JP2005097069A - Cold hydraulic treating material, effective utilization method for treating material, modified article modified with treating material, and inorganic formed article worked and prepared by treating material - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cold hydraulic treating material which is free from pollution and has secured shelf life and to provide an effective utilization method for the treating material. <P>SOLUTION: The treating material is prepared by adding active silica, a sulfate and an aid composition (phosphate composition, barium salt composition, or the like) into inactive calcia glass and forming the mixture into one pack. The modified or treated material and a formed article are obtained by a process for mixing a single material comprising the treating material or a one prepared by combining the treating material with an objective base material (sand particle body, hydrated soil, a contaminated base material, or the like) with a water based active agent and a working process comprising, if need, a process for forming and an aging process. The active silica is an alkali silanol base material expressed by formula (1) [ in formula (1), M is hydrogen, Na or K], and the sulfate is a sulfate-containing compound containing an oxyacid salt compound expressed by formula (2) [in formula (2), M is an alkali metal, Z is an alkaline earth metal and R is Al or 3-valent iron]. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention adds an active silica having water-soluble sodium and an alkali silanol group and a sulfate having a sulfate group to an inert calcium glass prepared by giving a heat history to a mixed raw material prepared in advance. 3 essential ingredients, and 4 ingredients with auxiliary composition added if necessary, are energy-saving, non-polluting and one-packed, ensuring shelf life, hydraulic reaction, The present invention relates to a “processing material” technical field that exhibits a processing body or a cured body / processing material body forming function for a target material by processing.

  Furthermore, the present invention relates to a single material made of a treatment material or a target material [sand particles, fillers, hydrous soils, contaminated materials, adsorbent powders, heat resistant powders, alkali silicate materials, galactor aggregates. To the composite material that combines the body and the like] with the coexistence of the water-based active agent to make a mixture, the processing step to use the mixture as a molded product as necessary, and then the water in the mixture or molded product Through a series of energy-saving work steps consisting of a curing process that completes the hard reaction, the water-resistant, heat-resistant, water-eluted pH is modified to a modified product with a pH of less than 12, or processed into an inorganic product. Related to “Technology for Utilization of Treatment Materials”.

  Furthermore, in addition to the treatment / curing function of the treatment material, the present invention has a special functionality of the treatment material [water elution prevention ability of nitrogen components, insolubility / fixation ability of heavy metals, capture / resolution of dioxins, Introducing the soluble chlorine component insolubility and immobilization ability, etc.], and subjecting the problem to the target material to a low-load type by subjecting it to a series of work processes in which the water-based activator coexists with the target material having the problem The present invention relates to the technical field of “reformed products” that have been modified in

  Furthermore, the present invention uses a single material or a composite material as a treatment material, and a series of work steps in which a water-based active agent is allowed to coexist, so that the target material is a structure, a composite cured body, a granule, an aggregate body. It has been processed and prepared into molded bodies consisting of adhering bodies, films, hydrous soil treated bodies, non-polluted products, consolidated adsorbents, heat insulating / heat insulating / heat resistant materials, acid resistant materials or integrated materials, etc. The present invention relates to the technical field of “inorganic molded products” in which the inorganic molded product is water and heat resistant and has a low alkalinity with a water elution pH of less than 12.

  In the technical field of the background art related to the present invention, materials such as a solidifying material, a curing agent, a processing material, a binder, and a processing material that exhibit hydraulic properties at room temperature, and a function that demonstrates the functionality of these materials are used. Examples include modified products of various materials, and inorganic molded products prepared by secondary processing by utilizing and processing these materials.

  Conventionally, the following six types of materials can be cited as representative techniques disclosed as inorganic hydraulic materials that exhibit functions such as formation of a cured product and adhesion by exhibiting hydraulic properties at room temperature. Among them, cement-based solidifying materials and water glass-based curing materials have been widely used.

1. A cementing material based on the hydration reaction of hydraulic minerals, mainly calcium salts, which have a proven track record as plaster and cement.
2. Plaster material by hydration reaction of calcium sulfate that has been partially dehydrated and has a proven track record in sculpture and dental molds.
3. An alumina sol material comprising a binding aluminazo formed by neutralizing an aluminum sulfate of a sulfuric acid band such as a water treatment agent with an alkali.
4). Light burned magnesia material that demonstrates the hydraulic binding ability of light burned magnesia and the hardening action of phosphate components such as fertilizers in fields such as agricultural civil engineering.
5). Silica-based treatment material that is cured by polymerizing silanol groups generated by acid neutralization of alkali silicates to form siloxane bonds.
6). Silanol-based material in which sodium silanol groups are polymerized with calcium and alkali produced as a by-product is fixed with zeolites.

  The prior art has the following problems. Secondary products processed using cement and lime cementing materials, which are currently most widely used, exhibit strong alkalinity of pH 12 or higher, especially when the products come into contact with the aquatic environment. It releases alkaline components that have an impact on the environment and induces secondary pollution caused by alkali.

  Moreover, since the cementing material processes an alkaline component with high heat in the manufacturing process, it has a problem that occurs in the manufacturing process. That is, in the cement manufacturing process, it is essential to adopt “magcro brick” as a heat-resistant brick that can withstand the alkali that is a component of the cement material at a high temperature. As a result, coexistence of harmful hexavalent chromium is unavoidable in cement products, and environmentally harmful hexavalent chromium is eluted and diffused from cement secondary products made from cement containing hexavalent chromium. However, it has become a problem [reference: former notification from the Ministry of International Trade and Industry (March 24, 2000)] because it contaminates the living environment.

  Furthermore, in cement production, a high-temperature (about 1400 ° C) treatment process is essential, and this high temperature requires precious energy waste, and the associated fear of global warming due to the release of carbon dioxide can be avoided. Absent. In addition, the hydraulic hardening mechanism in the formation of a solidified body by cement is based on the formation of hydrates, and heat resistance cannot be expected from the formed matrix. Furthermore, since the solidified body made of cement is basically a calcium salt, it does not have the ability to withstand acidity such as acid rain, and its range of use is naturally limited. Of course, it is said that it is not preferable to contain a sodium component fundamentally in cement.

  Furthermore, Portland cement forms a concrete structure by kneading and curing together with various aggregates. When organic components such as saccharides and phosphate components coexist in the aggregates, etc., these saccharides etc. The organic component and phosphoric acid component of the cement are first consumed by the calcium salt, which is a hydrating mineral of cement, making it difficult to ensure the strength of the concrete product that is formed. There is a tendency not to get.

  Furthermore, Portland cement has been adopted and used in the civil engineering field as a binding modifier for mud mud, sludge, soft soil, hydrous mud of volcanic ash clay, and the like. However, when trying to solidify hydrous mud such as mud mud, sludge, soft soil, and volcanic ash clay composed of fine particles with cement, the soil particle size of the fine particles is finer than the cement particle size, Fine soil particles surround the cement particles, and it is impossible to expect the formation of a good binder / solidified body by inhibiting the cement hardening mechanism.

  A typical example of the plaster material is calcined gypsum, which is a hemihydrate gypsum obtained by partially dehydrating dihydrate calcium sulfate. Since calcined gypsum forms a solidified body by a hydration reaction, it has been used as an easier and more solidified material than in the past. However, when water is added to calcined gypsum to form hydrated gypsum, large shrinkage occurs during formation of a solidified body of hydrated gypsum, and a high-strength binder / solidified body cannot be expected. Moreover, with gypsum, acid-resistant and heat-resistant cured bodies cannot be obtained, and their uses are naturally limited.

  As an alumina sol material, a binder effect of an alumina sol produced when an acidic compound such as aluminum sulfate is neutralized with an alkaline compound is expected. However, since the neutralization reaction proceeds very quickly, it is difficult to control the neutralization reaction of the sol formation in accordance with the actual construction work conditions. It becomes difficult, and it is far from the practical use of on-site construction.

  The light-fired magnesium material is made from fired magnesium oxide, and since the solidified product formed is low alkali, it is used as a low-alkaline binder / solidified material forming material. Specifically, it has been used in agricultural civil engineering that dislikes alkali generated from concrete. However, light-burned magnesia material is expensive because the raw material magnesia is expensive, and it is highly versatile because it increases construction costs for a wide range of applications such as agriculture, fisheries, and civil engineering where low prices are required. It is scarce and uncommon and has been adopted limited to applications in special fields.

  The silica-based treatment material is based on a liquid alkali silicate having a silanol group typified by water glass, and a predetermined amount of a curing agent such as an acidic compound is added to the main agent to form a polysiloxane bond [-Si-O-Si. -] The result which produced | generated n and produced | generated the hardening body is shown. In particular, silica-based treatment materials have long been used as binders in the fields of construction and civil engineering, and in the fields of adhesives and coating agents. In addition, it has been widely used for a long time as a raw material for producing silica gel and as a solidified body requiring acid resistance and heat resistance.

  However, since the silica-based treatment material using alkali silicate as a raw material is based on the combined use of alkali silicate and an acidic curing agent, various problems remain. For example, the workability on site and the expression balance of various physical properties of the produced solidified body are poor, and if work time is secured with emphasis on workability, it takes a long time to develop various physical properties of the produced solidified body, There is a tendency to worsen the construction and workability that expects the completion of various physical properties in a short period of time.

  In the silica-based treatment material using these alkali silicates as a raw material, the solidified product formed by being subjected to normal temperature construction generally tends to leave a water-soluble alkali salt as a by-product in the produced solidified product, When water comes into contact with the resulting solidified product, this by-product alkali salt dissolves again in water and dissolves the generated silica component, making it difficult to secure a water-resistant solidified product, especially outdoors. Not suitable for use in etc.

In addition, the water-soluble alkali salt remaining in the produced solidified body reacts with moisture and carbon dioxide in the air to generate alkali carbonate, and the white powder is blown on the solidified body surface due to the so-called white flower phenomenon. Cause.
From the problems described above, the silica-based treatment material is a substantially unsolved problem, and product troubles caused by these problems have not been solved.

  As a silanol-based material obtained by improving a silica-based treatment material, the present inventors have disclosed various patent application technologies (Japanese Patent Publication No. 53-24212, Japanese Patent Publication No. 53-109558, Japanese Patent Publication No. 57-42581, Japanese Patent Publication No. 53). No. 24206, No. 58-58306, No. 1-53230, No. 2-1791, No. 2-56299, etc.). Moreover, the technique which uses the specified water glass composition as a processing material using the sustained release characteristic of the phosphoric acid content which silicon phosphate has is also disclosed.

  In addition, the prior patent application technology of the present inventors (Japanese Patent Laid-Open No. 11-246261) includes a water-soluble powdery alkali silicate and a barium salt having a barium ion soluble in an alkaline solution, and a slow addition of phosphate ions. Reduced volume of industrial waste such as low-level radioactive waste from powdered one-pack alkali silicate composition consisting of four components not containing calcium components of powdered silicon phosphate and aluminum hydroxide A technique for treating a solidified material is disclosed.

  Further, the inventors of the present invention applied a silica-alkali composition and an aluminate composition in water in the prior patent application technology (Japanese Patent Application No. 11-263661, which prioritized Japanese Patent Application No. 10-004811). A wet fluid hydraulic silica-based binder is disclosed.

  Furthermore, the inventors of the prior application patent application technology (Japanese Patent Application Laid-Open No. 2002-128550) is composed of a silicate-based material, a calcium composition and an alkaline composition and an aqueous composition, An alkaline curing agent that is not a powdery one-pack product is disclosed. Furthermore, the present inventors have a patent application technology (Japanese Patent Application No. 2001-083816) comprising four members: a sulfur oxyacid salt composition, an alkali composition, a calcium composition, and an aqueous composition. A room temperature hydraulic solidified material that is not a one-pack product of powder is disclosed.

  Furthermore, the present inventors have disclosed in a patent application technology (Japanese Patent Application No. 2001-234183) a powdery one-pack composite composition comprising a calcium composition, an aluminum sulfate composition and an aluminum phosphate composition. A modified material is disclosed. However, the improved treatment material disclosed herein is a mixture of an active alkali component and an acidic component, and is a special means that takes into account the storage stability (shelf life) of a one-pack product when one-pack is used. Moreover, no device has been devised, and product deterioration that occurs during storage and storage until the one-pack product is used is inevitable.

  Furthermore, the inventors of the prior patent application technology (Japanese Patent Application No. 2001-339994) added calcined etc. to volcanic ash containing sulfur oxide in response to heat history, and heat-treated at 800 ° C. or lower in advance. An activated silicate obtained by adding sodium hydroxide to a calcium-silica composition that has been prepared once but has not been subjected to a sufficient deactivation treatment to ensure shelf life A method for producing a hydraulic solidified material as a component is disclosed.

  Furthermore, the inventors of the prior application patent application technology (Japanese Patent Application No. 2002-238623) disclosed that active silica having silanol groups, reactive alumina, sodium hydroxide, and calcium composition as a fixing material for heavy metals. A powdery one-pack composite composition comprising four members is disclosed. However, in the powdery one-pack composite composition of the present disclosure, no special means and contrivance have been made in consideration of the storage stability (shelf life) of the product.

  In the above-mentioned prior arts of the present inventors, the silanol group of activated silica is condensed to form a siloxane bond [—Si—O—Si—] n to be polymerized, and at this time free It is disclosed that a stable hardened body is formed by fixing sodium and contained heavy metals, and that an active calcium salt forms a hydratable mineral. There is no technical disclosure regarding a [treatment material] such as a solidified material having a device for coexisting and exhibiting both shelf life and functionality.

  Moreover, in the silanol-based material of the prior application technology, essential components that fulfill the hydraulic function are blended in accordance with the intended use, but these powdery essential components are prepared into a powdery composite composition in one pack. In addition, there is no special means or ingenuity for ensuring storage stability and exhibiting shelf life, and [treated materials] such as solidified materials have stable shelf life and hydraulic reaction. There is no disclosure of a material technology that exhibits a processing function and that also exhibits functions such as forming a solidified body with low alkalinity and immobilizing heavy metals.

  The problem to be solved by the present invention is the problem that has been held by conventionally used hydraulic solidification materials. Specifically, cement contains harmful hexavalent chromium, and processed cement products have secondary pollution caused by released alkali. Processed products with water glass have no water resistance and are not practical in nature. Furthermore, it can be mentioned that the product of hydraulic solidification material, which is the prior application technique of the present inventors, lacks shelf life and shelf life.

Further, specific problems to be solved by the present invention include the following items.
(1) Pollution-free solidification material that replaces cement and does not cause chromium contamination in living environment (2) Lowers the pH value of cement solidified material and suppresses secondary pollution to the environment (3) Organic and phosphoric acid-containing materials (4) Ensure storage stability (shelf life) of processing materials and obtain quality assurance reliability (5) Generate and solidify with inexpensive materials and easy construction workability Ensure strength of the body (6) It is a pollution-free solidified material manufactured in a process with a low environmental impact.

  The problem to be addressed by the present invention is that related products in the prior art lacked sufficient consideration and handling of environmental problems and depleted resources. For example, in the prior art, many products are manufactured at a high temperature that consumes a lot of energy and releases a large amount of carbon dioxide to the environment in the manufacturing process of the product, and in cement products, harmful chromium elements are diffused into the environment. The fact that it is contaminated and no measures are taken against the alkali component eluted from the solidified product can be mentioned.

  According to the present invention, it is composed of a powdery powder of three essential components of a calcia glass prepared from a mixed raw material prepared in advance, an active silica having an alkali silanol group, and a sulfate having a sulfate group. In the treated material;

  The mixed raw material is composed of a mixed raw material consisting of a single material or a combination of two or more selected from the group consisting of a silicate composition, a calcium composition and an alumina composition, and the basic ratio of the composition components of the mixed raw material However, at least 10 to 100 parts by weight of alumina and 50 to 350 parts by weight of alumina and, if necessary, 1 to 100 parts by weight of sodium oxide, with respect to 100 parts by weight of silica expressed on an oxide basis. And;

  The above-mentioned calcare glass is a calcined glass powder obtained by pulverizing and classifying the heat-treated product obtained by heat-treating the above mixed raw material at least at 820 ° C. into fine particles passing through a 100 mesh sieve, and the water elution pH of the heat-treated product powder Is an inert powder showing less than 12;

［式中；Ｍは水素、ナトリウムもしくはカリウム元素］で表されるアルカリシラノール基と水溶解性ナトリウムを保有しているケイ酸アルカリを主成分とする単一素材、もしくはシラノール基保有のケイ酸化合物とナトリウム塩化合物とが共存している複合素材からなる活性粉状体であり；The above active silica has the following composition formula (1)

[In the formula, M is an element of hydrogen, sodium or potassium] A single material mainly composed of alkali silicate having an alkali silanol group and water-soluble sodium, or a silicic acid compound having silanol group Active powder consisting of a composite material in which a sodium salt compound and a sodium salt compound coexist;

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒはアルミニウムまたは３価の鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金属元素のオキシ酸塩化合物の塩基性塩ないしは正塩群より選ばれる単独ないし２種以上の組み合わせからなる硫酸根含有化合物または組成物類の粉状体であり；The above sulfate has the following composition formula (2)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. A basic salt of a metal element oxyacid salt compound represented by the formula: or a sulfate group-containing compound or a powder of a composition comprising a combination of two or more selected from the group of normal salts Is;

  The above-mentioned one-pack formation is performed by adding 5 to 100 parts by mass of active silica and 3 to 140 parts by mass of sulfate with respect to 100 parts by mass of inert calcium glass having a particle size of 100 μm or less, preferably 50 μm or less. It is made into one pack by mixing the essential 3 components added in a quantity ratio uniformly;

  The above-mentioned treatment material provides a treatment material that ensures the shelf life by making the essential three components into one pack, and exhibits a treatment / curing / binding function for the target material by a normal temperature hydraulic reaction.

  According to the present invention, the treatment material composed of the three essential components of the inert calcium glass, active silica, and sulfate is further composed of four components including an auxiliary composition and is made into one pack. In the treated material;

  The above auxiliary composition is a crystal seed composition, sodium supplement composition, calcium supplement composition, sulfate radical supplement composition, reinforcing material composition, phosphate radical composition, barium salt composition, iron salt supplement composition, addition A composition comprising a single material or a combination of two or more selected from the group consisting of a raw material composition, a dispersion medium composition, a carrier composition and a functional composition, and the composition is a powder or spherical powder Powder, fibrous powder, flaky powder or sandy powder;

The above-mentioned one-pack is added to the essential three battles of 50 to 100 parts by weight of active active silica and 3 to 140 parts by weight of sulfate for 100 parts by weight of inert calcium glass, and further supplementary composition 4 components added in an amount of 1 to 300 parts by mass are uniformly mixed into one pack;
The above-mentioned treatment material is a one-pack of 4 components added to the essential 3 components of the treatment material to ensure shelf life, and exhibits treatment / curing function for the target material by room temperature hydraulic reaction A treatment material is provided.

  According to the present invention, the silicate composition comprises 45 to 80% by mass of silica, 5 to 35% by mass of alumina, 0.1 to 25% by mass of iron oxide, Selected from the group of lamellar clay minerals containing 0.5 to 25% by mass of metal [Mg or Ca], silicates, alkali silicates, hydrous earths, thermal history and waste silicates The treatment material according to claim 1 or 2, wherein the treatment material is a silicate composition mainly composed of a silicate composed of one kind or a combination of two or more kinds.

  According to the present invention, the layered clay mineral is selected from the group consisting of allophane, hysinger gel, pyroferrite, talc, mica, montmorillonite stone group, vermiculite, ryokdeite group, kaolinite and inosilicate. The treatment material according to claim 3, which is a layered clay mineral of ferrosilicate composed of a combination of at least species.

  According to the present invention, the silicate is a natural or synthetic silicate compound, wollastonite, zonotolite or tobermorite calcium silicate or magnesium silicate, quartzite, quartz, cristobalite, opalite, feldspar, The treatment material according to claim 3, which is a single or two or more combined silicate compounds selected from the group of rock minerals such as zeolite, granite, metamorphic rock, rhyolite, conglomerate, and mordenite. .

［式中：Ｍはナトリウムないしカリウム元素、ａは０．１ないし４の数、ｗは１６ないし５０の数］で表されるケイ酸アルカリの群より選ばれる単独ないし２種以上の組み合わせからなるケイ酸アルカリである請求項３項記載の処理材。According to the present invention, the alkali silicate has the following composition formula (3):

[Wherein, M is an element of sodium or potassium, a is a number of 0.1 to 4, and w is a number of 16 to 50] alone or in combination of two or more selected from the group of alkali silicates The treatment material according to claim 3, which is an alkali silicate.

  According to the present invention, the hydrous soils are the construction site ground and by-product soils, low-grade soils deposited in the sea, lakes, swamps, rivers and dams, hydrous clayey soils, mud mud soils, organic soils A treatment material comprising a single or a combination of two or more selected from the group of weathered rock, soft ground soil, viscous / sandy soil, and sewage sludge is a hydrous soil having a water content of at least 25% by mass. The

  According to the present invention, the thermal history material is incinerated ash of wastes mainly composed of silicate, carbonized ash, coal ash, fly ash, blast furnace, steelmaking slug, volcanic ash and lava volcanic ejecta. There is provided a treatment material which is a silicate compound which has been subjected to a heat treatment history and is composed of a single or a combination of two or more selected from the group of emissions from the ceramic industry and silicate glass.

  According to the present invention, the waste silicate is an oil-containing waste clay whose content of silicic acid is not less than 50% by mass represented by oxide standards, drained purified water cake during water purification, waste material for ceramic industry Composed of single or a combination of two or more selected from the group of ceramic inorganic waste products, residual soil or waste from construction and civil engineering industries, and silica-based waste discharged from the chemical industry. Treatment materials that are silicate compounds are provided.

  According to the present invention, the above-mentioned calcite composition comprises a calcite composition, a calcium salt composition, a waste composition, a cement composition, and a charcoal cal-modified composition containing at least 25% by mass or more of calcium oxide. A treatment material is provided that is a calcium composition comprising a single or a combination of two or more selected from the group.

［式中；ｗは零を含む２以下の数］で表される酸化カルシウムまたは水酸化カルシウムの群より選ばれる単独ないし２種以上の組み合わせからなるカルシヤ成分を酸化カルシウムで表して５０質量％以上含有しているカルシウム化合物である処理材が提供される。According to the present invention, the above-mentioned cashmere composition has the following composition formula (4):

[Wherein w is a number of 2 or less including zero] represented by calcium oxide, a calcium component consisting of a single or combination of two or more selected from the group of calcium oxide or calcium hydroxide represented by 50% by mass or more A treatment material that is a calcium compound is provided.

［式中；Ｔはアルミニウム、ケイ素、窒素、リン、炭素元素群の単独ないし２種以上の組み合わせの元素、Ｘはハロゲン元素、ａ、ｂ、ｃは零を含む１０以下の数、ｍは０．５ないし６の数、ｗは零を含む２８以下の数］で表されるカルシウムのオキシ酸塩化合物の正塩または塩基性塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなるカルシウム化合物をＣａＯ酸化物基準で少なくとも３０質量％含有しているカルシウム塩化合物である処理材が提供される。According to the present invention, the calcium salt composition has the following composition formula (5):

[Wherein, T is an element of an aluminum, silicon, nitrogen, phosphorus, or carbon element group alone or a combination of two or more, X is a halogen element, a, b, and c are numbers of 10 or less including zero, and m is 0 Calcium comprising a single or a combination of two or more selected from the group of normal salts or basic salt compounds of calcium oxyacid salt compounds represented by the number of .5 to 6 and w is a number of 28 or less including zero]] A treatment material is provided which is a calcium salt compound containing at least 30% by mass of the compound based on CaO oxide.

  The above-mentioned waste composition is mainly composed of a calcium salt compound consisting of lime neutralized sludge, waste gypsum, blast furnace and steelmaking slag, or a combination of two or more kinds selected from the group of waste calcium silicate. The processing material which is the wastes to be provided is provided.

  According to the present invention, the cement composition comprises Portland cement, mixed cement (blast furnace cement, silica cement, fly ash cement, etc.), special cement (white cement, alumina cement, super fast cement, colloidal cement, oil well cement). , Geothermal cement, swollen cement), or a treatment material that is a hydraulic cement mineral composed of a single or a combination of two or more.

  According to the present invention, the charcoal cal-modified composition comprises hydrochloric acid, sulfuric acid, sulfurous acid, nitric acid, nitrous acid, silicic acid, aluminosilicic acid, and aluminium with respect to 100 parts by mass of calcium carbonates mainly composed of calcium carbonate. A treatment material which is a carbonized cal-modified composition decarboxylated by adding 50 parts by mass of an acid group consisting of a single or a combination of two or more selected from the group consisting of acid, boric acid and phosphoric acid, and heat-treating at 980 ° C. or lower. Is provided.

「式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、ａは零を含む５以下の数、ｂは零を含む５以下の数、ｗは零を含む９以下の数］で表されるアルカリ金属またはアルカリ土類金属のアルミン酸塩もしくは水酸化アルミの群より選ばれる単独ないし２種以上の組み合わせからなるアルミニウム化合物である処理材が提供される。According to the present invention, the alumina composition has the following composition formula (6):

“In the formula: M is an alkali metal, Z is an alkaline earth metal, a is a number of 5 or less including zero, b is a number of 5 or less including zero, and w is a number of 9 or less including zero]. Provided is a treatment material that is an aluminum compound composed of a single or a combination of two or more selected from the group of alkali metal or alkaline earth metal aluminate or aluminum hydroxide.

  According to the present invention, the above-mentioned calcium glass has already undergone a thermal history, and a low crystal mainly composed of calcium silicate satisfying the above-mentioned basic composition ratio composed of silica, alumina, and calcium. In addition, there is provided a treatment material that is an amorphous compound and is an inactive powdery substance that is ground and classified and has a water elution pH of less than 12.

  According to the present invention, the active silica is an active unit composed of an alkali silicate composed of a single substance or a combination of two or more kinds selected from the group of alkali silicates represented by the composition formula (3). A treatment material that is a powder of active silica is provided.

According to the present invention, the active silica is a single active silica composed of sodium-modified silicate that modifies a silicate raw material with a sodium salt compound;
The silicate raw material is a silicate compound selected from the silicate composition;

［式中；Ｔはケイ素、アルミニウム、窒素、硫黄、炭素、ホウ素、リン元素群の単独ないし２種以上の組み合わせ元素、Ｘはハロゲン元素、ａおよびｂは零を含む１０以下の数、ｍは０．５ないし６の数、ｗは零を含む１２以下の数］で表されるナトリウム塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる活性な粉状体であり；Said sodium salt compound is the following composition formula (7)

[In the formula, T is silicon, aluminum, nitrogen, sulfur, carbon, boron, phosphorus element group alone or in combination of two or more elements, X is a halogen element, a and b are numbers of 10 or less including zero, m is An active powder comprising a single or a combination of two or more selected from the group of sodium salt compounds represented by the number of 0.5 to 6, w is a number of 12 or less including zero];

  The sodium-modified silicic acid is a mixed material obtained by adding 1 to 30 parts by mass of a sodium salt compound and 50 parts by mass or less of water with respect to 100 parts by mass of the silicate composition. An active sodium-modified silicic acid containing at least 50% by mass or more of an active alkali silanol group-containing sodium silicate comprising a powder that has been modified by reaction and dehydrated, dried, pulverized and classified as necessary. A treatment material is provided that is a single active silica powder of a salt.

  According to the present invention, the active silica is configured as a composite active silica in which a silicic acid-bearing silicic acid compound and a sodium salt compound coexist;

  The silicic acid compound having a silanol group (—OH) is one or more selected from the group consisting of hydrogel that is hydrous and amorphous silicic acid, xerogel that is amorphous silicic acid, and ferrosilicate compound Active granule consisting of a combination of:

  The active sodium salt compound is an active powder comprising a single or a combination of two or more selected from the group of sodium salt compounds represented by the composition formula (7);

  An active composite powder in which the composite active silica is uniformly mixed into one pack by adding a sodium salt compound in an amount of 30 to 180 parts by mass with respect to 100 parts by mass of silanol group-containing silicic acid compound A treatment material is provided.

  According to the present invention, in the composite constituent material prepared by coexisting two components of calcium glass constituting the treatment material and sodium-modified silicic acid of active silica;

  At least 820 mixed composite materials in which 10 to 100 parts by mass of the mixed material that is the raw material of the sodium-modified silicic acid is added to and mixed with 100 parts by mass of the mixed raw material that is the raw material of the calcia glass. A treated material that is heat treated at 0 ° C. to obtain a heat treated product, which is then pulverized and classified into fine particles passing through a 100-mesh sieve, and a powdery material in which two components of calcium glass and sodium-modified silicic acid of active silica coexist Is provided.

［式中：Ｍは原子価ｎ：の金属陽イオン、Ｘ＋Ｙは単位格子当りの四面体数］で表されるアルミノケイ酸の金属塩のゼオライト構造を有するゼオライトの群より選ばれる単独ないし２種以上の組み合わせからなるゼオライトもしくはゼオライト前駆体の粉状体である処理材が提供される。According to the present invention, the crystal seed composition as the auxiliary composition has the following unit cell composition formula (8):

[Wherein, M is a metal cation of valence n :, and X + Y is the number of tetrahedrons per unit cell] selected from the group of zeolites having a zeolite structure of a metal salt of aluminosilicate represented by A treatment material which is a powder of a zeolite or a zeolite precursor comprising a combination of the above is provided.

  According to the present invention, the sodium supplement composition as the auxiliary composition is an active sodium salt consisting of one or a combination of two or more selected from the group of sodium salt compounds represented by the composition formula (7). A treatment material that is a powder of a compound is provided.

  According to the present invention, the calcium supplement composition as the auxiliary composition is selected from the group consisting of a normal salt or a basic salt compound of a calcium oxyacid salt compound represented by the composition formula (5). A treatment material, which is a calcium salt composition comprising a combination of two or more, wherein the calcium salt composition contains at least 30% by mass of calcium oxide based on CaO oxide and is a powder of a calcium salt composition Is provided.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｈは１ないし８の数、ｎは２または３の数、ｗは零を含む１０以下の数］で表される各金属元素の硫黄のオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる硫酸根含有塩化合物類の粉状体である処理材が提供される。According to the present invention, the supplemental sulfate composition as the auxiliary composition is represented by the following composition formula (9):

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number from 1 to 8, and n is 2 or 3. Powders of sulfate group-containing salt compounds consisting of a single or a combination of two or more selected from the group of sulfur oxyacid salt compounds of each metal element represented by the number, w is a number of 10 or less including zero] A treatment material is provided.

  According to the present invention, the reinforcing material composition as the auxiliary composition is a metal powder / fiber, glass fiber, rock wool, carbon fiber, mineral fiber, vegetable fiber, organic fiber, inorganic powder, sand, Provided is a treatment material that is a filler, a fiber material, or an aggregate composed of single or a combination of two or more selected from the group of gravel, weight / lightweight aggregate and cullet.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｈは１ないし８の数、ｔはＧ元素原子価÷２の数、ｗは零を含む１０以下の数］で表される各金属元素のリンのオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなるリンのオキシ酸塩化合物類の粉状体である処理材が提供される。According to the present invention, the phosphoric acid radical composition as the auxiliary composition has the following composition formula (10):

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number from 1 to 8, and t is a G element valence. ÷ a number of 2 and w is a number of 10 or less including zero] Phosphorus oxyacid compounds composed of a single or a combination of two or more selected from the group of phosphorus oxyacid compounds of each metal element The processing material which is a powdery body of is provided.

［式中：ｆは４以下の数、ｗは零を含む１０以下の数］で表されるアルカリ溶液に可溶なバリウム塩群より選ばれる単独ないし２種以上の組み合わせからなるバリウム塩化合物の粉状体である処理材が提供される。According to the present invention, the barium salt composition which is the auxiliary composition has the following composition formula (11):

[Wherein f is a number of 4 or less, w is a number of 10 or less including zero] of a barium salt compound consisting of a single or a combination of two or more selected from the group of barium salts soluble in an alkaline solution A treatment material that is a powder is provided.

［式中；Ｔはアルミニウム、ケイ素、硫黄、窒素、リン元素群の単独ないし２種以上の組み合わせの元素、ｎは２ないし３の数、ｍは０．５ないし６の数、ｗは零を含む２８以下の数］で表される鉄の各元素のオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる鉄塩化合物の粉状体である処理材が提供される。According to the present invention, the iron salt supplement composition as the auxiliary composition is represented by the following composition formula (12):

[Wherein, T is an element of an aluminum, silicon, sulfur, nitrogen, phosphorus element group alone or a combination of two or more, n is a number of 2 to 3, m is a number of 0.5 to 6, and w is zero. A treatment material that is a powder of an iron salt compound consisting of a single or a combination of two or more selected from the group of oxyacid salt compounds of each iron element represented by the number of 28 or less inclusive] is provided.

  According to the present invention, the additive material composition which is the auxiliary composition is a treatment material which is a powder of an additive material consisting of a single material or a combination of two or more selected from the group of pigments, colorants and fillers. Is provided.

  According to the present invention, the dispersion medium composition as the auxiliary composition is kaolin, acid clay, bentonite, caustic earth, talc, zeolite, coal ash, bauxite, iron ore, perlite, gypsum, shell, silicate. There is provided a treatment material which is a dispersion medium composition comprising an inorganic compound consisting of a single or a combination of two or more selected from glass and volcanic ash and having a powder of 100 μm or less, preferably 10 μm or less.

According to the present invention, the support composition as the auxiliary composition is selected from the group consisting of charcoal, amorphous silica, activated silicic acid, activated alumina and zeolite having a surface area of 100 m ² / g or more. A treatment material which is an adsorptive carrier comprising a combination of at least species is provided.

  According to the present invention, the function-imparting composition that is the auxiliary composition is one or more selected from the group consisting of an activator, a magnetic substance, an antimicrobial agent, a water-repellent adsorbent, and a functional additive. The processing material which is a powdery body of the functional provision composition which consists of a combination is provided.

  According to the present invention, for a single material made of the above-mentioned treatment material or a composite material in which the target material is compounded with the single material, the water-based activator is allowed to coexist to the reformed product or processed into an inorganic molded product. In the utilization method that utilizes the treatment / curing function for the target material by the hydraulic reaction of the treatment material through the series of work steps to be prepared;

  The above-mentioned single item material is a single item of treatment material that is made into one pack by adding an auxiliary composition as required to the three essential components of calcium glass, active silica, and sulfate;

  From the group of the above-mentioned composite material, sand particles, filler, hydrous soil, contaminated material, adsorbent powder, heat-resistant powder, alkali silicate material and galactor aggregate with respect to 100 parts by mass of the treatment material A composite product in which 1 to 2000 parts by mass of a target material consisting of a single selected or a combination of two or more selected is mixed;

  The above water-based activator is selected from the group of natural water [rain water, river / lake water, pool water, well water, seawater], artificial pond / dam water, processed water, treated water or wastewater in the industry. An aqueous liquid serving as a reaction initiator for a treatment material comprising a combination of more than one species;

The above-mentioned modified processed product is a modified processed product that has been solved with low alkalinity by modifying the target material having a problem with a single material or a composite material;
The inorganic molded product is an inorganic molded product that is used as a cured product or binder that is a molded product by processing and preparing a single product or a composite material;

  The above-described series of work steps is a mixing step in which a water-based active agent is allowed to coexist with a single material or a composite material to make a fluid, plastic or flaky mixture, and if necessary, the mixture is used as a molded product. A plurality of steps consisting of a curing step to complete a hydraulic reaction in the admixture or the molded product;

The above mixing step is a step of mixing with 100 parts by mass of a single material through at least 15 parts by mass of an aqueous activator to form an admixture;
The above processing step is a step of molding the mixture into a specific shape or an unspecified shape to form a molded product;

  In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A process for making a modified product or an inorganic molded product under curing conditions in which it is allowed to stand for 10 minutes or longer in a single atmosphere or a multistage atmosphere consisting of a combination of two or more selected from the group of the following atmospheres;

  The above modified product or inorganic molded product is water-resistant and heat-resistant with respect to the target material, and has been modified or processed to a low alkalinity with a water elution pH of less than 12.

  The above utilization method applies the single material or composite material to a series of work processes by using the treatment material, thereby reforming the target material into the reformed product, or treating the treatment material or the target material as the raw material. As a method of use, a method for processing and preparing an inorganic molded product is provided.

  According to the present invention, the modified product or the inorganic molded product is water-resistant and heat-resistant, has a low alkalinity with a water elution pH of less than 12, and has solved the problems of the target material. Treated material, structure, composite hardened body, granule, aggregate body, adhered body, film, hydrous soil modified product, non-polluted product, consolidated adsorbent, heat insulation / heat retention / heat resistant material, acid resistant material or integral The utilization method which is an inorganic molded article which consists of a chemical compound is provided.

  According to the present invention, the treatment material is modified by a series of work steps that exhibit a treatment / curing function for the target material possessed by the treatment material and allow the aqueous material to coexist with the target material. In quality processed products;

  The above-mentioned treatment material is a treatment material that is made into one pack by adding an auxiliary composition to the essential three components of calcium glass, active silica, and sulfate as required;

  The above target material is selected from the group of problematic sand particles, fillers, hydrous soils, contaminated materials, adsorbent powders, heat-resistant powder particles, alkali silicate materials, and galactor aggregates. A target material consisting of a combination of more than one species;

  The above water-based activator is one or more selected from the group of natural water [rain water, river / lake water, pool water, seawater], artificial pond / dam water, processed water, treated water or wastewater in industry. An aqueous liquid which is a reaction initiator for a treatment material comprising a combination of

  The above-mentioned series of work steps is a mixing step in which a treatment material and an aqueous activator coexist with the target material to make it a fluid, plastic or dry blend, and if necessary, molding the blend A plurality of steps consisting of a curing step to complete a hydraulic reaction in the admixture or the molded product to obtain a modified product;

The above mixing step is a step of adding at least 10 parts by mass of the treatment material to 100 parts by mass of the target material and simultaneously forming an admixture through at least 10 parts by mass of the water-based active agent;
The above processing step is a step in which the mixture is molded into a specific shape or an unspecified shape to obtain a molded product;

  In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A process under curing conditions that is allowed to stand for at least 10 minutes in a single atmosphere or a multistage atmosphere composed of a combination of two or more selected from the group of atmospheres of

  The above-mentioned modified treatment products demonstrate the treatment and curing functionality of the treatment material through a series of work steps in which the treatment material and water-based activator coexist with the target material, ensuring water resistance and heat resistance, and water elution There is provided a modified product that has been modified to a low alkalinity having a pH of less than 12.

  According to the present invention, the treated material is modified by a series of work steps through an aqueous activator that coexists with the hydrous soil that is the target material;

  The above-mentioned target material contains nitrogen components (ammonia nitrogen, nitrate) above the reference value (1 mg / L) of total nitrogen elution amount in the sea area based on fishery water standards, and water is contained in an amount of 25 to 80% by mass. Fluid or plastic hydrous soil containing in the range of mass%;

  The above-described series of work steps is a mixing step in which 100 parts by weight of the treatment material is added to the amount corresponding to 50 to 2000 parts by weight of the hydrous soil based on the dry matter, and the water-containing soil is mixed through the water. It is a plurality of steps consisting of a curing process in which an admixture is molded into a specific shape, or a hydraulic reaction is completed without a molding process to obtain a modified product;

  The above-mentioned modified treated products are reformed in a series of work processes where the treated material and water-based activator coexist with the hydrous soil to be treated, and the elution amount of nitrogen components contained in the hydrous soil is determined based on the water quality standards for fisheries Provided is a modified product that is suppressed to a value within the above range, is water resistant and heat resistant, and has been subjected to a low alkalinity modification treatment with a water elution pH of less than 12.

  According to the present invention, in the modified treated product, the treated material is modified by a series of work steps through an aqueous activator that coexists with the contaminated material that is the target material;

  In the water elution test of heavy metals [lead, cadmium, chromium, arsenic, mercury], the above target material contains water-soluble heavy metals exceeding the national environmental standard value, and the water content is at least 15 masses. Contaminated soil ground contaminated material containing%;

  The above-described series of work steps are performed in the form of a powdery material treatment material or a slurry-like material in an amount corresponding to 50 to 2000 parts by mass on the basis of dry matter of in situ soil ground containing heavy metals or moved contaminated material. The water-containing treatment material is mixed in a mixing process in which water containing water is included in an amount corresponding to 100 parts by mass on a dry matter basis and mechanically mixed or injected into the contaminated material. A plurality of steps consisting of a curing step in which the hydraulic reaction is completed by leaving it for at least 24 hours under natural conditions at room temperature in the processing original position or the moving processing place;

The above-mentioned modified treated products are reformed in a series of work steps in which treated materials and water-based activators coexist on the contaminated materials to be treated, and the amount of water elution test for heavy metals containing contaminated materials is determined by the government. Water insolubilized within the range of environmental standard value, deformability strength value by external pressure measured by simple deformation measurement test is 40 KN / m ² or less, water resistance and heat resistance are ensured, water elution pH is 12 There is provided a modified product which has been modified to a low alkalinity of less than.

  According to the present invention, in the modified treated product in which the treatment material is treated by a treatment method by a series of work steps through a water-based activator that coexists with a contaminated material that is a target material;

  One or more selected from the group consisting of incinerated ash, sludge or contaminants, and marine hydrous mud of wastes containing the water-soluble chlorine at a concentration exceeding 0.1 mg / L. Contaminated material consisting of combinations;

  The above-described series of work steps is performed on at least 20 parts by mass of a water-based activator for a composite material by adding 100 parts by mass of the treatment material to 100 to 2000 parts by mass on the basis of the dry matter of the contaminated material. An admixture process is performed to form an admixture, and the admixture is molded into a specific shape, an unspecified shape, or a granule in a processing process to form a molded product, and then the molded product is subjected to at least a natural condition at room temperature. A plurality of steps consisting of a curing step that is allowed to stand for 24 hours to complete the hydraulic reaction and make a modified product;

  The above-mentioned modified processed product is treated in a series of work steps in which the treatment material and the water-based activator coexist with the contaminated material of the treated body award material to be treated, and the water-soluble chlorine content of the contaminated material to be treated. Is supplemented and fixed at 0.1 mg / L or less, the load strength of the modified granule is ensured to be 4 kg or more, water resistance and heat resistance are ensured, and water elution pH is less than 12 low alkalinity A modified product that has been modified is provided.

  According to the present invention, in the modified treated product in which the treatment material is treated by a treatment method by a series of work steps through a water-based activator that coexists with a contaminated material that is a target material;

  The above target material is a contaminated material containing dioxins at a concentration exceeding the national environmental standard value;

  The above-described series of work steps is performed by adding 100 parts by mass of a treatment material to 100 to 2000 parts by mass on the basis of dry matter of in situ soil ground containing dioxins or moved contaminated material, and at least for composite materials. A mixture obtained by mixing through 20 parts by mass of an aqueous activator, and then left under normal conditions at room temperature or a dry condition at 200 ° C. or less in the original processing position or transfer processing position as the mixture, In a plurality of steps consisting of a curing step in which at least 15% by mass or less of the water content containing the admixture is treated to make a modified product by completing the hydraulic reaction / treatment by treating it in the absence of water, preferably zero. Yes;

The above-mentioned modified product is treated in a series of work steps in which the treated material and water-based activator coexist with the contaminated material moved or moved from the in-situ ground to be treated. The concentration and concentration of dioxins is below the environmental standard value established by the national government due to the sequestration and decomposition action, and the deformability strength value due to external pressure measured by a simple deformability measurement test is 40 KN / m ² or less. In addition, there is provided a modified product that is secured to water resistance and heat resistance and is modified to be low alkaline with a water elution pH of less than 12.

  According to the present invention, the water-based activator is applied to a single material that is a processing material or a composite material that combines the target material with the processing material by exerting a processing / curing function for the target material of the processing material. In an inorganic molded product that is processed and prepared into a molded body with a series of working steps to coexist;

  The above-mentioned single item material is a single treatment material that is made into one pack by adding auxiliary composition to the essential three components of calcium glass, active silica and sulfate, if necessary;

  The composite material is selected from the group of sand particles, fillers, hydrous soil, contaminated materials, adsorbent powders, heat-resistant powder particles, alkali silicate materials, and trash aggregates with respect to 100 parts by mass of the treatment material. A composite material in which 1 to 2000 parts by mass of a target material consisting of a single or a combination of two or more of the above is mixed;

  The above water-based activator is one or more selected from the group of natural water [rain water, river / lake water, pool water, sea water], artificial pond / dam water, processed water, treated water or wastewater in industry. An aqueous liquid which is a reaction initiator for a treatment material comprising a combination of

  The above-described series of work steps is a mixing step in which the single material or composite material and an aqueous activator coexist to form a fluidity, plasticity, or lumpy blend, and if necessary, the blend is formed into a molded product. A plurality of steps consisting of a curing step followed by a curing step to complete the hydraulic reaction of the blend or the molded product to form an inorganic molded product;

  The mixing step is a step of mixing the single material or the composite material with at least 15 parts by mass of an aqueous activator to form an admixture;

  The above processing step is a step of molding the mixture into a specific shape or an unspecified shape to obtain a molded product;

  In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A step of leaving in a single atmosphere selected from the group of atmospheres or a multistage atmosphere consisting of a combination of two or more for at least 10 minutes;

  The above-mentioned inorganic molded product has a structure, composite hardened body, granule, aggregate, adherend, film, hydrous soil reforming treatment through a series of work steps in which a water-based active agent coexists with a single material or composite material. Products, non-polluted products, consolidated adsorbents, heat-insulating / heat-retaining / heat-resistant materials, acid-resistant materials or inorganic molded products made of integrated materials, water resistance, heat resistance, low elution pH of less than 12 An inorganic molded product that is a molded product of is provided.

  According to the present invention, a hardened body, a structure, a composite hardened body, a granule or an aggregate are prepared and processed by the above-described series of work steps in which a water-based active agent is allowed to coexist with a composite material in which the treatment material is combined with a target material. In inorganic molded products that have been

  The target material is a sand granule having a particle size of 0.2 to 50 mmφ and a bulk specific gravity of 0.2 to 3.5 g / cc;

  The mixing step in the series of work steps described above is for a composite material in which 100 parts by mass of the processing material is combined with 1 to 2000 parts by mass of the sand granule that is the target material. A step of coexisting at least 15 parts by mass of the aqueous active agent to form a homogeneous mixture, and the processing step is a step of forming the mixture into a specific shape or an unspecified shape to form a molded product. Yes;

The above-mentioned inorganic molded product is prepared in a series of work steps in which a water-based activator is allowed to coexist with a composite material having a sand granule as a target material, and a specific shape or uniaxial compressive strength of 2,000 KN / m ² or more is secured Hardened body, structure, composite hardened body, granule or aggregate of unspecified shape, water resistance and heat resistance are ensured, and low-alkaline hardened body, structure, composite with water elution pH of less than 12 An inorganic molded article that is a cured body, granule, or aggregate is provided.

According to the present invention, in the inorganic molded product that is processed and prepared into an adherent by the above-described series of work steps through the aqueous activator to the composite material that combines the treatment material with the target material;
The target material is a powdery filler having a particle size of 100 μm or less;

  The mixing step in the series of work steps described above is performed on a composite material obtained by combining 100 parts by mass of the treatment material with respect to 1 to 2000 parts by mass of the filler to be prepared, and 100 parts by mass of the composite material. In contrast, at least 15 parts by mass of a water-based activator is coexisted to form a paste-like mixture, and the processing step involves coating and bonding the paste-like mixture to the surface, inner surface or gap surface of the base material. , Binding, coating, multi-layer coating, soaking, spraying, pasting, spraying, pouring or applying by injection means to form a molded product;

The above-mentioned inorganic molded product is prepared in a series of work steps in which a water-based active agent is allowed to coexist with a composite material whose target material is a filler, and a shear fracture adhesive force of 2,000 KN / m ² or more is secured to prepare an adherent. Thus, an inorganic molded article that is a low-alkaline adhering substance having water resistance and heat resistance and having a water elution pH of less than 12 is provided.

  According to the present invention, the aggregate group of granular materials is consolidated and consolidated by the above-described series of operation steps by the paste-like admixture prepared by combining the processing material with the filler and the filler. In an inorganic molded product that is processed and prepared into a coconut-shaped molded body having at least a through-hole;

  The aggregate group of the above-mentioned granular bodies is a group of aggregates of 1 to 10 mmφ spheres, hollow bodies, cylinders, flake bodies, granulated bodies, or unspecified granular bodies, or a mixture of a plurality of them;

  At least 15 parts by mass with respect to 100 parts by mass of the composite material, wherein the paste-like mixture is a composite material in which 100 parts by mass of the treatment material is combined with 10 to 2000 parts by mass of the filler. A paste-like admixture mixed with a water-based active agent of

  The processing step in the series of work steps described above covers the granule surface by adding the paste-like admixture in an amount sufficient to wet the entire granule surface of the aggregate group with respect to the aggregate group of granules. It is a processing step to secure the aggregate group of granules covered with paste-like admixture in a specific shape,

  The curing process in the above series of work processes is a curing process in which a group of granular materials coated with a paste-like admixture in a specific shape is allowed to stand in an atmosphere at least at room temperature for 24 hours;

  The above-mentioned inorganic molded product of a cocoon-like molded body is prepared into a coconut-like molded body in which through voids are secured and consolidated and consolidated, water resistance and heat resistance are ensured, and water elution pH is 12 An inorganic molded article which is a low alkaline cocoon-shaped molded article of less than is provided.

According to the present invention, in the inorganic molded product that is processed and prepared into a film by the series of operation steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;
The preparation target material is a powdery filler having a particle size of 100 μm or less;

  The mixing step in the series of work steps described above is for a composite material in which 100 parts by mass of the treatment material is combined with 1 to 2000 parts by mass of the filler that is the target material. At least 15 parts by mass of a water-based active agent to make a fluid or plastic admixture, and the processing step comprises converting the fluid or plastic admixture into a metallic or inorganic fiber woven or non-woven fabric; A process of forming a composite product into a specific shape film of 1 to 20 mm in the form of a film, plate or coating;

  In the above curing process, the molded product formed by applying and processing a fluid or plastic admixture is processed at 2 to 120 ° C. in the atmosphere, oxygen-less gas, water, sea, soil, solution, steam, During molding, the mold-processed product that has been applied and cured is cured for at least 10 minutes in a single atmosphere or a multi-stage atmosphere consisting of a combination of two or more selected from the group of atmospheres during heating, decompression, or pressurization. A process that removes the mold from the mold as needed and makes it a molded product;

  The above-mentioned inorganic molded product is prepared into a film-like molded body through a series of work steps in which a water-based active agent coexists with a composite material intended for a filler, ensuring water resistance and heat resistance, and water elution pH An inorganic molded article having a low alkalinity film having an A of less than 12 is provided.

According to the present invention, in the inorganic molded product that is processed and prepared into the hydrous soil modified body by the series of work steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;
The target material is a hydrous soil that contains water in a range of 25% to 80% by weight and is fluid or plastic;

  In the above-mentioned series of work steps, the mixing step is performed on a composite material in which 100 parts by mass of the treatment material is added to an amount corresponding to 50 to 2000 parts by mass on the basis of the dry matter of the above-mentioned hydrous soil that is the target material. Mixing with soil-containing water;

  The mixing step in the series of work steps is a step in which the mixture is molded into a specific-shaped structure, a container-integrated product, or an unspecified-shaped granule to obtain a molded product;

  The curing process in the above series of work processes is a process of curing the molded product in the air, in the soil, in water or in seawater, and if necessary, the molded product that has been subjected to the curing process in advance. A process consisting of a second stage curing process in soil, water or seawater;

The above-mentioned inorganic molded product is prepared into a specific shape or non-specific shape hydrous treated earth body with a uniaxial compressive strength of 1000 KN / m ² or more, water resistance and heat resistance are ensured, and water elution pH is 12 An inorganic molded article which is a low alkaline hydrous soil reformer of less than is provided.

According to the present invention, in the inorganic molded product processed and prepared into the hydrous treated soil by the series of work steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;
The survey target material combined in the above composite material is hydrous soil in the original position of a rustic or plastic soft ground having a water content of at least 20% by mass;

  If necessary, the mixing step in the series of work steps is performed on the amount corresponding to 50 to 2000 parts by mass on the dry matter basis of the soft ground that is the above-mentioned in situ hydrous soil that is the target material. An amount equivalent to 100 parts by mass in terms of dry matter of a single material of a treatment material, a composite material of a treatment material in which sand particles are combined, or a slurry-like treatment material in which at least 75 to 120 parts by mass of an aqueous activator is added to the treatment material Is a process of mixing into a hydrous soil by atmospheric pressure excavation, under-pressure excavation, agitation injection or a push-in type admixing process with an injecting pressurization process without a certain range of the original soft ground;

  The curing process in the above series of work steps is a step of leaving the in-situ soft ground admixture for 24 hours or longer under the in-situ natural conditions in which the admixture is not subjected to the processing step;

The above-mentioned inorganic molded product is prepared in a soft ground where the uniaxial compressive strength is modified to at least 300 KN / m ² in the soft ground in situ, water resistance and heat resistance are ensured, and the water elution pH is less than 12 An inorganic molded article which is an alkaline water-containing treated soil is provided.

  According to the present invention, in the inorganic molded product that is processed and prepared into a non-polluted material by the series of work steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;

  The target material to be combined in the above-mentioned composite material is a water-soluble heavy metal exceeding the environmental standards set by the national government in at least one water elution test of heavy metals [lead, cadmium, chromium, arsenic, mercury]. Containing contaminating material;

  The above contaminated material is a single or a combination of two or more selected from the group of waste incineration ash, sludge or contaminants;

  At least 20 parts by mass of the mixing step in the above series of work steps is performed on a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass with respect to 100 to 2000 parts by mass of the dried material of the contaminated material as the target material A step of blending with an aqueous activator;

  The curing process is a process in which the processing step in the series of work steps described above is a step of forming a molded product by performing a molding process into a specific shape, an unspecified shape, or a granular shape. A step of leaving it for 24 hours to form a molded body;

  When the above inorganic molded product is granulated, the load strength is secured to 4 kg or more, the contained heavy metals are fixed, and the results of the water elution test are water insoluble and fixed within the range of the environmental standards set by the country. It is a molded product of a cured product, structure or granule, prepared as a non-polluted product that can be reused and recycled, ensuring water resistance and heat resistance, and having a low alkalinity with a water elution pH of less than 12. An inorganic molded product that is a pollution product is provided.

According to the present invention, in the inorganic molded product that is processed and prepared into the adsorbent powder by the series of operation steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;
The target material to be combined in the composite material is an adsorbent powder having a specific surface area of 10 m 2 / g or more;

  The mixing step in the above series of work steps is at least 20 parts by mass for a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass of the adsorptive powder as a target material on a dry matter basis. A process of blending with a water-based active agent of

The processing step in the above series of work steps is a step of forming a processed product by molding into a specific shape, non-specific shape, or granule;
The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;

  The above-mentioned inorganic molded product is prepared as a consolidated adsorbent having a specific surface area reduction rate of 40% or less, water resistance and heat resistance are ensured, and low alkaline consolidated adsorption with water elution pH of less than 12. An inorganic molded article that is a body is provided.

  According to the present invention, in the inorganic molded product that is processed and prepared into a heat insulating, heat retaining, and heat resistant material by the series of work steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;

  The raw material to be compounded in the above-mentioned composite material is a heat-resistant granular material having a particle size of 10 to 5000 mμ made of an oxide or a non-oxide compound;

  The mixing step in the above series of work steps is at least 20 masses for a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass of the heat-resistant granular material that is the target material on a dry matter basis. A mixture through a part of an aqueous activator;

  The processing step in the above series of work steps is a step of forming a processed product by molding into a specific shape, non-specific shape, or granule;

  The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;

  The above-mentioned inorganic molded product is heat-resistant / heat-retained / heat-resistant with at least 80% heat-resistant strength retention when exposed to non-fired heat-retained / refractory materials or 500 ° C. atmosphere that can be applied on-site without being heat-treated in advance. An inorganic molded article that is a low-alkaline heat insulating, heat retaining, and heat resistant material that is adjusted to the material, has water resistance, and has a water elution pH of less than 12 is provided.

  According to the present invention, in the inorganic molded product processed and prepared into the acid-resistant material by the series of working steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;

  The target material to be compounded in the above-mentioned composite material is a single alkali silicate comprising a single or a combination of two or more selected from the alkali silicate compound group represented by the composition formula (3), or the siliceous An alkali silicate material composed of a water glass composite product obtained by adding 1 to 2000 parts by mass of the powdery filler having a particle size of 100 μm or less to 100 parts by mass of an acid-alkali material alone;

In the above-described series of work steps, the mixing step is performed by adding a silicic acid as a pair to a composite material obtained by adding 100 parts by mass of a treatment material to 100 to 2000 parts by mass of an alkali silicate-based material that is an alkali silicate single product or a water glass composite product. A step in which the total amount of coexisting water is adjusted to at least 20 parts by mass in consideration of the alkali-containing water content to make an admixture;
The processing steps in the series of work steps are steps in which the mixture is molded into a specific-shaped structure, a coated adhering body, or an unspecified-shaped powder or granule to form a molded product;

  The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;

  The inorganic molded product has been prepared as an acid-resistant material with a solidified body strength retention rate of at least 80% when immersed in an acidic solution of pH 3, ensuring water resistance and heat resistance, and having a water elution pH of 12 An inorganic molded article that is an acid-resistant material having a low alkalinity of less than 5 is provided.

  According to the present invention, in the inorganic molded article prepared as an integrated product by the series of operation steps through the aqueous activator to the composite material in which the treatment material is combined with the target material;

  The target material to be compounded in the above composite material is a plate, film, sphere, granule, square, column, fiber, string, lump, or a mixture of these craps that are stored in containers to create voids. A junk aggregate having;

  The fluidity slurry in which the mixing step and the processing step in the above series of work steps are adjusted by adding at least 25 parts by mass of an aqueous activator to the treatment material with respect to the galactor aggregate stored in containers and having voids. Injecting and filling the body into the gaps in the junk aggregate and integrating them together, and forming the junk aggregate into an integrated molded product;

  The curing step in the above series of work steps is a step in which the integrated molded product is allowed to stand for at least 24 hours under natural conditions to form a molded body;

  42. The above-mentioned inorganic molded product is prepared as a consolidated integrated product in which a galactor aggregate is integrated, and is a low-alkaline integrated product that ensures water resistance and heat resistance and has a water elution pH of less than 12. Inorganic molded product.

  The effect of the present invention is to solve the problems of conventional hydraulic solidification materials and to give environmental impact to non-polluting treatment materials (room temperature hydraulic solidification materials) that ensure shelf life. Providing a stable supply at low cost with no manufacturing technology, proposing effective use and processing technology of the processing material, supplying inorganic molded products using the processing material, and disposing of it in various industries and fields The purpose is to contribute to the resolution of environmental problems and the creation of a recycling-oriented society by providing inorganic molded products that can be recycled by effectively using the materials and wastes that are used.

BEST MODE FOR CARRYING OUT THE INVENTION

1. Background In recent years, rapid development due to the advancement of science and technology and the globalization of information media has led the human society to a richer society. These advances and developments leave various problems for the earth and humanity, and have caused many adverse effects on society, the economy, and the living environment. In order to improve and eliminate these harmful effects, it is required to build a recycling society. In addition, there is a need for innovations for the burden of global warming in energy and resource utilization, and safe and low-cost recycling of waste.

  The present invention has been established as a technology that can meet these current social and environmental needs, and to conserve and build a recycling-oriented society and an environment that is friendly to the global environment, and to secure and reserve depleted thermal energy sources. The present invention technology has been completed with the goal of keeping it.

  The present inventors demonstrate the multi-functionality (hydraulic solidification, adhesion, formation of low alkaline solidified material, immobilization of heavy metals, etc.) that can deal with environmental problems with the treatment / curing mechanism by hydraulic reaction / treatment at room temperature It is a processing material that can be processed, is non-cemented and chromeless pollution-free, is manufactured in a low-load environment, and the manufactured processing material does not change quality during long-term storage (shelf life) The present invention has been reached through repeated research and development in search of a secured “treatment material”.

  In addition, the present inventors, for various target materials as necessary, a series of processes including an admixing step performed through an aqueous activator added to the light treatment material, a processing step, and then a curing step as necessary. Through the work process, research and development were repeated for the energy-saving “utilizing and using method of processing material” to complete the hydraulic reaction / processing function of the processing material with respect to the target material, resulting in the present invention.

  Furthermore, the target material having various problems is modified by the above-mentioned processing material by the above-mentioned series of work steps to solve the problem with a low load type in the environment, for example, fixing and insolubilizing the contained heavy metals. In search of a “modified product” that exhibits functionality; a structure suitable for various uses and purposes through a series of work steps in which the above-mentioned treatment material is added to the target material and the water-based activator coexists. Process and prepare composite molded bodies, granules, aggregates, adherents, hydrous soil-modified products, undisclosed materials, consolidated adsorbents, heat insulating / heat retaining / heat resistant materials, acid resistant materials or integrated products, The present invention has been accomplished through repeated research and development in search of a “mineralized product” that is water- and heat-resistant and has a low alkalinity with a water elution pH of less than 12.

2. Composition of “treated material” and shelf life In the treated material of the present invention, the calcium component necessary for exhibiting the hydraulic function is an inert calcium glass prepared through a thermal history in advance. Three components, which are active silica glass, active silica having active silanol groups and sodium ions, and sulfate containing sulfate groups, are basically essential.

  Furthermore, in the treatment material of the present invention, as an optional form according to need, the treatment material may be constituted by a powdery material of 4 components to which various auxiliary compositions are added in addition to the above-mentioned essential 3 components. It is convenient to add functionality as required to the treatment material.

  The feature of the treatment material of the present invention is that the powdery composition in which the above essential three-component or four-component powders are mixed and packed into one pack has “shelf life”, and an aqueous activator. The function of forming the treated body, cured body, and binder is demonstrated by contact with

  In order for the treatment material of the present invention to be established as a useful product for general use, even if the produced treatment material is stored and stored in a natural environment for a long period of time for storage and storage, the treated material after being left is altered.・ It is very important that shelf life is ensured so that there is no deterioration and the quality is such that the hydraulic reaction and treatment functions can be fully activated by bringing the active agent into contact with the treatment material. .

  In general, calcium components essential for hydraulic solidification materials are sensitive to water, humidity and carbon dioxide in the air under normal conditions in nature, and are easily altered to find solidification materials and treatment materials. The hydraulic function that is being used cannot be fully exhibited. In other words, it does not have “shelf life” that enables storage, and is not a product that is suitable for general-purpose construction.

  Furthermore, in order to impart a hydraulic reaction / treatment function at room temperature to the treatment material of the present invention, unless it is necessary to ensure shelf life, an intrinsically active calcium component, an active silanol group and sodium It is advantageous to start the reaction in response to the reaction with the aqueous activator by making active silica having ions into one pack and allowing them to coexist.

  However, placing a material with water-soluble sodium ions that are sensitive to active water, humidity, and carbon dioxide in a single pack not only loses shelf life. It is in a very dangerous state because it involves a rapid exothermic reaction that occurs when it comes into contact with water and humidity in the air.

  In addition, the sulfate radical component essential for the hydraulic solidifying material generally exists as a sulfate compound of a basic salt or a neutral salt, or is supplied as a stable compound having crystal water. Therefore, it is not possible to further expect the hydration mechanism required for the construction of these sulfate compounds, and the cost rises because the crystal water is partially dehydrated if necessary and used. Moreover, stable “shelf life” cannot be expected.

  Of course, without making several active components necessary for the treatment material into one pack, these components are brought into the construction site separately and separately, and measured and mixed at the construction site to perform the desired construction work. Although the present invention does not exclude that it is carried out, weighing each necessary raw material at the construction site, mixing and applying to the construction work is actually a very cumbersome work, not practical, It is not comparable to construction workability with one-pack products.

  The shelf life in the treated material of the present invention is that the calcium component necessary for the treated material is mixed and prepared in advance, then heat treated at a temperature of at least 820 ° C., and then pulverized and classified to form a fine powder. Even if it is made into a one-pack, it can be used as a treatment material even if it is made into a one-pack by devising a part of the coexisting calcium component to be low-crystallized or amorphized and modifying it to an inert material with a water elution pH of less than 12. Shelf life can be ensured.

  The calcium glass prepared in advance in the present invention has a water elution pH of less than 12, indicating that there is little elution of alkaline components such as calcium from the glass glass to water, and the calcium component is inactivated, When one-packed treatment material is exposed to natural conditions, it is insensitive to the reactivity with moisture, water, and carbon dioxide coexisting in the natural atmosphere, creating conditions that can secure shelf life of storage stability ing.

  Accordingly, the treated material of the present invention possesses active silica mainly composed of silicic acid having an active alkali silanol group and sulfate radicals with respect to an inert powdery calcare glass obtained by heat-treating a mixed raw material prepared in advance. In addition to the three essential components with the addition of sulfate powder, the energy-saving, non-polluting, and one-pack type with four components plus various auxiliary compositions depending on the intended use and stable shelf life. Can be provided as a simple treatment material.

3. Calcium glass, which constitutes the treatment material
In the present invention, the calcium glass necessary to ensure shelf life is appropriately selected and mixed with a predetermined amount of a silicate composition, a calcium composition or an alumina composition which is a target raw material of a mixed raw material to be a raw material, It is preferable to prepare a heat-treated product that has been subjected to a heat treatment of at least 820 ° C. for 15 minutes, and pulverize and classify the heat-treated product as a fine powder that passes through at least a 100-mesh sieve.

  The mixed raw material used as the raw material of the calcium glass in the present invention is at least a silicate composition shown below including three components of calcium, silica and alumina essential for the mixed raw material, and further 4 components added with sodium oxide as required. It is preferable that they are mixed in an amount ratio that satisfies the basic ratio range shown below by appropriately selecting and combining the three compositions of the calcium oxide composition and the alumina composition, and further, if necessary, from single items of each component. .

  However, the silicate composition, the calcium composition and the alumina composition that are selectively mixed as the raw material for mixing are combined with a combination of calcium, silica, alumina, and if necessary, sodium oxide in a single composition. May contain. In this case, according to the composition content of the mixed raw material, excess and deficient components can be supplemented as necessary, or the raw material of the mixed raw material can be made from a two-component composition or a single composition.

  The material selected for the mixed raw material of the present invention is not limited to an active material, and supports inert calcium carbonate, crystalline silicate, and moisture that have not been adopted as a raw material for solidification material in the prior art. Materials that are contained as adsorbed or crystallized water, non-oxidizing material, and materials that are inert but easily form glass at high temperatures can be selected and adopted.

  However, for raw materials containing moisture, carbonic acid, etc., raw materials that are non-oxidizing substances, or inert raw materials, the contained moisture, carbonic acid, etc. are heated by heat treatment in an oxidizing atmosphere of at least 820 ° C. The calcined glass of the present invention can be formed by decomposition, volatilization, and emission of non-oxidizing substances and inert raw materials by a reaction involving thermal oxidation. However, these raw materials need to be selected and blended with due consideration of mass changes caused by heat treatment.

  The silicate composition suitable for the mixed raw material of the present invention depends on the composition of the calcium composition and alumina composition used together, but is basically 45 to 80% by mass of silica expressed on an oxide basis. A suitable silicate composition containing 5 to 35% by mass of alumina, 0.1 to 25% by mass of iron oxide, and 0.5 to 25% by mass of an oxide of an alkaline earth metal -It is preferable to select and adopt.

  As the silicate composition suitably selected for the mixed raw material in the present invention, single or 2 selected from the group consisting of layered clay minerals, silicates, alkali silicates, hydrous earths, thermal history and waste silicates. The silicate composition which has as a main component silicic acid which consists of a combination of a seed | species or more can be mentioned.

  Examples of the layered clay mineral that is a silicate composition include amorphous allophane and hysingelite, which are ferrosilicates, and crystalline ferrosilicate (2: 1 layer type pyroferrite, talc, mica group, montmorillonite group, Preferable examples include vermiculite; 2: 2 layer type ryokdeite group; 1: 1 layer type kaolinite) and inosilicate.

  Any of the above-mentioned layered clay minerals can be adopted in the present invention. However, from the viewpoint of availability and reactivity, the 2: 1 layer type dioctahedral or trioctahedral smectai group, which is a hydrous ferrosilicate mineral. A layered clay mineral mainly composed of a hydrous ferrosilicate mineral is preferred.

  However, since the hydrous ferrosilicate mineral is a natural mineral, impurities generally coexist. Therefore, in the case of a hydrous layered clay mineral coexisting with impurities, if it is a clay mineral containing at least 50% by mass or more of the active ingredient in the layered clay mineral, the layered clay mineral can be obtained without impairing the object of the present invention. Can be adopted.

  Generally, the layered clay mineral made of ferrosilicate mineral contains 20 to 35% by mass of water. However, the layered clay mineral is preferably a dry powder. Therefore, the moisture content is adjusted to a dry powder state with an amount of 25% by mass or less, preferably 20% by mass or less, and the fineness is a powder that substantially passes at least 80% by mass through a 65 mesh sieve. It is preferable from the viewpoint of reactivity and workability.

  Silicates that are silicate compositions include natural or synthetic silicate compounds such as wollastonite, zonotolite and tobermorite calcium silicate and magnesium silicate, quartzite, quartz, cristobalite, opalite, feldspar, It can be selected from rock minerals such as zeolite, granite, metamorphic rock, rhyolite, conglomerate and aluminosilicate mineral consisting of mordenite, or a silicate compound consisting of two or more combinations. .

  Specific examples of silicates include crystalline aluminosilicates containing at least 50% by mass of natural or synthetic silicate compounds, crystalline aluminosilicates commonly used in industrial fields such as civil engineering, ceramics, and chemistry. Preferred examples include aluminosilicate compounds.

  In addition, refined pulverized products such as bauxite based on natural alumina, calcium silicate, silica mineral silica, quartz, tridymite, cristobalite, opal, feldspar, potassium feldspar, plagioclase, zeolite, mordenite, etc. Can be suitably adopted as a silicate (SGMS2). In addition, hydrated gel-like or dried amorphous silica that is neutralized with a silicate solution (such as water glass) by acid or alkali to form a precipitate, or halogen such as silicon tetrachloride A synthetic silicate compound such as anhydrous amorphous silica produced by gas-phase oxidation in an oxygen atmosphere can also be suitably exemplified.

［式中：Ｍはアルカリ金属、ａは０．１ないし４の数、ｗは１．６ないし５０の数］で表されるケイ酸アルカリの群より選択される単独ないし２種以上の組み合わせケイ酸アルカリを挙げることができる。As an alkali silicate which is a silicate composition, the following composition formula (3)

[Wherein, M is an alkali metal, a is a number of 0.1 to 4, and w is a number of 1.6 to 50]. An acid alkali can be mentioned.

  Since alkali metal of alkali silicate is generally easily available and inexpensive, sodium is preferable. Moreover, a sodium salt compound is indispensable as a basic component which comprises the processing material of this invention, and it is preferable from being able to replenish a silicic acid and sodium simultaneously from an alkali silicate.

  However, depending on the purpose / use and workability of the present invention, an alkali silicate composed of an alkali metal alone or in combination with potassium or lithium may be employed. In addition, an alkali silicate in which an alkaline earth metal component (calcium or magnesia component) is mixed can be adopted in the present invention.

  The sodium salt of alkali silicate is JIS-converted as water glass, is industrially mass-produced, and has a product in powder form, which is preferable. However, alkali silicates are generally commercialized in a liquid state. However, liquid alkali silicates are supported and absorbed by the mixed raw materials of the present invention having the ability to support and absorb liquids. Can be adopted.

  Hydrous soils that are silicate compositions include the construction site ground and by-product soil that occurs secondaryly, sedimentary soil such as sludge in the sea, lakes, swamps, rivers, dams, natural clay soil, Mud mud, organic soil, rock weathered soil, soft ground soil, viscous / sandy soil, water purification cake discharged from water treatment plant and sewage sludge selected at least 25% by mass Examples include hydrous soils.

  In particular, since the water purification cake discharged from the water purification plant is discharged in large quantities under certain composition conditions in conjunction with the use of water in urban areas, it is subject to disposal. It is very suitable as an acid salt composition.

  When the hydrous earth is adopted for the silicate composition, the water content of the hydrous earth is preferably as small as possible because of the subsequent thermal work process. When selecting the hydrous earth, it is preferable that the moisture content is subjected to heat treatment after dehydration adjustment by dehydration, drying, etc. in advance.

  Thermal history materials that are silicate compositions include waste ash incinerated ash, dry distillation ash, coal ash and fly ash discharged from thermal power plants, blast furnaces and steelmaking. Silicate compound with one or more combinations selected from the group of slag, volcanic eruptions such as volcanic ash generated by volcanic eruption, effluent from ceramic industry and silicate glass You can choose the kind.

  As the volcanic ash effective as the thermal history ash of the present invention, volcanic ash mainly composed of aluminum silicate, which is ejected by volcanic activity, or volcanic ash clay that has been weathered and modified based on volcanic ash as a main component can be suitably selected. When the volcanic ash contains sulfate radicals, the contained sulfate radicals can serve as an effective sulfuric acid source as a component of the treatment material.

  Volcanic eruptions are mainly composed of volcanic eruptions, volcanic ash from the past, and aluminum silicates from volcanic scoria, but the composition differs depending on the volcanic zone of the eruption matrix, aluminum silicates. In addition, alkaline earth metal calcium and magnesium, and trace amounts of heavy metals such as iron and manganese coexist. However, these trace-containing components, particularly components such as iron, are also useful as components of the treatment material (S) of the present invention.

  The silicate glass adopted as the thermal history ash of the present invention is a glass that has been melted at high temperature with vitreous silicate as a main component, and glassy silicates of glass wastes are discharged from the ceramic industry. And silicate wastes that have received a thermal history.

Waste silicates, which are silicate compositions, include waste white clay containing oil containing 50% by mass or more of silicic acid expressed by oxide standards, paper sludge and paper discharged from the paper industry. Sludge ash, red mud produced by processing bauxite, which is a raw material for producing aluminum, ceramic-related waste materials, waste products of ceramic products, residual soil and waste from construction and civil engineering industries, and silica-based waste discharged from the chemical industry Wastes mainly composed of silicate compounds consisting of a single or a combination of two or more selected from the group of substances are preferred.
In particular, waste clay and paper sludge are preferable because they have combustible energy necessary for heat treatment. Red mud is preferable because it contains a sodium component necessary for the treatment material.

  In particular, activated clay produced by activating acid clay is used as a decolorizing and purifying agent for refining edible oils such as salad oil and animal oil, but waste containing oil discarded here is used. Since clay contains oil, there is a danger of ignition and decay, and he is hesitant to dispose of it. Adopting waste white clay as a silicate composition as a mixed raw material is preferable because the oil content contained can be used as an energy source for the subsequent thermal work process.

  Of course, suitable raw material compositions for the silicate composition are selected from the group of raw materials depending on the intended use of the present invention and the social, economic and environmental situations where each raw material is placed. It is very preferable that the mixed raw material of the present invention is constituted by mixing two or more combinations.

  The calcium composition suitable for the mixed raw material of the present invention is appropriately selected from various calcium compounds and natural minerals, industrial chemicals, industrial wastes, modified processed products, etc. according to the purpose and use of the treatment material (S). Can do.

  In particular, as a calcium composition suitable for the mixed raw material of the present invention, a calcium composition, a calcium salt composition, a waste composition, a cement composition, and a charcoal cal-modified composition containing 25% by mass or more of calcium oxide. It can be appropriately selected and used from a calcite composition mainly composed of a calcite composed of a single or a combination of two or more selected from the above group.

  Calcium (calcium lime: calcium oxide), which is representative of the calcite composition, reacts violently with water and generates a large amount of heat (15540 cal. Per mole), so handling it with great care. Calcium oxides and hydroxides react sensitively with carbonic acid and water in the air and change into carbonates and hydroxides. However, in the present invention, the mixed raw material (SGM) may be adopted in consideration that it is heat-treated to prepare an inactive material.

  In addition, a calcium compound representing a calcium composition generally has a coexistence of calcium element and alkaline earth metals magnesium, zinc, strontium, barium element, etc. which are homologous elements on the periodic table. As long as it is mixed in an amount of 10% by mass or less, the basic chemical reaction of the present invention and the specified functional effect are not impaired.

［式中；ｗは零を含む２以下の数］で表される酸化カルシウムまたは水酸化カルシウムの群より選ばれる単独ないし２種以上の組み合わせからなるカルシヤ成分を酸化カルシウムで表して５０質量％以上含有しているカルシウム化合物から選択することができる。As the calcite composition adopted in the calcite composition, the following composition formula (4)

[Wherein w is a number of 2 or less including zero] represented by calcium oxide, a calcium component consisting of a single or combination of two or more selected from the group of calcium oxide or calcium hydroxide represented by 50% by mass or more It can be selected from contained calcium compounds.

  Specific examples of the calcium standard composition include natural or synthetic, calcium oxide (quick lime) or calcium hydroxide (slaked lime) mainly composed of by-produced calcium. The calcite of these calcite compositions (SGMC1) is produced in large quantities as quick lime by decarboxylation of calcium carbonate such as limestone under a thermal atmosphere of about 950 ° C. or higher. Steel, chemical industry, paper, building materials, It is used in a wide range of fields such as fertilizers, agricultural chemicals, and soil improvement, and is inexpensive and easily available.

  Calcium hydroxide (slaked lime) is produced by adding water and digesting calcium oxide prepared as quick lime. Chemical industry (sugar, leather, bleached powder), construction / building materials, fertilizers, agricultural chemicals, It is used in large quantities in a wide range of fields such as soil stabilization treatment, is inexpensive and easily available, and can be suitably adopted as a representative enemy calcium composition of the present invention.

［式中；Ｔはアルミニウム、ケイ素、窒素、リン、炭素元素群の単独ないし２種以上の組み合わせの元素、Ｘはハロゲン元素、ａ、ｂ、ｃは零を含む１０以下の数、ｍは０．５ないし６．０の数、ｗは零を含む２８，０以下の数］で表されるカルシウムのオキシ酸塩化合物の正塩または塩基性塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなるカルシウム化合物を酸化物基準で少なくとも３０質量％含有しているカルシウム塩化合物から選択することができる。The calcium salt composition adopted for the calcium composition includes the following compositional formula (5)

[Wherein, T is an element of an aluminum, silicon, nitrogen, phosphorus, or carbon element group alone or a combination of two or more, X is a halogen element, a, b, and c are numbers of 10 or less including zero, and m is 0 A number of 0.5 to 6.0, and w is a number of 28,0 or less including zero], or a single or two or more kinds selected from the group of normal salts or basic salt compounds of calcium oxyacid salt compounds A calcium compound composed of a combination can be selected from calcium salt compounds containing at least 30% by mass based on oxides.

  Specific examples of the calcium salt composition include natural minerals, industrial chemicals, and by-products such as calcium aluminate, calcium silicate, and calcium nitrate, which are basic or normal salt compounds. Suitable examples include calcium phosphate, phosphate ore, calcium carbonate, limestone, and calcium chloride.

  Among the calcium salt compositions selected as the calcium composition, calcium carbonates such as marble, limestone, waste shells, and synthetic calcium carbonate are easily available and suitable. In addition, in the present invention, since the mixed raw material using the calcium salt composition as a raw material is heat-treated, it is not necessary to perform a decarboxylation step in advance, and calcium carbonates can be directly used as a raw material for the mixed raw material.

  The waste composition adopted for the calcite composition includes lime neutralized sludge, waste gypsum made of by-product or gypsum board, slag of blast furnaces and steelmaking, and waste calcium silicate for heat insulation and insulation. It can be selected from wastes mainly composed of a calcium salt compound consisting of a single or a combination of two or more selected.

  Cement compositions adopted for the calcite composition include Portland cement, mixed cement (blast furnace cement, silica cement, fly ash cement, etc.), special cement white cement, alumina cement, super fast setting cement, colloidal cement, oil well cement, It can be selected from hydraulic cement minerals consisting of one or a combination of two or more selected from the group of geothermal cement and swelling cement.

  Charcoal cal-modifying composition adopted as the calcia composition includes hydrochloric acid, sulfuric acid, sulfurous acid, nitric acid, nitrous acid, silicic acid, aluminosilicic acid, and aluminium with respect to 100 parts by mass of calcium carbonate mainly composed of calcium carbonate. It is possible to select from a carbonized cal-modified composition that has been decarboxylated by adding 50 parts by mass of an acid radical consisting of a single or a combination of two or more selected from the group consisting of acid, boric acid and phosphoric acid and heat-treating it at 980 ° C. it can.

  Specific examples of the char-modified cal-modified composition selected as the calcia composition include hydrochloric acid, sulfuric acid, sulfurous acid, and nitric acid with respect to 100 parts by mass of natural meteorite, calcite, marble, shells and the like mainly composed of calcium carbonate. , Nitrous acid, silicic acid, aluminosilicic acid, aluminate, boric acid and phosphoric acid are added alone or in combination of two or more acid radicals at least 30 parts by mass and heat-treated within a range not exceeding 1000 ° C. Preferable examples of the carbonized cal-modified composition are decarboxylated.

  In particular, shells such as scallops and oysters are a treasure house as a calcium component raw material. However, since the shell is mainly composed of calcium carbonate, it is left unusable and disposed of. Adopting this shell as a raw material of the mixed raw material of the present invention is effective in reusing the shell. Moreover, applying shellfish as raw material to solidify and recycle seabed waste, etc., improves the marine environment by recycling waste that must be disposed of (such as sludge) using seafood waste. It is very preferable to be able to do it.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、ａは零を含む５．０以下の数、ｂは零を含む５．０以下の数、ｗは零を含む９．０以下の数］で表されるアルカリ金属またはアルカリ土類金属のアルミン酸塩もしくはアルミナ水和物の群より選ばれる単独ないし２種以上の組み合わせからなるアルミニウム化合物の粉末組成物を処理材（Ｓ）の使用目的／用途に応じて適宜選択・組み合わせて採択することができる。As the alumina composition constituting the mixed raw material of the present invention, the following composition formula (6)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, a is a number of 5.0 or less including zero, b is a number of 5.0 or less including zero, and w is 9.0 or less including zero. Use of the treatment material (S) for a powder composition of an aluminum compound consisting of a single or a combination of two or more selected from the group of alkali metal or alkaline earth metal aluminates or alumina hydrates They can be selected and combined as appropriate according to the purpose / use.

  A specific example of the alumina composition is preferably an alumina-containing compound that is soluble in an ionic alkali. In particular, an industrial chemical aluminum hydroxide can be preferably mentioned. Furthermore, various aluminum-containing compounds and minerals such as bauxite, coal ash, sodium aluminate, calcium aluminate and the like can be adopted. Furthermore, when preparing the present invention glass, there is a thermal working process in an oxidizing atmosphere, so that metallic aluminum can be selected under certain conditions.

  In the mixed raw material of the present invention, considering the composition of each of the above raw materials, at least 10 to 100 parts by weight of alumina and 15 to 150 parts by weight of alumina with respect to 100 parts by weight of silica expressed on an oxide basis. It is preferable to select and combine sodium oxide so that a basic composition ratio in the range of 1 to 30 parts by mass is ensured and combined as a raw material. In addition, in the basic composition ratio regarding the mixed raw material, when each raw material contains a component (for example: water, carbon dioxide, nitrate radical, organic component, etc.) that is released by heat treatment, It is necessary to determine the content of the mixed raw material.

  In the mixed raw material of the present invention, when the constituent of the calcium component is less than 15 parts by mass with respect to 100 parts by mass of silica, in the processing material of the present invention, it is activated by the reaction between the aqueous activator and the sodium salt compound. There is a tendency that the role of activated calcium is not fully fulfilled. Further, when the calcium component is more than 150 parts by mass, the network structure of the silica polymer composed of siloxane bonds formed becomes weak and the object of the present invention cannot be effectively achieved.

  Further, when the amount of alumina constituting the mixed raw material is less than 15 parts by mass, the formation of zeolite or zeolite precursor necessary for the function of the active inorganic molded product is not completed, and it is not preferable. The network structure of the silica polymer becomes weak, and the object of the present invention cannot be achieved efficiently.

  In the present invention, in addition to calcium glass as a constituent component of the treatment material, a sodium salt compound is an essential component in addition to sodium glass, and therefore, sodium oxide components may already be present in the calcium glass. Therefore, it is possible to select a raw material composition in which sodium oxide coexists in the range of 30 parts by mass as the composition component constituting the mixed raw material.

  The raw materials mixed and blended by selecting and combining the above components / compositions are subjected to a thermal working process maintained at least at 820 ° C. for at least 15 minutes to reduce crystallization or crow mainly composed of silicate. It is preferable as a calcium silica suitable for the purpose of the present invention because it is made of an inert compound that has been converted into a glass and is prepared to have a water elution pH of less than 12.

  In the thermal working process, heat treatment at a temperature lower than 820 ° C. is not sufficient for the low crystallization / vitrification reaction of the mixed raw material, which is not satisfactory as a vitreous inert glass, and the water elution pH of the heat-treated product is low. Less than 12 cannot be satisfied, and the function as a processing material of the present invention including storage stability and shelf life cannot be fully exhibited at the same time.

  In order to reliably complete the inactivation in the present invention, a thermal working process at a temperature higher than 820 ° C. may be preferable depending on the composition content of the mixed raw material. However, even if the temperature condition of the heat treatment is higher than 1000 ° C., there is no problem as a vitrification condition for the calcareous glass of the present invention, but a high temperature is not preferable because energy is wasted.

  The heat-treated product recovered by heat-treating the mixed raw material of the present invention is processed according to the present invention, which comprises, as a constituent, a calcia glass that is classified and recovered as a fine powder that has passed through at least a 100-mesh sieve by a dry grinding method known in the art and publicly The material is preferable because it quickly activates the reaction via water and sufficiently exhibits the functionality required for the treatment material.

  In particular, in the present invention, slag discharged from a blast furnace and steelmaking of a steel mill adopted for a calcium composition and charcoal cal-modified compositions are subjected to a thermal history and contain calcium silicate as a main component. The basic composition ratios of silica, alumina, and calcium required for calcium glass are already satisfied.

  In addition, the pulverized products of the calcite compositions that have already undergone these thermal histories have already been inactivated with a water elution pH of less than 12, so that thermal work requiring further thermal energy is required. It is preferable because it can be directly adopted and incorporated as a constituent component of the treatment material of the present invention, as a glass having a shelf life required for the treatment material of the present invention, without any steps.

4). "Sulfate" that constitutes the treatment material
In the treatment material of the present invention, in addition to the essential constituents consisting of the powdered form of deactivated calcium glass and the powdered form of active active silica, a predetermined amount of the powdered form of sulfate is added as a hydration inducer. It is important to form a dense solid matrix by depositing and producing hydrated crystals composed of sulfate in the gaps of the network skeleton composed of the silica polymer constituting the cured matrix of the present invention. .

  As the sulfate of the present invention, a compound or composition having various sulfate groups can be suitably selected and blended according to the purpose and application of the present invention. However, calcium sulfates that form water-containing crystals can be particularly preferably used as the sulfate that can effectively reinforce strength by imparting denseness to the cured product formed of the treatment material of the present invention.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒは３価のアルミニウムないし鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金属元素のオキシ酸塩化合物の塩基性塩または正塩の群より選ばれる単独ないし２種以上の組み合わせからなる硫酸根保有化合物や組成物を挙げることができる。The sulfate of the present invention generally has the following composition formula (2)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is trivalent aluminum or iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. And a sulfate group possessing compound or composition comprising a single salt or a combination of two or more selected from the group consisting of a basic salt or a normal salt of an oxyacid salt compound of a metal element represented by it can.

  Furthermore, as the sulfate in the present invention, the sulfate-containing composition represented by the above general composition formula (2) is further classified, and a gypsum-type composition containing a calcium sulfur oxyacid salt as a main component, Three types, the alum-type composition containing aluminum sulfate as the main component and the mirabilite-type composition containing sodium sulfate as the main component, can be preferably mentioned as the sulfate of the present invention.

［式中：Ｚはアルカリ土類金属のカルシウムないしマグネシウム、ｂは１０以下の数、ｎは２または３の数、ｗは零を含む２以下の数］で表されるカルシウムの硫黄のオキシ酸塩を好適に挙げることができる。As a gypsum-type composition of sulfate, the following composition formula (2-A)

[Wherein Z is an alkaline earth metal calcium or magnesium, b is a number of 10 or less, n is a number of 2 or 3, and w is a number of 2 or less including zero] Preferable examples include salts.

  Calcium sulfate, which is a gypsum-type composition, is known in seven types, dihydrate, hemihydrate, and anhydrous salt, in which crystal water interconverts with temperature. In the present invention, any gypsum can be adopted, and there is no significant difference in the effect on the object of the present invention. However, dihydrate gypsum is common because of the availability of gypsum.

  In addition, calcium sulfate, which is a gypsum-type composition, can suitably select waste gypsum that is by-produced and disposed of in the production of phosphoric acid and titanium oxide (titanium white) such as pigments. . In addition, the gypsum board used in large quantities in the construction industry can be suitably selected as a sulfate raw material because the waste gypsum board used as construction waste is collected in a dry manner.

［式中：Ｍはアルカリ金属元素類、Ｒは３価のアルミニウムないし鉄、ａは０．２ないし２０の数、ｃは１ないし２０の数、ｗは零を含む２５以下の数、ｎは２または３の数］で表されるアルカリ金属を含むアルミニウムまたは鉄の硫黄のオキシ酸塩の塩基性塩もしくは正塩の群より選ばれる単独ないし２種以上の組み合わせの明礬型組成物を挙げることができる。As a clear composition of sulfate, the following composition formula (2-B)

[Wherein, M is an alkali metal element, R is trivalent aluminum or iron, a is a number of 0.2 to 20, c is a number of 1 to 20, w is a number of 25 or less including zero, n is A clear type composition of one or a combination of two or more selected from the group of basic salts or normal salts of aluminum or iron sulfur oxyacid salts containing an alkali metal represented by the number 2 or 3] Can do.

  A typical example of the alkali metal aluminum or iron sulfur oxyacid salt that is an alum-type composition is an octahedral double salt crystal formed from a mixed solution of aluminum sulfate and potassium sulfate. As the sulfate radical composition of the present invention, aluminum sulfate and iron sulfate having zero a in the composition formula (2-B) can also be effectively adopted.

  Moreover, since the treatment material of the present invention is expected to produce zeolites in the formed solidified / cured body, the coexistence of an aluminum component is preferable. Therefore, in the present invention, an alum-type composition in which an aluminum component coexists with a sulfate radical component is very effective. In addition, when arsenic coexists as an immobilization target for heavy metals, the coexistence of iron ions is effective for immobilization, and from this aspect, the iron-containing clear composition (2-B) is effective and effective. It is.

  Accordingly, powdered aluminum sulfate (band), which is widely used as a water treatment material for industrial chemicals, is suitable as a sulfate raw material of the present invention, and as a waste acid when minerals such as clay are further treated with sulfuric acid. The iron-containing aluminum sulfate containing iron produced as a by-product can be suitably adopted.

［式中：Ｍはアルカリ金属元素、ａは１ないし２０の数、ｗは零を含む２０以下の数、ｎは２または３の数］で表される塩基性塩もしくは正塩のリチウム、ナトリウムもしくはカリウムであるアルカリ金属の硫黄のオキシ酸塩化合物群より選ばれる単独ないし２種以上の組み合わせの芒硝型組成物を好適に挙げることがきる。As the mirabilite type composition of the sulfate radical composition, the following composition formula (2-C)

[Wherein, M is an alkali metal element, a is a number of 1 to 20, w is a number of 20 or less including zero, and n is a number of 2 or 3] Alternatively, a single salt type or a combination of two or more types selected from an alkali metal sulfur oxyacid salt compound group which is potassium can be preferably mentioned.

  The representative compound of the oxyacid salt compound of alkali metal that is lithium, sodium or potassium, which is the mirabilite type composition (2-C), is naturally produced as mirabilite (sodium sulfate) or anhydrous salt, Produced in the rock salt production area as a double salt with a certain gypsum.

  Industrially, it is by-produced as a by-product mirabilite etc. at the time of waste liquid processing such as human silk and waste liquid. Natural or synthetic or by-product mirabilite containing impurities can also be suitably adopted. In addition, a compound containing a double salt or basic salt containing potassium, a salt compound of an alkaline earth metal, a mixed salt coexisting with a carbonate, or the like can also be suitably adopted as the mirabilite type composition.

  In addition, when the alkali metal of sulfate in the mirabilite type composition is sodium, it is necessary to consider the amount of sodium element contained and contained as a sodium salt compound to be used together, and occupies the entire treatment material of the present invention It is necessary to strictly adjust the types and blending amounts of the sulfate and sodium salt compounds so that the amount of sodium oxide is in the range of 20% by mass.

  In the treatment material of the present invention, silica glass, active silica, and sulfate raw materials selected in accordance with the purpose and application of the present invention and the required functionality may share their roles. In such a case, the quantity as the raw material for the processing material is preferable because it decreases, but it is necessary to select the quantity ratio necessary for its functionality and role.

5). "Active silica" that constitutes the treatment material
The treatment material of the present invention is prepared by using, as a reaction initiator, an active silica powder that is active together with sulfate, which will be described later, with respect to an inert Kalsha glass powder prepared by heat treatment of a mixed raw material prepared in advance. It can be provided as a treatment material that can be fixed in one pack to ensure shelf life and form a cured body.

The active silica adopted as an essential component of the treatment material in the present invention has an active alkali silanol group and water-soluble sodium, and the reaction initiator is used when the treatment material starts the reaction via an aqueous activator. It is very important because it plays a role as.
Generally, an alkali silanol group is produced as an alkali salt of a silanol group produced by reacting silicic acid or a silicate with an alkali. The active silica of the present invention is a generic term for compounds having an alkali silanol group that has an ionic alkali.

  In particular, in the present invention, the reaction that is started by contacting the water-based activator with the treatment material is the calcium silicate or aluminum silicate of the calcium glass in which the alkali is co-existing when the reaction is started by contacting the water-based activator with the active silica. The basic point is that the alkali is immobilized by the reaction to produce a water-insoluble alkali salt compound (zeolite) of aluminosilicate.

  In parallel with the formation of the network matrix, which is the basic skeleton formed by the silica polymer composed of the polysiloxane bond formed here, calcium sulfate as the coexisting sulfate component, calcium silicate from the calcium glass component, etc. and alkali of aluminosilicate Hydrated minerals such as salts are deposited and formed in the gaps of the network matrix, and the matrix is constructed by giving strength to the cured body forming the inorganic molded article of the present invention.

  The active silica in the present invention is divided into two types: single active silica obtained by modifying a single alkali silicate or silicate raw material with a sodium salt compound, and composite active silica obtained by coexisting a silicate compound and a sodium salt compound. Can be mentioned.

［式中；Ｍはナトリウムやカリウムのアルカリ金属］で表されるアルカリシラノール基を保有しているケイ酸アルカリを主成分とする単一素材、またはシラノール基を保有するケイ酸化合物とナトリウム塩化合物との複合素材からなる活性な粉状体であることが好ましい。単一アクティブシリカの具体的な例は、アルカリシラノール基を保有するケイ酸アルカリならびにナトリウム変性ケイ酸の群より選ばれる単独ないし２種の組み合わせからなるケイ酸アルカリを主成分とする粉状体を挙げることができる。As the single active silica which is an active silica having an active alkali silanol group constituting the treatment material of the present invention, the following compositional formula (1) is basically used.

[Wherein M is an alkali metal such as sodium or potassium] a single material mainly composed of an alkali silicate having an alkali silanol group, or a silicic acid compound having a silanol group and a sodium salt compound It is preferable that it is an active powdery body made of a composite material. A specific example of the single active silica is a powdery substance mainly composed of an alkali silicate composed of a single or a combination of two selected from the group consisting of alkali silicate having an alkali silanol group and sodium-modified silicic acid. Can be mentioned.

［式中：Ｍはアルカリ金属元素、ａは０．１ないし４の数、ｗは１．ないし１０の数］で表されるケイ酸アルカリの群より選ばれる単独ないし２種以上の組み合わせからなるアルカリシラノール基保有のケイ酸アルカリからなる活性な粉状体を挙げることができる。特に、ケイ酸アルカリは、一般には水ガラスとしてＪＩＳ化され、汎用されており、入手しやすいことから本発明の単一アクティブシリカとして好ましい。特にケイ酸ナトリウムは、水ガラスの中でも汎用されており、安価であることから好ましい。The alkali silicate as the single active silica of the present invention has the following composition formula (3):

[Wherein, M is an alkali metal element, a is a number from 0.1 to 4, and w is 1. Or an active powdery substance composed of an alkali silicate having an alkali silanol group and comprising a single or a combination of two or more selected from the group of alkali silicates represented by the number of thru 10]. In particular, alkali silicate is generally used as the single active silica of the present invention because it is generally JISed as water glass and is widely used and easily available. In particular, sodium silicate is preferred because it is widely used in water glass and is inexpensive.

  The other single active silica of the present invention is preferably a single active silica composed of an alkali-modified silicate having a silanol group obtained by modifying a silicate raw material with a name trim salt compound. As the silicate raw material, a silicate composition selected from the mixture raw materials in the calcium glass can be preferably exemplified.

［式中；Ｔはケイ素、アルミニウム、窒素、硫黄、炭素、ホウ素、リン元素群の単独ないし２種以上の組み合わせ元素、Ｘはハロゲン元素、ａおよびｂは零を含む１０以下の数、ｍは０．５ないし６．０の数、ｗは零を含む１２以下の数］で表されるナトリウム塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる活性な粉状体が好ましい。The above sodium salt compound has the following composition formula (7):

[In the formula, T is silicon, aluminum, nitrogen, sulfur, carbon, boron, phosphorus element group alone or in combination of two or more elements, X is a halogen element, a and b are numbers of 10 or less including zero, m is An active powdery substance consisting of a single or a combination of two or more selected from the group of sodium salt compounds represented by the number of 0.5 to 6.0 and w is a number of 12 or less including zero] is preferred.

  The sodium-modified silicic acid is a mixture obtained by adding 1 to 30 parts by mass of a sodium salt compound and 100 parts by mass of water in an amount of 50 parts by mass or less with respect to 100 parts by mass of the silicate composition. Active sodium-modified silicate single active silica containing at least 50% by mass of an active alkali silanol group-containing alkali silicate, which is denatured by reaction, dehydrated, dried, pulverized and classified as necessary A powdery body is preferred.

  Specific examples of sodium-modified silicic acid are shown in Reference Example 2 of the Examples. In the present invention, a calcium glass prepared by treating three components of a silicate composition, a calcium composition, and an alumina composition part at a temperature of 820 ° C. or higher is added with a sodium salt compound. In addition, the mixed composite raw material in which the four components are combined can be treated at a temperature of 820 ° C. or higher, and the alkali-modified silicic acid of calcium glass and active silica can be simultaneously and efficiently prepared.

  As the silicate raw material of this sodium-modified silicic acid, any silicate composition selected as a mixed raw material of calcium glass can be suitably selected. Single or 2 selected from the group of crystalline mineral lamellar clay minerals, layer-ribbon minerals, rocks, low crystalline / amorphous minerals, volcanic products, wastes and various natural and synthetic silicates The silicate raw material which consists of a combination of a seed | species or more can be selected suitably.

  Examples of silicates used as raw materials for sodium-modified silicic acid include kaolinite, serpentine, pyroferrite, talc, smectite, montmorillonite stone group, vermiculite, mica group, ryokdeite as a layered clay mineral of crystalline mineral Layers-ribbon minerals such as sepiolite and palygorskite), low crystalline and amorphous minerals such as imogolite, allophane, hisingerite, benwesite etc .; rocks such as feldspar, quartz rock, granite, metamorphic rock, rhyolite, conglomerate Volcanic ash, lava, scoria, etc. as volcanic ejecta; water purification cake discharged from water purification plants as waste, hydrous silicic acid sludge accumulated in rivers, lakes, seas, etc., blast furnace / steel slug, fly ash, etc. Various incineration ash, etc .; various Tennobu and synthetic silicates such as aluminum silicate, calcium silicate, It not alone selected from the group of magnesium Lee acids can be mentioned silicates consisting of a combination of two or more thereof.

  Sodium-modified silicic acid is prepared by reacting an admixture obtained by adding 1 to 30 parts by mass of sodium hydroxide and 50 parts by mass or less of water with respect to 100 parts by mass of the silicate raw material at 100 ° C. or higher. Denatured and recovered as a powder containing at least 50% by mass or more of active alkali silanol group-containing sodium silicate as a powder consisting of powder that has been dehydrated, dried, crushed and classified as necessary Can be prepared.

  In the present invention, instead of a single material having an alkali silanol group as the active silica, a silicic acid compound having a silanol group and a predetermined amount of a sodium salt compound are mixed into one pack, and a silicic acid compound A powdery body made of a mixed material in which a sodium salt compound coexists can be selected as a preferred active silica of the present invention. Reasons why a composite material in which a silicic acid compound having a silanol group coexists with a sodium salt compound can be replaced with a sodium silicate having a single alkali silanol group, which is an essential component of the treatment material of the present invention. Is as follows.

  That is, even in a treatment material prepared with a treatment material that is made into a one-pack in a mixed material state, water-soluble sodium is secured, and when subjected to the utilization utilization method of the present invention via water to the treatment material, The sodium salt compound in the mixed material immediately starts to react with the silicic acid compound having an active silanol group and is transformed into sodium silicate having an alkali silanol group in the reaction system. It exists in the place which can fully exhibit the functionality as a processing material of invention.

  The silicic acid compound having a silanol group includes an activity composed of an amorphous silicic acid hydrogel, a water-free xerogel, and a hydrous ferrosilicate compound having a layered structure alone or in combination of two or more. Can be mentioned.

［式中；Ｔはケイ素、アルミニウム、窒素、硫黄、炭素、ホウ素、リン元素群の単独ないし２種以上の組み合わせ元素、Ｘはハロゲン元素、ａおよびｂは零を含む１０以下の数、ｍは０．５ないし６．０の数、ｗは零を含む１２以下の数］で表されるナトリウム塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる活性なナトリウム塩化合物の粉状体を好適に挙げることができる。The active sodium salt compound includes the following compositional formula (7):

[In the formula, T is silicon, aluminum, nitrogen, sulfur, carbon, boron, phosphorus element group alone or in combination of two or more elements, X is a halogen element, a and b are numbers of 10 or less including zero, m is Active sodium salt compound powder comprising a single or a combination of two or more selected from the group of sodium salt compounds represented by the number of 0.5 to 6.0 and w is a number of 12 or less including zero] Can be preferably mentioned.

  Specific examples of the sodium salt compound include sodium sulfate (sodium salt), sodium chloride (Shioh), sodium carbonate, sodium nitrate, sodium aluminate, sodium borate, and sodium hydroxide. It is suitable as a granular material containing soluble sodium in water consisting of the above combination. Among them, sodium hydroxide is typical, is inexpensive and easily available, and is free from other salts, so that it is preferable as a constituent of the treatment material of the present invention. However, sodium hydroxide is regulated by the Poisonous and Deleterious Substances Control Law and is dangerous and requires careful attention.

  The sodium salt compound adopted as the sodium salt compound of the present invention may coexist with potassium and lithium, which are elements belonging to the same element as the sodium element. The coexistence of potassium and lithium in the sodium salt compound basically does not specifically inhibit the function of the treatment material of the present invention, and mixing of 10% by mass or less is not a problem.

  Furthermore, another typical example of the sodium salt compound is sodium chloride which is a halogen compound. Salt is a popular sodium salt compound. However, when sodium chloride is adopted as a constituent component of the treatment material, chlorine is mixed in the treatment material, and the adoption is limited.

  Active silica obtained by adding the active sodium salt compound in an amount ratio of 30 to 180 parts by mass to 100 parts by mass of the silicate compound and mixing homogeneously is preferable as an essential component effective for the treatment material. . Even when an active sodium salt compound is mixed in an amount of 30 parts by mass or less with respect to 100 parts by mass of the silicic acid compound in the composite active silica, the functionality as a treatment material of the present invention, in particular, sufficient formation of polysiloxane bonds And the formation of zeolite precursors and the like are hindered.

  In composite active silica, even when 180 parts by mass or more of an active sodium salt compound is added to 100 parts by mass of a silicic acid compound to form a composite one-pack, free sodium that is not immobilized in the treatment material remains, resulting in a cured product. The water elution pH cannot be kept low. In addition, in the case of target materials possessing active silanol groups, such as clayey soil, hydrated silicate, clayey sludge, etc., the active silica compounded in the treatment material should be reduced as much as possible. Can do. That is, the silanol group possessed by the target material can be utilized as a necessary component for the treatment material.

6). "Auxiliary composition" that constitutes the treatment material
The treatment material of the present invention comprises a two-component treatment material obtained by adding active silica to calcium glass as an essential component. However, in the present invention, various workability and functionality are required for the treatment material corresponding to the various purposes and applications of the present invention and the various needs and conditions of the inorganic molded products of the present invention. .

  Therefore, in addition to the basic characteristics of the basic processing material of the present invention, in order to tailor the processing material (S) that can cope with various purposes / uses, needs and conditions, workability and functionality, It is preferable and necessary to provide a treatment material for a treatment material prepared by adding various auxiliary compositions to the treatment material as necessary.

  When supplying the treatment material of the present invention in a large amount at a low cost, a treatment material having a basic composition is prepared in advance as a general-purpose product with three essential components of calcium glass, active silica, and sulfate, which are the basic composition of the treatment material of the present invention. In addition, there is an advantage of providing necessary processing materials to each user by adding / complementing an auxiliary composition later in order to make this general-purpose product exhibit necessary functionality according to each purpose and application.

  The auxiliary composition suitably added to the treatment material of the present invention includes a crystal seed composition that promotes the formation of zeolite formed during the formation of a cured product, a sodium supplement composition as a supplement ingredient, and a calcium supplement composition as a supplement ingredient. , A sulfate radical composition as a supplement, an auxiliary composition that reinforces the strength of the formed cured body; a phosphate group composition, a barium salt composition, and an iron salt supplement composition that further improve the functionality of the formed cured body , 12 types of auxiliary compositions composed of a powdery body including a fibrous body composed of a material, an additive material composition, a dispersion medium composition, a carrier composition, and a function-imparting composition.

  The crystal seed composition suitably adopted as the auxiliary composition of the present invention is added and blended as a nucleus for forming crystals of aluminosilicate zeolite formed from the treated material, so that the zeolite can be quickly incorporated into the cured product. It is preferable to allow a small amount of zeolite to coexist as seed crystal for growth.

［式中：Ｍは原子価ｎ：の金属陽イオン、Ｘ＋Ｙは単位格子当りの四面体数］で表されるアルミノケイ酸の金属塩のゼオライト構造を有するゼオライトの群より選ばれる単独ないし２種以上の組み合わせからなるゼオライトもしくはゼオライト前駆体を好適に挙げることができる。As the crystal seed composition which is an auxiliary composition of the present invention, the following unit cell composition formula (8)

[Wherein, M is a metal cation of valence n :, and X + Y is the number of tetrahedrons per unit cell] selected from the group of zeolites having a zeolite structure of a metal salt of aluminosilicate represented by Zeolite or zeolite precursor composed of a combination of

  In particular, as the crystal seed composition in the present invention, a natural product can be selected, but water-glass, coal ash fly ash, or zeolite with a fixed crystal form that is industrially produced using volcanic ash as a raw material, for example, 4A type A synthetic zeolite or the like can also be selected. The seed zeolite is preferably fine particles having a particle size of 10 μm or less, preferably 6 μm or less.

  By selecting and blending the sodium supplement composition as an auxiliary composition of the present invention according to the purpose and application of the present invention, it is possible to impart a function of fixing heavy metals and a dense reinforcing function to the cured body formed of the treatment material. Zeolite formation can be supplemented.

［式中；Ｔはケイ素、アルミニウム、窒素、炭素、ホウ素、リン元素群の単独ないし２種以上の組み合わせ元素、Ｘはハロゲン元素、ａおよびｂは零を含む１０以下の数、ｍは０．５ないし６．０の数、ｗは零を含む１２以下の数］で表されるナトリウム塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる活性な粉状体から目的・用途に合わせて適宜選択して採択することが好適である。As a supplement composition for sodium which is an auxiliary composition of the present invention, the following composition formula (7), which is also adopted for composite active silica

[Wherein, T is silicon, aluminum, nitrogen, carbon, boron, phosphorus element group alone or a combination of two or more elements, X is a halogen element, a and b are numbers of 10 or less including zero, m is 0.00. A number from 5 to 6.0, w is a number of 12 or less including zero], and the active powdery substance consisting of a single or a combination of two or more selected from the group of sodium salt compounds is used according to the purpose and application. It is preferable to select and adopt as appropriate.

  In particular, powdered caustic soda, which is widely used industrially, is preferable because sodium can be replenished alone. Further, when supplementing sodium sulfate [sodium sulfate], which is also widely used industrially and powdered, is preferable because necessary sulfate radicals can be simultaneously supplemented together with sodium.

  Sodium supplemental compositions suitable for the auxiliary composition of the present invention include sodium silicate, sodium aluminate, sodium nitrate, sodium nitrite, sodium sulfite, sodium sulfate, soda ash, baking soda, basic or basic among reagents and industrial chemicals. Normal salt sodium borate, basic or normal salt sodium phosphate, sodium chloride, sodium fluoride, etc. can be selected according to the use and purpose of the present invention,

  As a material for supplementing the deficiency of the calcium component in the cured product formed in the treatment material of the present invention by selectively blending the calcium supplement composition which is an auxiliary composition of the present invention according to the purpose and use of the present invention, A preferred example of the composition is a composition selected as a mixed raw material for the glass of the present invention.

  Specific examples of the calcium supplement composition include a calcium composition, a calcium salt composition, a waste composition, a cement powder composition, and a charcoal which are adopted as the calcium composition constituting the mixed raw material of the present invention. Preferable examples include a powdery body mainly composed of a calcium oxide composed of a single or a combination of two or more selected from the group of cal-modifying compositions.

  In particular, in the present invention, as a main component of the treatment material of the present invention, a calcium glass mainly composed of inert calcium silicate is adopted. Therefore, when an active calcium supplement composition is blended, Therefore, it is necessary to give sufficient consideration to the selection of a calcium supplement composition that does not impair the storage stability of the treatment material.

  Insufficient calcium sulfate component of the hydrate in the cured product formed in the treatment material of the present invention by selectively blending the sulfate supplement composition as an auxiliary composition of the present invention according to the purpose and use of the present invention. As a material for supplementing the component, a sulfate group-containing compound of the composition formula (2) adopted as the sulfate of the present invention can be preferably exemplified.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｈは１ないし８の数、ｎは２または３の数、ｗは零を含む１０以下の数］で表される各金属元素の硫黄のオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなる硫酸根含有塩化合物類の粉状体を好適に選ぶことができる。Furthermore, the sulfate supplement composition which is an auxiliary composition of the present invention has the following composition formula (9):

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number from 1 to 8, and n is 2 or 3. Powders of sulfate group-containing salt compounds consisting of a single or a combination of two or more selected from the group of sulfur oxyacid salt compounds of each metal element represented by the number, w is a number of 10 or less including zero] Can be preferably selected.

  In order to reinforce and add reinforcement to the inorganic molded product formed by adopting the treatment material of the present invention, it is effective to add and blend various reinforcing materials. It is preferable that a reinforcing material composition is appropriately selected as an auxiliary composition (ST) that enables reinforcement at this time to be added and added uniformly.

  Examples of the reinforcing material composition that is an auxiliary composition of the present invention include metal powder, metal fiber, glass fiber, rock wool, mineral fiber, carbon fiber, wood / bamboo pulp, hemp and the like that are known and used in the industry. Preferred examples include plant fibers, organic fibers, inorganic powders, sand, gravel, heavy aggregates, lightweight aggregates, and a single or a combination of two or more fillers selected from the cullet group, fibrous materials and aggregates. Can do. Examples of the metal powder of the reinforcing material composition include metal-based powders containing alloys such as stainless steel, silicon, zinc, aluminum, nickel and iron, and oily pastes of these powders.

  The fiber material of the reinforcing material composition includes metal fiber, glass fiber, rock wool, mineral fiber, carbon fiber, vegetable fiber (wood / bamboo pulp, hemp, etc.) and organic fiber (aramid fiber, polyethylene fiber, etc.) Therefore, it is possible to favorably mention fibrous reinforcing materials that are long fibers and short fibers.

  As the aggregate of the reinforcing material composition, natural sand granulate sand, gravel, volcanic eruption scola and crushed stone, processed stones and modified stones, waste glass cullet, incinerated ash molten slug A fine aggregate having a particle size of less than 5 mmφ or a coarse aggregate having a particle size of 5 mmφ or more, which is a sized product of ceramic product or cement product waste, can be preferably used as the aggregate. Furthermore, the aggregates of the reinforcing material composition include light aggregates such as perlite and vermiculite, which have a large amount of pores by heat-treating meteorites, and heavy aggregates such as iron ore and manganese ore. Can be selected according to the inorganic molded product required in the present invention

  By selectively blending the phosphate radical composition as an auxiliary composition of the present invention in accordance with the purpose and application of the present invention, it is possible to reduce the functionality of the cured product formed from the treatment material of the present invention without lowering the functionality such as strength. The alkaline cured product can be further neutralized. Furthermore, when using the processing material of the present invention to form each inorganic molded product, rapid curing may be required from the construction conditions or workability. In such a case, it is effective to use the phosphate group composition as an auxiliary composition as a curing accelerator.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｈは１．０ないし８．０の数、ｔはＧ元素原子価÷２の数、ｗは零を含む１０以下の数］で表される各金属元素のリンのオキシ酸塩化合物群より選ばれる単独ないし２種以上の組み合わせのリンのオキシ酸塩化合物類からなる硬化促進剤を好適に挙げることができる。As a phosphate radical composition which is an auxiliary composition of the present invention, the following composition formula (10)

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number of 1.0 to 8.0, and t is G element valence ÷ number of 2 and w is a number of 10 or less including zero] Each of the metal element phosphorus oxyacid salt compounds selected from the group of single or two or more phosphorus oxyacid salts The hardening accelerator which consists of compounds can be mentioned suitably.

  The phosphate group composition suitably adopted as the auxiliary composition of the present invention is a role of neutralizing the calcium composition constituting the treatment material and the sodium salt compound to adjust the pH value of the formed product to be low. Can be fulfilled. In particular, after the formation of zeolite, which is a sodium aluminum silicate, the calcium content is insolubilized by the formation of calcium phosphate crystals, and secondary alkali pollution can be avoided.

  Specific examples of the phosphate radical composition suitably adopted in the present invention include sodium phosphate, potassium phosphate, magnesium phosphate, calcium phosphate, barium phosphate, aluminum phosphate, phosphorus, among reagents or industrial chemicals. It can be appropriately selected from titanium oxide, silicon phosphate, iron phosphate, zinc phosphate (antimicrobial agent) and the like.

  Furthermore, in the phosphate radical composition of the present invention, after treatment with a phosphoric acid chemical widely used as a surface treatment agent (parkerizing treatment agent) for metal products (automobiles, vehicles, building materials, home appliances, etc.), industrial waste As a result, sludge containing a large amount of phosphate discharged as can be used effectively.

［式中：ｊは１．０ないし８．０の数］で表される燐酸ケイ素群より選ばれる「リン酸分の徐放性」を有するリン酸ケイ素を挙げることができる。単独ないし２種以上の組み合わせのケイ素のリンであり、下記に示すFurthermore, as the phosphate radical composition of the present invention, a powdery body made of silicon phosphate that exhibits sustained release in an alkaline solution can be exemplified.
Silicon phosphate has the following composition formula (9-A)

Examples thereof include silicon phosphates having a “sustained release property of phosphoric acid” selected from the group of silicon phosphates represented by [wherein j is a number from 1.0 to 8.0]. Single or two or more types of silicon phosphorus, shown below

［式中：Ｘはリン酸ケイ素１ｇを４規定苛性ソーダ溶液１００ｍｌ中に撹拌分散せしめ、Ｘは経過時間（分）、Ｙは４規定苛性ソーダ溶液中に溶出したリン酸（リンの酸化物）量（ｍｇ／１００ｍｌ）］で表され、リン酸ケイ素のリン酸分（リンの酸化物）溶出の初期溶出量（ｂ）が２００以下であり、式中のａに相当する平均加水分解速度定数（ａ）が０．２以上の範囲にあるリン酸分の溶出状態をいう。“Sustained release property of phosphoric acid” in silicon phosphate can be evaluated by the following test method, and the following formula (T-1)

[In the formula: X is 1 g of silicon phosphate stirred and dispersed in 100 ml of 4N caustic soda solution, X is elapsed time (min), Y is the amount of phosphoric acid (phosphorus oxide) eluted in 4N caustic soda solution ( mg / 100 ml)], the initial elution amount (b) of the phosphoric acid content (phosphorus oxide) elution of silicon phosphate is 200 or less, and the average hydrolysis rate constant (a ) Refers to the elution state of phosphoric acid in the range of 0.2 or more.

  As the auxiliary composition of the present invention, a barium salt composition can be selectively blended according to the purpose and use of the present invention. Depending on the construction conditions and workability when adding a water-based activator to a single material of the treatment material of the present invention or a composite material in which the treatment material is added to the target material to form an inorganic molded product as a fluid or plastic mixture, There are times when it is desirable to ensure sufficient pot life (workable time) when construction work such as processing of admixture is required. In order to ensure the pot life of the admixture at this time, it is effective when a powdery body composed of a barium salt composition is blended with the treatment material of the present invention.

［式中：ｆは４．０以下の数、ｗは零を含む１０以下の数］で表されるアルカリ溶液に可溶なバリウム塩より選ばれる単独ないし２種以上の組み合わせのバリウム塩化合物の粉体が、処理材（Ｓ）を用いた均質混和物における作業性を調整する上で好ましい。As a barium salt composition which is an auxiliary composition of the present invention, the following compositional formula (11)

[Wherein f is a number of 4.0 or less, w is a number of 10 or less including zero] selected from barium salts soluble in an alkaline solution, or a combination of two or more kinds of barium salt compounds. The powder is preferable for adjusting workability in the homogeneous mixture using the treatment material (S).

  The adjusting function such as workability in the powdered barium salt compound adopted as the barium salt composition of the present invention can be estimated by “the soluble content of barium ions in an alkaline solution = BS”. “BS” can be evaluated by the following test method.

  "Testing method for soluble part (BS) of barium ions in alkaline solution" is a sample solution in which 10 g of barium salt compound was stirred and dispersed in 100 ml of 1N sodium hydroxide solution at 25 ° C. for 10 minutes. The barium ion amount of BS is measured as BaO, and the barium amount of BS is obtained by displaying the amount of all barium elements in the sample barium salt compound converted to BaO in%.

  In order to manage the formation of the cured product of the admixture comprising the treatment material of the present invention whose workability is adjusted by the barium salt composition, the “soluble matter BS in an alkali solution” of the barium salt composition It is preferable that it is 10% or more. When the “soluble matter in the alkali solution” is 10% or less, it is not preferable because it becomes difficult to manage the workability of the mixture.

  In general, barium hydroxide or barium oxide, which is an industrial chemical, is suitable as a barium salt compound that satisfies the above-mentioned “soluble matter in an alkali solution” and is inexpensive and easily available. However, barium silicate is preferred as the barium salt compound as a barium salt composition that does not adversely affect the formed zeolites and can ensure a sufficient working life for forming the zeolites.

  In the barium silicate as the barium salt composition, f in the composition formula (11) is preferably a number of 4 or less, and if the number is 4 or more, the activity of barium ions cannot be used effectively. In addition, the number of w in the composition formula (11) is preferably 9 or less. If the number is 9 or more, the storage stability of the barium salt compound is not ensured, and the national standard of the present invention cannot be achieved.

  When the iron salt replenishment composition is selectively blended as an auxiliary composition of the present invention, when fixing and insolubilizing the heavy metal treatment material contained in the target material containing heavy metals to be water-insoluble, especially arsenic or chromium. On the other hand, it is preferable to allow the iron salt powder to coexist in order to effectively exhibit fixation and insolubilization and effectively achieve fixation and insolubilization of heavy metals.

［式中；Ｔはアルミニウム、ケイ素、硫黄、窒素、リン元素群の単独ないし２種以上の組み合わせの元素、ｎは２ないし３の数、ｍは０．５ないし６の数、ｗは零を含む２８以下の数］で表されるカルシウムの各元素のオキシ酸塩化合物の正塩または塩基性塩群より選ばれる単独ないし２種以上の組み合わせの鉄塩化合物を好適に挙げることができる。As an iron salt supplement composition which is an auxiliary composition of the present invention, the following composition formula (12)

[Wherein, T is an element of an aluminum, silicon, sulfur, nitrogen, phosphorus element group alone or a combination of two or more, n is a number of 2 to 3, m is a number of 0.5 to 6, and w is zero. Preferred examples include an iron salt compound of a single or a combination of two or more selected from a normal salt or basic salt group of an oxyacid salt compound of each element of calcium represented by the number of 28 or less.

  A divalent or trivalent iron hydroxide compound is particularly effective as the iron salt replenishment composition suitably employed in the present invention. However, from the viewpoint of easy availability as industrial chemicals or wastes, divalent or trivalent iron chloride, iron sulfate, and metal iron can also be preferably mentioned. These metal iron, iron chloride, and iron sulfate react with the calcium composition contained in the treatment material, and also react with oxygen and moisture in the atmosphere to easily produce iron hydroxide compounds, insolubilizing heavy metals. The auxiliary effect can be exhibited.

  The additive material composition which is an auxiliary composition of the present invention can preferably include a powdery body of an additive material selected from the group of pigments, colorants and fillers alone or in combination of two or more. The additive material composition is an additive material that imparts functionality according to the needs of the products prepared with the treatment material, and is important for making the product exhibit special characteristics.

  The shape of the additive material composition of the present invention is preferably a powder or powder having a particle size of less than 50 μm. Specific shapes may be powdery, sandy, massive, needle-like, columnar, spherical, hollow, plate-like, flake-like, deformed or various shapes, depending on the purpose and application of the present invention. You can choose.

  The additive material composition suitable for the present invention includes paints, adhesives, various treatment materials generally used in plastic processing, cement processing, wood processing, etc., and materials that are well known and used in the industry. The pigments, colorants, and fillers shown below can be appropriately selected and used. However, suitable examples of the additive material composition (ST8) adopted in the present invention are not limited to the additive materials shown below.

  As the pigment, any of various extender pigments known and used in the art can be adopted. Specifically, carbon black, titanium oxide, silica fine powder (white carbon, etc.), fused silica, silicates and clays, alumina, fused alumina, shells and other calcium carbonate, magnesium carbonate, zirconium oxide, etc. are suitable. Can be mentioned.

  In addition, iron oxide (valve, etc.), iron hydroxide, chromium oxide, lead chromate (yellow lead, etc.), ultramarine, zinc oxide and zinc borate, calcined pigments of various metal oxides, inorganic colored pigments, non-oxidized Suitable pigment powders that are strong in alkalis, such as pigments, metals and alloys, and organic pigments (insoluble azo pigments, condensed polycyclic pigments, quinacridone pigments, isoindolinone pigments, cyanine blue, cyanine green, etc.) Can be listed.

  As the colorant, in addition to the above-mentioned inorganic and organic pigments, various organic coloring compounds, various inks and natural or synthetic dyes that are known and publicly used in the industry may be used alone or in combination of two or more. By selecting from the colorants, it is possible to impart the desired hue to the product.

  Fillers include diamond, glass, nitride, carbide, ceramic, ceramics, silicon oxide (silica, silica sand, silica fumes, fused silica, etc.), rock (serpentine, andesite, meteorite, etc.), clay (kaolin, bentonite, Gyrome, talc, mai or kibushi clay, etc.), calcined clay (bauxite, montmorillonite, etc.), gypsum, phosphorus ore, iron ore, manganese ore, shell, zircon sand, etc. Preferred fillers can be mentioned.

  In preparing various inorganic molded products by adopting the treatment material of the present invention, it is a necessary condition that the target material of the treatment material is dispersed and contacted sufficiently homogeneously. It is effective to blend a dispersion medium composition as an auxiliary composition in order to enable uniform dispersion.

  As the dispersion medium composition which is an auxiliary composition of the present invention, the treatment material is compatible, is an inorganic powder, is produced or discharged in large quantities as industrial or waste, and is in a powder form, Moreover, it is desirable that the material be available at low cost.

  Specific examples of natural products include kaolin, acid clay, bentonite, bauxite, caustic earth, talc, zeolite, lime powder, bauxite, perlite, gypsum, shell, silicate glass, and volcanic ash group. A granular material of 100 μm or less, preferably a fine powdery inorganic compound of 10 μm or less, in combination of more than one species is effective. In particular, a silicate material of an inorganic compound is compatible with the treatment material of the present invention. A well-suited dispersion medium composition can be mentioned.

  In addition, waste byproducts and wastes discharged from the industry can also be suitably exemplified. For example, coal ash (fly ash) emitted from thermal power plants, slugs emitted from blast furnaces in the steel industry, flue gas desulfurization, gypsum produced as a by-product from the titanium industry, and seafood waste This is preferable because waste by-products such as scallops and oysters and other crushed shell products and wastes are inexpensive and available in large quantities.

  Examples of the support composition having adsorptivity as the auxiliary composition of the present invention include charcoal, amorphous silica, activated alumina, activated aluminum silicates (for example, adsorbent having a specific surface area of 10 m 2 / g or more (for example, Acidic clay, activated clay, etc.) and a carrier composition having adsorbability of one or a combination of two or more selected from the zeolite group.

  In particular, the carrier composition of the present invention is obtained by preliminarily capturing or adsorbing sodium hydroxide, which is a soluble material, which is an activation material blended in the treatment material of the present invention, on the carrier composition. It is effective for ensuring powder properties and exhibiting functionality. Furthermore, the present invention has the technology of effectively promoting the formation of zeolites without liberating or releasing the incorporated soluble material out of the reaction system, and in particular fixing and insolubilizing soluble sodium ions. is important.

  Specific examples of the carrier composition include animals and plants containing various organic compounds and organic materials, and natural products that are collected, produced, and processed in the fields of agriculture, livestock, and fisheries. Wastes, products and fermentation residues from fermentation of various natural materials, wastes from manufacturers of paper, pulp, and textile fabrics, processing waste, and various plastics and organic matter discharged from processing sites Examples include charcoal mainly composed of charcoal recovered by dry distillation treatment of raw materials at 400 to 1000 ° C., and charcoal-silicate composites containing silica and alumina having adsorption performance. it can.

  As the function-imparting composition which is an auxiliary composition of the present invention, a powdery material comprising one or a combination of two or more selected from the group of antimicrobial agents, activators, water-repellent adsorbents and functional additives is suitable. By adding and blending according to the purpose and application of the present invention, various functionalities can be added to the modified processed products and inorganic molded products formed using the functionality of the processing material. Can do.

  Generally these functional provision compositions can be suitably selected from inorganic or organic materials or materials known and used in the art. Of course, the adsorptive carrier, antimicrobial agent, activator, water-repellent adsorbent and functional additives that are adopted in the functional composition of the present invention are limited to the materials or materials described in the claims. However, a material or a material that is combined with the treatment material (S) of the present invention to form one pack and exhibits usefulness is not excluded as the functionality-imparting composition of the present invention.

  Preferable examples of the activator that is a functional composition include aluminum phosphate, boric acid, various catalysts, and photocatalytic titanium oxide. In particular, boric acid incorporated into a polysiloxane bond is effective as a material (buffer band forming agent) that forms a buffer zone that gives play to the polysiloxane bond by incorporating trivalent boron into tetravalent silicon. .

［式中：Ｍはリチウム、ナトリウムないしはカリウムのアルカリ金元素、Ｚはマグネシウム、カルシウムないしは亜鉛のアルカリ土類金属、ｇは１．０ないしは４．０の数、ｗは零を含む１０以下の数］で表されるアルカリ金属ないしはアルカリ土類金属のホウ素のオキシ酸塩の群の単独ないしは２種以上の組み合わせからなる各元素のホウ素のオキシ酸塩化合物からなる緩衝帯形成剤を挙げることができる。As a buffer zone forming agent as an activator which is a functional composition, the following composition formula (16)

[Wherein, M is an alkaline gold element of lithium, sodium or potassium, Z is an alkaline earth metal of magnesium, calcium or zinc, g is a number of 1.0 to 4.0, and w is a number of 10 or less including zero. And a buffer zone forming agent comprising a boron oxyacid salt compound of each element consisting of a single or a combination of two or more boron oxyacid salt groups of alkali metals or alkaline earth metals represented by .

  In particular, in the present invention, when it is desired to avoid the distortion generated by the impact of hot water on the matrix formed from the treatment material, adding a buffer zone forming agent or borate which is a function-imparting composition is tetravalent. It is effective because a buffer zone can be formed by adding trivalent boron to a tight matrix made of silicon and oxygen.

  Examples of the magnetic material that is the functional composition according to the present invention include powdered materials such as ferrite, iron oxide, chromium oxide, and cobalt, which are made of general iron oxide. Furthermore, as a special magnetic material, a powdered magnetic material made of a composite metal such as iron-boron, cobalt-boron, neodymium-iron, neodymium-boron, and the like can be given.

［式中：Ｄは１価または２かの銀、銅、亜鉛もしくはニッケル元素、Ｔはカルシウム、マグネシウム、ホウ素、アルミニウム、炭素、ケイ素、リンまたは硫黄元素、Ｖは零を含む３．５以下の数、ｗは零を含む２４．０以下の数、ｙは０．５ないし１．０の数、ｘは０．５ないし３．０の数］で表わされる銀、銅、亜鉛もしくはニッケル元素の塩でカルシウム、マグネシウム、ホウ素、アルミニウム、炭素、ケイ素、リンまたは硫黄元素のオキシ酸塩化合物の群の単独ないし２種以上の組み合わせからなる抗微生物剤を好適に挙げることができる。As an antimicrobial agent which is a function-imparting composition, the following composition formula (17)

[Wherein D is a monovalent or bivalent element of silver, copper, zinc or nickel, T is an element of calcium, magnesium, boron, aluminum, carbon, silicon, phosphorus or sulfur, and V is 3.5 or less including zero. Number, w is a number of 24.0 or less including zero, y is a number of 0.5 to 1.0, and x is a number of 0.5 to 3.0]. Preferable examples include antimicrobial agents composed of a single salt or a combination of two or more of the group of oxyacid salt compounds of calcium, magnesium, boron, aluminum, carbon, silicon, phosphorus, or sulfur.

  Examples of the water-repellent adsorbent that is a functional imparting composition include organosiloxanes and organopolysiloxanes having water repellency in the adsorbent support described above, and further a liquid water-repellent agent of a fluorine compound as an inorganic adsorbent support. The supported powdery body can be suitably adopted.

  Examples of the functional additive that is a functional imparting composition include various conventionally known and publicly used functional imparting agents. Specifically, buffer zone forming agent, rust preventive agent, foaming agent, antifoaming agent, heavy metal insolubilizing material, heavy metal immobilizing material, antioxidant, anti-slip agent, water absorbing agent, anti-condensation agent, snow melting agent , Freeze thaw agent, flocculant, water treatment agent, blocking agent, preservative, swelling agent, adsorbent, incombustible / flame retardant, color former, heating element, smoke generator and the like.

  Furthermore, ultraviolet / near infrared / infrared absorbers, infrared / far infrared generators, radiation generators, light emitters, photocatalysts, explosives, initiators, elastic bodies, thermal conductors, conductors, dielectrics, antistatic agents , Electromagnetic wave absorption / shielding agent, insulating material, deodorant, deodorant, fragrance, fragrance, surfactant, repellent, insecticide, insecticide, herbicide, antimicrobial agent, antibacterial agent, preservative, various agricultural chemicals And fertilizers, plant species, various active agents and the like.

  In the present invention, the crystal seed composition, the sodium supplement composition, the calcium supplement composition, the sulfate composition, the reinforcing bone composition, the phosphate composition, the barium salt composition, the iron salt, which are auxiliary compositions of the present invention. A powdery composite auxiliary composition comprising a fibrous material comprising a single or a combination of two or more of the group of the supplement composition, additive material composition, dispersion medium composition, carrier composition and functional composition. The auxiliary composition can be selected and blended appropriately according to the intended use of the present invention and combined with the treatment material of the present invention.

7). One-packed "treatment material"
The treatment material of the present invention is composed of an active active silica and a sulfate powder, and an inert calcium glass having a water elution pH of less than 12 that has been prepared in advance to a powder, and optionally an auxiliary composition. By adding products to make a mixed one-pack, various functionalities including processing and curing functions can be exhibited while shelf life is ensured.

  In the treatment material of the present invention, 5 to 100 parts by mass of active active silica and 3 to 200 parts by mass of sulfate are added to 100 parts by mass of inactive calcium glass, and further supplemented as necessary. The composition can be provided as a powder composition that is added in an amount of 1 to 400 parts by mass and mixed into one pack.

  In the treatment material of the present invention, any one of the essential three components of the powdery material of inert calcium glass, the powdery material of active active silica and the powdery material of sulfate is the basic component shown here. When the amount ratio is not satisfied, the treatment material cannot complete the hydraulic reaction / treatment activated via the water-based activator, and the treatment material must exhibit water resistance, heat resistance, low alkalinity The modified product and the inorganic molded product cannot be recovered, and the functions such as immobilization of heavy metals and capture / decomposition of dioxins cannot be exhibited.

  In the treatment material of the present invention, when the amount of active silica added to 100 parts by mass of the calcium glass is less than 5 parts by mass, the inactive calcium glass cannot be activated, and the treatment material of the present invention is required. It cannot exert its characteristics. Moreover, when more than 100 mass parts is mix | blended, the modified process goods and hardened | cured material which are formed by utilizing the processing material of this invention cannot be obtained with a low alkali.

  Further, in the treatment material of the present invention, when the amount of sulfate added to 100 parts by mass of the calcia glass is less than 3 parts by mass, the strength sufficient for the cured product required by the inorganic molded product of the present invention is obtained. I can't. Further, when an amount greater than 140 parts by mass is blended, the amount of polysiloxane bonds forming the basic matrix of the cured product of the present invention is reduced, and a satisfactory modified product or cured product cannot be obtained. .

  However, in the present invention, particularly when the main purpose is fixation / insolubilization of heavy metals and capture / decomposition of dioxins, for example, heavy metals are in situ in soil soil contaminated with heavy metals or dioxins. When carrying out fixing / insolubilization treatment or dioxin capture / decomposition treatment, it is not preferable for the treated soil ground to solidify into a solid concrete for subsequent use of the treated ground. Therefore, in the treatment material according to the present invention for these purposes, the amount of sulfate added to 100 parts by mass of the calcia glass is greater than 3 parts by mass, but preferably less than 10 parts by mass. It is preferable without stiffening.

  Furthermore, the blending amount of the auxiliary composition blended in the treatment material of the present invention is determined by the purpose / use and workability of utilizing the treatment material, and further the calcia glass blended in the treatment material according to the situation at the construction site, In consideration of the contents of active silica and sulfate, it is necessary to determine the type and amount of the auxiliary composition to be blended and the blending contents based on the results of preliminary experiments conducted as necessary.

  In addition, in the case of calcia glass, active silica, sulfate, and the composition and composition content of the auxiliary composition constituting the treatment material of the present invention, if the compound or composition content to be adopted for the treatment material of the present invention is the same or similar, Sometimes a single compound or composition can serve a dual role. In such a case, it is preferable because the same compound or composition component can exhibit at least two different roles. Sodium sulfate (sodium salt), which is given as an example where the same compound or composition component plays a dual role, can be active silica and simultaneously play a role as sulfate. In addition, aluminum sulfate (sulfate band) is an alumina composition that constitutes a mixed raw material for preparing calcium glass, and at the same time can serve as a sulfate.

  Furthermore, as an example that plays a dual role, water glass which is an alkali silicate of an silicate composition and an active silica silicate, a gypsum composition of a sulfate and a calcium composition, an alumina composition And sodium aluminate which is a sodium salt composition, silicate compound which is a raw material alkali-modified silicate raw material of active silica, and silicate compound of silicate composition.

  Each component blended in the treatment material of the present invention effectively exhibits the functionality of the treatment material of the present invention even if the same component is selected as a component that can fulfill two roles by exhibiting separate functionality. When possible, it is preferable because the number of raw material species adopted as a raw material for the treatment material can be reduced. Specific examples capable of exhibiting such a plurality of roles with the same compound or composition component are further described in the examples described later.

  In the treatment material of the present invention, when various modified treatment products or inorganic molded products are prepared using a treatment material via a water-based activator, depending on the target material to be described later, components constituting the treatment material are used. In addition, among the target materials, for example, blast furnace slag, fly ash, incineration ash and the like, which are target materials, can be actively used as component materials of the processing material.

  Furthermore, in the present invention, it is important that the treatment material of the present invention is a powdery body in order to ensure shelf life and effectively exhibit the functional effects of the treatment material of the present invention. As the granular material in the treatment material of the present invention, it is generally important that the treatment material is a granular material composed of fine particles of 100 μm or less, preferably 50 μm or less, so that the treatment material effectively activates the reaction via water. is there.

  When the particle size of the component constituting the treatment material is larger than 50 μm, the reaction caused by the treatment material of the present invention via the aqueous activator occurs only on the surface of the composition summary, and the reaction / treatment function is more efficient. Is not preferable. However, in the auxiliary composition of the present invention, if there is no problem in workability, it is also possible to adopt a granular material having a fiber shape, sand shape, flake shape or the like as a constituent of the treatment material of the present invention.

  In addition, since the treatment material of the present invention can be used as a treatment material corresponding to the environment, the one-pack treatment material contains a pollutant harmful to the environment with a content below the environmental standard value established by the country and a water elution amount. It is preferable to be provided in a pollution-free type composed of the above materials.

  The process of making the treatment material of the present invention into one pack is based on the purpose, application, and workability of the treatment material for each of the prepared powdery glass, active silica, and each powder prepared as an auxiliary composition as necessary. It can be achieved by a simple homogeneous mixing operation using various mixing devices known and used in the industry.

  The packaging form of the treated material of the present invention has a shelf life with stable shelf life, so that the treated powder is completely blocked from natural water and carbon dioxide gas. Although it is not necessary to have a packing form to be used, it is preferable to have a packing form that is effective for movement and workability and can be moved without scattering the powdered product.

8). Processing / Curing Functionality of “Treatment Material” Demonstrating the functionality of forming the treated body or cured body / bundled body of the processing material of the present invention, the reaction that is initiated via an aqueous activator is completed, and water resistance The heat-resistant and low-alkaline modified or inorganic molded product with water elution pH of less than 12
1. Formation of polysiloxane bond (-Si-O-Si-) n by sodium removal. 2. Formation of zeolite precursors such as sodium immobilization Formation of hydrated crystalline minerals such as calcium silicate and calcium sulfate.

  The above three reactions that the treatment material of the present invention is activated via the aqueous activator are basic reactions that are initiated when the treatment material is in contact with the aqueous activator, but are intended for use of the treatment material of the present invention. Depending on the type of the target material to be used, the purpose / application and workability of the present invention, it is preferable that the degree to be exhibited by the above-mentioned three points of reaction is given with some strength.

  In the above three-point reaction in which the treatment material of the present invention is activated via an aqueous activator, a silica polymer composed of siloxane bonds formed by condensation of active alkali silanol groups of active silica possessed by the treatment material is formed. It is important that the aluminum silicate, which is also possessed by the treatment material, captures and reacts with sodium ions released when forming a zeolite or zeolite precursor, which is a water-insoluble compound, at least at room temperature.

  The ability of the treatment material of the present invention to immobilize water-soluble sodium as a water-insoluble zeolite or zeolite precursor is a low-alkaliness treatment or hardening when the target material is modified or processed and prepared by the treatment material of the present invention. It enables the formation of body and binder.

  Furthermore, the treatment material of the present invention has a functionality capable of immobilizing water-soluble sodium as a water-insoluble zeolite or zeolite precursor. At the same time, when water-soluble heavy metals coexist, it fixes sodium ions. As described above, it is possible to form a water-insoluble zeolite or zeolite precursor incorporating heavy metals by binding to the formed zeolite or zeolite precursor to prevent diffusion of heavy metals into the aqueous environment.

  Furthermore, dioxins are a general term for compounds including isomers of polychlorinated dibenzopararadixin. Accordingly, dioxins are stable and toxic compounds, and the decomposition and removal of dioxins including PCB is an important environmental issue. The treatment material of the present invention can exhibit the function of capturing and decomposing dioxins by the function of immobilizing water-soluble sodium as a water-insoluble zeolite or zeolite precursor.

  That is, for example, at the current position of contaminated soil ground containing dioxins, when the treated material of the present invention is mixed into the contaminated soil through the contained water in the same manner as in the case of contaminated soil ground due to heavy metals, Calcium and sodium contained in the material come into contact with dioxins in a dry state, and the dioxins can be decomposed into chlorine and an organic part.

  Suitable target materials when using the treatment material of the present invention to exhibit the curing function include sand particles, fillers, hydrous soils, contaminated materials, adsorptive powders, heat resistant powders, alkali silicates A target material composed of a single material or a combination of two or more selected from the group of system materials (alkali silicate single product, water glass composite product) and galactor aggregates can be preferably mentioned.

Suitable target materials to be used when the treatment function of the present invention is utilized include sand particles, fillers, hydrous soils containing water-soluble heavy metals, dioxins, water-soluble chlorine, etc. Suitable for target materials that have a problem consisting of a single material or a combination of two or more selected from the group consisting of contamination materials, adsorbent powders, heat-resistant powder particles, alkali silicate materials, and galactor aggregates Can be mentioned.
Of course, the target material targeted by the present invention is not limited to the above target materials.

  Other specific target materials subject to the treatment method of the present invention are “environmental standard values” (tables) defined by the government in the case of elution of at least one kind of heavy metals (lead, cadmium, chromium, arsenic, mercury). 1) and is treated with the contaminated soil containing water-soluble heavy metals in the dry state or the contaminated soil ground containing moisture or the contaminated material moved or moved . Furthermore, in addition to the above heavy metals, copper, selenium, fluorine, boron, cyan, and other elements that are subject to environmental standards can be used as pollutant materials.

  Environmental standards related to soil contamination are stated in Article 16 of the Environmental Standards on Soil Contamination in Article 9 of the Environmental Pollution Countermeasures Basic Act, "Protecting human health for environmental conditions related to soil contamination, and The standards (hereinafter referred to as “environmental standards”) that should be maintained in order to preserve the living environment and the period of achievement thereof are as follows.

  Contaminated soils are listed in Table 1 as “environmental standards” for heavy metals in the “Survey and Countermeasure Guidelines Operational Standards on Soil and Groundwater Contamination”. However, “environmental standards” classify pollutants into two types, such as heavy metals (including cyanide, PCB, and agricultural chemicals) and volatile organic compounds, and a definition different from the general classification is introduced. Some exceptions are classified as non-volatile and volatile, and they are distinguished in research and countermeasures.

  In the present invention, the water-based activator that activates the reaction with the treatment material and exhibits the formation mechanism of the treated body, the cured body, and the bound body includes rainwater, groundwater, river / lake water, well water, Single or two or more types selected from the group of seawater, pool water, artificial ponds / dam water, processed water, pure water, tap water, industrial water, water discharged from the industry and by-product and treated water An aqueous activator comprising a combination can be mentioned.

In particular, it is most preferable to select water in the natural world such as river water or seawater because it is easily available at the work site and is inexpensive.
Further, the water-based active agent adopted in the present invention is not limited to the water-based active agent added from others, but water contained in the control material to be treated and cured by the processing material of the present invention, for example, It is preferable to use water held by sludge, etc., which is soft soil in hydrous soil, and low-quality mud such as rivers and sea areas.

  The field where the one-packed treatment material of the present invention is used is a field where the treatment / curing function of the treatment material of the present invention is exhibited and effectively used. The seven types of functions shown below can be representatively exemplified as the function of modifying or processing and preparing the processing material to be processed by the processing material of the present invention.

1. 1. Forming a cured body with hydraulic properties at room temperature 2. Formation of a low alkaline modified product 3. Insoluble and immobilization of heavy metals 4. Capture and decomposition of dioxins Chlorine ion capture 6. Capture of nitrogen in water Capture of phosphoric acid in water

Of these seven types of functions, the two types of functionality of “formation of cured body with normal temperature hydraulic property” and “formation of low alkaline modified product” are explained in the above-mentioned section of “treatment material”. In addition, this is a basic function of the treated material of the present invention, which is achieved by a reaction activated by the treated material of the present invention via an aqueous activator to process and prepare an inorganic molded body.
Further details will be described in the “utilizing and using” and “inorganic molded products” sections.

The other five types of functionality are the functionality exhibited in accordance with the target material to be targeted, and will be described in detail in the section of “modified product” described below.
As a typical example, the ability to take in heavy metals and fix them as water-insoluble minerals during the formation of zeolite precursors where the treatment material exhibits heavy metals that are harmful to the human body is, for example, the source of contaminated soil in environmental problems. Detoxification treatment at the position can be mentioned.

  In addition, dioxins that are harmful to the human body capture the dioxins in which the silicate of the treatment material is in an oily state, and then the high concentration of sodium and calcium alkali components that are in contact in the dry state. The functionality for decomposing dioxins can include, for example, detoxification treatment in situ on contaminated soil due to environmental problems.

  In addition, the water-soluble chlorine contained in the incineration ash and the like is captured by the zeolite or zeolite precursor formed by the treatment material of the present invention, and then modified to a water-insoluble mineral containing chlorine. The water-soluble chlorine contained in the water and the like can be improved by water recharge.

9. “Utilizing and using treated materials”
The utilization method of the treatment material for effectively utilizing and utilizing the function of forming the treated body or the cured body / binder having the treated material of the present invention is important. In particular, the reaction is initiated via an aqueous activator added as a reaction initiator to the treatment material of the present invention, and the treatment material is a single material or a composite in which various target materials coexist with the treatment material and the above-described aqueous activator. The utilization conditions and specifications for preparing useful modified processed products and inorganic molded product groups are important in the utilization method that completes the hydraulic reaction applied to a series of work steps as raw materials.

  The utilization and utilization method of the treatment material of the present invention targets the case of a single material only of the treatment material of the present invention and a composite material that is mixed and mixed by adding a predetermined amount of treatment material to various target materials. It is roughly divided into two types.

  The target materials that are targeted in the composite material of the present invention include sand particles, fillers, hydrous soils, contaminated materials (including heavy metals, dioxins, chlorine, nitrogen and phosphorus), adsorptive powder, heat resistance A target material consisting of a single particle or a combination of two or more selected from the group of powders, alkali silicate materials (alkali silicate single product, water glass composite product) and galactor aggregates can be preferably mentioned. .

  In the composite material according to the present invention, the target material may be homogeneously mixed at a ratio of 10 to 2000 parts by mass with respect to 100 parts by mass of the processing material of the present invention according to the purpose and application of the present invention. Furthermore, at least 15 parts by mass of an aqueous activator is added separately, or added simultaneously when the treated material of the present invention and the target material are mixed and mixed, or if the target material already holds the aqueous activator, retain it. In consideration of the water-based active agent, it can be subjected to a series of work steps of the present invention.

  The utilization method of preparing the inorganic molded product of the present invention is a mixing step of making an admixture with a single material or composite material via an added aqueous activator, and if necessary, converting the admixture with a molded product. And a series of three working steps comprising a curing step for reforming the admixture or the molded product into an inorganic molded product.

  The mixing step in the series of work steps for preparing the inorganic molded product group of the present invention by utilizing the treatment material of the present invention is a homogeneous integration by various means, with the water-based activator coexisting with the single product material or the composite material of the present invention. The process of mixing and mixing in the form of fluid, mayonnaise, paste, plastic, frustration, integrated, etc. to form homogeneous blends of moldable single or composite materials It is.

  A suitable mixture in the present invention is the target material 100 with respect to the single material or the composite material prepared in advance by mixing in a certain amount ratio, or at the original position where the target material to be processed exists. By adding 5 to 50 parts by mass of the treatment material of the present invention to parts by mass, and further mixing at least 15 parts by mass of water and mixing together, the mixture can be prepared as a moldable mixture.

  The mixing means in the mixing step to be integrated as an admixture in the present invention is generally a mixer, a kneader, an agitator known or used in the food industry, chemical industry, ceramic industry, civil engineering / architecture industry, etc. Machines, stirrers, reactors, dispersers, stabilizers, and other devices that enable homogeneous mixing, such as cement milk, secondary products such as concrete and ceramic products, etc. It can be easily achieved by using a mixer, a kneader or the like.

  In addition, it is possible to use a method of pouring or injecting a slurry-like treatment material into a target material in which a space is secured in a container, a bag, or the like in advance, and integrating them by a method of injecting or stirring. Of course, the mixing means in the mixing step of the present invention is not limited to the method of homogeneously mixing the target material that has been moved and brought in with a mixing device, etc. (For example, underwater such as the sea floor, rivers, dams, deep layers of the ground, etc.) A mixing step can also be performed.

  As a specific example of the in-situ in-situ mixing process, an example of a construction method constructed by improving soft ground or the like can be given. In this construction method, a powdered or slurry solidified material such as cement is injected and stirred into the deep layer of the ground under high pressure. Also in the mixing step of the present invention, the treated material of the present invention is obtained by the same deep mixing method. Target materials such as water-containing mud and contaminated ground can be mixed on site.

  Of course, when the treatment material of the present invention is mixed with the target material, the essential components of the treatment material of the present invention, such as calcia glass, active silica and sulfate, and auxiliary compositions to be added as necessary, are not in a one-packed state, respectively. A work process based on a mixing process in which a predetermined amount selected from a single item is added to the in-situ target material separately and mixed homogeneously through water in a multi-step procedure is possible, but is complicated.

  Furthermore, when processing the powdery treatment material into the target material as a modified product or a curing / solidifying material, the target material is added as necessary and mixed homogeneously through water, or a powdery one-pack treatment material, or A method of dispersing the raw material components constituting the treatment material in a predetermined amount of water in advance to make it wet, plastic or slurry, and mixing with the target material is also preferable from the viewpoint of preventing dust scattering and improving the mixing efficiency. It is valid.

  When the inorganic molded product group of the present invention needs to be processed and molded into a specific shape or non-specific shape according to the purpose and use of the present invention, the mixture prepared in the mixing step is used for each purpose and use. It is possible to shift to affirmative curing without subjecting it to a processing step in which the molding process is performed in a specific state or a mixture that is not specified.

  As a means for processing and molding the admixture in the present invention into various shapes, generally known and publicly used in this industry that are publicly known and used in the food industry, chemical industry, ceramic industry, civil engineering and construction industry, etc. It is a method of molding by vibration, pouring, pushing, hammering, casting, granulation, spraying, drawing, etc. in normal shape, pressurization, decompression, etc. in a specific shape mold, and stirring, blowing up, dispersing, etc. in an unspecified shape It can be molded by means such as injection.

  Especially in the granulation and molding of granules and aggregates, known and publicly used rolling granulation, extrusion granulation, agitation granulation, spray granulation, spray granulation, packing granulation, pelletizer, etc. Can be granulated to a particle diameter of 1 to 8 mmφ.

  Examples of specific shapes required for the inorganic molded product group of the present invention include, in the case of specific shapes, spherical, granular, hollow, rectangular, box-shaped, rod-shaped, columnar, tubular, linear, fibrous, and plate-shaped , Tile, wall, film, container, U-shaped, earthen pipe, fume pipe, fishing reef, tetrapot, brick, interior / partition / partition plate, outer wall, pots, figurine, ornaments, sleepers, bench, desk , Roof tiles, ceramics, sanitary wares, various structures, special shapes specified and other shapes.

  In addition, in the case of unspecified shapes, aggregates, granular aggregates, powder aggregates, adherents according to the target shape, non-fired and non-fired refractory materials, protective materials, thermal insulation materials, ornaments, art Articles, figurines, sand, covered sand, ground, roads, treatment plants, etc., and unspecified shapes corresponding to the original position of the target material.

  The group of inorganic molded products prepared in the present invention is not limited to inorganic molded products obtained by processing a mixture into a molded body, and is also intended for inorganic molded products that are not processed and molded. No special molding process is required for inorganic molded products such as improvement, modification to contaminated soil, and installation of straw.

  The curing process in the series of work steps for preparing the group of inorganic molded products of the present invention is to provide reaction / curing conditions to a pre-prepared admixture or molded product, ensuring water resistance and heat resistance, and water elution pH 12 It is a process for preparing and providing as an inorganic molded product suitable for each application and purpose with less than.

  The treatment condition of the curing process in the present invention is basically that the admixture or molded product is in the atmosphere at room temperature of 2 to 40 ° C., in a single atmosphere or in a multi-stage combination atmosphere in water, sea, soil or solution. In this step, the reaction and curing are allowed to proceed for at least 1 hour.

  The curing process at room temperature is preferable because it does not require special equipment or energy. However, the conditions of the curing process are not limited to normal temperature and normal pressure, and can be increased or reduced. In addition to the atmosphere, the atmosphere can be a nitrogen atmosphere in which oxygen is cut off, another inert gas, a specific gas, humidification, or a curing process at room temperature and warming in an aqueous system. Furthermore, it is also possible to irradiate the atmosphere of the curing process with infrared rays, electromagnetic waves / radiation and various wavelengths.

  Under the reaction / curing treatment conditions in this curing process, when the treatment temperature is lower than 2 ° C., it takes time to advance the reaction / curing, which is not practical. Further, when the treatment temperature exceeds 100 ° C., the evaporation of the intervening water starts abruptly and tends to hinder the formation of hydrated minerals necessary for the cured product of the present invention, which needs to be considered.

  However, even if the temperature condition in the curing process of the present invention is in the range of 40 to 800 ° C. exceeding 40 ° C., the reaction and curing of the inorganic molded product can be completed. In particular, when producing the inorganic molded products of the present invention in a production line in a factory where productivity is required, application of a curing process under heating is effective for increasing production efficiency. Moreover, a curing process at a high temperature is more effective when a means for suppressing moisture evaporation, for example, a condition for sealing / pressurizing or a means for physically suppressing evaporation is used in combination.

  In the curing process at room temperature of the present invention, the mixture or molded product is allowed to stand at 2 to 40 ° C. for at least 1 hour, and after the initial reaction has passed, various atmospheres (atmospheric pressure, various (In a replacement atmosphere with gas, etc.), in solution (pure water, rainwater, tap water, industrial water, seawater, river water, drainage, wastewater treated water, salt-containing solution, etc.), in soil or in multiple stages in the air and in the solution The reaction and curing can be progressed and completed in the atmosphere. Of course, these atmospheres are decompressed and pressurized. It can also be cured by changing under conditions such as heating and humidification.

  However, the time of exposure and standing at a predetermined temperature in the curing process of the present invention is generally 1 hour or more at normal temperature, and 12 hours is sufficient, but 2 days or more, preferably 7 days or more, Furthermore, the reaction and curing are almost completed by leaving it to stand for more than 28 days. Some special inorganic molded products may require more time than 7 days, but the required temperature and time can be confirmed by a simple experiment performed in advance.

10. About “modified product” In the present invention, the treated material of the present invention is compared with the target material to be treated that has problems (containing heavy metal, containing dioxin, containing chlorine, containing nitrogen and phosphorus, etc.). Among the processing and curing functions that we have, we emphasize the processing function and modify the target material to be processed with at least the sound of the sound. Problems with the target material (heavy metal content, dioxin content, chlorine content, Nitrogen / phosphorus content etc.) can be eliminated, and an effective modified product can be obtained.

  Specific treatment conditions in the treatment method of the present invention are based on a series of work steps through the aqueous activator described in the above-mentioned “utilizing and utilizing method” of the treatment material of the present invention. As a specific example, the processing material of the present invention is added in an amount ratio of 10 to 100 parts by mass with respect to 100 parts by mass of the target material, and at least 15 parts by mass of an aqueous activator is added separately, or the processing material of the present invention and the target A series of work steps of the present invention are added at the same time when the materials are mixed and mixed, or when the target material already holds an aqueous activator, taking into account the retained aqueous activator. Should be attached.

  In addition, it is possible to perform a series of work steps in a moving place where the target material is moved, while the work of the series of work steps via the water-based activator in the modification process of the target material to be processed can be performed. A series of work steps can also be performed in the original position where the slag exists, for example, in the soft ground or the contaminated soil ground.

A series of work steps in the processing method of the present invention includes a mixing step in which a predetermined amount of a processing material and an aqueous activator coexist with a target material to form an admixture, and if necessary, the admixture is molded. It is constituted by a series of three process steps including a process step for making a product, and then a curing step for modifying the mixture or the molded product into an inorganic molded product.
A specific example in which the functionality of the treatment material of the present invention is exhibited to modify the target material will be shown below.

  Specific target materials for the treatment method of the present invention include nitrogen content and phosphoric acid content target materials such as nitrogen content (ammonia nitrogen and nitrate) and phosphoric acid content of metallic phosphorus. Examples include low-grade hydrous mud such as harbors, rivers, lakes, and dams, and hydrous soils such as sludge containing oxide salts.

  The treatment conditions for the hydrous soil containing nitrogen and phosphoric acid in the treatment method of the present invention are as follows: moisture is contained in the range of 25% by mass to 80% by mass, and fluid or plastic hydrous soil is 100 to 100 on a dry matter basis. Addition of 100 parts by mass of the treatment material to the amount equivalent to 2000 parts by mass, and at this time, using the water contained in the hydrous soil, the mixing process for mixing with the hydrous soil is known and publicly used in the industry. -Prepare an admixture in which the treated material is homogeneously dispersed in the hydrous soil by mechanical mixing by injection or the like.

  The admixture is then subjected to a direct curing process in which it is left in a normal temperature atmosphere for at least 24 hours without subjecting it to a special processing process, so that the nitrogen content can be determined by an elution test of nitrogen (ammonia nitrogen, nitrate). The water-containing soil modified product in which the elution amount is suppressed within the environmental standard value ensures water resistance and heat resistance, and can be modified to a water elution pH of less than 12.

  The treatment conditions for preventing the elution of the heavy metals contained in the contaminated material that is the soil contaminated with heavy metals are the treatment material or slurry of the present invention with respect to the amount corresponding to 50 to 2000 parts by mass of the contaminated material on a dry matter basis. Known and publicly used in the industry through the water content treatment material in an amount equivalent to 100 parts by weight on a dry matter basis and, if necessary, at least 15 parts by weight of a water-based activator. A mixture in which the treatment material is homogeneously mixed with the contaminated material is prepared by mechanical mixing by mixing, mixing, stirring, and injection methods.

Next, by subjecting to a curing process where the mixture is left under normal conditions of normal temperature at the processing original position or moving processing position, the deformability strength value by an external pressure measured by a simple type deformability measurement test is 40 KN / m. ² or less, water-free and heat-resistant in a non-polluted product or treated soil ground that is a hardened body in which the contained heavy metals are fixed and the water elution value is secured within the range of the environmental standard value established by the country. Property is ensured, and the water elution pH can be modified to less than 12.

  In addition to the contaminated soil of heavy metals such as factory sites, the target materials contaminated with heavy metals include incineration ash of general and industrial waste, fly ash discharged from thermal power plants, sea and rivers・ Sedimentary hydrous soil such as sludge such as swamps, lakes, dams, etc., and soil in rice fields contaminated with heavy metals such as cadmium and lead.

  Furthermore, specific other target materials that are subject to the treatment method of the present invention include dioxins, and contaminated soil containing dioxins exceeding the “environmental standard value” established by the country. In-situ soil soil or contaminated material that has been moved can be used as the target material. Of course, contaminated materials that coexist with dioxins and heavy metals can also be used as target materials.

  The treatment conditions for detoxifying the dioxins of the contaminated material, such as soil contaminated with dioxins, is the treatment material of the present invention or the water content in the form of slurry with respect to the amount corresponding to 50 to 2000 parts by mass of the contaminated material on a dry matter basis The state treatment material is added in an amount corresponding to 100 parts by weight on a dry matter basis, and if necessary, at least 15 parts by weight of a water-based activator is added, and if it contains water, contaminated soil through the water including the contained water On the other hand, an admixture in which the treatment material of the present invention is homogeneously mixed with the contaminated soil is prepared by a mechanical mixing or injection mixing process known or publicly used in the art, or by mixing, mixing, stirring, or pouring.

Next, the mixture is left at normal temperature or at normal temperature at the processing or transfer processing site as the mixture, or, if necessary, at 200 ° C. or less, the moisture content of the mixture is made as close to zero as possible. By applying to the curing process in the absence of, the deformable strength value by external pressure measured by a simple deformability measurement test is 40 KN / m ² or less, and the contained dioxins are captured and decomposed and rendered harmless The water elution pH should be reduced to less than 12 by ensuring the water resistance and heat resistance of the non-polluted products or the treated soil ground where the dioxin content is reduced within the range of the national environmental standards. Can do.

  Furthermore, specific other target materials that are subject to the treatment method of the present invention include contaminated materials such as incinerated ash of wastes containing water-soluble chlorine, and hydrous soil containing seawater. Can be cited as a material.

  The treatment conditions for preventing the elution of the chlorine content of the target material containing water-soluble chlorine content and making it harmless are as follows. The amount of the target material is equivalent to 50 to 2000 parts by mass on the dry matter basis. An amount corresponding to 100 parts by mass of the treatment material or slurry-like water-containing state treatment material and, if necessary, at least 15 parts by mass of a water-based activator is added. If water is contained, the contained water is included. Processed material is homogeneously mixed into the target material through a mixing process using water, which is known in the industry as a publicly known / official mixing / mixing / stirring / injection mechanical mixing or mixing apparatus. Prepare a blend.

  Next, the admixture is prepared into a molded product obtained by molding and granulating into a structure having a specific shape, a container integrated product, or a granule having an unspecified shape in a processing step. Next, the granules that become a general civil engineering material by the treatment method consisting of a series of work steps by subjecting the molded products such as granules to a curing step that is allowed to stand in room temperature air for at least 7 days, and eluting with chlorine The amount is controlled to be equal to or less than the standard of tap water, water resistance and heat resistance are ensured, and a reforming treatment such as a granular product having a water elution pH of less than 12 can be performed.

  The modification treatment method of the present invention is to fully exhibit the multi-functionality of the treatment material of the present invention, to allow the treatment material of the present invention to act on the target material that must be treated, and to treat in the living environment. Because it is possible to modify the target materials in unforeseen circumstances and reuse them as useful resources and materials in the living environment, this is a useful technology that can deal with environmental problems by reducing the environmental burden and saving energy at a low cost. I can say that.

11. "Inorganic molded products"
In the present invention, the processing material of the present invention is obtained by utilizing and utilizing the hydraulic processing material of the present invention having water-soluble sodium and sulfate radicals of the present invention and having shelf life ensured comprising a series of work steps. Various minerals made of a low alkaline modified product having a water elution pH of less than 12 and a cured product that exhibits the function of forming a treated product or cured product / binder having a water resistance and heat resistance. A group of molded products can be provided.

  The inorganic molded product of the present invention is a single product material of the present invention only or a composite material prepared by adding the treatment material to the target material described in the section of the utilization method and treatment method. It is processed and prepared by the utilization / treatment method attached to the mixing step, processing step, and curing step in a series of work steps that activate the reaction.

  Examples of target materials that are preferably adopted for the composite material of the present invention include sand particles, fillers, hydrous soils, contaminated materials, adsorptive powders, heat-resistant powders, alkali silicate materials, and trash aggregates. There are 8 types. Of course, the target material targeted by the processing material of the present invention is not limited to the above target material.

  Of course, the present invention is not limited to the method of mixing with the permission of equipment capable of homogeneously mixing the target material that has been moved in when the target material and the treatment material to be inorganic molded products are homogeneously mixed. The processing material is brought into the local site where the target material is present (for example, underwater such as the seabed, rivers, dams, deep layers of the ground, etc.). It is also possible to target materials that are in a state in which processing and utilization methods that can be integrated and mixed are applicable.

  The inorganic molded product of the present invention can be produced in 13 types [cured body, solidified structure, composite cured body (including various secondary products), granules by using and utilizing the treatment material of the present invention according to the purpose and application of the present invention. (Including different layer / multi-layer granules), aggregates, adherents (including coconut bodies), films, hydrous soil treated soil (including in situ soft ground piles), non-polluted (including in situ heavy metals and dioxins) For the purpose of a group of inorganic molded products such as contaminated soil ground), consolidated adsorbents, heat insulating / heat insulating / heat resistant materials, acid resistant materials and integrated products].

  In addition, the inorganic molded product group that processes and utilizes the functional characteristics of the treatment material of the present invention is not limited to the preparation of the 13 types of inorganic molded product group described above, but the 13 types of inorganic molded product group of the present invention. As a basis, various inorganic molded products that have been improved, improved, deformed, combined and added by utilizing the group of inorganic molded products can be further provided.

  In the inorganic molded product in the present invention, 10 parts of the target material can be added to 100 parts by mass of the treatment material composed of three essential components of calcium glass, active silica and sulfate, and an auxiliary composition added as necessary. From 2000 parts by mass of water and at least 15 parts by mass of water as a raw material, the present invention is subjected to a series of work steps which are the above utilization / treatment methods comprising three steps of a mixing step, a processing step, and a reforming step. Each of the inorganic molded products can be processed and prepared.

  The preparation of an inorganic molded article made of a treated body or a cured body using only a single material of the treatment material of the present invention is, for example, at least 15 parts by mass of water as an aqueous activator with respect to 100 parts by mass of the single material of the treatment material. In addition, a moldable mixture can be prepared as an admixture by an intimate mixing process.

  Next, the cured product and the solidified structure are obtained by subjecting the admixture to a curing process in which the molded product is allowed to stand at room temperature for 1 hour or longer through a processing step of forming the molded product into a specific shape or an unspecified shape. In addition, it is possible to prepare a group of inorganic molded products that are ensured of water resistance and heat resistance composed of a composite cured body, a granule body, an aggregate body, and the like and have a water elution pH of less than 12.

  In particular, when the additive material composition, dispersion medium composition, carrier composition or functionality-imparting composition as an auxiliary composition is already blended into the treatment material of the present invention and made into one pack, a single material Since each of them can exhibit various auxiliary functions, the inorganic molded product group of the present invention can be prepared by selecting a single material containing an auxiliary composition corresponding to an inorganic molded product of various shapes.

  Preparation of inorganic molded product groups such as hardened bodies, structures, composite hardened bodies, granule bodies or aggregate bodies using and processing composite materials in which sand particles are combined with the treatment material of the present invention is first 1 to 50 mmφ. For a composite material in which 100 parts by mass of a treatment material is added to 10 to 2000 parts by mass of a sand granule having a particle size of 0.2 to 3.5 g / cc and a bulk specific gravity, at least 15 parts per 100 parts by mass of the composite material. By a mixing step in which at least 15 parts by mass of the water-based active agent is added in addition to parts by mass, a moldable and homogeneous admixture such as basaba, plastic, mayonnaise, paste, or fluid is prepared.

Next, the mixture is processed into a specific shape or non-specific shape and processed into a molded product, and the molded product is subjected to a curing process. Unless otherwise specified, at least a uniaxial compressive strength of 100 KN / m ² or more of a specific shape structure or composite cured body, or an unspecified shape granule or bone granulated to a particle size of 1 to 8 mmφ It is possible to prepare an inorganic molded product group having a certain strength composed of a group of materials and the like, ensuring water resistance and heat resistance, and having a water elution pH of less than 12.

  The process of preparing a specific shaped structure, composite hardened body and other inorganic molded product group utilizing and processing the composite material composed of the sand granule of the present invention is a process of molding cement-concrete secondary processed products. Sometimes, it can be molded into each specific shape by processing techniques and means generally adopted in the industry.

  Specific examples of structures of specific shapes according to the present invention, composite hardened bodies, etc. include blocks, bricks, refractory materials, foundation stones, interlocking, tetrapots, fishing reefs, partition / partition plates, outer walls, poles, pillars, Stepping stones, building materials, earthen pipes, fume pipes, pots, flower beds, ornaments, figurines, sleepers, benches, desks, tiles, porcelain. Examples include pottery, sanitary ware, and heat insulating materials.

  In the inorganic prize of the present invention, a chromeless and heat-resistant secondary processed product can be manufactured in place of a conventional cemented secondary product. Also. As it is possible to process and adjust inorganic premiums at least at room temperature, it is an energy-saving alternative to ceramic products that have been produced as pottery by consuming large amounts of energy in the ceramic industry, and does not impact the environment that does not emit carbon dioxide. An inorganic molded product that is both water-resistant and heat-resistant can be processed and prepared without firing in an environmentally friendly manner.

  The water-resistant and heat-resistant, water-elution pH of the present invention, which is an inorganic molded product that can be processed and prepared with a chromium-free, insoluble and chrome-free material, can be replaced by conventional ceramic products, particularly bricks and refractory materials, Materials, tiles, sanitary wares, containers, pots, building materials, tiles, porcelain / ceramics, ornaments and figurines can be mentioned.

  The processing step of preparing a group of inorganic molded products such as unspecified shaped granules or aggregates utilizing the composite material comprising the sand granule of the present invention granulates spheres, cylinders, granules or aggregates Therefore, granulation techniques and means generally adopted in the industry, such as growth type rolling type, vibration type, sintering type, mixing type, flow type or crushing type, compression type compression molding type or It can be processed and prepared into an inorganic molded product of granules according to the purpose by granulating means such as extrusion molding, flaker type by droplet generation, injection type or casting type.

  Specific examples of unspecified shaped granules or aggregates according to the present invention include gravel / sand substitutes, aggregates, embankments, interstitial materials, fillers, and base materials (heat insulation materials, Heat insulating material, water retaining material, shielding material, soundproofing material, deodorant, detergent, antimicrobial agent, etc.), catalyst and the like.

  When the inorganic molded product group of the present invention is a cured body such as a structure, general-purpose aggregates can be suitably adopted as the sand granule of the target material of the present invention. As aggregates at this time, “fine aggregate” made of sand, crushed stone, etc. having a particle size of 5 mmφ or less, and “coarse aggregate” made of gravel, crushed stone, etc., having a particle size of 5 mmφ or more, which are used in concrete products, etc. Alternatively, these “mixed aggregates” can be suitably selected according to the purpose and application of the present invention.

  In the present invention, in addition to the general-purpose aggregate, a crystalline, sandy, massive, granular, acicular, columnar, spherical, hollow, plate having a bulk specific gravity in the range of 0.9 to 2.5 g / cc Inorganic, organic natural materials and synthetic processed materials of various shapes such as shapes, rods, flakes, films, and unspecified shapes can be selected as the sand granules of the present invention.

  In addition, natural or synthetic lightweight aggregates (vermiculite, perlite, artificial materials, etc.) having a bulk specific gravity of less than 0.9 g / cc can also be selected as the sand granules. Furthermore, heavy aggregates [iron ore, manganese ore, etc.] having a bulk specific gravity of 2.5 g / cc or more can be appropriately selected according to the purpose and application of the present invention.

  In addition, wastes mainly composed of inorganic materials that are discarded from daily life and industry (waste glass cullet, cement product waste, ceramic product waste, recycled products, construction waste soil, incinerated ash molten slugs) Etc.) can also be suitably selected as the sand granule of the target material of the present invention.

  As an adherent using the composite material comprising the filler of the present invention, a composite material in which 100 parts by mass of a treatment material is added to 10 to 2000 parts by mass of a powdery filler having a particle size of 100 μm or less, In the mixing step of mixing through an aqueous activator to be added at least 20 parts by mass, a fibrous material of the reinforcing material composition is added as necessary to prepare a paste-like mixture.

  Next, the paste-like admixture is applied to the surface, inner surface or gap surface of various substrates in the processing step, applied, bonded, covered, multilayered, roller-coated, brushed, troweled, soaked, sprayed It is possible to obtain a molded product that is subjected to a coating process by affixing, spraying, winding, winding, patching, pouring, or pouring.

By using and utilizing a series of work steps by subjecting the molded product subjected to the coating process to the curing step, water adhesion as an adherent having a shear fracture adhesion of at least 2,000 KN / m ² is achieved. It is possible to prepare an inorganic molded product having heat resistance and a water elution pH of less than 12.

  When the inorganic molded product in the present invention is an adherent, the target material can be selected as a representative target material such as a filler made of an inorganic material that is an additive material composition that is an auxiliary composition. In particular, as the filler adopted for the adhering body, inorganic powders such as pigments, fillers, and active materials composed of fine powder having a particle size of 100 μm, preferably 50 μm or less, are used for exerting the adhesion effect. Is preferred.

  Specific examples of the adherend according to the present invention include an adhesive, a binder, a joint material, a caulking material, a filling material, a binding material, a dumping material, a hardening material, a backing material, an anchor material, a coating material, a granule and a granule. Surface glaze agent such as body, multilayer film forming material, coating material, flooring material, wall material, waterproof curtain material, paint, paint film, various functional films (antibacterial, deodorant, anti-condensation, magnetic, luminous Coloring property, antioxidant property, exothermic property, heat conductivity, insulating property, ultraviolet ray, near infrared ray, infrared ray absorbing property, electromagnetic wave absorbing property, aromaticity, insecticidal property, repellent property, etc.).

  As an example of applying the adherend of the present invention, a granular material is obtained by utilizing a paste-like admixture prepared via a water-based active agent added to a composite material composed of a filler for a group of granular materials. It is possible to prepare water-resistant and heat-resistant cocoon-like inorganic molded products (粟 -okoshi bodies) that have through-holes that allow gas and liquid to pass through. .

  The aggregate group of the granular material of the raw material is a granular group having a particle diameter of 1 to 20 mmφ, and the granule constituting the aggregate group is a lightweight material such as an inorganic silicate or pearlite. Materials, concrete, metals, ceramics, ceramic products, glass, melts, wastes, etc., organic wood, bamboo, fiber, paper, rubber, plastics, etc. can be composite products of these.

  粟 To prepare the sorghum, add the paste-like admixture prepared by using the composite material consisting of the filler to the aggregate group of the above-mentioned granule, and paste the granule surface of the aggregate group into the paste-form mixture. It can be completed by binding the aggregates of the aggregates in a state where they are coated and coated with an object and securing the voids formed between the aggregated aggregates and applying the curing process.

  例 Specific examples of scorpions are inorganic, water- and heat-resistant various liquid filters, purifiers, etc., gas adsorbers, catalyst bodies, cleaners, heat insulation materials, active materials, etc. In addition, it can be provided for applications in fields where breathability, water permeability and light weight are expected, such as soundproof wall materials, base materials such as greening plants, building materials, and civil engineering materials.

  As a film utilizing the composite material comprising the filler of the present invention, at least a composite material obtained by adding 100 parts by mass of a treatment material to 10 to 2000 parts by mass of a powdery filler having a particle size of 100 μm or less is used. In the mixing step of mixing through 15 parts by mass of an aqueous activator, a mixture that is fluid or plastic is first prepared.

  Depending on the purpose and required film form and application, the target material to be used as a composite material is not limited to a filler, but can be a filling material or auxiliary composition containing various active agents in the target material to be used as a composite material. The above paste-like admixture can be prepared by selecting a material selected from the indicated reinforcing material composition and additive material composition.

  Next, the fluid or plastic admixture prepared here is combined with a woven or non-woven fabric made of metal or inorganic fiber to form a film or plate-like specific shape film having a thickness of 1 to 20 mm. Formed into a film shape by the processing process.

  Next, the molded product formed into a film is processed in an atmosphere of 2 to 120 ° C. in air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression or pressurization. In a single atmosphere selected from the group described above or in a multi-stage atmosphere consisting of a combination of two or more, it is allowed to stand for at least 10 minutes, and the formed processed product is cured and removed from the mold as necessary. By the curing process, an inorganic premium product having an inorganic film-like, plate-like or coating-like water resistance and heat resistance and a water elution pH of less than 12 can be processed and prepared.

  The cured product or granule using the composite material comprising the hydrous soil of the present invention contains 50 to 2000% by weight of water or 25% to 80% by mass of a hydrous soil that is fluid or plastic. Homogeneous admixture in a mixing process in which water containing soil-containing soil is used and mixed through this contained water for a composite material in which 100 parts by weight of the treatment material is added to the amount corresponding to part by weight. To prepare.

Next, the homogenous mixture is formed into a molded product obtained by molding a specific shape structure, container integrated product or unspecified granule in a processing step, and the molded product is cured in the air or in water. By utilizing and using the work process attached to the structure, a specific shape or unspecified shape structure with a uniaxial compressive strength of at least 800 KN / m ² , a container integrated product, or a granule is water- and heat-resistant and is eluted with water. It can be prepared as an inorganic molded product having a pH of less than 12.

  When the inorganic molded product in the present invention is a hydrous soil treatment, the target material is a fluid or plastic sea / river / swamp containing a water content of 25% by mass or more, preferably 80% by mass or less. Hydrous soil such as sludge and mud accumulated in lakes and dams, soft soil, clay soil such as rice fields, and filter cakes generated in various water treatment plants can be suitably selected.

  Furthermore, the soft ground can be hardened by using the composite material comprising the hydrous soil according to the present invention to improve the soft ground. As the soft ground, a utilization method for constructing a series of work processes at the following original positions is suitable for the original position of a soft or soft ground having a water content of at least 20% by mass. Can adapt.

  First, the water-based activator is applied to the treatment material or the powdery material treatment material prepared in advance for the amount corresponding to 50 to 2000 parts by mass on the basis of the dry matter of the soft ground soil at the soft soil in situ, which is the hydrous soil. An amount corresponding to 100 parts by mass in terms of dry matter is prepared for a fluid or slurry water-containing treatment material added at least 25 parts by mass immediately before construction.

  Next, the powdered material treatment material or fluid or slurry-like water treatment material by the mixing process in which the hydrous soil in the original position of the target soft ground is subjected to normal pressure excavation, excavation under pressure, agitation injection or pressure injection to mix. Can be injected and mixed with stirring at a predetermined ratio if necessary to prepare a mixture to reinforce and reinforce the soft ground.

Furthermore, by subjecting the in-situ mixture to a curing process in which it is allowed to stand at room temperature in a natural environment for at least 24 hours, water resistance and heat resistance are obtained in a modified ground having a uniaxial compressive strength of at least 200 KN / m ² . Is ensured, and a board inorganic molded article made of a modified reinforcing ground having a water elution pH of less than 12 can be prepared.

  Using the technology to reinforce soft ground according to the present invention, in the original position of the soft ground, the processing material is adopted within the fixed diameter in the vertical direction of the soft ground, and the deep injection mixing method is adopted in the civil engineering industry to form a pile. Reinforced and hardened bodies can be formed, and rice fields can be reinforced with low alkalinity.

  In the case of sludge etc. that is subject to processing disposal, it becomes possible to utilize sludge etc. as a recyclable recyclable material by effectively applying the utilization method of treatment materials according to the present invention, It can be selected as an effective means for solving environmental problems.

  In addition, as a non-polluted product made into a granule using the composite material composed of the contaminated material of the present invention, one or two or more kinds selected from the group of incineration ash, sludge or pollutant of general waste and industrial waste Contaminated materials that contain more than the “environmental standards” (see Table 1) established by the country in the amount of water elution of at least one kind of heavy metals (lead, cadmium, chromium, arsenic, mercury) consisting of combinations set to target.

  In the mixing step of mixing at least 20 parts by mass of an aqueous activator, a homogeneous mixture is prepared for a composite material obtained by adding 100 parts by mass of a treatment material to 100 to 2000 parts by mass of a contaminated material on a dry matter basis. The molded product is prepared by preparing and granulating the homogeneous mixture into a specific shape structure, container-integrated product, or unspecified granule in a processing step.

  Next, the granule that becomes a general civil engineering material is used in a granule that becomes a general civil engineering material by using a utilization process consisting of a series of work steps by subjecting the molded product of the granule to a curing step that is allowed to stand in room temperature air for at least 24 hours. Therefore, it is possible to prepare a granular, non-polluted inorganic molded product having ensured properties and having a water elution pH of less than 12.

As the consolidated adsorbent using the composite material comprising the adsorbent powder of the present invention, the adsorbent powder (QA) having a specific surface area of 10 m ² / g or more is 100 to 2000 parts by mass on a dry matter basis. A homogeneous admixture is prepared in a mixing step of mixing at least 20 parts by mass of an aqueous activator for a composite material to which 100 parts by mass of a treatment material is added.

  Next, the homogenous mixture is molded into a specific shape structure or non-specific shape powder or granule in a processing step to form a molded product, and the molded product is subjected to a curing step. By using the utilization method consisting of a series of work steps, an inorganic molded product having a water resistance and heat resistance of less than water elution pH 12 is prepared with a consolidated adsorbent whose specific surface area reduction rate is suppressed within 40%. be able to.

When the inorganic molded product in the present invention is a consolidated adsorbent, the target material is further an inorganic powder having a specific surface area of 10 m ² / g or more. Specifically, silica gel, alumina gel, clays, silica Preferable examples include acid aluminums, zeolites, and charcoal.

  Furthermore, various organic compounds discarded from the fields of agriculture, forestry, livestock and fisheries, organic materials of animals and plants, fermentation fields, pruning waste materials and thinning materials for landscaping, paper / pulp fields, textiles / cloth fields, various plastics Examples thereof include charcoal-silicate powders mainly composed of charcoal obtained by dry distillation treatment of organic materials discharged from soot or the like at 400 to 900 ° C.

  In the present invention, the heat insulation / heat insulation / heat-resistant material utilizing the heat-resistant powder is heat-resistant including the waste material of heat insulation / heat insulation / heat-resistant material having a particle size of 10 to 5000 mμ which is an oxide or non-oxide. Homogeneous mixing in a mixing process of mixing at least 20 parts by mass of an aqueous activator for a composite material obtained by adding 100 parts by mass of a treatment material to 100 to 2000 parts by mass of a dry matter based on dry matter Prepare the product.

  Next, the homogenous mixture is molded into a specific shape structure or nonspecific shape powder or granule by a processing process at room temperature to obtain a molded product, and the molded product is dehydrated and heated. By subjecting it to a curing process including treatment, at least 80% heat resistance strength retention rate when exposed to an unfired heat-retaining / refractory material or 500 ° C. atmosphere that can be applied on-site without performing heat treatment molding in advance was secured. It is possible to prepare an inorganic molded product that is heat-insulating, heat-retaining, and heat-resistant and has water resistance and has a water elution pH of less than 12.

  In the case where the inorganic molded article in the present invention is a heat insulating, heat insulating, and heat resistant material, examples of the target material include inorganic powders that are resistant to oxide or non-oxide heat. Specifically, composites of magnesia, calcium, silica, alumina and oxides, non-oxides such as silicon carbide and nitrides, various crystalline aluminum silicates, calcium silicates and asbestos, and vermiculite A lightweight material such as perlite can be preferably mentioned. Of course, the above-mentioned oxides and non-oxides can be suitably used as waste materials after use as heat insulating materials, heat insulating materials, refractory materials and the like.

［式中：Ｍはアルカリ金属、ａは０．１ないし４の数、ｗは１，６ないし５０．０以下の数］で表されるアルカリケイ酸塩化合物群より選ばれる単独ないし２種以上の組み合わせからなるケイ酸アルカリ、もしくは対象素材が、ケイ酸アルカリ１００質量部に対して、砂粒体または充填材１００ないし２０００質量部を加えて複合化されたケイ酸アルカリ系素材を対象として調製することができる。The acid resistant material utilizing the alkali silicate-based material of the present invention for the composite material is the above-described composition formula (3).

[Wherein, M is an alkali metal, a is a number of 0.1 to 4, and w is a number of 1,6 to 50.0 or less] alone or in combination of two or more selected from the group of alkali silicate compounds An alkali silicate material comprising a combination of the above, or a target material is prepared by adding 100 to 2000 parts by mass of a sand granule or filler to 100 parts by mass of an alkali silicate, and preparing an alkali silicate-based material that has been combined. be able to.

  Furthermore, the acid-resistant material in the present invention is obtained by utilizing and treating a composite material composed of water glass compounded days obtained by adding 100 to 2000 parts by mass of a sand granule or filler to 100 parts by mass of the alkali silicate material. By preparing, an inorganic molded product which is an acid-resistant material with higher applicability can be prepared.

  As the acid-resistant material in the present invention, an alkali silicate-containing material alone or a composite material obtained by adding 100 parts by weight of a treatment material to 100 to 2000 parts by weight of a water glass composite product, the amount of water contained in the alkali silicate is considered. In the mixing step, the total amount of water is adjusted to at least 20 parts by mass and mixed to prepare a fluid or plastic mixture.

  Next, the fluidized or plastic admixture has a specific shape structure, a coating adhering body or an unspecified shape of powder or granule is processed into a molded product, and the molded product is processed in the natural atmosphere. Is subjected to a curing step that is allowed to stand for 24 hours to ensure water resistance and heat resistance with an acid resistant material that ensures at least 80% solids strength retention when immersed in a pH 3 acidic solution. A product can be prepared.

  The acid-resistant material according to the present invention is an incombustible and heat-resistant inorganic material, and is workable at room temperature. Therefore, it is effective as an acid-resistant flooring material for food factories, chemical factories, kitchens and the like. It is also effective as a waterway or flooring in a hot spring resort on the acidic side.

  Since the treatment material suitable for the acid-resistant material of the present invention is required to have acid resistance, the compounding amount of calcium or the like having poor acid resistance is suppressed within a range that does not impair the hardening / solidification strength, and mainly a silica polymer composed of a siloxane bond. It is necessary to select the composition of the treatment material so that a cured body is formed.

  As the consolidated integrated product utilizing the composite material composed of the galactor aggregate of the present invention, a galactor product composed of a plate shape, a film shape, a spherical shape, a granular shape, a rectangular shape, a columnar shape, a fibrous shape, a string shape, a lump shape, or a mixture thereof. A fluid slurry-like water-containing treatment prepared by adding at least 25 parts by mass of an aqueous activator to a powdery treatment material composition in advance for the voids of an aggregate housed in containers. Prepare the material.

  Next, the slurry-like water-containing treatment material prepared in advance is poured into containers in which the trash is stored, and the aggregate is integrally formed and processed by a mixing process / processing step that fills and integrates the gaps of the trash assembly. Next, by subjecting the molded product to a curing process at room temperature or under a certain condition, the consolidated integrated product of the garacta aggregate is secured with water resistance and heat resistance, and is an integrated inorganic molding with a water elution pH of less than 12. Product can be prepared.

  In the present invention, it is possible to form an integrated product by an injection method using a processing material slurry in a container in which a trash assembly is stored. Therefore, for example, when a junk aggregate is formed of dangerous radioactive wastes or dangerous substances composed of harmful pollutants, an integrated object forming operation can be performed remotely from the dangerous substances. In addition, the method of the present invention is not limited to radioactive waste, and various hazardous materials can be handled as a safe integrated object by a safe work system with the handling workability. preferable.

Physical property evaluation test method

In the present invention, the following test methods were adopted in order to evaluate the physical properties of the treated material (S) and the inorganic molded products.
The physical property test method in the present invention basically conforms to the method described in JIS, but a special test method for the present invention is partially adopted.
The standard preparation method for each specimen in the physical property evaluation test of the present invention was performed according to the following procedure.
In the present specification, “parts” and “%” are indicated by “mass” unless otherwise specified.

1. Confirmation test of hydraulic function and shelf life function in treatment material (S) 1-1 Preparation of curing / solidification test specimen by treatment material Preparation of curing / solidification specimen by treatment material is 100 parts by mass of the treatment material of the sample. On the other hand, using 20 parts by mass of water as a standard, the whole is mixed to prepare an admixture, and the admixture is granulated into granules of 2 to 7 mm and set in a sealable plastic container Then, it was left to stand at room temperature (about 25 ° C.) for 7 days to complete the reaction and curing, and was evaluated as a granular cured / solidified test body.

1-2 Hydraulic Function Confirmation Test of Treated Material The confirmation test of the hydraulic function in the sample treated material is performed by using 10 g of the test specimen prepared by the method described in “Preparation of Cured / Solidified Test Specimen Using Treated Material” in 100 g of water. The mixture was slowly stirred for 30 minutes, and the case where the charged granular specimen did not collapse was designated as “hydraulic”, and the case where it collapsed was designated as “no hydraulic”.

1-3 Shelf life function confirmation test of treated material The shelf life function test of the sample treated material was performed according to the following procedure. First, a 30% by mass sulfuric acid solution (total pressure P / mgHg = 13.5) was taken in a sealed desiccator and maintained at 25 ° C. to adjust the atmosphere at 78% relative humidity (R). In this desiccator with relative humidity (R) 78, 20 g (Y ₀ ) of sample was placed in a watch glass, sealed, left at 25 ° C. for 7 days, and exposed to conditions of relative humidity (R) 78 for 7 days. A sample (Ya) was collected.

When the sample (Ya) collected here was not already in a cured or powdered state, this sample (Ya) was judged as “no shelf life” at this point.
In addition, when the collected sample (Ya) is collected in powder form, the “hydraulic function” is confirmed by the method described in “Preparation of Curing / Solidification Test Specimen Using Treatment Material”. The case with the function was evaluated as “with shelf life”, and the case without the hydraulic function was evaluated as “without shelf life”.

2. Preparation of Standard Specimen The cylindrical specimen is prepared by adding 20 parts by mass of water to 100 parts by mass of the treatment material as a standard, and making the target material and the target material plasticized as necessary. The necessary water is added to the mixture, and the whole is mixed to prepare an integrated product [mixture]. The mixture is injected and filled into a cylindrical container (Reference: JSR5201) of φ50 × 100 mm, and the surface is filled with a vinyl film or the like. After covering and sealing, reaction and curing were performed at room temperature (about 25 ° C.) for a predetermined time (7 days), and then demolded to prepare a cylindrical specimen.

  The preparation method of the granular test specimen is based on a blend of adding 20 parts by mass of water with respect to 100 parts by mass of the treatment material, and if necessary, water necessary for making the target material and the target material plasticized. In addition, the whole is mixed to prepare an integrated product [admixture], which is granulated into granules of 2 to 7 mm in diameter and set in a sealable plastic container at room temperature (about 25 ° C.). Reaction and curing were carried out for a predetermined time (7 days) to prepare a granular processed test specimen.

3. Water resistance confirmation test A cylindrically prepared test specimen prepared in advance is immersed in water kept at about 20 ° C. for 1 day, and there is no abnormality in the treated test specimen after immersion, and the strength reduction rate of uniaxial compressive strength is Treated specimens within 10% are evaluated as “water resistant”, treated specimens after immersion are abnormal, and treated specimens with a uniaxial compressive strength reduction rate exceeding 10% are “water resistant”. It was evaluated.

4). Heat resistance confirmation test Pre-prepared cylindrical processed test specimens are left exposed in an electric heating oven at 400 ° C for 2 hours. The exposed specimens have no abnormalities, and the strength retention rate of uniaxial compressive strength is 50% or more. The treated test specimen was evaluated as “heat-resistant”, the treated specimen after the exposure was abnormal, and the treated specimen having a uniaxial compressive strength retention rate of less than 50% was evaluated as “heat-resistant”. .

5). Water elution pH value In this test, 20 g of pure water at 20 ° C. was introduced into 100 g of 10 g of sample specimen [standard: 7-day curing sample] of inorganic molded product prepared with treated glass and treated material. The pH of the elution test solution collected by stirring at 20 ° C. for 60 minutes was measured with a pH meter to obtain the pH value of the 10% by mass suspension elution test solution of the test specimen.

6). Uniaxial compressive strength test This test is basically a homogenous mixture (cylindrical specimen (φ5 × 10 cm: n = 3) in accordance with the method described in JSCE F506 and JSCE G505 adopted in the concrete / mortar test. ), And after standing at room temperature for 7 days in a sealed state, the uniaxial compressive fracture strength (q) of the treated specimen was measured, and the compressive fracture strength (q) at this time was displayed in KN / m ² units. .

7). Granule Strength Test This test was adopted as a simple test method for evaluating the strength of a granular processed test specimen that was adjusted under predetermined conditions.
As test specimens, nine test specimens having a particle diameter of 3 to 5 mm selected from the test specimens were used as samples. The strength measurement tester has at least 7mm springs that can withstand its own weight at the four corners of two 2mm thick steel plates (50x50mm), and a granular sample at the center of the gap between the two steel plates. Set one piece, apply a load with a weight to the upper center of the iron plate, measure the total weight of the load weight when the sample granule collapses, and use the average value obtained by measuring nine samples. The strength of the sample granule was evaluated.

8). Adhesion test This test is based on the method described in JIS K 6852, using three rectangular test pieces of 30 × 25 cm steel plate and 30 × 25 cm asbestos plate with a thickness of 0.5 mm as the base material. Is polished to the extent that a metallic luster is produced using No. 240 kneaded abrasive paper, washed with a mixed solvent and dried. The asbestos board is washed with water and dried.

  Next, the paste-like admixture was applied to a 25 × 25 cm surface of a rectangular test piece base of an asbestos plate whose surface was cleaned at a thickness of 5 mm, and a rectangular test piece base of 5 mm thickness was coated with a steel plate thereon. Put the surfaces in correspondence. At this time, the 5 × 25 cm portion to which the homogeneous mixture is not applied is protruded and set on the straight lines opposite to each other to form an adhesion test specimen.

After leaving the specimen at room temperature of about 20 ° C. for 7 days, using a compressive strength tester, the ear-shaped part of the specimen is put up and a load is applied in the longitudinal direction, and the shear breaking force at that time is broken by the loading speed. The strength (KN / m ² ) was measured to evaluate the adhesion. However, when the asbestos member of the base material was broken rather than the adhesive part to which the load was applied, it was evaluated as an adhesive strength exceeding the strength of the base material.

9. Water-reducing treatment strength test This test is a mixture of water-containing hydrous soil with a predetermined amount of treated soil added with a treatment material, and is prepared as a cylindrically treated specimen according to the standard treatment specimen adjustment method. The compressive fracture strength (q) in the uniaxial direction was measured, and the compressive fracture strength (q) at this time was displayed in KN / m ² units.

10. Nitrogen elution test This test is based on the analysis method of the bottom sediment investigation method for the elution measurement of nitrogen content in the pollution-free material treated with the contaminated material of the present invention. Take a sample at a height of 10 cm, pour seawater that has been subjected to deoxygenation in advance, collect the eluted seawater after 24 hours and measure the contamination value in the eluted seawater in units of mg / L displayed.

11. Heavy metal elution test In the present invention, the main composition analysis of the heavy metals contained in the contaminated material in the target material is based on the bottom sediment investigation method II in the soil analysis method, and the analysis of the main component is performed by the fluorescent X-ray analysis method did. Contained trace heavy metals conformed to the analysis method of the sediment survey method.

The amount of elution of heavy metals was determined by analyzing and measuring a test solution prepared according to the following two pH range elution test methods.
1 Dissolution test method of Ministry of the Environment No. 46 which is a dissolution test in neutral range 2 Dutch NEN7341 dissolution test method which is a dissolution test in acidic range

Detection method for each heavy metal:
Cd; JIS K0102 / 1998 55.3 ICP emission spectrophotometry Pb: JIS K0102 / 1998 54.3 ICP emission spectrophotometry Cr: JIS K0102 / 1998 65.2 ICP diphenyl galbazide absorptiometry As: JIS K0102 / 1998 61.2 ICP hydride generation atomic absorption spectrophotometry Hg Method listed in Appendix 1 of Environment Agency Notification No.59 December 1971

11-1 Environmental Agency Notification No. 46 Dissolution Test [abbreviation: pH 7 dissolution test method]
11-11 Preparation of Samples Samples collected are air-dried, medium pebbles, wood chips, etc. are removed, and clots and aggregates are crushed, and then the soil that has been passed through a non-metallic 2 mm sieve is mixed thoroughly.
11-12 Preparation of Sample Solution Sample (g) and solvent (with pure hydrochloric acid added so that the hydrogen ion concentration index is 5.8 or more and 6.3 or less) at a ratio by weight / volume ratio of 10%. Mix so that the mixture becomes 500 ml or more.

11-13 Elution Preparation Sample solution is shaken at room temperature (generally 20 ° C.) and normal pressure (generally 1 atm) (previously adjusted to about 200 times per minute and shake width adjusted to 4 cm to 5 cm) ) And shake continuously for 6 minutes.
11-14 Preparation of test solution The sample solution by the above operation is allowed to stand for 10 to 30 minutes, then centrifuged at about 3,000 rpm for 20 minutes, and the supernatant is filtered with a membrane filter having a pore size of 0.45 μm. Filter to collect the filtrate, and use the exact amount required for quantification as the test solution.

11-2 Netherlands NEN7341 dissolution test [abbreviation: pH4 dissolution test method]
11-21 Preparation of sample The collected sample soil is air-dried, medium pebbles, wood chips, etc. are removed, the clot and aggregate are crushed, and then the soil obtained by passing through a non-metallic 2 mm sieve is sufficient. Mix.

Preparation of 11-22 sample solution 800 g of distilled water is added to 16 g of the sample, and the mixture is maintained at pH 7 with 1 mol / L of nitric acid and stirred for 3 hours. Next, the solution is filtered through a membrane filter having a pore diameter of 0.45 μm, and the filtrate is taken. The amount necessary for quantification is accurately measured, and this is used as a pH 7 eluate. Further, 800 g of distilled water is added to the pH 7-eluted filtration residue, and this time, while maintaining the pH at 4 with 1 mol / L nitric acid, the mixture is stirred for 3 hours. Next, the solution is filtered through a membrane filter having a pore diameter of 0.45 μm, and the filtrate is taken as a pH 4 eluate.
11-23 Preparation of test solution The pH 7 eluate and pH 4 eluate obtained by the above operation are added and mixed, and the amount required for quantification is accurately measured, and this is used as the test solution.

12 Simple Deformability Measurement Test In this test, a simple deformability measurement test was adopted instead of the “standard penetration test” in order to evaluate the deformability of the treated soil according to the present invention.
In this test, an admixture was made into a cylindrical test specimen (φ5 × 10 cm: n = 3) based on the description of JSCE F 506 and JSCE G 505, which are basically adopted in the mortar test, and in a sealed state. After standing at room temperature for 7 days, the uniaxial compressive fracture strength (qu) was measured and displayed in KN / m ² units.

軸圧縮強度（ｑｈ）を測定し、耐熱性強度保持率を下記ｑ（％）で求めた。13. Specific surface area reduction rate In this test, the specific surface area Aq of the material to be dried and the specific surface area of the consolidated product obtained by consolidation molding of the target material were measured using an automatic BET specific surface area measuring device [Sorptomatic Series 1800 made by CARLOERABA] (m ² / g), and the specific surface area reduction rate (A) of the solidified body relative to the target material was determined by the following formula.

The axial compressive strength (qh) was measured, and the heat resistant strength retention was determined by the following q (%).

14 Acid material strength retention of these studies is previously prepared cylindrical treatment test body (25 ° C.) specimen uniaxial compressive strength of 7 days curing (q ₀₎ was allowed to stand for 1 day immersion in pH3 sulfuric acid solution at 25 ° C. Measure the uniaxial compressive strength (qa) of the test specimen after immersion, and evaluate the case where the rate of decrease in the uniaxial compressive strength of the following formula (q) is within 20% as “acid-resistant”, post-immersion treatment test A test specimen in which abnormalities occurred in the body or the strength reduction rate of the uniaxial compressive strength exceeded 20% was evaluated as “no acid resistance”.

15. Measurement of dioxins The analysis of dioxins concentration was requested from a public institution, and the results of measurement and quantification with a gas chromatograph mass spectrometer were adopted.

In this example, a processing material composed of three essential components of calcium glass, active silica and sulfate, and a processing material of a powdery body composed of four components including an auxiliary composition;
Furthermore, about the utilization method of the processing material used for the mixing process, processing process, and curing process using water to the processing material, and the processing method using the processing material;
Furthermore, modified products, cured products, structures, composite cured products, granules, adherents, hydrous soil modified products, non-polluted materials, consolidated adsorbents, heat insulation / heat insulation / heat resistant materials, acid resistant materials and integrated products About inorganic molded products
The present invention will be described below by way of specific examples with reference examples.
[Reference Example 1]

In this reference example, the inert calcium glass in this example prepared from a mixed raw material prepared in advance will be described.
The mixed raw materials prepared in advance are expressed in terms of basic composition ratios on the basis of oxides, and at least 10 to 100 parts by weight of alumina and 50 to 350 parts by weight of calcium, and optionally oxidized with respect to 100 parts by weight of silica. Sodium was secured in the range of 1 to 100 parts by mass.

The silicate composition constituting the mixed raw material was selected from the group of layered clay minerals, silicate compounds, alkali silicates, hydrous soils, and thermal history, and specific examples are shown in Table 2.
The calcium composition constituting the mixed raw material was selected from the group consisting of a calcium composition, a calcium salt composition, a waste composition, a cement composition and a charcoal modified composition, and specific examples are shown in Table 3.
The alumina composition constituting the mixed raw material was selected from the group of aluminate or alumina hydrate, and specific examples are shown in Table 4.

  In addition, as shellfish modified composition, oil content was contained in activated clay used for refining oils and fats with respect to 100 parts by weight of scallop shell powder (main component: Calcia 54.3% by mass) that has been disposed of. A binary mixture of 60 parts by mass of waste clay was heat-treated at about 950 ° C., and then two kinds of shell decarboxylated and shell-modified products obtained by pulverizing and classifying the heat-treated products were selected.

  For the glassy glass in this reference example, the mixed raw materials adjusted by the types shown in Table 6 and the blending ratios in which the basic amount ratios are secured are treated for 2 hours at the treatment temperature (° C.) shown in Table 6 to recover the heat-treated product. The processed product is pulverized and classified to prepare a powder passing through a 100 mesh sieve, and the water elution pH of 10% suspension is measured to confirm the properties (shelf life) of the prepared calcium glass. did.

  In this reference example, as a powdered calcium glass, it was not a heat-treated product obtained by heat-treating a specially selected mixed raw material, but was subjected to a heat history selected as a mixed raw material constituting component, and was ground and pulverized. Blast furnace slag powder and shell modified products were selected separately.

  Moreover, in this reference example, in order to compare with the processing material of this invention, the composition when a part of essential components [silica, a calcium oxide, alumina] lacks, and the composition when heat treatment conditions are not given In the same manner, the water elution pH was measured and displayed together in Table 5.

［参考例２］

[Reference Example 2]

  In this reference example, as the active silica adopted in this example, a single material that is an alkali silicate or alkali-modified silicic acid from commercially available reagents and industrial chemicals, and a silicic acid compound having a silanol group and a sodium salt compound are used. Compounds and compositions were chosen that are suitable as composite materials that are mixtures.

  As an alkali silicate material which is a single material of active silica, water glass powder (sodium metasilicate) (sample number: SN-1) of a commercial industrial chemical was selected.

  As alkali-modified silicic acid which is a single material, 100 parts by mass of 30% by weight caustic soda solution is added to 100 parts by mass of acid clay selected with a silicate composition as a mixed raw material of silica glass, and then 100 ° C. The powdery alkali modified silicic acid (sample number: SN-2) prepared by reacting and grinding for 60 minutes was selected.

［参考例３］A mixed material of active silica was prepared by mixing a predetermined amount of a silicate compound and a sodium salt compound shown in Table 7.

[Reference Example 3]

  In this reference example, as a sulfate to be adopted in this example, a commercially available reagent and an industrial chemical, a gypsum-type composition mainly containing calcium sulfur oxyacid salt, and an alum mainly containing aluminum sulfate. The composition contents were selected from the mold compositions and the mirabilite composition mainly composed of sodium sulfate.

  In this reference example, sodium sulfate, calcium sulfate, waste gypsum board, aluminum sulfate, etc. classified as sulfate are the same as the compounds classified as other active silica, calcium composition, and alumina composition. There is a case.

［参考例４］

[Reference Example 4]

  The auxiliary composition in this reference example is a crystal seed composition, a sodium supplement composition, a calcium supplement composition, a sulfate radical supplement composition, a reinforcing material composition, a phosphate radical composition, a barium salt composition, an iron salt supplement composition. A fibrous material from among the commercially available reagents, industrial chemicals and pre-purified and prepared materials selected from the group consisting of an additive material composition, a dispersion medium composition and a function-imparting composition. The materials shown in Table 9 were selected, which were refined as necessary with powdery bodies including flakes and sandy bodies.

  As the crystal seed composition, a powder of 4A zeolite with an aluminosilicate of industrial chemicals with an Al / Si atomic ratio of 4.2, a ring number of 8 and a secondary particle size of 20 μm or less and natural zeolite from Fukushima are selected. It is.

  Sodium supplement composition and calcium supplement composition are selected to supplement the necessary sodium and calcium components according to the purpose and application of the treatment material when utilizing the treatment material consisting of the three essential components.・ You can choose.

  As the reinforcing material composition, vermiculite having a low specific gravity and iron ore suitable for an aggregate such as fishing reef having a high specific gravity were selected as filler aggregates together with general river sand. In addition, fiber-like stainless steel fiber or glass fiber was selected as the reinforcing material.

  As the phosphate group composition, silicon phosphate [silica / 5 phosphorus oxide molar ratio of 3.0 is adopted as a curing agent for alkali silicate-based solidifying material when volume-reducing and solidifying low-level waste at a nuclear power plant. : Pulverized product calcined at 950 ° C. at 1.0]. Further, the phosphate sludge is composed mainly of 25.0% by weight of iron phosphate 25.0, zinc phosphate 7.5, silica 10.5, alumina 8.4, moisture, when the steel sheet for automobiles is processed. A 35.0 sludge was chosen.

  As a barium salt composition, barium silicate prepared in a simple reaction type (barium oxide / silica: molar ratio = as a retarder for delaying the reaction rate between the treatment material of the present invention and the aqueous activator to ensure workability) 1.0: 1.0, reaction / pulverized product at 250 ° C.) and commercially available industrial chemical barium hydroxide.

  The red mud selected as the iron salt supplement composition is a waste mainly composed of iron components discharged when sodium aluminate is recovered by reacting bauxite with caustic soda. The ionic iron component has a function of insolubilizing and immobilizing arsenic elements, which are heavy metals, and can be selected.

The additive material composition was appropriately selected from pigments, colorants, fillers and the like widely used in the industry according to the purpose and application of the present invention.
Since the treatment material of the present invention is alkali at the start of the reaction that is activated via the added aqueous activator (W), the selected pigment, colorant, filler, etc. have alkali resistance. Selected compounds and compositions.

As the adsorptive support of the functional composition, carbon-aluminum silicate composite obtained by carbonizing industrial waste paper sludge (main component (mass%): carbon :: 25.5, silica: 35.6, alumina 27.5, calcium 11.4) were selected.
As the activator of the functional composition, aluminum phosphate powder, which is widely used as a hardener for water glass, was selected.

As antimicrobial agents (antibacterial agents) for the functional composition, boric acid, zinc borate, and silver borate that are effective as antimicrobial agents were selected.
As the adsorptive water repellent for the functional composition, a functional composition having water repellency as a powder was selected by impregnating activated carbon powder with 10% by mass of dimethyldimethoxysilane.

［実施例１］

[Example 1]

In this example, a preliminarily prepared treatment glass shown in the reference example, and a treated material obtained by homogenously mixing three essential components of active silica and sulfate by a dry mixing method to form a one-pack will be described.
Furthermore, the processing material compared with this invention processing material and the hydraulic solidification material of a prior art are demonstrated along with a comparative example.

  The mixing ratio of the essential three components of the treatment material in this example is the amount shown in Table 10 for materials selected from the calcium glass shown in Reference Example 1, the active silica shown in Reference Example 2 and the sulfate shown in Reference Example 3. A treated material obtained by one-packing the mixture by dry homogeneous mixing was used as a sample.

  In addition, as a comparative example compared with the constituent components of the present invention shown in Reference Example 1, the essential three components shown in Reference Example 1 (Table 5) are secured, but a heat history that is an inactivation treatment is given. An untreated sample (Table 5: Sample number: HSG1) was selected.

  Furthermore, a sample of a comparative example (Table 5: Sample No .: HSG2 to HSG4) of a glass glass composed of a blending composition lacking any of the essential components among the three essential components is selected, and a table that is a standard blend of the inventive treatment material Samples to be comparative examples prepared based on the formulation of the sample number (1-1) shown in FIG.

  Furthermore, in this example, as a comparative example of the prior art that can be compared with the treatment material of the present invention, Portland cement (JIS R 5210) that forms a solidified body at room temperature, water glass-based solidified material [main component: No. 2 water Four types of glass + aluminum phosphate], silica-based binder and alkaline curing agent [main component: calcite + clay + caustic soda] were selected and displayed in Table 11.

  For the treatment materials of the present invention prepared with the above three essential components and comparative examples, a confirmation test was performed in accordance with the method for confirming the hydraulic function and shelf life function shown in the physical property evaluation test method section. The results are shown in Table 10 and Table 11 together.

  As a result of the above, all of the treatment materials of this example in which the essential three components of the inactivated calcium glass, active silica, and sulfate of the present invention are secured have a shelf life function, It is well understood that it exhibits a hard function, and it is understood that the product is effective as a general-purpose treatment material that exhibits normal temperature hydraulic properties.

However, it lacks a sample of non-inactivated calcite glass [Comparative Example: H-1] and any of the three essential components of calcite glass, active silica and sulfate constituting the treatment material of the present invention. The provided sample [Comparative Example: H-2 to H-4] cannot exhibit the hydraulic function that is the basis as the treatment material.
In addition, since none of the samples of the comparative examples had a hydraulic function, the shelf life test could not be tested.

Furthermore, in the case of the four types of typical hydraulic solidification materials in the prior art, the hydraulic function at room temperature is ensured, but none of the shelf life is ensured, and the shelf life in the present invention. It can be understood that the treatment material is clearly distinguished from the treated material.
[Example 2]

  In this example, the treatment material prepared by the essential three components shown in Example 1 and the four components added with various auxiliary compositions shown in Table 12 were homogeneously mixed to form a one-pack. explain.

  In the processing material in a present Example, with respect to 100 mass parts of processing materials selected from the processing material which consists of the essential 3 component prepared in Example 1, each shown in Table 12 from the auxiliary composition shown in the reference example 4. A supplementary composition of a type corresponding to the purpose and use was added in a predetermined amount of parts by mass, and the sample was prepared as a one-packed processing material by dry mixing and homogeneous mixing.

  With respect to the physical properties of the treatment material of the present invention prepared with the four components added with the above auxiliary composition, a confirmation test was conducted by a method for confirming the hydraulic function and shelf life function, and the results are also shown in Table 12. .

As a result of the above, the treatment material of the present invention consisting of four components obtained by adding an auxiliary composition to the three essential components of calcium glass, active silica, and sulfate exhibits a hydraulic function and possesses shelf life function. Therefore, it is well understood that each functionality can be provided according to the purpose and application.
[Example 3]

  In this example, an inorganic molded product (cylindrical processing specimen in this example) is obtained through a mixing process, a processing process, and a curing process, which are a series of work processes that activate the reaction via an aqueous activator added to the treatment material. A method of utilizing and using the processed material will be described.

  The processing materials adopted in the present embodiment for use and utilization of the processing materials are three types [sample numbers: 1-2, 1-5, 1- 18]. In addition, three types [sample numbers: 2-1, 2-7, 2-9], which are single-component materials composed of four components obtained by adding an auxiliary composition to the three essential components prepared in Example 2, were selected.

  In this example, in preparing the specimen, river sand (0.5 to 4 mm) or small gravel [45 to 9 mm], which is a sand granule, is selected as a target material together with a single material, and the blending ratio shown in Table 13 is used. We also selected composite materials that were combined.

  The utilization method of each treatment material is the work process conditions shown in Table 13 [type and amount of water-based activator, atmosphere in the curing process (multi-stage atmosphere depending on the case), temperature (corresponds to the atmosphere) and time (day) ], Through a mixing step, a processing step, and a curing step, a φ50 × 100 mm cylindrical test body [homogeneously filled into a mold made by molding] in the standard test body shown in the physical property evaluation test method section was prepared.

Physical property values [water resistance, heat resistance, uniaxial compression] of cylindrical treatment test specimens prepared according to the utilization method of the treatment material of the present invention, which is subjected to the work process by adding aggregate and various aqueous activators to each treatment material Strength (q = KN / m ² ) and water elution pH] were measured and evaluated.
These results are also shown in Table 14.

  As a result of the above, for the single material of the treatment material of this example or the composite material composited with sand particles, various aqueous activators are added as reaction initiators and mixed to make an admixture, then the admixture Is subjected to a series of work steps consisting of a curing step in which a cylindrical mold is filled and molded into a cylindrical processed specimen, and the mixture filled in the cylindrical mold is cured under the conditions shown in Table 13. It is well understood how to use and utilize the processing material prepared into a solidified body that is water resistant and heat resistant, has a water elution pH of less than 12 and has a certain strength.

［実施例４］

[Example 4]

  In this example, from a cured body such as various structures or composite cured bodies prepared by curing and solidifying by starting a reaction through an aqueous activator added to a composite material in which sand particles are combined as a target material with a treatment material The inorganic molded product will be described.

  The treatment materials adopted in this example are 4 types of treatment materials composed of the essential 3 components prepared in Example 1 or 2 or 4 components added with an auxiliary composition [sample numbers: 1-2, 1-6. , 1-18, 2-9].

  As sand granule which is the target material adopted in the present embodiment, five types of river sand having a particle size of 0.5 to 4 mm, artificial lightweight aggregate, manganese ore, molten slag treated with incinerated ash, and glass cullet A composite material was selected that was combined with the processing material.

  As the water-based activator adopted in this example, well water used for drinking was selected. Table 15 shows the type and blending amount of the treatment material, the blending amount of sand granules as the target material, the blending amount of well water, and the like in this example.

  The evaluation as a cured body inorganic molded product adapted to various structures in this example or an inorganic molded product such as a composite cured body is φ50 in the standard test body shown in the physical property evaluation test method in the following work process. A columnar test body of × 100 mm [filled mold in mold, n = 3] was prepared, subjected to a uniaxial compressive strength test, and the strength of the resulting solidified body was measured. The results are shown in Table 16.

  The working process in the present example is a mixture of treatment material, sand granule as a target material, and well water as a water-based activator in an amount ratio shown in Table 15, and the mixture is filled into a cylindrical mold. After being molded into a cylindrical molded product, it was subjected to a curing process that was allowed to stand in the atmosphere for 7 days in a sealed state at about 20 ° C. to obtain a cylindrical processed specimen.

The physical property values [water resistance, heat resistance, water elution pH, uniaxial compressive strength (q = KN / m ² )] of the prepared cylindrically treated specimens were measured and evaluated. These results are also shown in Table 16.

As a result of the above, by mixing well water with a composite material in which sand particles are combined with the treatment material of this example, the combined mixture is formed into a molded product and then subjected to a curing process, thereby hardening and solidifying each. The body has water resistance and heat resistance, the water elution pH of the cured body is less than 12, exhibits a strength of 30,000 KN / m ² or more, and is suitable for the purpose and application of the present invention. It is well understood that the article is prepared utilizing a treatment material.
[Example 5]

  In this example, a granular inorganic molded product prepared by granulating by starting a reaction via an aqueous activator added to a composite material obtained by combining a sand granule as a target material with the treatment material of the present invention will be described.

As the treatment materials adopted in this example, two types [sample numbers: 1-2, 2-9] were selected from the treatment materials prepared in Examples 1 and 2.
Three types of sand particles [river sand B, pearlite, manganese ore] having a particle size in the range of 0.2 to 2 mm were selected as the sand particles that are target materials adopted in this example.
The water-based activator adopted in this example was selected from well water for drinking.

  The granular inorganic molded product in this example was prepared by mixing the processing material, the target sand material and the well water in the blending amounts shown in Table 17 in a mixer having a rotary stirring shaft blade and mixing and stirring for about 10 minutes. The mixture is subjected to a mixing and processing step of forming a granule having a particle diameter of 2 to 10 mmφ while making an admixture, and the granule thus formed is subjected to a curing step in a normal temperature atmosphere for 7 days. Each body inorganic molded product was prepared.

  The physical property values [water resistance, heat resistance, water elution pH, strength due to load (kg)] of each granular inorganic molded product prepared here were measured and evaluated in accordance with the physical property evaluation test method of this specification. . These results are also shown in Table 18.

As a result, the well material is mixed with the composite material obtained by combining the sand granule with the treatment material of the present embodiment, and the resulting mixture is integrated and granulated to be mixed and processed (K), and then cured at room temperature. Granules recovered by attaching to the water have water resistance and heat resistance, have a water elution pH value of less than 12, exhibit a load strength of 500 kg or more, and are suitable for the purpose and application of the present invention It is well understood that an inorganic molded article is prepared using a treatment material.
[Example 6]

  In this example, an adherent inorganic molded article using a paste-like mixture prepared through a water-based active agent added to a composite material obtained by combining a filler as a target material with a treatment material will be described.

As treatment materials in this example, two types [sample numbers: 1-2, 2-9] were selected from the treatment materials prepared in Examples 1 and 2.
As the filler of the target material, 8 types of powders of 100 μm or less from the materials shown in the auxiliary composition [sample numbers: ST3-2, ST3-5, ST9-4, ST9-7, ST9-8, ST10- 2, ST10-4, ST10-7].
Tap water was chosen as the water based activator.

  The paste-like admixture in the present example was prepared by adding tap water as a water-based activator to the treatment material and the filler as the target material at the mixing ratio shown in Table 19, and mixing and integrating them. The admixture was adopted.

Next, in accordance with the physical property evaluation test method shown in this specification, after preparing an adhesion test body for an adhesion test using a steel plate and an asbestos plate as a test piece, a curing process [at room temperature of about 20 ° C. for 7 days The sample for adhesion was measured. The adhesion test specimen prepared here was confirmed for water resistance and heat resistance, and the shear fracture strength [KN / m ² ] was measured. The results are shown in Table 20.

As a result of the above, the adhesion test specimen prepared by the paste-like admixture obtained by mixing and integrating the treatment material of this example, the powder filler having a particle size of 100 μm or less and the water-based activator of tap water has an adhesive force (shear fracture). It is understood that (strength) is 3,000 KN / m ² or more, has water resistance and heat resistance, and is processed and prepared into an inorganic molded article that is an adherent suitable for the purpose and application of the present invention.

［実施例７］

[Example 7]

  In this example, by using a paste-like mixture prepared with a composite material obtained by combining a filler with the treatment material shown in Example 6, a through-hole that was processed and prepared by integrally binding aggregate aggregates of granular materials An inorganic molded product made of a cocoon-like molded body having voids will be described for the case where the coconut-like molded body processed and prepared here is used as a non-combustible soundproof board.

Examples of aggregates of granular materials, which are skeleton-forming materials in this example, include waste glass cullet, pearlite, alumina, and granule products of the present invention (5-4, 5-5) that have been sized to a particle size of about 3 to 7 mmφ. 5-6) were selected.
As a binder for collecting the granular aggregates, the paste-like mixture having fluid plasticity of Sample No. 5-1 prepared in Example 6 was selected.

  粟 Okoshi-like inorganic molded product is prepared by adding about 5 kg of water to 10 kg of the selected granular aggregate group, moistening the granular group surface, then adding 15 kg of the paste-like mixture of the prepared binder and mixing. Wet with a binder. Next, the granule group wetted with the binder is cast into a 300 × 300 mm mold having a thickness of 30 mm, left to cure at room temperature for at least 24 hours, and then demolded to form an inorganic molded product of a cocoon-shaped molded product. Was prepared.

  In accordance with the physical property evaluation test method shown in this specification, the water resistance and the heat resistance were confirmed, and the water elution pH was measured. In addition, in order to confirm that each cocoon-shaped inorganic molded product is penetrating, water is dropped on the surface of the coconut-shaped inorganic molded product on the board, and water is placed under the inorganic molded product made of coconut-shaped molded products. Penetration was confirmed by the method of flowing out. These results are shown in Table 21.

  Moreover, in order to evaluate the soundproofing effect when applying the inorganic molded product [Sample No. 7-5] comprising the coconut-shaped molded body prepared in this example as a non-combustible soundproofing plate, in accordance with JIS A 1416 standard. Evaluation was made as a soundproof board. Nonflammability, bulk specific gravity, dimensional stability, compressive strength, bending strength, water resistance and weather resistance were measured, and are also shown in Table 22. The evaluation results are also shown in Table 20.

As a result of the above, the aggregate group of 6 types of granular materials (5-4, 5-5, 5-6) processed and prepared with the waste glass cullet, pearlite, alumina and the treatment material of the present invention was used as the pasty form of this example. When the admixture is collected as a binder and molded into an inorganic molded product made of a disk-like molded body, it has a water elution pH of less than 12 and has water resistance and heat resistance. It is well understood that when a saw-shaped molded body is used for a soundproofing effect, it is effectively processed and prepared as an excellent incombustible soundproofing plate.
[Example 8]

  In this embodiment, hydrous soil is selected as the target material, a treatment material is added to the hydrous soil, and the reaction is started by using the water contained in the hydrous soil as an aqueous activator. Next, a method for utilizing and utilizing the processing material to be processed and prepared and an inorganic molded product made of the hydrous soil modified material will be described.

As the treatment materials adopted in this example, two types [sample numbers: 1-12, 2-3] were selected from the treatment materials prepared in Examples 1 and 2.
The hydrous soil that is the target material adopted in the present example is hydrous sludge collected from the sea area [Ago Bay] [water content ratio: about 158, water content: 61.5%, particle size composition: clay 63, silt 24 , 10 sand, 3% gravel].

  The treated specimen used as the hydrous soil reformer of this example was a plastic blend obtained by mixing and integrating seawater containing a treatment material to the sludge of the hydrous soil as a water-based activator at the blending ratio shown in Table 23. Next, the mixture is molded into a cylindrical test body (structure) and left in the air at room temperature (about 25 ° C.) for 28 days, and the mixture is molded into a 7 mmφ granular test body (granule). After 24 hours in the air, it was left in seawater for 2 months, and a molded specimen was obtained by a utilization method using the hydrous soil modified body as a structure or granule.

The physical properties of each cylindrical specimen (solidified body) and granular specimen (granules) were evaluated by water resistance, heat resistance, water elution pH, nitrogen elution test (mg / L), and uniaxial compressive strength test of the solidified body [ KN / m ² ] and the load strength test (kg) of the granules were measured. The results are also shown in Table 24.

  In Table 25, “Water quality standards for fisheries products” are listed as [preferred water quality standards in the water areas published by the Japan Fisheries Protection Association, although there is no legally established water quality standard for aquatic products] The elution amount of total nitrogen is shown for reference.

  As a result, the water sludge having a water elution pH of 12 or less is obtained by processing in a series of work steps using the treatment material of the present invention and a curing step in the sea with respect to the marine sludge that is the hydrous soil selected as the material to be treated. It has been modified to a hydrous soil modified body that has a solidified body strength that does not re-mudify with granules.

In particular, marine sludge granules cured in seawater have sufficient strength as the curing proceeds in seawater, and the sludge is not re-mudized by treating the sludge in seawater with the treatment material of the present invention. It is well understood that it is provided as a granule for applications such as sand-covering and embankment in the sea, and is effective as a recycling technology in sludge underwater.
[Example 9]

  In this example, the target material is soft ground that is hydrous soil, and the treatment material is homogeneously mixed at the original position of the soft ground, and the reaction is started through the water content contained in the soft ground. The reformed product of soft ground that has been subjected to the reforming reinforcement process will be described.

As the treatment material adopted in this example, sample number 2-8 was selected from the treatment material prepared in Example 2, and a slurry-like treatment material prepared by dispersing 100 kg of the treatment material powder in 90 kg of water in advance was selected. It is.
As the hydrous soil soft ground which is the target material adopted in this example, a soft ground with a water content of 30% by mass in Miwa Town, Ibaraki Prefecture was selected.

The reforming and reinforcing treatment in the soft ground is equivalent to 150 kg with respect to 1 m ^{3 of the} soft ground under pressure by a chemical mixing and stirring type deep mixing device widely used for soil improvement in the civil engineering industry. Inject and agitate the slurry of the amount of treatment material, and mix the slurry-like treatment material to the ground up to 4m below the soft ground by infusion and agitation to make a blend, then cure in situ for 7 days, then modify The soil of the reinforced ground was sampled and the physical properties were evaluated.

As a result, the uniaxial compressive strength of the soft ground subjected to the modification reinforcement treatment was 250 KN / m ² or more, and the water elution pH was 9.5 or less.
As a result of the above, the slurry-like treated material of this example was injected into the in situ soft ground without mixing harmful chrome into the soft ground as in the case of reinforcing with cement, thereby reinforcing the soft ground. It is well understood that the ground to be reinforced is formed by forming the pile to be applied.
[Example 10]

  In this example, for the contaminated soil in the contaminated soil ground contaminated with heavy metals as the target material, the treatment material is mixed homogeneously with the contaminated soil, and the water contained in the contaminated soil The modified product obtained by starting the reaction through the process, in which the contained heavy metals are insolubilized and fixed, and modified into a non-polluted product will be described.

As the treatment material as the modification treatment material in this example, Sample Nos. 2-7 having a small amount of sulfate blended were selected from the treatment materials prepared in Example 2.
Moreover, as a comparative example of this example, commercially available Portland cement was selected as the treatment material.

  As the contaminated soil that is the target material in this example, contaminated soil [soil A and soil B] contaminated with a plurality of heavy metals [cadmium, lead, arsenic chromium, mercury] collected from two sites of the chemical factory I chose. Their main components [mass% based on dry matter] and the concentrations of contained heavy metals (mg / kg = ppm) are also shown in Table 26.

  The reforming method for making insoluble and immobilized non-polluted heavy metals by the treatment material is the treatment ratio at the blending ratio shown in Table 27 based on the physical property evaluation test method for the contaminated soil as the target material. And water were added and mixed using a test mortar mixer [Mighty 30 (capacity 20 liters: stirring 60 rpm): Aikosha Seisakusho Co., Ltd.], which was a mixing apparatus, and a plastic mixture was obtained with a backlash.

The mixture was then placed in a sealed container, left at room temperature (about 25 ° C.) for 24 hours, and then left for 2 months and sampled to prepare an analytical sample for heavy metal elution test.
In addition, regarding the untreated contaminated soil, the insoluble and immobilization effect of the heavy metals of the present invention was also compared and confirmed as a sample for analysis of elution test of heavy metals.

  Moreover, in the Portland cement selected as a comparative example of the present invention, a commercial cement was mixed with the contaminated soils A and B at the blending ratio shown in Table 27 according to the same conditions and methods as the processing method in the present example. In the same manner as in this example, the samples were left for 2 months and used as samples for heavy metal dissolution test analysis.

In order to confirm the physical properties of the modified treated sample in the analytical sample, dissolution tests (mg / L) of heavy metals at pH 7 and pH 4 were performed, and the results are shown in Tables 28, 29 and 30. . In addition, tests were conducted on simple deformability and water elution pH by a simple deformability measurement test [q = KN / m ² ], and the results are also shown in Table 31.

In addition, Table 32 shows the elution standard values obtained by the elution test at pH 7 for heavy metals defined by the country.

  As a result of the above, in the untreated state, in the contaminated soil ground where harmful heavy metals are eluted and pollute the environment with heavy metals, the single treatment product of the present invention is treated as a treatment material in the contaminated soil in situ. The treatment material single product of the present invention is reformed at once to contain a plurality of heavy metals, and the contained heavy metals do not elute even in a pH 4 solution assuming acid rain, and are insoluble and immobilized within the environmental standards. In addition, the soil has a water elution pH of less than 12 and is water resistant, and is a soil that is not concreted and can be reused, and is modified to a non-polluted treatment that is easy to reuse. Is well understood.

However, when using cement as a treatment material in the prior art, it is possible to temporarily cover the contained heavy metals, but no insoluble minerals that insolubilize or immobilize heavy metals have been generated. If left unattended (for 2 months), heavy metals will elute into the environment and exceed the environmental standards. Unlike the technology of the present invention, heavy metals contained in contaminated soil are not stably modified with cement. .
[Example 11]

  In this embodiment, the target material is a contaminated soil ground containing heavy metals, and the treatment material of the present invention is homogeneously mixed with the contaminated soil to contain water contained in the contaminated soil. When the reaction process is started through the process, the series of work steps of the present invention are executed on the on-site process scale, and the heavy metals contained therein are insolubilized and fixed in-situ to make a reformed product that is a non-polluted product. Quality processing technology will be described.

As the treatment material in this example, the treatment material of sample number 2-7 made of the powdery material treatment material prepared in Example 2 was selected.
As the contaminated soil which is the target material in this example, contaminated soil [soil C ground: 10 m × 30 m × depth, which is contaminated with multiple heavy metals [cadmium, lead, arsenic chromium, mercury] collected from the former site of the chemical factory 2m] was selected. Table 33 shows the main component [mass% on the basis of dry matter] and the concentration of heavy metals [mg / kg = ppm] based on the average value of the analysis results of the sampling soil collected from various places in the soil C ground.

  The mixing process in the in-situ reforming process in which a plurality of heavy metals by the treatment material of the present invention are insolubilized and fixed to be non-polluted is a mixing apparatus widely used for ground improvement in the civil engineering industry. "Soil improvement method" and "Backhoe stirring method" were adopted.

The remediation treatment of contaminated soil in the “Self-propelled soil improvement method” in the mixing process is based on the RETERRA equipment [manufactured by Komatsu: rated output 107 KW / 195 rpm, mixing method: soil cutter + 3-axis large rotary hammer + aftercutter] position ground to set up was charged with contaminated soil mined in situ installation was RETERRA apparatus for contaminated soil 1 m ³ was charged, successively mixed with the treated material was added at a mixing ratio of the treatment material 100 kg, Return the admixture mixed with contaminated soil-containing water to the mining site, start the reaction via water, and leave it in place for 24 hours to insoluble and immobilize heavy metals. A reforming treatment was performed.

Modifying treatment contaminated soil in the "backhoe stirring method" mixing step, backhoe implement [Komatsu Seisakusho, Kyatabira movable flat product: piling at 0.6 m ^3: it comes with stirrer 0.8 m ³ volume of the bucket bringing the local and] is made to, with respect to soil 1m ³ depth capacity assuming the depth 1m in advance contaminated soil ground, with a treating agent added by the mixing ratio of the treatment material 100kg uniformly and intimately with backhoe, Hitoshi Then, the reaction was started through water containing contaminated soil, and subjected to a curing process in which the reaction was allowed to stand for 24 hours in the in-situ mixing position, and insoluble and fixed reforming treatment of the contained heavy metals was performed.

In this embodiment, the sample soil for analysis is collected from the untreated contaminated soil ground in the original position and each treated soil ground which has been left in the original position for 24 hours in a series of two processes and made into non-polluted substances. The dissolution test (mg / L) and the water elution PH of heavy metals at pH 7 and pH 4 were measured.
The above analysis results are also shown in Table 34.

As a result of the above, in the in situ soil soil contaminated with heavy metals, a single treatment material of the present invention is used to improve the insolubilization and immobilization of multiple heavy metals using the “self-propelled soil improvement method” and “backhoe agitation method”. It is well understood that, depending on the process, the heavy metals contained in multiple types are insoluble and fixed without impacting the environment in the 24 hours of standing curing process, and modified into an inorganic molded product as a non-polluted product, depending on the process. Is done.
[Example 12]

  In this example, the target material is incinerated ash containing heavy metals, which is a contaminated material, and the admixture whose reaction is activated via the aqueous activator added to the incinerated ash in addition to the treatment material is granulated. A granulated inorganic molded product that is processed and molded by chemical granulation to insolubilize and immobilize the contained heavy metals to make a non-polluted product will be described.

As the treatment material in this example, sample number 2-8 was selected from the powdery material treatment material prepared in Example 2.
The incinerated ash that is the target material in this example contains heavy metals [cadmium, lead, arsenic chromium, mercury] shown in Table 35 as incinerated ash collected by incineration of general waste or industrial waste. Incinerated ash was chosen.
The water-based activator adopted in this example was selected from well water for drinking.

  In this example, the processing preparation to granulate the incinerated ash and make it an inorganic molded product made of non-polluted material without elution of heavy metals is a composite in which sand granules are combined as a target material with the treatment material shown in Example 5 An inorganic molded product was prepared according to the utilization method of the granule prepared from the material.

  The working process for processing and preparing the granule using the incinerated ash as the target material in this example is a mixer having rotating stirring shaft blades by adding 20 kg of treatment material and 60 kg of well water to 100 kg of incinerated ash as the target material. The mixture is subjected to an admixing and processing step for forming a granule having a particle diameter of 2 to 10 mmφ while mixing and stirring for about 10 minutes, and the molded granule is subjected to 7 days in a normal temperature atmosphere. An inorganic molded product made of granules was processed and prepared by a process for the curing process.

The physical property values [insoluble / fixed heavy metals, water resistance, heat resistance, water elution PH value, strength due to load (kg) of each granule] prepared here are the physical property evaluation test methods in this specification And measured and evaluated in accordance with each.
These results are also shown in Table 36.

As a result of the above, the incinerated ash granule made into a granular form by adding well water to the treatment material and mixing and integrating the incinerated ash containing heavy metals contained in the contaminated material has water resistance and heat resistance, The water elution pH value is less than 12, shows a load strength of 5 kg or more, and has been prepared as an inorganic molded product made of non-polluted products with insoluble and immobilized harmful heavy metals. The utilization and utilization method of the processing material of the present invention for recycling is well understood.
[Example 13]

  In this example, the target material is a contaminated material composed of dioxin-containing contaminated soil, and the treatment material is homogeneously mixed with the contaminated soil and reacted through the water contained in the contaminated soil. An inorganic molded product that captures and decomposes contained dioxins through a series of start-up work steps to make them non-polluted will be described.

As the treatment material in this example, sample number 2-10 was selected from the treatment material of the powdery composition prepared in Example 2.
The contaminated soil [soil D] contaminated with dioxins collected from the rubbish incineration site was selected as the contaminated soil as the target material in this example. The state of contamination with dioxins in soil D is shown in Table 37 as pg-TEQ / g concentration.

  A series of work steps for capturing and decomposing dioxins by the treatment material of the present invention to make it non-polluted is a ratio of 20 parts by mass of the treatment material and 20 parts by mass of water with respect to 100 parts by mass of the contaminated soil as the target material. The mixing mortar mixer [Mighty 30 (capacity 20 liters: stirring 60 rpm): Aikosha Mfg. Co., Ltd.], which is an agitating and mixing apparatus, was mixed and integrated by stirring and mixing to make a plastic mixture with the lumps. It was attached.

  Next, the mixture is divided into two without special molding, each mixture is subjected to two different curing processes (A curing process or B curing process), and the mixture is modified to dioxins. Was captured and decomposed.

  In the curing process A, the admixture was released to room temperature in the atmosphere (during the test period: average of about 20 ° C.) and left for at least 7 days, and the treated soil was dehydrated to a moisture content of 5% by mass or less. It recovered as treated soil A.

  In the B curing process, the mixture is opened to room temperature in the atmosphere (during the test period: average of about 20 ° C.) and left for at least 24 hours, and then exposed to 100 ° C. for about 30 minutes for further dehydration treatment. The treated soil that had been subjected to dehydration treatment in which the moisture content of the soil was zero was recovered as treated soil B.

Dioxin content in the treated soil A and the treated soil B subjected to the modification treatment was measured, and the result of the treated soil A was displayed in Table 38 and the result of the treated soil B was displayed in Table 39.
Moreover, the simple type deformability measurement test [q = KN / m ² ] in the treated soil A and the treated soil B was tested, and the water elution pH was tested. The results are also shown in Table 40.

  As a result, in the untreated contaminated soil, the treatment / reaction via water with the treatment material of the present invention was started up for the contaminated soil containing dioxins to form an admixture, and then the admixture Is subjected to a reforming process that makes the water content as close to zero as possible without any special high-energy treatment, thereby capturing and decomposing dioxins contained in contaminated soil. The soil treated with non-polluted materials that have been reduced to below the standard has been modified, and contaminated materials contaminated with dioxins can be purified at a low cost without any special environmental impact. Well understood.

［実施例１４］

[Example 14]

  In this example, the target material is water-soluble chlorine-containing incineration ash, which is a contaminated material, and the treatment material is homogeneously mixed with the incineration ash and reacted via an aqueous activator added to the incineration ash. The method of utilizing and using the processing material to granulate and granulate the admixture that has been activated and to make the water-soluble chlorine insoluble and immobilized to make it a non-polluted product will be described.

As the treatment material adopted in this example, sample number: 2-5 was selected from the treatment materials prepared in Examples 1 and 2.
The incinerated ash recovered by incineration of general waste containing 1.35% by mass of water-soluble chlorine was selected as the contaminating material that was the target material adopted in this example.
The water-based activator adopted in this example was selected from well water for drinking.

  In this example, incineration ash is granulated and water-soluble chlorine is insolubilized / immobilized to produce an inorganic molded product made of non-polluted material. The processing material shown in Example 5 is compounded with sand granules as the target material. It was based on the utilization method of granules prepared from the composite material.

  The working process for processing and preparing the granule using the incinerated ash as the target material in this example is a mixer having rotating stirring shaft blades by adding 20 kg of treatment material and 60 kg of well water to 100 kg of incinerated ash as the target material. The mixture is subjected to a mixing and processing step for forming a granule having a particle diameter of 2 to 10 mmφ while mixing and stirring for about 10 minutes, and the molded granule is subjected to 28 days in a normal temperature atmosphere. An inorganic molded product made of granules was processed and prepared by a process for the curing process.

  The water resistance / heat resistance, water elution pH, load strength (kg) and water-soluble chlorine (mg / kg) in the granules prepared here were measured and evaluated in accordance with physical property evaluation test methods. These results are also shown in Table 41.

As a result of the above, the incinerated ash granule that was made into a granular material by adding well water to the treated material and mixing it with the incinerated ash containing water-soluble chlorine containing the contaminated material has water resistance and heat resistance. The water elution pH is less than 12, shows a load strength of 5 kg or more, and is prepared as an inorganic molded product made from water-soluble chlorine insoluble and immobilized and made non-polluted. Thus, the utilization method of the processing material of the present invention to be recycled is well understood.
[Example 15]

  In this embodiment, an inorganic molded product in which a heat-resistant film is processed and prepared by an energy-saving type using a paste-like mixture prepared from a composite material obtained by combining a filler as a target material with a treatment material and water will be described.

As a treatment material in this example, sample number: 2-9 was selected from the treatment materials prepared in Example 2.
As the filler of the target material, fly ash [sample number: 10-4] discharged from the thermal power plant which is a powdery material of 100 μm or less from the material shown in the auxiliary composition was selected.
Tap water was chosen as the water based activator.

  The paste-like admixture in the present example was prepared by a mixing process in which 100 parts by mass of fly ash as an object material and 40 parts by mass of tap water were added to 100 parts by mass of the treated material of the present invention and kneaded and mixed homogeneously.

Film processing with paste-like admixture is performed on both sides of glass fiber woven fabric using a woven fabric made of glass fibers (weight: 149 g / m ² , thickness: 0.2 mm, width: 92 cm) as a base material. The impregnated paste mixture prepared with the treatment material, filler and water of the present invention is impregnated to a total thickness of about 4 mm and left on a plastic film at about 80 ° C. for 60 minutes to complete the hydraulic reaction. An inorganic film based on a glass fiber woven fabric was processed and prepared in the curing process.

  The water resistance and heat resistance of the inorganic film prepared here were confirmed, and the water elution pH was measured. As a result, it had water resistance and heat resistance, and the water elution PH was 9.0. Further, the tensile strength of the film molded and prepared with the treatment material of the present invention was 980 N (vertical 50 mm × width 100 mm).

As a result of the above, a film prepared using a glass fiber woven fabric as a base material by a paste-like admixture obtained by mixing and integrating the treatment material of this example, a powder filler having a particle size of 100 μm or less, and an aqueous activator of tap water. It is understood that the adhesion test specimen is processed and prepared into an inorganic molded article having a certain tensile strength, water resistance and heat resistance, and a low alkaline film having a water elution pH of 9.0.
[Example 16]

  In this example, for a composite material obtained by combining an adsorbent powder as a target material with a treatment material, the adsorbent powder prepared and processed by starting a reaction via an aqueous activator is solidified and consolidated. The inorganic molded product forming the adsorbent will be described.

As the treatment material in this example, two types of sample numbers 2-1 and 2-8 were selected from the powdery material treatment material prepared in Example 2.
As the adsorptive powder of the target material in this example, the inorganic adsorbent powder (silica gel powder, natural zeolite powder, carbon-silicate alumina, acidic acid having a specific surface area of 500 m ² / g or more shown in Table 42 is used. I chose white clay powder.

The charcoal-silicate alumina selected in the present example is carbonized charcoal obtained by carbonizing industrial waste paper sludge selected as an adsorbent support in the functional composition with the auxiliary composition of the reference example. An acid aluminum composite [main component: carbon: 25.5, silica: 35.6, alumina 27.5, calcium 11.4 (% by mass)] was selected.
Tap water was selected as the water based activator adopted in this example.

  The processing and preparation of the consolidated adsorbent in the present example was carried out by using the granule with the sand granule as the target material shown in Example 5 at the blending ratio shown in Table 42 and the adsorbent powder to the treatment material. Body and tap water are added to a batch type simple cement mortar preparation machine [φ100 × 0.5cm Tarai type equipped with a stirrer at the center] to prepare an admixture with mixing and stirring for about 10 minutes. Then, it was granulated and molded into granules having a diameter of 2 to 8 mmφ, and subjected to a curing process that was allowed to stand at 20 ° C. for 7 days to prepare an inorganic molded product comprising the granules.

  The inorganic molded product comprising the granule processed and prepared here was evaluated by measuring water resistance, heat resistance, water elution pH and specific surface area reduction rate (%) according to the physical property evaluation test method. The results are also shown in Table 43.

As a result of the above, the adsorbent powder has a mixture obtained by integrating the treated material of the present invention, an inorganic adsorbent powder having a specific surface area of 500 m ² / g or more, and water. The specific surface area reduction rate of the granule processed and prepared without being crushed by the treatment material binder is ensured to be 20% or less, the water elution PH is less than 12, and it has water resistance and heat resistance. It is well understood that adsorptive granules having a specific surface area of the body are processed and prepared.
[Example 17]

  In this example, a paste-like material prepared by adding a water-based activator to a composite material in which carbon-aluminum silicate is combined with a treatment material with respect to the surface of the particle, with the particle as a core as a core. An inorganic molded product made of a granule in which a mixture film is coated and coated to form a heterogeneous film in which a heterogeneous film having a different function from the core particle is formed on the surface of the core particle will be described.

  As a granule serving as a core of a granule for forming a heterogeneous film, a commercially available pearlite grain having a bulk specific gravity of 0.5 to 0.6 (g / cc) that is sized to 2 to 8 mm (800 obsidian) is used. A lightweight inorganic granular material that was rapidly heated at ˜1200 ° C. and expanded in volume was selected.

The treatment material [sample number: 1-17] shown in Example 1 was selected as the treatment material.
As the carbon-aluminum silicate for preparing the paste-like admixture with the treatment material of the present invention, the carbon-aluminum silicate squeezed with the support composition of the reinforcing composition having adsorptive functionality was selected.
The paste-like admixture was prepared by adding 100 parts by mass of the treatment material and 100 parts by mass of water of the water-based activator to 100 parts by mass of carbon-aluminum silicate and mixing them uniformly.

  To process and prepare a heterogeneous film on the surface of the granule, which is the core of the granule, the core core is placed in a batch type simple cement mortar preparation machine [φ100 × 0.5cm Tarai type with a stirrer in the center]. The pearlite granule is added, and the surface of the pearlite granule is coated with the paste-like mixture of charcoal-aluminum silicate while stirring and mixing the fluid-plastic paste-like mixture prepared with charcoal-aluminum silicate and the treatment material. did. Next, the granule coated with carbon-aluminum silicate as a heterogeneous film was allowed to stand at room temperature for 24 hours to prepare a light-weight granule coated with an adsorbing heterogeneous film.

  The physical properties of the lightweight adsorbent comprising the condylar granule having a heterolayer prepared here were measured and evaluated. As a result, the lightweight condyle granule having a heterolayer film had heat resistance and water resistance, a bulk specific gravity of 0.60, and a water elution pH of 8.5.

As a result of the above, a granule having a small bulk specific gravity is used as the core, and this granule core is coated with the treatment material of the present invention and carbon-aluminum silicate, has heat resistance and water resistance, and has adsorptivity. A light-weight granule is formed by coating a heterogeneous film, and the inorganic material comprising a granule having a heterogeneous film that is coated with an inorganic and adsorptive material by using the treatment material according to the present invention. It is well understood that molded articles are prepared.
[Example 18]

  In this example, for a composite material in which a heat-resistant granular material containing heat insulation, heat insulation, and heat-resistant waste material as a target material is combined as a target material, a reaction is started via water to prepare a molded body. Insulating, heat-insulating and heat-resistant inorganic molded products prepared at least at room temperature will be described.

As the treatment material in this example, two types of sample numbers 2-1 and 2-8 were selected from the powdery material treatment material prepared in Example 2.
As the heat-resistant granular material that is the target material in this example, an oxide or non-oxide inorganic powder granular material including waste materials for heat insulation, heat retention, and heat resistance shown in Table 38 was selected.
Tap water was selected as the water based activator adopted in this example.

  The heat insulating, heat retaining and heat resistant material of the present example was prepared by adding the treatment material and tap water to the heat resistant granular material of the target material and mixing and mixing them at the mixing ratio shown in Table 44. did. Next, the mixture was molded into a cylindrical test specimen and allowed to stand at room temperature for 7 days to prepare a circular processed specimen.

The water resistance, water elution pH, and heat resistance strength retention rate were measured in accordance with the physical property evaluation test method for the physical properties of each heat treatment, heat retention, and heat resistant material formed into a cylindrical processed test body molded at room temperature.
The results are also shown in Table 45.

As a result of the above, the heat-insulating / heat-retaining / heat-resistant material prepared by normal temperature construction that is subjected to the curing process by mixing the heat-resistant granular material including waste materials into the target shape through water with the treated material of the present invention is The heat-insulating, heat-retaining and heat-resistant materials that have a certain heat-resistant strength retention rate and have a water elution pH of less than 12 are processed at room temperature to prepare unfired heat-insulating, heat-retaining and heat-resistant materials that can be applied on site. Understood.
[Example 19]

  In this example, a heat-insulating, heat-insulating and heat-resistant material is required for a mixture obtained by adding water to a composite material in which heat-treated powder containing waste material of heat-insulating, heat-insulating and heat-resistant materials as a target material is treated. Explains non-fired heat insulation, heat insulation, and heat-resistant materials prepared by direct processing and construction at room temperature.

As the treatment material in this example, two types of sample numbers 2-1 and 2-8 were selected from the powdery material treatment material prepared in Example 2.
As the heat-resistant granular material, which is the target material in this example, an oxide or non-oxide inorganic granular material including the waste materials of heat insulation / heat insulation / heat resistant materials shown in Table 40 was selected.
Tap water was selected as the water based activator adopted in this example.

  The heat insulating, heat retaining and heat resistant materials in this example were mixed at the blending ratio shown in Table 40, and the fluid plastic admixture was obtained by adding the treatment material and tap water to the target heat resistant powder and mixing them together. A product was prepared. Next, the admixture was molded into a cylindrical test specimen and allowed to stand at room temperature for 7 days to prepare a circular processed test specimen as a heat insulating, heat retaining and heat resistant material.

The water resistance, water elution pH, and heat resistance strength retention rate were measured in accordance with the physical property evaluation test method for the physical properties of each heat treatment, heat retention, and heat resistant material formed into a cylindrical processed test body molded at room temperature.
The results are also shown in Table 41.

As a result of the above, heat-resistant granular materials including waste materials of heat insulation, heat insulation, and heat resistant materials are made into a fluid or plastic admixture with the treatment material water of the present invention, and at room temperature where heat insulation, heat insulation, heat resistant materials are required. It is well understood that it is possible to construct on-site construction type non-fired heat insulation, heat insulation, and heat resistant material with a constant heat resistant strength retention and a water elution pH of less than 12 by performing the construction.
[Example 20]

  In Examples, an acid-resistant material inorganic molded article prepared by activating a reaction via water contained or added to a composite material obtained by combining alkali silicate or composite water glass as a target material with a treatment material will be described. .

As the treatment material in this example, three types of sample numbers 1-10, 1-14 and 2-2 were selected from the powdery material treatment material prepared in Example 2.
As the alkali silicate which is the target material in this example, commercially available No. 3 water glass [JIS K 1408: SiO ₂ 28-30%, Na ₂ O 9-10%] [sample number: QS-1] is selected. It is.

The composite water glass which is a target material of this example is a term of an auxiliary composition with respect to 100 parts by mass of commercially available No. 2 water glass [JIS K 1408: SiO ₂ 34 to 36%, Na ₂ O 14 to 15%]. The composite water glass [sample number: QW-1] in which 15 parts by mass of white carbon shown in FIG.
Tap water was selected as the water-based activator adopted in this example.

  The acid-resistant material in the present example is a mixture ratio shown in Table 42, and the processing material and, if necessary, aggregate (river sand: 0.5 to 4 mm) with respect to the target material alkali silicate or composite water glass. Was added, and tap water that gave fluidity necessary for workability was added as needed to prepare a mortar-like mixture that was mixed and integrated.

  The prepared mortar-like mixture was molded into a cylindrical test specimen and allowed to stand at room temperature for 7 days to prepare a circular processed specimen as an acid resistant material. The physical properties of each prepared cylindrically treated specimen were evaluated by measuring the water resistance, water elution pH, and the strength retention of acid resistant material when immersed in an acidic solution of pH 3. The results are also shown in Table 43.

  As a result of the above, the acid resistant material prepared by combining the treated material of the present invention with an alkali silicate or composite water glass is immersed in an acidic solution of pH 3 and has no change in material, and is water resistant and heat resistant. Above is acid resistant. Therefore, it is fully understood that it is effective as a flooring material or a structure material for chemical factories, food factories, kitchens, hot spring resorts, etc. that require acid resistance.

［実施例２１］

[Example 21]

  In the present embodiment, the solidified material in which the slurry in which the treatment material is dispersed in the water-based activator is injected and mixed and integrated into a container in which a galactor aggregate which is an aggregate of galactors as a target material is stored. Explaining the integrated inorganic molded product

  As a processing material in a present Example, it can inject | pour when processing material [sample number 1-15] is prepared in the slurry form from the powdery body processing material prepared in Example 1 on the basis of sample number 1-15. In order to ensure fluidity, a treatment material [Sample No. 2-15] is obtained by adding 10 parts by mass of barium silicate) which is a barium salt composition of an auxiliary composition to 100 parts by mass of the treatment material [Sample No. 1-15]. 10] and two types of treatment materials of sample number 2-2 prepared in Example 2 were selected.

  In order to inject the treatment material into the container in which the trash assembly is stored, a slurry mixture (G) in which 100 kg of tap water was added to 100 kg of each treatment material and dispersed was selected. The fluidity of the admixture (G) prepared here was measured as viscosity in a certain time range, and the continuity of the integrated work for injecting the admixture into the trash assembly container was confirmed.

  The viscosity of the fluid admixture of this example was measured by adding 35 ° C. water to the powdery treatment material maintained at 30 ° C. at a predetermined ratio and stirring the prepared fluid admixture at a constant temperature of 52 ° C. After curing in a tank, the viscosity of the mixture after 60 minutes was measured with a C-type viscometer, and the results are shown in Table 44 in CP [centipoise].

  In this example, the limit paste viscosity that enables injection integration without leaving a gap in the container is in a range where the paste viscosity after 10 minutes of paste preparation does not exceed 8000 CP, while the working life that can be worked is set. One hour was defined as a condition that ensures a good workability with a viscosity not exceeding 20,000 CP in the range of one hour.

  As a junk aggregate which is a target material in the present embodiment, a junk of tablet ellipsoidal spheres obtained by pressure-molding waste sodium sulfate (sodium salt) powder contained in a 200 L drum can into a 30 × 20 × 15 mm almond shape. I picked an aggregate

  As the garakuta aggregate which is the target material in this example, the garakuta which consists of a group of tablet ellipsoidal spheres obtained by pressure-molding waste sodium sulfate (sodium salt) powder contained in a 200 L drum can into an almond shape of 30 × 20 × 15 mm I picked an aggregate

  The almond-shaped salt cake formed into a pressure tablet was filled into a 200 L drum can lined with a special cement and filled with 260 kg to obtain an integrated molded product. 110 kg of the slurry-treated material was poured into the molded object to be integrated with care so as not to leave a gap in the drum can in 10 minutes to obtain an integrated molded object.

  At this time, a cylindrically processed specimen was simultaneously prepared in accordance with the physical property evaluation test method shown in this specification for the slurry-like treatment material adopted for the integrally molded product, and left at room temperature (about 25 ° C.) for 7 days. For each cylindrically treated specimen, physical properties of the prepared cylindrically treated specimen were evaluated by measuring water resistance and water elution pH. The results are also shown in Table 45.

  As a result of the above, the slurry of the treatment material of the present invention in which the injection fluidity is ensured for a certain period of time is poured into the drum can container in which the target material having a certain porosity is stored in the group of almond-like sodium sulfate. When integrated into an integrated molded product, a group of almond-like sodium sulfate aggregates is prepared into an integrated solid body.

  The effect of solidifying various shapes of waste as an integrated material in this way makes it possible to integrate and dispose of tangible wastes that are disliked to diffuse, for example, This suggests that it can be effectively used as a disposal method.

  The present invention solves the problems that conventional hydraulic solidification materials have, and is stable at low cost with a manufacturing technology that does not give environmental load to ordinary temperature hydraulic processing materials with versatility with shelf life ensured It can be used in industrial fields that can contribute to the elimination of environmental problems and the creation of a recycling-oriented society. The possibility is expected.

Claims (52)

In a processing material which is composed of a powdery powder of three essential components of a calcia glass prepared from a mixed raw material prepared in advance, an active silica having an alkali silanol group and a sulfate having a sulfate group;
The mixed raw material is composed of a mixed raw material consisting of a single material or a combination of two or more selected from the group consisting of a silicate composition, a calcium composition and an alumina composition, and the basic ratio of the composition components of the mixed raw material However, at least 10 to 100 parts by weight of alumina and 50 to 350 parts by weight of alumina and, if necessary, 1 to 100 parts by weight of sodium oxide, with respect to 100 parts by weight of silica expressed on an oxide basis. And
The above-mentioned calcare glass is a calcined glass powder obtained by pulverizing and classifying the heat-treated product obtained by heat-treating the above mixed raw material at least at 820 ° C. into fine particles passing through a 100 mesh sieve, and the water elution pH of the heat-treated product powder Is an inert powder showing less than 12;
The above active silica has the following composition formula (1)

[In the formula, M is an element of hydrogen, sodium or potassium] A single material mainly composed of alkali silicate having an alkali silanol group and water-soluble sodium, or a silicic acid compound having silanol group Active powder consisting of a composite material in which a sodium salt compound and a sodium salt compound coexist;
The above sulfate has the following composition formula (2)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. A basic salt of a metal element oxyacid salt compound represented by the formula: or a sulfate group-containing compound or a powder of a composition comprising a combination of two or more selected from the group of normal salts Is;
The above-mentioned one-pack formation is performed by adding 5 to 100 parts by mass of active silica and 3 to 140 parts by mass of sulfate with respect to 100 parts by mass of inert calcium glass having a particle size of 100 μm or less, preferably 50 μm or less. It is made into one pack by mixing the essential 3 components added in a quantity ratio uniformly;
The above-mentioned treatment material is a treatment material characterized in that the essential three components are packed into one pack to ensure shelf life, and a treatment / curing / binding function is exerted on the target material by a normal temperature hydraulic reaction. In the treatment material which is composed of four components obtained by adding an auxiliary composition to the treatment material composed of the essential three components of the inert calcium glass, active silica and sulfate;
The above auxiliary composition is a crystal seed composition, sodium supplement composition, calcium supplement composition, sulfate radical supplement composition, reinforcing material composition, phosphate radical composition, barium salt composition, iron salt supplement composition, addition A composition comprising a single material or a combination of two or more selected from the group consisting of a raw material composition, a dispersion medium composition, a carrier composition and a functional composition, and the composition is a powder or spherical powder Powder, fibrous powder, flaky powder or sandy powder;
The above-mentioned one-packing is performed by adding 50 to 100 parts by weight of active active silica and 3 to 140 parts by weight of essential active ingredient of 3 to 140 parts by weight with respect to 100 parts by weight of inert calcium glass, and further adding an auxiliary composition. 4 components added in an amount of 1 to 300 parts by mass are uniformly mixed into one pack;
The above-mentioned treatment material is a one-pack of 4 components added to the essential 3 components of the treatment material to ensure shelf life, and exhibits treatment / curing function for the target material by room temperature hydraulic reaction The treatment material according to claim 1.   The silicate composition comprises 45 to 80% by mass of silica, 5 to 35% by mass of alumina, 0.1 to 25% by mass of iron oxide, and alkaline earth metal [Mg or Ca]. A lamellar clay mineral containing 0.5 to 25% by mass of an oxide of the above, silicate, alkali silicate, hydrous soil, thermal history and waste silicate The treatment material according to claim 1 or 2, which is a silicate composition mainly composed of a combination silicate.   The layered clay mineral is composed of one or a combination of two or more selected from the group consisting of allophane, hysinger gel, pyroferrite, talc, mica, montmorillonite stone group, vermiculite, ryokdeite stone group, kaolinite and inosilicate. The treatment material according to claim 3, which is a layered clay mineral of ferrosilicate.   The silicate is a natural or synthetic silicate compound, wollastonite, zonotolite and tobermorite calcium silicate, magnesium silicate, quartzite, quartz, cristobalite, opalite, feldspar, zeolite, granite / metamorphic rock, The treatment material according to claim 3, which is a single or a combination of two or more kinds of silicate compounds selected from the group of rock minerals such as rhyolite and conglomerate and mordenite. The alkali silicate is represented by the following composition formula (3)

[Wherein, M is an element of sodium or potassium, a is a number of 0.1 to 4, and w is a number of 16 to 50] alone or in combination of two or more selected from the group of alkali silicates The treatment material according to claim 3, which is an alkali silicate.   The above-mentioned hydrous soils are the construction site ground and by-product soils, low-grade soils deposited in the sea, lakes, swamps, rivers, dams, hydrous clayey soils, mud mud soils, organic soils, weathered rocks, The treatment material according to claim 3, which is a hydrous soil having a water content of at least 25% by mass, consisting of a single or a combination of two or more selected from the group of soft ground soil, viscous / sandy soil and sewage sludge.   The above-mentioned thermal history materials are incineration ash of wastes mainly composed of silicate, carbonization ash, coal ash, briash, blast furnaces and steelmaking slugs, volcanic ash and lava volcanic products, emissions from the ceramic industry 4. The treatment material according to claim 3, wherein the treatment material is a silicate compound which comprises a single or a combination of two or more selected from the group of materials and silicate glass and has undergone a heat treatment history.   The above-mentioned waste silicate is an oil-containing waste white clay expressed by an oxide standard and having a silicic acid content of 50% by mass or more, discharged water purification cake during water purification, ceramic waste materials, ceramic inorganic moldings Silicate compound consisting of a single or a combination of two or more selected from the group of waste products, residual soil or waste soil from the construction and civil engineering industries, and silica-based waste discharged from the chemical industry The treatment material according to claim 3, which is a kind.   The above-mentioned calcite composition is selected from the group consisting of a calcite composition containing at least 25% by mass of calcium oxide, a calcium salt composition, a waste composition, a cement composition, and a charcoal cal-modified composition. The treatment material according to claim 1 or 2, which is a calcium composition comprising a combination of two or more. The above-mentioned calcite composition has the following composition formula (4)

[Wherein w is a number of 2 or less including zero] represented by calcium oxide, a calcium component consisting of a single or combination of two or more selected from the group of calcium oxide or calcium hydroxide represented by 50% by mass or more The treatment material according to claim 10, which is a calcium compound contained. The calcium salt composition has the following composition formula (5):

[Wherein, T is an element of an aluminum, silicon, nitrogen, phosphorus, or carbon element group alone or a combination of two or more, X is a halogen element, a, b, and c are numbers of 10 or less including zero, and m is 0 Calcium comprising a single or a combination of two or more selected from the group of normal salts or basic salt compounds of calcium oxyacid salt compounds represented by the number of .5 to 6 and w is a number of 28 or less including zero]] The treatment material according to claim 10, which is a calcium salt compound containing at least 30% by mass of the compound based on CaO oxide.   The above-mentioned waste composition is mainly composed of a calcium salt compound consisting of lime neutralized sludge, waste gypsum, blast furnace and steelmaking slag, or a combination of two or more kinds selected from the group of waste calcium silicate. The treatment material according to claim 10, which is a waste material to be treated.   Portland cement, mixed cement (blast furnace cement, silica cement, fly ash cement, etc.), special cement (white cement, alumina cement, super-hard cement, colloidal cement, oil well cement, geothermal cement, swelling cement) The treatment material according to claim 10, which is a hydraulic cement mineral composed of one or a combination of two or more selected from the group of the above.   The charcoal cal-modified composition contains hydrochloric acid, sulfuric acid, sulfurous acid, nitric acid, nitrous acid, silicic acid, aluminosilicic acid, aluminate, boric acid and phosphorus with respect to 100 parts by mass of calcium carbonate containing calcium carbonate as a main component. The treatment material according to claim 10, which is a carbonized cal-modified composition which is decarboxylated by adding 50 parts by mass of an acid radical consisting of a single or a combination of two or more selected from the group of acids and heat-treating it at 980 ° C or lower. The alumina composition has the following composition formula (6):

“In the formula: M is an alkali metal, Z is an alkaline earth metal, a is a number of 5 or less including zero, b is a number of 5 or less including zero, and w is a number of 9 or less including zero]. The treatment material according to claim 1 or 2, which is an aluminum compound comprising one or a combination of two or more selected from the group of alkali metal or alkaline earth metal aluminate or aluminum hydroxide.   The above-mentioned calcium glass is a low crystalline or amorphous compound mainly composed of calcium silicate which has already undergone a thermal history and satisfies the above-mentioned basic composition ratio composed of at least silica, alumina and calcium. The treatment material according to claim 1, wherein the treatment material is an inactive powdery material that is pulverized and classified and has a water elution pH of less than 12. 4.   Active single active silica powder comprising the active silica composed of an alkali silicate consisting of a single or a combination of two or more selected from the group of alkali silicates represented by the composition formula (3) The treatment material according to claim 1 or 2. The active silica is a single active silica composed of sodium-modified silicate that modifies the silicate raw material with a sodium salt compound;
The silicate raw material is a silicate compound selected from the silicate composition;
Said sodium salt compound is the following composition formula (7)

[In the formula, T is silicon, aluminum, nitrogen, sulfur, carbon, boron, phosphorus element group alone or in combination of two or more elements, X is a halogen element, a and b are numbers of 10 or less including zero, m is An active powder comprising a single or a combination of two or more selected from the group of sodium salt compounds represented by the number of 0.5 to 6, w is a number of 12 or less including zero];
The sodium-modified silicic acid is a mixed material obtained by adding 1 to 30 parts by mass of a sodium salt compound and 50 parts by mass or less of water with respect to 100 parts by mass of the silicate composition. An active sodium-modified silicic acid containing at least 50% by mass or more of an active alkali silanol group-containing sodium silicate comprising a powder that has been modified by reaction and dehydrated, dried, pulverized and classified as necessary. The treatment material according to claim 1 or 2, which is a powder of a single active silica salt. The active silica is configured as a composite active silica in which a silicic acid compound having a silanol group and a sodium salt compound coexist;
The silicic acid compound having a silanol group (—OH) is one or more selected from the group consisting of hydrogel that is hydrous and amorphous silicic acid, xerogel that is amorphous silicic acid, and ferrosilicate compound Active granule consisting of a combination of:
The active sodium salt compound is an active powder comprising a single or a combination of two or more selected from the group of sodium salt compounds represented by the composition formula (7);
An active composite powder in which the above composite active silica is uniformly mixed into one pack by adding 30 to 180 parts by weight of a sodium silicate salt compound to 100 parts by weight of silanol group-containing silicate compound The treatment material according to claim 1, which is a body. In a composite material prepared by coexisting two components of calcium glass constituting the treatment material and sodium-modified silicic acid of active silica;
At least 820 mixed composite materials in which 10 to 100 parts by mass of the mixed material that is the raw material of the sodium-modified silicic acid is added to and mixed with 100 parts by mass of the mixed raw material that is the raw material of the calcia glass. A heat-treated product that has been heat-treated at 0 ° C. and then pulverized and classified into fine particles that have passed through a 100-mesh sieve to form a powdery product in which two components of calcium glass and sodium-modified silicic acid of active silica coexist. 3. The treatment material according to 1 or 2. The crystal seed composition as the auxiliary composition is represented by the following unit cell composition formula (8):

[Wherein, M is a metal cation of valence n :, and X + Y is the number of tetrahedrons per unit cell] selected from the group of zeolites having a zeolite structure of a metal salt of aluminosilicate represented by The treatment material according to claim 2, which is a powder of zeolite or zeolite precursor comprising a combination of the above.   The supplemental sodium supplement composition is a powder of an active sodium salt compound consisting of a single or a combination of two or more selected from the group of sodium salt compounds represented by the composition formula (7). The processing material according to claim 2.   The calcium supplement composition as the auxiliary composition is a single or a combination of two or more selected from the group consisting of a normal salt or a basic salt compound of a calcium oxyacid salt compound represented by the composition formula (5). The treatment material according to claim 2, wherein the calcium salt composition is a powder of a calcium salt composition containing at least 30% by mass of calcium oxide based on CaO oxide. The sulphate radical replenishing composition as the auxiliary composition has the following composition formula (9):

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number from 1 to 8, and n is 2 or 3. Powders of sulfate group-containing salt compounds consisting of a single or a combination of two or more selected from the group of sulfur oxyacid salt compounds of each metal element represented by the number, w is a number of 10 or less including zero] The treatment material according to claim 2.   The reinforcing material composition as the auxiliary composition is made of metal powder / fiber, glass fiber, rock wool, carbon fiber, mineral fiber, vegetable fiber, organic fiber, inorganic powder, sand, gravel, weight / light bone The treatment material according to claim 2, which is a filler, a fiber material or an aggregate composed of a single material or a combination of two or more selected from the group of materials and cullet. The phosphate group composition which is the auxiliary composition is represented by the following composition formula (10):

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, titanium, silicon and iron, h is a number from 1 to 8, and t is a G element valence. ÷ a number of 2 and w is a number of 10 or less including zero] Phosphorus oxyacid compounds composed of a single or a combination of two or more selected from the group of phosphorus oxyacid compounds of each metal element The treatment material according to claim 2, which is a powdery material. The barium salt composition, which is the auxiliary composition, has the following composition formula (11):

[Wherein f is a number of 4 or less, w is a number of 10 or less including zero] of a barium salt compound consisting of a single or a combination of two or more selected from the group of barium salts soluble in an alkaline solution The treatment material according to claim 2 which is a powdery body. The iron salt replenishing composition as the auxiliary composition has the following composition formula (12):

[Wherein, T is an element of an aluminum, silicon, sulfur, nitrogen, phosphorus element group alone or a combination of two or more, n is a number of 2 to 3, m is a number of 0.5 to 6, and w is zero. The treatment material according to claim 2, which is a powder of an iron salt compound consisting of a single or a combination of two or more selected from the group of oxyacid salt compounds of each element of iron represented by .   The treatment material according to claim 2, wherein the additive material composition which is the auxiliary composition is a powdery material of an additive material consisting of a single material or a combination of two or more selected from the group of pigments, colorants and fillers.   The auxiliary medium is a dispersion medium composition comprising kaolin, acid clay, bentonite, caustic earth, talc, zeolite, coal ash, bauxite, iron ore, perlite, gypsum, shell, silicate glass and volcanic ash. 3. The treatment material according to claim 2, which is a dispersion medium composition comprising a selected inorganic compound composed of a single or a combination of two or more and a powder of 100 μm or less, and preferably a fine powder of 10 μm or less. The support composition which is the auxiliary composition is a single or a combination of two or more selected from the group consisting of charcoal, amorphous silica, activated silicic acid, activated alumina and zeolite having a surface area of 100 m ² / g or more. The treatment material according to claim 2, which is an adsorptive carrier.   The function-imparting composition as the auxiliary composition is a function-imparting composition consisting of one or a combination of two or more selected from the group consisting of an activator, a magnetic substance, an antimicrobial agent, a water-repellent adsorbent and a functional additive The treatment material according to claim 2, which is a powdery body of the composition. A single material or a single material composed of the treatment material according to any one of claims 1 to 33, or a composite material obtained by combining a target material with a single material, In a utilization method utilizing the processing / curing function for the target material due to the hydraulic reaction of the processing material through a series of work steps to process and prepare the inorganic molded product;
The above-mentioned single item material is a single item of treatment material that is made into one pack by adding an auxiliary composition as required to the three essential components of calcium glass, active silica, and sulfate;
From the group of the above-mentioned composite material, sand particles, filler, hydrous soil, contaminated material, adsorbent powder, heat-resistant powder, alkali silicate material and galactor aggregate with respect to 100 parts by mass of the treatment material A composite product in which 1 to 2000 parts by mass of a target material consisting of a single selected or a combination of two or more selected is mixed;
The above water-based activator is selected from the group of natural water [rain water, river / lake water, pool water, well water, seawater], artificial pond / dam water, processed water, treated water or wastewater in the industry. An aqueous liquid serving as a reaction initiator for a treatment material comprising a combination of more than one species;
The above-mentioned modified processed product is a modified processed product that has been solved with low alkalinity by modifying the target material having a problem with a single material or a composite material;
The inorganic molded product is an inorganic molded product that is used as a cured product or binder that is a molded product by processing and preparing a single product or a composite material;
The above-described series of work steps is a mixing step in which a water-based active agent is allowed to coexist with a single material or a composite material to make a fluid, plastic or flaky mixture, and if necessary, the mixture is used as a molded product. A plurality of steps consisting of a curing step to complete a hydraulic reaction in the admixture or the molded product;
The above mixing step is a step of mixing with 100 parts by mass of a single material through at least 15 parts by mass of an aqueous activator to form an admixture;
The above processing step is a step of molding the mixture into a specific shape or an unspecified shape to form a molded product;
In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A process for making a modified product or an inorganic molded product under curing conditions in which it is allowed to stand for 10 minutes or longer in a single atmosphere or a multistage atmosphere consisting of a combination of two or more selected from the group of the following atmospheres;
The above modified product or inorganic molded product is water-resistant and heat-resistant with respect to the target material, and has been modified or processed to a low alkalinity with a water elution pH of less than 12.
The above utilization method applies the single material or composite material to a series of work processes by using the processing material, thereby reforming the target material into the modified processing product, or processing material or target material as the material A utilization method characterized by processing and preparing an inorganic molded product as a raw material.   The above-mentioned modified treated product or inorganic molded product is a modified treated product or structure in which water resistance and heat resistance are ensured, water elution pH is low alkalinity of less than 12, and the problem of the target material is solved Body, composite hardened body, granule body, aggregate body, adhering body, film, hydrous soil modified product, non-polluted product, consolidated adsorbent, heat insulating / heat retaining / heat resistant material, acid resistant material or integrated product The utilization method according to claim 34. 34. The treatment material according to any one of claims 1 to 33 is modified by a series of work steps in which a treatment / curing function for a target material included in the treatment material is exhibited and an aqueous activator is allowed to coexist with the target material. In quality-treated modified products;
The above-mentioned treatment material is a treatment material that is made into one pack by adding an auxiliary composition to the essential three components of calcium glass, active silica, and sulfate as required;
The above target material is selected from the group of problematic sand particles, fillers, hydrous soils, contaminated materials, adsorbent powders, heat-resistant powder particles, alkali silicate materials, and galactor aggregates. A target material consisting of a combination of more than one species;
The above water-based activator is one or more selected from the group of natural water [rain water, river / lake water, pool water, seawater], artificial pond / dam water, processed water, treated water or wastewater in industry. An aqueous liquid which is a reaction initiator for a treatment material comprising a combination of
The above-mentioned series of work steps is a mixing step in which a treatment material and an aqueous activator coexist with the target material to make it a fluid, plastic or dry blend, and if necessary, molding the blend Comprising a plurality of steps consisting of a curing step to complete a hydraulic reaction in the admixture or molded product, and a modified product is obtained;
The above mixing step is a step of adding at least 10 parts by mass of the treatment material to 100 parts by mass of the target material and simultaneously forming an admixture through at least 10 parts by mass of the water-based active agent;
The above processing step is a step in which the mixture is molded into a specific shape or an unspecified shape to obtain a molded product;
In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A process under curing conditions that is allowed to stand for at least 10 minutes in a single atmosphere or a multistage atmosphere composed of a combination of two or more selected from the group of atmospheres of
The above-mentioned modified treatment products demonstrate the treatment and curing functionality of the treatment material through a series of work steps in which the treatment material and water-based activator coexist with the target material, ensuring water resistance and heat resistance, and water elution A modified product having a low alkalinity with a pH of less than 12. In the modified treated product in which the treated material is modified by a series of work steps through an aqueous activator that coexists with the hydrous soil that is the target material;
The above-mentioned target material contains nitrogen components (ammonia nitrogen, nitrate) above the reference value (1 mg / L) of total nitrogen elution amount in the sea area based on fishery water standards, and water is contained in an amount of 25 to 80% by mass. Fluid or plastic hydrous soil containing in the range of mass%;
The above-mentioned series of work steps are mixed in the mixing step of adding 100 parts by mass of the treatment material to the amount corresponding to 50 to 2000 parts by mass of the hydrous soil based on the dry matter, and mixing through the water containing the hydrous soil. And the mixture is formed by a plurality of steps consisting of a curing step that completes the hydraulic reaction without forming or molding the mixture into a specific shape to obtain a modified product;
The above-mentioned modified treated products are reformed in a series of work processes where the treated material and water-based activator coexist with the hydrous soil to be treated, and the elution amount of nitrogen components contained in the hydrous soil is determined based on the water quality standards for fisheries 37. The modified product according to claim 36, wherein the modified product is suppressed to within a value, water resistance and heat resistance are ensured, and the water elution pH is modified to a low alkalinity of less than 12. In the modified treated product in which the treated material is modified by a series of work steps via an aqueous activator that coexists with the contaminated material that is the target material;
In the water elution test of heavy metals [lead, cadmium, chromium, arsenic, mercury], the above target material contains water-soluble heavy metals exceeding the national environmental standard value, and the water content is at least 15 masses. Contaminated soil ground contaminated material containing%;
The above-described series of work steps are performed in the form of a powdery material treatment material or a slurry-like material in an amount corresponding to 50 to 2000 parts by mass on the basis of dry matter of in situ soil ground containing heavy metals or moved contaminated material. The water-containing treatment material is mixed in a mixing process in which water containing water is included in an amount corresponding to 100 parts by mass on a dry matter basis and mechanically mixed or injected into the contaminated material. Curing process in which the hydraulic reaction is completed by leaving it for at least 24 hours under natural conditions at room temperature in the original processing position or moving processing place or at a temperature of 200 ° C. or lower for at least 30 minutes. Consists of multiple steps consisting of:
The above-mentioned modified treated products are reformed in a series of work steps in which treated materials and water-based activators coexist on the contaminated materials to be treated, and the amount of water elution test for heavy metals containing contaminated materials is determined by the government. Water insolubilized within the range of environmental standard value, deformability strength value by external pressure measured by simple deformation measurement test is 40 KN / m ² or less, water resistance and heat resistance are ensured, water elution pH is 12 The modified product according to claim 36, which has been modified to have a low alkalinity of less than 40%. In the modified treated product in which the treatment material is treated by a treatment method by a series of work steps through a water-based activator that coexists with a contaminated material that is a target material;
One or more selected from the group consisting of incinerated ash, sludge or contaminants, and marine hydrous mud of wastes containing the water-soluble chlorine at a concentration exceeding 0.1 mg / L. Contaminated material consisting of combinations;
The above-described series of work steps is performed on at least 20 parts by mass of a water-based activator for a composite material by adding 100 parts by mass of the treatment material to 100 to 2000 parts by mass on the basis of the dry matter of the contaminated material. An admixture process is performed to form an admixture, and the admixture is molded into a specific shape, an unspecified shape, or a granule in a processing process to form a molded product, and then the molded product is subjected to at least a natural condition at room temperature. It consists of multiple steps consisting of a curing process that is left for 24 hours to complete the hydraulic reaction and make a modified product;
The above-mentioned modified processed product is treated in a series of work steps in which the treatment material and the water-based activator coexist with the contaminated material of the treated body award material to be treated, and the water-soluble chlorine content of the contaminated material to be treated. Is supplemented and fixed at 0.1 mg / L or less, the load strength of the modified granule is ensured to be 4 kg or more, water resistance and heat resistance are ensured, and water elution pH is less than 12 low alkalinity The modified product according to claim 36, wherein the modified product has been modified. In the modified treated product in which the treatment material is treated by a treatment method by a series of work steps through a water-based activator that coexists with a contaminated material that is a target material;
The above target material is a contaminated material containing dioxins at a concentration exceeding the national environmental standard value;
The above-described series of work steps is performed on the composite material by adding 100 parts by mass of the treatment material to 100 to 2000 parts by mass on the basis of the dry matter basis of the in situ soil ground containing dioxins or moved contaminated material, The mixture is mixed by an admixing process in which at least 20 parts by mass of an aqueous activator is mixed, and then heated and dried for at least 24 hours or at 200 ° C. or lower in natural conditions at normal temperature in the processing original position or transfer processing position. A modified treated product that is allowed to stand for at least 30 minutes under the conditions and is treated in a water-free state in which the water content of the admixture is 15% by mass or less, preferably zero, to complete the hydraulic reaction / treatment. It consists of multiple processes consisting of a curing process;
The above-mentioned modified product is treated in a series of work steps in which the treated material and water-based activator coexist with the contaminated material moved or moved from the in-situ ground to be treated. The concentration and concentration of dioxins is below the environmental standard value established by the national government due to the sequestration and decomposition action, and the deformability strength value due to external pressure measured by a simple deformability measurement test is 40 KN / m ² or less. 37. The modified product according to claim 36, wherein water-resistant and heat-resistant properties are ensured, and the water-elution pH is modified to a low alkalinity of less than 12. A single material that is the processing material or a composite material that combines the target material with the processing material by exhibiting the processing / curing function for the target material of the processing material according to any one of claims 1 to 33. In an inorganic molded product that is processed and prepared into a molded body with a series of work steps in which a water-based active agent coexists;
The above-mentioned single item material is a single treatment material that is made into one pack by adding auxiliary composition to the essential three components of calcium glass, active silica and sulfate, if necessary;
The composite material is selected from the group of sand particles, fillers, hydrous soil, contaminated materials, adsorbent powders, heat-resistant powder particles, alkali silicate materials, and galactor aggregates with respect to 100 parts by mass of the treatment material. A composite material in which 1 to 2000 parts by mass of a target material consisting of a single or a combination of two or more of the above is mixed;
The above water-based activator is one or more selected from the group of natural water [rain water, river / lake water, pool water, seawater], artificial pond / dam water, processed water, treated water or wastewater in industry. An aqueous liquid which is a reaction initiator for a treatment material comprising a combination of
The above-described series of work steps includes a mixing step in which the single material or composite material and the water-based active agent coexist to form a fluidity, plasticity, or scabbard mixture, and if necessary, the mixture is formed into a molded product. Comprising a plurality of steps consisting of a curing step followed by a curing step to complete the hydraulic reaction of the admixture or the molded product to obtain an inorganic molded product;
The mixing step is a step of mixing the single material or the composite material with at least 15 parts by mass of an aqueous activator to form an admixture;
The above processing step is a step of molding the mixture into a specific shape or an unspecified shape to form a molded product;
In the curing process described above, the admixture or the molded product is subjected to 2 to 120 ° C. air, oxygen-free gas, water, sea, soil, solution, steam, warming, decompression, or pressurization. A step of leaving in a single atmosphere selected from the group of atmospheres or a multistage atmosphere consisting of a combination of two or more for at least 10 minutes;
The above-mentioned inorganic molded product has a structure, composite hardened body, granule, aggregate, adherend, film, hydrous soil reforming treatment through a series of work steps in which a water-based active agent coexists with a single material or composite material. Products, non-polluted products, consolidated adsorbents, heat-insulating / heat-retaining / heat-resistant materials, acid-resistant materials or inorganic molded products made of integrated materials, water resistance, heat resistance, low elution pH of less than 12 An inorganic molded product characterized by being a molded body. Inorganic molded product processed and prepared into a cured body, structure, composite cured body, granule or aggregate by the above-described series of work steps in which a water-based active agent coexists with a composite material in which the treatment material is combined with the target material. In;
The target material is a sand granule having a particle size of 0.2 to 50 mmφ and a bulk specific gravity of 0.2 to 3.5 g / cc;
The mixing step in the series of work steps described above is for a composite material in which 100 parts by mass of the processing material is combined with 1 to 2000 parts by mass of the sand granule that is the target material. A step of coexisting at least 15 parts by mass of the aqueous active agent to form a homogeneous mixture, and the processing step is a step of forming the mixture into a specific shape or an unspecified shape to form a molded product. Yes;
The above-mentioned inorganic molded product is prepared in a series of work steps in which a water-based activator is allowed to coexist with a composite material having a sand granule as a target material, and a specific shape or uniaxial compressive strength of 2,000 KN / m ² or more is secured Hardened body, structure, composite hardened body, granule or aggregate of unspecified shape, water resistance and heat resistance are ensured, and low-alkaline hardened body, structure, composite with water elution pH of less than 12 42. The inorganic molded article according to claim 41, which is a cured body, a granule or an aggregate. In an inorganic molded product that is processed and prepared into an adhering body by the above-described series of work steps through a water-based activator to a composite material in which the treatment material is combined with the target material;
The target material is a powdery filler having a particle size of 100 μm or less;
The mixing step in the series of work steps described above is performed on a composite material obtained by combining 100 parts by mass of the treatment material with respect to 1 to 2000 parts by mass of the filler to be prepared, and 100 parts by mass of the composite material. In contrast, at least 15 parts by mass of a water-based activator is coexisted to form a paste-like mixture, and the processing step involves coating and bonding the paste-like mixture to the surface, inner surface or gap surface of the base material. , Binding, coating, multi-layer coating, soaking, spraying, pasting, spraying, pouring or applying by injection means to form a molded product;
The above-mentioned inorganic molded product is prepared in a series of work steps in which a water-based active agent is allowed to coexist with a composite material whose target material is a filler, and a shear fracture adhesive force of 2,000 KN / m ² or more is secured to prepare an adherent. 42. The inorganic molded article according to claim 41, wherein the inorganic molded article is a low-alkaline adhering body having water resistance and heat resistance secured and having a water elution pH of less than 12. By using the paste-like admixture prepared by combining the treatment material with the filler as the target material, the aggregate group of granular materials is integrated and consolidated by the above-described series of work steps, thereby providing a through gap. In an inorganic molded product that has been processed and prepared into a coconut-shaped molded product;
The aggregate group of the above-mentioned granular bodies is a group of aggregates of 1 to 10 mmφ spheres, hollow bodies, cylinders, flake bodies, granulated bodies, or unspecified granular bodies, or a mixture of a plurality of them;
At least 15 parts by mass with respect to 100 parts by mass of the composite material, wherein the paste-like mixture is a composite material in which 100 parts by mass of the treatment material is combined with 10 to 2000 parts by mass of the filler. A paste-like admixture mixed with a water-based active agent of
The processing step in the series of work steps described above covers the granule surface by adding the paste-like admixture in an amount sufficient to wet the entire granule surface of the aggregate group with respect to the aggregate group of granules. It is a processing step to secure the aggregate group of granules covered with paste-like admixture in a specific shape,
The curing process in the above series of work processes is a curing process in which a group of granular materials coated with a paste-like admixture in a specific shape is allowed to stand in an atmosphere at least at room temperature for 24 hours;
The above-mentioned inorganic molded product of a cocoon-like molded body is prepared into a coconut-like molded body in which through voids are secured and consolidated and consolidated, water resistance and heat resistance are ensured, and water elution pH is 12 42. The inorganic molded product according to claim 41, wherein the molded product is a low alkaline cocoon-shaped molded product of less than 40%. In an inorganic molded product that is processed and prepared into a film by the series of operation steps via a water-based activator to a composite material in which the treatment material is combined with a target material;
The preparation target material is a powdery filler having a particle size of 100 μm or less;
The mixing step in the series of work steps described above is for a composite material in which 100 parts by mass of the treatment material is combined with 1 to 2000 parts by mass of the filler that is the target material. At least 15 parts by mass of a water-based active agent to make a fluid or plastic admixture, and the processing step comprises converting the fluid or plastic admixture into a metallic or inorganic fiber woven or non-woven fabric; A process of forming a composite product into a specific shape film of 1 to 20 mm thick, film-like, plate-like or coated-like;
In the above curing process, the molded product formed by applying and processing a fluid or plastic admixture is processed at 2 to 120 ° C. in the atmosphere, oxygen-less gas, water, sea, soil, solution, steam, During molding, the mold-processed product that has been applied and cured is cured for at least 10 minutes in a single atmosphere or a multi-stage atmosphere consisting of a combination of two or more selected from the group of atmospheres during heating, decompression, or pressurization. The process of removing the mold from the mold as needed
The above-mentioned inorganic molded product is prepared into a film-like molded body through a series of work steps in which a water-based active agent coexists with a composite material intended for a filler, ensuring water resistance and heat resistance, and water elution pH 42. The inorganic molded article according to claim 41, wherein the film is a low alkaline film of less than 12. In an inorganic molded product that is processed and prepared into a hydrous soil reformer by the series of operation steps via a water based activator to a composite material in which the treatment material is combined with the target material;
The target material is a hydrous soil that contains water in a range of 25% to 80% by weight and is fluid or plastic;
In the above-mentioned series of work steps, the mixing step is performed on a composite material in which 100 parts by mass of the treatment material is added to an amount corresponding to 50 to 2000 parts by mass on the basis of the dry matter of the above-mentioned hydrous soil as the target material Mixing with soil-containing water;
The mixing step in the series of work steps is a step in which the mixture is molded into a specific-shaped structure, a container-integrated product, or an unspecified-shaped granule to obtain a molded product;
The curing process in the above series of work processes is a process of curing the molded product in the air, in the soil, in water or in seawater, and if necessary, the molded product that has been subjected to the curing process in advance. A process consisting of a second stage curing process in soil, water or seawater;
The above-mentioned inorganic molded product is prepared into a specific shape or non-specific shape hydrous treated earth body with a uniaxial compressive strength of 1000 KN / m ² or more, water resistance and heat resistance are ensured, and water elution pH is 12 42. The inorganic molded article according to claim 41, which is a less alkaline, hydrous soil-modified body. In an inorganic molded product that is processed and prepared into a hydrous treated soil by the series of work steps via a water-based activator in a composite material that combines the treatment material with a target material;
The survey target material combined in the above composite material is hydrous soil in the original position of a rustic or plastic soft ground having a water content of at least 20% by mass;
If necessary, the mixing step in the series of work steps is performed on the amount corresponding to 50 to 2000 parts by mass on the dry matter basis of the soft ground that is the above-mentioned in situ hydrous soil that is the target material. An amount equivalent to 100 parts by mass in terms of dry matter of a single material of a treatment material, a composite material of a treatment material in which sand particles are combined, or a slurry-like treatment material in which at least 75 to 120 parts by mass of an aqueous activator is added to the treatment material Is a process of mixing into a hydrous soil by atmospheric pressure excavation, under-pressure excavation, agitation injection or a push-in type admixing process with an injecting pressurization process without a certain range of the original soft ground;
The curing process in the above series of work steps is a step of leaving the in-situ soft ground admixture for 24 hours or longer under the in-situ natural conditions in which the admixture is not subjected to the processing step;
The above-mentioned inorganic molded product is prepared in a soft ground where the uniaxial compressive strength is modified to at least 300 KN / m ² in the soft ground in situ, water resistance and heat resistance are ensured, and the water elution pH is less than 12 42. The inorganic molded article according to claim 41, which is an alkaline hydrous soil. In an inorganic molded product that is processed and prepared to be non-polluted by the series of work steps through a water-based activator to a composite material in which the treatment material is combined with a target material;
The target material to be combined in the above-mentioned composite material is a water-soluble heavy metal exceeding the environmental standards set by the national government in at least one water elution test of heavy metals [lead, cadmium, chromium, arsenic, mercury]. Containing contaminating material;
The above contaminated material is a single or a combination of two or more selected from the group of waste incineration ash, sludge or contaminants;
At least 20 parts by mass of the mixing step in the above series of work steps is performed on a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass with respect to 100 to 2000 parts by mass of the dried material of the contaminated material as the target material A step of blending with an aqueous activator;
The curing process is a process in which the processing step in the series of work steps described above is a step of forming a molded product by performing a molding process into a specific shape, an unspecified shape, or a granular shape. A step of leaving it for 24 hours to form a molded body;
When the above inorganic molded product is granulated, the load strength is secured to 4 kg or more, the contained heavy metals are fixed, and the results of the water elution test are water insoluble and fixed within the range of the environmental standards set by the country. It is a molded product of a cured product, structure or granule, prepared as a non-polluted product that can be reused and recycled, ensuring water resistance and heat resistance, and having a low alkalinity with a water elution pH of less than 12. 42. The inorganic molded article according to claim 41, which is a pollution product. In an inorganic molded product that is processed and prepared into an adsorbent powder by the series of operation steps via a water-based activator in a composite material in which the treatment material is combined with a target material;
The target material to be combined in the composite material is an adsorbent powder having a specific surface area of 10 m 2 / g or more;
The mixing step in the above series of work steps is at least 20 parts by mass for a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass of the adsorptive powder as a target material on a dry matter basis. A process of blending with a water-based active agent of
The processing step in the above series of work steps is a step of forming a processed product by molding into a specific shape, non-specific shape, or granule;
The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;
The above-mentioned inorganic molded product is prepared as a consolidated adsorbent having a specific surface area reduction rate of 40% or less, water resistance and heat resistance are ensured, and low alkaline consolidated adsorption with water elution pH of less than 12. 42. The inorganic molded article according to claim 41, which is a body. In an inorganic molded product that is processed and prepared into a heat insulating, heat insulating, and heat resistant material by the series of operation steps through a water based activator to a composite material that combines the treatment material with a target material;
The raw material to be compounded in the above-mentioned composite material is a heat-resistant granular material having a particle size of 10 to 5000 mμ made of an oxide or a non-oxide compound;
The mixing step in the above series of work steps is at least 20 masses for a composite material in which 100 parts by mass of the treatment material is added to 100 to 2000 parts by mass of the heat-resistant granular material that is the target material on a dry matter basis. A mixture through a part of an aqueous activator;
The processing step in the above series of work steps is a step of forming a processed product by molding into a specific shape, non-specific shape, or granule;
The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;
The above-mentioned inorganic molded product is heat-resistant / heat-retained / heat-resistant with at least 80% heat-resistant strength retention when exposed to non-fired heat-retained / refractory materials or 500 ° C. atmosphere that can be applied on-site without being heat-treated in advance. 42. The inorganic molded article according to claim 41, wherein the inorganic molded article is a low-alkaline heat insulating, heat retaining, and heat resistant material that is adjusted to a material, has water resistance, and has a water elution pH of less than 12. In an inorganic molded product that is processed and prepared into an acid-resistant material by the series of operation steps via a water-based activator in a composite material that combines the treatment material with a target material;
The target material to be compounded in the above-mentioned composite material is a single alkali silicate comprising a single or a combination of two or more selected from the alkali silicate compound group represented by the composition formula (3), or the siliceous An alkali silicate material composed of a water glass composite product obtained by adding 1 to 2000 parts by mass of the powdery filler having a particle size of 100 μm or less to 100 parts by mass of an acid-alkali material alone;
In the above-described series of work steps, the mixing step is performed by adding a silicic acid as a pair to a composite material obtained by adding 100 parts by mass of a treatment material to 100 to 2000 parts by mass of an alkali silicate-based material that is an alkali silicate single product or a water glass composite product. A step in which the total amount of coexisting water is adjusted to at least 20 parts by mass in consideration of the alkali-containing water content to make an admixture;
The processing steps in the series of work steps are steps in which the mixture is molded into a specific-shaped structure, a coated adhering body, or an unspecified-shaped powder or granule to form a molded product;
The curing step in the above series of work steps is a step in which the molded product is allowed to stand under natural conditions for at least 24 hours to form a molded body;
The inorganic molded product has been prepared as an acid-resistant material with a solidified body strength retention rate of at least 80% when immersed in an acidic solution of pH 3, ensuring water resistance and heat resistance, and having a water elution pH of 12 42. The inorganic molded article according to claim 41, which is an acid resistant material having a low alkalinity of less than 40%. In an inorganic molded article prepared as an integrated product by the series of operation steps through a water-based activator in a composite material in which the treatment material is combined with a target material;
The target material to be combined in the above composite material is a plate, film, sphere, granule, horn, column, fiber, string, paper scrap, lump or these shapes A gargle aggregate in which garbled objects made of a mixture of materials are housed in predetermined containers and have gaps between the garbled objects;
The fluidity slurry in which the mixing step and the processing step in the above series of work steps are adjusted by adding at least 25 parts by mass of an aqueous activator to the treatment material with respect to the galactor aggregate stored in containers and having voids. Injecting and filling the body into the gaps in the junk aggregate and integrating them together, and forming the junk aggregate into an integrated molded product;
The curing step in the above series of work steps is a step in which the integrated molded product is allowed to stand for at least 24 hours under natural conditions to form a molded body;
42. The above-mentioned inorganic molded product is prepared as a consolidated integrated product in which a galactor aggregate is integrated, and is a low-alkaline integrated product that ensures water resistance and heat resistance and has a water elution pH of less than 12. Inorganic molded product.