のものであればよく、常温で液体状でも固体状でもよい。各種化粧料に使用可能な溶媒を使用するのが好ましい。具体的には、メタノール、エタノール、プロピルアルコール、イソプロピルアルコール、ブタノール、アミルアルコール、ヘキシルアルコール、ヘプチルアルコール、オクチルアルコール、カプリルアルコール、ノニルアルコール、デシルアルコール、フェノール、ベンジルアルコール等の一価アルコール系溶剤類、ノルマルペンタン、ノルマルヘキサン、ノルマルヘプタン、ノルマルオクタン、イソヘキサン、イソオクタン、ガソリン、ミネラルスピリット等の石油系炭化水素類、ベンゼン、トルエン、キシレン、シクロヘキサン、エチルベンゼン、アミルベンゼン等の芳香属炭化水素系溶剤類、ジペンテン、テレビン油等の植物系炭化水素系溶剤類、ニトロパラフィン、ニトロベンゼン等のニトロ炭化水素系溶剤類、アセトン、メチルエチルケトン、メチルイソブチルケトン、エチルブチルケトン、ジイソブチルケトン等のケトン系溶剤類、塩化メチレン、クロロホルム、四塩化炭素、パークロルエチレン、モノクロルベンゼン等のハロゲン化炭化水素系溶剤類、エチルエーテル、イソプロピルエーテル、ブチルエーテル、ヘキシルエーテル、プロピレンオキシド、エチレングリコールモノメチルエーテル、エチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル等のエーテル系溶剤類、ぎ酸メチル、ぎ酸エチル、ぎ酸ブチル、酢酸メチル、酢酸エチル、酢酸ブチル、酢酸アミル、プロピオン酸エチル、プロピオン酸ブチル、プロピオン酸イソブチル、酪酸エチル、酪酸ブチル、乳酸メチル、乳酸エチル、乳酸ブチル、乳酸アミル等のエステル系溶剤類、サフラワー油、大豆油、月見草油、ブドウ種子油、ローズヒップ油、ククイナッツ油、アルモンド油、ゴマ油、コムギ胚芽油、トウモロコシ油、綿実油、アボガド油、オリーブ油、ツバキ油、パーシック油、ヒマシ油、ラッカセイ油、ヘーゼルナッツ油、マカデミアナッツ油、メドフォーム油、カカオ脂、シア脂、木ロウ、ヤシ油、パーム油、パーム核油、サザンカ油、茶油、牛脂、馬脂、ミンク油、乳脂、卵黄油、タートル油等の油脂類、流動パラフィン、流動イソパラフィン、イソドデカン、イソヘキサデカン、スクワラン、スクワレン、ワセリン、パラフィン、セレシン、マイクロクリスタリンワックス等の炭化水素油類、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸、リノール酸、ウンデシレン酸、ヒドロキシステアリン酸、ラノリン脂肪酸等の脂肪酸、ミリスチルアルコール、セチルアルコール、セトステアリルアルコール、ステアリルアルコール、アラルキルアルコール、ベヘニルアルコール、オレイルアルコール、ホホバアルコール、バチルアルコール、コレステロール、フィトステロール、ラノリンアルコール、イソステアリルアルコール等の高級アルコール類、C12−15アルキルベンゾエート、イソノナン酸イソオクチル、イソノナン酸2−エチルヘキシル、イソノナン酸イソノニル、イソノナン酸イソトリデシル、オクタン酸アルキル(C14,C16,C18)、オクタン酸セチル、オクタン酸イソセチル、オクタン酸セトステアリル、オクタン酸ステアリル、オクタン酸イソステアリル、ラウリン酸ヘキシル、ミリスチン酸イソプロピル、ミリスチン酸ミリスチル、ミリスチン酸ヘキシルデシル、ミリスチン酸セチル、ミリスチン酸オクチルドデシル、ミリスチン酸イソステアリル、パルミチン酸イソプロピル、パルミチン酸2−エチルヘキシル、パルミチン酸オクチル、パルミチン酸セチル、ステアリン酸エチル、ステアリン酸ブチル、ステアリン酸ヘキシルデシル、ステアリン酸ステアリル、イソステアリン酸エチル、イソステアリン酸イソプロピル、イソステアリン酸ヘキシルデシル、イソステアリン酸イソステアリル、イソステアリン酸ポリグリセリル、ジイソステアリン酸ポリグリセリル、トリイソステアリン酸ポリグリセリル、テトライソステアリン酸ポリグリセリル、オレイン酸エチル、オレイン酸オレイル、オレイン酸フィトステリル、ラノリン脂肪酸オクチルドデシル、エイコセン酸オクチル、脂肪酸(C18−C36)グリコール、乳酸オクチルドデシル、コハク酸ジエトキシエチル、コハク酸2−エチルヘキシル、コハク酸ジオクチル、アジピン酸ジイソブチル、アジピン酸ジヘプチルウンデシル、アジピン酸PPG−3ミリスチル、アジピン酸PPG−2−ミレス−10、ジカプル酸プロピレングリコール、ジカプリン酸プロピレングリコール、ジノナン酸プロピレングリコール、ジカプリルカプリン酸プロピレングリコール、ジステアリン酸プロピレングリコール、ジイソステアリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジオクタン酸ネオペンチルグリコール、ジカプリン酸ネオペンチルグリコール、リンゴ酸ジイソステアリル、セバシン酸ジエチル、セバシン酸ジイソプロピル、ダイマー酸ジイソプロピル、ダイマー酸硬化ヒマシ油、ダイマージリノール酸ジイソステアリル・フィトステリル、ダイマージリノレイル水添ロジン縮合物、ジイソステアリン酸ダイマージリノレイル、ダイマージリノール酸ダイマージリノレイル、トリオクタン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、トリオクタノイン、トリカプリル酸グリセリル、トリカプリルカプリン酸グリセリル、トリミリスチン酸グリセリル、トリイソステアリン酸グリセリル、カプリル/カプリン/ミリスチン/ステアリン酸トリグリセリル、ヒドロキシステアリン酸グリセリル、トリベヘニン、テトラオクタン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリスリット、テトライソステアリン酸ペンタエリスリチル、テトライソステアリン酸スクロース、ヒドロキシアルキル(C12−C14)ヒドロキシダイマージリノレイルエーテル、ヒドロキシアルキル(C16−C18)ヒドロキシダイマージリノレイルエーテル、ヒドロキシステアリン酸コレステリル、ヒドロキシステアリン酸/ステアリン酸/ロジン酸ジペンタエリスリチル、ヒドロキシステアリン酸/イソステアリン酸ジペンタエリスリチル、ヘキサヒドロキシステアリン酸ジペンタエリスリチル、オクタン酸/ステアリン酸/アジピン酸グリセリル、ネオペンタン酸オクチルドデシル、ネオペンタン酸イソトリデシル、ネオペンタン酸オクチルドデシル、ネオペンタン酸ミリスチル、ジイソノナン酸プロピレングリコール、トリ2−エチルヘキサン酸グリセリル、トリ2−エチルヘキサン酸トリメチロールプロパン、マカデミアナッツ脂肪酸フィトステリル、PPG−7/コハク酸オリゴエステル、ヘキシルデカン酸/セバシン酸ジグリセリルオリゴエステル、サリチル酸エチルヘキシル、N−ラウロイル−L−グルタミン酸ジフィトステリル・オクチルドデシル、ラウロイルサルコシンイソプロピル、等のエステル油類、ミツロウ、カンデリラロウ、鯨ロウ、綿ロウ、カルナウバロウ、ベイベリーロウ、ヌカロウ、イボタロウ、オレンジラッフィー油、モンタンロウ、サトウキビロウ、セラックロウ、ラノリン、硬質ラノリン、還元ラノリン、吸着精製ラノリン、ホホバオイル、等のロウ類、メチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロテトラシロキサン、アルキル変性シリコーン、アルコール変性シリコーン、アミノ変性シリコーン、エポキシ変性シリコーン、オレフィン変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、フェノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、リン酸変性シリコーン、フッ素変性シリコーン、高級脂肪酸変性シリコーン、ポリエーテル変性シリコーン等のシリコーン類、パーフルオロポリエーテル、ハイドロフルオロエーテル、パーフルオロメチルシクロペンタン、パーフルオロジメチルシクロヘキサン、パーフルオロジメチルシクロブタン、メトキシノナフルオロブタン、エトキシノナフルオロブタン、ドデカフルオロペンタン、テトラデカフルオロヘキサン、パーフルオロデカン、パーフルオロオクタン、4−トリトリフルオロメチルパーフルオロモルホリン、4−ペンタフルオロエチルパーフルオロモルホリン等のフッ素系油剤、UV吸収剤としてはフェルラ酸イソステアリル、パラアミノ安息香酸、パラアミノ安息香酸モノグリセリンエステル、N,N−ジメチルパラアミノ安息香酸エチルエステル、N,N−ジエトキシパラアミノ安息香酸エチルエステル、N,N−ジプロポキシパラアミノ安息香酸エチルエステル等の安息香酸類、ホモメンチル−N−アセチルアントラニレート等のアントラニル酸類、アミルサリシレート、メンチルサリシレート、ホモメンチルサリシレート、オクチルサリシレート、フェニルサリシレート、ベンジルサリシレート等のサリチル酸類、オクチルシンナメート、エチル−4−イソプロピルシンナメート、メチル−2,5−ジイソプロピルシンナメート、エチル−2,4−ジイソプロピルシンナメート、プロピル−p−メトキシシンナメート、イソプロピル−p−メトキシシンナメート、イソアミル−p−メトキシシンナメート、オクチル−p−メトキシシンナメート、2−エトキシエチル−p−メトキシシンナメート、シクロヘキシル−p−メトキシシンナメート等の桂皮酸類、2,4−ジヒドロキシベンゾフェノン、2,2’−ジヒドロキシ−4−メトキシベンゾフェノン、2−ヒドロキシ−4−メトキシベンゾフェノン、2−ヒドロキシ−4−メトキシベンゾフェノン−5−スルホン酸塩、4−フェニルベンゾフェノン、4−ヒドロキシ−3−カルボキシベンゾフェノン等のベンゾフェノン類、3−ベンジリデン−d,l−カンファー、ウロカニン酸、ウロカニン酸エチルエステル、2−フェニル−5−メチルベンゾキサゾール、ジベンザラジン、ジアニソイルメタン、4−tert−ブチル−4’−メトキシジベンゾイルメタン、シリコーン変性紫外線吸収剤、フッ素変性紫外線吸収剤等が挙げられる。これらのうち1種又は2種以上を本発明において親油性溶媒として使用できる。尚、複数成分の混合物で本発明に使用する親油性溶媒を構成する場合、複数成分を混合して得られた溶媒自体が親油性で均一の溶液であれば、構成成分の1種以上が親油性でなくとも構わない。 In the present invention, the dispersion medium of the oil dispersion may be any lipophilic one, and may be liquid or solid at room temperature. It is preferable to use a solvent that can be used for various cosmetics. Specifically, monohydric alcohol solvents such as methanol, ethanol, propyl alcohol, isopropyl alcohol, butanol, amyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, capryl alcohol, nonyl alcohol, decyl alcohol, phenol and benzyl alcohol. Petroleum hydrocarbons such as benzene, toluene, xylene, cyclohexane, ethylbenzene, and amylbenzene, and aromatic hydrocarbon solvents such as benzene, toluene, xylene, cyclohexane, ethylbenzene, amylbenzene, and the like, and normal pentane, normal hexane, normal heptane, normal octane, isohexane, isooctane, gasoline, and mineral spirits , Plant hydrocarbon solvents such as dipentene and turpentine oil, nitro hydrocarbon solvents such as nitroparaffin and nitrobenzene, acetone, methyl ether Ketone solvents such as luketone, methyl isobutyl ketone, ethyl butyl ketone, diisobutyl ketone, halogenated hydrocarbon solvents such as methylene chloride, chloroform, carbon tetrachloride, perchlorethylene, monochlorobenzene, ethyl ether, isopropyl ether, Ether solvents such as butyl ether, hexyl ether, propylene oxide, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, methyl formate, ethyl formate, butyl formate, methyl acetate, ethyl acetate, butyl acetate , Amyl acetate, ethyl propionate, butyl propionate, isobutyl propionate, ethyl butyrate, butyl butyrate, methyl lactate, ethyl lactate, butyl lactate, amyl lactate, etc. , Safflower oil, soybean oil, evening primrose oil, grape seed oil, rosehip oil, cucumber nut oil, almond oil, sesame oil, wheat germ oil, corn oil, cottonseed oil, avocado oil, olive oil, camellia oil, persic oil, castor oil , Peanut oil, hazelnut oil, macadamia nut oil, medofoam oil, cocoa butter, shea butter, tree wax, palm oil, palm oil, palm kernel oil, sasanqua oil, tea oil, beef tallow, horse fat, mink oil, milk fat, egg yolk Oils and fats such as turtle oil, liquid paraffin, liquid isoparaffin, isododecane, isohexadecane, squalane, squalene, petrolatum, paraffin, ceresin, microcrystalline wax and other hydrocarbon oils, lauric acid, myristic acid, palmitic acid, stearin Acid, behenic acid, oleic acid, linoleic acid, undeci Fatty acids such as renoic acid, hydroxystearic acid, lanolin fatty acid, myristyl alcohol, cetyl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, oleyl alcohol, jojoba alcohol, batyl alcohol, cholesterol, phytosterol, lanolin alcohol, isostearyl alcohol Higher alcohols such as C12-15 alkylbenzoate, isooctyl isononanoate, 2-ethylhexyl isononanoate, isononyl isononanoate, isotridecyl isononanoate, alkyl octanoate (C14, C16, C18), cetyl octanoate, isocetyl octanoate, octane Cetostearyl acid, stearyl octoate, isostearyl octoate, hexyl laurate Isopropyl myristate, myristyl myristate, hexyl decyl myristate, cetyl myristate, octyl dodecyl myristate, isostearyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, octyl palmitate, cetyl palmitate, ethyl stearate, stearin Acid butyl, hexyldecyl stearate, stearyl stearate, ethyl isostearate, isopropyl isostearate, hexyldecyl isostearate, isostearyl isostearate, polyglyceryl isostearate, polyglyceryl diisostearate, polyglyceryl triisostearate, polyglyceryl tetraisostearate, oleic acid Ethyl, oleyl oleate, phytostearate Lanolin fatty acid octyldodecyl, eicosenate octyl, fatty acid (C18-C36) glycol, octyl dodecyl lactate, diethoxyethyl succinate, 2-ethylhexyl succinate, dioctyl succinate, diisobutyl adipate, diheptyl undecyl adipate, PPG-3 myristyl adipate, PPG-2-milles-10 adipate, propylene glycol dicaprate, propylene glycol dicaprate, propylene glycol dinonanoate, propylene glycol dicaprycaprate, propylene glycol distearate, propylene glycol diisostearate, dioleic acid Propylene glycol, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, diisostearyl malate, seba Diethyl silicate, diisopropyl sebacate, diisopropyl dimer acid, dimer acid hydrogenated castor oil, dimer stearyl phytosteryl dimer dilinoleate, dimer dilinoleyl hydrogenated rosin condensate, dimer stearic acid dimer dilinoleyl, dimer dilinoleic acid die Marginoleyl, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, trioctanoin, glyceryl tricaprylate, glyceryl tricaprylate, glyceryl trimyristate, glyceryl triisostearate, capryl / caprin / myristine / tristearate Glyceryl, glyceryl hydroxystearate, tribehenine, pentaerythrityl tetraoctanoate, pentaerythritol tetraisostearate , Pentaerythrityl tetraisostearate, sucrose tetraisostearate, hydroxyalkyl (C12-C14) hydroxy dimer dilinoleyl ether, hydroxyalkyl (C16-C18) hydroxy dimer dilinoleyl ether, cholesteryl hydroxy stearate, hydroxy stearic acid / Stearic acid / dipentaerythrityl rosinate, hydroxystearic acid / dipentaerythrityl isostearate, dipentaerythrityl hexahydroxystearate, octanoic acid / stearic acid / glyceryl adipate, octyldodecyl neopentanoate, isotridecyl neopentanoate, octyldodecyl neopentanoate, myristyl neopentylate, Propylene glycol diisononanoate, tri-2-ethyl Glyceryl hexanoate, trimethylolpropane tri-2-ethylhexanoate, macadamia nut fatty acid phytosteryl, PPG-7 / succinic acid oligoester, hexyldecanoic acid / diglyceryl sebacic acid oligoester, ethylhexyl salicylate, diphytosteryl octyl N-lauroyl-L-glutamate Ester oils such as dodecyl, lauroyl sarcosine isopropyl, beeswax, candelilla wax, whale wax, cotton wax, carnauba wax, bayberry wax, nukawa, ibotarou, orange luffy oil, montan wax, sugarcane wax, shellac wax, lanolin, hard lanolin, reduced lanolin, Adsorbed refined lanolin, jojoba oil, waxes, methylpolysiloxane, methylphenylpolysiloxane, decamethylcyclotetrasi Loxane, alkyl modified silicone, alcohol modified silicone, amino modified silicone, epoxy modified silicone, olefin modified silicone, carboxyl modified silicone, carbinol modified silicone, phenol modified silicone, methacryl modified silicone, mercapto modified silicone, phosphoric acid modified silicone, fluorine modified Silicones such as silicone, higher fatty acid modified silicone, polyether modified silicone, perfluoropolyether, hydrofluoroether, perfluoromethylcyclopentane, perfluorodimethylcyclohexane, perfluorodimethylcyclobutane, methoxynonafluorobutane, ethoxynonafluorobutane , Dodecafluoropentane, tetradecafluorohexane, perfluorodecane, Fluoro-based oils such as fluorooctane, 4-trifluoromethylperfluoromorpholine, 4-pentafluoroethylperfluoromorpholine, and UV absorbers include isostearyl ferulate, paraaminobenzoic acid, monoglycerin ester of paraaminobenzoic acid, N, N -Benzoic acids such as dimethylparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, anthranilic acids such as homomenthyl-N-acetylanthranilate, amyl Salicylates such as salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, octylcinnamate, ethyl-4-isopro Rucinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p- Cinnamic acids such as methoxycinnamate, 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2-hydroxy- Benzophenones such as 4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 4-hydroxy-3-carboxybenzophenone, 3-benzylidene-d, l -Camphor, urocanic acid, urocanic acid ethyl ester, 2-phenyl-5-methylbenzoxazole, dibenzalazine, dianisoylmethane, 4-tert-butyl-4'-methoxydibenzoylmethane, silicone-modified UV absorber, fluorine-modified An ultraviolet absorber etc. are mentioned. Of these, one or more can be used as the lipophilic solvent in the present invention. When the lipophilic solvent used in the present invention is composed of a mixture of a plurality of components, if the solvent itself obtained by mixing the plurality of components is a lipophilic and homogeneous solution, at least one of the components is a lipophilic solvent. It does not have to be oily.
本発明の油性分散体はできるだけ単純な組成のものが好ましいが、酸性エステル油で被覆された表面処理粉体の含有量については特に制限はなく任意の割合で配合することができる。なお、前記表面処理粉体の好ましい含有量は1〜95重量%であり、特に好ましい含有量は5〜90重量%である。また、このような油性分散体を化粧料に配合する場合において、上記表面処理粉体と親油性溶媒と必要な場合にはその他の成分とを直接混合して化粧料を製造しても良く、あるいは、あらかじめ上記表面処理粉体と親油性溶媒とを混合して本発明の油性分散体を調製してからこれを用いて化粧料を製造してもいずれの方法でも良い。 The oily dispersion of the present invention preferably has a composition as simple as possible, but the content of the surface-treated powder coated with the acidic ester oil is not particularly limited and can be blended at an arbitrary ratio. In addition, the preferable content of the surface-treated powder is 1 to 95% by weight, and the particularly preferable content is 5 to 90% by weight. In addition, when such an oily dispersion is blended in a cosmetic, the surface-treated powder, a lipophilic solvent, and if necessary, other components may be directly mixed to produce a cosmetic, Alternatively, the surface-treated powder and the oleophilic solvent are mixed in advance to prepare the oily dispersion of the present invention, and then a cosmetic is produced using this, and any method may be used.
本発明の油性分散体は、被覆粉体をより分散させるため、またその分散をより安定化させるため、又は油性分散体の機能を第三成分との相乗効果でより向上させるため等、各種の目的で第三成分以上の他の成分を含んでも良い。このような目的で配合される成分には、各種の界面活性剤が含まれ、例えばPOEラウリル硫酸トリエタノールアミン等のアルキルエーテル硫酸エステル塩、ドデシルベンゼンスルホン酸ナトリウム等のアルキルベンゼンスルホン酸塩、ラウリル硫酸ナトリウム、ラウリル硫酸カリウム等の高級アルキル硫酸エステル塩、N−アシルサルコシン酸、N−ミリストイル−N−メチルタウリンナトリウム等の高級脂肪酸アミドスルホン酸塩、硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等の高級脂肪酸エステル硫酸エステル塩、高級脂肪酸エステルスルホン酸塩、高級脂肪酸アルキロールアミド硫酸エステル塩、脂肪酸セッケン、スルホコハク酸塩、二級アルコール硫酸エステル塩、POEアルキルエーテルカルボン酸、POEアルキルアリルエーテルカルボン酸塩、α−オレフィンスルホン酸塩、ラウロイルモノエタノールアミドコハク酸ナトリウム、N−パルミトイルアスパラギン酸ジエタノールアミン、カゼインナトリウム等のアニオン系界面活性剤、塩化ステアリルトリメチルアンモニウム等のアルキルトリメチルアンモニウム塩、塩化ジステアリルジメチルアンモニウムジアルキルジメチルアンモニウム塩等のアルキルピリジニウム塩、アルキル四級アンモニウム塩、アルキルアミン塩、アルキルジメチルベンジルアンモニウム塩、アルキルイソキノリニウム塩、ジアルキルモリホニウム塩、POEアルキルアミン、ポリアミン脂肪酸誘導体、アミルアルコール脂肪酸誘導体、塩化ベンザルコニウム、塩化ベンゼトニウム等のカチオン系界面活性剤、2−ココイル−2−イミタゾリニウムヒドロキサイド−1−カルボキシエチロキシ2ナトリウム塩等のイミダゾリン系両性界面活性剤、アルキルベタイン、アミドベタイン、ラウリルジメチルアミノ酢酸ベタイン等のベタイン系両性界面活性剤、セスキオレイン酸グリセリン、モノステアリン酸グリセリン等のグリセリン脂肪酸エステル、ポリリシノール酸ヘキサグリセリル、モノステアリン酸ジグリセリル、デカオレイン酸デカグリセリル等のポリグリセリン脂肪酸エステル、ソルビタンモノオレート、ソルビタンセスキオレエート等のソルビタン脂肪酸エステル、モノステアリン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル、POEソルビタンモノオレエート等のPOEソルビタン脂肪酸エステル、POEグリセリントリイソステアレート等のPOEグリセリン脂肪酸エステル、POEモノオレート、POEジステアレート等のPOE脂肪酸エステル、POEラウリルエーテル、POEステアリルエーテル等のPOEアルキルエーテル、POE・POP水添ラノリン等のPOE・POPアルキルエーテル、硬化ひまし油誘導体、グリセリンアルキルエーテル、アルカノールアミド、ショ糖脂肪酸エステル、デキストリン脂肪酸エステル、イヌリン脂肪酸エステル、ヒドロキシステアリン酸等のノニオン系界面活性剤、その他レシチン等のリン脂質類、トレハロースリピド等の糖脂質類、パーフルオロアルキルリン酸塩、パーフルオロアルキルスルホン酸塩、パーフルオロアルキルカルボン酸塩等のフッ素系界面活性剤等、アクリル酸メタクリル酸アルキル共重合体、ベントナイト、スメクタイト、カオリン等の天然又は合成の粘土鉱物、有機アミンカチオン変性ベントナイト等の有機変性粘土鉱物、アエロゾル等を挙げることができる。 The oil-based dispersion of the present invention can be used in various ways, for example, to further disperse the coated powder, to stabilize the dispersion, or to further improve the function of the oil-based dispersion by synergistic effects with the third component. Other components other than the third component may be included for the purpose. Ingredients formulated for such purposes include various surfactants, such as alkyl ether sulfates such as POE lauryl sulfate triethanolamine, alkylbenzene sulfonates such as sodium dodecylbenzenesulfonate, lauryl sulfate. Higher fatty acid ester sulfates such as higher alkyl sulfates such as sodium and potassium lauryl sulfate, higher fatty acid amide sulfonates such as N-acyl sarcosine, N-myristoyl-N-methyltaurine sodium, and hardened coconut oil fatty acid sodium glycerin sulfate Ester salt, higher fatty acid ester sulfonate, higher fatty acid alkylolamide sulfate ester, fatty acid soap, sulfosuccinate, secondary alcohol sulfate ester, POE alkyl ether carboxylic acid, POE alkyl allyl ester Tercarboxylate, α-olefin sulfonate, sodium lauroyl monoethanolamide succinate, diethanolamine N-palmitoyl aspartate, sodium caseinate, alkyltrimethylammonium salts such as stearyltrimethylammonium chloride, distearyl chloride Alkyl pyridinium salts such as dimethyl ammonium dialkyl dimethyl ammonium salts, alkyl quaternary ammonium salts, alkyl amine salts, alkyl dimethyl benzyl ammonium salts, alkyl isoquinolinium salts, dialkyl morpholinium salts, POE alkyl amines, polyamine fatty acid derivatives, amyl Alcohol fatty acid derivatives, cationic surfactants such as benzalkonium chloride and benzethonium chloride, 2-cocoyl-2-imita Izoazoline amphoteric surfactants such as zolinium hydroxide-1-carboxyethyloxy disodium salt, betaine amphoteric surfactants such as alkylbetaines, amidobetaines, lauryldimethylaminoacetic acid betaines, glyceryl sesquioleate, monostearic acid Glycerin fatty acid esters such as glycerin, polyglycerin fatty acid esters such as hexaglyceryl polyricinoleate, diglyceryl monostearate, decaglyceryl decaoleate, sorbitan fatty acid esters such as sorbitan monooleate and sorbitan sesquioleate, propylene glycol monostearate, etc. Propylene glycol fatty acid ester, POE sorbitan fatty acid ester such as POE sorbitan monooleate, POE glycerin triisostearate, etc. POE fatty acid esters such as POE glycerin fatty acid ester, POE monooleate and POE distearate, POE alkyl ethers such as POE lauryl ether and POE stearyl ether, POE / POP alkyl ethers such as POE / POP hydrogenated lanolin, hardened castor oil derivatives, glycerin alkyl ether , Alkanolamides, sucrose fatty acid esters, dextrin fatty acid esters, inulin fatty acid esters, nonionic surfactants such as hydroxystearic acid, other phospholipids such as lecithin, glycolipids such as trehalose lipid, perfluoroalkyl phosphates , Fluorine-based surfactants such as perfluoroalkyl sulfonate and perfluoroalkyl carboxylate, alkyl methacrylate methacrylate copolymer, bentonite, Mekutaito, mention may be made of natural or synthetic clay minerals such as kaolin, clay minerals modified with organic compounds such as organic amine cation-modified bentonite, aerosols and the like.
本発明で使用する被覆粉体を分散媒に混練又は混合分散させる方法は、公知の方法を採用すればよく特に限定されない。例えば、ニーダー混練、ヘンシル混練、ロール混練、エクストルーダー混練等の混練混合機、プロペラミキサー、ハイスピードミキサー、ディゾルバー、ホモジナイザー、アルテマイザー、湿式ジェットミル、コロイドミル、マスコロイダー、ビーズミル、サンドミル、バスケットミル等の湿式混合分散機を使用して油性分散体を製造することができる。 The method of kneading or mixing and dispersing the coated powder used in the present invention in a dispersion medium is not particularly limited as long as a known method is adopted. For example, kneader mixing machines such as kneader kneading, hensil kneading, roll kneading, extruder kneading, propeller mixer, high speed mixer, dissolver, homogenizer, artemizer, wet jet mill, colloid mill, mass colloider, bead mill, sand mill, basket mill An oil-based dispersion can be produced using a wet mixing and dispersing machine such as, for example.
常温で固体状の親油性溶媒(1種単独溶媒又は複数溶媒の混合物が含まれる。)に被覆粉体を分散させる方法としては、特に困難は無い。例えば、その親油性溶媒を融点以上の温度に加熱して液化した状態で粉体を分散させるとよい。この方法は、例えば口紅等の常温で固体状のワックス等を多く配合する剤型に普通に行われる方法である。 There is no particular difficulty as a method of dispersing the coated powder in a lipophilic solvent that is solid at room temperature (including a single solvent or a mixture of a plurality of solvents). For example, the powder may be dispersed in a state in which the lipophilic solvent is liquefied by heating to a temperature equal to or higher than the melting point. This method is a method that is usually performed in a dosage form that contains a large amount of solid wax at room temperature, such as lipstick.
更に、本発明の油性分散体は従来から使用されている粉体や被覆粉体を配合することなく本発明で使用する被覆粉体のみで分散体とすることが、本発明の効果をより発現する点で好ましいが、本発明の効果を害しない範囲で従来から使用される粉体を一部配合して油性分散体とすることもできる。あるいは、本発明に使用する酸性エステル油を粉体に表面処理する工程と、親油性溶媒と混合して油性分散体を調製する工程とを同時に行うことも可能である。 Furthermore, the effect of the present invention can be further manifested in that the oil-based dispersion of the present invention is made only with the coating powder used in the present invention without blending the powder or coating powder conventionally used. However, it is also possible to make an oily dispersion by partially blending conventionally used powders as long as the effects of the present invention are not impaired. Or it is also possible to perform simultaneously the process of surface-treating the acidic ester oil used for this invention to a powder, and the process of mixing with a lipophilic solvent and preparing an oil-based dispersion.
本発明の油性分散体を配合する化粧料としては、パウダーファンデーション、リキッドファンデーション、クリームファンデーション、油性ファンデーション、スティックファンデーション、プレストパウダー、フェイスパウダー、口紅、リップグロス、頬紅、アイシャドウ、アイブロウ、アイライナー、マスカラ、水性ネイルエナメル、油性ネイルエナメル、乳化型ネイルエナメル、エナメルトップコート、エナメルベースコート、等の仕上用化粧品、エモリエントクリーム、エモリエントローション、ミルキーローション、マッサージローション、コールドクリーム、美白クリーム、乳液、化粧水、美容液、カーマインローション、クレンジングジェル、液状洗顔料、洗顔フォーム、洗顔クリーム、洗顔パウダー、メイククレンジング、ボディグロス、等の基礎化粧品、ヘアーグロス、ヘアクリーム、ヘアオイル、ヘアーシャンプー、ヘアリンス、ヘアカラー、ヘアブラッシング剤、等の頭髪用化粧品、その他として日焼け止め及び日焼けクリームや乳液、石鹸、浴用剤、制汗剤、香水等を挙げることができる。 Cosmetics for blending the oil dispersion of the present invention include powder foundation, liquid foundation, cream foundation, oil foundation, stick foundation, pressed powder, face powder, lipstick, lip gloss, blusher, eye shadow, eyebrow, eyeliner, Finishing cosmetics such as mascara, aqueous nail enamel, oily nail enamel, emulsified nail enamel, enamel top coat, enamel base coat, emollient cream, emollient lotion, milky lotion, massage lotion, cold cream, whitening cream, milky lotion, lotion , Essence, carmine lotion, cleansing gel, liquid facial cleanser, facial cleansing foam, facial cleansing cream, facial cleansing powder, makeup cleansing, Basic cosmetics such as degloss, hair gloss, hair cream, hair oil, hair shampoo, hair rinse, hair color, hair brushing, etc., and other sunscreen and tanning creams and emulsions, soap, bath preparation, antiperspirant Agents, perfumes and the like.
本発明の油性分散体を配合する化粧料には、発明の効果を損なわない範囲で、通常の化粧料等に用いられる顔料分散剤、油剤、界面活性剤、紫外線吸収剤、防腐剤、酸化防止剤、皮膜形成剤、保湿剤、増粘剤、染料、顔料、香料等を適宜配合することができる。 In the cosmetics containing the oil dispersion of the present invention, pigment dispersants, oils, surfactants, ultraviolet absorbers, preservatives, antioxidants used in ordinary cosmetics, etc., as long as the effects of the invention are not impaired. An agent, a film forming agent, a humectant, a thickener, a dye, a pigment, a fragrance and the like can be appropriately blended.
(化粧料以外の用途)
本発明の油性分散体は、化粧料のみならずプラスチックの添加剤、インク、塗料、トナー(磁性粉)、化学繊維、包装材料、電子材料等の各種分野で広く使用される粉体の油性分散体にも適用可能である。特に、他の分野で、化粧料に使用可能な粉体を使用し、同様に分散体を必要とする場合には、上記化粧料用に説明した油性分散体が当該他の分野でも同様に採用可能である。
(Uses other than cosmetics)
The oil dispersion of the present invention is an oil dispersion of powders widely used in various fields such as cosmetics as well as plastic additives, inks, paints, toners (magnetic powders), chemical fibers, packaging materials, electronic materials, etc. It can also be applied to the body. In particular, when powders that can be used in cosmetics are used in other fields and a dispersion is required in the same manner, the oil-based dispersions described for cosmetics are also used in other fields as well. Is possible.
以下に、実施例及び比較例を挙げて本発明を詳細に説明する。当然のことながら、これらの実施例は本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples. Of course, these examples do not limit the invention in any way.
[酸性エステル油の合成例1](一価アルコールと二塩基酸の部分エステル)
攪拌機、温度計、窒素ガス吹き込み管および水分離器を備えた四つ口フラスコにオレイルアルコール2.2kg、コハク酸0.8kgとキシレンおよびパラトルエンスルホン酸を全仕込み量に対して5%、0.2%加え、180℃にて計算量の水が水分離器にたまるまで反応を行う。反応終了後、未反応物を分別し、常法にて脱臭・脱色し酸性エステル油2.2kgを得た。得られたエステル油の酸価は43であった。
[Synthesis Example 1 of Acidic Ester Oil] (Partial ester of monohydric alcohol and dibasic acid)
A four-necked flask equipped with a stirrer, thermometer, nitrogen gas blowing tube and water separator was charged with 2.2 kg of oleyl alcohol, 0.8 kg of succinic acid, xylene and paratoluenesulfonic acid, 5% of the total charge, 0 Add 2% and carry out the reaction at 180 ° C. until the calculated amount of water accumulates in the water separator. After completion of the reaction, unreacted substances were separated and deodorized and decolorized by a conventional method to obtain 2.2 kg of acidic ester oil. The acid value of the obtained ester oil was 43.
[酸性エステル油の合成例2](一価のアルコールとヒドロキシ二塩基酸の部分エステル)
合成例1と同様にして、ラウリルアルコール2.0kg、リンゴ酸1.0kgを反応させる。反応終了後、常法にて精製し酸性エステル油2.5kgを得た。得られたエステル油の酸価は35であった。
[Synthesis Example 2 of Acidic Ester Oil] (Partial ester of monohydric alcohol and hydroxy dibasic acid)
In the same manner as in Synthesis Example 1, 2.0 kg of lauryl alcohol and 1.0 kg of malic acid are reacted. After completion of the reaction, purification was conducted by a conventional method to obtain 2.5 kg of acidic ester oil. The acid value of the obtained ester oil was 35.
[酸性エステル油の合成例3](二価アルコールと二塩基酸の部分エステル)
合成例1と同様にして、ネオペンチルグリコール1.2kg、アジピン酸1.8kgを反応させる。反応終了後、常法にて精製し酸性エステル油2.4kgを得た。得られたエステル油の酸価は75であった。
[Synthesis example 3 of acidic ester oil] (partial ester of dihydric alcohol and dibasic acid)
In the same manner as in Synthesis Example 1, 1.2 kg of neopentyl glycol and 1.8 kg of adipic acid are reacted. After completion of the reaction, purification was conducted by a conventional method to obtain 2.4 kg of acidic ester oil. The acid value of the obtained ester oil was 75.
[酸性エステル油の合成例4](四価アルコールと二塩基酸のエステル)
合成例1と同様にして、ペンタエリスリット1.0kg、アゼライン酸2.0kgを反応させる。反応終了後、常法にて精製し酸性エステル油2.4kgを得た。得られたエステル油の酸価は70であった。
[Synthesis Example 4 of Acid Ester Oil] (Ester of Tetrahydric Alcohol and Dibasic Acid)
In the same manner as in Synthesis Example 1, 1.0 kg of pentaerythritol and 2.0 kg of azelaic acid are reacted. After completion of the reaction, purification was conducted by a conventional method to obtain 2.4 kg of acidic ester oil. The acid value of the obtained ester oil was 70.
[酸性エステル油の合成例5](一価アルコールと多塩基酸の部分エステル)
合成例1と同様にして、イソステアリルアルコール2.2kg、クエン酸0.8kgを反応させる。反応終了後常法にて精製し酸性エステル2.3kgを得た。得られたエステル油の酸価は88であった。
[Synthesis Example 5 of Acidic Ester Oil] (Partial ester of monohydric alcohol and polybasic acid)
In the same manner as in Synthesis Example 1, 2.2 kg of isostearyl alcohol and 0.8 kg of citric acid are reacted. After completion of the reaction, the product was purified by a conventional method to obtain 2.3 kg of an acidic ester. The acid value of the obtained ester oil was 88.
[酸性エステル油の合成例6](一価アルコールと多塩基酸の部分エステル)
合成例1と同様にして、イソステアリルアルコール2.0kg、クエン酸1.0kgを反応させる。反応終了後常法にて精製し酸性エステル2.2kgを得た。得られたエステル油の酸価は135であった。
[Synthesis Example 6 of Acidic Ester Oil] (Partial ester of monohydric alcohol and polybasic acid)
In the same manner as in Synthesis Example 1, 2.0 kg of isostearyl alcohol and 1.0 kg of citric acid are reacted. After completion of the reaction, purification was conducted by a conventional method to obtain 2.2 kg of an acidic ester. The acid value of the obtained ester oil was 135.
[酸性エステル油の合成例7](一価アルコールとダイマー酸の部分エステル)
合成例1と同様にして、イソパルミチルアルコール1.5kg、ダイマー酸(オレイン酸二量体を主成分とする炭素数36の二塩基酸)3.4kgを反応させる。反応終了後常法にて精製し酸性エステル3.6kgを得た。得られたエステル油の酸価は48であった。
[Synthesis Example 7 of Acidic Ester Oil] (Partial ester of monohydric alcohol and dimer acid)
In the same manner as in Synthesis Example 1, 1.5 kg of isopalmityl alcohol and 3.4 kg of dimer acid (a dibasic acid having 36 carbon atoms mainly composed of oleic acid dimer) are reacted. After completion of the reaction, purification was conducted by a conventional method to obtain 3.6 kg of an acidic ester. The acid value of the obtained ester oil was 48.
[油性分散体の製造実施例1]
セリサイトFSE(三信鉱工(株))100重量部に合成例1の酸性エステル油を5重量部と軽質流動イソパラフィン5重量部を加え高速ヘンシルミキサーで15分間混合した。その後、アトマイザーを通した後105℃で8時間乾燥し酸性エステル油処理セリサイトを得た。酸性エステル処理セリサイト80重量部とC12−C15アルキルベンゾエート(FINSOLV TN:FINETEX社)20重量部をホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散して油性分散体を得た。
[Production Example 1 of Oily Dispersion]
5 parts by weight of the acidic ester oil of Synthesis Example 1 and 5 parts by weight of light liquid isoparaffin were added to 100 parts by weight of sericite FSE (Sanshin Mining Co., Ltd.), and mixed for 15 minutes with a high-speed Hensyl mixer. Then, after passing through an atomizer, it dried at 105 degreeC for 8 hours, and obtained acidic ester oil processing sericite. 80 parts by weight of acidic ester-treated sericite and 20 parts by weight of C12-C15 alkyl benzoate (FINSOLV TN: FINETEX) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed with a homogenizer for 15 minutes to obtain an oily dispersion.
[油性分散体の製造実施例2]
酸化チタンCR−50(石原産業(株))100重量部と合成例2の酸性エステル油5重量部をヘンシルミキサーで10分間混合する。この混合物をジェットミル(ホソカワミクロン(株))で粉砕処理した後、105℃で8時間乾燥して酸性エステル油処理酸化チタンを得た。酸性エステル処理酸化チタン2重量部とラウリン酸ヘキシル(クロダモルHL−R:クローダジャパン(株))93重量部、ヤシ油グルコシド2.5重量部、及びポリグリセリル2−ジポリヒドロキシステアレート2.5重量部とを90℃にてホモディスパーで5分間混合分散後、ホモジナイザーで分散し油性分散体を得た。
[Production Example 2 of Oily Dispersion]
100 parts by weight of titanium oxide CR-50 (Ishihara Sangyo Co., Ltd.) and 5 parts by weight of the acidic ester oil of Synthesis Example 2 are mixed with a Hensyl mixer for 10 minutes. This mixture was pulverized with a jet mill (Hosokawa Micron Corporation) and then dried at 105 ° C. for 8 hours to obtain acidic ester oil-treated titanium oxide. 2 parts by weight of acidic ester-treated titanium oxide, 93 parts by weight of hexyl laurate (Crodamol HL-R: Croda Japan Co., Ltd.), 2.5 parts by weight of coconut oil glucoside, and 2.5 parts by weight of polyglyceryl 2-dipolyhydroxystearate The mixture was mixed and dispersed with a homodisper at 90 ° C. for 5 minutes, and then dispersed with a homogenizer to obtain an oily dispersion.
[油性分散体の製造実施例3]
実施例1のセリサイトを酸化鉄イエローLL−100P(チタン工業(株))に変え、更に合成例1の酸性エステル油を合成例3の酸性エステル油5重量部に変えて同様に表面処理を行い酸性エステル油処理黄酸化鉄を得た。酸性エステル処理黄酸化鉄70重量部とN−ラウロイル−L−グルタミン酸ジフィトステリル(エルデュウPS203:味の素(株))30重量部をホモディスパーで5分間混合分散後、サンドグラインダーを通し分散して油性分散体を得た。
[Production Example 3 of Oily Dispersion]
The sericite of Example 1 was changed to iron oxide yellow LL-100P (Titanium Industry Co., Ltd.), and the acidic ester oil of Synthesis Example 1 was changed to 5 parts by weight of the acidic ester oil of Synthesis Example 3 to similarly perform the surface treatment. Then, an acidic ester oil-treated yellow iron oxide was obtained. 70 parts by weight of acid ester-treated yellow iron oxide and 30 parts by weight of diphytosteryl N-lauroyl-L-glutamate (Eldou PS203: Ajinomoto Co., Inc.) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed through a sand grinder to obtain an oily dispersion. Got.
[油性分散体の製造実施例4]
実施例1のセリサイトを酸化鉄ベンガラ七宝(森下弁柄工業(株))に変え、更に合成例1の酸性エステル油を合成例4の酸性エステル油6重量部に変えて同様に表面処理を行い酸性エステル油処理ベンガラを得た。酸性エステル処理ベンガラ50重量部とトリオクタノイン(TIO:日清オイリオ(株))50重量部を練合機で練り合わせた後、3本ロールにて分散し油性分散体を得た。
[Production Example 4 of Oily Dispersion]
The sericite of Example 1 was changed to iron oxide bengara cloisonne (Morishita Benzai Kogyo Co., Ltd.), the acidic ester oil of Synthesis Example 1 was changed to 6 parts by weight of the acidic ester oil of Synthesis Example 4, and the same surface treatment was performed. The acid ester oil-treated bengara was obtained. 50 parts by weight of acidic ester-treated bengara and 50 parts by weight of trioctanoin (TIO: Nisshin Oilio Co., Ltd.) were kneaded with a kneader, and then dispersed with three rolls to obtain an oily dispersion.
[油性分散体の製造実施例5]
実施例1のセリサイトを酸化鉄ブラックBL−100P(チタン工業(株))に変え、更に合成例1の酸性エステル油を合成例5の酸性エステル油5重量部に変えて同様に表面処理を行い酸性エステル油処理黒酸化鉄を得た。酸性エステル処理黒酸化鉄65重量部とステアリル変性アクリルシリコーン(KP−561P:信越化学工業(株))35重量部を練合機で練り合わせた後3本ロールにて分散し油性分散体を得た。
[Production Example 5 of Oily Dispersion]
The sericite of Example 1 was changed to iron oxide black BL-100P (Titanium Industry Co., Ltd.), and the acid ester oil of Synthesis Example 1 was changed to 5 parts by weight of the acid ester oil of Synthesis Example 5 to similarly perform the surface treatment. The acid ester oil-treated black iron oxide was obtained. 65 parts by weight of acid ester-treated black iron oxide and 35 parts by weight of stearyl-modified acrylic silicone (KP-561P: Shin-Etsu Chemical Co., Ltd.) were kneaded with a kneader and dispersed with three rolls to obtain an oily dispersion. .
[油性分散体の製造実施例6]
脂肪酸処理微粒子酸化チタン(TTO−S−4:石原産業(株))100重量部に合成例6の酸性エステル油10重量部を加え高速ヘンシルミキサ−で20分間混合する。この混合物をジェットミル(ホソカワミクロン(株))で粉砕処理した後、105℃で5時間乾燥して酸性エステル油処理微粒子酸化チタンを得た。酸性エステル処理微粒子酸化チタン30重量部とオクトクリレン(Eusolex OCR:MERCK社)65重量部、及びアエロゾルR812(日本アエロゾル(株))5重量部とをホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散し油性分散体を得た。
[Production Example 6 of Oily Dispersion]
10 parts by weight of the acid ester oil of Synthesis Example 6 is added to 100 parts by weight of fatty acid-treated fine particle titanium oxide (TTO-S-4: Ishihara Sangyo Co., Ltd.) and mixed for 20 minutes with a high-speed Hensyl mixer. This mixture was pulverized with a jet mill (Hosokawa Micron Corporation) and then dried at 105 ° C. for 5 hours to obtain fine particles of acid ester oil-treated fine titanium oxide. 30 parts by weight of acidic ester-treated fine particles of titanium oxide, 65 parts by weight of octocrylene (Eusolex OCR: MERCK) and 5 parts by weight of Aerosol R812 (Nippon Aerosol Co., Ltd.) are mixed and dispersed with a homodisper for 5 minutes, and then with a homogenizer for 15 minutes. Dispersion gave an oily dispersion.
[油性分散体の製造実施例7]
微粒子酸化亜鉛(FINEX−50:堺化学工業(株))100重量部に合成例7の酸性エステル油7重量部とシリコーンオイルKF−9901(信越化学工業(株))5重量部を加え高速ヘンシルミキサーで20分間混合する。その後、アトマイザーを通した後105℃で6時間乾燥し酸性エステル油処理微粒子酸化亜鉛を得た。酸性エステル処理微粒子酸化亜鉛60重量部とイソヘキサデカン(パーメチル101A:PRESPERSE)40重量部とをホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散し油性分散体を得た。
[Production Example 7 of Oily Dispersion]
7 parts by weight of acid ester oil of Synthesis Example 7 and 5 parts by weight of silicone oil KF-9901 (Shin-Etsu Chemical Co., Ltd.) are added to 100 parts by weight of fine particle zinc oxide (FINEX-50: Sakai Chemical Industry Co., Ltd.). Mix for 20 minutes with a sill mixer. Then, after passing through an atomizer, it dried at 105 degreeC for 6 hours, and obtained acidic ester oil process fine particle zinc oxide. 60 parts by weight of acidic ester-treated fine particles of zinc oxide and 40 parts by weight of isohexadecane (permethyl 101A: PRESPERSE) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed with a homogenizer for 15 minutes to obtain an oily dispersion.
[油性分散体の製造実施例8]
雲母チタン(メルクジャパン(株):TIMIRON SUPER BLUE)100重量部に合成例6の酸性エステル油7重量部を加えヘンシルミキサーで15分間混合する。その後105℃で5時間乾燥し酸性エステル油処理雲母チタンを得た。酸性エステル処理雲母チタン65重量部と酢酸エチル35重量部をホモディスパーで20分間混合分散し油性分散体を得た。
[Production Example 8 of Oily Dispersion]
7 parts by weight of the acidic ester oil of Synthesis Example 6 is added to 100 parts by weight of mica titanium (Merck Japan Co., Ltd .: TIMIRON SUPER BLUE) and mixed for 15 minutes with a Hensyl mixer. Thereafter, it was dried at 105 ° C. for 5 hours to obtain acidic ester oil-treated titanium mica. 65 parts by weight of acidic ester-treated mica titanium and 35 parts by weight of ethyl acetate were mixed and dispersed with a homodisper for 20 minutes to obtain an oily dispersion.
[油性分散体の製造実施例9]
エクセルマイカJP−2(三好化成株式会社)100重量部に合成例6の酸性エステル油10重量部を加えヘンシルミキサーで10分間混合する。その後105℃で5時間乾燥し酸性エステル油処理エクセルマイカJP−2を得た。酸性エステル処理エクセルマイカJP−2を70重量部とジオクタン酸ネオペンチルグリコール30重量部をホモディスパーで20分間混合分散し油性分散体を得た。
[Production Example 9 of oily dispersion]
10 parts by weight of the acidic ester oil of Synthesis Example 6 is added to 100 parts by weight of Excel Mica JP-2 (Miyoshi Chemical Co., Ltd.) and mixed for 10 minutes with a Hensyl mixer. Then, it dried at 105 degreeC for 5 hours, and obtained acidic ester oil processing Excel mica JP-2. 70 parts by weight of acid ester-treated Excelmica JP-2 and 30 parts by weight of neopentyl glycol dioctanoate were mixed and dispersed with a homodisper for 20 minutes to obtain an oily dispersion.
[比較例1]
特開2002−128628号公報の実施例6に記載の方法でセリサイトFSE(三信鉱工(株))をポリダイマージリノール酸ダイマージリノレイル5重量%処理セリサイトを得た。この処理セリサイト80重量部とC12−C15アルキルベンゾエート(FINSOLV TN:FINETEX社)20重量部をホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散して油性分散体を得た。
[Comparative Example 1]
A sericite FSE (Sanshin Mining Co., Ltd.) was treated with a polydimerlinoleic acid dimer linoleyl 5 wt% sericite by the method described in Example 6 of JP-A-2002-128628. 80 parts by weight of this treated sericite and 20 parts by weight of C12-C15 alkyl benzoate (FINSOLV TN: FINETEX) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed with a homogenizer for 15 minutes to obtain an oily dispersion.
[比較例2](特表2001−524504号公報記載の油性分散体)
酸化チタンCR−50(石原産業(株))2重量部と、ラウリン酸ヘキシル(クロダモルHL−R:クローダジャパン(株))93重量部、ヤシ油グルコシド2.5重量部、及びポリグリセリル2―ジポリヒドロキシステアレート2.5重量部とを90℃にてホモディスパーで5分間混合分散後、ホモジナイザーで分散し室温に冷却して油性分散体を得た。
[Comparative Example 2] (Oil dispersion described in JP 2001-524504 A)
2 parts by weight of titanium oxide CR-50 (Ishihara Sangyo Co., Ltd.), 93 parts by weight of hexyl laurate (Crodamol HL-C: Croda Japan Co., Ltd.), 2.5 parts by weight of coconut oil glucoside, and polyglyceryl 2-di After mixing and dispersing 2.5 parts by weight of polyhydroxystearate with a homodisper at 90 ° C. for 5 minutes, the mixture was dispersed with a homogenizer and cooled to room temperature to obtain an oily dispersion.
[比較例3]
特開2002−188024号公報の実施例4に記載の方法で酸化鉄イエローLL−100P(チタン工業(株))を処理しイヌリンステアリン酸エステル処理黄酸化鉄を得た。この処理黄酸化鉄70重量部とN−ラウロイル−L−グルタミン酸ジフィトステリル(エルデュウPS203:味の素(株))30重量部とをホモディスパーで5分間混合分散後、サンドグラインダーを通し分散して油性分散体を得た。
[Comparative Example 3]
Iron oxide yellow LL-100P (Titanium Industry Co., Ltd.) was treated by the method described in Example 4 of JP-A-2002-188024 to obtain inulin stearate-treated yellow iron oxide. 70 parts by weight of this treated yellow iron oxide and 30 parts by weight of diphytosteryl N-lauroyl-L-glutamate (Erdu PS203: Ajinomoto Co., Inc.) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed through a sand grinder to obtain an oil dispersion. Got.
[比較例4](特開平2002−363033号公報記載の油性分散体)
ベンガラ七宝(森下弁柄工業(株))50重量部とヘキサデセンコポリマー20重量部、トリオクタノイン(TIO:日清オイリオ(株))50重量部とを練合機で練り合わせた後、3本ロールにて分散し油性分散体を得た。
[Comparative Example 4] (Oil dispersion described in JP-A-2002-363033)
Three rolls after kneading 50 parts by weight of Bengala Cloisonne (Morishita Benzari Kogyo Co., Ltd.), 20 parts by weight of hexadecene copolymer and 50 parts by weight of trioctanoin (TIO: Nissin Oilio Co., Ltd.) with a kneader. To obtain an oily dispersion.
[比較例5]
特開平05−339518号公報の実施例1に記載の方法で酸化鉄ブラックBL−100P(チタン工業(株))を処理しジメチルポリシロキサン5重量%処理黒酸化鉄を得た。この処理黒酸化鉄65重量部とステアリル変性アクリルシリコーン(KP−561P:信越化学工業(株))35重量部とを練合機で練り合わせた後3本ロールにて分散し油性分散体を得た。
[Comparative Example 5]
Iron oxide black BL-100P (Titanium Industry Co., Ltd.) was treated by the method described in Example 1 of JP-A No. 05-339518 to obtain a black iron oxide treated with 5% by weight of dimethylpolysiloxane. 65 parts by weight of this treated black iron oxide and 35 parts by weight of stearyl-modified acrylic silicone (KP-561P: Shin-Etsu Chemical Co., Ltd.) were kneaded with a kneader and then dispersed with three rolls to obtain an oily dispersion. .
[比較例6](特開2000−26262号公報の油性分散体の製造)
脂肪酸処理微粒子酸化チタン(TTO−S−4)30重量部とオクトクリレン(Eusolex OCR:MERCK社)65重量部、及びアエロゾルR812(ドイツ:Degussa社)5重量部とをホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散し油性分散体を得た。
[Comparative Example 6] (Manufacture of oil-based dispersion disclosed in JP 2000-26262 A)
30 parts by weight of fatty acid-treated fine particle titanium oxide (TTO-S-4), 65 parts by weight of octocrylene (Eusolex OCR: MERCK) and 5 parts by weight of Aerosol R812 (Germany: Degussa) are mixed and dispersed with a homodisper for 5 minutes. The oil dispersion was obtained by dispersing for 15 minutes with a homogenizer.
[比較例7]
特表2002−516602号公報の実施例16に記載の方法で微粒子酸化亜鉛(FINEX−50:堺化学工業(株))を処理しシリコーンポリマー処理10重量%処理微粒子酸化亜鉛を得た。この処理微粒子酸化亜鉛60重量部とイソヘキサデカン(パーメチル101A:PRESPERSE)40重量部とをホモディスパーで5分間混合分散後、ホモジナイザーで15分間分散し油性分散体を得た。
[Comparative Example 7]
Particulate zinc oxide (FINEX-50: Sakai Chemical Industry Co., Ltd.) was treated by the method described in Example 16 of JP-T-2002-516602 to obtain 10% by weight treated particulate zinc oxide treated with silicone polymer. 60 parts by weight of the treated fine zinc oxide and 40 parts by weight of isohexadecane (permethyl 101A: PRESPERSE) were mixed and dispersed with a homodisper for 5 minutes, and then dispersed with a homogenizer for 15 minutes to obtain an oily dispersion.
[比較例8]
特開2001−181136号公報の製造例1に記載の方法で雲母チタン(メルクジャパン(株):TIMIRON SUPER BLUE)を処理しN−オクチルトリエトキシシラン7重量%処理雲母チタンを得た。この処理雲母チタン65重量部と酢酸エチル35重量部とをホモディスパーで20分間混合分散し油性分散体を得た。
[Comparative Example 8]
Mica titanium (Merck Japan Co., Ltd .: TIMIRON SUPER BLUE) was treated by the method described in Production Example 1 of JP-A-2001-181136 to obtain 7% by weight of N-octyltriethoxysilane-treated mica titanium. 65 parts by weight of this treated mica titanium and 35 parts by weight of ethyl acetate were mixed and dispersed with a homodisper for 20 minutes to obtain an oily dispersion.
[比較例9]
特開2000−212041号公報の実施例3−1に記載の方法でエクセルマイカJP−2(三好化成株式会社)100重量部にN−パルミトイルシルクアミノ酸亜鉛5重量%被覆エクセルマイカJP−2を得た。この処理エクセルマイカJP−2を70重量部とジオクタン酸ネオペンチルグリコール30重量部とをホモディスパーで20分間混合分散し油性分散体を得た。
[Comparative Example 9]
Excelmica JP-2 coated with 5% by weight of N-palmitoyl silk amino acid zinc on 100 parts by weight of Excelmica JP-2 (Miyoshi Kasei Co., Ltd.) by the method described in Example 3-1 of JP-A-2000-212041 It was. 70 parts by weight of this treated Excel Mica JP-2 and 30 parts by weight of neopentyl glycol dioctanoate were mixed and dispersed with a homodisper for 20 minutes to obtain an oily dispersion.
上記の如く得られた本発明の酸性エステル油により被覆された表面処理粉体と親油性溶媒とを含有する油性分散体と比較例の分散体について下記の試験方法による評価を行った。結果を表1に示した。 The following test method evaluated the oil-based dispersion containing the surface-treated powder coated with the acidic ester oil of the present invention obtained as described above and the lipophilic solvent and the dispersion of the comparative example. The results are shown in Table 1.
(1)油性分散体中の粉体の粒度
各ディスパージョンをレーザー回折式粒度測定装置((株)島津製作所製「SALD−2000J」)の高濃度粒度測定装置を用いて平均粒子径(D50:μm)を測定した。
(1) Particle size of powder in oil dispersion The average particle size (D50) of each dispersion was measured using a high-concentration particle size measuring device of a laser diffraction particle size measuring device (“SALD-2000J” manufactured by Shimadzu Corporation). μm).
(2)経時での分散安定性
各ディスパージョンを50ccの透明ガラス容器に30cc採り蓋をして50℃のオーブン中に1ヶ月間放置し固液の分離状態(安定:〇、分離:×)を観察した。
(2) Dispersion stability over time Each dispersion is placed in a 50 cc transparent glass container, covered with 30 cc, and left in a 50 ° C. oven for 1 month to separate the solid and liquid (stable: ◯, separated: x) Was observed.
(3)経時での油性分散体中の粉体の粒度
上記(2)の試料を上記(1)の方法で平均粒子径(D50)を測定した。
(3) Particle size of powder in oil dispersion over time The average particle size (D50) of the sample of (2) was measured by the method of (1) above.
表1に示すように本発明の油性分散体は、従来の油性分散体(比較例1〜9)と比較して分散性と分散安定性に非常に優れている。また、表1から本発明の油性分散体では、エステル油の酸価が15以上100以下とした場合(実施例1〜5及び7)には分散性と分散安定性に特に優れている事が分かる。 As shown in Table 1, the oil dispersion of the present invention is very excellent in dispersibility and dispersion stability as compared with conventional oil dispersions (Comparative Examples 1 to 9). Moreover, in the oil-based dispersion of the present invention from Table 1, when the acid value of the ester oil is 15 or more and 100 or less (Examples 1 to 5 and 7), the dispersibility and the dispersion stability are particularly excellent. I understand.
次に本発明の油性分散体を各化粧料に配合し従来の油性分散体と比較しその効果を検証した。 Next, the oily dispersion of the present invention was blended in each cosmetic and compared with a conventional oily dispersion to verify its effect.
[実施例1](2WAYパウダーファンデーション)
表2に示す組成の2WAYパウダーファンデーションを次の方法により製造した。
[Example 1] (2WAY powder foundation)
A 2WAY powder foundation having the composition shown in Table 2 was produced by the following method.
(製法)
(1)成分1〜6を混合して均一に粉砕した。
(2)成分7〜12を均一に溶解する。
(3)上記(2)を(1)に加え粉砕しフルイに通した後プレス成型してパウダーファンデーションを得た。
(Manufacturing method)
(1) Components 1 to 6 were mixed and ground uniformly.
(2) The components 7 to 12 are uniformly dissolved.
(3) The above (2) was added to (1), pulverized, passed through a sieve, and press molded to obtain a powder foundation.
以上のようにして得られた実施例のパウダーファンデーションは、比較例のものと比較して使用感が良く化粧持ちに優れ温度変化や経時による安定性に優れたものであった。 The powder foundations of the examples obtained as described above were excellent in use feeling and excellent in makeup lasting compared with those in the comparative examples, and were excellent in temperature change and stability over time.
[実施例2](アイシャドウ)
表3に示す組成のアイシャドウを次の方法により製造した。
[Example 2] (Eyeshadow)
Eye shadows having the compositions shown in Table 3 were produced by the following method.
(製法)
(1)成分1〜6を混合して均一に粉砕した。
(2)成分7〜12を均一に溶解する。
(3)上記(2)を(1)に加え粉砕しフルイに通した後プレス成型してアイシャドウを得た。
(Manufacturing method)
(1) Components 1 to 6 were mixed and ground uniformly.
(2) The components 7 to 12 are uniformly dissolved.
(3) The above (2) was added to (1), pulverized, passed through a sieve, and press molded to obtain an eye shadow.
以上のようにして得られた実施例のアイシャドウは、比較例のものと比較して付着性が良く温度変化や経時による安定性に優れたものであった。 The eye shadows of the examples obtained as described above had better adhesion than those of the comparative examples, and were excellent in temperature change and stability over time.
[実施例3](乳化型ファンデーション)
表4に示す組成の乳化型ファンデーションを次の方法により製造した。
[Example 3] (Emulsification foundation)
An emulsified foundation having the composition shown in Table 4 was produced by the following method.
(製法)
(1)成分1〜6を混合溶解し、成分7〜11を添加して均一に分散した。
(2)成分12〜16を加熱溶解する。
(3)上記(1)で得られた成分に上記(2)で得られた成分を徐添して乳化後冷却して成分17を添加して乳化型ファンデーションを得た。
(Manufacturing method)
(1) Components 1 to 6 were mixed and dissolved, and components 7 to 11 were added and dispersed uniformly.
(2) Components 12 to 16 are dissolved by heating.
(3) The component obtained in (2) above was gradually added to the component obtained in (1) above, emulsified and cooled, and then component 17 was added to obtain an emulsified foundation.
以上のようにして得られた実施例の乳化型ファンデーションは、比較例のものと比較して発色性や使用感が良く化粧持ちに優れ温度変化や経時による安定性に優れたものであった。 The emulsified foundations of the examples obtained as described above were excellent in color development and feeling of use as compared with those of the comparative examples, had excellent makeup, and excellent in temperature change and stability over time.
[実施例4](アイライナー)
表5に示す組成のアイライナーを次の方法により製造した。
[Example 4] (Eyeliner)
An eyeliner having the composition shown in Table 5 was produced by the following method.
(製法)
(1)成分1〜5を加温混合して均一に分散した。
(2)成分6〜8を加温溶解した。
(3)上記(1)に(2)を徐添して乳化後冷却して成分9を加えアイライナー
を得た。
(Manufacturing method)
(1) Ingredients 1-5 were heated and mixed and dispersed uniformly.
(2) Components 6 to 8 were dissolved by heating.
(3) (2) was gradually added to the above (1), emulsified and cooled, and component 9 was added to obtain an eyeliner.
以上のようにして得られた実施例のアイライナーは、比較例のものと比較して付着性が良く温度変化や経時による安定性に優れたものであった。 The eyeliner of the example obtained as described above had better adhesion than that of the comparative example and was excellent in temperature change and stability over time.
[実施例5](エモリエントクリーム)
表6に示す組成のエモリエントクリームを次の方法により製造した。
[Example 5] (emollient cream)
An emollient cream having the composition shown in Table 6 was produced by the following method.
(製法)
(1)成分1〜5を混合溶解し、成分6、7を添加して均一に分散した。
(2)成分8〜11を加熱溶解した。
(3)上記(1)で得られた成分に上記(2)で得られた成分を徐添して乳化後冷却して成分12を添加してエモリエントクリームを得た。
(Manufacturing method)
(1) Components 1 to 5 were mixed and dissolved, and components 6 and 7 were added and dispersed uniformly.
(2) Components 8 to 11 were dissolved by heating.
(3) The component obtained in (2) above was gradually added to the component obtained in (1) above, emulsified and cooled, and then component 12 was added to obtain an emollient cream.
以上のようにして得られた実施例のエモリエントクリームは、比較例のものと比較して発色性と使用感が良く温度変化や経時による安定性に優れたものであった。 The emollient creams of the examples obtained as described above had good color development and usability compared to those of the comparative examples, and were excellent in temperature change and stability over time.
[実施例6](2層型サンスクリーンローション)
表7に示す組成のサンスクリーンローションを次の方法により製造した。
[Example 6] (two-layer sunscreen lotion)
Sunscreen lotions having the compositions shown in Table 7 were produced by the following method.
(製法)
(1)成分1〜5を混合溶解し、成分6、7を添加して均一に分散した。
(2)成分8〜12を加熱溶解した。
(3)上記(1)で得られた成分に上記(2)で得られた成分を徐添して乳化後冷却して成分13を加えサンスクリーンローションを得た。
(Manufacturing method)
(1) Components 1 to 5 were mixed and dissolved, and components 6 and 7 were added and dispersed uniformly.
(2) Components 8 to 12 were dissolved by heating.
(3) The component obtained in (2) above was gradually added to the component obtained in (1) above, emulsified and cooled, and then component 13 was added to obtain a sunscreen lotion.
以上のようにして得られた実施例のサンスクリーンローションは、比較例のものと比較して紫外線防止効果が高くかつ使用感が良好で温度変化や経時による安定性に優れたものであった。 The sunscreen lotion of the example obtained as described above had a higher ultraviolet ray preventing effect than the comparative example, had a good feeling of use, and was excellent in temperature change and stability over time.
[実施例7](口紅)
表8に示す組成の口紅を次の方法により製造した。
[Example 7] (lipstick)
Lipsticks having the compositions shown in Table 8 were produced by the following method.
(製法)
(1)成分1〜6と成分9.10を加熱して均一に溶解する。
(2)成分7と8を加え均一に分散した。
(3)脱気後、型に流し込みし冷却した後フレーミングをして口紅を得た。
(Manufacturing method)
(1) Components 1-6 and 9.10 are heated and dissolved uniformly.
(2) Components 7 and 8 were added and dispersed uniformly.
(3) After degassing, it was poured into a mold, cooled, and then framing to obtain a lipstick.
以上のようにして得られた実施例の口紅は、比較例のものと比較して発色性、光沢、およびすべり性が良く温度変化や経時による安定性に優れたものであった。 The lipsticks of Examples obtained as described above were excellent in color development, gloss and slipperiness as compared with those of Comparative Examples, and excellent in temperature change and stability over time.
[実施例8]
(ネイルエナメルの製造)
表9に示す組成のネイルエナメルを次の方法により製造した。
[Example 8]
(Manufacture of nail enamel)
Nail enamels having the compositions shown in Table 9 were produced by the following method.
(製法)
成分1〜9を均一に混合分散溶解した。
上記(1)に成分10を添加してネイルエナメルを得た。
(Manufacturing method)
Ingredients 1-9 were uniformly mixed, dispersed and dissolved.
Nail enamel was obtained by adding Component 10 to (1) above.
以上のようにして得られた実施例のネイルエナメルは、比較例のものと比較して光輝感に優れ温度変化や経時による安定性に優れたものであった。 The nail enamel of the example obtained as described above was excellent in glitter feeling compared to the comparative example and excellent in temperature change and stability over time.
[実施例9](アイライナー)
表10に示す組成のアイライナーを次の方法により製造した。
[Example 9] (Eyeliner)
An eyeliner having the composition shown in Table 10 was produced by the following method.
(製法)
成分3〜10を0加熱して均一に混合分散する。
上記(1)を成分1および2を加え、攪拌しながら冷却しアイライナーを得た。
(Manufacturing method)
Ingredients 3 to 10 are heated to 0 and mixed and dispersed uniformly.
Components (1) and (2) were added to the above (1) and cooled with stirring to obtain an eyeliner.
以上のようにして得られた実施例のアイライナーは、比較例のものと比較して付着性が良く温度変化や経時による安定性に優れたものであった。 The eyeliner of the example obtained as described above had better adhesion than that of the comparative example and was excellent in temperature change and stability over time.
[実施例10](洗顔フォーム)
表11に示す組成の洗顔フォームを次の方法により製造した。
[Example 10] (Face-washing foam)
Face wash foams having the compositions shown in Table 11 were produced by the following method.
(製法)
成分2〜4の成分を混合して溶解する。
上記(1)に成分1を分散する。
成分5を成分6に加熱溶解後、上記(2)に加え洗顔フォームを得た。
(Manufacturing method)
The components 2 to 4 are mixed and dissolved.
Component 1 is dispersed in (1) above.
After component 5 was dissolved in component 6 by heating, it was added to the above (2) to obtain a facial cleansing foam.
以上のようにして得られた実施例の洗顔フォームは、比較例のものと比較して使用感が良く洗浄後のつっぱり感がなく温度変化や経時による安定性に優れたものであった。 The facial cleansing foams of the examples obtained as described above were excellent in usability compared to those in the comparative examples, had no feeling of tension after washing, and were excellent in temperature change and stability over time.
[実施例11](ボディシャンプー)
表12に示す組成のボディシャンプーを次の方法により製造した。
[Example 11] (Body shampoo)
A body shampoo having the composition shown in Table 12 was produced by the following method.
(製法)
(1)成分2〜6を混合溶解する。
(2)上記(1)に成分1を加えよく混合してボディシャンプーを得た。
(Manufacturing method)
(1) Components 2 to 6 are mixed and dissolved.
(2) Component 1 was added to (1) and mixed well to obtain a body shampoo.
以上のようにして得られた実施例のボディシャンプーは、比較例のものと比較して洗浄後のつっぱり感がなく温度変化や経時による安定性に優れたものであった。
The body shampoo of the example obtained as described above was superior in stability due to temperature change and aging, without a feeling of tension after washing, as compared with the comparative example.
Claims (7)
前記酸性エステル油が、炭素数1〜36の少なくとも1種のアルコールと炭素数1〜36の少なくとも1種のカルボン酸とを反応させて得ることができる総炭素数16以上のエステル化合物を含み、且つ前記酸性エステル油の酸価が15以上であることを特徴とする油性分散体。 An oily dispersion of a powder containing a surface-treated powder coated with an acidic ester oil and a lipophilic solvent as a dispersion medium,
The acidic ester oil contains an ester compound having a total carbon number of 16 or more that can be obtained by reacting at least one alcohol having 1 to 36 carbon atoms with at least one carboxylic acid having 1 to 36 carbon atoms, And the acid value of the said acidic ester oil is 15 or more, The oil-based dispersion characterized by the above-mentioned.
炭素数1〜36の少なくとも1種のアルコールと炭素数1〜36の少なくとも1種のカルボン酸とを反応させて得ることができる、総炭素数16以上のエステル化合物を含み、且つ酸価が15以上である酸性エステル油と、
親油性溶媒とを含むことを特徴とする粉体の油性分散体。 At least one powder;
It contains an ester compound having a total carbon number of 16 or more, which is obtained by reacting at least one alcohol having 1 to 36 carbon atoms with at least one carboxylic acid having 1 to 36 carbon atoms, and has an acid value of 15 Acidic ester oil that is above,
An oily dispersion of powder comprising a lipophilic solvent.
A cosmetic comprising 0.1 to 100% by weight of the oily dispersion according to any one of claims 1 to 6.
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JP2009263213A (en) * | 2008-04-03 | 2009-11-12 | Shin Etsu Chem Co Ltd | Powder surface-treated with organopolysiloxane having carboxy group, dispersion of the same, and cosmetic comprising the same |
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JP2007161648A (en) * | 2005-12-14 | 2007-06-28 | Shiseido Co Ltd | Micro-particle zinc oxide dispersion and cosmetic comprising the same |
JP2007191684A (en) * | 2005-12-21 | 2007-08-02 | Kao Corp | Antistatic agent for coating resin |
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JP2008120813A (en) * | 2006-11-13 | 2008-05-29 | L'oreal Sa | Powder compact composition |
JP2009263213A (en) * | 2008-04-03 | 2009-11-12 | Shin Etsu Chem Co Ltd | Powder surface-treated with organopolysiloxane having carboxy group, dispersion of the same, and cosmetic comprising the same |
US9023969B2 (en) | 2008-04-03 | 2015-05-05 | Shin-Etsu Chemical Co., Ltd. | Powder surface-treated with an organopolysiloxane having carboxyl groups, a dispersion of the same, and a cosmetic comprising the same |
JP2009275211A (en) * | 2008-04-18 | 2009-11-26 | Riso Kagaku Corp | Non aqueous pigment ink |
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