JP2004530533A - 低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 - Google Patents
低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 Download PDFInfo
- Publication number
- JP2004530533A JP2004530533A JP2002555914A JP2002555914A JP2004530533A JP 2004530533 A JP2004530533 A JP 2004530533A JP 2002555914 A JP2002555914 A JP 2002555914A JP 2002555914 A JP2002555914 A JP 2002555914A JP 2004530533 A JP2004530533 A JP 2004530533A
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- JP
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- Prior art keywords
- sodium
- polyphosphate
- acid
- beverage
- silica gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 238000000034 method Methods 0.000 title claims abstract description 69
- 235000013361 beverage Nutrition 0.000 title claims abstract description 53
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 42
- 239000003463 adsorbent Substances 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 79
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 53
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 38
- 239000001205 polyphosphate Substances 0.000 claims abstract description 38
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 38
- 239000003352 sequestering agent Substances 0.000 claims abstract description 37
- 239000002594 sorbent Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 30
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 30
- 239000000017 hydrogel Substances 0.000 claims abstract description 26
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 21
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 21
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000376 reactant Substances 0.000 claims abstract description 12
- 239000000741 silica gel Substances 0.000 claims description 41
- 229910002027 silica gel Inorganic materials 0.000 claims description 41
- 239000002253 acid Substances 0.000 claims description 34
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 22
- 238000005406 washing Methods 0.000 claims description 12
- 239000002243 precursor Substances 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims 2
- 235000013405 beer Nutrition 0.000 abstract description 20
- 230000008569 process Effects 0.000 abstract description 19
- 239000000356 contaminant Substances 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 22
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 239000000499 gel Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 238000001179 sorption measurement Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000015107 ale Nutrition 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- 241000206761 Bacillariophyta Species 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000013124 brewing process Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229940006199 ferric cation Drugs 0.000 description 1
- 229940045203 ferrous cation Drugs 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000020004 porter Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 102000012498 secondary active transmembrane transporter activity proteins Human genes 0.000 description 1
- 108040003878 secondary active transmembrane transporter activity proteins Proteins 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 235000015106 stout Nutrition 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
- C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
- C12H1/0408—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of inorganic added material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Silicon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/760,353 US6555151B2 (en) | 2001-01-12 | 2001-01-12 | Process for making and using a low beverage soluble iron content adsorbent and composition made thereby |
| PCT/US2002/001005 WO2002055190A2 (en) | 2001-01-12 | 2002-01-14 | Process for making and using a low beverage soluble iron content adsorbent and composition made thereby |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007241602A Division JP2008080332A (ja) | 2001-01-12 | 2007-09-18 | 低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004530533A true JP2004530533A (ja) | 2004-10-07 |
| JP2004530533A5 JP2004530533A5 (enExample) | 2005-12-22 |
Family
ID=25058843
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002555914A Pending JP2004530533A (ja) | 2001-01-12 | 2002-01-14 | 低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 |
| JP2007241602A Pending JP2008080332A (ja) | 2001-01-12 | 2007-09-18 | 低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007241602A Pending JP2008080332A (ja) | 2001-01-12 | 2007-09-18 | 低い飲料可溶性鉄含有量の吸着剤を作製するための方法およびこれらを使用する方法、ならびにこれらによって作製された組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6555151B2 (enExample) |
| EP (1) | EP1385620A2 (enExample) |
| JP (2) | JP2004530533A (enExample) |
| KR (1) | KR20030077574A (enExample) |
| CN (1) | CN1284620C (enExample) |
| AU (1) | AU2002234246A1 (enExample) |
| BR (1) | BR0206382A (enExample) |
| CA (1) | CA2433658A1 (enExample) |
| MX (1) | MXPA03006304A (enExample) |
| WO (1) | WO2002055190A2 (enExample) |
| ZA (1) | ZA200305278B (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2857599B1 (fr) * | 2003-07-16 | 2006-02-24 | Realdyme | Procede biologique de detoxication d'un milieu liquide alimentaire et milieu liquide alimentaire detoxifie obtenu selon ce procede |
| US7229655B2 (en) * | 2003-12-30 | 2007-06-12 | Pq Corporation | Composition of, and process for using, silica xerogel for beer stabilization |
| WO2008024952A2 (en) * | 2006-08-25 | 2008-02-28 | World Minerals, Inc. | Processes for reducing beer soluble iron in diatomaceous earth products, diatomaceous earth products and compositions thereof, and methods of use |
| CN105712357A (zh) * | 2008-09-26 | 2016-06-29 | 英默里斯筛选矿物公司 | 含有降低的可溶性金属水平的硅藻土产品、其制备方法及使用方法 |
| US20110180470A1 (en) * | 2010-01-27 | 2011-07-28 | James Jeffrey Harris | Aqueous iron removal process and apparatus |
| US9005687B2 (en) * | 2010-03-15 | 2015-04-14 | Millercoors Llc | Methods for reducing soluble metal ions in diatomaceous earth filter aids |
| ES2868093T3 (es) | 2012-09-17 | 2021-10-21 | Grace W R & Co | Medio y dispositivos de cromatografía |
| CN103788989B (zh) * | 2012-10-29 | 2015-11-25 | 中国石油化工股份有限公司 | 一种蒸汽裂解方法 |
| WO2015168383A1 (en) | 2014-05-02 | 2015-11-05 | W. R. Grace & Co.-Conn. | Functionalized support material and methods of making and using functionalized support material |
| US10695744B2 (en) | 2015-06-05 | 2020-06-30 | W. R. Grace & Co.-Conn. | Adsorbent biprocessing clarification agents and methods of making and using the same |
| IT201800004721A1 (it) * | 2018-04-19 | 2019-10-19 | Dispositivo per la stabilizzazione del vino ed altre bevande vegetali e relativo procedimento di stabilizzazione. | |
| CN111747419B (zh) * | 2020-07-08 | 2023-08-22 | 青岛美高集团有限公司 | 一种降低硅胶中重金属含量的方法 |
| US12435295B1 (en) | 2021-11-15 | 2025-10-07 | Sciessent Llc | Water-based anti-odor fabric treatment compositions |
| GB202305914D0 (en) | 2023-04-21 | 2023-06-07 | Pq Silicas Uk Ltd | Clarifying agents |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1215928A (en) | 1967-04-28 | 1970-12-16 | Unilever Ltd | A process for reducing haze in beer |
| CH510115A (de) * | 1968-11-22 | 1971-07-15 | Brauerei Ind Ag F | Verfahren zur Herstellung eines Adsorptionsmittels |
| US3800031A (en) * | 1972-04-06 | 1974-03-26 | Grace W R & Co | Process for preparing silica hydrogel |
| US3846337A (en) * | 1972-07-20 | 1974-11-05 | Union Oil Co | Phosphate-silica-aluminosilicate compositions of improved crushing strength and methods of preparing the same |
| US4134857A (en) | 1977-02-07 | 1979-01-16 | Johns-Manville Corporation | Use of tannic or gallic acid to produce low beverage soluble iron content filter aid |
| FR2471949A1 (fr) | 1979-12-20 | 1981-06-26 | Rhone Poulenc Ind | Procede de fabrication de silices precipitees fines |
| US4508742A (en) | 1983-05-06 | 1985-04-02 | Pq Corporation | Treating beer to prevent chill haze and metal contamination |
| US4847235A (en) * | 1986-02-03 | 1989-07-11 | Scm Glidco Organics Corp. | Silica product |
| US4758440A (en) * | 1986-02-03 | 1988-07-19 | Heem Peter V D | Process for chillproofing a malt beverage and silica product for chillproofing |
| US5215733A (en) * | 1986-04-25 | 1993-06-01 | Unilever Patent Holdings B.V. | Manufacture of silica gels using shear to reduce the particle size prior to washing with a hydrocyclone |
| GB8707526D0 (en) | 1987-03-30 | 1987-05-07 | Unilever Plc | Amorphous silicas |
| US4847532A (en) * | 1988-05-27 | 1989-07-11 | Tektronix, Inc. | Tensed shadow mask assembly for cathode-ray tube |
| JPH038710A (ja) * | 1989-06-05 | 1991-01-16 | Jgc Corp | 瀘過性の良い微粉末シリカゲルの製造法 |
| US5641532A (en) * | 1995-12-15 | 1997-06-24 | The Procter & Gamble Company | Beverages having stable flavor/cloud emulsions in the presence of polyphosphate-containing preservative systems by including gellan gum |
| WO2000066705A2 (en) | 1999-05-03 | 2000-11-09 | Pq Holding, Inc. | Process and composition for reducing chill haze in beverages |
| RU2160777C1 (ru) * | 2000-02-16 | 2000-12-20 | Открытое акционерное общество "Воскресенские минеральные удобрения" | Способ осветления пива |
-
2001
- 2001-01-12 US US09/760,353 patent/US6555151B2/en not_active Expired - Lifetime
-
2002
- 2002-01-14 EP EP02701048A patent/EP1385620A2/en not_active Withdrawn
- 2002-01-14 AU AU2002234246A patent/AU2002234246A1/en not_active Abandoned
- 2002-01-14 KR KR10-2003-7009304A patent/KR20030077574A/ko not_active Withdrawn
- 2002-01-14 CA CA002433658A patent/CA2433658A1/en not_active Abandoned
- 2002-01-14 JP JP2002555914A patent/JP2004530533A/ja active Pending
- 2002-01-14 BR BR0206382-4A patent/BR0206382A/pt not_active IP Right Cessation
- 2002-01-14 MX MXPA03006304A patent/MXPA03006304A/es active IP Right Grant
- 2002-01-14 CN CNB02803659XA patent/CN1284620C/zh not_active Expired - Fee Related
- 2002-01-14 WO PCT/US2002/001005 patent/WO2002055190A2/en not_active Ceased
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2003
- 2003-03-17 US US10/390,361 patent/US20030170361A1/en not_active Abandoned
- 2003-07-08 ZA ZA200305278A patent/ZA200305278B/en unknown
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2007
- 2007-09-18 JP JP2007241602A patent/JP2008080332A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1284620C (zh) | 2006-11-15 |
| WO2002055190A3 (en) | 2003-11-13 |
| US20030170361A1 (en) | 2003-09-11 |
| CN1503693A (zh) | 2004-06-09 |
| MXPA03006304A (es) | 2003-09-16 |
| US20020094364A1 (en) | 2002-07-18 |
| BR0206382A (pt) | 2004-02-03 |
| KR20030077574A (ko) | 2003-10-01 |
| WO2002055190A2 (en) | 2002-07-18 |
| AU2002234246A1 (en) | 2002-07-24 |
| US6555151B2 (en) | 2003-04-29 |
| EP1385620A2 (en) | 2004-02-04 |
| JP2008080332A (ja) | 2008-04-10 |
| ZA200305278B (en) | 2004-10-20 |
| CA2433658A1 (en) | 2002-07-18 |
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