JP2004527610A - 含フッ素エチレンコポリマー - Google Patents
含フッ素エチレンコポリマー Download PDFInfo
- Publication number
- JP2004527610A JP2004527610A JP2002571556A JP2002571556A JP2004527610A JP 2004527610 A JP2004527610 A JP 2004527610A JP 2002571556 A JP2002571556 A JP 2002571556A JP 2002571556 A JP2002571556 A JP 2002571556A JP 2004527610 A JP2004527610 A JP 2004527610A
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- weight
- ethylene
- comonomer
- fluorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001038 ethylene copolymer Polymers 0.000 title claims abstract description 42
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000005977 Ethylene Substances 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 3
- 229920001577 copolymer Polymers 0.000 claims description 59
- 239000000203 mixture Substances 0.000 claims description 32
- -1 methacrylate ester Chemical class 0.000 claims description 27
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 22
- 229910052731 fluorine Inorganic materials 0.000 claims description 22
- 239000011737 fluorine Substances 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000010526 radical polymerization reaction Methods 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- 125000005647 linker group Chemical group 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- 229920001897 terpolymer Polymers 0.000 description 11
- 239000000835 fiber Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- 229920002313 fluoropolymer Polymers 0.000 description 8
- 239000004811 fluoropolymer Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000003709 fluoroalkyl group Chemical group 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 238000004255 ion exchange chromatography Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000005001 laminate film Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920006355 Tefzel Polymers 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- NZZFYRREKKOMAT-UHFFFAOYSA-N diiodomethane Chemical compound ICI NZZFYRREKKOMAT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical compound C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- QFARLUFBHFUZOK-UHFFFAOYSA-N sulfamoyl hydrogen sulfate Chemical compound NS(=O)(=O)OS(O)(=O)=O QFARLUFBHFUZOK-UHFFFAOYSA-N 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27391201P | 2001-03-07 | 2001-03-07 | |
| PCT/US2002/007058 WO2002072648A2 (en) | 2001-03-07 | 2002-03-07 | Fluorine-containing ethylene copolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004527610A true JP2004527610A (ja) | 2004-09-09 |
| JP2004527610A5 JP2004527610A5 (enExample) | 2005-12-22 |
Family
ID=23045954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002571556A Withdrawn JP2004527610A (ja) | 2001-03-07 | 2002-03-07 | 含フッ素エチレンコポリマー |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6953830B2 (enExample) |
| EP (1) | EP1366092B1 (enExample) |
| JP (1) | JP2004527610A (enExample) |
| CA (1) | CA2438317A1 (enExample) |
| DE (1) | DE60211315T2 (enExample) |
| WO (1) | WO2002072648A2 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1481015A2 (en) * | 2002-03-07 | 2004-12-01 | E.I. Du Pont De Nemours And Company | Fluorine-containing ethylene copolymers |
| EP1556421B1 (en) * | 2002-10-29 | 2006-03-29 | E.I. du Pont de Nemours and Company | Ethylene copolymer with fluorine-containing graft and a process for preparing the same |
| EP2069440B1 (en) * | 2006-08-02 | 2011-09-28 | Battelle Memorial Institute | Electrically conductive coating composition |
| US20210061979A1 (en) * | 2018-02-13 | 2021-03-04 | Sumitomo Chemical Company, Limited | Polymer, resin composition, molded article, and production method for polymer |
| CN112480296B (zh) * | 2019-09-12 | 2023-10-27 | 浙江省化工研究院有限公司 | 一种亲水改性的乙烯-三氟氯乙烯共聚物、其制备方法及应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE463666A (enExample) * | 1942-10-26 | |||
| US2599640A (en) * | 1944-08-04 | 1952-06-10 | Du Pont | Copolymers of chlorotrifluoroethylene, an olefinic hydrocarbon and a vinyl carboxylate |
| GB596943A (en) * | 1944-08-04 | 1948-01-14 | Du Pont | Process for the production of copolymers containing chlorotrifluoroethylene and vinyl esters |
| US3194796A (en) * | 1962-03-22 | 1965-07-13 | Du Pont | Elastomeric fluorocarbon terpolymers of vinylidene fluoride, hexafluoropropylene and a halogen free polar monomer |
| US3445434A (en) * | 1964-10-30 | 1969-05-20 | Du Pont | Copolymers of tetrafluoroethylene,ethylene and an olefinic acid |
| JPS5244578B2 (enExample) * | 1974-04-23 | 1977-11-09 | ||
| US4065613A (en) * | 1975-03-17 | 1977-12-27 | E. I. Du Pont De Nemours And Company | Alternating copolymers of alkyl acrylate/ethylene/branching agents |
| US5210166A (en) * | 1985-11-07 | 1993-05-11 | Basf Aktiengesellschaft | Copolymers of ethylene with polyalkylene glycol (meth)acrylates |
| US5096962A (en) * | 1990-11-29 | 1992-03-17 | Lord Corporation | Acrylic adhesive compositions |
| FR2689134B1 (fr) * | 1992-03-27 | 1997-08-14 | Atochem Elf Sa | Copolymeres d'ethylene ou de derives de l'ethylene et de (methiacrylates fluores leur procede de fabrication et leur application aux semelles de ski. |
| IT1264662B1 (it) * | 1993-07-05 | 1996-10-04 | Ausimont Spa | Perflurodiossoli loro omopolimeri e copolimeri e loro impiego per il rivestimento di cavi elettrici |
| US5623036A (en) * | 1994-09-12 | 1997-04-22 | Elf Atochem S. A. | Method for making a surface hydrophobic |
| US6165560A (en) * | 1997-05-30 | 2000-12-26 | Micell Technologies | Surface treatment |
| EP0911347B1 (en) * | 1997-10-15 | 2006-08-23 | E.I. Du Pont De Nemours And Company | Copolymers of maleic anhydride or acid and fluorinated olefins |
| US6476114B2 (en) * | 1997-11-19 | 2002-11-05 | 3M Innovative Properties Company | Thermoplastic polymer film comprising a fluorochemical compound |
| WO1999025760A1 (en) * | 1997-11-19 | 1999-05-27 | Minnesota Mining And Manufacturing Company | Thermoplastic polymer film comprising a fluorochemical compound |
| US20020119319A1 (en) * | 2001-02-28 | 2002-08-29 | Asahi Glass Company, Limited | Fluorine-containing copolymer, composition and laminate |
-
2002
- 2002-03-07 CA CA002438317A patent/CA2438317A1/en not_active Abandoned
- 2002-03-07 WO PCT/US2002/007058 patent/WO2002072648A2/en not_active Ceased
- 2002-03-07 EP EP02709804A patent/EP1366092B1/en not_active Expired - Lifetime
- 2002-03-07 DE DE60211315T patent/DE60211315T2/de not_active Expired - Fee Related
- 2002-03-07 JP JP2002571556A patent/JP2004527610A/ja not_active Withdrawn
- 2002-03-07 US US10/469,293 patent/US6953830B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6953830B2 (en) | 2005-10-11 |
| DE60211315T2 (de) | 2007-05-24 |
| US20040077811A1 (en) | 2004-04-22 |
| CA2438317A1 (en) | 2002-09-19 |
| WO2002072648A2 (en) | 2002-09-19 |
| DE60211315D1 (de) | 2006-06-14 |
| EP1366092B1 (en) | 2006-05-10 |
| EP1366092A2 (en) | 2003-12-03 |
| WO2002072648A3 (en) | 2002-12-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050307 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050307 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20061005 |