JP2005132691A - Ceramic-made tray - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a ceramic-made tray which can prevent deformation and breakage by enhancing soaking with small temperature fluctuation of the tray, and excellent in heat resistance. <P>SOLUTION: This tray is one for setting an insulator in the heating process of manufacturing a spark plug, and the tray is made of a ceramic sintered material which has a thermal conductivity at ambient temperature of not smaller than 30 W/(m×K). The ceramic sintered material has four-point bending strength at ambient temperature of not smaller than 600 MPa, Young's modulus of not smaller than 200 GPa, and relative density of not smaller than 97%. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a tray used for setting an insulator in a heating process in manufacturing a spark plug.

  As a spark plug for an internal combustion engine, a spark plug that generates a spark between a center electrode and a ground electrode and has an electric resistance portion between the stem and the center electrode is used. This spark plug manufacturing method is described in, for example, Patent Document 1 and Patent Document 2. In other words, a ceramic insulator is filled with a powdered resistance material, and a plurality of insulators filled with the resistance material are set on a tray. And a tray is conveyed in a continuous furnace and an insulator is heated. Thereafter, the insulator is taken out from the furnace, the stem is pressed at a temperature lower than the heating temperature in a state where the insulator is set on the tray, the stem is pushed into the insulator, and then the housing is fixed to the insulator.

  In Patent Document 1, a terminal fitting is fixed to one end side of a through hole formed in the axial direction of an insulator, and a center electrode is fixed to the other end side. A spark plug manufacturing method in which a sintered conductive material portion mainly composed of a mixture of glass and a conductive material is formed between a terminal fitting and a center electrode in a hole to electrically connect them. A terminal fitting is disposed on one end side of the through hole of the insulator, and a center electrode is disposed on the other end side, and the terminal fitting and the center electrode are disposed in the through hole. The assembly manufacturing process for manufacturing the assembly in which the packed layer of the raw material powder of the sintered conductive material part is formed, and the packed layer of the raw material powder starts to soften from the center electrode side in the axial direction of the insulator Heating process for heating the assembly, and so on For the heated assembly, the position of the center electrode with respect to the through hole is fixed, and the terminal fitting is pressed in a direction approaching the center electrode in the axial direction of the through hole, whereby the packed layer of the raw material powder in the through hole is formed. A spark plug manufacturing method including a pressing step of pressing between a center electrode and a terminal fitting is described.

  3 and 5 of Patent Document 1 are rectangular plate-like materials made of ceramics or metal, and a plurality of assembly holding through holes are formed in a matrix shape. A setter that is held in a standing state is described.

  Patent Document 2 discloses a spark plug manufacturing method in which a spark is generated between a center electrode and a ground electrode, and a terminal portion has an electric resistance portion between the stem and the center electrode, the center electrode and the stem A resistor filling step of filling a powdered resistance material into the insulator, a heating step of heating a plurality of insulators filled with the resistor in a furnace, and a plurality of insulators after the heating step A spark plug manufacturing method including a step of pushing a plurality of insulators out of a furnace and pushing a stem into the insulator so as to be cooled substantially uniformly is described.

  FIG. 3 of Patent Document 2 describes a metal tray equipped with a plurality of insulators filled with a resistance material.

JP-A-11-251033 JP 2002-1981156 A

  Conventionally, a tray made of heat-resistant steel such as SCH21 material has been widely used as a tray (also called a setter) for setting an insulator in a heating process when manufacturing a spark plug. However, since the heat-resistant steel tray has a low thermal conductivity of about 17 W / (m · K), when the insulator is heated in a continuous furnace, the temperature of the tray itself varies, and the insulator can be heated uniformly. There was a problem that became difficult and adversely affected the quality of the plug. In addition, since heat-resistant steel has a large heat capacity, it takes a long time until the insulator is soaked, resulting in a disadvantage that the heat treatment cycle is extended.

  In addition, the heat-resistant steel tray is easily deformed by repeated heat cycles, and there is a problem that oxide scale is generated on the tray surface. Furthermore, there is a drawback that the specific gravity is large and the weight is bulky and the workability is inferior.

  On the other hand, as described in Patent Document 1, a ceramic tray is also disclosed. However, the conventional ceramic tray has a problem that the temperature of the tray itself varies and is inferior in heat uniformity, and deformation or breakage occurs due to press pressurizing the stem into the insulator.

  Accordingly, an object of the present invention is to provide a ceramic tray excellent in heat resistance that prevents deformation and breakage, and has improved heat uniformity with little variation in temperature of the tray itself.

  That is, the ceramic tray of the present invention is a tray used for setting an insulator in a heating process when manufacturing a spark plug, and the tray is formed of a ceramic sintered body. The thermal conductivity is 30 W / (m · K) or more.

  In the present invention, the ceramic sintered body has a four-point bending strength at room temperature of 600 MPa or more. The ceramic sintered body has a Young's modulus of 200 GPa or more. Moreover, the relative density of the ceramic sintered body is 97% or more. The ceramic sintered body is a silicon nitride ceramic sintered body.

  In the present invention, by forming the tray with ceramics, it has excellent heat resistance, can be about half the weight of heat resistant steel, and can prevent deformation due to repeated thermal cycles. The greatest feature of the present invention is that by increasing the thermal conductivity of the ceramic itself to 30 W / (m · K) or more, the temperature variation of the tray conveyed into the heating furnace is reduced, and the insulator is heated uniformly. Product quality can be improved. Further, by increasing the thermal conductivity, the rate of temperature rise can be increased, the heat treatment cycle can be shortened, the production efficiency can be increased, and energy saving can be achieved. The thermal conductivity of the ceramic is more preferably 50 W / (m · K) or more.

  The ceramic sintered body has a 4-point bending strength at room temperature of 600 MPa or more (more preferably a 4-point bending strength of 800 MPa or more) and a Young's modulus of 200 GPa or more (more preferably a Young's modulus of 280 GPa or more). Can be prevented from being deformed or broken against press-pressing. Moreover, in order to fully exhibit the mechanical characteristics of ceramics, it is necessary to be a dense sintered body, and the relative density is desirably 97% or more. More desirably, the relative density is 99% or more.

  Examples of the ceramic include silicon nitride, alumina, and silicon carbide. Among them, silicon nitride is preferable because of high toughness and excellent high-temperature characteristics. In the case of a silicon nitride sintered body, the thermal conductivity can reach 30 W / (m · K) by controlling the content. Preferably, by reducing the contents of aluminum and oxygen present as impurities in the sintered body, that is, the aluminum content in the sintered body is 0.2% by weight or less and the oxygen content is 5.0% by weight. By setting it as% or less, the thermal conductivity at room temperature can be improved.

  FIG. 1 shows an example of a ceramic tray of the present invention. 1A is a plan view, and FIG. 1B is a longitudinal sectional view. In FIG. 1, a ceramic tray 1 has a rectangular plate shape, and a plurality of through holes 2 into which an insulator 3 is inserted and mounted are perforated. After a plurality of insulators 3 are inserted and set in the through holes 2 of the tray 1, the tray 1 is conveyed into a continuous furnace and the insulator 3 is heated.

  The ceramic tray of the present invention was produced as follows. First, as a sintering aid, 3.0% by weight of magnesium oxide powder having an average particle size of 0.2 μm, 3.0% by weight of yttrium oxide powder having an average particle size of 0.3 μm, and silicon nitride powder having an average particle size of 0.5 μm Then, an appropriate amount of a dispersant was added, and the mixture was pulverized and mixed in ethanol. Next, after vacuum drying, the mixture was granulated through a sieve, filled in a rubber mold, and then subjected to cold isostatic pressing (CIP) with hydrostatic pressure to produce a molded body. This formed body was fired for a predetermined time in a nitrogen gas atmosphere at 1700 to 2000 ° C. to obtain a ceramic tray made of a silicon nitride ceramic sintered body.

  Further, from the silicon nitride ceramic sintered body of the present invention, a test piece for measuring thermal conductivity and density having a diameter of 10 mm × thickness of 3 mm, a four-point bending test piece of length 3 mm × width 4 mm × length 40 mm, 12 mm × A test piece for measuring Young's modulus of 1 mm × 60 mm was collected. The thermal conductivity was calculated by measuring the specific heat and thermal diffusivity at room temperature in accordance with the laser flash method JIS R1611. For the density, the true density of the silicon nitride sintered body was determined from the blend composition by the Archimedes method, and the relative density was determined by dividing the measured value by the true density. The 4-point bending strength was measured according to JIS R1601 at room temperature. Young's modulus was measured by a strain gauge method at a test speed of 1 mm / min.

  The silicon nitride sintered body forming the ceramic tray of the present invention has a thermal conductivity of 65 W / (m · K) at room temperature, a 4-point bending strength at room temperature of 900 MPa, a relative density of 99.6%, and a Young's modulus. It was 290 GPa or more. The aluminum content in the sintered silicon nitride was 0.02% by weight, and the oxygen content was 0.5% by weight.

  Using a tray made of a silicon nitride sintered body as an example of the present invention and a tray made of heat-resistant steel of SCH 21 as a comparative example, the temperature change with respect to the elapsed time when both trays were charged into a heating furnace was examined. The result is shown in FIG. After the silicon nitride tray was transported to the heating furnace, the entire tray reached a soaking temperature in 16 minutes, whereas the heat resistant steel required heating for 22 minutes.

  According to the ceramic tray of the present invention, since it has a high thermal conductivity, it can solve the problems in conventional heat-resistant steel, and further improve the product quality and the production efficiency by shortening the heat treatment cycle time. Can measure.

An example of the ceramic tray of the present invention is shown. The temperature change with respect to the elapsed time at the time of charging a tray into a heating furnace is shown.

Explanation of symbols

  1 tray, 2 through-holes, 3 insulators

Claims (5)

A tray used for setting an insulator in a heating process when manufacturing a spark plug, the tray being formed of a ceramic sintered body, and the thermal conductivity of the ceramic sintered body at room temperature being 30 W / (m · K). A ceramic tray characterized by the above. 2. The ceramic tray according to claim 1, wherein the ceramic sintered body has a four-point bending strength at room temperature of 600 MPa or more. The ceramic tray according to claim 1 or 2, wherein the ceramic sintered body has a Young's modulus of 200 GPa or more. The ceramic tray according to any one of claims 1 to 3, wherein a relative density of the ceramic sintered body is 97% or more. 5. The ceramic tray according to claim 1, wherein the ceramic sintered body is a silicon nitride ceramic sintered body.