JP2008308396A - Water-containing composition, utilization and treatment method, and non-polluting water-resistant treated object - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a technique developed to eliminate at least at ordinary temperature, problems indicated in a cementitious or water glass type cementing material in prior art and expressed by keywords such as hexavalent chromium leaching, high alkalinity of a pH of 12 or higher; deficient pot life; non-water resistance, reduction in supply cost; hazards from water leaching of a group of contamitant harmful elements, and energy load. <P>SOLUTION: Provided are a basal water-containing composition prepared by adding a reactive powder composition containing calcia to a binding liquid composition comprising a stable modified alkali silicate having oxy acid ions of one or more elements selected from sulfur, phosphorus, carbon, and boron and homogeneously mixing them; a utilization and treatment method comprising utilizing the basal water-containing composition as a base constituent; and a non-polluting water-resistant treated object subjected to treatment by utilizing the basal water-containing composition as a base utilization treatment agent. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention is a water-containing composition that exhibits hydraulic fixing / binding / curing / water resistance functionality at room temperature, a method for utilizing the water-containing composition, and a non-polluting treatment prepared using the water-containing composition. The present invention relates to a technical field for providing a mold water-resistant treated body.

  According to the present invention, the reactive liquid composition is added to the binding liquid composition, and the mixture is homogeneously mixed and is alkaline with a pH value of 10 or more, and is shaped through water at least at room temperature. Slurry-type basic water-containing composition that exhibits detoxification treatment and non-re-mudging treatment, or a juice-type functional water-containing composition obtained by adding a functional group to the basic water-containing composition, and further composite The present invention relates to a technical field that provides a mortar-like composite water-containing composition to which an additional material group is added.

  The present invention according to still further details adopts a water-containing composition that is a basic water-containing composition, a functional water-containing composition or a composite water-containing composition, and utilizes the water-containing composition for the water-containing composition itself or the water-containing composition. Consists of utilization processing means according to the purpose, application, and working environment based on the base material to be treated as necessary for the contact admixture mixed with the material to be treated selected as the treatment agent. The present invention relates to a technical field that provides a utilization processing method for processing and preparing a water-containing, non-polluted, water-resistant treated body having a predetermined shape through a series of work steps.

  The present invention according to still further details adopts the above-mentioned water-containing composition, to the water-containing composition itself, or to a contact mixture in which the water-containing composition is added and mixed with the material to be treated as a treatment agent. Recycled materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, etc., with predetermined shapes that are processed and prepared through a series of work processes consisting of utilization processing means according to the purpose, application, and work environment , Non-polluted nature that can be supplied in the fields of soil ground improvement materials, fireproofing / thermal insulation materials, ceramics / pottery materials, crafts / processing materials, adhesives / hardening agents, water purification / treatment agents or plant growth base materials The present invention relates to a technical field for providing a mold water-resistant treated body.

  As background art related to the present invention in the prior art, there can be mentioned inorganic cementing materials collectively referred to as mortar materials having a hydraulic function at room temperature, solidifying materials, curing agents, binders and the like. Further, the present invention relates to a technology for providing a cured / solidified body, a molded body, a structure body, an adhesive body and the like prepared by a processing method using these cementing materials. Typical inorganic cementing materials that have a normal temperature hydraulic function vary depending on the hydraulic component, but generally three types of cementing materials are available: gypsum, cement, and water glass. It has been adopted separately and widely used.

  Of course, the working functions required of these cementing materials are assured of sufficient workability and usable time so that the construction work can be performed safely and quickly, and at least the room temperature of the construction site. Set target values under construction and curing conditions (for example, sufficient curing speed that enables early opening, water resistance of the cured product, sufficient strength and dimensional stability as a structural material, adhesion to the substrate, necessary Accordingly, there has been a demand for a technology that can provide a cured / solidified body that can ensure lightness, smoothness of the surface of the cured body, surface properties, etc.) at a low price.

  Furthermore, in today's technology related to the present invention, the “environmental basic law” and related instructions, notifications, ordinances, etc., which are always related to “protecting human health and maintaining the living environment” In response to the `` desirable standards '', the water-eluted heavy metals, which are harmful substances that adversely affect the living environment and human health, are not diffused into the living environment, the human environment is not adversely affected, and the global environment is protected. There is a need for ingenuity and development technology that can be improved.

  Among them, cement-based cementing materials have been widely used as cementing materials that form hydrated minerals by a hydraulic hardening function. However, concrete products prepared with cement-based cementing materials have a high pH value of 11 or more, are strongly alkaline, and when left in the atmosphere where acid rain falls, product quality deteriorates due to acid rain. Tend to. In addition, cement is coexisting with harmful hexavalent chromium that is inevitably mixed in from the manufacturing process (see: Notification from the former Ministry of International Trade and Industry dated March 24, 2000). Products tend to elute and diffuse alkaline components and hexavalent chromium that are harmful to the living environment.

  Furthermore, in order to produce cement, a heat treatment process at a high temperature (about 1400 ° C.) is indispensable, and high temperature treatment inevitably consumes a large amount of valuable energy, and carbon dioxide generated by this high temperature heat treatment. The fact that the release of is inducing global warming is inevitable. Cement products are generally susceptible to the effects of moisture and carbon dioxide in the air, and therefore tend to deteriorate the quality of cement products, and tend to have poor quality stability and shelf life. Moreover, since the concrete product prepared with cement mortar is a hydrated mineral, the concrete product cannot be expected to have heat resistance.

  Furthermore, Portland cement has been adopted and used in the civil engineering field as a binding modifier such as mud mud, sludge, soft soil, and hydrous mud of volcanic ash clay. However, when trying to solidify hydrous mud such as mud mud, sludge, soft soil, and volcanic ash clay composed of fine particles with cement, the soil particle size of the fine particles is finer than the cement particle size, Fine soil particles surround the cement particles, leaving the problem that it is impossible to expect the formation of good binders and solidified bodies by inhibiting the hardening mechanism of the cement.

  As a plaster cementing material, it has been widely used as a plaster material. A basic example of the gypsum cementing material is calcined gypsum, which is a half-water gypsum obtained by partially dehydrating dihydrate calcium sulfate. Since calcined gypsum forms a solidified body by a hydration reaction, it has been used as an easier and more solidified material than in the past. However, since the rate of formation and formation of hardened gypsum formed by adding water to calcined gypsum is high, working time cannot be secured when constructing at large construction sites, etc., and it is not practical. . In addition, with a gypsum-based cured product, a product having acid resistance and heat resistance cannot be obtained, and its use is naturally limited.

In addition, the specific gravity of a cemented or gypsum-based cured body is generally as large as about 2.3 g / cm ³ . Therefore, the total weight of the target structure or molded body tends to increase greatly, and it is not suitable for the field that requires a lightweight cured body. Cement-based or gypsum-based water-kneaded mortar has poor fluidity, and when the amount of water added is increased in order to obtain fluidity, shrinkage cracks tend to occur in the formed concrete or gypsum product. In addition, there is a tendency that a predetermined solidified body strength cannot be obtained.

  In addition, special applications of cement-based or gypsum-based mortars include the field of water-resistant lightweight structures and molded bodies, the field of self-leveling materials that are labor-saving and excellent in work fluidity, and containers filled with junk waste. There is a great need in the field of integrated solidification materials that can be easily injected and solidified. Therefore, conventionally, for the weight reduction of cement-based or gypsum-based cementing materials, generally, a manufacturing method has been adopted in which a cement-based hardened body is manufactured by adding aggregates having bubbles or bubbles, or lightweight aggregates. For example, the technique regarding manufacture of a lightweight solidified body etc. is disclosed by patent document 1 grade | etc.,. Moreover, in the conventional technology, the specific gravity of the mortar and fresh concrete to be adopted is adjusted in the light direction from the standpoint of obtaining fluidity in the mortar, and lightweight aggregates are added to the cement to adjust the specific gravity in the light direction. Specific examples of applications that are adjusted and applied to “self-leveling materials” can be given.

  In addition, for example, in Patent Document 2, an inorganic binder composed of alumina cement, Portland cement, gypsum, calcium hydroxide or calcium carbonate is used in combination with oxycarboxylic acid or a salt thereof and zinc salts as a fluidity reduction preventing agent, A self-leveling material obtained by adding a water reducing agent, a viscosity modifier, and an antifoaming agent is disclosed. Patent Document 3 discloses a fast-hardening cement made of alumina cement, Portland cement, gypsum, blast furnace slag powder, silica sand, olivine powder, oxycarboxyl as a high-performance water reducing agent, thickener, and setting modifier. A composition obtained by adding a drug comprising an acid or a salt thereof, sodium aluminate, sodium carbonate, or sodium sulfate is disclosed.

  Further, Patent Document 4 discloses a cement containing a hardener made of calcium aluminate and alkali or alkaline earth metal sulfate, oxycarboxylic acid (salt) organic substance and / or calcium hydroxide, aluminate, alkali carbonate. A composition in which various kinds of known fluidizing agents and antifoaming agents are added to those obtained by adding an inorganic compound such as a setting retarder to adjust the setting speed is disclosed. Further, Patent Document 5 discloses a self-leveling material obtained by adding a water reducing agent, a polymer emulsion, and a lithium salt and aluminum sulfate as a coagulation adjusting agent to a hydraulic composition comprising alumina cement, gypsum, and blast furnace slag powder. Has been.

  Furthermore, in Patent Document 6, the hydraulic component is composed of alumina cement, Portland cement, gypsum and blast furnace slag, and in a wide temperature range, work characteristics (high fluidity, high fluidity retention), curing characteristics (smoothness, surface A self-leveling material mainly used for adjusting a floor base of a general building, which is excellent in properties) and suppressed in material separation, is disclosed. Furthermore, Patent Document 7 discloses a self-leveling material made from fine powders such as papermaking sludge ash, blast furnace slag, fly ash and the like, and anhydrous gypsum or hemihydrate gypsum and a water reducing agent.

  JP 2006-051644 A   JP 63-129051 A   Japanese Patent Application Laid-Open No. 07-0669704   Japanese Patent Laid-Open No. 08-217508   JP-A-10-231165   JP 2004-331415 A   JP 2006-193344 A

  As a water glass-based cementing material, a cured product in which a polysiloxane bond is formed by adding a curing agent, particularly an acidic curing agent, with an alkali silicate having a silanol group typified by water glass as a main ingredient is formed. Therefore, since ancient times, it has been used as a binder and an adhesive in the fields of construction and civil engineering, and in the field of coating agents and the like. However, the curing mechanism of water-glass cementing materials made from alkali silicate as the raw material leaves a water-soluble alkali salt in the system based on the mixing reaction between alkali silicate and acidic curing agent. Therefore, various problems remain.

  In particular, a water glass cementing material generally tends to have a poor balance between workability including working time at the construction site and various physical properties exhibited by the formed cured / solidified body, in particular, the expression of water resistance. Therefore, in general, water glass cementing materials require a long time to develop various physical properties as a cured / solidified product when securing work working time with emphasis on workability. When a property that completes various physical properties in a hardened / solidified product in a short period of time is expected, the construction / workability at the work site tends to deteriorate. Moreover, the formed cured / solidified body tends to have a lot of abnormalities such as shrinkage cracks and white flower.

  In addition, in these water glass-based cementing materials made from these alkali silicates, the cured / solidified product formed by applying at normal temperature is generally a water-soluble alkali in the formed cured / solidified product. Salt remains as a by-product and tends to exhibit a high pH value that adversely affects the living environment. Therefore, when water comes into contact with the cured / solidified product formed, the by-product water-soluble alkali salt is dissolved in water again to dissolve the hardened and solidified polysilica component. Therefore, it is difficult to secure a water-resistant cured body, and in particular, it tends to be unsuitable for providing a cured / solidified body prepared from a water glass-based cured / solidified material as a product that is used outdoors.

  In relation to the invention technology related to the water glass cementing material, the present inventors have disclosed variously in the prior patent technology, for example, Patent Documents 08, 09, 10, and 11 include boric acid or A technique relating to a water glass composition in which silicon phosphate or the like is used together is disclosed. In addition, Patent Document 12, which is a prior art patent technology of the present inventors, is soluble in powdered silicon phosphate and an alkaline solution that slowly releases acidic phosphate ions with respect to water-soluble powdered alkali silicate. Liquefied powdery one-pack alkali silicate composition composed of four components with barium salt containing barium ions and calcium hydroxide of aluminum hydroxide, and almond-like industry such as low-level radioactive waste A technique is disclosed in which a processing material is injected into a drum can containing wastes and solidified by volume reduction.

  Furthermore, in Patent Documents 13, 14, 15, 16, and 17, which are the prior application patent technologies of the present inventors, specially prepared via water for wastes and incineration ash that coexist with harmful elements. Add the hydraulic silica-based binder, alkaline curing agent, hydraulic binder, or inorganic treatment material to make an admixture, and react and cure the admixture at least at room temperature to produce incinerated ash etc. Each of the technologies for fixing and insolubilizing coexisting element groups as water-insoluble minerals and providing a shaped cured body is disclosed. Conventionally, as a general defect in a water glass-based cementing material, it has been pointed out that a cured product lacks water resistance due to a water glass-based hydraulic cured material forming material. However, in the technique in the hydraulic hardening body forming material system disclosed in Patent Documents 13, 14, 15, 16, and 17, which are the prior application patent techniques of the present inventors, the water glass system having a silanol group is used. Even if the material is selected as a hydraulic hardened body forming material, a technology for providing a non-re-mudified treated product that has secured water resistance has already been completed.

  The technology for the water glass cementing material in the above inventions of the present inventors is that the element group including harmful heavy metals coexisting with the silicates which are the wastes which are the selected materials is within the range of the environmental standard. Since the processing technology for insolubilizing and immobilizing in water is already completed, low-cost waste “ashes” etc. are used as the raw material of the fluid liquid composition made of the alkali silicate-based cured body forming material. It can be adopted safely. Therefore, according to the present invention, the basic technology has already been established to provide a low-pollution water-resistant treated body by the hydraulic hydrated composition having excellent fluidity of the alkali silicate system while solving environmental problems. Therefore, it is possible to effectively advance this research and development on the line of the inventors' inventive technology.

  Japanese Examined Patent Publication No. 53-024206   Japanese Patent Publication No.58-058306   Japanese Patent Publication No. 01-053230   Japanese Examined Patent Publication No. 02-056299   Japanese Patent No. 3431486   JP-A-11-263661   JP 2002-128550 A   JP 2002-249348 A   JP 2005-097069 A   JP 2006-247645 A

  The basic problem to be solved by the present invention is that hydraulic fixing and bonding, which has been widely used as a conventional technology in various fields such as the civil engineering / construction industry, molding / processing industry, materials manufacturing industry, waste treatment industry, etc. There are various problems that the cement-based or water-glass-based inorganic cementing material that exerts the action as an adhesion / curing / water-resistant functional agent, and problems related to the environment problem and the technology to solve the recycling society. It is in.

  For example, in cement (Portland cement) based cementing materials in the prior art, harmful hexavalent chromium is mixed into product cement from magcro bricks used in cement manufacturing equipment when producing cement. Coexistence of is inevitable. Therefore, when secondary processed products made of cement come into contact with water, especially acid rain, harmful hexavalent chromium is eluted, causing a harmful effect of contaminating the living environment consisting of water. In addition, secondary processed products made of cement generally have a high pH value of 12 or more, and have an adverse effect on the living environment as well as elution of hexavalent chromium.

  On the other hand, the water glass cementing material has no problem in that it does not coexist with hexavalent chromium. However, in the water glass cementing material, the reaction between the alkaline component and the acidic component forms a curing mechanism in the water glass cementing material, which is a combination of the acidic curing agent and the alkaline main agent. As the reaction proceeds quickly, water glass cementing material cannot be secured at work site at room temperature, and there is a problem in construction workability. Has poor water resistance and solid body strength, and the alkaline component easily dissolves and diffuses in the living environment, causing adverse effects on the living environment, and its improvement is an issue.

  Furthermore, cement-based or water glass-based inorganic cementing materials are highly demanded mainly in the field of civil engineering and construction, and are therefore required to be versatile and have a low price. Therefore, various incineration ash, which is also industrial waste, can be selected as silicates used as the material for inorganic cementing materials, but these incineration ash coexists with harmful water-eluting elements. These coexisting harmful water-eluting elements (cadmium, arsenic, mercury, lead, chromium, selenium, fluorine, boron, manganese, etc.) are selected as raw materials for inorganic cementing materials for general products without treatment. I can't do it.

  Furthermore, in the water glass cementing material in the prior art, sodium silicate as a main component is generally mixed with silica sand and soda ash and melted at 1300 to 1500 ° C., and the product is mixed in a low pressure autoclave. It is manufactured by melting, and a sufficient energy load is applied, leaving a problem. Therefore, in the price reduction of water glass cementing materials, there is still a problem in the technological development to manufacture sodium silicate at a low price without applying any energy load when manufacturing the main component sodium silicate. Yes.

  The key issues listed in the above-mentioned conventional cement-based or water-glass inorganic cementing materials are "elution of hexavalent chromium", "pH value of 12 or more", "lack of work life". “Non-water resistant”, “Low price”, “Coexisting harmful water-eluting element group”, “Energy load”, and the like. There is a need in the present invention for a technique that can cope with the problems related to the keywords shown in these inorganic cementing materials in the prior art and solve these problems. In addition, the technology for processing various incinerated ash silicates that are in the process of being disposed of in a low-load environment and reforming them into low-cost, useful and versatile recycling materials. The present invention is required to solve the problem as an important technical problem related to the construction of an environmental problem and a recycling society.

  According to the present invention, in the water-containing composition, which is a basic water-containing composition in which the reactive powder composition is added to the binding liquid composition and mixed homogeneously;

［式中：Ｍはナトリウムないしカリウム元素の単独ないしは２種組み合わせのアリカリ金属元素、ａは０．５ないし３の数、ｂ、ｃ、ｅならびにｄは０．０５ないし１の数、ｗは４ないし４０の数］で表される水溶媒、アルカリ金属元素イオン、シラノール基を保有するケイ酸アルカリならびに硫黄、リン、炭素またはホウ素の単独ないし２種以上の組み合わせ元素のオキシ酸イオンを主成分とするアルカリ性の液状組成物で構成されており、該液状組成物の液状態での安定性が常温で少なくとも３０日間確保されている変性ケイ酸アルカリからなる液状組成物であり；The binding liquid composition described above has the following composition formula (1):

[Wherein, M is a single or a combination of two or more kinds of sodium or potassium elements, a is a number of 0.5 to 3, b, c, e and d are numbers of 0.05 to 1, and w is 4 Or an aqueous solution of an alkali metal element ion, a silanol group and an oxyacid ion of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements. A liquid composition composed of a modified alkali silicate that is composed of an alkaline liquid composition that has a liquid state stability of at least 30 days at room temperature;

  The above reactive powder composition is incineration ash for general and industrial waste, incineration ash for papermaking waste, phosphorus-containing incineration ash for sewage sludge / agricultural settlement drainage sludge, coal ash discharged from thermal power generation, iron making・ Aluminosilicate containing active calcium in a single or a combination of two or more selected from the group of slag discharged during steelmaking, layered clay minerals, low crystalline / amorphous silicates, volcanic products, eco-cement or Portland cement It is composed of an alkaline powder composition having a salt compound as a main component and a particle diameter in the range of 5 μ to 1 mmφ, and the powder composition exhibits an activation function for the binding liquid composition. A pulverulent composition consisting of silicates;

  50 to 140 parts by mass of a reactive powder composition composed of an active calcium-containing aluminosilicate compound with respect to 100 parts by mass of the binding liquid composition composed of a modified alkali silicate as the basic water-containing composition. Prepared as a basic water-containing composition in which a stable slurry is ensured by mixing in a homogeneous amount and in a homogeneous mixture;

The above water-containing composition has a composition specific gravity in the prepared basic water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has an alkaline pH value of 10 or more, and at least water at room temperature. Thus, a water-containing composition having a treatment function of performing a detoxification treatment and a non-re-mudging treatment is provided.

［式中：Ｍはナトリウムないしカリウム元素、ａは０．５ないし４の数、ｗは４ないし３０の数］で表されるシラノール基を保有する液状のケイ酸アルカリ５０ないし２００質量部を加えて均質混和して構成されている含水組成物が提供される。According to the present invention, the binding liquid composition comprises 1 to 1 alkali metal salt of an oxyacid of sulfur, phosphorus, carbon, or boron alone or in combination of two or more with respect to 100 parts by mass of water. Added in an amount of 40 parts by mass and dissolved, then the following composition formula (2)

[Wherein M is a sodium or potassium element, a is a number of 0.5 to 4, w is a number of 4 to 30, and 50 to 200 parts by mass of a liquid alkali silicate having a silanol group represented by And a water-containing composition constituted by homogeneous mixing.

  According to the present invention, the binding liquid composition is prepared by adding 80 to 140 parts by weight of water and 20 to 60 parts by weight of an alkali metal compound with respect to 100 parts by weight of the easily reactive silicates. A liquid silicate alkali composition mainly comprising an alkali silicate having an alkali silanol group reacted at a normal temperature with stirring is prepared, and then 100 parts by mass of the liquid silicate alkali composition. Provided is a water-containing composition comprising an alkali metal salt of oxyacid of sulfur, phosphorus, carbon or boron alone or in combination of two or more kinds in an amount of 1 to 40 parts by mass. .

  According to the present invention, the reactive powder composition comprises a toxic element group of one or a combination of two or more selected from the group of cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine or manganese. There is provided a water-containing composition which is coexistent at a concentration of at least 15 mg / kg and which is composed of a granular material mainly composed of an active calcium-containing aluminosilicate compound.

  According to the present invention, in the water-containing composition that is a functional water-containing composition that is added to the basic water-containing composition and mixed and mixed homogeneously with the addition of a functional group.

  The above-mentioned function-providing material group includes a calcium composition that replenishes alkalinity, a sulfate composition that improves the reinforcement of the cured body, a phosphate composition that improves the curing function and immobilizes fluorine, and the reinforcement of the cured body Carbonate composition that improves water resistance and water resistance, barium salt composition that can adjust the working life, aluminum / iron salt composition that is a compound of aluminum or iron, and a buffer zone that gives buffering properties to the formed hardened body It is composed of a forming composition, or a group of function-providing materials selected from the group of function-providing compositions imparting fillability and coloring / pigment properties, or a combination of two or more kinds;

  The functional water-containing composition is a calcium composition, a sulfate composition, a phosphate composition, a carbonate composition, and a barium salt composition composed of a function-providing material group with respect to 100 parts by mass of the basic water-containing composition. 1 to 30 parts by mass of a functional material group consisting of 1 to 30 parts by mass of a material, an aluminum / iron salt composition, a buffer zone forming composition or a functional composition, or a combination of two or more functional ingredients. Prepared as a functional water-containing composition with a juice-like shape;

The water-containing composition has a composition specific gravity in the prepared functional water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has a pH value of 10 or more, and has water at least at room temperature. Thus, a water-containing composition having a treatment function of performing a detoxification treatment and a non-re-mudging treatment is provided.

［式中；ｗは零を含む２以下の数］で表される酸化カルシウムまたは水酸化カルシウムの群より選ばれる単独ないし２種の組み合わせカルシウム化合物をカルシヤ規準で表して５０質量％以上含有している機能付与素材群である含水組成物が提供される。According to the present invention, a calcia composition that is the group of function-imparting materials is represented by the following composition formula (3):

[In the formula, w is a number of 2 or less including zero] represented by a calcium standard or a combination of two or more kinds of calcium compounds selected from the group of calcium hydroxide or calcium hydroxide. A water-containing composition that is a group of function-providing materials is provided.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒはアルミニウムまたは３価の鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金蔵元素の硫黄のオキシ酸塩化合物の塩基性塩または正塩の群より選ばれる単独ないし２種以上の組み合わせの機能付与素材群である含水組成物が提供される。According to the present invention, the sulfate composition as the group of function-providing materials has the following composition formula (4):

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. A water-containing composition which is a single or a combination of two or more kinds of function-providing materials selected from the group consisting of a basic salt or a normal salt of a sulfur oxyacid salt compound of a metallurgy element represented by Provided.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、亜鉛、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｄは１ないし８の数、ｔはＧ元素原子価÷２の数、ｗは零を含む１０以下の数］で表される金属元素のリンのオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせで構成されている機能付与素材群である含水組成物が提供される。According to this invention, the phosphate group composition which is the said functional provision raw material group is following composition formula (5).

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, zinc, titanium, silicon and iron, d is a number from 1 to 8, and t is a G element. Functionality-providing material composed of a single or a combination of two or more selected from the group of phosphorus oxyacid salt compounds of metal elements represented by the valence ÷ 2 number, w is a number of 10 or less including zero] A group of hydrous compositions is provided.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒはアルミニウムまたは３価の鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金蔵元素の炭素のオキシ酸塩化合物の塩基性塩または正塩の群より選ばれる単独ないし２種以上の組み合わせの機能付与素材群である含水組成物が提供される。According to this invention, the carbonate composition which is the said functional provision raw material group is following formula (6).

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. A water-containing composition, which is a single or a combination of two or more types of function-providing materials selected from the group of basic salts or normal salts of carbon oxyacid salt compounds of gold elements represented by Provided.

［式中：ｅは４以下の数、ｗは零を含む１０以下の数］で表されるアルカリ溶液に可溶なバリウム塩より選ばれる単独ないし２種以上の組み合わせの群より選ばれるバリウム塩化合物の機能付与素材群である含水組成物が提供される。According to the present invention, the barium salt composition as the group of function-providing materials has the following composition formula (7):

[In the formula: e is a number of 4 or less, w is a number of 10 or less including zero] A barium salt selected from a group of single or a combination of two or more selected from barium salts soluble in an alkaline solution A water-containing composition that is a group of functional materials for a compound is provided.

［式中；Ｔはケイ素、硫黄、窒素、リン元素群の単独ないし２種以上の組み合わせの元素、ｎは２ないし３の数、ｍは０．５ないし６の数、ｗは零を含む２８以下の数］で表されるアルミニウムないしは２価ないしは３価の鉄元素のオキシ塩化合物の群より選ばれる単独ないし２種以上の組み合わせアルミニウム・鉄塩の化合物ないしは組成物である粉粒体からなる機能付与素材群である含水組成物が提供される。According to the present invention, an aluminum / iron salt composition that is a group of the above-mentioned function-imparting materials has the following composition formula (8):

[Wherein T is an element of a single or a combination of two or more of silicon, sulfur, nitrogen and phosphorus elements, n is a number from 2 to 3, m is a number from 0.5 to 6, and w is zero. 28 It is composed of aluminum or a divalent or trivalent iron element oxysalt compound represented by the following number, or a single or a combination of two or more aluminum / iron salt compounds or a granular material that is a composition. A water-containing composition that is a group of functional materials is provided.

［式中：Ｍはリチウム、ナトリウムまたはカリウムのアルカリ金元素、Ｚはマグネシウム、カルシウムまたは亜鉛のアルカリ土類金属、ｇは１．０ないしは４．０の数、ｗは零を含む１０以下の数］で表されるアルカリ金属またはアルカリ土類金属のホウ素のオキシ酸塩の群の単独ないし２種以上の組み合わせ金属のホウ素のオキシ酸塩化合物からなる機能付与素材群である含水組成物が提供される。According to the present invention, the buffer-band-forming composition that is the group of function-providing materials has the following composition formula (9):

[Wherein, M is an alkaline gold element of lithium, sodium or potassium, Z is an alkaline earth metal of magnesium, calcium or zinc, g is a number of 1.0 to 4.0, and w is a number of 10 or less including zero. ] A water-containing composition, which is a functional group-providing material group consisting of a boron oxyacid salt group of an alkali metal or an alkaline earth metal represented by the following formula: The

  According to the present invention, the function-imparting composition which is the group of function-imparting materials is a pigment, a colorant, an activator, and a filler-dispersant that are composed of a powdery material having a particle size in the range of 1 μm to 1 mmφ. , Magnetic substance, catalyst, oxidant, carrier, aggregating / separating agent, agrochemical / herbicide / fertilizer / microbial nutrient, plant seeds and fungi, antimicrobial agent, water repellent and functional additive, etc. A water-containing composition that is a single group or a combination of two or more types of functional materials is provided.

  According to the present invention, a composite water-containing composition that is mixed and mixed homogeneously with the addition of a composite additional material group, with the above-mentioned function-providing material group, if necessary, to the basic water-containing composition. In a water-containing composition that is a product;

  The composite additional material group is composed of a filler material composition composed of a filling granular material having a particle diameter in the range of 3 μm to 1 mmφ, and a bone material composition composed of an aggregate body having a particle diameter in the range of 1 to 7 mmφ. Consists of single or multiple combined additive materials selected from a group of objects;

  The above composite water-containing composition is added with a function-providing material group in an amount of 1 to 30 parts by weight as required with respect to 100 parts by weight of the basic water-containing composition. It is prepared as a composite water-containing composition in which a mortar shape is ensured by adding 10 to 1300 parts by mass of a composite additive material group alone or in combination of a plurality of raw material compositions;

The above-mentioned water-containing composition has a composition specific gravity in the prepared composite water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has a pH value of 10 or more, and is at least at room temperature. Thus, a water-containing composition having a treatment function of performing a detoxification treatment and a non-re-mudging treatment is provided.

  According to the present invention, the filler material composition, which is the composite additive material group, has a particle size of 1 mmφ or less, and is a dry product or a wet product containing moisture within a range of 50% by mass. Rock crushed stones, sands, clays, ceramics, ceramics, carbonized products, charcoal, glass, volcanic products, slag, incinerated ash silicates, gypsum, hardened cement, sediment, sludge, sludge, Inorganic oxides, metals, wood / bamboo / plants / cereals, leather / bones, organic matter / plastics / rubber, synthetic / refining chemicals, or single or combined composites of wastes A water-containing composition that is a group of function-providing materials in the form of powder, small lump, sand, fiber, or flake is provided.

  According to the present invention, the bone material composition which is the composite additional material group has a particle diameter in the range of 1 to 7 mmφ, and minerals / rock crushed stones / sands / clays, ceramics / baked goods, dry distillation products・ Charcoal, glass, volcanic products, slag, incinerated ash silicates, gypsum, hardened cement, sediment, sludge, sludge, inorganic oxides, metals, wood, bamboo, plants, grains Spherical, granular, lump, plate, sand, chip consisting of a single material or combination of two or more kinds of chemicals, skin / bones, organic matter / plastic / rubber, synthetic / refined chemicals or wastes Provided is a water-containing composition that is a group of function-imparting materials in the shape of a shape, flake shape, fiber shape, specific shape, and nonspecific shape.

  According to the present invention, the bone material composition which is the composite additional material group is made of plastics, waste plastics, or old tires, and bone is chipped in a particle size range of 0.1 to 4 mmφ. A water-containing composition that is a group of materials is provided.

  According to the present invention, the composite additive material group may coexist with an element group of one or a combination of two or more selected from the group of harmful cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine, and manganese. Incinerated ash / coal ash / slags of thermal history silicates, single sediments or combinations of two or more selected from the group consisting of sediment, sludge, hydrous silicates, minerals, rocks, dredged sand, and clays A water-containing composition that is an additional material group is provided.

According to the present invention, the specific gravity of the hydrated composition in the basic hydrated composition, the functional hydrated composition or the composite hydrated composition as the hydrated composition is in the range of 1.10 to 1.90 g / cm ³ . Thus, a water-containing composition having high fluidity can be provided, which can be completed within 2 minutes when the water-containing composition is flowed on a horizontal surface housing within a range of 1 square meter.

  According to the present invention, the basic water-containing composition, the functional water-containing composition, or the water-containing composition that is a composite water-containing composition is adopted, and the water-containing composition itself is used as the material to be used and processed. Utilization treatment method for processing and preparing a water-containing, non-polluted, water-resistant treatment body of a predetermined shape by applying a series of work steps comprising utilization treatment means according to the purpose, application, and working environment on the basis of the target substrate In;

  The above-mentioned base materials to be treated are minerals, rocks, cinnabar sand, clays, ceramics, ceramics, dry distillation products, charcoal, glass, volcanic products, slag, incinerated ash thermal history silicates, gypsum, cement hardened bodies , Inorganic oxides, metals, wood / bamboo / plants, fibrous bodies, paper bodies, skin / bones / animal bodies, organisms / plastics / rubber, synthetic / refining chemicals or single waste materials Or a structure-type housing surface, a surface of a group of miscellaneous objects, a shape securing mold surface, a gap between fiber reinforcement groups or a particle assembly group void, which is prepared in advance by a combination of two or more kinds of composite materials;

  The above-described series of work steps are performed with respect to the selected water-containing composition itself, exhibiting the binding, solidification, and processing functions on the basis of the selected base material to be processed, so that the water-containing composition itself has a predetermined shape. A processing step that is a processed product processed into a body, and then a curing step that completes the properties as a predetermined shape by advancing reaction and curing at least at room temperature with respect to the processed product;

  The processing steps in the above-described series of work steps include spraying / spraying, coating / painting, self-horizontal flow, binding, adhesion, lamination, pasting / adhesion, at least at room temperature, on the base material to be treated. , Bonding, spreading, jointing, soaking, impregnation, gliding, assembly, integration, pouring, pouring, pouring, filling, dead weight, vibration, press-fitting, vacuum packing, molding, kneading, fitting, stirring, stirring A process of forming a processed product in a predetermined shape by a processing means that operates a processing tool / equipment that enables binding, solidification and processing functions via water consisting of mixing means;

  The curing process in the series of work steps described above, the processed product in the air, water, sea, soil, solution, steam under normal pressure, pressurization, decompression conditions in the range from room temperature to 100 ° C., Release in a single atmosphere selected from the group of non-oxygen gas atmospheres or a multistage atmosphere of a combination of two or more, preferably at room temperature for at least 3 hours to allow the reaction / curing to proceed, and to have a predetermined shape A process for preparing and preparing a water-containing, non-polluting, water-resistant treated body that has completed its property characteristics;

  The above-mentioned predetermined shape body is a hydrous coated shape body, a binding shape body, a collective shape body, a multi-layer shape body, a specific shape body, a structural shape body, a film-shaped body mainly composed of silicates. A shaped body, a reinforced shaped body or a predetermined shaped body that ensures properties as an integral shaped body;

  The above utilization treatment method is applied to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment on the basis of the selected substrate to be treated, with the hydrous composition itself as the utilization treatment target agent. The water-containing composition itself is processed into a non-polluted, water-resistant, water-resistant treated body comprising a predetermined shaped body that has been subjected to a detoxification treatment and a non-re-mudging treatment by shaping at least at room temperature through water. A utilization processing method to prepare is provided.

  According to the present invention, the basic water-containing composition, the functional water-containing composition, or the water-containing composition that is a composite-type water-containing composition is adopted as a utilization treatment agent, and the water-containing composition is selected for the material to be treated. The composition is used as a treatment agent to be mixed in an additional contact mixture to prepare a contact mixture, and the contact mixture is subjected to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment. In the utilization treatment method for treating and preparing the selected material to be treated into a water-containing, non-polluting, water-resistant treated body having a predetermined shape;

  The above-mentioned processing target material is silicic acid composed of a granular material group by use consisting of a filling granular material having a particle diameter in the range of 3 μm to 1 mmφ, and an aggregate body having a particle diameter in the range of 0.1 to 7 mmφ. Treatment target consisting of a salt powder granule, an organic material group consisting of an organic substance having a particle diameter in the range of 1 to 10 mmφ, or a dry substance or a wet substance of a combination of two or more selected from an in-situ soil ground group Composed of materials;

  The above-mentioned contact admixture represents the material to be treated selected in the mixing step on the basis of dry matter, and 100 parts by mass of the water-containing composition as the treatment agent, 10 to 90 parts by mass, and water as necessary. Is added at a rate of at least 5 parts by mass, and the entire apparatus is mixed by additional contact with equipment that can be added and mixed by mixing to ensure a homogeneous plastic, mud or wet powder. Prepared as a contact mixture;

  The above-described series of work steps are performed on a preliminarily prepared contact mixture, based on the base material to be treated selected as necessary, or by making full use of processing tools and equipment, Demonstrating the processing function, processing the contact mixture into a processed product obtained by processing into a predetermined shape, and then proceeding the reaction / curing to the processed product at least at room temperature to obtain the properties as the predetermined shape Consists of a curing process that completes

  The processing steps in the series of work steps described above are performed on the contact mixture based on the base material to be treated, which is selected as necessary, at least at room temperature by spraying / spraying, coating / painting, self-horizontal flow, and bonding. Adhesion, Adhesion, Lamination, Adhesion / Adhesion, Joining, Spreading, Jointing, Soaking, Impregnation, Splashing, Assembly, Integration, Pouring, Pouring, Injection, Filling, Self-weight / Vibration / Press-fitting / Vacuum-packing, Mold Processing tools that operate binding, solidification, and processing functions via water consisting of take-up, kneading, setting, agitation, agitation, and mixing means to make processed products in a predetermined shape. Process;

  The curing process in the series of work steps described above, the processed product in the air, water, sea, soil, solution, steam under normal pressure, pressurization, decompression conditions in the range from room temperature to 100 ° C., Allow at least 15 minutes in a single atmosphere selected from the group of non-oxygen gas atmospheres or a multistage atmosphere of a combination of two or more, preferably at least 3 hours at room temperature to allow the reaction and curing to proceed. A process for preparing and preparing a water-containing, non-polluting, water-resistant treated body whose properties as a shaped body have been completed;

  The above-mentioned predetermined shape body is a hydrated fixed shape body mainly composed of silicates, an unspecified shape body, a granule type shape body, a powder type shape body, a soil type shape body, a shape type shape body or a treatment type A predetermined shape having a characteristic as a shape;

  The above utilization treatment method applies the water-containing composition itself as a utilization treatment target material to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment on the basis of the selected treatment target substrate. The water-containing composition itself is processed into a non-polluted, water-resistant, water-resistant treated body comprising a predetermined shaped body that has been subjected to a detoxification treatment and a non-re-mudging treatment by shaping at least at room temperature through water. A utilization processing method to prepare is provided.

According to the present invention, the above-mentioned raw material group to be treated is a silica gel, alumina gel, clay, aluminum silicate, zeolite, charcoal, organic substance having a specific surface area of 10 m ² / g or more. A group of powders having absorptive function composed of dry-distilled products; heat- and fire-resistant groups consisting of magnesia, alumina, alumina gel, silica, aluminosilicate, carbide and nitride having a particle size in the range of 1 to 5 mmφ Group of granular material of material: Calcium silicate (tobermorite, zonolite), fiber-based granular group of heat insulating and heat-insulating base material made of alumina fiber, rock wool, carbon fiber, metal fiber; Various incinerated ash, calcium-based powder, bottom sediment / sludge, clay aluminosilicate, zeolite, dehydrated / water-retaining particles composed of amorphous alumina / silica The utilization processing method which is another granular material group is provided.

  According to the present invention, the silicate granular material as the material to be treated includes minerals, rocks, cinnabar sand, layered clay minerals, incineration ash of general / industrial wastes, papermaking, sawdust, crops, Food processing waste incineration ash, phosphorus-containing incineration ash from sewage sludge / agricultural settlement drainage sludge, coal ash discharged during thermal power generation, slag discharged from steel and steel making, low crystalline / amorphous silicates, volcanic eruption Utilization of silicate powders composed mainly of silicates selected from the group of materials, eco-cement, Portland cement, bottom sediment, dredged soil, sludge, sludge, and phosphorus-containing sludge A processing method is provided.

  According to the present invention, the organic material group that is the material to be treated is spherical, granular, massive, plate-like, sandy, chip-like, flake-like, or fibrous, having a particle size in the range of 1 to 10 mmφ. Contains 50% by mass or more of organic substances containing water in specific or unspecified shapes, including agricultural wastes, food processing wastes, deforested and fallen leaves of forest and landscaping plants , Sawdust, phosphorus-containing sludge from sewage / agricultural settlements, livestock manure, animal / plant-related industrial / life waste, industrial / life-related garbage / residue, and animal / vegetable organic materials alone In addition, there is provided a utilization processing method that is a group of two or more organic materials.

  According to the present invention, the in-situ soil ground that is the material to be treated is a soil ground existing in the original position, a soft ground, a road / bank / bank, a humus land, a forest, a farmland / field, a ridge / gutter, Utilization treatment methods that are in-situ soil ground composed of residential land / public land, factory / store land, park / garden or slope / plant cultivation base are provided.

  According to the present invention, the water-containing non-pollution type water-resistant treated body having a predetermined shape prepared by making use of a series of work steps comprising the above-described utilization treatment method is within a temperature range of 950 ° C. or lower. It is subjected to a work process consisting of a dehydration process that uses dehydration and heat treatment means that provides a hot atmosphere to dry or calcinate, and is shaped to be detoxified and non-re-mudified. Thus, there is provided a utilization treatment method for treating and preparing an anhydrous non-polluted water-resistant treated body in which an anhydrous shaped body or a ceramic type shaped body is secured.

  According to the present invention, the water treatment composition in the basic water-containing composition, the functional water-containing composition or the composite water-containing composition is adopted, and the utilization treatment method according to any one of claims 20 to 25 Water-free, pre-determined shapes that have been processed and prepared using a series of working steps consisting of a processing step consisting of a curing step at least at room temperature, and a processing step by a processing means that exhibits binding, solidification and processing functions via water In pollution-type water-resistant treated bodies;

  The above-mentioned predetermined shape body is a hydrous coated shape body, a binding shape body, a collective shape body, a multi-layer shape body, a specific shape body, a structural shape body, a film-shaped body mainly composed of silicates. Shaped body, reinforced shaped body, integrated shaped body, fixed shaped body, unspecified shaped body, granular shaped body, granule shaped shaped body, soil type shaped body, shaped shaped shaped body or treated shaped shaped body Is a predetermined shape body in which the properties of

The above pollution-free water-resistant treatment body adopts a water-containing composition and, if necessary, a series of utilization treatment methods using water according to the purpose, application, and work environment on the basis of the substrate to be treated. A predetermined shape of water containing a specific gravity of 1.20 to 2.40 g / cm ³ is applied to the working process, and the pH value is less than 10, and a non-polluting treatment is performed. Has been subjected to a non-re-mudging process that ensures water resistance without re-mudging, and a uniaxial compressive strength of a predetermined shape is ensured to be 10 KN / m ² or more as required, Shear fracture adhesion is secured at 5KN / m ² or more, recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, soil ground improvement materials, fire resistance / thermal insulation materials, ceramics / ceramic materials, Crafts / processing materials, adhesives / curing agents, water purification / treatment agents Ku is non-polluting type water-resistant treating body which can supply property is ensured in the field of plant growth substrate is provided.

  According to the present invention, the coating-type shaped body adopts the water-containing composition itself as a coating agent, and sprays / sprays, applies, sticks / adheres on the surface of the structural casing that is the substrate to be treated. A structural enclosure by applying a series of work processes that operate processing tools and devices that enable binding, solidification, and processing functions via water consisting of soaking, self-horizontal flow, binding, bonding or laminating means. Floor, wall / partition plate, pillar, roof / tile, bridge pier, structure, foundation structural frame, processing frame, ceramics / ceramics, crafts or self-forming floor There is provided a non-pollution type water-resistant treated body that is a water-containing coated shaped body.

  According to the present invention, the coated shape body is constructed by adopting the water-containing composition itself as the horizontal surface self-forming coating agent, which has the above-mentioned high fluidity and can complete 10 kg of the horizontal surface self-secure within 2 minutes. Pour water at the base of the surface of the structural enclosure that is the target substrate, and operate a device that enables a binding function through water that allows pouring, ensuring a smooth horizontal floor surface by self-forming the horizontal floor surface By subjecting to a series of work steps, a pollution-free water-resistant treatment body is provided which is a water-containing coated shape body in which a horizontal floor surface is self-formed on the surface of the structural housing.

  According to the present invention, the binder-shaped body adopts the water-containing composition itself as a binder / adhesive, and binds / adheres, laminates on the surface of the structural casing that is the substrate to be treated. Attaching / adhering / joining / joining / soaking / impregnating / pouring / injection / filling means through a series of work processes that operate the tools / equipment that enable binding / solidification / treatment functions via water 28. The pollution-free water-resistant treated body according to claim 27, which is a water-containing binder-shaped body comprising a plywood, a joint adhesive body, a binding body, an adhesive body, an adhesive body, and an adhesive body on the surface of the structural housing.

  According to the present invention, the aggregated shaped body adopts the water-containing composition itself as a binder / adhesive, and is a granular material in the range of a particle size of 20 μ to 40 mmφ which is a substrate to be treated, a spherical shape, Bonding, bonding, soaking, impregnation, pouring, pouring in the base of the surface of miscellaneous objects consisting of hollow, cylindrical, granule, aggregate, granule, junk, flake or flake Integrated assembly on the surface of miscellaneous objects by subjecting to a series of work processes that operate tools and devices that enable water binding, solidification, and processing functions through filling, stirring, stirring, and mixing means A non-polluting type that is a water-containing aggregated body consisting of an assembly, carrier, water permeable plate, ventilation body, soundproof body, fireproof body, water purification / treatment body, heat insulation / heat insulation material or catalyst body in a cocoon shape A water resistant treated body is provided.

  According to the present invention, the cocoon-like aggregate that is the aggregate-type shape body is an aggregate that has a through space and is integrated, and is a water-containing aggregate type that consists of an aggregate that is in the shape of a cocoon A pollution-free water-resistant treated body that is a shaped body is provided.

  According to the present invention, the multilayer shaped body is in the range of a particle size of 20 μ to 40 mmφ which is a substrate to be treated by adopting the water-containing composition itself as a binder / adhesive. In the base of the surface of miscellaneous objects consisting of garlic, flakes, lumps, and granules, binding, bonding, soaking, impregnation, pouring, pouring, filling, stirring, stirring, and mixing are used. By applying a series of work steps to operate tools and equipment that enable binding, solidification, and processing functions, coatings, multilayers, adsorbents, There is provided a non-polluting water-resistant treated body which is a water-containing multilayer shaped body comprising a odorant, a water purifying body, a heat insulating and heat insulating material or a catalyst body.

According to the present invention, the coated body that is the multilayer shaped body is a carbon, amorphous silica, activated silica, which is an adsorbent powder having a specific surface area of 100 m ² / g or more as a substrate to be treated. Select granule materials with single or two or more combined adsorptive properties selected from the group of acids, activated silicates, diatomaceous earth, activated alumina, activated aluminosilicate compounds, carbon-containing carbonized products, adsorptive incineration ash or zeolite Then, the selected water-containing composition itself is adopted as a binding / adhesive, and a tool that enables binding, solidification, and processing functions via water consisting of soaking, impregnation, pouring, stirring, stirring, and mixing means. An adsorbent having a specific surface area of 50 m ² / g or more by applying an adhesion coating film on the surface of an adsorbent granule on the surface of a miscellaneous object by subjecting it to a series of work steps for operating the apparatus There is provided a pollution-free water-resistant treated body that is a water-containing multi-layer shaped body made of a deodorant.

  According to the present invention, the above-mentioned specific mold-shaped body adopts the water-containing composition itself as a cementing / curing agent, and pours, pours, pours, and fills in the base of the shape-secured mold that is the substrate to be treated By applying a series of work processes to operate tools and equipment that enable binding, solidification and processing functions through water consisting of self-weight, vibration, press-fitting, mold making, kneading, and fitting means, Remove the pre-determined shape completed in the secure formwork from the secure formwork, pillar, plate / brick, fence / wall material, tile, pipe, fiber / string, sphere, U-shape There is provided a non-pollution type water-resistant treated body which is a specific type of water-containing shape composed of grooves, wave breakers, fishing reefs, crafts, tanks and containers.

  According to the present invention, the structure-type shape body adopts the water-containing composition itself as a cementing / curing agent, and is poured into the base of the shape-secured formwork that is the substrate to be treated, poured, poured, By applying a series of work processes that operate tools and equipment that enable binding, solidification and processing functions via water consisting of filling, dead weight, vibration, press-fitting, mold making, kneading, and fitting means, A non-polluting type that is a water-containing structural shape consisting of pillars, walls / plates, bridge piers, frames, and foundation structures by removing the predetermined shape completed in the shape-secured formwork from the shape-secured formwork A water resistant treated body is provided.

  According to the present invention, the film-shaped mold body adopts the water-containing composition itself as a cementing / curing agent, and is poured, poured, poured, in a base of a form-secured mold that is a substrate to be treated. By applying a series of work processes that operate tools and equipment that enable binding, solidification and processing functions via water consisting of filling, dead weight, vibration, press-fitting, mold making, kneading, and fitting means, A non-polluting type that is a water-containing film-shaped mold body consisting of a plate, a film / film body, and a film-shaped specific shape body by removing the predetermined shape body completed in the shape-secured formwork from the shape-secured formwork A water resistant treated body is provided.

  According to the present invention, the reinforcing shaped body adopts the water-containing composition itself as a cementing / curing agent, assembles metal bars as a substrate to be treated, woven / nonwoven fabric of fibers, organic rod Pouring, pouring, pouring, filling, self-weight / vibration / press-fitting, mold-making, kneading, and water-binding, solidification, and processing functions are possible. Pillars and pipes, bridge piers, skeletons, foundation structural skeletons, and foundations of specific shapes that have been integrated and completed with fiber braids by attaching them to a series of work processes that operate , Board / brick / interlocking, fences / wall materials, pipes, fibers / strings, spheres, U-shaped grooves, wave-dissipating materials, fishing reefs, crafts, containers or water-containing membranes of specific shapes Provided with non-polluting, water-resistant treated bodies that are mold-shaped bodies It is.

  According to the present invention, the one-piece shaped body adopts the water-containing composition itself as a cementing / curing agent, and is a waste material, wastes, low-level radioactive waste that is a substrate to be treated, Aggregated by powder, granule, granule, galactor, flake, shape, or volume holder having a diameter in the range of 0.3 to 9 mmφ, and stored and formed in a container as necessary. In the space of the collective group, it is formed by pouring, pouring, pouring, filling, gathering / integration, dead weight / vibration / press-fitting, mold making, kneading, concentrating / stirring / mixing through water. It is a water-containing monolithic body made up of integrated processed products that are assembled by integrating a group of assembly by attaching to a series of work processes that operate tools and devices that enable deposition, solidification, and processing functions. There is nothing Damage type waterproof treatment is provided.

  According to the present invention, the above-mentioned regular mold-shaped body uses the water-containing composition as a treatment agent, and the water-containing composition is additionally contacted with the application-specific powder group or silicate powder body as a processing target material. Mix the mixture into a contact mixture, then pour, pour, inject, fill, self-weight / vibration / press-fit, mold, knead, and inset in the base of the form-locked mold that is the substrate to be processed Forming a predetermined shape body completed in a form-assuring formwork by subjecting it to a series of work processes that operate tools and equipment that enable binding, solidification and processing functions via water consisting of means Remove from securing formwork, pillars / pipes, plates / brick / floor / interlocking, fences / wall materials, membranes, fibers / strings, spheres, U-shaped grooves, waves For extinguishing blocks, fishing reefs, crafts, containers or specific shapes That unburned consisting base of sanitary ware, crockery a steady-shape body of water pollution-free type waterproof treatment is provided.

  According to the present invention, the base of the non-fired sanitary ware / porcelain in the above-described fixed shape body is made of an inorganic paint / coating agent or an organic paint / coating agent having a resistance mainly composed of organopolysiloxane, Non-fired sanitary ware and porcelain surfaces are coated and coated with non-fired sanitary ware and porcelain. A pollution-free water-resistant treated body is provided.

Unspecified shape body According to the present invention, the above-mentioned unspecified shape body uses the water-containing composition as a treatment agent, and the water-containing composition is added to the granular material group or silicate powder body according to use which is the material to be treated. Add contact mixing to make a contact mixture, then stir, agitate, mix, knead, extrude, rolling granulation, crushing, water binding, solidification, treatment function By applying a series of work processes to operate the tools and equipment that enable it, segment auxiliary materials in the form of granular materials, granules, granules, sand, small lumps formed from the material to be processed, mortar Highly fluidized material, landfill / banking, filling / filling materials, synthetic aggregates, granule with specific surface area, non-fired fireproof / heat insulation / heat insulating material, catalysts, water purification / treatment agent, plant growth base , Water-containing unspecified shapes made of soil, soil, soil improvement materials or civil engineering materials A pollution-free water-resistant treated body is provided.

  According to the present invention, the granule that is the granule-shaped body is water-containing soil, sludge, sludge, bottom sediment, and an optional incinerated ash is added to the moisture regulator as necessary. The water-containing composition is added to the silicate granular material to make a contact mixture, and the contact mixture is stirred, stirred, mixed, kneaded, extruded, tumbled granulated, crushed, classified by means of Hydrated soil, sludge, sludge, bottom sediment silicate granules by attaching to a series of work processes that operate tools and equipment that enable binding, solidification and processing functions through water Segment auxiliary materials in the form of granules, granules, sand, small lumps, mortar high fluidization materials, landfill / filling, filling materials, fillers, synthetic aggregates, catalysts, water purification / Hydrous condyle consisting of treatment agent, plant growing base, soil, soil improvement material or civil engineering material A type shaped body nonpolluting type waterproof treatment is provided.

According to the present invention, the granule having a specific surface area which is an unspecified shape body has a specific surface area of 100 m ² / g or more as a granular material group or silicate granular material according to use which is a material to be treated. Selected from the group consisting of charcoal, amorphous silica, activated silicic acid / silicate, diatomaceous earth, activated alumina / aluminosilicate compound, carbon-containing carbonized product, adsorptive incineration ash or zeolite Single or a combination of two or more types of adsorbent powder materials, adsorbent, deodorant or water having a specific surface area of 50 m ² / g or more and having a granular shape, granular shape, sand shape, or small lump shape There is provided a pollution-free water-resistant treated body which is a water-containing unspecified shape body comprising a purifying body.

  According to the present invention, the granule-shaped body is a contact mixture by adding the water-containing composition to the silicate granular material that is the material to be treated, using the water-containing composition as a treatment agent. A series of tools and devices that enable the binding, solidification, and processing functions via water consisting of stirring, stirring, mixing, kneading, extrusion, rolling granulation, crushing, and classifying means. By applying to the work process, segment auxiliary material in the form of granule, granule, sand, crushed or small lump formed from the silicate powder that is the material to be processed, high fluidizing material of mortars It is a water-containing granule-shaped body consisting of landfill, embankment, soil, filling materials, fillers, synthetic aggregates, catalysts, water purification / treatment agents, plant growth base materials, soil improvement materials or civil engineering materials. A pollution-free water-resistant treated body is provided.

  According to the present invention, the water purification / treatment agent, which is a granule-shaped body, is a powder material made of incinerated ash containing phosphorus or hydrated sludge containing phosphorus as a silicate powder material to be treated. Non-polluting, water-resistant, which is a non-specific water-containing form consisting of a water purifying and treating agent that captures fluorine and heavy metals that are in the form of granules, granules, sand, and small blocks A sex processor is provided.

  According to the present invention, the unfired refractory, heat insulating and heat insulating material which is the above-mentioned amorphous shape body is a material group or silicate powder body according to use which is a material to be treated, such as magnesium, alumina, alumina. Heat- and fire-resistant base particles composed of gel, silica, aluminosilicate, carbide, nitride; calcium silicate (tobermorite, zonotlite), alumina fiber, rock wool, carbon fiber, metal fiber Fiber-based granular material group of heat-insulating base material; selecting a granular material consisting of incinerated ash that has undergone a thermal history, unfired fire-resistant and heat-insulating in granular, granular, sandy, and small lump shapes A non-polluting water-resistant treated body that is an unspecified water-containing body made of a heat insulating material is provided.

  According to the present invention, the above-mentioned powder type processed body is a contact mixture by adding the water-containing composition to the silicate powder body, which is the material to be treated, using the water-containing composition as a treatment agent. A series of tools and devices that enable the binding, solidification, and processing functions via water, which comprises stirring, stirring, mixing, kneading, extrusion, rolling granulation, crushing, and classifying means. By attaching to the above work process, segment auxiliary material made of silicate granular material that is the material to be treated, high fluidity material of mortars, substitute for hydraulic cement, non-fired fireproof and heat insulation・ Heat-retaining material, horizontal floor self-shaped body, fillers, landfill / filling / filling material, soil improvement material, non-polluting, water-resistant treated body consisting of water-containing granular material made of soil or greening base material Is provided.

  According to the present invention, the high fluidization material of the mortar that is the above-mentioned powder-type shaped body is selected from various incinerated ash powder material materials as the silicate powder material to be treated, There is provided a non-pollution type water-resistant treated body which is a granular, granular, sandy or small lump, and is a water-containing granule-shaped body made of a high fluidizing material capable of ensuring good fluidity in cement mortars. .

  According to the present invention, the above-mentioned soil type shaped body is a silicate granular material composed of water-containing phosphorus sludge and phosphorus-containing incinerated ash, which is a material to be treated, using the water-containing composition as a treatment agent, and further if necessary. The water-containing composition is added to the organic material group and a deodorant having a deodorizing function to make a contact mixture, and the contact mixture is stirred, stirred, mixed, kneaded and extruded.・ Fermented compost as needed by attaching to a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions via water consisting of rolling granulation, crushing, and classification means By using aerobic microorganisms that have an oxidization function and adding agitation and mixing, and composting and composting, the phosphosilicate-containing granular material or organic material group that is the material to be processed is also used. Has been Vertical, fill, Nakagomi material, soil conditioner, black soil, soil dressing, a soil-shaped body of water consisting of greening base material or cultivating plant material nonpolluting type waterproof treatment is provided.

  According to the present invention, the above-mentioned shape-type shape body is obtained by using the water-containing composition as a treatment agent, and adding the water-containing composition to the in-situ soil ground that is the material to be treated to obtain a contact mixture, By subjecting the admixture to a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions via water consisting of known and official processing means in situ, A certain original position The original position consisting of piles, fences, roads, embankments, banks, side roads, gutters, slopes, mountain forests, farmland / fields, residential land / public land or parks / gardens formed in soil There is provided a non-pollution type water-resistant treated body which is a water-containing shape-type body.

  According to the present invention, the treatment-type shape body uses the water-containing composition as a treatment agent, and the water-containing composition is additionally contacted and mixed with the in-situ soil ground that is the material to be treated to form a contact mixture. By subjecting the admixture to a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions via water consisting of known and official processing means in situ, Soil ground that has been improved / repaired from the soil formed by a certain in-situ soil ground, mountain forest land, farmland / fields, roads, residential land / public land, factory / store land, or water containing water in the original position There is provided a pollution-free water-resistant treated body that is a treated shaped body.

  According to the present invention, the moisture-containing non-polluted water-resistant treated body having the predetermined shape is dried by applying a hot atmosphere within a temperature range of 950 ° C. or lower, which is the utilization treatment method according to claim 26. By subjecting it to a work process that makes full use of the dehydration construction means that is composed of the dehydration and heat treatment means that are baked, it is possible to obtain powder, granules, structures, specific shapes or non-specific shapes. Non-pollution-type water resistance in which an anhydrous anhydrous shape body or ceramic-type shape body having a certain pH value of less than 10 is secured, shaped as a predetermined shape body, subjected to detoxification treatment and non-re-mudging treatment A treatment body is provided.

  The effect of the present invention is that the water-containing composition of the present invention exhibits the binding, solidification and processing functions at least at room temperature, and enables labor-saving on-site construction work at room temperature in the field of inorganic cementing material utilization. Moreover, even if silicate wastes coexisting with water-eluting element groups that are harmful to the raw material and the material to be treated are selected, the treated product formed here has a pH value of less than 10 and is detoxified and non-toxic. Because of the re-mudging treatment, the non-polluting water-resistant treated body of the present invention has no risk of adverse effects on the living environment. Recyclable materials, life-related materials, environmental countermeasure materials, agricultural / fishery materials , Civil engineering / building materials, ground / ceramic materials, water purification / treatment agents, crafts / processing materials, plant growth base materials, etc. And In the place where it is possible to provide a technology that can contribute to the creation of a recycling-oriented society to promote the recycling of wastes.

[Explanation of special terms and special titles]
In the present specification, definitions and simple contents of terms and special notation specifically adopted in the present invention will be described below.

1. "Sulfur, phosphorus, carbon or boron oxyacid ions"
The term “sulfur, phosphorus, carbon or boron oxyacid ion” refers to “sulfur trioxide ions” which are represented by the binding liquid composition constituting the basic water-containing composition of the present invention. "Oxygen ion of phosphorus", "Phosphorus oxyacid ion" represented by "Phosphorus pentoxide ion", "Carbon oxyacid ion" represented by "Carbon dioxide ion" and "Boron trioxide ion" These “oxygen ions of boron” represent these acid group ion groups.

2. “Liquid state stability”:
“Liquid state stability” refers to a state in which the binding liquid composition stably ensures a fluid liquid state in the binding liquid composition constituting the water-containing composition of the present invention. In the present specification, a state in which a liquid state with fluidity is stably ensured at least at room temperature for 30 days is defined as having “stability” in the liquid state.

3. “Reactive silicates”:
“Easily reactive silicates” refers to 10 parts by mass of silicates adopted as a raw material of the binding liquid composition constituting the water-containing composition of the present invention at room temperature in 100 parts by mass of at least 10% by mass of caustic soda solution. In a treated product immersed for 24 hours, silicates are reacted with caustic soda and the unreacted solid weight is reduced by 10% by weight or more from the initial weight.

4). “Harmful elements”:
In addition to the element groups of cadmium, arsenic, mercury, lead, chromium, selenium, boron, and fluorine specified and described in the Soil Contamination Countermeasures Law based on the Basic Environment Law, the “hazardous element group” includes the present specification. Then, it is an element group with sodium and manganese added. In addition, the pollution state of harmful elements in water and other media is evaluated with reference to the soil elution standards, groundwater content standards, and soil content reference values shown in Table 1 shown in the environmental standards of the Ministry of the Environment. .

5. "Shaping process":
“Shaping treatment” in the present invention means that a practical treatment method using the water-containing composition of the present invention is applied to a substantial powder that becomes muddy in water, and the treated product at this time is thrown into water. Means that it is treated in a non-re-mud state without causing mudification. Therefore, even if it is in a granular state, it is not re-mudged by pouring into water, and when the separation from water is in a clear state, it is judged that a shaping process that does not cause re-mudging is performed. .

6). “Detoxification”:
The “detoxification treatment” in the present invention means that the treated body of the present invention first secures a pH value of less than 10 and then a group of elements harmful to the water-containing composition and the material to be treated and sodium used in the present invention. In the case where ions coexist, the non-polluted non-re-mudified treated material prepared by the utilization treatment method of the present invention, the dissolution test method in the neutral range (see the section of the evaluation test method for physical properties and the like below: When applied to the Environment Agency No. 46 Dissolution Test Method, the water dissolution amount of the coexisting harmful elements in the neutral range dissolution test method is within the range of the environmental standard value, and at the same time is harmful as well as fixing and insolubilizing sodium ions. This refers to a state in which the element group is fixed and insolubilized and is prepared as a non-pollution type non-re-mudging treatment body in a state that does not adversely affect the living environment.

7). "Non-re-mudging process":
“Non-re-mudging treatment” in the present invention means a tool / apparatus that enables construction means capable of exhibiting a binding / solidification / treatment function via water for a fluid hydrous composition that exhibits a treatment function. By subjecting the group to a series of operation steps, it is shaped into a predetermined shape including powder by water-resistant binding and curing, and at the same time, the pH value in the treated product is less than 10 and water resistance. Is secured and non-re-mudging treatment is applied.

[Basic Technical Overview of the Present Invention]
Hereinafter, the best conditions and forms suitable for carrying out the present invention will be specifically described.
As already summarized in [Problems to be Solved by the Invention] of the present specification, the problem in the present invention is “elution of hexavalent chromium” which has been shown in cement-based or water-glass cementing materials in the prior art. ”“ PH value of 12 or higher ”“ Lack of work working time ”“ Non-water resistance ”“ Low price ”“ Coexisting harmful water-eluting elements ”“ Energy load ” The invention is a technique developed to solve these problems.

  In response to the above-mentioned problems imposed on the present invention, the present inventors have conducted research and development in search of a technology that can solve these problems. In particular, the inventors of the present invention have disclosed the inventive technique relating to a water glass cementing material (see: Patent Documents 08, 09, 10, 11). Furthermore, the present inventors have made harmful water-eluting element groups coexisting in wastes insoluble / immobilized in water-insoluble minerals, so that harmful water-eluting element groups are safe for humans and the living environment. Inventive technology for reforming to a state has been disclosed (see Patent Documents 13 to 17). Based on the inventive technology, research and development of the present invention was conducted on the line.

  The present inventors are wastes such as silicates that are subject to treatment / disposal with a water glass-based cementing material that does not coexist with harmful hexavalent chromium as a main component in the water-containing composition of the present invention. While recycling the materials of incinerated ash, these materials were adopted as the raw materials of the present invention to obtain a low price for the product, and the working work life was sufficiently secured and shaped. The treated product has a pH value of 10 or less, does not cause re-mudging in water, is water-resistant, does not dissolve or diffuse harmful water-eluting elements into the living environment, does not harm humans and the environment, and circulates. Through research and development that contributes to the creation of a type society, labor-saving on-site work is possible, and water glass-based cementing materials that can provide products to each application field at low prices are sought. Invented.

  In the present invention, the basis of the means for solving the problems of the present invention corresponding to the water glass based cementing material and the like in the prior art is the water-containing composition of the present invention. The water-containing composition that is the basis of the present invention is a binding liquid composition composed of a modified alkali silicate having an oxyacid ion of one or more combined elements of sulfur, phosphorus, carbon, or boron. The technical disclosure is made as a basic composition of a slurry-type basic water-containing composition in which a reactive powder composition composed of an aluminosilicate compound having a calcium oxide is added and homogeneously mixed.

  Furthermore, in the present invention, a functional material group is added to the slurry-based basic water-containing composition composed of the binding liquid composition and the reactive powder composition which are the basic composition of the present invention. A juice-like functional water-containing composition mixed homogeneously is disclosed as an enlarged composition. Furthermore, in the present invention, a hydrated mortar-shaped composite water-containing composition is added to a slurry-based basic water-containing composition or a juice-like functional water-containing composition, and the mortar-shaped composite water-containing composition is mixed homogeneously. It is disclosed as a composition.

  The present invention according to still further details adopts a water-containing composition that is a basic water-containing composition, a functional water-containing composition or a composite water-containing composition, and utilizes the water-containing composition for the water-containing composition itself or the water-containing composition. Consists of utilization processing means according to the purpose, application, and working environment based on the base material to be treated as necessary for the contact admixture mixed with the material to be treated selected as the treatment agent. The utilization processing method which attaches | subjects to a series of work processes and processes and prepares the water-containing pollution-free water-resistant processing body which consists of a predetermined shape body is disclosed.

The composition of the water-containing composition of the present invention is shown in Table 2 below for reference.

  The present invention according to still further details adopts the above-mentioned water-containing composition, to the water-containing composition itself, or to a contact mixture in which the water-containing composition is added and mixed with the material to be treated as a treatment agent. In addition, a predetermined shape that is processed and prepared using a series of work processes consisting of utilization processing means according to the purpose, application, and work environment is recycled into resources, life-related materials, environmental measures materials, agriculture and fishery materials, Secured with properties that can be supplied to the fields of civil engineering and construction materials, soil ground improvement materials, fireproofing and heat insulation materials, ceramics and ceramic materials, crafts and processing materials, adhesives and curing agents, water purification and treatment agents, or plant growth base materials A pollution-free water-resistant treated body is disclosed.

Table 3 shows an outline of an active treatment method for adopting and preparing the water-containing composition of the present invention and a non-polluting water-resistant treated body having a predetermined shape.

  The novelty in the water-containing composition of the present invention is the content of the components of the water-containing composition comprising the binding liquid composition and the reactive powder composition constituting the basic water-containing composition of the water-containing composition. On the basis of this, there is an effect based on the processing function which is formed here through water at least at normal temperature and is subjected to detoxification treatment and non-re-mudging treatment. In particular, a binding liquid composition is proposed in which a modified alkali silicate containing oxyacid ions of sulfur, phosphorus, carbon, or boron alone or in combination of two or more elements ensures a stable liquid state. In the technical configuration of the present invention. Therefore, it is considered that the novel technology in the present invention that can deal with the undisclosed technology in the prior art is due to the following features exhibited by the constituent components constituting the water-containing composition in the present invention, I can understand.

1. A modified sodium silicate coexisting with acid radicals is prepared in advance as a stable binding liquid composition.
2. An aluminosilicate coexisting with active calcium is prepared as a reactive powder composition.
3. A water-containing composition having a pH value of 10 or more is composed of a binding liquid composition and a reactive powder composition.
4). Functionality can be improved by adding a functional material group or a composite additive material group to the basic water-containing composition.
5. The processing target material can be processed by mixing the water-containing composition with the target processing material.

Due to the novelty of the water-containing composition of the present invention described above, the main effects obtained from the water-containing composition of the present invention and the pollution-free water-resistant treated body prepared by treatment using the water-containing composition are as follows. It is understood that there is an effect shown.
1. Water glass cementing material ensures sufficient work life at the work site where problems are encountered.
2. A self-leveling surface can be formed with an excellent flowable water-containing composition, and labor-saving work is possible.
3. Coexisting materials with harmful water-eluting elements can be selected as a component of the water-containing composition.
4). Formation of water-insoluble minerals (zeolite / apatite) with heavy metals fixed.
5. Predetermined shaped body has low alkalinity and no harmful substances are eluted.
6). By adopting a low-priced water-containing composition, construction is possible with a low-cost, labor-saving construction method at room temperature.

  Moreover, the novelty in the utilization processing method in this invention has the oxyacid ion of the single or 2 or more types of combination element of sulfur, phosphorus, carbon, or boron which is the novel water-containing composition of this invention. Adopting a water-containing composition selected from a slurry-based basic water-containing composition comprising a modified alkali silicate as a main component, a juice-like functional water-containing composition or a mortar-shaped composite water-containing composition. The water-containing composition is subjected to a series of working steps via water that can perform any of the treatment functions of fixing, binding, curing, and water resistance at least at room temperature. There are three types of utilization processing methods to be described later in detail for processing and preparing the processing body.

Furthermore, the novelty in the pollution-free water-resistant treated body of the present invention possesses oxyacid ions of sulfur, phosphorus, carbon or boron alone or in combination of two or more of the novel alkaline properties of the present invention. Selected from a slurry-like basic water-containing composition, a juice-like functional water-containing composition, or a mortar-like composite water-containing composition, which is a novel water-containing composition of the present invention comprising a modified alkali silicate. A water-containing composition having a specific gravity in the range of 1.20 to 2.40 g / cm ³ by utilizing the utilization treatment method comprising a series of working steps through water at least at room temperature according to the present invention. The predetermined shape body is subjected to a shaping treatment, subjected to a non-polluting treatment with a pH value of less than 10, and further subjected to a non-re-mudging treatment for ensuring water resistance. Ri, shaped body strength needed are ensured 10NK / m ² or more in a uniaxial compression strength, shear failure adhesion are ensured 5KN / m ² or more, recycling materials, life-related materials, Agricultural / fishery materials, civil engineering / building materials, soil ground improvement materials, fireproofing / thermal insulation materials, ceramics / pottery materials, crafts / processing materials, adhesives / hardening agents, water purification / treatment agents or plant growth base materials The technical disclosure provides a non-pollution type water-resistant treated body in which proper properties are ensured.

  The reaction mechanism at normal temperature at which the water-containing composition of the present invention exhibits any of the fixing, binding, curing, and water-resistant treatment functions described above is derived from the components constituting the water-containing composition. In other words, it possesses alkaline and active calcium for a binding liquid composition that contains oxyacid ions of one or more of the combination elements of sulfur, phosphorus, carbon or boron, which are alkaline and acid radical ions. The reactive powder composition composed of the aluminosilicate compound is considered to be derived from the reaction mechanism resulting from the reaction shown below that occurs basically when mixed with water.

1. 1. Silica group-containing silicic acid forms a silica polymer network composed of polysiloxane bonds. 2. Sulfate ions react with calcium in the reactive powder composition to form a water-resistant hydrated mineral. 3. Phosphate ions react with calcium in the reactive powder composition to form a water-resistant hydrated mineral. 4. Precipitate formation of dense silicate-based hydrated minerals between silica polymer network matrices. 5. Toxically fix harmful elements to zeolite precursor minerals and fix them as water-insoluble minerals. 6. Fluorine is immobilized on phosphocalcium apatite mineral and immobilized as a water-insoluble mineral. Secures water resistance by immobilizing sodium in water-insoluble aluminosilicate alkali salt mineral

  The important reaction developed in the reaction mechanism of the present invention described above is that the functional reaction that exhibits the fixing, binding, curing, and water resistance of the water-containing composition proceeds through water at least at room temperature. is there. The water required for the reaction at this time does not need to be excessive, the amount of water that is adsorbed and supported by the raw materials used for the water-containing composition is sufficient, and the raw materials are retained as crystal water. Even the amount of water that has been used is sufficient even if it is discharged by reactive decomposition.

  However, what is important is that in the binding liquid composition constituting the water-containing composition, the silica component coexisting in advance is in a liquid state via water, and a silanol group is present in the system in advance. Is in a state of being. Formation of a silica polymer is difficult from solid silica in which various basic components coexist. The silica polymer is easily condensed from the silanol group of the alkali salt in a liquid state to form a silica polymer comprising a siloxane bond by dealkalization. That is, a silica polymer having a siloxane bond, which is required in the present invention, cannot be formed with silica having no solid silanol group. Therefore, in order to form a silica polymer composed of a siloxane bond, it is important that a silanol group of an alkali salt in a liquid state is prepared in advance.

  Moreover, the reaction that takes place through water in the water-containing composition of the present invention in a liquid state at least at room temperature is water-insoluble along with the formation of a water-insoluble silica polymer through a plurality of reaction processes under a plurality of multiple conditions. Calcium-based hydrated minerals, alkali aluminosilicate minerals, and phosphorus-containing calcium-based apatite minerals are expected to be completed. In particular, the important reaction process in the water-containing composition of the present invention includes a reaction in which a silica having silanol groups forms a silica polymer composed of a polysiloxane bond, and an element group ion and a sodium ion containing water-eluting heavy metals are aluminosilicated. The reaction is to form a zeolite precursor immobilized in an acid alkali salt and a water-insoluble mineral in which fluorine is incorporated into the phosphorous calcium-containing apatite and immobilized.

  Since the water-containing composition of the present invention is composed of an alkaline aluminosilicate compound containing calcium and an alkali silicate having an alkali silanol group, it is a composition that is inherently in a liquid state exhibiting high alkalinity. However, the treated body formed at room temperature from the water-containing composition of the present invention is water insoluble in the presence of coexisting sodium ions, calcium ions, etc., although no acidic component neutralizing alkali is brought into the system. Since the water-insoluble mineral is formed by being immobilized on the surface, the pH value of the treated body formed here is shifted to a low alkali side of less than 10. From these phenomena, it is well understood that sodium ions, calcium ions and the like are immobilized as water-insoluble minerals, and at the same time, element group ions including water-eluting heavy metals are immobilized on water-insoluble minerals.

  Furthermore, the water-containing composition of the present invention is different from a treated body that is a hardened / solidified body formed by entanglement of a crystal composed of a hydrated mineral formed of Portland cement or the like, and a silica polymer that forms a network structure is used. It is assumed that a basic matrix is formed, and a crystal body made of each water-insoluble mineral is deposited and embedded in the gaps of the basic matrix made of a network structure to form a processed body made of a strong matrix matrix.

  In particular, in the present invention, in order to provide a product price at a low price, silicates composed of wastes that can be accepted at a low price are selected for the material components of the raw material constituting the hydraulic liquid composition of the present invention. be able to. Examples of silicates that can be adopted in the present invention include incineration ash of general and industrial wastes that have received a heat history, incineration ash of paper wastes, incineration ash of phosphorus-containing sewage sludge and agricultural settlement drainage sludge, thermal power Granules made of coal ash discharged during power generation, slag discharged from iron and steel making, Portland cement, etc., as well as water-containing granules made up of natural clay minerals, sediments containing sludge, sludge, etc. A body can be mentioned suitably.

  However, since the wastes composed of silicates adopted in the present invention are essentially wastes, harmful substances coexist. In particular, coexisting elements (cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine, sodium, etc.) containing heavy metals with water elution that are highly harmful to humans and the environment. Therefore, it is not allowed to provide silicates coexisting with harmful element groups as a product group for use in a living environment without treatment. Of course, in the wastes composed of silicates adopted in the present invention, it is preferable to fix various heavy metals coexisting in addition to the above element group in the same manner as the above element group.

  However, in the present invention, an aluminosilicate compound having active calcium composed of wastes coexisting elements containing water-eluting heavy metals in the reactive powder composition constituting the water-containing composition of the present invention, etc. Can be adopted as a raw material. That is, in Patent Documents 13, 15, 16, and 17, which are the inventors' inventive technology, an element group containing water-eluting heavy metals coexisting with wastes and the like is previously taken in and immobilized in a water-insoluble mineral, Disclosed is a technique for modifying a processed product that clears environmental standards.

  In other words, harmful heavy metals and alkali metals are disclosed in an immobilization technology in which they are incorporated into a zeolite precursor made of an alkali salt of aluminosilicate to form a water-insoluble mineral, and fluorine and the like are apatite minerals made of a fluorophosphocalcic compound. Disclosure of immobilization technology to incorporate water-insoluble minerals, and at the same time, immobilization technology to incorporate sodium and calcium into each of the above water-insoluble minerals has already been disclosed as an inventor's invention technology, and is formed of cement or the like. Unlike the highly alkaline hardened / solidified body, the pollution-free water-resistant treated body of the present invention makes full use of the technology to insolubilize and immobilize the harmful elements that coexist with low alkalinity with a pH value of less than 10 and alkali metals. Is possible.

  As described above, as understood from the reaction mechanism exhibited by the water-containing composition of the present invention, the technical features of the present invention compared to the prior art are liquid alkali silicates such as sulfur, phosphorus or carbon oxyacid ions, For example, calcium sulfate radicals, phosphate radicals and carbonate radicals are dissolved in advance, while fixing harmful element groups in the gaps of the silica polymer formed by the polysiloxane bonds that form a matrix in the network structure, respectively. -It is possible to form a low alkalinity non-pollution water-resistant treated body by depositing and supplementing water-insoluble hydrated minerals such as sulfuric acid, calcium-phosphate, silicate-calcium, and alkali aluminosilicate.

  Of course, the water-containing composition of the present invention is a water-containing composition that exhibits any of the fixing, binding, curing, and water-resistant processing functions at least at room temperature, but any of the fixing, binding, curing, and water-resistant processing functions. The conditions for exhibiting the conditions can change the strength of the content of the processing function to be exhibited depending on the content of the constituent components of the water-containing composition, the proportion of the blended components, the work process, the work environment, and the like within the scope of the present invention. However, the water-containing composition of the present invention has a treatment function that exhibits a detoxification treatment and a non-re-mudging treatment by being shaped at least at room temperature via water.

[Basic water-containing composition]
The water-containing composition in the present invention is based on a basic slurry-type water-containing composition basically composed of a binder liquid composition and a reactive powder composition. The binding liquid composition constituting the basic water-containing composition of the present invention basically has a silanol group, and forms a silica polymer composed of a polysiloxane bond by dehydration condensation of the retained silanol group, Formation of a matrix having a network structure composed of a silica polymer that is the basis of the matrix in the treated body is expected.

  On the other hand, the reactive powder composition constituting the water-containing composition of the present invention is formed from the binding liquid composition by causing a catalytic action that promotes dehydration condensation on silanol groups possessed by the binding liquid composition. Matrix matrix formed from a water-containing composition that promotes the formation of a network structure composed of a silica polymer, and at the same time promotes the formation of hydrated minerals composed of calcium-based compounds that fill and deposit between the network structures composed of a silica polymer Can be expected to strengthen and strengthen.

  The binding liquid composition constituting the basic water-containing composition of the present invention is a liquid composition containing water, alkali ions, silicic acid having a silanol group, and oxyacid ions of sulfur, phosphorus, carbon or boron. It is structured as a thing. Since the binding liquid composition of the present invention has a silanol group, the formation of a silica polymer by dehydration condensation of the silanol group exhibits an adhesive / binding function. In addition, it is important that the binding liquid composition is alkaline in order to stably secure a silanol group having sulfur, phosphorus, carbon or boron oxyacid ions for a certain period in a liquid state. It is.

［式中：Ｍはナトリウムないしカリウム元素の単独ないしは２種組み合わせのアリカリ金属元素、ａは０．５ないし３の数、ｂ、ｃ、ｅならびにｄは０．０５ないし１の数、ｗは４ないし４０の数］で表される水溶媒、アルカリ金属元素イオン、シラノール基を保有するケイ酸アルカリならびに硫黄、リン、炭素またはホウ素の単独ないし２種以上の組み合わせ元素のオキシ酸イオンを主成分とするアルカリ性の液状組成物で構成されており、該液状組成物の液状態での安定性が常温で少なくとも３０日間確保されている変性ケイ酸アルカリからなる液状組成物であり，該含水組成物である液状組成物の安定液状態が常温で３０日間は確保されている変性ケイ酸アルカリからなる液状組成物として調製されていることが好ましい。Specifically, the binding liquid composition constituting the water-containing composition of the present invention has the following composition formula (1):

[Wherein, M is a single or a combination of two or more kinds of sodium or potassium elements, a is a number of 0.5 to 3, b, c, e and d are numbers of 0.05 to 1, and w is 4 Or an aqueous solution of an alkali metal element ion, a silanol group and an oxyacid ion of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements. A liquid composition comprising a modified alkali silicate having a liquid state stability of at least 30 days at room temperature, the liquid composition comprising: It is preferable that the liquid composition of a certain liquid composition is prepared as a liquid composition composed of a modified alkali silicate that is secured at room temperature for 30 days.

  In the binding liquid composition in the basic water-containing composition of the present invention, it is important that the binding liquid composition is in a liquid state, so that the functional properties as a water-containing composition can be sufficiently exhibited at least at room temperature. It is essential that the liquid is in a liquid state in which water is present. Temporarily, the binding liquid composition is configured in a powder state, and the composition component of the binding liquid composition in the water-containing composition of the present invention is configured in a powder state, and the reactive powder composition in the powder state In order to fully demonstrate the functionality of fixing, binding, curing, and water resistance at room temperature, the powdered composition that is packed in a powder is first contacted with water. Crushing is a priority.

  However, when water is first brought into contact with a one-packed composition composed of an alkali silicate in a powder state and an aluminosilicate compound containing calcium, the necessary silanol groups are dissolved in the process of dissolving the alkali silicate in water. Prior to formation, an active aluminosilicate compound that possesses an active calcite reacts with basic silicate and alkali silicate via water to form calcium silicate preferentially. Since the composition tends to impair silanol group formation necessary for the formation of the silica polymer, which is a basic component of the matrix, and the composition forms the silica polymer that ensures the water resistance required for the treated body of the present invention. It is not preferable.

  The water constituting the binding liquid composition in the liquid state of the present invention is not limited to pure water, and a wide range of aqueous solvents can be employed. Examples of the aqueous solvent suitably adopted in the present invention include natural water, artificially treated water, waste water, or water contained in the materials constituting the water-containing composition, adsorbed water, or single or two or more kinds selected from the group of coexisting water. A combination of these aqueous solvents can be selected and employed. Specifically, rainwater, rivers / lakes / pool water, spring water, well water, seawater, artificial pond / dam water, natural water; drinking water, industrial water, agricultural water, tap water, sewage treatment water, industrial water Artificial treated water that is by-product water; industrial wastewater, domestic wastewater, wastewater that is various treated water; and hydrous soil, bottom sediment, soil ground, industry that are material components that constitute the hydrous composition of the present invention An aqueous solvent in which the wastes, the material to be treated, etc. are selected from the group of inclusion water, adsorbed water or coexisting water can be preferably mentioned.

  Further, in the water-containing composition of the present invention, an important condition is that the binding liquid composition is in a liquid state, and sulfur, phosphorus, carbon or boron represented by sulfate radical, phosphate radical, carbonate radical, etc. The binding liquid composition is in a condition that ensures a stable liquid state by coexisting oxyacid ions of one or two or more combination elements. In general, when an ionic sulfate group, phosphate group, carbonate group, or the like is added to a liquid alkali silicate, the silica component tends to settle and separate from the liquid alkali silicate as a gel substance.

  Therefore, it is difficult to ensure the presence of ionic sulfate groups, phosphate groups, carbonate groups, etc. in a stable liquid state in a liquid alkali silicate. However, in the binding liquid composition of the present invention, although it is within a certain range, ionic sulfate groups, phosphate groups, and carbonate groups are allowed to coexist in a safe liquid state in the liquid alkali silicate. The novelty and features are found in the concentration ratio conditions and coexistence conditions.

  As in the case of conventional water glass cementing materials, water resistance is ensured for liquid alkali silicates that contain only silanol groups and do not coexist with ionic sulfate, phosphate, and carbonate radicals. It is difficult to form a treated body. However, as in the present invention, when the binding liquid composition of the present invention in which a sulfate group, a phosphate group, and a carbonate group are preliminarily coexisted in a liquid alkali silicate having a silanol group in an ionic state, this is adopted. When a reactive powder composition, which is an aluminosilicate containing active calcium, is added to the binding liquid composition and mixed, the aluminosilicate first contains sulfate with active sulfate, phosphate and carbonate radicals. At the time of contact with water via water, the reaction of sulfate radical, phosphate radical, carbonate radical and active calcium can preferentially cause the reaction.

  Accordingly, the formation of a silica polymer by a condensation reaction in a liquid alkali silicate having a silanol group is preferentially formed without being obstructed by other ionic components, and water that is a salt compound of each acid group and calcium. An insoluble hydrated mineral is formed, and a salt mineral that is a water-insoluble hydrated mineral is newly deposited in the silica polymer network matrix required in the present invention, and formed as a treated body. Reinforcing properties can be imparted to the matrix matrix, and the strength of the treated body can be improved.

  The biggest disadvantage of the water glass cementing material in the prior art is that, in the processed shaped product in the room temperature reaction, the free sodium ions coexist with the gelled solidified silicic acid. It is in the lack of water resistance because the sodium ion restarts the reaction again through water and transforms silicic acid into water-soluble ionic sodium silicate. Therefore, in the present invention, in order to eliminate the disadvantages of the water glass cementing material, a zeolite which is a water-insoluble aluminosilicate sodium salt by reacting a readily reactive aluminosilicate with dissolved sodium ions. The present inventors have found a condition for forming a water-insoluble mineral composed of a precursor, preventing re-dissolution of the silica component, preventing re-mudging of the formed product, and forming a treated body with ensured water resistance.

  In the water-containing composition of the present invention, a binding liquid in which a stable liquid state comprising a modified alkali silicate having an oxyacid ion of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements is secured. Suitable preparation means for preparing the composition are roughly classified into two types: a method using water glass as a main material (water glass method) and a method using a readily reactive silicate as a main material (silicate method). Can be separated.

［式中：Ｍはナトリウムないしカリウム元素、ａは０．５ないし４の数、ｗは４ないし３０の数］で表されるシラノール基を保有する液状のケイ酸アルカリ５０ないし２００質量部を加えて均質に混和して変性ケイ酸アルカリからなる結着性液状組成物として調製される方式が好適である。As a means for preparing the binding liquid composition of the present invention by the water glass method, oxyacid of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements in advance with respect to 100 parts by mass of water as an aqueous solvent. 1 to 40 parts by mass of an alkali metal salt is added and dissolved, and then the following compositional formula (2)

[Wherein M is a sodium or potassium element, a is a number of 0.5 to 4, w is a number of 4 to 30, and 50 to 200 parts by mass of a liquid alkali silicate having a silanol group represented by A method in which the mixture is homogeneously mixed and prepared as a binding liquid composition comprising a modified alkali silicate is preferable.

  The solid or liquid alkali silicate having a silanol group constituting the binding liquid composition of the present invention is generally JIS-converted as water glass and widely used, so that the present invention is easy to obtain. The binding liquid composition can be suitably selected as a solid or liquid alkali silicate. Of course, the water glass is generally a liquid alkali silicate, but a powder solid alkali silicate is also provided, and the powder solid alkali silicate is previously dissolved in water to form a binding liquid. It can be adopted as a composition.

  The feature of the binding liquid composition of the present invention is that a single, or combination of two or more of sulfur, phosphorus, carbon or boron is used with respect to an alkaline liquid alkali silicate in order to ensure water resistance of the cured product to be formed. The purpose is to dissolve the oxyacid ion of the element in advance. As the oxyacid ion of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements employed in the binding liquid composition of the present invention, one or two of alkali metal sulfur, phosphorus, carbon or boron is used. It is preferable to adopt an oxyacid salt of the above combination element.

  As the oxyacid salt of an alkali metal sulfur, phosphorus, carbon or boron, which is preferably selected for the binding liquid composition of the present invention, or a combination element of two or more thereof, sodium sulfate, potassium sulfate, sodium sulfite is generally used. Potassium sulfite, sodium phosphate, potassium phosphate, sodium phosphite, sodium carbonate, sodium bicarbonate, potassium carbonate, sodium borate, potassium borate, etc. can be suitably selected from commercially available reagents, industrial chemicals, etc. it can.

  In the preparation of the binding liquid composition by the water glass method, when the solid or liquid alkali silicate is less than 50 parts by mass with respect to 100 parts by mass of water, a value satisfying the strength of the formed cured body. Cannot be obtained. When the amount of the solid or liquid alkali silicate is more than 200 parts by mass, the mortar of the obtained water-containing composition does not have plasticity or fluidity, and the workability of the treatment tends to be difficult.

  In addition, when the blending amount of the oxyacid salt of alkali metal sulfur, phosphorus, carbon or boron alone or two or more combined elements previously dissolved in the binding liquid composition is less than 1 part by mass, The formation of new hydrated minerals formed from dissolved sulfur, phosphorus, carbon or boron oxyacid ions cannot be expected, and water-resistant water-insoluble hydrated minerals are not contained within the silica polymer network matrix. It is not expected that the matrix matrix is newly deposited and reinforced and improved.

  As a means for preparing the binding liquid composition of the present invention by a silicate method, 80 to 140 parts by mass of water and 2 to 4 parts by mass of sodium ion in terms of sodium oxide are used with respect to 100 parts by mass of easily reactive silicates. To prepare a liquid silicate alkali composition mainly composed of sodium silicate having an alkali silanol group and reacted at least at room temperature with mixing and stirring, and then the liquid silicate alkali composition 100 Modified silicate alkali composition by adding 1 to 40 parts by mass of an alkali metal salt of oxyacid of sulfur, phosphorus, carbon or boron alone or in combination of two or more with respect to parts by mass A means system prepared as a binding liquid composition comprising a product is preferred.

  In the means for preparing the binding liquid composition of the present invention by the silicate method, the easily reactive silicates are incineration ash of general / industrial wastes, incineration ash of papermaking wastes, and phosphorus-containing materials that have received a heat history. Incineration ash of sewage sludge / agricultural settlement drainage sludge, coal ash discharged during thermal power generation, slag or Portland cement discharged during iron and steel making, and layered clay minerals and rocks of crystalline minerals, low crystals / amorphous minerals or Silicates composed of active silicates selected from the group of volcanic products are used alone or in combination of two or more. In addition, the sodium ion adopted in means 2 for preparing the binding liquid composition of the present invention can be generally prepared by selecting sodium hydroxide caustic soda and dissolving it in water. Of course, sodium ions can be prepared by dissolving various sodium salt compounds in water, but it is not preferable because of generally poor reactivity.

  In the means for preparing the binding liquid composition of the present invention by a silicate method, the preparation of a liquid silicate alkali composition containing sodium silicate having an alkali silanol group as a main component is a highly reactive silicate. It can be prepared by adding 80 to 140 parts by mass of water and 2 to 4 parts by mass of sodium ions in terms of sodium oxide based on 100 parts by mass and reacting at least at ordinary temperature with mixing and stirring. Of course, when the readily reactive silicates are aluminosilicates or other silicates, the prepared liquid composition is not a clear liquid composition but is recovered as a slurry-like composition leaving undissolved components. . However, even if a slurry-like liquid composition in which an insoluble component remains is adopted as the water-containing composition of the present invention, it does not give any special adverse effect to the effect and action of the water-containing composition of the present invention.

  In the means for preparing the binding liquid composition of the present invention by the silicate method, in order to prepare the binding liquid composition from the prepared liquid silicate alkali composition, 100 parts by mass of the liquid silicate alkali composition is added. On the other hand, it possesses oxyacid ions of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements dissolved by adding 1 to 40 parts by mass of an alkali metal sulfur or phosphorus oxyacid salt. A liquid composition comprising a modified silicate alkali composition can be prepared. In this case as well, in the same manner as in the water glass system described above, the amount ratio of the alkali metal sulfur or phosphorus oxyacid salt dissolved in the liquid silicate alkali composition has the same effect and action. appear.

  Reactive powder composition that plays the role of a curing agent and exhibits the function of fixing / binding / curing / water resistance of the water-containing composition to the binding liquid composition constituting the basic water-containing composition of the present invention Incineration ash for general and industrial waste, incineration ash for papermaking waste, incineration ash for phosphorus-containing sewage sludge / agricultural settlement wastewater sludge, coal ash discharged during thermal power generation, slag discharged during steelmaking and steelmaking Mainly composed of laminar clay minerals, low crystalline / amorphous silicates, volcanic eruptions, aluminosilicate compounds with active calcia possessed by one or a combination of two or more selected from the group consisting of eco-cement and portland cement The content of coexisting water (inclusion water, adsorbed water, contained water, etc.) is 10% by mass or less, and the particle size is in the range of 5 μm to 1 mmφ, and is in a substantially granular state. For binding liquid composition of It is preferably composed of a granular material made of alkaline silicates that exhibit a hardening function by a hydraulic activation function.

  In particular, the reactive powder composition constituting the basic water-containing composition of the present invention is mainly composed of an aluminosilicate compound, but it is important that the aluminosilicate compound has an active calcium component. If necessary, an active calcium component can be added to the aluminosilicate compound. Since the aluminosilicate compound of the reactive powder composition of the present invention has an active calcium component, the binding liquid composition in which the active calcium component constitutes the basic water-containing composition. It becomes possible to promote the dehydration condensation of the silanol groups possessed by the catalytic action.

  In addition, the granular material based on the active calcium-bearing aluminosilicate compound of the reactive powder composition of the present invention is selected from the group of cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine or manganese. In some cases, a harmful element group of a single or a combination of two or more types may be present at a concentration of at least 15 mg / kg. Therefore, there is no problem in adopting the reactive powder composition of the present invention.

  It is important that silicates mainly composed of an aluminosilicate compound constituting the reactive powder composition of the present invention contain a calcium component. In particular, the aluminosilicate compound contains at least 10% by weight, preferably 15% by weight or more of the calcium component, effectively exerts the curing function in the water-containing composition, and the formed cured body has water resistance. It is important for granting. Therefore, when the content of the calcium component in the selected aluminosilicate compound is small, it is effective to supplement the calcium component separately.

  The active powder that is an alkaline aluminosilicate compound constituting the reactive powder composition of the present invention preferably has a particle size in the range of 5 μm to 1 mmφ. When the powder particle size is smaller than 10 μφ, it is not preferable because the specific surface area of the powder is generally increased and the amount of water absorbed is increased, which impairs the fluidity of the prepared water-containing composition. On the other hand, when the particle size of the granular material is larger than 1 mmφ, the reaction surface necessary for the curing mechanism possessed by the granular material is decreased, and it is difficult to obtain a cured product having hardness. However, when the aggregate effect is obtained in addition to the original function in the reactive powder composition added to the water-containing composition of the present invention, an aluminosilicate compound can be adopted in the range of a particle diameter of 5 mmφ. .

  Furthermore, in order to provide a pollution-free water-resistant treated body formed from the binding liquid composition and the reactive powder composition of the present invention at a low price, the necessary aluminosilicate compound is selected from wastes. It is also preferable from the standpoint of recycling waste. However, since wastes that are aluminosilicate compounds generally contain a group of elements including harmful water-eluting heavy metals, aluminosilicate is a waste that coexists with harmful water-eluting elements. When selecting a salt compound, it is necessary to provide the product to the market in a state that passes the environmental standards indicated in the waste disposal method and the like. Therefore, in the present invention, the water-containing composition of the present invention is prepared under conditions that allow the coexisting harmful water-eluting elements to be formed by incorporation into a sodium aluminosilicate salt or fluoroapatite mineral that is a water-insoluble mineral. It is preferable that

  Furthermore, since the ionic alkali metal element coexists in the water-containing composition of the present invention, there is a tendency to shift the pH value of the originally formed cured product to a high range. However, in the water-containing composition of the present invention, since the aluminosilicate compound takes in an alkali metal element to form a water-insoluble alkali salt of aluminosilicate, the pH value of the pollution-free water-resistant treated body to be formed is adjusted. A low alkalinity of less than 10 can be ensured.

  In addition, the active alkaline reactive powder composition constituting the water-containing composition of the present invention forms a water-insoluble mineral and contains a group of hydrated minerals such as calcium-based silicate, aluminosilicate, sulfate, and the like. It is also important as a raw material to be formed. The hydrated mineral group formed here is deposited on a network structure composed of a polysiloxane-bonded silica polymer formed from the binding liquid composition constituting the binding liquid composition of the present invention. Thereby, it becomes possible to give predetermined | prescribed hardness with respect to the pollution-free water-resistant processed body formed by this invention.

  The mixing ratio in the basic water-containing composition of the present invention is that the reactive powder composition is added in an amount of 50 to 140 parts by mass with 100 parts by mass of the binding liquid composition, and homogeneous mixing is performed. It has been prepared as a slurry-based basic water-containing composition that exhibits at least a fixing, binding, curing, and water-resistant treatment function at room temperature, and a reactive powder composition with respect to 100 parts by mass of the binding liquid composition. When the amount is less than 50 parts by mass, formation of the hydrated mineral group is reduced, and formation of a strong matrix cannot be expected. In addition, sodium ions are not sufficiently fixed, and it is not possible to form a low-alkaline cured / solidified body.

  Further, when the reactive powder composition is more than 140 parts by mass with respect to 100 parts by mass of the binding liquid composition, the formation of the silica polymer that forms the skeleton of the formed cured / solidified body is not sufficient. Therefore, it is not possible to expect the formation of an integrated and strong matrix matrix having water resistance in the cured / solidified body. In particular, when expecting a slurry having a fluidity secured to the basic water-containing composition of the present invention, sufficient consideration should be given to the amount ratio as well as its type in the formulation of the reactive powder composition that is a particle-to-component. I need to pay.

  Furthermore, it is preferable that the basic water-containing composition of the present invention has a slurry-like excellent fluidity and a sufficient working life in the series of working steps of the present invention. However, when the reactive powder composition is more than 140 parts by mass in order to ensure the slurry-like flowability, it is not preferable because the flowability of the water-containing composition tends to be impaired. In addition, when increasing the amount of water added to the binding liquid composition in order to ensure the flowability of the basic water-containing composition of the present invention, it is desirable to form a strong treated body. This is not preferable.

  Of course, the basic water-containing composition composed of the binding liquid composition and the reactive powder composition of the present invention is prepared by previously packing the necessary binding liquid composition and the reactive powder composition into one pack. It is also possible to keep it. However, the one-packed water-containing composition at this time needs attention because the stability of securing the liquid state is limited in time. Therefore, in the water-containing composition of the present invention, the binding liquid composition and the reactive powder composition, which are constituent compositions, are individually brought to the construction site, and the binding liquid composition and the reactive powder at the construction site. It is necessary to prepare a water-containing composition by homogeneously mixing with the composition, and to perform on-site construction.

The composition specific gravity of the basic water-containing composition of the present invention is generally in the range of 1.10 to 2.00 g / cm ³ , has excellent fluidity, is alkaline with a pH value of 10 or more, This is preferable for ensuring a stable liquid normal state. The specific gravity of the basic water-containing composition of the present invention is in the range of 1.10 to 2.00 g / cm ³ and the alkalinity having a pH value of 10 or more is ensured. In order to form the treatment, sufficient work pot life is ensured, and the shape treatment of the treated body of the present invention with the water-containing composition of the present invention can be utilized based on the smooth flowability, It is preferable because a labor-saving processing means can be adopted.

[Functional water-containing composition]
In the water-containing composition of the present invention, on the basis of the slurry-like basic water-containing composition shown above, the performance characteristics and construction workability of the water-containing composition are variously expanded depending on the application, purpose, environment, etc. Sex is required. In order to meet these demands, a composition with expanded functionality in the water-containing composition can be selected. As a composition with expanded functionality, the basic liquid composition of the present invention and a slurry-based basic water-containing composition composed of a binding liquid composition and a reactive powder composition are given functions. A juice-like functional water-containing composition mixed with a raw material group and homogeneously mixed can be selected as the enlarged composition. Furthermore, in the present invention, a mortar-shaped composite water-containing composition obtained by adding a composite additive material group to a slurry-based basic water-containing composition or a juice-like functional water-containing composition and mixing them homogeneously is used as an expanded composition. You can choose.

  In the juice-like functional water-containing composition of the present invention, the functional water-containing composition is prepared as a water-containing composition by adding a function-providing material group to the slurry-based basic water-containing composition and mixing and mixing them uniformly. The The functional material group that is added to the basic water-containing composition includes a potassium composition that replenishes alkalinity, a sulfate composition that improves the reinforcing property of the cured body, and a phosphorus that improves the curing function and immobilizes fluorine. Acid salt composition, carbonate composition that improves the reinforcing property and water resistance of the cured body, barium salt composition that can adjust the working life, aluminum / iron salt composition that is a compound of aluminum or iron, formation hardening It may be a buffering zone forming composition that imparts buffering properties to the body, or a functional imparting material group that is selected from the group of functionalizing compositions that impart filling properties and coloring / pigment properties. preferable.

［式中；ｗは零を含む２以下の数］で表される酸化カルシウムまたは水酸化カルシウムの群より選ばれる単独ないし２種の組み合わせカルシウム化合物からなるカルシヤ成分を酸化物規準で表して５０質量％以上含有している機能付与素材群におけるカルシウム補充成分として好適に挙げることができる。As the calcia composition constituting the functional material group in the functional water-containing composition of the present invention, the following composition formula (3)

[Wherein w is a number of 2 or less including zero] 50 parts by mass of a calcium component consisting of a single or two kinds of combined calcium compounds selected from the group of calcium oxide or calcium hydroxide represented by the oxide standard % As a calcium supplement component in the function-providing material group containing at least%.

  Calcium (calcium lime: calcium oxide), which is representative of the calcite composition, reacts violently with water and generates a large amount of heat (15540 cal. Per mole), so handling it with great care. In addition, a single product made of calcium oxide and hydroxide reacts sensitively with carbonic acid and water in the air and changes to carbonates and hydroxides, impairing the storage stability of the treated product. Therefore, it is necessary to pay sufficient attention to blending with the treatment material of the present invention.

  In addition, a calcium compound representing a calcium composition generally has a coexistence of calcium element and alkaline earth metals magnesium, zinc, strontium, barium element, etc. which are homologous elements on the periodic table. As long as it is mixed in an amount of 10% by mass or less, the basic chemical reaction of the present invention and the specified functional effect are not impaired.

  Specific examples of the calcium composition include calcium oxide (quick lime) or calcium hydroxide (slaked lime) mainly composed of natural, synthetic, and by-product calcium. The calcite composition, calcite, is produced in large quantities as quick lime by decarboxylating calcium carbonate such as limestone in a hot atmosphere of about 950 ° C or higher. Steel, chemical industry, paper, building materials, fertilizer, agricultural chemicals, soil improvement It is used in a wide range of fields such as low cost and easy to obtain.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒはアルミニウムまたは３価の鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金蔵元素の硫黄のオキシ酸塩化合物の塩基性塩または正塩の群より選ばれる単独ないし２種以上の組み合わせの化合物からなり、中性ないしアルカリ性の機能付与素材群として補強性を向上せしめる補助的成分として挙げることができる。As a sulfate composition constituting the functional material group in the functional water-containing composition of the present invention, the following composition formula (4)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. Or a combination of two or more kinds of compounds selected from the group consisting of a basic salt and a normal salt of a sulfur oxyacid salt compound of a metallurgy element represented by the formula: It can mention as an auxiliary | assistant component which improves reinforcement property as a provision raw material group.

  In particular, the sulfate composition adopted as an auxiliary component to be added to the functional water-containing composition of the present invention is sulfur based on sulfates of alkali metal, alkaline earth metal, aluminum or iron oxyacids. Oxyacid ion-containing compounds or compositions. Specifically, a salt-type compound mainly composed of an alkali metal sulfur oxyacid salt which is widely used in industry, a gypsum type compound mainly composed of an alkaline earth metal sulfur oxyacid salt, Three types of alum-type compounds mainly composed of aluminum sulfate or iron sulfate can be preferably exemplified.

  In the binding liquid composition to which the sulfur oxyacid ion-bearing compound is added in the present invention, in particular, the ionic sulfur oxyacid ion via the added water is the thermal history of the reactive powder composition. It reacts with the calcium component in the active aluminosilicate compound to form gypsum, etc., improving the strength of the cured body formed and forming salts with added sulfur oxyacid ions. Alkali metal or aluminum or iron element is preferably released as an ion by the reaction of the calcium component and sulfur oxyacid ion, and reacts with the silicate aluminosilicate to form a water-insoluble mineral. .

  Specific examples of the sulfate composition suitably adopted in the present invention include, in general, reagents, industrial chemicals, prototypes, industrial chemicals, industrial materials, wastes, potassium sulfate, sodium sulfate, sodium sulfite. Calcium sulfate, calcium sulfite, magnesium sulfate, aluminum sulfate, iron sulfate, aluminum sulfate / iron, etc. can be preferably mentioned.

［式中：Ｇはナトリウム、カリウム、マグネシウム、カルシウム、バリウム、アルミニウム、亜鉛、チタン、ケイ素ならびに鉄の群の単独ないし２種以上の組み合わせの元素、ｄは１ないし８の数、ｔはＧ元素原子価÷２の数、ｗは零を含む１０以下の数］で表される各金属元素のリンのオキシ酸塩化合物の群より選ばれる単独ないし２種以上の組み合わせ化合物からなる機能性粉粒体の硬化機能を向上改善する補助的成分として、また系内に共存する水可溶性のフッ素成分をフルオロアパタイト鉱物として固定化せしめる補助的成分として挙げることができる。As the phosphate composition constituting the function-imparting material group in the functional water-containing composition of the present invention, the following composition formula (5)

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, zinc, titanium, silicon and iron, d is a number from 1 to 8, and t is a G element. Functional particle consisting of a single compound or a combination of two or more selected from the group of phosphorus oxyacid salt compounds of each metal element represented by the formula: valence ÷ 2 number, w is a number of 10 or less including zero] As an auxiliary component for improving and improving the hardening function of the body, and an auxiliary component for fixing the water-soluble fluorine component coexisting in the system as a fluoroapatite mineral.

  The surface hardness of the cured body prepared and formed by the self-horizontal surface forming mold by the functional water-containing composition of the present invention is set to ensure that the pencil hardness is H or more. This is effective as an accelerator for promoting the development of the strength of the cured body for improving the surface hardness of the cured body. In particular, depending on the construction site, a series of work process schedules and work environment, adding the phosphate composition to the alkali silicate silicate composition which is a constituent of the water-containing composition of the present invention is a preparation. This is effective in improving the surface hardness of the cured body while ensuring the workability and working life of the binding liquid composition.

  Further, the phosphate radical composition that is suitably added to the functional water-containing composition of the present invention is formed by neutralizing the alkaline constituents such as calcium and sodium, which are constituents of the binding liquid composition. It can play the role of adjusting the pH value of the cured product to be low. In particular, after the formation of zeolites, which are sodium aluminosilicates, the calcium content is fixed by the formation of calcium phosphate crystals, and secondary pollution to the environment due to elution of alkaline components can be avoided. Therefore, it is also effective in securing the formed solidified body with low alkalinity.

  Specific examples of the phosphate composition suitably adopted in the present invention include sodium phosphate, potassium phosphate, magnesium phosphate, calcium phosphate, barium phosphate, and aluminum phosphate among reagents or industrial chemicals. , Zinc phosphate, titanium phosphate, silicon phosphate, iron phosphate, zinc phosphate, (antimicrobial agent) and the like. Furthermore, in the phosphate radical composition of the present invention, after treatment with a phosphoric acid chemical widely used as a surface treatment agent (parkerizing treatment agent) for metal products (automobiles, vehicles, building materials, home appliances, etc.), industrial waste As a result, sludge containing a large amount of phosphate discharged as can be used effectively. Further, incineration ash such as phosphorus-containing sewage sludge and agricultural settlement drainage sludge in the active aluminosilicate compound adopted in the present invention can be expected to have the same effect.

［式中：ｆは１．０ないし８．０の数］で表されるリン酸ケイ素の群より選ばれる「リン酸分の除放性」を有するリン酸ケイ素を挙げることができる。Moreover, as a suitable phosphate radical composition that improves workability and coercive force, a powdered silicon phosphate exhibiting release properties in an alkaline solution can be exemplified. As a silicon phosphate suitable as an auxiliary component of the present invention, the following composition formula (10)

Examples thereof include silicon phosphates having a “release property of phosphoric acid” selected from the group of silicon phosphates represented by the formula: [wherein f is a number of 1.0 to 8.0].

［式中：Ｘはリン酸ケイ素１ｇを４規定苛性ソーダ溶液１００ｍｌ中に攪拌分散せしめ、Ｘは経過時間（分）、Ｙは４規定苛性ソーダ溶液中に溶出したリン酸（リンの酸化物）量（ｍｇ／１００ｍｌ）］で表され、リン酸ケイ素のリン酸分（リンの酸化物）溶出の初期溶出量（ｂ）が２００以下であり、式中ａに相当する平均加水分解速度定数ａが０．２以上の範囲にあるリン酸分の溶出状態をいう。The “release property of phosphoric acid” in silicon phosphate can be evaluated by the test method described below, and the following formula (1)

[In the formula: X is 1 g of silicon phosphate stirred and dispersed in 100 ml of 4N caustic soda solution, X is elapsed time (minutes), Y is the amount of phosphoric acid (phosphorus oxide) eluted in 4N caustic soda solution ( mg / 100 ml)], and the initial dissolution amount (b) of the phosphoric acid content (phosphorus oxide) of silicon phosphate is 200 or less, and the average hydrolysis rate constant a corresponding to a in the formula is 0 The elution state of phosphoric acid content in the range of 2 or more.

［式中：Ｍはアルカリ金属、Ｚはアルカリ土類金属、Ｒはアルミニウムまたは３価の鉄、ａ、ｂ、ｃは零を含む２０以下の数、ｎは２または３の数、ｗは零を含む２５以下の数］で表される金蔵元素の炭素のオキシ酸塩化合物の塩基性塩または正塩の群より選ばれる単独ないし２種以上の組み合わせの化合物からなる機能付与素材群によ処理硬化体の補強性と耐水性を向上せしめる補助的成分として挙げることができる。As the carbonate composition constituting the function-imparting material group in the functional water-containing composition of the present invention, the following composition formula (6)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. Treated with a functional material group consisting of a single or a combination of two or more selected from the group consisting of basic salts and normal salts of carbon oxyacid salt compounds of gold elements represented by It can be mentioned as an auxiliary component for improving the reinforcing property and water resistance of the cured product.

  Specific examples of the carbonate composition suitably adopted in the present invention include limestone, marble, calcite, aragonite, chalk, sorghum, stalactite, shellfish, coral, calcium carbonate, precipitated calcium carbonate, and calcium bicarbonate. Specific examples include dolomite, sodium carbonate, and sodium bicarbonate. In particular, shells such as scallops and oysters as a calcium carbonate raw material are a treasure house as a calcium component raw material. However, since the shell is mainly composed of calcium carbonate, it is left unusable and disposed of. Adopting this shell as a raw material of the mixed raw material of the present invention is effective in reusing the shell. Moreover, applying shellfish as raw material to solidify and recycle seabed waste, etc., improves the marine environment by recycling waste that must be disposed of (such as sludge) using seafood waste. It is very preferable to be able to do it.

  Further, in the function-providing material group of the present invention, a carbonate compound compounded can also be selected. For example, a combination of a carbonate-calcium compound, a carbonate-sodium compound, a calcium-containing compound, a combination of a carbonate-calcium compound and a sodium-containing compound, or a combination of a carbonate-sodium compound and a calcium-containing compound can be given. . In particular, we select limestone or shell powder that is a waste, and activate sodium hydroxide to react with the limestone or shell powder at room temperature to activate the limestone or shell by the action of alkali at room temperature. Can also be adopted.

［式中：ｅは４以下の数、ｗは零を含む１０以下の数］で表されるアルカリ溶液に可溶なバリウム塩の群より選ばれる単独ないし２種以上の組み合わせのバリウム塩化合物で調整されている機能付与素材群を作用付加型の作業可使時間を調整可能な補助的成分として好適に挙げることができる。The barium salt composition constituting the function-imparting material group in the functional water-containing composition of the present invention includes the following composition formula (7)

[Wherein, e is a number of 4 or less, w is a number of 10 or less including zero], or a barium salt compound of one or a combination of two or more selected from the group of barium salts soluble in an alkaline solution. The function-providing material group that has been adjusted can be preferably cited as an auxiliary component that can adjust the work-use time of the action addition type.

  The functional water-containing composition of the present invention is a material that can ensure sufficient workability to carry out construction work with sufficient fluidity according to the construction site, a series of work process schedules, and work environments. Usage time is required. As a curing retarder that enables maintenance of the pot life of the material that can sufficiently secure this work time, the function-containing water-containing composition of the present invention exhibits the fixing, binding and curing functions, and the work work conditions are The barium salt composition can be effectively selected to ensure sufficient.

  The adjustment function such as workability in the barium salt compound of the powder adopted as the barium salt composition of the present invention can be estimated by “the soluble content of barium ions in an alkali solution = BS”. “BS” can be evaluated by the following test method. “Method for testing soluble content of barium ions in alkaline solution” refers to barium in a collected solution obtained by filtering a sample solution obtained by stirring and dispersing 10 g of a barium salt compound in 100 ml of a 1N sodium hydroxide solution at 25 ° C. for 10 minutes. The amount of ions is measured as BaO, the amount of all barium elements in the sample barium salt compound converted to BaO is displayed in%, and the barium amount of BS is determined. In order that the binding liquid composition prepared by the binding liquid composition of the present invention has a workability adjusted by the barium salt composition and manages the formation of a cured product, the “of the barium salt composition” The “soluble matter BS in the alkaline solution” is preferably 10% or more. When the “soluble matter in the alkali solution” is 10% or less, it is not preferable because it becomes difficult to manage the workability of the mixture.

  In general, barium hydroxide or barium oxide, which is an industrial chemical, is suitable as a barium salt compound that satisfies the “soluble matter in an alkaline solution” and is inexpensive and easily available. However, barium silicate is effective as a barium salt compound as a barium salt composition that does not adversely affect the zeolites to be formed and can ensure a sufficient working life for the formation of zeolites. In particular, barium silicate as the barium salt composition is preferably such that e in the composition formula (5) is a number of 4 or more, and if the number is 4 or more, the activity of barium ions cannot be effectively used. Further, the number of w in the composition formula (5) is preferably 9 or less, and when the number is 9 or more, the storage stability of the barium salt compound is not ensured, and the object of the present invention cannot be achieved.

［式中；Ｔはケイ素、硫黄、窒素、リン元素群の単独ないし２種以上の組み合わせの元素、ｎは２ないし３の数、ｍは０．５ないし６の数、ｗは零を含む２８以下の数］で表されるアルミニウムないしは２価ないしは３価の鉄元素のオキシ塩化合物の群より選ばれる単独ないし２種以上の組み合わせからなるアルミニウム・鉄塩化合物ないしは組成物である粉粒体からなる機能付与素材群を好適に挙げることができる。特にアルミ・鉄塩組成物を本発明の機能付与素材群として、本発明の機能型含水組成物に加えるときは、系内に共存する水溶出性の有害なクロム、ヒ素ないしはフッ素群を固定化して水不溶性鉱物を形成する効果があることからも好ましい。As the aluminum / iron salt composition constituting the functional group-containing material group in the functional water-containing composition of the present invention, the following composition formula (8)

[Wherein T is an element of a single or a combination of two or more of silicon, sulfur, nitrogen and phosphorus elements, n is a number from 2 to 3, m is a number from 0.5 to 6, and w is zero. 28 From the aluminum or iron salt compound or composition comprising a single or a combination of two or more selected from the group of aluminum or divalent or trivalent iron element oxysalt compounds The function provision material group which becomes can be mentioned suitably. In particular, when an aluminum / iron salt composition is added to the functional water-containing composition of the present invention as a functional group of the present invention, the water-soluble harmful chromium, arsenic or fluorine group coexisting in the system is immobilized. This is also preferable because of the effect of forming a water-insoluble mineral.

  As a single compound or composition of an aluminum salt that constitutes an aluminum / iron salt composition that is preferably selected for the functionally imparted material group of the present invention, a readily reactive amorphous alumina, aluminum hydroxide, aluminosilicate Alkali-aluminum salt composition such as sodium aluminate prepared by dissolving salt, aluminum chloride, aluminum sulfate, aluminum nitrate, aluminum phosphate, aluminum borate, etc., and further dissolving metal aluminum or readily reactive alumina in caustic soda, etc. Furthermore, an aluminate composition such as calcium aluminate or alumina cement can be preferably mentioned.

  As the aluminate composition adopted in the present invention, the waste powder composition or the cement powder composition mentioned in the above-mentioned calcite composition, and the natural mineral powder group are easily reactive to alkali. A composite type aluminate composition containing at least 15% by weight of the aluminum-containing compound is selected and combined.

  The alkali-aluminum salt composition was prepared by adding 1 to 200 parts by weight of caustic soda on an oxide basis and 100 to 100 parts by weight of an alumina-containing compound, and adding water in the range of 1 to 200 parts by weight. In order to effectively form aluminosilicate or the like in the cured body, an alkali metal aluminate composition that has been subjected to a reaction treatment under conditions is suitable.

  As a single compound or composition of an iron salt that is preferably selected for the functionally imparted material group of the present invention, a divalent or trivalent iron hydroxide compound is particularly effective, and it is divalent or trivalent from the viewpoint of availability. Preferred examples include valent iron chloride, iron sulfate, and metal iron. These metallic iron components, iron chloride and iron sulfate react with the calcium composition blended in the functional water-containing composition of the present invention, and react with oxygen and moisture in the atmosphere to easily form an iron hydroxide compound. Further, it is possible to exert an auxiliary effect in the detoxification treatment for insolubilizing and immobilizing heavy metals, which is one of the functional functions required for the water-containing composition of the present invention.

  Furthermore, the aluminum / iron salt composition which is the functional group of the present invention includes a single compound or composition of the above-described aluminum salt and an aluminum / iron salt in which the single compound or composition of the iron salt is combined. The composition is easily available and can be suitably selected. In particular, as a composite aluminum / iron salt composition, minerals or clays co-containing natural iron / aluminum, and iron-containing bands that are commercially available as water treatment agents, etc. may be preferably mentioned. it can.

［式中：Ｍはリチウム、ナトリウムまたはカリウムのアルカリ金元素、Ｚはマグネシウム、カルシウムまたは亜鉛のアルカリ土類金属、ｇは１．０ないし４．０の数、ｗは零を含む１０以下の数］で表されるアルカリ金属またはアルカリ土類金属のホウ素のオキシ酸塩の群の単独ないし２種以上の組み合わせ金属のホウ素のオキシ酸塩化合物の機能付与素材群からなる形成処理体に緩衝性を付与する補助的成分として好適に挙げることができる。As the buffer zone forming composition constituting the function-imparting material group in the functional water-containing composition of the present invention, the following composition formula (9)

[Wherein, M is an alkaline gold element of lithium, sodium or potassium, Z is an alkaline earth metal of magnesium, calcium or zinc, g is a number of 1.0 to 4.0, and w is a number of 10 or less including zero. In the process of forming a body comprising a functional group of boron oxyacid compounds of a single or a combination of two or more kinds of boron oxyacid salts of an alkali metal or alkaline earth metal represented by the following formula: It can mention suitably as an auxiliary | assistant component to provide.

  In the cured body of the present invention, it is preferable to provide a buffer band so as not to leave distortion in the matrix of the cured body to be formed. In the cured body formed in the present invention, a silica polymer composed of a polysiloxane bond forms a basic matrix. The silica polymer, which is the basic matrix, basically consists of tetravalent silicon and divalent oxygen that are regularly arranged to form a polymer matrix. There is no room for the matrix structure, and there is no escape space for the generated strain energy. Distortion energy tends to accumulate more and more.

  Moreover, the silica polymer produced from the alkali silicate is dehydrated, so that the polymerized matrix shrinks, and the strain energy resulting from the shrinkage tends to accumulate in the cured body, which impairs the product's merchantability. , Tend to cause trouble that impairs product value. In order to eliminate the strain energy resulting from this shrinkage, it is effective to provide a buffer band by incorporating trivalent boron between silicon bonds.

  As the buffer band forming composition selected in the present invention, a boron-containing compound containing boron having a trivalent valence that is soluble in an alkaline solution and easily reactive with a siloxane bond that is a skeleton of a silica polymer Is preferred. Specifically, an alkali salt that is an alkali borate is suitable, and the alkali element is preferably potassium or sodium, and examples thereof include potassium borate and sodium borate. Since alkali borate is a powder, it is preferable to select from anhydrous salts, trihydrate, pentahydrate, heptahydrate, and hydrate. In addition, for example, boron oxide, boric acid, boron phosphate, zinc borate, calcium borate, zinc borate, aluminum borate and the like, which are industrial chemicals, can be preferably mentioned.

  Examples of the function-imparting composition in the functional water-containing composition of the present invention include a pigment, a colorant, and an activator composed of a powder having a particle size in the range of 1 μm to 1 mmφ. , Packing and dispersing agents, magnetic materials, catalysts, oxidizing materials, carriers, aggregating and separating agents, agricultural chemicals, herbicides, fertilizers, microbial nutrients, plant seeds and fungi, antimicrobial agents, water repellents, functional additives, etc. It consists of a compound or composition of a single or a combination of two or more selected from the group, and specific shapes include powder, sand, lump, needle, column, sphere, hollow, plate, flake, Preferred examples include functional powders that are deformed or have various shapes.

  Functionality-providing compositions in the present invention are materials and materials known and used in the industry, industrial chemicals, agricultural fertilizers and agricultural chemicals, reagent products, custom-made products, etc., and plastic processing, cement processing, wood processing, etc. Can be appropriately selected from the paints, adhesives, and various modifying treatment agents used in the above. However, the functionality-imparting composition adopted for the modification treatment agent of the present invention is not limited to the materials, raw materials, compounds or compositions described herein.

  As the pigment, all known and publicly used extender pigments in the industry can be adopted, such as carbon black, titanium oxide, silica fine powder (white carbon, etc.), fused silica, silicates and clays, alumina, Preferable examples include calcium carbonate such as fused alumina and shells, magnesium carbonate, and zirconium oxide. In addition, iron oxide (valve, etc.), iron hydroxide, iron chloride, chromium oxide, lead chromate (yellow lead, etc.), ultramarine, zinc oxide and zinc borate, calcined pigments of various metal oxides, inorganic colors Resistant to alkalinity of pigments, non-oxides, metals and alloys, and organic pigments (insoluble azo pigments, condensed polycyclic pigments, quinacridone pigments, isoindolinone pigments, cyanine blue, cyanine green, etc.) Preferred examples include pigment powder.

  As the colorant, in addition to the above-mentioned inorganic / organic pigments, various organic coloring compounds, various inks and natural / synthetic dyes that are known and used in the industry are used alone or in combination of two or more kinds. By selecting, it becomes possible to give a desired hue to the product.

  Preferred examples of the activator include aluminum phosphate, boric acid, various catalysts, photocatalyst titanium oxide, and waste phosphate sludge. Moreover, as a magnetic body of a functional provision composition, powdery bodies, such as a ferrite, iron oxide, chromium oxide, cobalt etc. which made the general iron oxide porcelain, can be raised. Examples of the special magnetic material include a powdered magnetic material made of a composite metal such as iron-boron, cobalt-boron, neodymium-iron, or neodymium-boron.

  As a filler dispersant, when it is selectively blended into a water-containing composition according to the purpose, application, and environment of the present invention, and molded into a predetermined shape corresponding to the purpose, the mixing dispersibility in the blended mixture is improved. In addition, when each composition used as a blending raw material contains water, it becomes an adsorption modifier for the water content, and improves the processing and construction workability as an admixture fluidity or plasticity improver of the water-containing composition. Convenient for

  The filling dispersion composition of the present invention is preferably an inorganic powder that is compatible with the water-containing composition. Also, it may be a powdery product such as a granular product that is produced in large quantities as a natural product, or discharged as wastes that coexist with harmful water-eluting heavy metals, and is easily available at low cost. It is desirable that it is a new material. As specific examples, generally for natural products, kaolin, acid clay, bentonite, bauxite, diatomaceous earth, talc, zeolite, lime powder, bauxite, perlite, gypsum, shell powder, silicate and volcanic ash group are selected as appropriate. Can be appropriately selected from waste gypsum, glass waste, blast furnace slag, coal ash, various incineration ash, inorganic adsorbent / support / medium, etc., selected as the material to be modified in the present invention.

  Since the above dispersion medium composition requires dispersibility, it is effective to use an inorganic compound of 100 μm or less, preferably a fine powder or fine powder particle of 10 μm or less, and particularly an inorganic compound silicic acid. The salt-based material can be cited as a suitable dispersion medium composition having good compatibility with the modifying agent of the present invention. Moreover, as the oil dispersion medium such as dioxins, lipophilic silicate materials are suitable, and smectite group acid clay and bentonite, which are layered clay minerals, and activated clay can be preferably selected. .

  Further, as pigment fillers, powdered diamond, glass, nitride, carbide, ceramic, ceramics, silicon oxide (silica stone, silica sand, silica hum, fused silica, etc.), rock (serpentine, andesite, meteorite, etc.) , Clay (kaolin, bentonite, gyrome, talc, mica, woody clay, etc.), calcined clay (kaolin, clay, etc.), gypsum, phosphorus ore, iron ore, manganese ore, shell, zircon sand, etc. Preferable examples include fillers in the form of powders such as flakes and fibers.

  Magnetic materials include rare earth sintered magnets that are hard magnetic materials, ferrite sintered magnets, bonded magnets, cast magnets, sintered silicon steels that are semi-rigid or soft magnetic materials, PB and PC based sintered bodies, Oxide soft magnetic material or magnetic stainless steel, which is hard or soft ferrite, and metals such as iron, nickel, cobalt, etc., and composite alloys, etc. Magnets, plastic working magnets, ferrite magnets, rolled magnets, bonded magnets, cast magnets, or metal soft magnetic materials that are soft magnets, oxide soft magnetic materials, sintered soft magnetic materials, amorphous soft magnetic materials, nanocrystals You can choose from soft magnetic materials.

  Catalysts include platinum, palladium, nickel, zinc, iron, silver, copper, and other metals or alloys, and chromium, iron, zinc, molybdenum, selenium, cesium, copper, etc. Salts, etc., and zeolites, aluminosilicates and various minerals can be mentioned.

  As oxidants, chlorates such as potassium chlorate, sodium chlorate, ammonium chlorate, parium chlorate, calcium chlorate; perchlorates such as potassium perchlorate, sodium perchlorate, ammonium perchlorate ; Inorganic peroxides such as potassium peroxide, sodium peroxide, calcium peroxide, magnesium peroxide and barium peroxide; chlorites such as potassium chlorite, sodium chlorite and copper chlorite; bromine; Preferable examples include bromates such as potassium acid, sodium bromate, and magnesium bromate; and nitrates such as ammonium nitrate, sodium nitrate, potassium nitrate, parium nitrate, and silver nitrate.

  Further, iodates such as potassium iodate, sodium iodate, calcium iodate; permanganates such as potassium permanganate, ammonium permanganate; sodium dichromate, ammonium dichromate, etc. Dichromates; sodium periodate, metaperiodate, chromium dioxide, lead dioxide, sodium nitrite, potassium hypochlorite, sodium hypochlorite, potassium peroxodisulfate, sodium peroxodisulfate, ammonium peroxodisulfate, Preferable examples include potassium peroxoborate and ammonium peroxoborate.

The carrier is particularly selected from the group consisting of charcoal, activated carbon, amorphous silica, diatomaceous earth, activated silicic acid, activated alumina, zeolite or various incineration ash having a surface area of 10 m ² / g or more. Preferable examples include powders having adsorptive or supporting properties and moisture-adjusting functions composed of a combination of more than one species. In particular, the carrier supports and absorbs highly reactive sodium hydroxide or the like blended with the present modification treatment agent in advance on the support adsorbent composition to ensure the powder properties of the modification treatment agent. It is effective for exhibiting the processing function. Further, it is important to release the highly reactive sodium hydroxide and the like to be released from the reaction system and to effectively participate in the formation of zeolites without being released.

  Specific examples of the carrier include animals and plants containing various organic compounds and organic materials, and natural products and wastes collected, produced and processed in the fields of agriculture, livestock and fisheries, In addition, products produced by fermentation of various natural materials, fermentation residues, wastes produced by manufacturers and processors of paper, pulp, and textile fabrics, as well as various plastics and organic materials emitted from their processing sites, etc. Preferable examples include charcoal mainly composed of charcoal recovered by dry distillation at 400 to 1000 ° C., and a charcoal-silicate composite containing silica or alumina having adsorption performance. .

  By attaching and consolidating the above granular materials having porous pores with conventional organic adhesives, etc., it is intended to form granules and molded / structured bodies that are easy to use and handle Sometimes, the coexisting harmful substances can not be detoxified, and the adsorptive porous pores of the powder are crushed and cannot be used as an adsorbent, It has been difficult to process the adsorbent particles into easy-to-handle granules and molded / structured bodies.

  In particular, when selecting a water-containing mud composed of sludge or sediment with a high water content as the material to be modified according to the present invention, dehydrating the water retained in the water-containing mud is a non-polluting process that is formed. It is preferable when the mold modifying treatment agent is recovered as a solidified body, and in order to reduce at least the water content ratio that also serves as a dehydration treatment, a carrier having high water absorption is blended in advance in the water-containing composition. preferable.

  As a granular material that acts as a moisture adjusting agent that adsorbs and adjusts the moisture contained or liberated in the water-containing body employed in the present invention, the water-adsorbing and inclusion properties are high, the pore volume is large, or Inorganic powders with a large specific surface area, such as various silicate incineration ash, dried clay, zeolites, silica gel, alumina gel, aluminum silicate compound fouling, lime, calcined gypsum, calcium chloride, etc., or water An acrylic resin powder having high adsorptivity can be preferably used.

  As an aggregating / separating agent, water-dispersed particles, materials that agglomerate algae (blue water, etc.) and hydrous particles, and agglomerate-precipitating agents and algae are also inorganic systems that do not contain aluminum sulfate (sulfate band) ferric chloride, polychlorinated There are aluminum (PAC) and the like, and an organic synthetic polymer compound such as acrylic or polyester is preferable.

  Examples of the agrochemicals, herbicides, fertilizers, and microbial nutrients include agricultural chemicals, herbicides, fertilizers, and microbial nutrients that are generally used and adopted in fields such as agriculture and horticulture. In particular, when adopting detoxification treatment in soil ground, farmland or ground improvement areas, etc., it is also possible to improve the soil such as farmland and ground improvement areas, and at the same time provide the effects of fertilization, weeding, insecticide, etc. It is preferable to add and supplement fertilizers, microbial active nutrients, and the like to the modified treatment agent of the present invention.

  As plant seeds and fungi, when the modifying agent of the present invention is adopted for detoxification treatment in soil ground, especially farmland and ground improvement areas, etc. In order to simultaneously impart the effects of breeding and overgrowth, it is preferable to previously add and blend plant seeds and fungi according to the land environment and purpose of use in the present modification treatment agent.

［式中：Ｄは１価または２かの銀、銅、亜鉛もしくはニッケル元素、Ｔはカルシウム、マグネシウム、ホウ素、アルミニウム、炭素、ケイ素、リンもしくは硫黄元素、Ｖは零を含む３．５以下の数、ｗは零を含む２４．０以下の数、ｙは０．５ないし１．０の数、ｘは０．５ないし３．０の数］で表される銀、銅、亜鉛、ニッケル元素の塩でカルシウム、マグネシウム、ホウ素、アルミニウム、炭素、ケイ素、リン、硫黄元素のオキシ酸塩化合物の群の単独ないし２種以上の組み合わせ抗微生物剤を好適に挙げることができる。As an antimicrobial agent, the following composition formula (11)

[Wherein D is a monovalent or bivalent element of silver, copper, zinc or nickel, T is an element of calcium, magnesium, boron, aluminum, carbon, silicon, phosphorus or sulfur, and V is 3.5 or less including zero. Number, w is a number of 24.0 or less including zero, y is a number of 0.5 to 1.0, x is a number of 0.5 to 3.0], silver, copper, zinc, nickel element Preferred examples of the salt include a single group or a combination of two or more types of oxyacid salt compounds of calcium, magnesium, boron, aluminum, carbon, silicon, phosphorus, and sulfur elements.

  As the water repellent, a liquid water repellent such as a silane compound, organosiloxane, organopolysiloxane, etc. having water repellency, and a fluorine-based compound was previously supported on the inorganic adsorbent support. A powdery body having water repellency can be suitably adopted. Organosiloxanes include silane compounds having X groups (amino groups, epoxy nobles, methacryloxy groups) that can react with organic resins with so-called silane coupling agents and silanol groups that can be fused with inorganic materials, modified silane compounds or polymers Suitable organopolysiloxanes can be mentioned.

  Furthermore, as other functional additives, various conventionally known and publicly used various function-imparting agents can be mentioned. Specifically, buffer zone forming agent, rust preventive agent, foaming agent, antifoaming agent, heavy metal insolubilizing material, heavy metal immobilizing material, antioxidant, anti-slip agent, water absorbing agent, anti-condensation agent, snow melting agent , Freezing and thawing agent, water treatment agent, blocking agent, preservative, phosphorescent agent, swelling agent, adsorbent, incombustible / flame retardant, color former, fuming agent, foaming agent, ultraviolet / near infrared / infrared absorber, red Outside / far infrared ray generator, radiation generator, illuminant, photocatalyst, oxidizing agent, reducing agent, explosive, detonator, elastic body, thermal conductor, conductor, dielectric, antistatic agent, electromagnetic wave absorption / shielding Agents, insulating materials, deodorants, deodorants, fragrances, fragrances, surfactants, repellents, various active agents, and the like.

  The functional group-containing material group constituting the functional water-containing composition of the present invention includes a calcium composition, a sulfate composition, a phosphate composition, a carbonate composition, a barium salt composition, an aluminum / iron salt composition, and a buffer. It is said that it is preferable to be a granular composition composed of a function-providing material group composed of a single or a combination of two or more selected from the group of a band-forming composition and a function-imparting composition. Therefore, in the present invention, not only the respective function imparting material groups can be adopted alone but also in a plurality of combinations.

  As the function-imparting material group to be adopted in a plurality of combinations in the present invention, for example, according to the purpose and application of the present invention, a combination of a plurality of powder composition that is a function-imparting material group, respectively, or as necessary A granular composition in which a plurality of components are reacted in advance or combined to form a composition can be suitably adopted.

  In the present invention, as a group of function-providing materials of a plurality of combinations, for example, an active gypsum group in combination with a sulfate composition that is mirabilite and a carbonate composition that consists of calcium carbonate such as shellfish and limestone. It is also possible to prepare a function-providing material group that exhibits an inexpensive filler effect comprising a combination of sodium salts.

  Furthermore, in the present invention, a function-providing material group formed by reacting the binding liquid composition and the powder composition that is the function-providing material group in advance may be adopted. For example, when a carbonate composition composed of calcium carbonate such as shellfish or limestone and a binding liquid composition composed of alkali silicate having an acid root are mixed in advance, calcium carbonate such as inert limestone is mixed. When activated, the water-containing composition tends to sufficiently exhibit the functionality of fixing, binding, curing, and water resistance at room temperature.

  In the functional water-containing composition of the present invention, the mixing ratio of the functional material group to the basic water-containing composition is 1 to 300 parts by weight of the functional material group with respect to 100 parts by weight of the slurry-based water-containing composition. It is preferable to prepare a juice-like functional water-containing composition that is homogeneously mixed by adding two members in a ratio and exhibits a function of fixing, binding, curing, and water resistance at least at room temperature. Of course, depending on the type, content, amount, etc. of the constituents of the function-imparting material group, the minimum conditions for the construction work of the obtained water-containing composition, the properties and characteristics of the treatment body formed from the water-containing composition, Within the scope of the present invention, it is necessary to confirm by conducting preliminary experiments as necessary.

In particular, when a mortar-like water-containing composition or a functional water-containing composition having a high fluidity capable of securing a horizontal plane within 2 minutes is required, the liquid specific gravity constituting the basic water-containing composition or the functional water-containing composition is 1.10. To 2.40 g / cm ³ , a pH value of 10 or more, and a treatment function that exhibits a detoxification treatment and a non-re-mudging treatment by being shaped through water at least at room temperature. It is preferable that the reactive powdery composition with respect to the binding liquid composition and the functional material group are selected and mixed homogeneously so as to exhibit the above.

  Further, as the functional water-containing composition of the present invention, the function-providing material group added to the basic water-containing composition was further formed with the construction work conditions required for the water-containing composition, and the purpose / use of the cured body. Select the type, contents, amount, etc. of the functional material group to be blended according to the work schedule, such as the properties and characteristics required for the treatment body, the status, environment and conditions of the construction work site, etc. It is necessary to confirm by conducting a preliminary experiment.

[Composite water-containing composition]
The mortar-like composite water-containing composition of the present invention is homogeneously mixed and mixed with the basic water-containing composition of the present invention by adding a functional material group as necessary and further adding a composite additional material group. It is preferable that the mortar-like composite water-containing composition is prepared. As a composite additive material group added to the composite water-containing composition of the present invention, effects such as filling properties, pigment properties, dispersibility, activity or moisture control properties with a particle size in the range of 3 μm to 1 mmφ are imparted. A composite additive material group composed of a single or a plurality of combinations of a bone material composition that provides a composite action effect such as reinforcement as a filler material composition or an aggregate having a particle size in the range of 1 to 7 mmφ. Can be selected according to the purpose, application, workability and the like.

  It is a composite additive material group constituting the composite water-containing composition of the present invention, and the filler material composition having a particle size of 1 mmφ or less is a dry product or a wet product containing moisture within a range of 50% by mass. Yes, minerals / rock crushed stones / sands / clays, ceramics / baked goods, carbonized products / charcoal, glass / volcanic products / slag / incinerated ash silicates, gypsum / hardened cement, bottom sediment / sludge -Sludges, inorganic oxides, metals, wood, bamboo, plants, cereals, leather, bone, organic matter, plastics, rubber, synthetic and purified chemicals, or single or two or more waste materials A group of function-providing materials in the form of powder, small lump, sand, fiber, or flake made of a combination composite material can be preferably mentioned. Of course, even if the function-added material group, which is a composite additional material group, is in a slurry state where it is in a water-containing state as long as the fluidity of the composite water-containing composition is not impaired, it does not matter.

  In particular, specific examples of the filler material composition suitably adopted for the composite additive material group of the present invention include filling property, pigment property, dispersibility, activity, reinforcing property, catalytic property, supportability, moisture adjustment. Diamonds, nitrides, carbides, ceramics, ceramics, silicates (silica, silica sand, silica hum, fused silica, etc.), ores (serpentine, andesite, meteorite, limestone, gypsum, phosphorus ore, Iron ore, manganese ore, zircon sand, iron sand, etc.), clay (kaolin, talc, bentonite, acid clay, caustic clay, zeolite, gyrome, talc, mica, bauxite, woody clay, etc.), calcined clay (kaolin, clay, etc.) ), Wastes mainly composed of silicate, a heat history silicate (waste gypsum, glass waste, coal ash, incineration ash of coal, sewage sludge, organic materials, blast furnace and steel making) Rug), volcanic ash and lava volcanic products, ceramic waste or silicate glass, shells, organic matter, etc., as appropriate from the group of materials in powder, small granular, massive, sand granular, fibrous, etc. You can select and adopt.

  The above-mentioned filler material composition requires filling properties, pigment properties, dispersibility, activity or moisture control properties, etc., so that the granular material has a particle size of 100 μm or less, preferably 50 μm or less. It is effective to be an inorganic compound of powder particles. In particular, a silicate material of an inorganic compound can be mentioned as a filler material composition having a good compatibility with the water-containing composition of the present invention and suitable as a dispersion medium. In addition, as a dispersion medium for oil such as dioxins, a lipophilic silicate material is suitable, and a filler material composition comprising a smectite group acid clay or bentonite, which is a layered clay mineral, and activated clay. Can be preferably selected.

  Therefore, in order to make the water-containing composition of the present invention exhibit the decomposition technology of dioxins and the like disclosed in the prior application techniques of the inventors (Patent Documents 16 and 17), the lipophilic dioxins and the like are dispersed in oil. It is preferable to add a silicate-based material such as acidic clay effective for properties to the water-containing composition of the present invention, which is effective for the decomposition of dioxins and the like.

  The composite additive material group constituting the composite water-containing composition of the present invention, and the bone material composition having a particle size in the range of 1 to 7 mmφ includes minerals, rock crushed stones, sands, clays, ceramics, Ceramics, carbonized products, charcoal, silicates of glass, volcanic products, slag, incinerated ash, gypsum, hardened cement, sediment, sludge, sludge, inorganic oxides, metals, wood, bamboo, Plants, grains, skins / bones, organic substances / plastics / rubbers, synthetic / refining chemicals or wastes, single or single combination of two or more, spherical, granular, block, plate, Preferred examples of the functional material group are sand, chip, flake, fiber, specific shape, and non-specific shape.

  In particular, an inorganic aggregate is generally used as a bone material composition that is preferably selected as a composite additive material group of the present invention, and a specific example of an inorganic aggregate is a sea material that is a natural aggregate.・ Used from river / mountain sand, gravel, pumice and volcanic product sand, crushed stone as artificial aggregate, granulated products of silicates such as blast furnace slag, incineration ash, and concrete waste as recycled aggregate Preferred examples include natural aggregates and artificial aggregates.

Furthermore, as a bone material composition to be adopted for the composite additive material group of the present invention, the bulk specific gravity is in the range of 0.8 to 2.0 g / cm ³ and the aggregate particle size is in the range of 0.1 to 3 mmφ. Artificial lightweight aggregates or by-product lightweight aggregates, such as sintered aggregates, and fired products such as volcanic gravel, expanded shale, expanded clay, expanded slag, coal ash, etc., which are natural and artificial lightweight aggregates, An inorganic lightweight fine aggregate made of pearlite, vermiculite or the like can be preferably exemplified.

  The inorganic lightweight fine aggregate adopted in the present invention generally has pores having a specific surface area, and in order to prepare the water-containing composition intended in the present invention, the pores possessed by the granular material In order to ensure fluidity, it is important that the powder is previously filled with water or the like and modified into a wet granular material. It is preferable that the pores of the granular material are filled with water or the like in advance because it is not necessary to waste the alkali silicate having a binding effect through the pores of the aluminosilicate compound.

  Still further, as the bone material composition to be adopted for the composite additive material group of the present invention, the organic powder as an organic lightweight fine aggregate is made of plastics, waste plastics or old tires, and has a particle size of 0. An aggregate group in which chips are inserted in the range of 1 to 4 mmφ can be preferably cited. Specific examples of the organic particulate material that can be preferably cited include plastics that are made into chips. In particular, acrylic resins, polyurethane resins, phenol resins, melamine resins, polyester resins, epoxy resins, urea resins and the like that are polymer resins and thermosetting resins can be given.

  Furthermore, thermoplastic resins such as vinyl chloride resin, polyethylene, polypropylene, polystyrene, polyamide, polycarbonate, ABS resin, acrylic fiber, polyacetal, fluororesin, polyvinylidene chloride, polyptadiene, and synthetic fibers such as nylon, vinylon, acrylic fiber, rayon Etc., such as polyisoprene and butadiene which are synthetic rubbers. Furthermore, as plastics that are organic powder particles, the powder particles that are made into chips in the range of 0.1 to 3 mmφ in aggregate particle size made of waste plastics or old tires are particularly lightweight. It is also preferable to make it.

  Of course, the plastics which are these organic polymer compounds in the present invention do not have to be individual products, and the plastics may be combined or reinforced. Furthermore, in the present invention, the plastics that are organic polymer compounds may be waste plastics or used tires that are used wastes of plastics. Thus, when selecting waste plastics, old tires, etc. as materials, it is preferable from the standpoint of recycling waste plastics, old tires, etc.

  Moreover, the plastics, waste plastics and old tires preferably adopted in the present invention are preliminarily molded or pulverized / classified into a granular body or chip body having a particle diameter in the range of 0.1 to 3 mmφ. It is preferable that the shape has a material function. Even if the particle size of the plastics constituting the organic lightweight aggregate of the present invention is smaller than 0.1 mmφ, a special effect cannot be found as an organic lightweight aggregate, and when the particle size is larger than 3 mmφ, The surface of the formed cured body tends to be difficult to obtain smooth smoothness, which is not preferable.

  In the composite water-containing composition of the present invention, depending on the purpose, application, environment, workability, etc. in the water-containing composition of the present invention, the material having a function imparted as needed with respect to 100 parts by weight of the basic water-containing composition. Add the group in an amount of 1 to 30 parts by weight, and add the filler material composition or the composite material material of bone material composition alone or in combination in multiple amounts in the amount of 10 to 1300 parts by weight and mix homogeneously. It is preferably prepared as a composite water-containing composition in which a mortar shape is ensured.

  In the composite water-containing composition of the present invention, when 100 parts by weight of the basic water-containing composition or the functional water-containing composition is added to the composite additive material group in a proportion of more than 1300 parts by weight and mixed homogeneously In the water-containing composition of the present invention, the performance of any of the treatment functions of fixing, binding, curing, and water resistance at the normal room temperature is remarkably reduced, and the content of solid components in the water-containing composition system is increased. This is not preferable because the workability tends to decrease. Of course, in order to sufficiently exert the effect of adding the composite additive material group, the composite additive material group is contained in an amount of 10 parts by mass or more with respect to 100 parts by mass of the basic water-containing composition or the functional water-containing composition. In addition, it is preferable that they are mixed homogeneously.

  In general, the amount ratio of the function-added material group and the composite additive material group to be blended to constitute the functional water-containing composition or the composite-type water-containing composition of the present invention is the kind of the function-added material group and the compound additive material group to be blended. Since the properties, workability, etc. of the treatment body to be formed differ depending on the particle size, particle size distribution, shape, dry / wet condition, source / production area, etc. It is preferable to confirm and determine the type and blending amount of the function-providing material group and composite additive material group for the water-containing composition. Of course, the present invention is not limited to the functionally imparted material group and the composite additive material group disclosed in the present specification, and the water-containing composition of the present invention is shaped at least at a basic temperature through water. Adopting a function-added material group and a composite additive material group that are selected within a range that does not impair the conditions for exhibiting the processing function. I will not refuse.

  Of course, the functional water-containing composition or the composite material containing the composite water-containing composition has a harmful water-eluting element group such as cadmium, arsenic, mercury, lead, chromium, selenium, boron. In many cases, a single or a combination of two or more elements selected from the group of fluorine and manganese coexist. Especially composed of incineration ash / coal ash / slag of thermal history silicate, single or a combination of two or more selected from the group consisting of sediments, sludge, hydrous silicates, minerals, rocks, dredged sand, clays. In the functional material group or the composite additive material group, a harmful water-eluting element group always coexists.

  Active sodium, silicic acid and alumina comprising an aluminosilicate compound constituting a reactive powdery composition as well as an alkali silicate constituting a binding liquid composition constituting the water-containing composition of the present invention Ingredients are blended according to the type and amount ratio of each component sufficient to incorporate a water-eluting element group into a water-insoluble zeolite precursor composed of an alkali salt of aluminosilicate to form a water-insoluble mineral. preferable.

  In particular, in the composite water-containing composition of the present invention, when a labor-saving type with high fluidity that can secure a horizontal plane within 2 minutes is required, a composite material composition or a bone material material composition is added. It is possible to secure a horizontal plane within 2 minutes that a water-containing composition having a high water content in the binding liquid composition is mixed in an amount ratio of 15 parts by mass or more with respect to 100 parts by mass of the material group. This is preferable for ensuring high fluidity.

[Activation treatment method]
The slurry-like basic water-containing composition of the present invention, the juice-like functional water-containing composition or the water-containing composition which is a mortar-like composite water-containing composition is adopted, and is fixed at least at room temperature. As a utilization treatment method of applying a series of work steps to exhibit any treatment function of binding, curing, and water resistance to the water-containing composition, and processing and preparing a pollution-free water-resistant treatment body comprising a predetermined shape body, There are roughly three types of utilization processing methods.
1. A method of utilizing the water-containing composition itself by applying a work process based on the substrate to be treated.
2. A method of utilizing and treating a water-containing composition as a treatment for a material to be treated.
3. A method of utilizing the water-containing pollution-free water-resistant treated body by applying a dehydration process.

  Specific utilization treatment means in the utilization treatment method of the present invention are generally known in the food / fermentation industry, chemical industry, ceramic industry, civil engineering / architecture / construction industry, agriculture / horticulture / landscaping industry, etc. Appropriate selections can be made from publicly used equipment and facilities. In that respect, in a series of work steps that demonstrate any treatment function of fixing, binding, curing, and water resistance at least at room temperature of the water-containing composition of the present invention, the novel equipment and facilities unique to the present invention are used. There is no need to devise specially.

  In a series of work steps in the utilization treatment method of the present invention, the material to be treated is prepared in advance according to the three types of utilization treatment methods of the present invention, the hydrous composition itself, or the selected treatment target material. It is necessary to select different work processes depending on the water-containing, pollution-free, water-resistant treated body. In general, the water-containing composition itself can complete a water-containing, pollution-free water-resistant treatment body having a predetermined shape in the processing step and the curing step. In addition, in the selected material to be treated, a water-free, non-polluting, water-resistant treatment body having a predetermined shape is started in the mixing step in which the water-containing composition as the treatment agent is added and mixed. Can be completed. Furthermore, in the water-containing non-polluting water-resistant treated body, an anhydrous non-polluting water-resistant treated body having a predetermined shape can be completed by positive dehydration exposed to a thermal atmosphere.

  Part 1 of the utilization treatment method of the present invention is the water-based composition itself in the slurry-based basic water-containing composition, juice-like functional water-containing composition or mortar-shaped composite water-containing composition of the present invention. Based on the selected base material to be treated, it is subjected to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment, and processed into a water-free, pollution-free, water-resistant treatment body having a predetermined shape. This is a utilization processing method.

  The base materials to be adopted in Part 1 of the utilization treatment method of the present invention are minerals, rocks, cinnabar sand, clays, ceramics, ceramics, carbonized products, charcoal, glasses, volcanic products, slag, incineration ash Thermal history silicates, gypsum / cement hardened body, inorganic oxides, metals, wood / bamboo / plant body, fibrous body, paper body, skin / bone / animal body, organic body / plastic / rubber, synthetic / Pre-prepared structure-type body surface, surface of miscellaneous objects group, shape-retaining formwork surface, fiber streak prepared in advance by single-component materials such as refined chemicals or wastes, or two or more combined composite materials A gap between groups or a grain aggregate group void is preferable.

As the construction target material prepared in advance adopted in Part 1 of the utilization processing method of the present invention, the following five types of construction target materials can be representatively selected. Of course, the construction target material adopted in the present invention is not limited to the construction target material shown here.
1. 1. Structural type structural body surface, which is a rough structural type structural body surface for foundation work in civil engineering and construction sites. 2. Surfaces of miscellaneous objects that are spherical, flakes / plates, cylinders, granules, lumps, and junk. 3. Form securing mold surface on the mold, outer wall, etc. for recovering the processed body as a secondary processed product 4. Clearance between fiber braids composed of metal reinforcement, fiber woven / nonwoven fabric, and organic rod assembly Granule aggregate group voids consisting of voids formed of aggregates such as granules, aggregates, and junk

  The series of work steps adopted in Part 1 of the utilization treatment method of the present invention are the treatment targets selected by utilizing the utilization treatment means that allows the selected water-containing composition itself to exhibit binding, solidification and treatment functions. Based on the base material, the water-containing composition itself is used as a processing target agent and processed into a processed product processed into a predetermined shape, and then the processed product is subjected to reaction and curing at least at room temperature to be predetermined. It is preferable that it is comprised by the curing process which has completed the property as a shape body.

  The processing steps constituting the series of working steps adopted in Part 1 of the utilization processing method of the present invention are: spraying / spraying at least at room temperature, coating / coating, self-treatment of the water-containing composition itself on the basis of the substrate to be processed. Horizontal sinking, binding, bonding, laminating, sticking / adhering, joining, spreading, filling, soaking, impregnation, dusting, assembly, integration, pouring, pouring, pouring, filling, dead weight / vibration / pressing / depressurizing Processed products in a specified shape by processing means that operate processing tools and equipment that enable binding, solidification, and processing functions via water consisting of molding, kneading, fitting, stirring, stirring, and mixing It is preferable that it is a process.

  Specific processing tools and devices that enable binding, solidification, and processing functions in the processing steps of the series of work steps of the present invention include the food industry, chemical industry, ceramic industry, civil engineering, architecture, and construction industry. Commonly known and publicly used mixing / kneading / granulating machines, stirring granulators, pressure granulating / molding machines, flow-feeding molding machines, extrusion granulating / molding machines, packing systems Granulators and molding machines, as well as various types of granulators and molding machines, coating machines, adhesion / binding machines, coating / coating machines adopted at the processing site for secondary products such as cement milk, concrete and ceramic products A device that is appropriately selected from construction processing means such as an apparatus, a floor adjustment device, and a sink preparation method device, and that is suitable for the purpose, application, work environment, etc. the purpose It is preferable to choose depending on the application and work environment. In particular, in the formation of a film-like film or the like, the water-containing composition itself of the present invention is formed on the surface of a mold which is a substrate to be treated in the processing step, in the form of a film, plate, film or film having a thickness of 1 to 20 mm In the curing process, the continuous film is cured by exposing it to room temperature or 100 ° C for 15 minutes or longer, and the cured organism is removed from the surface of the mold to form a film-like or film-like body. It can be recovered.

  In addition, the curing process that constitutes a series of work steps of the present invention is a process product prepared in the processing step in the air, water, sea, under normal pressure, pressure, and reduced pressure conditions in the range from room temperature to 100 ° C. Release in a single atmosphere selected from the group of atmospheres in soil, solution, steam, or non-oxygen gas or in a multi-stage atmosphere of a combination of two or more types for at least 15 minutes, preferably at room temperature for 3 hours. It is preferable that the curing is a step of treating and preparing a water-containing, non-polluting, water-resistant treated body that has been completed as a predetermined shape.

  The predetermined shape body prepared and treated in Part 1 of the utilization processing method of the present invention is a water-containing coated shape body, a binding shape body, a collective shape body, a multilayer shape body, a specific shape body mainly composed of silicates. Examples of the shape-shaped body, the structural-type shaped body, the film-shaped shaped body, the reinforced-type shaped body, and the predetermined-shaped body having the characteristics as an integral shaped body can be given. A specific example of each of the predetermined shapes mentioned here will be described in detail in the section of “Pollution-free water-resistant treated body” described later.

  In Part 1 of the utilization treatment method of the present invention, a series of work steps comprising utilization treatment means according to the purpose, application, and work environment on the basis of the selected treatment target base material with the water-containing composition itself as the utilization treatment target agent. In addition, the water-containing non-polluting water-resistant treatment comprising a predetermined shaped body in which the water-containing composition itself is shaped at least at room temperature via water and subjected to detoxification treatment and non-re-mudging treatment. It is a utilization processing method that is processed and prepared as a body.

  Part 2 of the utilization treatment method of the present invention is to fix and bind the water-containing composition in the slurry-like basic water-containing composition, juice-like functional water-containing composition or mortar-like composite water-containing composition of the present invention at least at room temperature.・ As a treatment agent that exhibits either a curing or water-resistant treatment function, the water-containing composition is added to the selected material to be treated and added as a contact mixture, and the contact mixture is used. Non-polluting water containing a predetermined shape by applying to a series of work processes consisting of utilization treatment means according to the purpose, application, and work environment based on the base material to be treated selected as necessary. This is a utilization treatment method for treating and preparing a mold water-resistant treated body.

  The processing target material selected in Part 2 of the utilization processing method of the present invention is a granular group according to use composed of a filling granular material having a particle size in the range of 3 μm to 1 mmφ, and a particle size of 1 to 7 mmφ. Silicate granular material consisting of aggregates in the range of 1, organic material group consisting of organic materials having a particle size in the range of 1 to 10 mmφ, or a single or two or more types selected from the group of in situ soil ground It is preferable that the material to be treated is composed of a dry product or a wet product in combination.

The granular group according to use in the material to be selected that is selected in Part 2 of the utilization processing method of the present invention includes silica gel, alumina gel, clays, aluminum silicate, zeolite having a specific surface area of 10 m ² / g or more. Adsorbent granular material group consisting of carbonic acid, organic matter, carbonized product; heat resistance / fire resistance consisting of magnesia, alumina, silica, aluminosilicate, carbide, nitride with particle size in the range of 1 to 5 mmφ Base granule group: Calcium silicate (tobermorite, zonotolite), alumina fiber, rock wool, carbon fiber, fiber type granule group of heat insulating and heat insulating base material consisting of metal fiber; Incinerated ash, calcium-based granule, bottom sediment / sludge, clay aluminosilicate, zeolite, amorphous alumina / silica A partly divided granular material group can be preferably exemplified.

Specifically, for example, a granular material having an adsorptive function having a specific surface area of 10 m ² / g or more, comprising a silica gel, alumina gel, clays, aluminum silicates, zeolite, charcoal, and an organic carbonized product. When selecting a group as a granular group according to application, especially when trying to handle a granular group having an adsorptive function as an adsorbent, etc., in the handling state, the adsorbent etc. The application range is narrow. Therefore, it is preferable that the granular material group having the adsorptive function is processed into a granule or a molded body that is easy to handle. However, when processing granular materials with adsorbing function into granules or molded products with general binders and adhesives, etc., the specific surface area that exhibits the adsorptive function that the granular materials had was filled. It is not preferable because it tends to disappear. However, when the effect of the water-containing composition of the present invention as a treatment agent, such as a binder or an adhesive, is expected, the adsorptive function is ensured without losing the adsorptive function of the powder group. Thus, it is preferable because it can be processed into a granule or a molded product that exhibits its effect as a binder and adhesion and is easy to handle.

  In addition, when a granular group of heat-resistant and refractory base materials composed of magnesia, alumina, silica, aluminosilicate, carbide, and nitride with a particle size in the range of 1 to 5 mmφ is selected as the granular group for each application It is possible to utilize the water-containing composition of the present invention as a heat-resistant binder / adhesive that is a treatment agent, and the water-containing composition of the present invention can be used as a heat-resistant / fire-resistant substrate powder group. Can be provided as a heat- and fire-resistant material for non-fired building furnaces, and can be suitably provided as a labor-saving non-fired building material. In addition, if you select a fiber group of heat-insulating and heat-insulating base materials consisting of calcium silicate (tobermorite, zonolite), alumina fiber, rock wool, carbon fiber, and metal fiber, The water-containing composition of the present invention has heat resistance, and the water-containing composition of the present invention can be used as a binder, an adhesive or the like without filling a gas / air layer held in a large amount by the heat insulating and heat insulating substrate. Yes, it is possible to process and prepare the heat-insulating base material fiber-based granular material group into easy-to-handle heat-insulating base material processed products, especially binders and adhesives that allow in-situ processing It is preferable because it can be used as an agent.

  In addition, various types of incinerated ash, calcia-based powders, clay aluminosilicates, zeolites, amorphous alumina / silica dehydrated and water-retaining powders that are subject to heat history are classified into powders for different applications. When selected as a group of granules, the water-containing composition of the present invention has effective binding / adhesive strength even if it is a water-containing silicate, so the present invention is applied to these water-containing silicates. It is possible to add the water-containing composition to exert binding / adhesive force, and it is preferable that it can be modified into, for example, easy-to-handle water-resistant granules or small lumps.

  In addition, the silicate granular material in the selected material to be adopted selected in Part 2 of the utilization treatment method of the present invention includes minerals, rocks, cinnabar, layered clay minerals, incineration ash of general and industrial wastes, papermaking Ash, sawdust, crops, food processing waste, incinerated ash, phosphorus-containing incinerated ash from sewage sludge, agricultural settlement drainage sludge, coal ash discharged from thermal power generation, slag discharged from iron and steel making, low crystal, non-crystalline Silicate powder composed mainly of crystalline silicates, volcanic products, ecocement, Portland cement, or single or a combination of two or more silicates selected from the group of sediment, dredged soil, sludge, and sludge A body can be mentioned suitably.

  In many cases, the silicate granular material that is a material to be processed in the present invention is generally a silicate granular material that is a silicate composed of wastes. Incineration ash of general / industrial wastes, especially silicates composed of wastes, incineration ash of papermaking, sawdust, agricultural products, food processing waste, phosphorus-containing incineration ash of sewage sludge / agricultural settlement drainage sludge These are silicates that have received thermal history such as coal ash discharged during thermal power generation and slag discharged during steelmaking and steelmaking. Silicates made from these wastes are based on the Basic Environmental Law shown in Table 1. If the harmful water-soluble elements specified in the Soil Contamination Countermeasures Law coexist and these harmful elements are not insolubilized in a state that does not cause harmful effects on the living environment, these wastes The silicates that have received the heat history cannot be reclaimed and reused.

  The water-containing composition of the present invention has a function of insolubilizing and immobilizing harmful element groups coexisting with silicates that have received a heat history composed of these wastes at least at room temperature, Because it is possible to insolubilize and immobilize harmful elements coexisting in silicates that have a thermal history consisting of these wastes in a living environment and in a state that does not harm humans, environmental problems It is effective as a treatment material and treatment method for insoluble and immobilization of harmful elements.

  In addition, the organic material group in the processing target material selected in Part 2 of the utilization processing method of the present invention contains or coexists with the organic material and has a spherical shape, granular shape, or lump shape having a particle size in the range of 1 to 10 mmφ. Contains 50% by mass or more of organic substances containing water in the form of plate, sand, chip, flake, fiber, specific shape, and unspecified shape, and is a waste of agricultural products and food processing Wastes, logging of forests and landscaping plants, fallen leaves, sawdust, phosphorus sludge containing sewage / agricultural settlement drainage, livestock manure, animal / plant-related industries / living waste, industrial / living waste In addition, a single organic material group or a combination of two or more organic material materials selected from the group of animal and plant organic materials can be preferably mentioned.

  If the specific example in the organic raw material group of this invention is shown, wastes, such as threshing baskets, such as rice and wheat, straws, vegetables, fruits, etc. can be mentioned as wastes of agricultural products. Examples of cutting waste and fallen leaves of mountain forests and landscaping plants include waste materials such as selection, fallen leaves, cut grass and thinned wood. Examples of sawdust include sawdust and wood scrap. Examples of livestock manure include manure from cows, pigs and chickens. Animal and plant-related industrial and domestic wastes include wastes such as animals, fresh fish, meat and vegetables discharged from fish and vegetable markets, and processing plants, and waste discharged from food factories and restaurants Good examples include garbage and garbage discharged from households.

  The water-containing sludge as an example constituting the organic material group in the present invention is preferably preliminarily added with incinerated ash as a moisture adjusting agent and an organic material group that exhibits a fertilizer effect. However, the organic material group of the present invention is an organic material that can be easily handled as a plant growth material according to the purpose and use of the present invention, and that the plant growth is effective and the effectiveness of plant growth is ensured. It is preferable to select and determine by a preliminary experiment in which the contents / types and blending ratio of the material group are examined. In particular, as an organic material group that is a material to be treated in the present invention, phosphorus-containing sludge containing sewage / agricultural settlement drainage containing phosphorus and organic components is generally harmful to the living environment and people. Since the element group coexists, the insoluble / fixation function of the harmful element group possessed by the water-containing composition of the present invention is utilized to prevent the harmful element group from coexisting in advance in harming the living environment and people. It is possible to be insoluble and immobilized in the state, which is effective.

  In addition, when these organic materials are recycled as plant growth materials, greening base materials, and black soil, etc., the harmful elements that coexist in the organic materials are insoluble and immobilized, It is preferable to effectively use the organic material group by composting and composting to exhibit the fertilizer effect of the organic material group. Therefore, the aerobic microorganism group that has a fermenting composting function that enables composting and composting at the same time as the detoxification treatment of insoluble and immobilization of harmful elements in the organic material group is added, and composting and composting is performed. At this time, it is effective to add and stir the deodorant having a deodorizing function of malodor if necessary. Of course, the organic material group to be treated by composting / composting can be appropriately selected from the above-mentioned organic material group to be treated materials.

  The in-situ soil ground in the processing target material selected in Part 2 of the utilization processing method of the present invention is the soil ground existing in the original position, soft ground, road / bank / bank, humus land, mountain forest land, farmland / Preferable examples include in situ soil ground composed of fields, ridges / grooves, residential land / public land, factories / store land, parks / gardens, and slopes / plant cultivation bases. In particular, for soil and ground that are in the original position and are not easy to carry, in order to solve the problems that occur there, it is unavoidable to adopt a solution processing means in the original position.

  In such a case, the water-containing composition of the present invention is brought into place in-situ, and the water-containing composition of the present invention is added and mixed with the material to be treated in-situ at the original position, so that the processing function of the water-containing composition of the present invention is in-situ. The contact mixture, which is applied on the soil ground and then mixed in-situ, is exposed and cured for at least 24 hours in a normal-temperature atmosphere in the environment in-situ without any processing process. A certain soil ground, soft ground, road, bank, farmland / residential land, public land, etc., and lump, pile, farmland ridge, gutter, road, bank, structure, etc. are detoxified and shaped. Can be prepared and processed into a predetermined shape. In particular, when repairing contaminated soil ground designated by the Soil Contamination Countermeasures Law, the water-containing composition of the present invention is additionally brought into contact with the contaminated soil ground in situ, and the coexisting harmful water-eluting elements are treated in situ. Thus, it can be insoluble and immobilized in a water-insoluble state. In addition, when the soil ground existing in the original position is soft, the water-containing composition of the present invention is additionally brought into contact with the soft soil ground to reinforce / strengthen it and repair it as an effective soil ground. Can do.

  The contact mixture prepared by the admixing step of adding the contact composition with the water-containing composition of the present invention to the processing target material selected according to the present invention as an effective processing agent is selected based on the dry target. In other words, the installation method or the addition contact mixing is possible by adding 10 to 90 parts by mass of the water-containing composition as the utilization treatment agent to 100 parts by mass, and adding water in an amount of at least 5 parts by mass as necessary. It is preferable that the mixture is prepared as a contact mixture in which the whole is subjected to additional contact mixing to ensure a homogeneous plastic, mud or wet powder. When the treatment target material is expressed on a dry matter basis with respect to 100 parts by mass, the amount of the water-containing composition that is the utilization treatment agent is less than 10 parts by mass, the effect of the water-containing composition as the utilization treatment agent is sufficient. I can't demonstrate it. Moreover, even if it mix | blends the quantity ratio of a water-containing composition more than 90 mass parts, the effect as a utilization processing agent improved in the process body cannot be anticipated.

  When the contact composition is added to the material to be treated selected in the present invention using the water-containing composition of the present invention as an effective treatment agent and a contact mixture is prepared by the mixing step, it is already contained in the material to be treated selected. The amount of water that must be added differs depending on the amount of water that is added, but the contact mixture prepared according to the present invention contains at least 10% by mass of water in the total amount of the blend. It is preferable for exerting the function and function as the utilization treatment agent in the water-containing composition.

  A series of work steps adopted in Part 2 of the utilization treatment method of the present invention is a binding or solidifying function based on a base material to be treated that is selected as necessary for a contact mixture prepared in advance. To achieve a processed product obtained by processing the contact mixture into a processed product, and then proceeding the reaction / curing to the processed product at least at room temperature to complete the properties of the processed product It is preferable that it is comprised by the curing process made to carry out.

  The processing steps constituting the series of work steps adopted in Part 2 of the utilization processing method of the present invention are at least based on the base of the substrate to be processed selected as necessary with respect to the contact mixture prepared in advance. Spraying / spraying at room temperature, application / painting, self-horizontal flow, binding, adhesion, lamination, sticking / adhesion, bonding, spreading, jointing, soaking, impregnation, dusting, integration, pouring, pouring, pouring, Processing in a given shape by operating processing tools and equipment that enable binding or solidification functions through water consisting of filling, self-weight, vibration, press-fitting, decompression stuffing, mold taking, kneading, fitting, stirring and mixing It is preferable that it is the process made into a processed material.

  In particular, when selecting in-situ soil ground as the processing target material, the location where the processing target material exists is applied to the place where the processing target material exists. It is necessary to start from the process of adding the water-containing composition of the present invention, which is the utilization treatment agent, to the additional contact, and to perform a series of work processes including a processing process and a curing process at the original position where the processing target material exists. Therefore, in order to execute the utilization processing method consisting of a series of work processes at the original position, the equipment that has been brought into the original position to operate the utilization processing method consisting of a series of work processes is operated. It is necessary to execute the utilization processing method.

  In addition, the processing step of making the treatment shaped product into an unspecified shape at the carry-in position where the material to be treated is present is a granulated granule such as a granule, an aggregate, a consolidated adsorbent, etc. It can also be set as the shape processing object made into a thing or an aggregate group. Methods and means for shaping into an unspecified shape are known in the art by means of stirring, blowing, dispersing, pouring, etc., publicly known rolling granulation, extrusion granulation, stirring granulation, spray granulation, spray granulation Adopting a step of processing into shaped products such as granules, aggregates, consolidated adsorbents, etc., granulated to 1 to 8 mmφ particle size by a granulator such as packing granulator, pelletizer, etc. it can. The processing means adopted in the processing step in the series of work steps of the present invention performs processing molding by newly attaching the contact mixture adjusted to the contact mixture suitable for processing in the mixing step to a device suitable for the processing step. However, when processing and preparing unspecified shaped products such as granules in a series of work processes, for example, unspecified shapes such as granules can be processed in parallel with the mixing and kneading apparatus in the mixing step. A product can also be prepared.

  In addition, when the mixing process is performed at the site where the material to be treated is present, the material to be reformed consisting of hydrous soil / sludge or sandy soil / clay / rock soil that coexists with harmful substances is present. Imported, publicly known and publicly used mixing / kneading equipment used in the civil engineering and construction industry, especially excavation / mixing equipment used in ground improvement sites such as soft ground, mixing / injecting machine for cement into the ground, etc. Therefore, it is possible to preferably adopt a device having a track record. For example, a method of injecting and stirring a powder or slurry-like modifying agent into the deep ground layer under high pressure by a method adopted for soft ground improvement, etc., a deep layer mixing method using an existing ground improvement method, backhoe, stabilizer, self The mixing process can be performed in-situ by a stirring and mixing method using heavy machinery such as a traveling soil improvement machine. In addition, the in-situ processing step where the material to be treated exists is either a method of injecting and stirring under normal pressure or high pressure in the ground surface layer or deep layer at the same time as the mixing step in the in-situ location where the material to be modified exists, or existing In-situ processing and preparation of shaped products consisting of piles, lumps, shores, gutters, ground, etc., using a dry or wet deep layer mixing method, etc. adopted by the ground improvement method in the civil engineering industry Can do.

  Further, in the present invention, a necessary series of devices capable of performing a mixing process, a processing process, a curing process, and a dehydrating process for performing a utilization process can be operated in a delivery manner to an original position where a series of work processes are performed. Carrying a transportable device compactly on a moving vehicle, moving a group of devices to a movable state and moving them to the original position or the carry-in position where the material to be processed exists, and executing a series of work processes Is possible. Therefore, the utilization processing of the present invention can be executed by bringing a series of apparatus groups to the position where the processing target material is present.

  The curing process that constitutes a series of work steps adopted in Part 2 of the utilization treatment method of the present invention is that the processed product prepared in the processing step is subjected to normal pressure, pressure, and reduced pressure conditions in the range from room temperature to 100 ° C. In air, water, sea, soil, solution, steam, non-oxygen gas atmosphere in a single atmosphere or a multistage atmosphere of a combination of two or more, preferably at room temperature It is preferable that it is a step of treating and preparing a water-containing, non-polluted, water-resistant treated body in which characteristics as a predetermined shape body are completed by allowing the reaction and curing to proceed for 3 hours. Naturally, when the in-situ soil ground is selected as the material to be treated, since the processing process is also performed in-situ, the surplus process is also performed under in-situ natural conditions.

  The predetermined shape body processed and prepared in Part 2 of the utilization treatment method of the present invention acts as a utilization treatment agent on the water-containing composition of the present invention for the material to be treated, and the water content mainly containing silicates is specified. Examples of mold-shaped bodies, unspecified shapes, granule-shaped shapes, powder-shaped shapes, soil-type shapes, shape-shaped shapes, or predetermined shapes that have been secured as processed-type shapes. . A specific example of each of the predetermined shapes mentioned here will be described in detail in the section of “Pollution-free water-resistant treated body” described later.

  Part 3 of the utilization treatment method of the present invention is the heat treatment within a temperature range of 950 ° C. or less with respect to the water-containing non-polluted water-resistant treated material prepared in Part 1 and Part 2 of the utilization treatment method of the present invention. It is subjected to a work process that makes full use of a dehydration process that is composed of a dehydration and heat treatment process that is dried or baked by giving an atmosphere, and is a powder, granule, structure, specific shape or non-specific shape. Anhydrous, non-polluting, water-resistant, which has a specific shape, anhydrous anhydrous shape or ceramic-type shape, is shaped as a specified shape, detoxified, and non-remudized It is a utilization processing method that is processed and prepared as a processing body.

  In the utilization treatment method of the present invention, the dehydration process constituted by the dehydration / heat treatment means in the third treatment method makes the harmful water-eluting element group insoluble in the non-polluting water-resistant treated body containing water to be dehydrated. The immobilized water-insoluble mineral group is decomposed into a water-soluble element group again after the water-insoluble mineral group is decomposed even if it is dried or calcined in a heat atmosphere of at least 950 ° C. The fact that it does not return is confirmed in the examples. In the case where the temperature range of the heat treatment means in the dehydration process exceeds 950 ° C., the pollution-free water-resistant treatment body generally receiving the heat treatment means tends to be sintered and modified, which is not preferable.

[Pollution-free water-resistant treated body]
In the present invention, at least at room temperature, the water-containing composition itself that exhibits any of the fixing, binding, curing, and water-resistant processing functions, or the water-containing composition as an effective treatment agent is added to the material to be treated by additional contact. The above-mentioned contact admixture is subjected to a series of work processes that operate processing tools and devices that enable binding or solidification functions via water at least at room temperature according to the purpose, application, and work environment. Already known and publicly used equipment / equipment that can make full use of any of the three types of utilization processing methods, such as food / fermentation industry, chemical industry, ceramic industry, civil engineering / architecture / Non-polluting water-resistant treatment consisting of a predetermined shape by selecting and selecting from well-known and publicly used equipment and facilities in the construction industry, agriculture, horticulture, landscaping industry, etc. It can be treated prepare.

The predetermined shape body, which is a pollution-free water-resistant treatment body prepared and processed here, has been subjected to a shaping treatment on a water-containing predetermined shape body having a specific gravity in the range of 1.20 to 2.40 g / cm ³ . A non-polluting treatment having a pH value of less than 10 has been performed, and a non-re-mudging treatment to ensure water resistance has been performed, and the shape body strength is 10 KN / m in uniaxial compressive strength as necessary. ² or more is secured, and shear fracture adhesion is 5KN / m ² or more. Recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, soil ground improvement materials, fire resistance / It can be provided as a non-polluting, water-resistant treated body with properties that can be supplied to the fields of heat insulation materials, ceramics / ceramic materials, crafts / processing materials, adhesives / curing agents, water purification / treatment agents, or plant growth base materials.

  As the predetermined shape body which is a non-pollution type water-resistant treated body in the present invention, as shown in Table 3 above, a water-containing shape body and a binding shape body mainly composed of silicates are included. , Collective shape, multi-layer shape, specific shape, structural shape, membrane shape, reinforcing shape, integral shape, fixed shape, unspecified shape, granule shape The shape, powder type shape, soil type shape, shape type shape or treatment type shape, further anhydrous anhydrous shape or properties as ceramic type shape are secured, and will be described in detail later The predetermined shapes according to the purpose, application, working environment and the like of the present invention described in (1) can be preferably mentioned.

  Hereinafter, details of each predetermined shape body that is a pollution-free water-resistant treated body that is treated and prepared using the utilization treatment method of the present invention by utilizing the water-containing composition of the present invention. Explained.

The coated shaped body that is the predetermined shaped body of the present invention adopts the water-containing composition itself as a coating agent, spraying / spraying, applying, pasting / adhering, on the surface of the structural housing that is the substrate to be treated, A structural enclosure by applying processing tools and devices that enable binding, solidification and processing functions through water, consisting of soaking, self-horizontal flow, binding, bonding or laminating means. Floor, wall / partition plate, pillar, roof / tile, bridge pier, structure, foundation structural frame, processing frame, ceramics / ceramics, crafts or self-forming floor And having a shear fracture adhesion of 5 KN / m ² or more, a water-containing coated shape body having a pH value of less than 10 is ensured and shaped as a predetermined shape body, detoxified and non-re-mud Pollution-free pollution It can be provided as a mold water-resistant treated body.

The self-forming floor of the horizontal floor surface in the coated shaped body of the present invention has a high flow rate with a specific gravity of a water-containing composition composed of rubber chips and lightweight aggregates in the range of 1.10 to 1.90 g / cm ^3. Adopted a water-containing composition that can be self-secured within 2 minutes and can be poured in as a covering / coating material that enables self-efficiency level. The structural frame is made by operating tools and devices that enable a water-based binding function on the surface of the surface of the surface and attaching it to a series of work steps to ensure a smooth finish horizontal floor surface by self-formation of the horizontal plane. Conserving a non-polluting, water-resistant treated body that has been formed into a water-containing coated shaped body with a pH value of less than 10 on the surface of the finished floor, and has been subjected to detoxification treatment and non-re-mudging treatment. Conversion It can be prepared for work. In particular, it can be provided as a pollution-free water-resistant treatment body that can be constructed in a labor-saving work process as a self-leveling finishing method in a place that requires a wide finishing horizontal floor surface.

The binding-type shaped body that is the predetermined shaped body of the present invention adopts the water-containing composition itself as a binding / adhesive, and is bonded / adhered, laminated on the surface of the structural casing that is the substrate to be treated. Attaching, adhering, joining, jointing, soaking, impregnation, pouring, pouring, or filling and watering through tools and equipment that enable binding, solidification, and processing functions are possible. Thus, it is composed of a plywood, a joint adhesive, a binder, an adhesive, an adhesive or an adherent on the surface of the structural housing, and a shear value of 5 KN / m ² or more is ensured by a shear fracture adhesion test, and a pH value of 10 It is possible to provide a non-polluted water-resistant treated body in which a binding-type shaped body having less water content is secured, shaped as a predetermined shaped body, detoxified and non-remudized.

Of course, the water-containing composition itself of the present invention, which effectively forms a binding-type body, can exhibit bonding / binding functions for materials in various materials / shapes as an inorganic bonding / binding agent. it can. In particular, when the water-containing composition itself of the present invention is employed as an inorganic adhesive / binder, it depends on the material and shape of the materials to be bonded / bonded. It can be provided as an inorganic adhesion / binding agent that bonds and binds materials with a strength of ² or more.

  The aggregated shape body which is the predetermined shape body of the present invention adopts the water-containing composition itself as a binder / adhesive, and is a granular material in the range of a particle size of 20 μ to 40 mmφ which is a substrate to be treated, a spherical shape, Bonding, bonding, soaking, impregnation, pouring, pouring in the base of the surface of miscellaneous objects consisting of hollow, cylindrical, granule, aggregate, granule, junk, flake or flake Integrated assembly on the surface of miscellaneous objects by attaching a series of work steps to operate tools and equipment that enable binding, solidification and processing functions via water consisting of filling, stirring, stirring and mixing means , A water-containing aggregate-shaped body having a pH value of less than 10 consisting of an aggregate, carrier, water permeable plate, ventilation body, soundproof body, fireproof body, water purification / treatment body, heat insulation / heat insulation material or catalyst body Is secured and shaped as a predetermined shape body It can be provided as a pollution-free water-resistant treated body that has been subjected to a detoxification treatment and a non-re-mudging treatment.

  In the aggregate shape body of the present invention, the wet composition itself is adopted as a binder / adhesive, and the particle size in the range of 20 μm to 40 mmφ as the substrate to be treated Bonding, adhesion, soaking, impregnation on the basis of the surface of miscellaneous objects consisting of bodies, spheres, hollows, cylinders, granules, aggregates, granules, junk bodies, flake bodies or discrete shapes By applying a series of work processes that operate a device that enables a treatment method using water that enables pouring, pouring, filling, agitation, stirring, and mixing, to enable the treatment of miscellaneous objects. Adhesive surfaces are integrated to provide a space with through-holes and water-permeable holes in miscellaneous objects, so that it is an agglomerated aggregate, carrier, water permeable plate, ventilation body, soundproof body, fireproof body, water purification Body, heat insulation, heat insulation material or catalyst Provided as a non-polluting, water-resistant treated body in which a water-containing aggregated shaped body having a pH value of less than 10 is secured and shaped as a predetermined shaped body and subjected to detoxification treatment and non-re-mudging treatment can do.

  The multilayer shaped body, which is the predetermined shaped body of the present invention, has a particle size of 20 μm to 40 mmφ which is a substrate to be treated by adopting the water-containing composition itself as a binder / adhesive. In the base of the surface of miscellaneous objects consisting of garlic, flakes, lumps, and granules, binding, bonding, soaking, impregnation, pouring, pouring, filling, stirring, stirring, and mixing are used. By applying a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions, coatings, multilayers, adsorbents, Odorant, water purification body, heat insulation / heat insulation material or catalyst body, water-containing multi-layer shape body with a surface area of less than 10 is secured, and it is shaped into a predetermined shape body and rendered harmless Treated and non-re-mudging treatment It can be provided as a non-polluting water-resistant treated body.

The coated body which is a multilayer shaped body of the present invention is a carbon, amorphous silica, activated silicic acid, activated silicic acid which is an adsorbent powder having a specific surface area of 100 m ² / g or more as a substrate to be treated. Adopted by selecting a granule material having single or two or more combined adsorptivity selected from the group of salt, diatomaceous earth, activated alumina, activated aluminosilicate compound, carbon-containing carbonized product, adsorptive incineration ash or zeolite Adopting the water-containing composition itself as a binder / adhesive, and tools / equipment that make the binding, solidification, and processing functions through water consisting of soaking, impregnation, pouring, stirring, stirring, and mixing means possible. By applying a series of working steps to work, the adsorbent, deodorant or the specific surface area of 50 m ² / g or more by applying an adhesion coating film on the surface of the adsorbent granules on the surface of the miscellaneous objects water Provided as a non-polluted water-resistant treated body that is shaped as a predetermined shaped body as a water-containing aggregate shaped body having a pH value of less than 10 as a purification body, and is subjected to a detoxification treatment and a non-re-mudging treatment. Can do.

The specific shape body, which is the predetermined shape body of the present invention, adopts the water-containing composition itself as a cementing / curing agent, and pours, pours, injects, and fills the base material of the shape securing mold that is the substrate to be treated. By applying a series of work processes that operate tools and equipment that enable binding, solidification and processing functions via water consisting of self-weight, vibration, press-fitting, mold making, kneading, and fitting means, Remove the pre-determined shape completed in the secure formwork from the secure formwork, pillar, plate / brick, fence / wall material, tile, pipe, fiber / string, sphere, U-shape grooves, Namishozai, reef, crafts, consists tank containers, uniaxial compressive strength 10KN / ^{m 2} or more, prefer Raku is ensured 20KN / ^{m 2} or more in a uniaxial compressive strength and pH value of 10 A specific shape with less water content is secured Can be provided as a non-polluting type water-resistant treating body detoxification as well as non-re-Doroka process is shaped processed as the body is subjected.

  The structural shape body that is the predetermined shape body of the present invention adopts the water-containing composition itself as a cementing agent, and pours, pours, injects, fills, and fills the base of the shape securing mold that is the substrate to be treated. Securing the shape by attaching a series of work steps to operate tools and equipment that enable binding, solidification and processing functions through water consisting of self-weight, vibration, press-fitting, mold making, kneading, and fitting means The predetermined shape body completed within the formwork is removed from the form-assuring formwork, and a water-containing structure-type shape body with a pH value of less than 10 consisting of pillars, walls / plates, bridge piers, frames and foundation structures is secured. Then, it can be provided as a non-polluting water-resistant treated body that has been shaped as a predetermined shaped body and subjected to a detoxification process and a non-re-mudging process.

  The film-shaped mold body, which is the predetermined body of the present invention, adopts the water-containing composition itself as a cementing / curing agent, and pours, pours, injects, in the base of the shape-secured mold that is the substrate to be treated. By applying a series of work processes to operate tools and equipment that enable binding, solidification and processing functions via water consisting of filling, dead weight, vibration, press-fitting, mold making, kneading, and fitting means, The predetermined shape body completed in the form-assuring mold is removed from the form-assuring form, and the water-containing membrane-like shape body having a pH value of less than 10 is composed of a plate, a film / film body, and a film-like specific shape body. Can be provided as a non-polluting water-resistant treated body that has been subjected to a detoxification treatment and a non-re-mudging treatment by being shaped as a predetermined shape body.

  Reinforced shape body which is a predetermined shape body of the present invention adopts the water-containing composition itself as a cementing / curing agent, assembles metal bars as a substrate to be treated, woven fabric / nonwoven fabric of fibers, organic rod Pouring, pouring, pouring, filling, self-weight / vibration / press-fitting, mold-making, kneading, and water-binding, solidification, and processing functions are possible. Pillars and pipes, bridge piers, skeletons, foundation structural skeletons, and foundations of specific shapes that have been integrated and completed with fiber reinforcement as a result of a series of work processes that operate the tools and equipment to be leveled , Plate, brick, interlocking, fence, wall material, pipe, fiber / string, sphere, U-shaped groove, wave-dissipating material, fishing reef, crafts, container or specific shape, etc. Reinforced shape with less water content is secured It can be provided as a non-polluting type water-resistant treating body shaped processed by detoxification treatment as well as non-re-Doroka treatment is performed as the predetermined-shaped body.

  The monolithic shape body, which is the predetermined shape body of the present invention, adopts the water-containing composition itself as a cementing / curing agent, and is a base material to be treated, such as trash, waste, low-level radioactive waste, Aggregated by powder, granule, granule, galactor, flake, shape, or volume holder having a diameter in the range of 0.3 to 9 mmφ, and stored and formed in a container as necessary. In the space of the collective group, it is formed by pouring, pouring, pouring, filling, gathering / integration, dead weight / vibration / press-fitting, mold making, kneading, concentrating / stirring / mixing through water. Moisture content with a pH value of less than 10 consisting of an integrated processed product that has been assembled by unifying the assembly group by subjecting it to a series of work steps that operate tools and devices that enable deposition, solidification and processing functions. Can be provided as a non-polluting type water-resistant treating body shaped processed by detoxification treatment as well as non-re-Doroka treatment is performed as a predetermined-shaped body is secured integral shaped body.

  The processing target material to be processed in the present invention is the processing target material shown in the previous section of the active processing method, and is a powder according to use comprising a filling granular material having a particle size in the range of 3 μm to 1 mmφ. A group of particles, a silicate granule composed of an aggregate having a particle size in the range of 1 to 7 mmφ, an organic material group composed of an organic material having a particle size in the range of 1 to 10 mmφ, or an in situ soil ground. It is preferably composed of a material to be treated consisting of a dry product or a wet product of one or a combination of two or more selected from the group. In the present invention, when adopting a utilization processing method for applying a series of work steps to these treatment target materials using a water-containing composition as a utilization treatment agent, a water-containing granular form having a pH value of less than 10, A non-polluting water-resistant treated body comprising a granular shaped body, a cured shaped body, a soil shaped body, a shaped mold body or a treated shaped body can be prepared by treatment.

The fixed shape body, which is the predetermined shape body of the present invention, uses the water-containing composition as a treatment agent, and the contacted mixture is obtained by adding the water-containing composition to the granular material group for each use, which is the material to be processed, by additional contact. Next, the contact admixture is poured into the base of the form-assured mold that is the substrate to be treated, and the solidification function through water consisting of pouring, pouring, filling, self-weight / vibration / press-filling, mold taking, kneading, and fitting. By applying to a series of work processes that operate tools and equipment that make it possible to remove the predetermined shape body completed in the form securing mold from the form securing mold, Vessels, pillars, U-shaped grooves, earthen pipes, fume pipes, fishing reefs, tetrapods, foundation stones, interlocking, plates, bricks, refractory materials, heat insulation materials, furnaces, etc. Materials, insulation, ceramics Piles, interiors / partitions / partitions / walls, tiles, exterior walls, building materials, pots, figurines, ornaments, decorations, art, protective materials, sleepers, benches, desks, ceramics, sanitary wares, tiles , Containers, pots, building materials, tiles, porcelain, ceramics, ornaments, figurines, wave-dissipating blocks, fishing reefs, crafts, containers or bases for non-fired sanitary ware / ceramics in specific shapes, etc. Uniform compressive strength of 10 KN / m ² or more, preferably 20 KN / m ² or more, and a water-containing fixed shape with a pH value of less than 10 is secured and shaped as a predetermined shape to make it harmless. It can be provided as a pollution-free water-resistant treated body that has been subjected to treatment and non-re-mudging treatment.

  The base of non-fired sanitary ware / ceramics in a specific shape body composed of the regular shape body of the present invention is based on an inorganic paint / coating agent or an organic paint / coating agent having a resistance mainly composed of organopolysiloxane, Non-fired sanitary ware base surface is coated and coated Non-fired sanitary ware is completed with non-fired sanitary ware / ceramics A water-containing fixed-shaped body with a pH value of less than 10 is secured. Thus, it can be provided as a non-polluting water-resistant treated body that has been shaped as a predetermined shaped body and subjected to a detoxification process and a non-re-mudging process.

  In particular, as an inorganic paint / coating agent having excellent weather resistance and other properties to be coated / coated on the surface of non-fired sanitary ware / ceramics bases that are regular shaped bodies, the present inventors have applied the patented technology ( Patent registration numbers: No. 2738904, No. 2774235, etc.) Non-fired sanitary ware / ceramics bases made of inorganic paints / coating agents with organopolysiloxane as the main component and excellent weather resistance When coating / coating the surface of the glass, it is possible to provide non-fired sanitary ware and ceramics that are not fired without consuming heat energy.

  The unspecified shape body which is a predetermined shape body of the present invention is a contact mixture by adding the water-containing composition to the granular material group according to use which is the material to be processed, using the water-containing composition as a treatment agent. Next, a series of tools and equipment that enable binding, solidification, and processing functions via water consisting of agitation, stirring, mixing, kneading, extrusion, rolling granulation, crushing, and classification means. By applying to the above work process, it is possible to increase the flow rate of the pulverized particles, granular, granulated, sandy or lump-shaped segment auxiliary materials, mortar, which are formed by the group of granular materials according to the use, which is the material to be processed Materials, landfills / fills, filling materials, fillers, synthetic aggregates, granules with specific surface area, non-fired fireproofing / heat insulation / thermal insulation materials, catalysts, water purification / treatment agents, plant growth base materials, customers PH value of less than 10 consisting of soil, soil improvement material or civil engineering material Unspecified shape of the water can be provided as a non-polluting type water-resistant treating body shaped processed by detoxification treatment as well as non-re-Doroka process is performed as is reserved a given shaped body.

The granule having a specific surface area, which is an unspecified shape body of the present invention, is a charcoal that is an adsorbent granular material having a specific surface area of 100 m ² / g or more as a granular material group by use as a material to be processed, Adsorbability of single or a combination of two or more selected from the group of crystalline silica, activated silicic acid, activated silicate, diatomaceous earth, activated alumina, activated aluminosilicate compound, carbon-containing carbonized product, adsorptive incineration ash or zeolite Moisture content with a specific surface area of 50 m ² / g or more is selected and a water content with a pH value of less than 10 consisting of an adsorbent, deodorant or water purifier in a granular, granular, sandy or small lump shape. Thus, it is possible to provide a non-polluted water-resistant treated body in which a non-specific shaped body is secured, shaped as a predetermined shaped body, detoxified, and non-remudized.

  In particular, when an adsorbent granular material having a specific surface area that is difficult to handle is processed into an easy-to-handle granule with an organic adhesive, for example, the adhesive function of the organic adhesive is It is impossible to process into a granule that has a specific surface area that is covered and adhered and crushed, and that has secured adsorptivity. On the other hand, the water treatment composition of the present invention containing the silica polymer as a main component is used as a binder / adhesive, and the utilization treatment method of the present invention is used to granulate the adsorbent granular material having a specific surface area. When it does, it becomes possible to granulate, without smashing the specific surface area which the adsorptive granular material has.

  Non-fired fireproof, heat insulating and heat insulating material which is an irregular shape body which is a predetermined shape body of the present invention is a powder, a alumina, an alumina gel, a silica, an aluminosilicate as a granular material group according to use which is a material to be treated. Heat- and fire-resistant base material granule group consisting of carbide, nitride; fiber system of heat insulating and heat-insulating base material consisting of calcium silicate (tobermorite, zonolite), alumina fiber, rock wool, carbon fiber, metal fiber Select a granular material consisting of various incinerated ash that has undergone a thermal history, from a non-fired fireproof, heat insulating and heat insulating material in granular, granular, sandy or small lump form It is possible to provide a non-polluted water-resistant treated body in which a non-specific water-containing shaped body having a pH value of less than 10 is secured, shaped as a predetermined shaped body, detoxified, and non-remudized. it can

The granule-type treated body according to the present invention has a hydrous composition as a treatment agent, and the hydrous composition is added to and mixed with the silicate powder that is the material to be treated to form a contact blend. Known and publicly used in the food industry, chemical industry, ceramic industry, civil engineering, construction and construction industries, etc., which are concrete tools and devices that enable the binding, solidification and processing functions of the contact mixture General-purpose mixing / kneading / granulating machines, agitation granulators, pressure granulators / molders, flow-feed granulators, extrusion granulators / molders, packing granulators / molders, and cement Various granulators / molding machines, coating machines, adhesion / binding machines, coating / coating machines, floor conditioners, sink preparation, which are adopted at the processing site for secondary products such as milk, concrete and ceramic products System tools and equipment A segment auxiliary material in the form of a granular material, granule, sand or small lump, which is subjected to a processing step in a series of work steps, which is formed from the material to be processed, a high fluidizing material for mortar , Landfill / banking, filling material, fillers, aggregates, catalysts, water purification / treatment agent, plant growth base material, soil improvement material or civil engineering material, with corn index (qc = KN / m ² ) A non-polluting, water-resistant structure in which a water-containing granule-shaped body having a pH value of less than 10 is secured and shaped as a predetermined shaped body and subjected to a detoxification process and a non-re-mudging process. It can be provided as a treatment body.

Granules that are granule-shaped bodies of the present invention are hydrated soil, sludge, sludge, bottom sediment, and silicate that is a material to be treated by adding anhydrous incineration ash to a moisture regulator as necessary The water-containing composition is added to the granular material as a treatment agent and added to the contact mixture to make a contact mixture. The contact mixture is stirred, stirred, mixed, kneaded, extruded, tumbled granulated, crushed, and classified. By applying a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions through water, hydrated soil, sludge, sludge, and sediment silicate granules Segment aids in the form of granules, granules, sand or small blocks, mortar high fluidization materials, landfills / fillings, filling materials, fillers, synthetic aggregates, catalysts, water purification / treatment Agent, plant growth base material, soil, soil improvement material or civil engineering material , Corn index ^{(qc = KN / m 2)} 20 less than pH value 10 or more is ensured hydrous granular shape body is ensured shaped treated with harmless as a predetermined shape-treated and non-re Doroka It can be provided as a pollution-free water-resistant treated body that has been treated.

  In particular, sludge and sediments that remain in sea areas and rivers make the sea areas and rivers a reservoir of harmful substances and make them hypoxic, adversely affecting fishery products such as seafood and seaweed beds. This is undesirable. In that respect, using the water-containing composition of the present invention as a treatment agent, the contact mixture is added to the sludge and sediment to obtain a contact mixture, and the contact mixture is granulated, and then the contact mixture in a sea area or a river. Is preferable because the sea area and the river area where sludge and sediments are retained can be regenerated as a good fish place.

  The water purification / treatment agent which is a granule-shaped body of the present invention selects a granular material composed of incinerated ash containing phosphorus or a hydrous sludge containing phosphorus as a silicate granular material to be treated, Predetermined shape with a water-containing unspecified shape having a pH value of less than 10 consisting of a water purification / treatment agent that captures fluorine and heavy metals that are eluted in water in granular, granular, sandy, and small lump shapes It can be provided as a non-polluting water-resistant treated body that has been subjected to a detoxification process and a non-re-mudging process.

The water-containing composition of the present invention basically has a binding, solidification, and processing function, particularly a function to fix a harmful water-eluting element group in a water-insoluble state, so that the material to be processed It is considered that the reaction mechanism for immobilizing a group of harmful water-eluting elements coexisting as a water-insoluble mineral is derived from the reaction described below.
1. 1. Toxic elements are fixed to zeolite precursor minerals as a water-insoluble mineral. 2. Fluorine is immobilized on phosphocalcium apatite mineral and fixed as a water-insoluble mineral. Secures water resistance by immobilizing sodium in water-insoluble aluminosilicate alkali salt mineral

  The water-containing composition of the present invention has a reaction mechanism in which this harmful water-eluting element group is immobilized as a water-insoluble mineral, and the formed granule-shaped body of the present invention is ionically dissolved in water. The fact that it can be used as a water purification / treatment agent that captures the water-eluting element group insoluble and immobilized can be well understood from the results of Examples described later.

  The powder-type processed body that is the predetermined shape body of the present invention uses the water-containing composition as a treatment agent, and the water-containing composition is added to and mixed with the silicate powder body that is the material to be processed to form a contact mixture. Well-known and publicly used in the food industry, chemical industry, ceramic industry, civil engineering, construction and construction industries, etc., which are concrete tools and devices that enable the contact admixture to bind, solidify and process. General-purpose mixing, kneading and granulating machines, agitation granulators, pressure granulators and molding machines, flow casting molding machines, extrusion granulators and molding machines, packing granulators and molding machines, Various granulation / molding machines, coating machine equipment, adhesion / binding machine equipment, coating / coating machine equipment, floor adjustment equipment, sinks adopted at the processing site for secondary products such as cement milk, concrete and ceramic products Operation of preparation-type tools and devices Segment auxiliary material made of silicate granular material that is the material to be treated, high fluidizing material of mortar, landfill / filling / filling material, soil improvement material, As a non-polluting, water-resistant treated body in which a water-containing powder-type shaped body, which is a guest soil or filler, is secured and shaped as a predetermined shaped body and subjected to detoxification treatment and non-re-mudging treatment Can be provided.

  The high fluidization material of the mortar that is the granular shape body of the present invention is selected from various incinerated ash granular materials as silicate granular materials to be treated, granular, granular, It is in the form of sand or small lump, and a water-containing powder-type shape body made of a highly fluidized material that can ensure good fluidity in cement mortars is secured and shaped as a predetermined shape body to make it harmless and non-destructive It can be provided as a pollution-free water-resistant treated body that has been subjected to re-mudging treatment. In particular, a treated body, which is a granular material that has been treated by using the water-containing composition of the present invention as an active treatment agent in advance for a material to be treated, such as incinerated ash in the presence of harmful heavy metals, is cement. It is possible to treat mortar as a highly fluidized material with good fluidity that can efficiently implement construction workability performed by means such as injection at the construction site. It is also preferable because it is possible to secure a demand destination that can use and supply a large amount.

Black soil, plant growth material, greening base material The soil type shape body, which is the predetermined shape body of the present invention, is composed of water-containing phosphorus sludge and phosphorus-containing incinerated ash, which are materials to be treated, using a water-containing composition as a treatment agent. Silicate powder and spheres, granules, lumps, plates, sand, chips, flakes, fibers, specific shapes, unspecified shapes with a particle size of 1 to 10mmφ Contains 50% by mass or more of organic matter containing water in the form of crops, waste from agricultural crops, food processing waste, logging waste from forests and landscaping plants, fallen leaves, sawdust, sewage / Phosphorus sludge from agricultural settlements, livestock excreta, animal and plant-related industrial / life waste, industrial / life-related garbage, and organic materials of one or a combination of two or more selected from the group of animal and vegetable organic materials The water content composition for the material group A tool that enables a binding or solidifying function via water consisting of pouring, pouring, pouring, filling, self-weight, vibration, press-fitting, kneading, and fitting.・ Additional stirring and mixing with aerobic microorganisms with fermenting composting function and deodorant with malodorous deodorizing function if necessary by applying to a series of work processes that operate equipment In addition to composting and composting treatment, landfills, embankments, medium-impregnated materials, soil improvement materials, black soil, greening base materials, or plant growth materials that are formed from organic materials that are the materials to be treated As a non-polluting water-resistant treated body in which a hydrous soil-like shaped body having a value of less than 10 is secured and shaped as a predetermined shaped body and subjected to a detoxification treatment and a non-re-mudging treatment It can be provided.

  In particular, in the present invention, when selecting an organic material group as a material to be treated, for example, a water-containing phosphorous sludge mainly composed of a silicate that emits malodor, the water-containing composition of the present invention is used as a treatment agent, and a moisture adjusting agent. By using additional agitation and mixing together with aerobic microorganisms having a fermenting composting function, such as phosphorus-containing incinerated ash, and a deodorant having a deodorizing function of bad odor, plant growth materials, greening base materials, A soil improvement material etc. can be suitably processed and prepared. In addition, a scouring material that has the effect of degrading sticky water-containing sludge, specifically, organic ruggedness is selected from wood sawdust, cereal cocoons, seed husks, rice husks, coffee cocoons, and tea husks. In addition, the soil-like shape body is secured to the water-containing phosphorus-containing sludge, which is an organic material group, and is processed into a predetermined shape body for detoxification and non-re-mud. Add aerobic microorganisms together with organic material composition to improve fertilizer effect by composting and composting treatment that is processed in parallel and planting materials, planting base materials, soil improvement materials It is preferable to prepare the treatment as such.

  In the present invention, the material to be treated is present in the original position, has a horizontal position, and is not easy to carry, for the original position soil ground, which is not easy to carry, in order to eliminate the problems occurring there, It is necessary to adopt treatment means to solve the problem of in-situ soil ground in-situ. In such a case, as a shape-type shape body that is a predetermined shape body of the present invention, the water-containing composition of the present invention is used as a treatment agent, and tools and devices that enable a treatment function through water brought into the original position. By attaching to a series of work processes that operate, the piles in the soil formed by the in-situ soil ground, which is the material to be treated, fence, road, bank, bank, side road, gutter, slope, mountain forest, An in-situ shape-shaped body with a water content of less than 10 in farmland / fields, residential land / public land or parks / gardens is secured, shaped into a predetermined shape, detoxified and non-remudated Can be provided as a pollution-free water-resistant treated body.

  In the present invention, the material to be treated is present in the original position, has a horizontal position, and is not easy to carry, for the original position soil ground, which is not easy to carry, in order to eliminate the problems occurring there, It is necessary to adopt treatment means to solve the problem of in-situ soil ground in-situ. In such a case, the treatment-type shaped body, which is the predetermined shaped body of the present invention, uses the water-containing composition as a treatment agent, and the water-containing composition is additionally contact-mixed with the in-situ soil ground that is the material to be treated. The contact mixture is subjected to a series of work processes that operate tools and devices such as a deep layer mixing method, a backhoe, a stabilizer, a self-propelled soil improvement machine, etc. that enable a processing function via water in situ. As a result, the soil formed from the in-situ soil ground that is the material to be treated is improved and restored soil ground, mountain forest land, farmland / field, road, residential land / public land, factory / store land or park / garden Provided as a non-polluting water-resistant treated body in which a hydrous treated shaped body having a pH value of less than 10 is secured, shaped as a predetermined shaped body, detoxified and non-remudized. Door can be.

  In the present invention, the water-containing, non-polluting, water-resistant treated body having the above-mentioned predetermined shape is dried or fired by applying a hot atmosphere within the temperature range of 950 ° C. or less, which is the utilization treatment method of the present invention. By subjecting it to a work process that makes full use of the dehydration construction means that is included in the dehydration process comprising dehydration and heat treatment means, it is in a powder, granule, structure, specific shape or non-specific shape, pH Non-polluting water-resistant treated body in which an anhydrous anhydrous shaped body or ceramic type shaped body having a value of less than 10 is secured, shaped as a predetermined shaped body, detoxified, and non-re-mudged Can be offered as. In particular, water-insoluble minerals that are immobilized as water-insoluble minerals, which are fixed as non-polluting water-containing minerals that have a harmful water-eluting element group, are immobilized as insoluble minerals even when subjected to a dehydration step by heat treatment. The extractable element group is maintained insoluble and immobilized, and can be provided as an anhydrous non-polluting water-resistant treated body.

[Physical property evaluation test method]
In the present invention, in order to evaluate the properties and performance of the fluid liquid composition according to the present invention and the formed pollution-free water-resistant treated body, basically, it conforms to a public method such as JIS description. The test / analysis method was adopted to evaluate the properties and performance of the fluid liquid composition and the formed pollution-free water-resistant treated body in the present invention.
In this specification, “parts” and “%” may be indicated by “mass” unless otherwise specified, and the capacity liter display may be indicated by “L”.

1. Evaluation of liquid state stability:
As a method for confirming the liquid state in which the binding liquid composition in the liquid state constituting the water-containing composition has a stable fluidity, the binding liquid composition left at room temperature for at least 30 days is 45 degrees. When the binding liquid composition flows on the glass plate having a 45 degree inclination and flows downward in a liquid state when set on the glass plate having the inclination of It was evaluated that the liquid state was stable.

2. Evaluation of horizontal plane self-assurance:
The amount of the total amount of the constituent components constituting the hydrous composition or the contact mixture was 10 kg, was taken in a Hobart mortar mixer (manufactured by Kansai Seiki Seisakusho: hereinafter abbreviated as “H mixer”), and stirred and mixed for a predetermined time. Pour 10 kg of the hydrous composition or contact mixture into the center of a horizontally set stainless steel plate and let it flow self-flowing within 2 minutes from the start of pouring and ensure that the entire hydrous composition or contact mixture is accurate. The case of forming a horizontal plane is evaluated as “Yes” in the self-secure fluidity of the horizontal plane. evaluated.

3. Working life of hydrous composition:
About 500 cc of a water-containing composition or contact mixture prepared in advance is collected in a 1-liter container, and left to stand in a constant temperature bath at 30 ± 5 ° C., and the container in which the water-containing composition or contact mixture is collected. When the inside was tilted at least 45 degrees, the time during which the apparent fluidity was ensured was evaluated as the working life of the water-containing composition or contact mixture.

4). Specific gravity measurement of water-containing composition and cured body:
The specific gravity of the water-containing composition was displayed by converting the specific weight (g / cm ³ ) by measuring the weight of the water-containing composition in a certain amount of container and measuring the weight of the water-containing composition. The specific gravity of the cured product was displayed by measuring the weight of the prepared cylindrical specimen and converting it to specific gravity (g / cm ³ ).

5. Preparation of cylindrical and granular specimens for treatment:
The cylindrical specimen was prepared by using a prepared water-containing composition or a contact mixture prepared by allowing the water-containing composition to act on the selected material to be treated as an effective treatment agent, as described in JSCE-F506 and JSCE-G505. In accordance with the method (concrete mortar test method), a cylindrical plastic container (see: JISR5201) is injected and filled into a cylindrical product, and then the surface of the cylindrical product is covered with a vinyl film and not sealed. A standard cylindrical specimen (φ5 × 10 cm: n = 3) was prepared by a demolding procedure after being subjected to a curing / recovery process at room temperature (about 25 ° C.) for 28 days.
Preparation of the granular specimen is carried out by preparing the prepared water-containing composition or the contact mixture prepared by allowing the water-containing composition to act on the selected material to be treated as a treatment agent into granules with a particle diameter of 2 to 7 mmφ. It was granulated, placed in a sealable plastic container, and prepared by reacting and curing at room temperature (about 25 ° C.) for 28 days unless otherwise specified.

6). Strength of treated body (columnar / granular specimen):
The strength of the cylindrical specimen that is the treated body is determined by measuring the compressive fracture strength (q) in the uniaxial direction of the cylindrical specimen in accordance with the method (concrete mortar test method) described in JSCE-F506 and JSCE-G505. The uniaxial compressive fracture strength (q) at this time was expressed in KN / m ² units.
The strength of the granular specimen as the treatment body is such that the prepared granular specimen is provided with at least 7 mm of springs that can withstand its own weight at the four corners of two 2 mm thick iron plates (50 × 50 mm), Set one granular sample in the center of the gap between the two iron plates, apply a weight to the upper center of the iron plate, measure the total weight of the weight when the sample granule collapses, The measured average value of nine weights was evaluated as the strength of the sample granules.

7). Treatment adhesion test:
The test of adhesion / binding force exhibited by the water-containing composition or the contact mixture was performed according to the method described in JISK-6852. That is, using a test plate in which a base steel plate and an alumina fired plate having a thickness of 0.5 mm are cut and adjusted to a rectangle of 30 × 25 cm, the portion corresponding to the adhesive surface of the steel plate is polished using 240th polishing paper. Gloss comes out, and the surface is washed with a mixed solvent and dried. On the other hand, the surface of the bonded surface of the alumina fired plate is thoroughly washed with water and dried. Next, the deformable mixture of the prepared sample was applied on a rectangular alumina fired plate 25 × 25 cm area to a thickness of about 2 mm, and bonded in a state corresponding to the 25 × 25 cm area of the rectangular steel plate test piece. At this time, the 5 × 25 cm portions that are not bonded are set so that they protrude in an ear shape on a straight line at opposite portions. Next, after the test piece (test body) that has been adhesively set is allowed to stand at a room temperature of about 20 ° C. for 7 days, the ear-shaped portion of the test piece (test body) is erected using a compression fracture testing machine, and weight is applied in the vertical direction. In addition, the shear fracture force (q) at that time was measured, and the weighted strength (q) at this time was displayed in units of kN / m ² . However, when the alumina fired plate used as the base material was broken instead of the adhesive part when the load was applied, it was evaluated as the adhesive strength exceeding the base material strength.

8). PH value measurement of water elution:
When measuring the pH value of water elution in each sample, if the sample is in a hardened / solidified state, 10 g is put into a container containing 50 g of pure water at 20 ° C. and pH 7 and about 30 ° C. for 30 minutes. The elution test solution which was stirred and then allowed to stand for 3 hours and collected was subjected to pH measurement with a pH meter, and was measured as the pH value in the suspension elution test solution with respect to 5 mass water of the sample.

9. Testing and analysis of toxic element elution:
In the present invention, the trace element group contained in each specimen and the main composition were analyzed in accordance with the bottom sediment investigation method II in the soil analysis method, and the analysis was performed by fluorescent X-ray analysis.
Further, the amount of water elution in the toxic water elution element group was measured in accordance with the “Ministry of the Environment No. 46 Elution Test Method” which is an elution test method in the neutral range, and was expressed in mg / L.
In this example, six kinds of representative elements selected from lead, chromium, arsenic, selenium, boron, and fluorine are selected as the harmful water elution element group in each extraction test solution prepared by the following method, and each extraction test solution is selected. Was measured according to a predetermined test measurement method.
9-1 Preparation of sample Air-dry the sample, remove medium pebbles, wood chips, etc., crush clots and aggregates, and thoroughly homogenize the sample passed through a non-metallic 2 mm sieve to make an elution test A test specimen was obtained.
9-2 Preparation of sample solution Dissolve test specimen (g) in a solvent (prepared so that hydrochloric acid is added to pure water as necessary, and the hydrogen ion concentration index is 5.8 to 6.3). Mix at a ratio of 10% by weight and prepare the prepared sample solution so that the mixed solution is 500 ml or more.
9-3 Elution of element group Shake the prepared sample solution at room temperature (generally 20 ° C) and normal pressure (generally 1 atm) (previously shake at about 200 times per minute, and shake width at 4 cm to 5 cm) Shake for 6 hours continuously.
9-4 Preparation of test solution The sample solution by the above operation is allowed to stand for 10 to 30 minutes, then centrifuged at about 3,000 rpm for 20 minutes, and the supernatant is filtered with a membrane filter having a pore size of 0.45 μm. Filter to collect the filtrate, and use the exact amount required for quantification as the test solution.
9-5 Concentration measurement in test solution The concentration measurement of the element group in each test solution was performed according to the method described below.
Cd; JIS K0102 / 55.4
Pb: JIS K0102 / 54.4
Cr: JIS K0102 / 65.1.5
As: JIS K0102 / 61.2
Se: JIS K0102-67.2
Hg: December 1971 Environment Agency Notification No.59 Attached Table 1
F: JIS K0102 / 34.1
B: December 7, 1971 Environment Agency Notification No. 59, Appendix 7
Na: JIS K0102 / 48.1

7). Water resistance confirmation test In the water resistance confirmation test, 10 g of a sample of each cured body is put into a container containing 100 g of water, and slowly stirred for 30 minutes. The case where there was no collapse was evaluated as “water resistance”, and the case where the granular test specimen was re-mudged due to disintegration or mudification was evaluated as “water resistance”.

8). Remudging test:
In the re-mudging test, in the same manner as in the water resistance confirmation test, 10 g of each molded body-shaped test body excluding the powder portion was put into a container containing 100 g of water, slowly stirred for 10 minutes, and allowed to stand. When the stirring liquid is turbid and the molded body state of the test specimen is clearly collapsed, the re-mudging is "Yes", and when the molded body state is secured, the re-mudging is "No". evaluated.

9. Measurement of soluble part of barium salt compound in alkaline solution The measuring method of "soluble part in alkaline solution" of barium is 10 g of powdered barium salt compound sample in 100 cc of 1N caustic soda solution at 25 ° C and stirred for 10 minutes. After the dispersion, the barium ions in the solution collected by filtering the sample solution are quantitatively analyzed, and barium ions (Ba) eluted in 1 kg of 1N caustic soda solution based on the total amount of barium elements in the collected sample as a reference (100). ⁺⁺ ) amount (mg / kg) was calculated.

10. Measurement of Phosphoric Acid Sustained Release The “sustained release of phosphoric acid content” in the phosphoric acid compound of the hardening reinforcing composition of the present invention is that 1 g of a sample is stirred and dispersed in 100 cc of a 4N sodium hydroxide solution at 25 ° C. Next, sampling was performed at 5 minutes and 120 minutes after dispersion, fractionated and filtered, the phosphoric acid content in the filtrate was quantified as phosphorus pentoxide (mg / 100 cc), and the elapsed time (minutes) was plotted on the horizontal axis of the graph. The initial phosphoric acid content elution amount b and the average hydrolysis rate constant a were calculated from the equation (1) shown above the straight line in which the vertical axis represents the integrated dissolution amount of phosphorus pentoxide (mg / 100 cc).

11. Specific surface area reduction rate In this test, the specific surface area Aq of the material to be dried and the specific surface area of the consolidated material obtained by consolidation molding of the target material were measured using an automatic BET specific surface area measuring device [Sorptomatic Series 1800 made by CARLOERABA] (m ² / g), and the specific surface area reduction rate (A) of the solidified body relative to the target material was determined by the following formula.

  With respect to the specific example of the water-containing composition, the utilization treatment method and the pollution-free water-resistant treated body of the present invention, with reference examples related to the water-containing composition of the present invention and the materials to be treated, etc. The following examples illustrate.

[Reference Example 1]
In this reference example, an alkali silicate having a silanol group constituting the binding liquid composition adopted in this example will be described.
The alkali silicate used as the raw material of the binding liquid composition adopted in this example is selected from commercially available reagents and industrial chemicals, and the contents are shown in Table 4. In addition, as the alkali silicate having the binding liquid composition, when the raw material is powdery, an alkali silicate prepared in a liquid state by adding a predetermined amount of water to the powdery alkali silicate is adopted. did.

[Reference Example 2]
In this reference example, as an alkali silicate composition having a silanol group constituting the binding liquid composition adopted in this example, an active silicate compound or composition is a soda salt compound. A liquid silicate alkali composition having active alkali silanol groups retained by adding water and reacting at least at room temperature will be described.

  The easily reactive silicate compound or composition used as the raw material of the silicate alkaline composition adopted in this example was selected from the easily reactive silicates shown in Table 5. On the other hand, the alkali metal compound used as the raw material of the silicate alkali composition was selected from commercially available reagents or industrial chemicals from sodium or potassium compounds shown in Table 6.

  The liquid silicate alkali composition is prepared by reacting at least a mixture of a readily reactive silicate, an alkali metal compound and water at a normal temperature for a predetermined time at a normal ratio. A liquid silicate alkali composition was prepared.

[Reference Example 3]
In this reference example, oxyacids of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements coexisting with an alkali silicate having a silanol group constituting the binding liquid composition adopted in this example Ions will be described.

The oxyacid ions of sulfur, phosphorus, carbon, or boron alone or in combination of two or more elements that coexist in the binding liquid composition in this example are selected from commercially available reagents or industrial chemicals, and are shown in Table 8.

[Reference Example 4]
In this reference example, the sulfur shown in Reference Example 3 was compared with the liquid alkali silicate prepared in Reference Example 1 and the alkali salt of silicic acid which was the modified silicate alkali composition prepared in Reference Example 2. A binding liquid composition in which a predetermined amount of oxyacid ions of phosphorus, carbon, or boron alone or in combination of two or more elements is allowed to coexist will be described.

  In addition to the liquid alkali silicate constituting the binding liquid composition in the present embodiment and the alkali salt of silicic acid which is a modified silicate alkali composition, sulfur, phosphorus, carbon or boron alone or Table 9 shows an example of the types and amount ratios in the binding liquid composition in which two or more kinds of combination element oxyacid ions are added and dissolved. In this example, a binding liquid composition other than this reference example can be prepared according to the purpose, application, and workability. The results of confirming the property that the stability of the binding liquid composition in the liquid state is ensured at room temperature for at least 30 days are also shown in Table 9.

[Reference Example 5]
In this reference example, the silicate system waste shown in Table 8 is used as a reactive powder composition having a particle size in the range of 5 μm to 1 mmφ mainly composed of an active aluminosilicate compound adopted in this example. A reactive powder composition composed of alkaline powder compositions of materials and minerals will be described.
The reactive powder composition is shown in Table 10, and harmful water-eluting element groups coexisting in the reactive powder composition (in this example, five elements of chromium, arsenic, selenium, boron and fluorine are representative). Table 11 shows the results of analysis of the amount of water elution (selected as) according to the Ministry of the Environment No. 46 test method.

[Reference Example 6]
In this reference example, a calcium-containing composition, a sulfate composition, a phosphate composition, a carbonate composition, a barium salt composition, an aluminum / iron salt composition, a buffer, which are the functionally imparted material groups adopted in this example. The band forming composition or the function-imparting composition will be described. In addition, the function provision raw material group of this invention is not limited to the compound and composition shown by this reference example.

  Calcium composition, sulfate group composition, carbonate composition, aluminum / iron salt composition, buffer zone forming composition, phosphate composition and barium salt composition adopted in this example include commercially available reagents, industrial Tables 12, 13, 14, 15, 16, 17, and 18 show the selected compositions selected from regenerated refined products of chemicals and wastes, prototypes based on the following preparation conditions, and the like.

The silicon phosphate selected as the phosphate group composition adopted in this example was selected from silicon phosphate [silica / 5 phosphorus oxide molar ratio of 3.0: 1. The pulverized product calcined at 950 ° C. at 0] was selected and shown in Table 15.

The barium silicate selected as the barium salt composition adopted in this example is classified as pulverized reaction waste obtained by reacting a mixture having a mixing molar ratio of barium oxide and silica of 1.0: 1.0 at 250 ° C. The crushed product was selected and shown in Table 15.

The functionality-imparting composition adopted in this example is selected from commercially available reagents, industrial chemicals and regenerated purified products of wastes, prototypes based on the following preparation conditions, etc., and shown in Table 19.

[Reference Example 7]
In this reference example, description will be made on a filler material composition composed of a granular material having a particle diameter in the range of 3 μm to 1 mmφ, which is a composite additive material group adopted in this example. Table 20 shows the filler material compositions typically handled in this example.

[Reference Example 8]
In this reference example, a bone material composition that is a composite additive material group adopted in this embodiment will be described.
As a general bone material composition, it was selected from sand and small gravel shown in Table 21, which are commercially available in the cement mortar industry, and a crushed granulated blast furnace slag.

The pores adopted in this example are filled with water, the bulk specific gravity is in the range of 0.8 to 2.0 g / cm ³ and the particle size is in the range of 0.1 to 4 mmφ. Or as a bone material composition which is a wet granular material made of an artificial inorganic lightweight aggregate, the bulk specific gravity shown in Table 22 is in the range of 0.8 to 2.0 g / cm ³ , and the particle size is Pore that is in the range of 0.1 to 4 mmφ and is adsorbed by adding water in an amount ratio of 100 parts by mass or less to 100 parts by mass of water-absorbing natural or artificial inorganic lightweight aggregate The wet lightweight aggregate was prepared by pre-filling with water.

Further, an organic lightweight aggregate capable of exhibiting a lightweight aggregate function having a specific gravity of 0.84 to 1.40 g / cm ³ and a particle size of 0.1 to 4 mmφ adopted in this embodiment. As the plastic granular material, the raw material of the plastic secondary processed products shown in Table 23, and the granular plastics or waste plastics having a particle diameter in the range of 0.1 to 4 mmφ are used. Selected from recycled products that have been refined and recycled into chips.

[Reference Example 9]
In this reference example, the surface of the miscellaneous object group or the particle aggregate group void, which is the substrate to be treated, adopted by the utilization processing method of the present invention will be described.
Table 25 shows the base materials constituting the surface of each miscellaneous substance group or the particle aggregate group void. The particle aggregate group voids were formed by introducing and filling the above-mentioned particle aggregate group into a 1-liter tin pail.

[Reference Example 10]
In the present reference example, the shape securing mold surface, the structural frame surface and the gap between the fiber braids, which are the processing target substrates adopted in the utilization processing method of the present invention, will be described.
In this example, the shape securing mold surface, which is the base material to be processed, is prepared for a test prototype by using a plate-shaped piece of about 30 × 30 cm square and a thickness of about 1 to 10 mm as a raw material. did. Further, the clearance between the fiber braids, which is the base material to be processed, is shown in Table 24 as a test prototype for assembling reinforcing bars or thick threads or bamboo strings in a lattice pattern.

[Reference Example 11]
In this reference example, an application-specific powder group, silicate powder or organic material group, which is a material to be processed for the contact mixture prepared in the mixing step in advance, will be described.

Examples of the granular material group according to use, which is the material to be treated adopted in this example, include commercially available reagents having a particle diameter in the range of 3 μm to 1 mmφ, industrial chemicals and waste regenerated refined products, prototypes, etc. Selected and shown in Table 26 below.

As the silicate granular material used as the material to be treated adopted in this example, an aggregate having a particle diameter in the range of 1 to 7 mmφ is made from commercially available reagents, industrial chemicals and wastes, purified products, and prototypes. Are shown in Table 27 below.

The organic material group that is the material to be treated adopted in the present embodiment includes organic substances having a particle size in the range of 1 to 10 mmφ in commercially available reagents, industrial chemicals and waste recycle products, prototypes, etc. And is shown in Table 28 below.

[Reference Example 12]
In this reference example, phosphorus-containing sewage-containing sludge and agricultural settlement drainage sludge, which are organic material groups adopted as processing target materials in this embodiment, will be described.
Table 29 shows the composition of the selected sewage-containing sewage sludge and agricultural settlement drainage sludge, and the amount of water leaching of harmful elements coexisting with these sewage-containing sludges.

[Reference Example 13]
In this reference example, the amount of water elution of harmful coexisting element groups in the in-situ soil ground adopted as the processing target material in this example is also displayed in Table 30.
Each collection site was the soil ground of a park or factory site, and the main component of the soil ground was not analyzed.

[Example 1]
In this example, the reactive liquid composition is added to the binding liquid composition and mixed homogeneously, and at least at room temperature, it is subjected to a shaping treatment through water to be detoxified and non-recycled. The water-containing composition, which is a basic water-containing composition having a treatment function that exhibits a mudification treatment, will be described.

  The binding liquid composition constituting the basic water-containing composition in the present example is a liquid alkali silicate or alkali silicate composition shown in Reference Example 4, which contains sulfur, phosphorus, carbon or boron. A binding liquid composition in which oxyacid ions of one or two or more combination elements coexist was selected. On the other hand, the reactive powdery composition constituting the basic water-containing composition was selected from the reactive powdery composition shown in Reference Example 4 which is mainly composed of an active aluminosilicate compound possessed by calcium.

The basic water-containing composition in this example was prepared by uniformly mixing the reactive powder composition with the binding liquid composition in the types and proportions shown in Table 31.
In addition, as a comparative example, in the binding liquid composition, it is selected as a constituent component of the binding liquid composition that does not allow oxyacid ions of sulfur, phosphorus, carbon, or boron alone or two or more combination elements to coexist. The case where only the alkali silicate is used as the binding liquid composition is selected.

  The evaluation of the basic water-containing composition in this example is based on the physical property evaluation test method in this specification, and measures the composition specific gravity, pH value and work working time in the basic water-containing composition. The specimens composed of the granular processed bodies prepared with the basic water-containing composition are evaluated by being subjected to pH value measurement and re-mudging test, and the results are also shown in Table 31.

  As a result of the above, the treated body obtained by curing and solidifying No. 2 water glass, which is a conventional technology as a comparative example, with quick lime at room temperature exhibits an alkalinity exceeding a pH value of 11 and has no water resistance and the treated body is submerged in water. In contrast, the basic water-containing composition of the present invention has sufficient workability and usable time, and the basic water-containing composition of the present invention is cured and solidified at room temperature. It is well understood that the body has been subjected to a detoxification treatment that fixes the alkali component, and has undergone a non-remudization treatment that ensures water resistance without re-mudging even when thrown into water.

[Example 2]
In this example, to the basic water-containing composition composed of a binding liquid composition and a reactive powder composition, a function-providing material group is added and mixed homogeneously, and at least at room temperature, the shape is formed through water. The water-containing composition, which is a functional water-containing composition having a treatment function that exhibits a detoxification treatment and a non-re-mudging treatment after being subjected to a dehydration treatment, will be described.

  The functional water-containing composition in this example is the type and amount shown in Table 30 for the functional material group selected from the functional material group shown in Reference Example 6 with respect to the basic water composition prepared in Example 1. The mixture was homogeneously mixed to prepare a juice-like water-containing composition.

  Evaluation of the functional water-containing composition in this example is based on the physical property evaluation test method in this specification, the composition specific gravity, pH value and work working time in the functional water-containing composition, The specimens composed of the granular processed bodies prepared with the functional water-containing composition are evaluated by subjecting them to pH value measurement and re-mudging test, and the results are also shown in Table 32.

  As a result of the above, the functional water-containing composition obtained by blending various types of function-providing material groups and mixing with the basic water-containing composition of the present invention has functionality according to each purpose, application, and workability. The treated body that has been provided with sufficient workability and has been cured and solidified at room temperature with the functional water-containing composition of the present invention is subjected to a detoxification treatment for fixing the alkaline component, It is well understood that a non-re-mudging treatment that does not re-mudged and ensures water resistance is performed even if it is put into the tank.

[Example 3]
In this example, a functional material group is added to a basic water-containing composition composed of a binding liquid composition and a reactive powder composition as needed, and a filler material that is a composite additive material group. The composition or the bone material composition is added and homogeneously mixed, and at least at room temperature, it is shaped through water and has a treatment function that exhibits harmless treatment and non-re-mudging treatment. The water-containing composition that is a composite water-containing composition will be described.

  The composite water-containing composition in the present example is a function-providing material group shown in Reference Example 6 and a packing material shown in Reference Example 7 as needed with respect to the basic water-containing composition prepared in Example 1. From the raw material composition or the bone material raw material composition shown in Reference Example 8, a composite additive raw material group was homogeneously mixed in the types and amounts shown in Table 33 to prepare a mortar-shaped water-containing composition.

  The evaluation of the composite water-containing composition in this example was carried out by measuring the composition specific gravity, pH value and working work time in the composite water-containing composition in accordance with the physical property evaluation test method in this specification, The specific gravity and compressive fracture of a specimen made of a treated body prepared in a cylindrical shape were evaluated by subjecting it to a pH value measurement and re-mudging test of a specimen made of a granular treated body prepared with a composite water-containing composition. The strength (q) is measured, and the results are also shown in Table 34.

  As a result, the basic water-containing composition of the present invention is provided with a function-providing material group as needed, and various stuffing material compositions or bone material composition are mixed and mixed. The composite composite water-containing composition is provided with functionality according to each purpose, application, and workability, and also exhibits the blending material composition and the blending material composition composition. The treated body that has sufficient workability and usable time and is cured and solidified at room temperature with the composite water-containing composition of the present invention has a certain level of strength and reinforcement provided by the compound additive material group. In addition, it is well understood that a detoxification treatment for immobilizing the alkali component is performed, and a non-remudization treatment is performed in which water resistance is ensured without re-mudging even if it is put into water.

[Example 4]
In this example, the water-containing composition of the present invention is adopted, and the processing step by the processing means that exerts the binding, solidification, and processing functions via water on the base of the surface of the structural casing that is the selected substrate to be processed. In addition, a water-containing, non-polluting, water-resistant treated body, which is a coated-type shaped body that is treated and prepared by a utilization processing method including a series of work steps including at least a curing step at normal temperature, will be described.

As the water-containing composition adopted in this example, a function-providing material group that effectively exhibits the binding / solidification / treatment function, particularly the binding function and the workability through the water in the utilization treatment method is added. For the functional water-containing composition or the composite water-containing composition to which the composite additive material group is added, the water-containing composition shown in Table 35 was selected as a coating agent.
A concrete plank (30 × 30 × 5 cm) was selected as the surface of the structural casing that is the substrate to be treated in this example.

  In the present embodiment, the coated shape body which is a non-pollution type water-resistant treated body is sprayed / sprayed, applied, pasted / adhered, or applied to the surface of a structural casing made of a concrete slab. Adopting a utilization processing method consisting of a series of work steps consisting of a processing step consisting of immersion and self-horizontal processing means and a curing step that is allowed to stand for at least 28 days at room temperature to prepare and treat the coated shape of the specimen. did.

  The evaluation of the water-containing non-polluting water-resistant treated body which is a coated shaped body in this example is based on the physical property evaluation test method in this specification, the specific gravity of each specimen prepared by treatment in the coated shaped body, It is subjected to a test of pH value, re-mudging test, and shear fracture adhesion force, and further measured and evaluated on behalf of chromium, arsenic, and fluorine in the coexisting element group, and the results are also shown in Table 35.

  As a result of the above, the water-containing non-polluted water-resistant treated body prepared and treated in this example has been subjected to a shaping process on a predetermined shape body made of a covering mold, and has a pH value of less than 10 and is a harmful element The group is fixed to be water-insoluble, non-polluted, and non-re-mudging treatment that ensures water resistance without re-mudging is performed. Non-polluting, water-resistant, water-resistant treated body that has properties that can be supplied to the fields of agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / ceramics materials, crafts / processing materials or adhesives / hardening agents It is well understood that

[Example 5]
In this example, the water-containing composition having high fluidity according to the present invention is adopted as a horizontal surface self-forming coating agent, and the binding / solidification via water is performed on the surface base of the structural casing that is the selected substrate to be treated.・ Covered shape body in which the horizontal floor surface is self-formed on the surface of the structural frame by operating a device that enables the processing function and subjecting it to a series of work steps by self-forming a smooth horizontal floor surface The water-containing pollution-free water-resistant treated body will be described.

A concrete plank (100 × 100 × 10 cm) was selected as the surface of the structural casing, which is the substrate to be treated in this example.
In addition, as the water-containing composition having high fluidity adopted in this example, old tire chips, river sand, and blast furnace slag crushed products are selected as aggregates, and the water-containing compositions having the types and blending ratios of the materials shown in Table 36 are used. Prepared in advance.

  As the covering-type shaped body that is a non-pollution type water-resistant treated body in this example, the selected water-containing composition is poured onto the surface of a structural frame made of a concrete slab, and horizontal by about 10 mm thickness by pouring means. A series of work steps in which the floor surface was self-formed by the fluidity of the water-containing composition and allowed to stand at room temperature for 28 days was adopted to prepare a coated shape having a horizontal floor surface.

  The evaluation of the water-containing non-polluting water-resistant treated body which is a coated shaped body in this example is based on the physical property evaluation test method in this specification, the specific gravity of each specimen prepared by treatment in the coated shaped body, It is subjected to a pH value, re-mudging test, and shear fracture adhesion test, and is further measured and evaluated on behalf of chromium, arsenic, and fluorine in the coexisting element group, and the results are also shown in Table 37.

  As a result of the above, the pollution-free water-resistant treated body prepared and treated in this example is shaped into a predetermined shape body consisting of a covering floor made of a horizontal floor surface that is self-forming by a fluid-saving composition due to the fluidity of the water-containing composition. It has been treated, has a pH value of less than 10 and has been subjected to a non-polluting treatment in which harmful elements are immobilized in water-insoluble and non-recyclable to ensure water resistance without re-mudging. Mud treatment has been applied, in the fields of recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials, crafts / processing materials or adhesives / hardening agents It is well understood that it is a water-containing, pollution-free, water-resistant treated body in which properties that can be supplied are ensured.

[Example 6]
In this example, the mortar-like water-containing composition itself of the present invention is adopted as a joint agent with a binding / adhesive agent, and binding / solidification via water is performed on the base of the surface of the structural casing that is the substrate to be treated.・ By attaching and adhering the surfaces of two types of structural enclosures by subjecting them to a series of work steps consisting of processing steps with processing means that exert processing functions and curing steps at least at room temperature The water-containing non-polluting water-resistant treated body which is a binding-type shaped body will be described.

As the surfaces of the two types of structural casings in this example, concrete planks (100 × 100 × 10 cm) and ceramic wall tiles (12 × 12 × 1 cm) were selected.
Moreover, as the mortar-like water-containing composition used as a joint agent in this example, a water-containing composition of sample number 03-07 prepared in Example 3 was selected by selecting river sand as an aggregate.

  As a binding-type shaped body that is a pollution-free water-resistant treated body in this example, a mortar-like water-containing composition that serves as a joint agent is used on a selected concrete plank to make use of binding and adhesion means. This is a binding-type shape with a ceramic wall tile attached to a thick plate by a series of work steps that are applied to a thickness of 5 mm, and a ceramic wall tile is crimped and pasted on it, and then allowed to stand at room temperature for 28 days. A water-containing pollution-free water-resistant treated body was prepared by treatment.

The evaluation of the water-containing non-polluting water-resistant treated body, which is a binding-type body in this example, is based on the physical property evaluation test method in this specification, in the binding-type body of each specimen prepared and processed. The shear fracture adhesion measured in the shear fracture adhesion test was 12 KN / m ² .

  As a result, the water-containing non-polluting water-resistant treated body, which is a binding-type shaped body prepared in this example, is a treated body obtained by curing and solidifying the mortar-shaped composite water-containing composition in Example 3. Similarly, the shaped body is processed into non-polluting treatment and non-re-mudging treatment. Recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fire resistance / It is well understood that it is a water-containing, non-polluting, water-resistant treated body with properties that can be supplied to the fields of heat insulation materials, ceramics / ceramic materials, crafts / processing materials or adhesives / hardening agents.

[Example 7]
In this example, the water-containing composition itself of the present invention is adopted as a binder / adhesive, and water-based binding is performed on the basis of a granule forming the surface of a miscellaneous object that is a substrate to be treated.・ By subjecting to a series of work steps consisting of processing steps that use solidification and processing functions and at least a curing step at room temperature, the surfaces of miscellaneous objects are gathered together to have a penetrating space. The water-containing non-polluting water-resistant treated body, which is a collective shaped body composed of an aggregate in the shape of a scoop, will be described.

The granules forming the surfaces of the miscellaneous objects in this example include the granules that are unspecified shaped products prepared and processed in Example 14, and the granules and aggregates that are existing products. Select a sphere, hollow body, cylindrical body, flake body, granule having a particle size of 2 to 12 mmφ and a bulk density of 0.2 to 3.5 g / cc, or 2-8 φmm from unspecified granules Commercialized pearlite grains with a bulk density of 0.5 to 0.6 (g / cc) [lightweight inorganic granular material obtained by rapidly heating obsidian at 800 to 1200 ° C. and volume-expanded (sample number CML- 03) and glass cullet (sample number CMW-02).
Further, the water-containing composition used as the binder / adhesive employed in this example includes a binding liquid composition, a reactive powder composition, a function-providing material group, a composite additive material group, and water as shown in Table 38. A water-containing composition composed of different kinds and amounts was selected.

  In the present embodiment, the sorghum-like aggregated shape body is integrated by adding water to the selected granule and wetting the pores and surface of the granule with water, and then adding a water-containing composition to the aggregate group of the granule. From the assembled shape having a penetrability in the shape of a cocoon, the granule aggregates were cast into a 300 × 300 mm mold having a thickness of 30 mm and allowed to cure at room temperature for at least 7 days. The following specimen was prepared.

  The evaluation of the water-containing, non-polluting, water-resistant treated body composed of the coral-shaped aggregate-shaped body prepared in this example was prepared and processed in this example in accordance with the physical property evaluation test method in this specification. The test samples were subjected to pH value, re-mudging test, specific gravity of the shape body, and elution test of representative element groups, and the results are also shown in Table 39.

  As a result of the above, the water-containing, non-polluted water-resistant treated body in the sorghum-shaped aggregate shaped body treated and prepared in this example has a pH value of less than 10 and has been subjected to a pollution-free treatment, Non-re-mudging treatment that ensures water resistance without re-mudging is performed, and it is useful as a soundproof / shut-off material, gas / liquid filter material, water purification material, etc. Moisture content that can be provided and can be supplied to the fields of recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials or craft / processing materials It is well understood that this is a non-pollution type water-resistant treated body.

[Example 8]
In this example, the water-containing composition itself of the present invention is adopted as a cementing / curing agent, and exhibits binding, solidification, and processing functions via water in the base of a form-secured formwork that is a substrate to be processed. The specific shape shape is removed from the form-assuring formwork by removing the predetermined shape body completed in the form-assured formwork by subjecting it to a series of work steps consisting of a processing step by the processing means and a curing step at least at room temperature. A non-polluting, water-resistant treated body that is treated and prepared into a body or a structural shaped body will be described.

In this embodiment, as a mold for securing the shape, which is the substrate to be treated, a cylindrical plastic container adopted in “Preparation of cylindrical specimen” (see JIS R5201) in the section of the physical property evaluation test method. (Φ5 × 10 cm) was selected.
As the water-containing composition itself of the present invention adopted in this example, the water-containing composition shown in Table 40 prepared in advance in Example 1, Example 2 and Example 3 was selected.

  The processing preparation of the specific type structure or the structure type shape body in this example is performed on a cylindrical plastic container in accordance with “Preparation of columnar specimen” described in the section “Method for evaluating physical properties”. After the selected water-containing composition is uniformly injected, the surface of the cylindrical plastic container is covered with a vinyl film and sealed, and subjected to a curing process for reaction and curing at room temperature (about 25 ° C.) for 28 days. Then, it was demolded to prepare a cylindrical specimen (φ5 × 10 cm: n = 3).

  The evaluation of the water-containing non-polluting water-resistant treated body treated and prepared for the specific shaped body or the structural shaped body in this example was conducted in accordance with the physical property evaluation test method in this specification. Subjected to specific gravity, pH value, re-mudging test, and uniaxial compressive fracture strength test for a specific shape or structural shape of the specimen, and also measured and evaluated on behalf of chromium, arsenic, and fluorine among the coexisting elements group The results are also displayed in Table 40.

  As a result of the above, the non-polluting, water-resistant treated body of the specific type structure or the structure type body prepared by treatment in this example imparts a function to the basic water-containing composition itself or the basic water-containing composition. The functional type or composite type water-containing composition itself to which the raw material group and the composite additional raw material group are added is shaped into a predetermined shape body in a mold having a predetermined shape, and the pH value is less than 10. And harmful elements are fixed in water-insoluble and non-polluted, and non-re-mudging is performed to ensure water resistance without re-mudging. Non-polluting, water-resistant, water-resistant treated body with properties that can be supplied in the fields of life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials or crafts / processing materials It is well understood.

[Example 9]
In this example, the water-containing composition itself of the present invention is adopted as a cementing / curing agent, and exhibits binding, solidification, and processing functions via water in the base of a form-secured formwork that is a substrate to be processed. The predetermined shape body completed in the form-assuring formwork is removed from the form-assured formwork by applying it to a series of work steps consisting of a processing step by the processing means and a curing step at least at room temperature, and a film shape The water-containing non-polluting water-resistant treated body processed and prepared in the mold shape will be described.

In this example, a thick plate (10 × 100 × 100 mm) made of a hard vinyl chloride resin was selected as the form-assuring mold that is the substrate to be treated.
As the water-containing composition of the present invention adopted in this example, the water-containing composition shown in Table 39 prepared in advance in Example 1, Example 2 and Example 3 was selected.

  The treatment preparation of the film-shaped mold body in this example is carried out by pouring, pouring, pouring, filling, self-weight / vibration of the selected water-containing composition onto a thick plate made of a selected hard vinyl chloride resin placed horizontally.・ Press-fit, mold-making, kneading, making use of the fitting means, pouring and injecting uniformly and horizontally to a thickness of about 3 mm, and subjecting to a curing process of reacting and curing at room temperature (about 25 ° C.) for 28 days Thereafter, it was demolded to prepare a membrane-like shaped specimen.

  The evaluation of the water-free, non-polluting, water-resistant treated body that is processed and prepared in the film-shaped body in this example is based on the physical property evaluation test method in this specification, and the film shape of each specimen prepared and processed. It is subjected to specific gravity, pH value, and re-sludge test in the mold-shaped body, and is further measured and evaluated on behalf of chromium, arsenic, and fluorine in the coexisting element group, and the results are also shown in Table 41.

  As a result of the above, the water-containing non-polluting water-resistant treated body, which is a film-shaped mold processed and prepared in this example, is a basic water-containing composition, or a function-added material group and a composite addition to the basic water-containing composition. A functional or composite water-containing composition to which a group of materials is added is formed into a film-like shape body on a mold that can secure the film-like shape, and has a pH value of less than 10 and is a harmful element The group is fixed to be water-insoluble, non-polluted, and non-re-mudging is performed to ensure water resistance without re-mudging. It is well understood that it is a water-containing, non-polluting, water-resistant treatment that has properties that can be supplied in the fields of agriculture / fisheries materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials or crafts / processing materials Is done.

[Example 10]
In this example, the water-containing composition itself of the present invention is adopted as a fluid cementing / curing agent, and the binding / solidification / treatment function via water is performed in the space group of the aggregate that is the substrate to be treated. Non-polluting, water-resistant, which is a water-containing integrated shape made of an integrated processed product that integrates the assembly group by subjecting it to a series of work steps consisting of a processing step by a processing means to be exhibited and a curing step at least at room temperature. The sex processing body will be described.

As the space of the assembly group which is the base material to be treated in this example, the sodium sulfate (salt salt) powder of the processing waste stored in the 200 L drum can lined with special cement is formed into an almond shape of 30 × 20 × 15 mm. The space of the collective group consisting of the tablet ellipsoidal sphere group consisting of pressure was selected.
As the fluidity cementing / curing agent as the water-containing composition in this example, the water-containing composition of sample number 05-03 prepared in Example 5 was selected.

  Pour, pour, pour, and pour 110 kg of the above water-containing composition excellent in fluidity into a 200 L drum can containing 260 kg of almond-shaped mirabilite that has been compressed into tablets, without leaving any voids in the drum can in 10 minutes. It was made into an integrated product by making full use of filling, dead weight, vibration and press-fitting means, and cured by leaving it to stand at room temperature for 28 days.

  As a result of the above, the pollution-free water-resistant treated body prepared and treated in this example was poured into a storage drum filled with trash waste so as not to leave a space. In a drum can, the shape is processed into a predetermined shape, and the harmful elements are fixed in water-insoluble with a pH value of less than 10 and subjected to pollution-free processing. In addition, non-re-mudging treatment that ensures water resistance without re-mudging has been performed. Recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery It is well understood that it is a water-containing, non-polluting, water-resistant treated body with properties that can be supplied in the field of materials, crafts and processed materials.

[Example 11]
In this example, the water-containing composition of the present invention was used as a treatment agent, and the water-containing composition was added to the granular material group for each use, which is the material to be treated, and added to the mixture to prepare a contact mixture and then treated. A series of operations consisting of a processing step by processing means that exerts binding, solidification and processing functions via water and a curing step at least at room temperature for the contact mixture in the base of the form-secured formwork that is the target substrate By attaching to the process, the processing body in the form-assuring mold is removed from the form-assuring mold, and there is no water content of brick-like interlocking, which is a fixed-type shape formed by a group of granular materials according to application. The pollution-type water-resistant treated body will be described.

As the granular group according to use in this example, kaolin, fused silica, and short fiber rock wool having a particle size in the range of 3 μm to 1 mmφ were selected.
As the utilization treatment agent that is the water-containing composition in this example, the water-containing composition prepared in Example 2 shown in Table 42 was selected.

  The brick-like interlocking, which is a fixed shape body in the present example, is prepared by mixing a predetermined amount of a water-containing composition uniformly with respect to the selected granular material group for each application, preparing a contact mixture beforehand, In accordance with “Preparation of cylindrical specimen” described in the physical property evaluation test method section, the mixture is homogeneously injected into the cylindrical plastic container, and the cylindrical plastic container The surface is covered with a vinyl film to be in a sealed state, subjected to a curing and reaction process at room temperature (about 25 ° C.) for 28 days, and then demolded to obtain a cylindrical specimen (φ5 × 10 cm: n = 3). It was prepared as a fixed shape body instead of brick interlocking.

  The evaluation of the water-containing, non-polluting, water-resistant treated body processed and prepared in the fixed shape body in this example is based on the physical property evaluation test method in this specification, and the fixed shape of each specimen prepared and processed. The specific gravity, pH value, re-mudging test, and uniaxial compressive fracture strength test are performed on the mold-shaped body, and the results are also shown in Table 42.

  As a result of the above, the water-containing, non-polluting, water-resistant treated body, which is a fixed-type shaped body assuming brick-like interlocking prepared in the present example, was selected for the selected granular material group for each application. The contact mixture obtained by adding the water-containing composition is mixed with a predetermined shape in a mold ensuring a predetermined shape, and is subjected to a non-polluting treatment with a pH value of less than 10. In addition, non-re-mudging treatment that ensures water resistance without re-mudging has been performed. Recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics industry -It is well understood that it is a water-containing, non-polluting, water-resistant treated body with properties that can be supplied in the field of pottery materials or crafts / processed materials.

[Example 12]
In this example, the water-containing composition of the present invention was used as a treatment agent, and the water-containing composition was added to the powder group for each use or the silicate powder that is the material to be treated in advance, and the contact mixture was mixed. Next, the processing mixture by the processing means that exerts the binding, solidification and processing functions via water, and at least at room temperature for the contact mixture in the base of the form-secured formwork that is the substrate to be processed By subjecting to a series of work steps consisting of a curing process, the predetermined shape body completed in the form securing mold is removed from the form securing mold, and the non-fired formed by the granular material group according to use Non-fired surface of non-fired sanitary ware and porcelain base materials coated and coated with non-fired sanitary ware and porcelain base materials with an organopolysiloxane-resistant inorganic paint / coating material Consisting of sanitary ware, porcelain class for non-polluting type water-resistant processing body will be explained.

  The contact admixture in this example is a kaolin, phosphorus-containing incinerated ash, or coal ash having a particle diameter in the range of 3 μm to 1 mmφ as a granular group or silicate powder according to use constituting the contact admixture. On the other hand, as a water-containing composition that is a utilization treatment agent, it is composed of a binding liquid composition, a reactive powder composition, a function-providing material group, a composite additive material group, and a type and amount ratio of water shown in Table 43. A water-containing composition was selected and mixed homogeneously in the proportions shown in Table 43.

  The non-fired sanitary ware and porcelain base material that is a fixed shape body in this example conforms to the “preparation of columnar specimen” described in the physical property evaluation test method in the pre-prepared contact mixture. Then, the selected contact mixture was poured into a cylindrical plastic container, and the surface of the cylindrical plastic container was covered with a vinyl film in a sealed state at room temperature (about 25 ° C.) for 28 days. After being subjected to a curing process for reaction and curing, it was removed from the mold, and a cylindrical specimen (φ5 × 10 cm: n = 3) was prepared as an unfired sanitary ware / porcelain base.

  The surface of the non-fired sanitary ware body prepared here is coated with an inorganic polymer excellent in weather resistance based on organopolysiloxane described in Nos. 2774235 and 2738904, which are patents of the present inventors. -Coated and processed to non-fired sanitary ware similar to sanitary ware and porcelain.

  The evaluation of the water-containing non-polluted water-resistant treated body treated and prepared in the non-fired sanitary ware and porcelain in this example is based on the physical property evaluation test method in this specification, and each specimen prepared and treated. The specific gravity, pH value, re-mudging test, uniaxial compressive fracture strength, and elution test of representative element groups in non-fired sanitary ware are shown, and the results are also shown in Table 44.

  As a result of the above, the water-containing non-polluting water-resistant treated body in this example is a contact obtained by adding the selected water-containing composition to the selected powder group or silicate powder and mixing them in advance. The base material of non-fired sanitary ware and porcelain is shaped in a mold that secures the predetermined shape, and then the surface of the non-fired sanitary ware and porcelain base is coated with organopolysiloxane. -Non-fired sanitary ware and porcelain that have been coated and prepared, and have a pH value of less than 10 and have been subjected to non-polluting treatment. It has been treated to ensure that it can be supplied to the fields of recyclable materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials, or crafts / processing materials. It is a non-polluting, water-resistant treated body that contains water Door is well understood.

[Example 13]
In this example, the water-containing composition of the present invention was used as a treatment agent, and the water-containing composition was added to the powder group for each use or the silicate powder that is the material to be treated in advance, and the contact mixture was mixed. And then subjecting the contact mixture to a series of working steps consisting of a processing step by processing means that exerts binding, solidification and processing functions via water and a curing step at least at room temperature, Non-polluting, water-resistant type consisting of unspecified shapes in the form of granular material, granular, granular, sandy or small lump that is made up of processing-target materials or silicate particles The processing body will be described.

  For the contact mixture in this example, a powder particle having a particle size in the range of 3 μm to 1 mmφ shown in Table 45 is selected as the powder group or silicate powder according to use constituting the contact mixture. On the other hand, as a water-containing composition that is a utilization treatment agent, it is composed of a binding liquid composition, a reactive powder composition, a function-providing material group, a composite additive material group, and a type and amount ratio of water shown in Table 45 A water-containing composition was selected and prepared by mixing homogeneously in the proportions shown in Table 45.

  The unspecified shape in the form of powder, granule, granule, sand or small lump in this example is described in “Preparation of granular test specimen” described in the section of physical property evaluation test method. In accordance with the above, the mixture is stirred in a Tarai type cement mortar mixer [Tairai type of φ100 × 0.5cm] having a rotating stirring shaft blade in the center of the stirring and mixing method, and mixed and stirred for about 10 minutes to make the whole mixture. However, after granulating into a granule with a particle size of 2 to 7 mmφ and curing for 24 hours in a sealable plastic container, the cultured organism is poured into water and cured in water at about 25 ° C. for 28 days. Each specimen was prepared by classification into a predetermined particle size range.

  The evaluation of the water-containing, non-polluting, water-resistant treated body prepared and processed into an unspecified shape in the form of granules, granules, granules, sand or small lump in this example is a physical property evaluation test in this specification In accordance with the method, the specific gravity, pH value, re-mudging test, breaking strength as a granule, and cone index were measured in each specimen made of each unspecified shape processed and prepared in this example. The results are shown in Table 46 together with the results of the dissolution test of the target element group.

As a result of the above, the water-containing non-polluting water-resistant treated body in this example is a contact obtained by adding the selected water-containing composition to the selected powder group or silicate powder and mixing them in advance. The admixture is processed and prepared into powder, granules, granules, sand or small lumps, and has a pH value of less than 10 and has been subjected to non-polluting treatment, ensuring water resistance without re-mudging. Non-re-mudging treatment is performed, and it is useful as a granule, aggregate, backfill material, adsorbent, etc. in an unspecified shape body, and has a corn index of 200 KN / m ² and is a civil engineering material. It is useful as a recycling material, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials, or craft / processing materials. It is well understood that it is a non-polluting, water-resistant treated body containing water.

[Example 14]
In this example, using the water-containing composition of the present invention as a treatment agent, the water-containing composition is additionally contacted with a silicate granular material having a specific surface area of 100 m ² / g or more, which is a material to be processed in advance. A series of work steps consisting of a processing step by processing means for mixing and preparing as a contact mixture and then exerting binding, solidification and processing functions via water and a curing step at least at room temperature. Non-pollution-type water-resistant treated body consisting of an unspecified shape that has a granular and adsorbing function and is formed by securing the specific surface area of the silicate powder that is the material to be treated. explain.

The contact mixture in this example is a synthetic zeolite having a specific surface area of 120 m ² / g shown in Table 43 or a paper having a specific surface area of 320 m ² / g as a silicate granular material constituting the contact mixture. -Select a silicate granule of charcoal-silicate that is a carbonized incineration ash of pulp waste material, and on the other hand, as a hydrous composition that is a utilization treatment agent, a binding liquid composition and a reactive powder form shown in Table 47 A water-containing composition composed of a composition, a function-providing material group, a composite additive material group, and a type and amount ratio of water was selected, and the mixture was uniformly mixed and prepared at the amount ratio shown in Table 47.

  The unspecified shape in the form of powder, granule, granule, sand or small lump in this example is described in “Preparation of granular test specimen” described in the section of physical property evaluation test method. In accordance with the above, the mixture is stirred in a Tarai type cement mortar mixer [Tairai type of φ100 × 0.5cm] having a rotating stirring shaft blade in the center of the stirring and mixing method, and mixed and stirred for about 10 minutes to make the whole mixture. However, it is granulated into granules with a particle size of 2 to 7 mmφ, placed in a plastic container that can be sealed, and is allowed to react and cure at room temperature (about 25 ° C) for 28 days unless otherwise specified. Each specimen was prepared by classification.

  The evaluation of the water-free, non-polluting, water-resistant treated body that has been processed and prepared into an unspecified shape in the form of granules in this example was performed in this example in accordance with the physical property evaluation test method in this specification. The specific gravity, pH value, re-mudging test, fracture strength as a granule, elution test of representative elements, and specific surface area measurement test were performed on the specimens made of each unspecified shape. Are also displayed in Table 48.

  As a result of the above, the water-containing non-polluting water-resistant treated body in this example is prepared by treating the hydrated silicate particles having a specific surface area with the water-containing composition and mixing the pre-mixed contact mixture into granules. Thus, it is difficult to handle, and the adsorbent granules having a specific surface area of at least about 80% are recovered by treating and preparing the adsorbable silicate granules into easy-to-handle granules and having a pH value of 10 Less polluted and non-re-mudging treatment is performed to ensure water resistance without re-mudging, recycling materials, life-related materials, agriculture / fishery materials, civil engineering -It is well understood that it is a water-containing, non-polluting, water-resistant treated body that ensures properties that can be supplied in the fields of building materials, fire-resistant / heat-retaining materials, ceramics / ceramic materials, or crafts / processed materials.

[Example 15]
In this embodiment, the hydrated ash composition of the present invention is used as a treatment agent, and the silicate powder is a carbon-silicate of dry distillation incineration ash to which phosphorus-containing incineration ash or phosphorus component as a material to be treated is added in advance. The water-containing composition is added to the body by addition contact mixing and prepared as a contact mixture, and then the processing step by the processing means for exerting the binding, solidification and processing functions via water to the contact mixture. In addition, by subjecting it to a series of work steps consisting of at least a curing step at room temperature, it is formed from unspecified shapes having a water purification function in granular form formed of silicate particles coexisting with the phosphorus component that is the material to be treated The pollution-free water-resistant treated body will be described.

  The contact admixture in this example is an incinerated ash containing phosphorus components shown in Table 45 as the silicate particles constituting the contact admixture or charcoal of dry distillation incinerated ash with the addition of phosphorus components- Select a silicate granular material that is a silicate, and on the other hand, a binding liquid composition, a reactive powder composition, a function-providing material group, a composite additive material shown in Table 45 as a water-containing composition that is a utilization treatment agent A water-containing composition composed of a group and the kind and amount ratio of water was selected and mixed homogeneously in the amount ratio shown in Table 49.

  The unspecified shaped body in the granular form in this example is the center of the stirring / mixing method based on the “preparation of granular specimen” described in the section of the physical property evaluation test method for the contact mixture prepared in advance. Take a talai-type cement mortar mixer (φ100 × 0.5cm talai type) with rotating stirring blades and granulate into granules of 2 to 7 mmφ while mixing and stirring for about 10 minutes to make the whole mixture. Each specimen was prepared by placing it in an open plastic container, reacting and curing at room temperature (about 25 ° C.) for 28 days, and classifying it into a predetermined shape range as necessary.

  In the present example, the evaluation of the water-containing non-polluted water-resistant treated body that has been processed and prepared into an unspecified shape in the form of granules was treated and prepared in this example in accordance with the physical property evaluation test method in this specification. The specific gravity, pH value, re-mudging test, breaking strength as a granule, and elution test of a representative group of elements are shown in Table 50, and the results are also shown in Table 50.

Furthermore, in order to confirm the water purification effect in the granular specimen treated and prepared in this example, it was subjected to a water purification treatment process of waste liquid containing harmful heavy metals, and the granular sample of this example was used. The removal rate of heavy metals was measured in a test to confirm the effect of removing harmful heavy metals in wastewater by trial.
The test for confirming the removal effect of heavy metals was conducted by filling a granular specimen into a vertical cylindrical tube (diameter: 30 × 200 mm) with a waste liquid coexisting with fluorine, cadmium, lead, and chromium at the concentrations shown in Table 47. From the upper part of the cylindrical tube filled with the specimen, the treated water was recovered from the lower part by a percolation system in which the waste liquid was injected at a rate of 100 cc / min to obtain a treated test solution. The concentration of fluorine, cadmium, and lead in the collected processing solution was measured to confirm the removal effect of heavy metals contained in the waste solution. The result of the removal effect of the heavy metals is also shown in Table 51.

  As a result of the above, the non-polluting, water-resistant treated body containing water in this example is silicic acid, which is a phosphorus-containing incinerated ash containing a selected phosphorus component or a carbon-silicate of dry distillation incinerated ash to which a phosphorus component is added. Granules in unspecified shapes that have been prepared by processing the contact mixture that has been pre-mixed with the water-containing composition selected for the salt powder granules into granules and have a pH value of less than 10 and are non-polluting In addition, non-re-mudging treatment that ensures water resistance without re-mudging is performed, and waste liquid coexisting with harmful heavy metals can be purified and removed. Water-containing, non-polluting water-resistant materials that have properties that can be supplied in the fields of resources, life-related materials, agriculture / fisheries materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials or crafts / processing materials It is well understood that it is a sex processing body.

[Example 16]
In this example, the water-containing composition of the present invention is used as a treatment agent, and is a material to be treated in advance, a group of heat- and fire-resistant base particles, a group of heat- and heat-insulating base fibers, The water-containing composition is added to and mixed with the granular material group or silicate granular material consisting of the granular material that has undergone a thermal history to prepare a contact mixture, and then the contact mixture is mixed. On the other hand, by subjecting it to a series of work steps consisting of processing steps with processing means that exerts binding, solidification and processing functions via water and a curing step at least at room temperature, it is a group of granular materials according to use that is the material to be treated A non-fired, water-resistant, non-polluted, water-resistant treated body composed of a specific shaped body or an unspecified shaped body that functions as an unfired fireproof, heat insulating, and heat insulating material is described.

  The contact mixture in the present example is a group of particles or silicate particles according to use constituting the contact mixture, as shown in Table 48, such as magnesia, alumina, alumina gel, silica, aluminosilicate, silicon carbide, Heat- and fire-resistant base material granule group made of silicon nitride; heat- and heat-insulating base material fiber granule made of calcium silicate (tobermorite, zonotolite), alumina fiber, rock wool, carbon fiber, metal fiber Group: Select a granular material composed of incinerated ash that has undergone a thermal history, while being composed of a binding liquid composition and a reactive powder composition shown in Table 52 as a water-containing composition that is a utilization treatment agent A base-type water-containing composition was selected and mixed homogeneously in the proportions shown in Table 52 to prepare a base material that would serve as an unfired fire-resistant, heat-insulating and heat-retaining material.

  The unspecified shape body serving as the fireproof / heat insulation / heat insulating material in the present example is described in the section of the physical property evaluation test method, which is a preliminarily prepared contact mixture that becomes a base material for the fireproof / heat insulation / heat insulation material. In accordance with “Preparation of cylindrical specimen”, the contact mixture prepared in a cylindrical plastic container is homogeneously injected, the surface of the cylindrical plastic container is covered with a vinyl film, sealed, and kept at room temperature for 28 days. After being subjected to a curing process of reaction and curing at (about 25 ° C.), it is removed from the mold and a cylindrical specimen (φ5 × 10 cm: n = 3) is prepared as an unspecified shape that becomes a fireproof, heat insulating and heat insulating material. did.

  The evaluation of the water-free, non-polluting, water-resistant treated body that has been processed and prepared into an unspecified shape in the form of granules in this example was performed in this example in accordance with the physical property evaluation test method in this specification. The specific gravity, pH value, re-mudging test, compressive strength, and elution test of representative element groups in the prepared cylindrical specimen are shown, and the results are also shown in Table 52.

Furthermore, a heat resistance test was performed in order to confirm the function as a fireproof, heat insulating and heat insulating material in the columnar specimen prepared by treatment in this example. The results are also displayed in Table 53.
In the heat resistance confirmation test, a cylindrical specimen was left and exposed in an electric heating oven at 600 ° C. for 2 hours. The specimen after the exposure had no abnormality and the strength retention rate of uniaxial compressive strength was 50% or more. The treated test specimen was evaluated as having “heat resistance”, and the treated specimen having an abnormality after exposure and having a uniaxial compressive strength strength maintenance rate of less than 50% was evaluated as “no heat resistance”. The heat shrinkage reduction rate (%) in the heat resistance confirmation test was determined by exposing a cylindrical specimen having a length dimension (Lo) to 600 ° C in an electric heating oven for 2 hours. The dimension (La) in the length direction of the test specimen that was not abnormal to the body was measured, and the thermal shrinkage reduction rate was expressed in%.

Heat resistance of treated body

  As a result of the above, the water-containing, non-polluting, water-resistant treated body in this example was subjected to heat and fire-resistant base material granular material group, heat-retaining and heat-insulating base material fiber-based granular material group, heat history Non-specific shapes that are fire-resistant, heat-insulating, and heat-retaining materials that have been prepared by treating a pre-mixed contact mixture by adding a selected water-containing composition to the material to be processed consisting of the granular material that has heat resistance. The heat shrinkage is small, the pH value is less than 10 and non-polluting treatment is performed, and further, non-re-mudging treatment is performed to ensure water resistance without re-mudging, and harmful It is possible to purify and remove waste liquids that coexist with heavy metals, such as recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials, or craft / processing materials. It is a water-free, pollution-free, water-resistant treated body that has properties that can be supplied to the field. Rukoto is well understood.

[Example 17]
In this example, the water-containing composition of the present invention is used as a treatment agent, and the water-containing composition is treated in advance with respect to the silicate powder particles that are in the powder particle state and coexist with harmful elements. The composition is added to the contact mixture and prepared as a contact mixture, and then the contact mixture is processed from a processing step by a processing means for exerting binding, solidification, and treatment functions via water and a curing step at least at room temperature. By subjecting to a series of work processes, water-free pollution that consists of a powder-type shape formed by insoluble and immobilizing harmful elements that coexist in the silicate powder that is the material to be treated The mold water-resistant treated body will be described.

For the contact admixture in this example, the wastes shown in Table 54 were selected as the silicate granular material of the granular material coexisting the harmful element group constituting the contact admixture, while the treatment agent used. A water-containing composition composed of a binding liquid composition and a reactive powder composition shown in Table 54 was selected as the water-containing composition, and the mixture was homogeneously mixed in the amount ratio shown in Table 54.
The granule-shaped body in this example was dried by taking a pre-prepared contact mixture in an open container made of PVC, and subjecting it to a curing process at room temperature (about 25 ° C.) for 28 days. It collected and prepared as a processing object in the state of a granular material.

  The evaluation of the water-containing non-polluting water-resistant treated body processed and prepared in the granular shape body in this example is based on the physical property evaluation test method in this specification, and each of the circles processed and prepared in this example. When subjected to pH value in columnar specimen, re-sludge test, elution test of element group, and further prepared in mortar form by adding water and cement to the powder type hair state in the powder state in this example In addition, it was necessary to ensure fluidity in the work, and the fluidity was measured as the working life. The results are also displayed in Table 55.

  As a result of the above, the water-containing non-polluting water-resistant treated body in this example is premixed by adding a water-containing composition to the silicate powder body in the state of powder body and coexisting with the harmful element group. The granules prepared by treating the contact admixture have a pH value of less than 10 and are subjected to non-polluting treatment by insolubilizing and immobilizing coexisting elements, etc., ensuring water resistance without re-mudging. Non-re-mudging treatment, segment auxiliary materials, high fluidity materials for mortars, hydraulic cement substitutes, non-fired fireproofing / heat insulation / thermal insulation materials, landfill / filling / filling materials, soil It can be applied to improved materials, customer soil, greening base materials, etc., recycled materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, fireproofing / thermal insulation materials, ceramics / pottery materials, crafts / processing Non-polluting, water-resistant water-resistant properties that ensure properties that can be supplied in the field of materials It is well understood that a physical body.

[Example 18]
In this example, using the water-containing composition of the present invention as a treatment agent, water-containing phosphorus-containing sludge and a phosphorus-containing incinerated ash containing odor, which is a raw material to be treated in advance, and further, if necessary, For the organic material group to be added and the deodorant having a deodorizing function of malodor, the water-containing composition is added to the contact mixture to prepare a contact mixture, and then water is added to the contact mixture. Addition agitation and composting and composting together with processing steps by processing means that exerts binding, solidification and processing functions, and curing steps at least at room temperature, aerobic microorganisms having fermentation composting function as needed Landfill / banking, medium-filled material, soil improvement material, black soil that is processed and prepared by processing together with the silicate powder or organic material group that is the material to be treated. Soil dressing, greening base material, the non-pollution water resistant treated is soil-shaped body of water that can be suitably provided in the cultivating plant material or the like will be described.

In this example, since the sewage hydrous sludge that gives off a bad odor is handled, a table prepared by selecting from materials such as commercially available reagents, industrial chemicals, and prototypes as a deodorant having a deodorizing function for bad odors. The formula deodorant shown in 56 was selected.

  The contact mixture in the present example is an organic material group consisting of phosphorus-containing sewage-containing sludge and agricultural settlement drainage sludge shown in Reference Example 12 as the silicate particles constituting the contact mixture. Select the material to be treated, and select the phosphorus-containing incinerated ash (sample number MS-05) shown in Reference Example 5 as the water conditioner for phosphorus-containing sewage-containing sludge and agricultural settlement drainage sludge. As the water-containing composition as an agent, a water-containing composition composed of a binding liquid composition and a reactive powder composition shown in Table 57 is selected, and homogeneously mixed in the amount ratio shown in Table 57 to make a contact mixture As prepared.

  The soil-type shaped body in the present example is obtained by taking a contact mixture prepared in advance in an open container, and with respect to 100 parts by mass of the contact mixture, Bacillus subtilis, Bacillus natto, which are commercially available as an aerobic microorganism group for composting, Composting treatment that adds about 1 part by mass of aerobic microorganisms cultured and grown on the basis of lactic acid bacteria and yeast, and fermentatively decomposes organic components that coexist while stirring at a rate of twice a day for 28 days at room temperature The sample was prepared by treating and preparing the soil-type shaped body. With respect to the collected soil-type shapes, a pH value and harmful element group elution test is performed, and a fertilizer test is performed in accordance with the Fertilizer Control Law. The results are also shown in Table 68.

  As a result, in order to adjust the moisture content of water-containing phosphorus-containing sludge that emits a foul odor, phosphorus-containing sewage sludge ash is incinerated ash, and a water-containing composition is added as a treatment agent to make contact mixture. Then, the soil-like shape body composed of a water-free, non-polluting, water-resistant treated body is prepared by adding aerobic microorganisms for composting to the contact mixture and subjecting it to composting and composting treatment. -It is well understood that it is a pollution-free water-resistant treatment body that can be suitably provided as a water-containing soil type shape body consisting of embankment, intermediate filling material, soil improvement material, black soil, customer soil, greening base material or plant growth material Is done.

  In addition, when performing composting and composting treatment in the preparation of soil-like shape bodies here, wastes of agricultural crops such as animal and plant industrial wastes which are organic materials group, forests and landscaping plants Logging waste, fallen leaves, sawn timber, livestock manure, animal and plant-related industrial and domestic waste, etc., combined with composting and composting, A soil-type shaped body that can be suitably provided for a plant growing material or the like can be prepared.

[Example 19]
In this example, the water-containing composition of the present invention is used as a treatment agent, and the water-containing composition is additionally contact-mixed with the in-situ soil ground, which is the material to be treated, to obtain a contact mixture, and the contact mixture is in-situ. By applying a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions through water, which are known and publicly used processing means, in the in-situ soil ground that is the processing target material Forms of water-containing shape in the original position consisting of piles, fences, roads, banks, banks, side roads, ditches, slopes, mountain forests, farmland / fields, residential land / public land or parks / gardens The pollution-free water-resistant treated body, which is a body, will be described.

  The in-situ soil ground used as the material to be treated in this example is selected from the in-situ soil ground in the soft ground state mainly composed of humus soil in Koga City, Ibaraki Prefecture shown in Reference Example 13, and is in this soft ground state. A soft ground soil mainly composed of humus soil collected from the in situ soil ground was used as a test object having a shape-type shape. Moreover, the water-containing composition shown in Table 69 was selected as the water-containing composition that is the utilization treatment agent adopted in this example.

  The shape-type shape body in this example was prepared by selecting a cylindrical plastic container in accordance with “Preparation of a cylindrical specimen” described in the section of the physical property evaluation test method for a contact mixture prepared in advance. The contact mixture was uniformly poured, the surface of the cylindrical plastic container was covered with a vinyl film, sealed, and subjected to a curing process of reaction and curing at room temperature (about 25 ° C.) for 28 days. A cylindrical specimen (φ5 × 10 cm: n = 3) was prepared as a specimen for a soft ground soil shape mold.

  The evaluation of the water-containing non-polluting water-resistant treated body processed and prepared in the shape-type shaped body in this example is based on the physical property evaluation test method in this specification, and each shape prepared and processed in this example. The pH value, the re-mudging test, and the uniaxial compressive strength of the test specimen composed of the mold-shaped body are measured, and subjected to the elution test of a representative element group. The results are also shown in Table 69.

  As a result, when the contact mixture is prepared in situ by adding the water-containing composition of the present invention to the in-situ soil ground in a soft ground state such as humus as a main component, the soft ground state The in-situ soil soil is a non-pollution-type water-resistant treated body that can be suitably provided as a shape-type shape body that has been detoxified in the in-situ and modified to an improved ground that exhibits a predetermined strength. It is well understood.

[Example 20]
In this example, using the water-containing composition of the present invention as a treatment agent, the water-containing composition is subjected to additional contact mixing with the in-situ soil ground contaminated with a harmful water-eluting element group that is a material to be treated. The contact mixture is used for a series of work processes that operate tools and devices that enable binding, solidification, and processing functions via water, which are known and publicly used processing means in situ. By doing so, the pollution-free water-resistant treated body which is a treated mold body by processing and modifying the soil soil ground in the contaminated soil which is the material to be treated to a pollution-free type in the original position will be described.

In-situ soil ground used as a material to be treated in this example is contaminated soil collected from in-situ soil ground contaminated with harmful water-eluting elements in Tokyo, Osaka and Tokushima City shown in Reference Example 13. Were the test subjects.
The water-containing composition shown in Table 70 was selected as the water-containing composition as the utilization treatment agent adopted in this example.

  The treated shaped body in this example is prepared by using a pre-prepared contact mixture in accordance with “Preparation of granular specimen” described in the section of physical property evaluation test method. Adopted in a talai-type cement mortar mixer [φ100 × 0.5cm talai type] with wings, mixed and stirred for about 10 minutes, granulated into granules with a particle size of 2 to 7 mmφ while making the whole mixture, open type A specimen comprising a treated shaped body was prepared by curing in a container of 28 days.

  The evaluation of the water-containing, non-polluting, water-resistant treated body treated and prepared in the treated shaped body in this example is based on the physical property evaluation test method in this specification, and each treatment prepared and treated in this example. The pH value, the re-mudging test, and the elution test of a representative group of elements in a specimen made of a mold-shaped body are given, and the results are also shown in Table 71.

  As a result, when the contact mixture is prepared in situ by adding the water-containing composition of the present invention to the in situ soil ground contaminated with harmful water-eluting element groups, it is in a soft contaminated soil state. A certain in-situ soil ground is preferably a non-polluting water-resistant treated body that can be suitably provided as a treated shaped body that has been insolubilized and immobilized in-situ and has been subjected to detoxification treatment at a pH value of 10 or less. Understood.

[Example 21]
In this example, the water-containing, non-polluted, water-resistant treated body prepared in advance using the water-containing composition of the present invention as a treatment agent is dried by applying a hot atmosphere within a temperature range of 950 ° C. or lower. The pH of the powder, granule, structure, specific shape or non-specific shape by subjecting it to a work process that makes full use of the dehydration process means that is composed of the dehydration and heat treatment means to be baked. Non-pollution-type water resistance that an anhydrous anhydrous shape body or ceramic-type shape body having a value of less than 10 is secured, shaped as a predetermined shape body, detoxified and non-remudized. The processing body will be described.

As the water-containing non-polluting water-resistant treated body in this example, the water-containing non-polluting type shown in Table 72 from the water-containing non-polluting water-resistant treated body prepared in each of the above examples. A water-resistant treated body was selected.
The anhydrous anhydrous shaped body or ceramic type shaped body in this example was subjected to heat treatment at a predetermined temperature for a selected water-containing non-polluting water-resistant treated body for a predetermined time, and each anhydrous shaped shaped body or ceramic type Shapes were processed and prepared.

  The evaluation of the anhydrous non-polluting water-resistant treated body comprising an anhydrous anhydrous shaped body or ceramic-type shaped body prepared and treated in this example is based on the physical property evaluation test method in this specification, and the pH value The re-mudging test and the elution test of typical element groups are shown, and the results are also shown in Table 72.

  As a result of the above, the water-containing non-polluted water-resistant treated body prepared in advance using the water-containing composition of the present invention as a utilization treatment agent is dried or fired by applying a hot atmosphere within a temperature range of 950 ° C. or lower. An anhydrous anhydrous shape or ceramic type shape that has been prepared by manual treatment by adding dehydration and heat treatment means to be detoxified, which has been shaped as a predetermined shape and secured by a water-containing, non-polluting, water-resistant treatment. Non-pollution-type water-resistant treated body that has been subjected to a detoxification process and a non-re-mudification process that has been processed into a predetermined shape with a pH value of less than 10 in a state where the treatment and the non-re-mudging process have been secured It is well understood that an anhydrous anhydrous shape or ceramic type shape is effectively utilized for each application.

Claims (53)

In a water-containing composition which is a basic water-containing composition that is mixed homogeneously by adding a reactive powder composition to a binding liquid composition;
The binding liquid composition described above has the following composition formula (1):

[Wherein, M is a single or a combination of two or more kinds of sodium or potassium elements, a is a number of 0.5 to 3, b, c, e and d are numbers of 0.05 to 1, and w is 4 Or an aqueous solution of an alkali metal element ion, a silanol group and an oxyacid ion of sulfur, phosphorus, carbon or boron alone or in combination of two or more elements. A liquid composition composed of a modified alkali silicate that is composed of an alkaline liquid composition that has a liquid state stability of at least 30 days at room temperature;
The above reactive powder composition is incineration ash for general and industrial waste, incineration ash for papermaking waste, phosphorus-containing incineration ash for sewage sludge / agricultural settlement drainage sludge, coal ash discharged from thermal power generation, iron making・ Aluminosilicate containing active calcium in a single or a combination of two or more selected from the group of slag discharged during steelmaking, lamellar clay minerals, low crystalline / amorphous silicates, volcanic ejecta, ecocement or portland cement It is composed of an alkaline powder composition having a salt compound as a main component and a particle diameter in the range of 5 μ to 1 mmφ, and the powder composition exhibits an activation function for the binding liquid composition. A pulverulent composition consisting of silicates;
50 to 140 parts by mass of a reactive powder composition composed of an active calcium-containing aluminosilicate compound with respect to 100 parts by mass of the binding liquid composition composed of a modified alkali silicate as the basic water-containing composition. Prepared as a basic water-containing composition in which a stable slurry is ensured by mixing in a homogeneous amount and in a homogeneous mixture;
The above water-containing composition has a composition specific gravity in the prepared basic water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has an alkaline pH value of 10 or more, and at least water at room temperature. A water-containing composition characterized by having a treatment function of performing a detoxification treatment and a non-re-mudging treatment by being subjected to a shaping treatment. The binding liquid composition is used in an amount of 1 to 40 parts by mass of an oxyacid alkali metal salt of sulfur, phosphorus, carbon or boron alone or in combination of two or more with respect to 100 parts by mass of water. And then dissolved, and then the following composition formula (2)

[Wherein M is a sodium or potassium element, a is a number of 0.5 to 4, w is a number of 4 to 30, and 50 to 200 parts by mass of a liquid alkali silicate having a silanol group represented by The water-containing composition according to claim 1, wherein the composition is homogeneously mixed.   The binding liquid composition is prepared by adding 80 to 140 parts by weight of water and 20 to 60 parts by weight of an alkali metal compound to 100 parts by weight of easily reactive silicates and mixing and stirring at least at room temperature. A liquid silicate alkali composition containing an alkali silicate having an alkali silanol group reacted as a main component is prepared, and then sulfur, phosphorus, carbon are added to 100 parts by mass of the liquid silicate alkali composition. Alternatively, the water-containing composition according to claim 1, wherein the composition is prepared by adding and dissolving an alkali metal salt of oxyacid of boron alone or in combination of two or more elements in an amount of 1 to 40 parts by mass.   The reactive powder composition contains at least 15 mg / kg of a harmful element group of one or a combination of two or more selected from the group of cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine or manganese. The water-containing composition according to claim 1, wherein the water-containing composition comprises a granular material containing an active calcium-containing aluminosilicate compound as a main component. In the water-containing composition which is a functional water-containing composition which is added to the basic water-containing composition according to any one of claims 1 to 4 and is mixed and mixed homogeneously with the addition of a function-providing material group;
The above-mentioned function-providing material group includes a calcium composition that replenishes alkalinity, a sulfate composition that improves the reinforcement of the cured body, a phosphate composition that improves the curing function and immobilizes fluorine, and the reinforcement of the cured body Carbonate composition that improves water resistance and water resistance, barium salt composition that can adjust the working life, aluminum / iron salt composition that is a compound of aluminum or iron, and a buffer zone that gives buffering properties to the formed hardened body It is composed of a forming composition, or a group of function-providing materials selected from the group of function-providing compositions imparting fillability and coloring / pigment properties, or a combination of two or more kinds;
The functional water-containing composition is a calcium composition, a sulfate composition, a phosphate composition, a carbonate composition, and a barium salt composition composed of a function-providing material group with respect to 100 parts by mass of the basic water-containing composition. 1 to 30 parts by mass of a functional material group consisting of 1 to 30 parts by mass of a material, an aluminum / iron salt composition, a buffer zone forming composition or a functional composition, or a combination of two or more functional ingredients. Prepared as a functional water-containing composition with a juice-like shape;
The water-containing composition has a composition specific gravity in the prepared functional water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has a pH value of 10 or more, and has water at least at room temperature. A water-containing composition characterized by having a treatment function of performing a detoxification treatment and a non-re-mudging treatment by being subjected to a shaping treatment. The calcium composition which is the said functional provision raw material group is the following composition formula (3)

[In the formula, w is a number of 2 or less including zero] represented by a calcium standard or a combination of two or more kinds of calcium compounds selected from the group of calcium hydroxide or calcium hydroxide. The water-containing composition according to claim 5, which is a function-providing material group. The sulfate composition which is the above-mentioned function-imparting material group has the following composition formula (4)

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. And a functionally imparted material group consisting of a single compound or a combination of two or more selected from the group consisting of basic salts and normal salts of sulfur oxyacid salt compounds of gold elements represented by Item 6. The water-containing composition according to Item 5. The phosphate group composition which is the said functional provision raw material group is the following composition formula (5)

[Wherein, G is an element of a single or a combination of two or more of the group of sodium, potassium, magnesium, calcium, barium, aluminum, zinc, titanium, silicon and iron, d is a number from 1 to 8, and t is a G element. Functionality-providing material composed of a single or a combination of two or more selected from the group of phosphorus oxyacid salt compounds of metal elements represented by the valence ÷ 2 number, w is a number of 10 or less including zero] The water-containing composition according to claim 5, which is a group. The carbonate composition which is the above-mentioned function-providing material group is represented by the following composition formula (6).

[Wherein, M is an alkali metal, Z is an alkaline earth metal, R is aluminum or trivalent iron, a, b and c are numbers of 20 or less including zero, n is a number of 2 or 3, and w is zero. A functionally imparted material group consisting of a single compound or a combination of two or more selected from the group consisting of basic salts and normal salts of carbon oxyacid salt compounds of gold elements represented by Item 6. The water-containing composition according to Item 5. The barium salt composition which is the above-mentioned function-imparting material group has the following composition formula (7)

[In the formula: e is a number of 4 or less, w is a number of 10 or less including zero] A barium salt selected from a group of single or a combination of two or more selected from barium salts soluble in an alkaline solution The water-containing composition according to claim 5, which is a functional group-providing material group of compounds. The aluminum / iron salt composition, which is the group of functional materials, has the following composition formula (8):

[Wherein T is an element of a single or a combination of two or more of silicon, sulfur, nitrogen and phosphorus elements, n is a number from 2 to 3, m is a number from 0.5 to 6, and w is zero. 28 It is composed of aluminum or a divalent or trivalent iron element oxysalt compound represented by the following number, or a single or a combination of two or more aluminum / iron salt compounds or a granular material that is a composition. The water-containing composition according to claim 5, which is a function-providing material group. The buffer zone forming composition that is the above-mentioned function-providing material group is represented by the following composition formula (9):

[Wherein, M is an alkaline gold element of lithium, sodium or potassium, Z is an alkaline earth metal of magnesium, calcium or zinc, g is a number of 1.0 to 4.0, and w is a number of 10 or less including zero. The water-containing material according to claim 5, which is a functional group-providing material group consisting of a boron oxyacid salt group of an alkali metal or an alkaline earth metal boron represented by the following formula: Composition.   The function-imparting composition as the group of function-imparting materials is a pigment, a colorant, an activator, a filler-dispersant, a magnetic substance, a catalyst, which is composed of a powder having a particle size in the range of 1 μm to 1 mmφ, Single or two or more selected from the group consisting of an oxidizing substance, a carrier, an aggregating and separating agent, an agrochemical, a herbicide, a fertilizer, a microbial nutrient, a plant seed and fungus, an antimicrobial agent, a water repellent, and a functional additive. The water-containing composition according to claim 5, which is a group of function-providing materials in combination. The composite additive material according to any one of claims 5 to 13 with the function-imparting material group according to any one of claims 5 to 13 to the basic water-containing composition according to any one of claims 1 to 4. In a water-containing composition that is a composite water-containing composition that is homogeneously mixed and mixed by adding groups;
The above composite additional material group is a filler material composition comprising a filler powder having a particle size in the range of 3 μ to 1 mmφ, or a bone material comprising an aggregate having a particle size in the range of 1 to 7 mmφ. It is composed of a single or multiple composite additive material group selected from the group of compositions;
The above composite water-containing composition is added with a function-providing material group in an amount of 1 to 30 parts by weight as required with respect to 100 parts by weight of the basic water-containing composition. It is prepared as a composite water-containing composition in which a mortar shape is ensured by adding 10 to 1300 parts by mass of a composite additive material group alone or in combination of a plurality of raw material compositions;
The above-mentioned water-containing composition has a composition specific gravity in the prepared composite water-containing composition in the range of 1.10 to 2.40 g / cm ³ , has a pH value of 10 or more, and is at least at room temperature. A water-containing composition characterized by having a treatment function of performing a detoxification treatment and a non-re-mudging treatment by being subjected to a shaping treatment.   The filler material composition, which is a composite additive material group, has a particle size of 1 mmφ or less, and is a dry product or a wet product containing water within a range of 50% by mass.・ Clays, ceramics, ceramics, carbonized products, charcoal, glass, volcanic products, slag, incinerated ash silicates, gypsum, hardened cement, sediment, sludge, sludge, inorganic oxides, metals , Wood / bamboo / plants / cereals, skin / bones, organic matter / plastics / rubber, synthetic / refined chemicals / wastes / single composites or powders of small combinations The water-containing composition according to claim 14, which is a group of function-providing materials in a lump shape, a sand particle shape, a fiber shape, or a flake shape.   The bone material composition, which is a composite additive material group, has a particle size in the range of 1 to 7 mmφ, and is made of minerals / rock crushed stones / sands / clays, ceramics / baked goods, carbonized products / charcoal, glass・ Volcanic products, slag, incinerated ash silicates, gypsum, hardened cement, sediment, sludge, sludge, inorganic oxides, metals, wood, bamboo, plants, grains, skin, bone, Spherical, granular, lump, plate, sand, chip, flake, and fiber made of organic materials, plastics, rubber, synthetic / refined chemicals or wastes, or a combination of two or more. The water-containing composition according to claim 14, which is a group of function-providing materials in a shape, a specific shape, and an unspecified shape.   The aggregate material composition which is the composite additional material group is an aggregate group made of plastics, waste plastics or old tires, and chipped in a particle size range of 0.1 to 4 mmφ. 16. The water-containing composition according to 16.   Thermal history silicate in which the composite additive material group coexists with a group of elements selected from the group of harmful cadmium, arsenic, mercury, lead, chromium, selenium, boron, fluorine and manganese. Claimed to be a single or a combination of two or more combinations selected from the group consisting of incinerated ash, coal ash, slag, sediment, sludge, hydrous silicates, soil consisting of minerals, rocks, dredged sand, and clays Item 15. A water-containing composition according to Item 14. The specific gravity of the hydrated composition in the basic hydrated composition, the functional hydrated composition or the composite hydrated composition as the hydrated composition is in the range of 1.10 to 1.90 g / cm ^3. The water-containing composition according to any one of claims 1 to 16, wherein the composition has high fluidity so that self-securing of the horizontal plane can be completed within 2 minutes when the product is poured on a horizontal plane frame within a square meter range. Adopting a water-containing composition that is a basic water-containing composition, a functional water-containing composition or a composite water-containing composition according to any one of claims 1 to 19, and using the water-containing composition itself as a material to be utilized, Based on the selected base material to be treated, it is subjected to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment, and processed into a water-free, pollution-free, water-resistant treatment body having a predetermined shape. In the utilization processing method to do;
The above-mentioned base materials to be treated are minerals, rocks, cinnabar sand, clays, ceramics, ceramics, dry distillation products, charcoal, glass, volcanic products, slag, incinerated ash thermal history silicates, gypsum, cement hardened bodies , Inorganic oxides, metals, wood / bamboo / plants, fibrous bodies, paper bodies, skin / bones / animal bodies, organisms / plastics / rubber, synthetic / refining chemicals or single waste materials Or a structure-type housing surface, a surface of a group of miscellaneous objects, a shape securing mold surface, a gap between fiber reinforcement groups or a particle assembly group void, which is prepared in advance by a combination of two or more kinds of composite materials;
The above-described series of work steps are performed with respect to the selected water-containing composition itself, exhibiting the binding, solidification, and processing functions on the basis of the selected base material to be processed, so that the water-containing composition itself has a predetermined shape. A processing step that is a processed product processed into a body, and then a curing step that completes the properties as a predetermined shape by advancing reaction and curing at least at room temperature with respect to the processed product;
The processing steps in the above-described series of work steps include spraying / spraying, coating / painting, self-horizontal flow, binding, adhesion, lamination, pasting / adhesion, at least at room temperature, on the base material to be treated. , Bonding, spreading, jointing, soaking, impregnation, gliding, assembly, integration, pouring, pouring, pouring, filling, dead weight, vibration, press-fitting, vacuum packing, molding, kneading, fitting, stirring, stirring A process of forming a processed product in a predetermined shape by a processing means that operates a processing tool or devices that enable binding, solidification, and processing functions via water consisting of mixing means;
The curing process in the series of work steps described above, the processed product in the air, water, sea, soil, solution, steam under normal pressure, pressurization, decompression conditions in the range from room temperature to 100 ° C., Release in a single atmosphere selected from the group of non-oxygen gas atmospheres or a multistage atmosphere of a combination of two or more, preferably at room temperature for at least 3 hours to allow the reaction / curing to proceed, and to have a predetermined shape A process for preparing and preparing a water-containing, non-polluting, water-resistant treated body that has completed its property characteristics;
The above-mentioned predetermined shape body is a hydrous coated shape body, a binding shape body, a collective shape body, a multi-layer shape body, a specific shape body, a structural shape body, a film-shaped body mainly composed of silicates. A shaped body, a reinforced shaped body or a predetermined shaped body that ensures properties as an integral shaped body;
The above utilization treatment method is applied to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment on the basis of the selected substrate to be treated, with the hydrous composition itself as the utilization treatment target agent. The water-containing composition itself is processed into a non-polluted, water-resistant, water-resistant treated body comprising a predetermined shaped body that has been subjected to a detoxification treatment and a non-re-mudging treatment by shaping at least at room temperature through water. A utilization method characterized by preparing. A basic water-containing composition, a functional water-containing composition, or a water-containing composition that is a composite water-containing composition according to any one of claims 1 to 19 is adopted as a utilization treatment agent, and the selected treatment target material is used. The water-containing composition is used as a utilization treatment agent to be mixed in an additional contact mixture to prepare a contact mixture, and the contact mixture is composed of utilization treatment means corresponding to the purpose, application, and working environment. In the utilization treatment method for treating and preparing the selected material to be treated into a water-containing, pollution-free water-resistant treatment body having a predetermined shape;
The above-mentioned processing target material is silicic acid composed of a granular material group by use consisting of a filling granular material having a particle diameter in the range of 3 μm to 1 mmφ, and an aggregate body having a particle diameter in the range of 0.1 to 7 mmφ. Treatment target consisting of a salt powder granule, an organic material group consisting of an organic substance having a particle diameter in the range of 1 to 10 mmφ, or a dry substance or a wet substance of a combination of two or more selected from an in-situ soil ground group Composed of materials;
The above-mentioned contact admixture represents the material to be treated selected in the mixing step on the basis of dry matter, and 100 parts by mass of the water-containing composition as the treatment agent, 10 to 90 parts by mass, and water as necessary. Is added at a rate of at least 5 parts by mass, and the entire apparatus is mixed by additional contact with equipment that can be added and mixed by mixing to ensure a homogeneous plastic, mud or wet powder. Prepared as a contact mixture;
The above-described series of work steps are performed on a preliminarily prepared contact mixture, based on the base material to be treated selected as necessary, or by making full use of processing tools and equipment, Demonstrating the processing function, processing the contact mixture into a processed product obtained by processing into a predetermined shape, and then proceeding the reaction / curing to the processed product at least at room temperature to obtain the properties as the predetermined shape Consists of a curing process that completes
The processing steps in the series of work steps described above are performed on the contact mixture based on the base material to be treated, which is selected as necessary, at least at room temperature by spraying / spraying, coating / painting, self-horizontal flow, and bonding. Adhesion, Adhesion, Lamination, Adhesion / Adhesion, Joining, Spreading, Jointing, Soaking, Impregnation, Splashing, Assembly, Integration, Pouring, Pouring, Injection, Filling, Self-weight / Vibration / Press-fitting / Vacuum-packing, Mold Processing tools that operate binding, solidification, and processing functions via water consisting of take-up, kneading, setting, agitation, agitation, and mixing means to make processed products in a predetermined shape. Process;
The curing process in the series of work steps described above, the processed product in the air, water, sea, soil, solution, steam under normal pressure, pressurization, decompression conditions in the range from room temperature to 100 ° C., Allow at least 15 minutes in a single atmosphere selected from the group of non-oxygen gas atmospheres or a multistage atmosphere of a combination of two or more, preferably at least 3 hours at room temperature to allow the reaction and curing to proceed. A process for preparing and preparing a water-containing, non-polluting, water-resistant treated body whose properties as a shaped body have been completed;
The above-mentioned predetermined shape body is a hydrated fixed shape body mainly composed of silicates, an unspecified shape body, a granule type shape body, a powder type shape body, a soil type shape body, a shape type shape body or a treatment type A predetermined shape having a characteristic as a shape;
The above utilization treatment method applies the water-containing composition itself as a utilization treatment target material to a series of work steps consisting of utilization treatment means according to the purpose, application, and work environment on the basis of the selected treatment target substrate. The water-containing composition itself is processed into a non-polluted, water-resistant, water-resistant treated body comprising a predetermined shaped body that has been subjected to a detoxification treatment and a non-re-mudging treatment by shaping at least at room temperature through water. A utilization method characterized by preparing. The above-mentioned raw material group for processing, which is the material to be treated, is composed of a dry-distilled product of silica gel, alumina gel, clays, aluminum silicates, zeolite, charcoal, organic matter having a specific surface area of 10 m ² / g or more. Aggregate group with adsorbing function; granule group of heat-resistant and refractory base material consisting of magnesia, alumina, alumina gel, silica, aluminosilicate, carbide, nitride with particle size in the range of 1-5mmφ A group of fiber-based particles of a heat-insulating and heat-insulating substrate composed of calcium silicate (tobermorite, zonolite), alumina fiber, rock wool, carbon fiber, metal fiber; It is a group of granular materials by use, consisting of a group of dehydrated and water-retaining particles composed of aluminium-based granular material, sediment / sludge, clay aluminosilicate, zeolite, amorphous alumina / silica. The utilization processing method according to claim 21.   The above-mentioned material to be treated is silicate granular material, minerals, rocks, cinnabar sand, layered clay minerals, incineration ash of general and industrial wastes, papermaking, sawdust, agricultural products, food processing wastes Incinerated ash, phosphorus-containing incinerated ash from sewage sludge / agricultural settlement drainage sludge, coal ash discharged from thermal power generation, slag discharged from iron and steel making, low crystalline / amorphous silicates, volcanic ejecta, ecocement, Portland cement The utilization treatment according to claim 21, which is a silicate granule mainly composed of a single or a combination of two or more kinds of silicates selected from the group consisting of sediment and sediment, dredged soil, sludge, sludge and phosphorus-containing sludge. Method.   The organic material group which is the material to be treated is spherical, granular, lump, plate, sand, chip, flake, fiber, specific shape, unspecified with a particle size in the range of 1 to 10 mmφ Containing 50% by mass or more of organic substances including water in the shape of crops, waste from agricultural crops, food processing waste, felling debris from forests and landscaping plants, fallen leaves, sawdust, sewage・ Phosphorus sludge from agricultural settlements, livestock manure, animal and plant-related industries and household wastes, industrial and household garbage and leftovers, and single or a combination of two or more selected from animal and plant-based organic materials The utilization processing method according to claim 21, which is a group of organic materials.   The in-situ soil ground, which is the material to be treated, is the soil ground, soft ground, road / bank / bank, humus land, mountainous land, farmland / field, culvert / gutter, residential land / public land, factory The utilization processing method according to claim 21, which is an in-situ soil ground composed of store land, park / garden or slope / plant cultivation base.   Within a temperature range of 950 ° C. or less, with respect to a water-containing, non-polluting, water-resistant treated body having a predetermined shape that has been treated and prepared using a series of work steps comprising the utilization treatment method according to claim 20 or 21. A dehydration process that makes full use of a dehydration and heat treatment means that is dried or baked by giving a thermal atmosphere is applied to the work process consisting of a dehydration process, which is shaped and rendered harmless and non-re-mudging. A utilization treatment method characterized in that it is treated and prepared into an anhydrous, non-polluting, water-resistant treated body in which an anhydrous shaped body or ceramic shaped body is secured. The water-containing composition in the basic water-containing composition, the functional water-containing composition, or the composite water-containing composition according to any one of claims 1 to 19, and the water-containing composition according to any one of claims 20 to 25. It is a predetermined shape body that has been processed and prepared using a processing process consisting of processing means that exhibits binding, solidification and processing functions through water, which is a utilization processing method, and a series of work processes at least at room temperature. In a water-containing, pollution-free, water-resistant treated body;
The above-mentioned predetermined shape body is a hydrous coated shape body, a binding shape body, a collective shape body, a multi-layer shape body, a specific shape body, a structural shape body, a film-shaped body mainly composed of silicates. Shaped body, reinforced shaped body, integrated shaped body, fixed shaped body, unspecified shaped body, granular shaped body, granule shaped shaped body, soil type shaped body, shaped shaped shaped body or treated shaped shaped body Is a predetermined shape body in which the properties of
The above pollution-free water-resistant treatment body adopts a water-containing composition and, if necessary, a series of utilization treatment methods using water according to the purpose, application, and work environment on the basis of the substrate to be treated. A predetermined shape of water containing a specific gravity of 1.20 to 2.40 g / cm ³ is applied to the working process, and the pH value is less than 10, and a non-polluting treatment is performed. Has been subjected to a non-re-mudging process that ensures water resistance without re-mudging, and a uniaxial compressive strength of a predetermined shape is ensured to be 10 KN / m ² or more as required, Shear fracture adhesion is secured at 5KN / m ² or more, recycling materials, life-related materials, agriculture / fishery materials, civil engineering / building materials, soil ground improvement materials, fire resistance / thermal insulation materials, ceramics / ceramic materials, Crafts / processing materials, adhesives / curing agents, water purification / treatment agents Ku is non-polluting type waterproof processed, characterized in that the available supply property is ensured in the field of plant growth substrates.   The above-mentioned coated-type body adopts the water-containing composition itself as a coating agent, and sprays / sprays, applies, affixes / adheres, immerses, self-horizontal flow on the surface of the structural casing that is the substrate to be treated. By applying a series of work processes that operate processing tools and devices that enable binding, solidification and processing functions via water consisting of binding, bonding or laminating means, coating and adhesion on the surface of the structural frame Water-coated type consisting of floors with layers, walls / partition plates, pillars, roofs / tiles, piers, structures, foundation structures, processing bodies, ceramics / ceramics, crafts or self-forming floors The pollution-free water-resistant treated body according to claim 27, which is a shaped body.   The coating-type shaped body adopts a water-containing composition itself having a high fluidity as claimed in claim 19 and capable of completing self-securing of 10 Kg within 2 minutes as a horizontal plane self-forming coating agent. A series of operations to ensure a smooth horizontal floor surface by self-formation of the horizontal floor surface by operating a device that enables a binding function via water that allows pouring and pouring at the base of the surface of the structural frame that is the material 29. The pollution-free water-resistant treatment body according to claim 28, which is a water-containing coating-type body in which a horizontal floor surface is self-formed on the surface of the structural housing by being subjected to a work process.   The above-mentioned binding-type body adopts the water-containing composition itself as a binding / adhesive, and is bonded / adhered, laminated, pasted / attached, bonded on the basis of the surface of the structural casing that is the substrate to be treated, By applying a series of work processes that operate tools, equipment, etc. that enable binding, solidification and processing functions via water consisting of jointing, soaking, impregnation, pouring, injection or filling means, 28. The pollution-free water-resistant treated body according to claim 27, which is a water-containing binder-shaped body comprising a plywood, a joint adhesive, a binder, an adhesive, a patch or an adherent on the surface.   The aggregated shape body adopts the water-containing composition itself as a binder / adhesive, and is a granular material having a particle size of 20 μ to 40 mmφ as a substrate to be treated, spherical, hollow, cylindrical, Bonding, bonding, soaking, impregnation, pouring, pouring, filling, mixing, stirring, stirring, etc. on the surface of the surface of various objects consisting of granules, aggregates, granules, junk, flakes, or discrete shapes By attaching to a series of work steps that operate tools and equipment that enable binding, solidification, and processing functions through water consisting of mixing means, it is in the form of an agglomerated worm-like shape on the surface of miscellaneous objects 28. A non-polluting water-resistant structure according to claim 27, which is a water-containing aggregated shape comprising an aggregate, a carrier, a water permeable plate, a ventilation body, a soundproof body, a fireproof body, a water purification / treatment body, a heat insulating / heat insulating material or a catalyst body. Sexual treatment body.   The cocoon-like aggregate that is the aggregate-type shape is an aggregate that has a through space and is integrated, and is a water-containing aggregate-type shape that is an aggregate that is in the shape of a heel. 31. Non-pollution type water-resistant treated body according to 31.   The multi-layered shape body adopts the water-containing composition itself as a binder / adhesive, and has a particle size of 20 μ to 40 mmφ which is a substrate to be treated. Granules, granules, garlic bodies, flake bodies Binding, solidification, treatment via water consisting of binding, adhesion, soaking, impregnation, pouring, pouring, filling, stirring, stirring, mixing means at the base of the surface of miscellaneous objects consisting of lumps and granules Covers, multilayers, adsorbents, deodorants, water purifiers with a coating adhesion layer on the surface of miscellaneous objects by attaching them to a series of work processes that operate tools and devices that enable functions 28. A pollution-free water-resistant treated body according to claim 27, which is a water-containing multi-layer shaped body comprising a heat insulating and heat insulating material or a catalyst body. Charcoal, amorphous silica, activated silicic acid, activated silicate, in which the coated body that is the multilayer shaped body is an adsorbent powder having a specific surface area of 100 m ² / g or more as a substrate to be treated , Diatomaceous earth, activated alumina, activated aluminosilicate compound, carbon-containing carbonized product, adsorptive incinerated ash, or selected from granule materials having two or more combined adsorptive properties selected from the group of zeolites, and selected water content Adopting the composition itself as a binder / adhesive and operating tools / equipment that enable water binding, solidification, and processing functions through immersion, impregnation, pouring, stirring, stirring, and mixing means. By including a series of work steps, an adsorbent or deodorant containing a specific surface area of 50 m ² / g or more by applying an adhesion coating film on the surface of adsorbent granules on the surface of miscellaneous objects. 34. The pollution-free water-resistant treated body according to claim 33, which is a multilayered body of water.   The above-mentioned specific type shape body adopts the water-containing composition itself as a cementing / curing agent, and pours, pours, injects, fills, self-weight / vibration / press-fit in the base of the shape-assuring mold that is the substrate to be treated By applying a series of work processes to operate tools and devices that enable binding, solidification, and processing functions via water consisting of stuffing, mold making, kneading, and fitting means, it will be in the form securing form Remove the finished shape from the form securing form, pillars, plates / bricks, fences / walls, tiles, pipes, fibers / strings, spheres, U-shaped grooves, wave extinguishing materials, 28. The pollution-free water-resistant treatment body according to claim 27, which is a water-containing specific shape body comprising fishing reefs, crafts or tanks / containers.   The structural type shape body adopts the water-containing composition itself as a cementing / curing agent, and pours, pours, injects, fills, self-weight / vibration Inside the form-locked formwork by applying a series of work processes to operate tools and devices that enable binding, solidification and processing functions through water consisting of press-fitting, mold-making, kneading, and fitting means. 28. A non-polluting water-resistant structure according to claim 27, which is a water-containing structural shape body comprising pillars, walls / plates, bridge piers, frame bodies, and foundation structures, by removing the predetermined shape body completed in step 1 from the form ensuring form. Sexual treatment body. The membrane-like mold body adopts the water-containing composition itself as a cementing agent, and pours, pours, pours, fills, fills with its own weight / vibration / press-fit, into the base of the shape-secured mold that is the substrate to be treated. In a form-assuring formwork, it is subjected to a series of work processes that operate tools, devices, etc. that enable binding, solidification, and processing functions via water consisting of means of molding, kneading, and fitting. 28. A pollution-free water-resistant treatment according to claim 27, wherein the completed predetermined shape body is removed from the form-assuring mold and is a water-containing film-like shape body comprising a plate, a film / film body, and a film-like specific shape body. body.   The reinforcing-type shaped body adopts the water-containing composition itself as a cementing / curing agent, and is composed of assembling of metal reinforcement as a substrate to be treated, woven / nonwoven fabric of fibers, and assembly of organic rods. Tools and devices that enable binding, solidification, and processing functions via water consisting of pouring, pouring, pouring, filling, self-weight, vibration, press-fitting, mold-making, kneading, and fitting means at the base of the gap in the braid The column / pipe, bridge pier, frame, foundation structure frame, foundation of specific shape, board / brick / inter It is a water-containing film-like shape body consisting of rocks, corals / wall materials, pipes, fibers / strings, spheres, U-shaped grooves, wave-dissipating materials, fishing reefs, crafts, containers or specific shapes Item 27. A pollution-free water-resistant treated product according to Item 27.   The one-piece shape body adopts the water-containing composition itself as a cementing / curing agent, and is a base material to be treated, such as trash, waste, and low-level radioactive waste, having a particle size of 0.3 to The space of the aggregate group formed by aggregation of powder, granule, granule, galactor, flake, shape, or volume holder in the range of 9 mmφ, and accommodated in the container as necessary Pouring, pouring, pouring, filling, gathering / integration, self-weight / vibration / press-fitting, molding, kneading, binding / stirring / stirring / stirring / mixing functions via water 28. A water-containing monolithic shape body comprising an integrated processed product obtained by integrating a collective group by subjecting a series of work steps to operate tools and devices that enable operation. Nothing Harm-type water-resistant treated.   The above-mentioned regular shaped body is a contact mixture obtained by adding the water-containing composition to the use-specific powder group or silicate powder, which is the material to be treated, by additional contact mixing with the water-containing composition as a treatment agent. And then pouring, pouring, pouring, filling, self-weight / vibration / press-fitting, mold taking, kneading, fitting through the water in the base of the form-assuring mold that is the substrate to be treated By applying a series of work processes that operate tools and equipment that enable binding, solidification, and processing functions, the predetermined shape completed in the form-assuring formwork is removed from the form-assuring formwork. , Pillars and pipes made of materials to be treated, plates / brick / floor / interlocking, fences / wall materials, membranes, fibers / strings, spheres, U-shaped grooves, wave-dissipating blocks, fishing reefs, crafts Products, containers and non-firing sanitary objects in specific shapes No pollution waterproof treatment of claim 27, wherein the steady-shape body of water consisting of a base of the vessel, crockery.   The non-fired sanitary ware and porcelain substrate in the above-mentioned fixed shape body is made of non-fired sanitary ware and porcelain with an inorganic paint / coating agent or an organic paint / coating agent having organopolysiloxane as a main component. 41. A non-fired sanitary ware / porcelain-like, water-containing, fixed-shaped body made of a non-fired sanitary ware / porcelain that is coated and coated with a non-fired surface. Pollution-type water-resistant treated body. Unspecified shape body The above-mentioned unspecified shape body is added to the water-containing composition by use of the water-containing composition as a treatment agent, and the water-containing composition is added to and mixed with the granular material group or silicate powder body that is the material to be treated. Tools / apparatus that make contact mixture, then mix, agitate, mix, knead, extrude, rolling granulation, crushing, water-binding, solidification and processing functions By subjecting to a series of work processes that operate, the segment auxiliary material that is formed from the material to be processed, granular, granular, sandy, small lump, high fluidizing material of mortar, landfill・ Filling, filling / filling materials, synthetic aggregates, granules with specific surface area, non-fired fireproofing / insulation / thermal insulation materials, catalysts, water purification / treatment agent, plant growth base, soil, soil improvement An unspecified shape body containing water or a civil engineering material. The pollution-free water-resistant treated product according to 7. Silicate powder that is a material to be treated in which the granule that is the granule-shaped body is water-containing soil, sludge, sludge, and sediment, and if necessary, anhydrous incineration ash is added to the moisture regulator The water-containing composition is added to the granule by addition contact mixing to obtain a contact mixture, and the contact mixture is stirred, stirred, mixed, kneaded, extruded, tumbled granulated, crushed, and bound via water.・ Granules formed from hydrated soil, sludge, sludge, and bottom sediment silicate granules by attaching to a series of work processes that operate tools and equipment that enable solidification and processing functions , Granular, sandy. Segment auxiliary material in the form of a small block, high fluidity material of mortar, landfill / filling, filling material, fillers, synthetic aggregates, catalysts, water purification / treatment agent, plant growth base, soil, improvement of soil 43. The pollution-free water-resistant treatment body according to claim 42, which is a hydrous granule-shaped body made of a material or a civil engineering material. The granular material having a specific surface area which is the above-mentioned unspecified shape body is an adsorbent granular material having a specific surface area of 100 m ² / g or more as a granular material group or silicate granular material according to use which is a material to be treated. 1 or more selected from the group consisting of charcoal, amorphous silica, activated silicic acid / silicate, diatomaceous earth, activated alumina / aluminosilicate compound, carbon-containing carbonized product, adsorptive incineration ash or zeolite Select a combination of adsorbent powder materials, and have a specific surface area of 50 m ² / g or more, and adsorbents in the form of granules, granules, sands, or small lumps, water containing deodorants or water purifiers The pollution-free water-resistant treated body according to claim 42, which is an unspecified shape body. The above-mentioned granule-type treated body uses the water-containing composition as a treatment agent, and the water-containing composition is added to and mixed with the silicate granular material that is the material to be treated to form a contact mixture, and the contact mixture is formed. Specific tools and devices that make it possible to attach, solidify, and treat, which are commonly used in the food industry, chemical industry, ceramic industry, civil engineering, construction, construction industry, etc. Kneading / granulating machine, agitating granulator, pressure granulating / molding machine, flow casting molding machine, extrusion granulating / molding machine, packing granulating / molding machine, cement milk, concrete and ceramic products Various granulators / molding machines, coating machines, adhesion / binding machines, coating / coating machines, floor adjustment equipment, flow-feeding tools / equipment adopted at the processing site for secondary products such as A series of work processes that operate It is attached to the processing step in the above, and the segment auxiliary material in the form of granules, granules, sand or small lumps, mortar high fluidization material, landfill / filling, Filling materials, fillers, aggregates, catalysts, water purification / treatment agents, plant growth base materials, soil improvement materials or civil engineering materials, with a cone index (qc = kN / m ² ) of 200 or more. 43. The pollution-free water-resistant treated product according to claim 42, which is a hydrous granular shaped product.   The water purification / treatment agent, which is the granular shape body, selects a granular material made of incinerated ash containing phosphorus or hydrous sludge containing phosphorus as a silicate granular material to be treated. 43. A non-polluting, water-resistant product according to claim 42, which is an unspecified water-containing body comprising a water purifying / treating agent that captures fluorine and heavy metals that are in the form of granules, sand, small lump, and are dissolved in water Processing body.   The non-fired fireproof, heat insulating, and heat insulating material that is the above-mentioned irregular shape body is a material group or silicate granular material that is a material to be treated, such as magnesium, alumina, alumina gel, silica, aluminosilicate. Heat- and fire-resistant base material powders composed of salt, carbide, and nitride; heat-insulating and heat-insulating base materials made of calcium silicate (tobermorite, zonolite), alumina fiber, rock wool, carbon fiber, and metal fiber Group of powder and granule group: Select powder material consisting of incinerated ash that has been subjected to thermal history, and water content including non-fired fireproof, heat insulating and heat insulating materials in granular, granular, sandy, and small lump shapes The pollution-free water-resistant treated body according to claim 42, which is an unspecified shape body.   The above-mentioned powder type processed material is obtained by using the water-containing composition as a treatment agent, and adding the water-containing composition to the silicate powder material, which is a material to be treated, to make a contact mixture. Agitating, stirring, mixing, kneading, extrusion, rolling granulation, crushing, and attaching to a series of work processes that operate tools and devices that enable binding, solidification, and processing functions via water. Segment auxiliary material made of silicate powder, which is the material to be treated, high fluidizing material for mortars, alternative to hydraulic cement, non-fired fireproof, heat insulating and heat insulating material, horizontal floor 28. The pollution-free water-resistant treated body according to claim 27, which is a water-containing powder-type shaped body comprising a surface self-shaped body, fillers, landfill / banking / filling material, soil improvement material, guest soil or greening base material.   The above-mentioned mortar high fluidizing material, which is a granular shape, is selected from various incinerated ash granular materials as silicate granular materials to be treated, granular, granular, sand 49. The pollution-free water-resistant treated body according to claim 48, which is a water-containing, granular-shaped body made of a highly fluidized material that is in the form of a solid or a small lump and can ensure good fluidity in cement mortars.   The above-mentioned soil-type shaped body is a hydrated phosphorus sludge that is a material to be treated and a silicate granular material composed of phosphorus-containing incinerated ash, and a group of organic materials as necessary. To the deodorant having a deodorizing function of bad odor, the water-containing composition is added to the contact mixture to make a contact mixture, and the contact mixture is stirred, stirred, mixed, kneaded, extruded, rolling granulation, Aerobic with fermenting composting function as needed by attaching to a series of work processes that operate tools and equipment that enable binding, solidification and processing functions via water consisting of crushing and classification means Landfill and embankment formed by using the phosphosilicate-containing granular material or organic material group that is the processing target material by adding and stirring and mixing together with the microorganism group and applying composting and composting treatment , Nakagome , Soil conditioner, black soil, soil dressing, greening base material or non-polluting water-resistant process of claim 27, wherein the soil-shaped body of water consisting of plant growth material.   The above-mentioned shape-type shape body uses the hydrous composition as a treatment agent, and the hydrous composition is additionally contact-mixed with the in-situ soil ground that is the material to be treated to form a contact mixture, and the contact mixture is in-situ. By applying a series of work processes to operate tools and equipment that enable binding, solidification, and processing functions via water consisting of known and official processing means, in-situ soil soil that is the processing target material Formed shape of water content in the original position consisting of piles, fences, roads, banks, banks, side roads, ditches, slopes, mountain forests, farmland / fields, residential land / public land or parks / gardens. The pollution-free water-resistant treated body according to claim 27.   The treatment-type shape body uses the water-containing composition as a treatment agent, and the water-containing composition is additionally contact-mixed with the in-situ soil ground that is the material to be treated to form a contact mixture, and the contact mixture is in-situ. By applying a series of work processes to operate tools and equipment that enable binding, solidification, and processing functions via water consisting of known and official processing means, in-situ soil soil that is the processing target material A water-containing treated shape body consisting of soil ground, mountain forest land, farmland / fields, roads, residential land / public land, factories / stores, or parks / gardens, which has been improved / repaired from the formed soil. The pollution-free water-resistant treated body according to claim 27.   27. A hot atmosphere within a temperature range of 950 ° C. or less, which is a utilization treatment method according to claim 26, with respect to the water-containing, non-polluting, water-resistant treated body comprising the predetermined shape body according to any one of claims 27 to 52. By applying a dehydration process means to a dehydration process consisting of a dehydration and heat treatment means that is dried or baked to give a powder, granule, structure, specific shape or An anhydrous anhydrous shape body or ceramic type shape body having a pH value of less than 10 that is a specific shape body is secured, shaped as a predetermined shape body, detoxified and non-remudized. Non-polluting water-resistant treated body characterized by