CN114502795A - 拒水拒油剂组合物、其制造方法及物品 - Google Patents
拒水拒油剂组合物、其制造方法及物品 Download PDFInfo
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- CN114502795A CN114502795A CN202080069897.7A CN202080069897A CN114502795A CN 114502795 A CN114502795 A CN 114502795A CN 202080069897 A CN202080069897 A CN 202080069897A CN 114502795 A CN114502795 A CN 114502795A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/186—Monomers containing fluorine with non-fluorinated comonomers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/28—Hexyfluoropropene
- C08F214/285—Hexyfluoropropene with non-fluorinated comonomers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/10—Vinyl esters of monocarboxylic acids containing three or more carbon atoms
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Abstract
提供:能够得到拒水性及其耐久性优异的物品的拒水拒油剂组合物。一种拒水拒油剂组合物,其包含含氟聚合物,所述含氟聚合物具有:基于式(1):CH2=CH‑Rf(Rf为碳数1~8的全氟烷基)所示的含氟烯烃的单元、基于具有碳数12以上的烷基的羧酸乙烯酯的单元、和基于除前述含氟烯烃以外的卤代烯烃或其衍生物的单元,相对于构成前述含氟聚合物的全部单元,前述基于含氟烯烃的单元的比例为15~35摩尔%,前述基于羧酸乙烯酯的单元的比例为30~60摩尔%,前述基于卤代烯烃或其衍生物的单元的比例为5~55摩尔%。
Description
技术领域
本发明涉及拒水拒油剂组合物、其制造方法及物品。
背景技术
作为对物品(纤维制品等)的表面赋予拒水拒油性的方法,已知使用包含含氟聚合物的拒水拒油剂组合物对物品进行处理的方法,所述含氟聚合物具备基于具有全氟烷基的(甲基)丙烯酸酯的单元。然而,基于(甲基)丙烯酸酯的单元中的酯键容易被基于碱等的水解切断。因此,从含氟聚合物失去全氟烷基,物品的拒水拒油性有时会降低。
作为能够得到拒水拒油性不易因碱等降低的物品的拒水拒油剂组合物,已知有包含如下的含氟聚合物的拒水拒油剂组合物,所述含氟聚合物不具备基于具有全氟烷基的(甲基)丙烯酸酯的单元。作为不具备基于具有全氟烷基的(甲基)丙烯酸酯的单元的含氟聚合物,已知具有基于(全氟烷基)乙烯的单元的含氟聚合物。
专利文献1记载了具有包含基于(全氟烷基)乙烯的单元的聚合物的分散液。另外,作为可以与(全氟烷基)乙烯聚合的单体,公开了硬脂酸乙烯酯、氯乙烯、4-羟丁基乙烯基醚等各种单体。实施例的例10公开了(全氟己基)乙烯(49.8摩尔%)与硬脂酸乙烯酯的共聚物,例29公开了(全氟己基)乙烯(40摩尔%)与乙酸乙烯酯与氯乙烯的共聚物。
专利文献2中记载了一种包含具有基于含氟烯烃的单元及基于烃系乙烯酯的单元的含氟聚合物而成的表面处理剂组合物。作为烃系乙烯酯,公开了硬脂酸乙烯酯。另外,作为任选的单体,公开了卤代乙烯及乙烯基烷基醚等非氟非交联性单体、非氟交联性单体。实施例18中公开了(全氟己基)乙烯(15摩尔%)与硬脂酸乙烯酯的共聚物。
现有技术文献
专利文献
专利文献1:国际公开第2019/138680号
专利文献2:国际公开第2013/058333号
发明内容
发明要解决的问题
然而,用专利文献1、2的实施例记载的包含含氟聚合物的拒水拒油剂组合物进行了处理的物品的拒水性及其耐久性不充分。
本发明提供:能够得到拒水性及其耐久性优异的物品的拒水拒油剂组合物、其制造方法,以及拒水性及其耐久性优异的物品。
用于解决问题的方案
本发明具有下述的方案。
[1]一种拒水拒油剂组合物,其包含含氟聚合物,所述含氟聚合物具有:基于下式(1)所示的含氟烯烃的单元、基于具有碳数12以上的烷基的羧酸乙烯酯的单元、和基于除前述含氟烯烃以外的卤代烯烃或其衍生物的单元,
相对于构成前述含氟聚合物的全部单元,基于前述含氟烯烃的单元的比例为15~35摩尔%,基于前述羧酸乙烯酯的单元的比例为30~60摩尔%,基于前述卤代烯烃或其衍生物的单元的比例为5~55摩尔%。
CH2=CH-Rf (1)
其中,Rf为碳数1~8的全氟烷基。
[2]根据前述[1]所述的拒水拒油剂组合物,其中,前述式(1)中的Rf为碳数1~6的全氟烷基。
[3]根据前述[1]或[2]所述的拒水拒油剂组合物,其中,前述羧酸乙烯酯具有碳数12以上的直链的烷基。
[4]根据前述[1]或[2]所述的拒水拒油剂组合物,其中,前述羧酸乙烯酯具有碳数12~30的烷基。
[5]根据前述[1]或[2]所述的拒水拒油剂组合物,其中,前述羧酸乙烯酯具有碳数16~20的烷基。
[6]根据前述[1]~[5]中任一项所述的拒水拒油剂组合物,其中,基于除前述含氟烯烃以外的卤代烯烃或其衍生物的单元为基于氯乙烯或偏二氯乙烯的单元。
[7]根据前述[1]~[6]中任一项所述的拒水拒油剂组合物,其中,前述含氟聚合物还具有基于具有反应性基团的交联性单体的单元,
相对于构成前述含氟聚合物的全部单元,基于前述交联性单体的单元的比例为0.1~20摩尔%。
[8]根据前述[7]所述的拒水拒油剂组合物,其中,前述反应性基团为羟基、环氧基或氨基。
[9]根据前述[7]或[8]所述的拒水拒油剂组合物,其中,前述交联性单体为乙烯基醚或烯丙基醚。
[10]一种拒水拒油剂组合物的制造方法,其中,在包含水性介质、单体成分、表面活性剂及聚合引发剂的乳化液中对前述单体成分进行聚合,从而制造包含含氟聚合物的拒水拒油剂组合物,
前述单体成分包含下式(1)所示的含氟烯烃、具有碳数12以上的烷基的羧酸乙烯酯、和除前述含氟烯烃以外的卤代烯烃或其衍生物,
相对于前述单体成分总体,前述含氟烯烃的比例为15~35摩尔%,前述羧酸乙烯酯的比例为30~60摩尔%,前述卤代烯烃或其衍生物的比例为5~55摩尔%,
CH2=CH-Rf (1)
其中,Rf为碳数1~8的全氟烷基。
[11]一种物品,其使用前述[1]~[9]中任一项所述的拒水拒油剂组合物进行了处理。
发明的效果
通过本发明的拒水拒油剂组合物,能够得到拒水性及其耐久性优异的物品。
通过本发明的拒水拒油剂组合物的制造方法,可以制造能够得到拒水性及其耐久性优异的物品的拒水拒油剂组合物。
本发明的物品的拒水性及其耐久性优异。
具体实施方式
本发明中的用语的含义、定义如下。
“基于单体的单元”为1分子单体聚合而直接形成的原子团、和对该原子团的一部分进行化学变换而得到的原子团的总称。
“(甲基)丙烯酸酯”为丙烯酸酯及甲基丙烯酸酯的总称。同样,“(甲基)丙烯酰氧基”为丙烯酰氧基及甲基丙烯酰氧基的总称。
聚合物的数均分子量(以下也记作“Mn”。)及质均分子量(以下也记作“Mw”。)为:通过采用使用标准聚甲基丙烯酸甲酯试样制作的标准曲线,用凝胶渗透色谱(以下也记作“GPC”。)测定而得到的聚甲基丙烯酸甲酯换算分子量。
对于固体成分浓度,以加热前的试样的质量为试样质量,以通过120℃的对流式干燥机将试样干燥4小时后的质量为固体成分质量,通过(固体成分质量/试样质量)×100来计算。
〔拒水拒油剂组合物〕
本发明的拒水拒油剂组合物(以下也记作“本组合物”。)包含特定的含氟聚合物(以下也记作“聚合物(A)”。)。
本组合物优选包含后述的水性介质。
本组合物优选为包含聚合物(A)、水性介质和表面活性剂的聚合物分散液。
本组合物还包括通过后述本发明的聚合物(A)的制造方法得到的分散液、以及为了对物品进行处理而进一步被任意的水性介质稀释的该分散液。
本组合物根据需要也可包含其他成分。
(聚合物(A))
聚合物(A)具有:基于下式(1)所示的含氟烯烃(以下也记作“单体a”。)的单元(以下也记作“单元a”。)、基于具有碳数12以上的烷基的羧酸乙烯酯(以下也记作“单体b”。)的单元(以下也记作“单元b”。)、和基于除前述含氟烯烃以外的卤代烯烃或其衍生物(以下也记作“单体c”。)的单元(以下也记作“单元c”。)。
CH2=CH-Rf (1)
其中,Rf为碳数1~8的全氟烷基。
聚合物(A)根据需要还可具备基于具有反应性基团的交联性单体(以下也记作“单体d”。)的单元(以下也记作“单元d”。)。
聚合物(A)根据需要还可具有基于除单体a、单体b、单体c及单体d以外的其他单体(以下也记作“单体e”。)的单元(以下也记作“单元e”。)。
单体a中,从向聚合物(A)转化的转化率容易变得良好的方面、原材料的获取性、及处理的容易性的方面来看,Rf的碳数优选为1~6,更优选为4~6,特别优选为6。
Rf优选为直链状。
作为单体a,可举出例如CH2=CH-CF3、CH2=CH-CF2CF3、CH2=CH-CF2CF2CF3、CH2=CH-CF(CF3)2、CH2=CH-(CF2)3CF3、CH2=CH-CF2CF(CF3)2、CH2=CH-C(CF3)3、CH2=CH-(CF2)4CF3、CH2=CH-CF2CF2CF(CF3)2、CH2=CH-(CF2)5CF3、CH2=CH-(CF2)5CF(CF3)2、CH2=CH-(CF2)7CF3。
作为单体a,优选CH2=CH-CF3、CH2=CH-CF2CF3、CH2=CH-CF(CF3)2、CH2=CH-(CF2)3CF3及CH2=CH-(CF2)5CF3,更优选CH2=CH-CF3、CH2=CH-CF2CF3、CH2=CH-(CF2)3CF3及CH2=CH-(CF2)5CF3,进一步优选CH2=CH-(CF2)3CF3及CH2=CH-(CF2)5CF3。
单体a也可组合使用2种以上。
单体b优选下式(2)所示的单体。
CH2=CH-O-C(=O)-R1 (2)
其中,R1为碳数12以上的烷基。
从拒水性及其耐久性优异的方面来看,上述式(2)中的R1的碳数为12以上,优选为16以上。另外,从获取性、及处理性优异的方面来看,R1的碳数优选为30以下,更优选为20以下。R1优选为直链状。
作为单体b,可举出例如肉豆蔻酸乙烯酯、棕榈酸乙烯酯、硬脂酸乙烯酯、油酸乙烯酯。
作为单体b,优选肉豆蔻酸乙烯酯、棕榈酸乙烯酯、硬脂酸乙烯酯,更优选硬脂酸乙烯酯。
单体b也可组合使用2种以上。
单体c之中,作为卤代烯烃,可举出例如卤代乙烯、卤代亚乙烯、氟乙烯(Fluoroethylene),具体而言,可举出氯乙烯、偏二氯乙烯、氟乙烯(vinyl fluoride)、偏二氟乙烯、三氟乙烯、氯三氟乙烯、四氟乙烯。
作为卤代烯烃的衍生物,可举出例如全氟(烷基乙烯基醚)。作为全氟(烷基乙烯基醚),可举出例如CF2=CFOCF3、CF2=CFOCF2CF3、CF2=CFOCF2CF2CF3、CF2=CFOCF2CF2CF2CF3、CF2=CFOCF2CF(CF3)OCF2CF2CF3。作为单体c,优选卤代乙烯或卤代亚乙烯,更优选氯乙烯或偏二氯乙烯,进一步优选氯乙烯。
单体c也可组合使用2种以上。
单体d中,作为反应性基团,能通过与其他官能团(本组合物中任选包含的交联剂的官能团、或用本组合物进行处理的物品表面存在的官能团等)的反应形成交联结构即可,可举出例如羟基、环氧基、氨基、单烷基氨基、二烷基氨基、羧基、异氰酸酯基、噁唑啉基、碳二亚胺基。单烷基氨基及二烷基氨基中的烷基的碳数例如为1~4。
作为单体d中的反应性基团,从获取性、及处理性优异的方面来看,优选羟基、环氧基或氨基,特别优选羟基。
单体d可以为具有1个聚合性的碳-碳双键的单官能单体,也可以为具有2个以上聚合性的碳-碳双键的多官能单体,从聚合性优异的方面来看,优选单官能单体。
作为单体d,可举出例如乙烯基醚、烯丙基醚、(甲基)丙烯酸酯、乙烯酯、(甲基)丙烯酰胺化合物。
作为乙烯基醚,可举出下式(3-1)所示的化合物。作为烯丙基醚,可举出下式(3-2)所示的化合物。作为(甲基)丙烯酸酯,可举出下式(3-3)所示的化合物。
CH2=CH-O-Z (3-1)
CH2=CHCH2-O-Z (3-2)
CH2=C(R)C(=O)O-Z (3-3)
其中,Z为具有反应性基团的有机基团。R为氢原子或甲基。
作为Z,可举出例如具有反应性基团的脂肪族烃基、具有反应性基团的芳基、被反应性基团取代的具有杂原子的环状的基团。
作为脂肪族烃基,可举出例如烷基、在烷基的碳原子间具有氧原子的基团、烯基、在烯基的碳原子间具有氧原子的基团、环烷基。烷基及烯基的碳数例如为1~6。形成环烷基的环的碳数例如为3~8。
作为杂原子,可举出氮原子、氧原子、硫原子。作为具有杂原子的环状的基团,优选为饱和基团,优选3~9元环,进一步优选3~6元环。
作为Z,优选羟烷基。羟烷基的碳数优选为2~6。
作为单体d,从与单体a~c的共聚性优异的方面和不易被碱等分解的方面来看,优选乙烯基醚或烯丙基醚,更优选烯丙基醚。
作为单体d,可举出例如具有羟基的乙烯基醚(2-羟基乙基乙烯基醚、3-羟基丙基乙烯基醚、4-羟基丁基乙烯基醚、二乙二醇单乙烯基醚、环己烷二甲醇单乙烯基醚等)、缩水甘油基乙烯基醚等乙烯基醚;具有羟基的烯丙基醚(乙二醇单烯丙基醚、二乙二醇烯丙基醚、甘油单烯丙基醚、季戊四醇三烯丙基醚、三羟甲基丙烷二烯丙基醚等)、缩水甘油基烯丙基醚等烯丙基醚;(甲基)丙烯酸羟基烷基酯((甲基)丙烯酸2-羟基乙酯、(甲基)丙烯酸3-羟基丙酯、(甲基)丙烯酸4-羟基丁酯、聚乙二醇(甲基)丙烯酸酯等)、(甲基)丙烯酸缩水甘油酯、(甲基)丙烯酸2-[(3,5-二甲基吡唑啉)羰基氨基]乙酯等(甲基)丙烯酸酯;N-羟甲基丙烯酰胺等(甲基)丙烯酰胺化合物。
这些之中,优选具有羟基的乙烯基醚、具有羟基的烯丙基醚,更优选4-羟基丁基乙烯基醚、二乙二醇单乙烯基醚、环己烷二甲醇单乙烯基醚、乙二醇单烯丙基醚。
单体d也可组合使用2种以上。
作为单体e,能与单体a~c共聚即可,可举出例如除单体a~c以外的乙烯酯、烯丙酯、乙烯基醚、烯丙基醚、烯烃、(甲基)丙烯酸酯、N-乙烯基吡咯烷酮、N-乙烯基-ε-己内酰胺、乙基乙烯基硫醚。
作为乙烯酯,可举出例如具有碳数11以下的烷基的羧酸乙烯酯,作为具体例,可举出乙酸乙烯酯、丁酸乙烯酯、新戊酸乙烯酯、己酸乙烯酯、辛酸乙烯酯、月桂酸乙烯酯、苯甲酸乙烯酯、氯乙酸乙烯酯、己二酸二乙烯酯。作为乙烯酯,从能够得到拒油性、拒醇性及拒水性优异的物品的方面来看,特别优选乙酸乙烯酯或新戊酸乙烯酯。
作为烯丙酯,可举出例如乙酸烯丙酯、己二酸二烯丙酯。
作为乙烯基醚,可举出例如甲基乙烯基醚、乙基乙烯基醚、正丁基乙烯基醚、异丁基乙烯基醚、叔丁基乙烯基醚、硬脂基乙烯基醚、1-氯甲基乙烯基醚、2-氯乙基乙烯基醚、氯丙基乙烯基醚、环己基乙烯基醚。
作为烯丙基醚,可举出例如烯丙基乙基醚、二烯丙基醚、1,3-二烯丙氧基-2-丙醇。
作为烯烃,可举出例如乙烯、丙烯。
作为(甲基)丙烯酸酯,可举出例如(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸叔丁酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸硬脂酯、(甲基)丙烯酸山嵛酯等(甲基)丙烯酸烷基酯;(甲基)丙烯酸2-全氟己基乙酯等(甲基)丙烯酸氟烷基酯。从可以得到拒水拒油性不易因碱等进一步降低的物品的方面来看,聚合物(A)优选不含基于具有全氟烷基的(甲基)丙烯酸酯的单元。因此,作为(甲基)丙烯酸酯,优选上述(甲基)丙烯酸烷基酯等不具有氟原子的(甲基)丙烯酸酯。
相对于构成聚合物(A)的全部单元,聚合物(A)中的单元a的比例为15~35摩尔%,优选为18~32摩尔%,更优选为20~30摩尔%。若单元a的比例为前述下限值以上,则用本组合物进行了处理的物品的拒油性优异。若单元a的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性优异。
相对于构成聚合物(A)的全部单元,聚合物(A)中单元b的比例为30~60摩尔%,优选为32~58摩尔%,更优选为34~56摩尔%。若单元b的比例为前述下限值以上,则用本组合物进行了处理的物品的拒水性及其耐久性优异。若单元b的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性的耐久性优异。
相对于构成聚合物(A)的全部单元,聚合物(A)中单元c的比例为5~55摩尔%,优选为15~50摩尔%,更优选为20~48摩尔%。若单元c的比例为前述下限值以上,则用本组合物进行了处理的物品的拒油性、及拒水性的耐久性优异。若单元c的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性优异。
聚合物(A)包含单元d时,相对于构成聚合物(A)的全部单元,聚合物(A)中的单元d的比例优选为0.1~8摩尔%,更优选为0.5~6摩尔%,进一步优选为1~4摩尔%。若单元d的比例为前述下限值以上,则用本组合物进行了处理的物品的拒水性的耐久性进一步优异。若单元d的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性及其耐久性进一步优异。
相对于构成聚合物(A)的全部单元,聚合物(A)中的单元e的比例优选为10摩尔%以下,更优选为5摩尔%以下,也可以为0摩尔%。
需要说明的是,构成聚合物(A)的全部单元为单元a、单元b、单元c、单元d及单元e的总计。
各单元的比例可以通过1H-NMR、及基于气相色谱的各单体成分的反应率计算。制造聚合物(A)时,单体成分向聚合物(A)转化的转化率高(例如90%以上)时,也可以基于单体成分的投入量计算各单元的比例。转化率可以通过后述实施例记载的方法求出。
聚合物(A)的Mn优选为10000以上,更优选为11000以上,进一步优选为12000以上。聚合物(A)的Mn优选为100000以下,更优选为70000以下,进一步优选为50000以下。若聚合物(A)的Mn为前述下限值以上,则用本组合物进行了处理的物品的拒水拒油性进一步优异。若聚合物(A)的Mn为前述上限值以下,则聚合物(A)的水分散性进一步优异。
聚合物(A)的Mw优选为10000以上,更优选为20000以上,进一步优选为30000以上。聚合物(A)的Mw优选为150000以下,更优选为120000以下,进一步优选为100000以下。若聚合物(A)的Mw为前述下限值以上,则用本组合物进行了处理的物品的拒水拒油性进一步优异。若聚合物(A)的Mw为前述上限值以下,则聚合物(A)的水分散性进一步优异。
(水性介质)
作为水性介质,可举出水、及包含水溶性有机溶剂的水。
水溶性有机溶剂为能够以任意的比例与水混溶的有机溶剂。作为水溶性有机溶剂,优选选自由醇(其中,醚醇除外。)、醚醇及非质子性极性溶剂组成的组中的至少1种。作为醇,可举出例如叔丁醇、丙二醇。作为醚醇,可举出例如3-甲氧基甲基丁醇、二丙二醇、二丙二醇单甲醚、三丙二醇。作为非质子性极性溶剂,可举出例如N,N-二甲基甲酰胺、二甲基亚砜、四氢呋喃(以下也记作“THF”。)、乙腈、丙酮、3-甲氧基-N,N-二甲基丙酰胺、3-丁氧基-N,N-二甲基丙酰胺、3-甲氧基-3-甲基-1-丁醇、三乙二醇二甲醚、四乙二醇二甲醚。作为液体介质为水性介质时的水溶性有机溶剂,从提高聚合物(A)与水性介质的相容性从而容易在物品上制成均匀的膜的方面来看,优选醚醇,更优选二丙二醇、三丙二醇及二丙二醇单甲醚。
水性介质为包含水溶性有机溶剂的水时,相对于水100质量份,水溶性有机溶剂的含量优选为1~80质量份,更优选为5~60质量份。
(表面活性剂)
作为表面活性剂,优选不具有氟原子的表面活性剂。
作为表面活性剂,可举出阴离子性表面活性剂、非离子性表面活性剂、阳离子性表面活性剂、两性表面活性剂。
作为表面活性剂,从包含聚合物(A)的水分散液的分散稳定性优异的方面来看,优选非离子性表面活性剂的单独使用、非离子性表面活性剂与阳离子性表面活性剂或两性表面活性剂的组合使用、或者阴离子性表面活性剂的单独使用,更优选非离子性表面活性剂与阳离子性表面活性剂的组合使用。
非离子性表面活性剂与阳离子性表面活性剂的比(非离子性表面活性剂/阳离子性表面活性剂)优选为100/0~40/60(质量比),更优选为97/3~40/60(质量比)。
非离子性表面活性剂与阳离子性表面活性剂的特定的组合中,相对于聚合物(A)100质量份,可以将表面活性剂的总量设为5质量份以下,因此可以减少由表面活性剂引起的对用本组合物进行了处理的物品的拒水拒油性的不良影响。
作为非离子性表面活性剂的例子,可举出日本特开2009-215370号公报的[0067]~[0095]段记载的表面活性剂s1~s6。
作为表面活性剂s1,优选聚氧乙烯烷基醚。
作为表面活性剂s2,优选乙炔二醇环氧乙烷加成物。
作为表面活性剂s3,优选环氧乙烷环氧丙烷聚合物。
非离子性表面活性剂也可组合使用2种以上。
作为阳离子性表面活性剂的例子,可举出日本特开2009-215370号公报的[0096]~[0100]段记载的表面活性剂s7。
作为表面活性剂s7,优选与氮原子键合的氢原子中的1个以上被烷基、烯基或末端为羟基的聚氧亚烷基链取代而成的铵盐,更优选下式(s71)所示的化合物s71。
[(R21)4N+]·X- (s71)
R21为氢原子、碳数为1~22的烷基、碳数为2~22的烯基、碳数为1~9的氟烷基、或末端为羟基的聚氧亚烷基链。4个R21可以相同,也可以不同,但4个R21不能同时为氢原子。X-为抗衡离子。
作为X-,优选氯离子、乙基硫酸根离子、或乙酸根离子。
作为化合物s71,可举出例如单硬脂基三甲基氯化铵、单硬脂基二甲基单乙基铵乙基硫酸盐、单(硬脂基)单甲基二(聚乙二醇)氯化铵、单氟己基三甲基氯化铵、二(牛脂烷基)二甲基氯化铵、二甲基单椰油胺乙酸盐。
阳离子性表面活性剂也可组合使用2种以上。
作为两性表面活性剂的例子,可举出日本特开2009-215370号公报的[0101]~[0102]段记载的表面活性剂s8。这些可以使用1种,也可组合使用2种以上。
作为表面活性剂的组合,从对用本组合物进行了处理的物品的拒水拒油性的不良影响少的方面、及包含聚合物(A)的分散液的分散稳定性优异的方面来看,优选表面活性剂s1与表面活性剂s2与表面活性剂s7的组合,或表面活性剂s1与表面活性剂s3与表面活性剂s7的组合,或表面活性剂s1与表面活性剂s2与表面活性剂s3与表面活性剂s7的组合,更优选表面活性剂s7为化合物s71的前述组合。
(其他成分)
作为其他成分,可举出例如除聚合物(A)以外的含氟聚合物、非氟系聚合物、非氟系拒水拒油剂、水溶性高分子树脂(例如亲水性聚酯及其衍生物、亲水性聚乙二醇及其衍生物、亲水性多胺及其衍生物)、交联剂、渗透剂(例如在中央具有乙炔基且形成左右对称结构的非离子性表面活性剂、日油株式会社制的DISPANOL(注册商标)系列)、胶体二氧化硅(例如日产化学株式会社制的SNOWTEX(注册商标)系列、ADEKA株式会社制的Adelite系列)、消泡剂(例如日信化学株式会社制的OLFINE(注册商标)系列、DOW CORNING TORAY CO.,LTD.制的FS ANTI FOAM系列)、造膜助剂、防虫剂、防霉剂、防腐剂、阻燃剂、抗静电剂(例如明成化学株式会社制的Director系列)、抗皱剂、柔软剂(例如有机硅乳液、聚乙烯蜡乳液、聚酰胺蜡乳液)、pH调节剂(例如二乙醇胺、三乙醇胺、乙酸、柠檬酸)。
本组合物包含交联剂时,与物品的粘合性容易提高。
作为交联剂,优选异氰酸酯系交联剂、羟甲基系交联剂、碳二亚胺系交联剂、及噁唑啉系交联剂。
作为异氰酸酯系交联剂,可举出例如芳香族嵌段型异氰酸酯系交联剂、脂肪族嵌段型异氰酸酯系交联剂、芳香族非嵌段型异氰酸酯系交联剂、脂肪族非嵌段型异氰酸酯系交联剂。异氰酸酯系交联剂优选用表面活性剂进行了乳化的水分散型、或具有亲水基团的自水分散型。
作为羟甲基系交联剂,可举出例如尿素或三聚氰胺与甲醛的缩合物或预缩合物、羟甲基-二羟基乙烯-脲及其衍生物、羟甲基-乙烯-脲、羟甲基-丙烯-脲、羟甲基-三嗪酮、双氰胺-甲醛的缩合物、羟甲基-氨基甲酸酯、羟甲基-(甲基)丙烯酰胺、它们的聚合物。
碳二亚胺系交联剂为分子中具有碳二亚胺基的聚合物,是与物品等的羧基、氨基、活性氢基显示优异反应性的交联剂。
噁唑啉系交联剂为分子中具有噁唑啉基的聚合物,是与物品等的羧基显示优异的反应性的交联剂。
作为其他交联剂,可举出例如二乙烯基砜、聚酰胺及其阳离子衍生物、多胺及其阳离子衍生物、二缩水甘油基甘油等环氧衍生物、(环氧-2,3-丙基)三甲基氯化铵、N-甲基-N-(环氧-2,3-丙基)氯化吗啉等卤化衍生物、乙二醇的氯甲醚的吡啶鎓盐、多胺-聚酰胺-表氯醇树脂、聚乙烯醇或其衍生物、聚丙烯酰胺或其衍生物、聚丙烯酰胺树脂系抗皱剂。
本组合物包含羟甲基系交联剂或聚丙烯酰胺树脂系抗皱剂时,作为添加剂,优选包含催化剂。作为优选的催化剂,可举出例如无机胺盐、有机胺盐。作为无机胺盐,可举出例如氯化铵。作为有机胺盐,可举出例如氨基醇盐酸盐、氨基脲盐酸盐。作为氨基醇盐酸盐,可举出例如单乙醇胺盐酸盐、二乙醇胺盐酸盐、三乙醇盐酸盐、2-氨基-2-甲基丙醇盐酸盐。
(各成分的比例)
本组合物包含水性介质时,水性介质的含量可以根据本组合物的期望的固体成分浓度适当选择。
在刚制造本组合物后,本组合物的固体成分浓度优选为25~70质量%,更优选为30~60质量%。
在将本组合物用于物品的处理时,本组合物的固体成分浓度优选为0.1~7质量%,更优选为0.2~5质量%。
在刚制造本组合物后,本组合物中的表面活性剂的含量优选相对于聚合物(A)100质量份为1~6质量份。
在将本组合物用于物品的处理时,本组合物中的交联剂的含量优选相对于聚合物(A)100质量份为1~50质量份。
(作用机制)
以上说明的本组合物中,聚合物(A)具有单元a,因此用本组合物进行了处理的物品的拒水拒油性不易因碱等降低。
并且,本组合物中,构成聚合物(A)的单元a、单元b及单元c的比例在特定的范围内,因此用本组合物进行了处理的物品的拒水性优异,并且拒水性不易因洗涤等降低,耐久性优异。
〔拒水拒油剂组合物的制造方法〕
本组合物例如可以通过如下方法制造:在包含水性介质、单体成分、表面活性剂及聚合引发剂的乳化液中对前述单体成分进行聚合,从而得到包含含氟聚合物的拒水拒油剂组合物。通过该方法,可以使单体成分向聚合物(A)转化的转化率提高,并且还能提高得到的聚合物(A)的数均分子量。
单体成分包含单体a、单体b和单体c。单体成分根据需要还可包含单体d、单体e。
相对于单体成分总体,单体a的比例为15~35摩尔%,优选为18~32摩尔%,更优选为20~30摩尔%。若单体a的比例为前述下限值以上,则用本组合物进行了处理的物品的拒油性优异。若单体a的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性优异。
相对于单体成分总体,单体b的比例为30~60摩尔%,优选为32~58摩尔%,更优选为34~56摩尔%。若单体b的比例为前述下限值以上,则用本组合物进行了处理的物品的拒水性及其耐久性优异。若单体b的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性的耐久性优异。
相对于单体成分总体,单体c的比例为5~55摩尔%,优选为15~50摩尔%,更优选为20~48摩尔%。若单体c的比例为前述下限值以上,则用本组合物进行了处理的物品的拒油性、及拒水性的耐久性优异。若单体c的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性优异。
单体成分包含单体d时,相对于单体成分总体,单体d的比例优选为0.1~8摩尔%,更优选为0.5~6摩尔%,进一步优选为1~4摩尔%。若单体d的比例为前述下限值以上,则用本组合物进行了处理的物品的拒水性的耐久性进一步优异。若单体d的比例为前述上限值以下,则用本组合物进行了处理的物品的拒水性及其耐久性进一步优异。
相对于单体成分总体,单体e的比例优选为10摩尔%以下,更优选为5摩尔%以下,也可以为0摩尔%。
需要说明的是,单体成分总体为单体a、单体b、单体c、单体d及单体e的总计。
作为聚合引发剂,可举出例如热聚合引发剂、光聚合引发剂、辐射线聚合引发剂、自由基聚合引发剂、离子性聚合引发剂,优选自由基聚合引发剂。作为自由基聚合引发剂,例如可以根据聚合温度而使用偶氮系聚合引发剂、过氧化物系聚合引发剂、氧化还原系引发剂。作为自由基聚合引发剂,优选偶氮系化合物,更优选偶氮系化合物的盐。聚合温度优选为20~150℃。
相对于单体成分100质量份,聚合引发剂的添加量优选为0.1~5质量份,更优选为0.1~3质量份。
对单体成分进行聚合时,也可使用分子量调节剂。作为分子量调节剂,例如优选芳香族化合物、巯基醇、巯基羧酸、烷基硫醇,更优选巯基羧酸或烷基硫醇。作为分子量调节剂,可举出例如巯基乙醇、巯基丙酸、正辛基硫醇、正十二烷基硫醇、叔十二烷基硫醇、硬脂基硫醇、α-甲基苯乙烯二聚体(CH2=C(Ph)CH2C(CH3)2Ph,其中Ph为苯基。)。
相对于单体成分100质量份,分子量调节剂的添加量优选为5质量份以下,更优选为2质量份以下,也可以为0质量份。
乳化液可以如下制备:将水性介质、单体成分及表面活性剂混合并用均化器、高压乳化机等进行分散后,添加聚合引发剂,从而制备。
乳化液中的单体成分的浓度优选为20~60质量%,更优选为30~50质量%。若乳化液中的单体成分的浓度为前述范围内,则在单体成分聚合时,可以使单体成分向聚合物(A)转化的转化率提高,并且可以充分地提高聚合物(A)的分子量。
相对于单体成分100质量份,乳化液中的表面活性剂的总量优选为1~6质量份。若表面活性剂的总量为前述范围的下限值以上,则乳化液的分散稳定性优异。若表面活性剂的总量为前述范围的上限值以下,则对用本组合物进行了处理的物品的拒水拒油性的不良影响少。
在乳化液中对单体成分进行聚合得到的聚合物(A)的分散液可以直接作为本组合物,也可以用水性介质稀释而调节固体成分浓度后制成本组合物。本组合物中还可以添加其他成分。
聚合结束时的单体成分向聚合物(A)转化的转化率优选为80%以上,更优选为90%以上。通过提高转化率,聚合物(A)的分子量也会提高,拒水拒油性能也变良好。另外,通过设为高转化率,可以抑制残留单体引起的性能降低,并且聚合物(A)中包含的氟原子的量变多,因此拒水拒油性变良好。
为了将转化率设为80%以上,优选进行乳化组成的最优化、聚合时间的最优化。
(作用机制)
以上说明的本组合物的制造方法中,对包含单体a的单体成分进行聚合,因此可以制造能够制造拒水拒油性不易因碱等降低的物品的本组合物。
另外,本组合物的制造方法中,在乳化液中对单体成分进行聚合,因此可以提高聚合物(A)的分子量。因此,可以制造能够制造拒水拒油性优异的物品的本组合物。
并且,本组合物的制造方法中,单体成分中包含的单体a、单体b及单体c的比例在特定的范围内,因此可以制造能够制造拒水性及其耐久性优异的物品的本组合物。
〔物品〕
本发明的物品是使用本组合物进行了处理的物品。
作为用本组合物进行了处理的物品,可举出例如纤维、纤维布帛(纤维机织物、纤维针织物、无纺布、起毛布等)、具备纤维布帛的纤维制品(滑雪服、雨衣、外套、茄克衫、风衣、羽绒服、运动装、工作服、制服、防护服等服装、帆布袋、背包、包、帐篷、轻型帐篷(zelt)等)、玻璃、纸、木、皮革、人工皮革、合成皮革、石、混凝土、陶瓷、金属、金属氧化物、陶瓷制品、树脂成形品、多孔树脂、多孔纤维。多孔树脂例如可以用作过滤器。作为多孔树脂的材料,可举出例如聚丙烯、聚对苯二甲酸乙二醇酯、聚四氟乙烯。作为多孔纤维的材料,可举出例如玻璃纤维、纤维素纳米纤维、碳纤维、乙酸纤维素。
作为进行处理的物品,优选纤维、纤维布帛、具备纤维布帛的纤维制品。
作为纤维的种类,并无特别限定,可例示出棉、羊毛、丝绸或纤维素等天然纤维、聚酯、聚酰胺、丙烯酸类或芳纶等合成纤维、人造丝、粘胶人造丝或天丝等化学纤维、天然纤维与合成纤维的混纺纤维、天然纤维与化学纤维的混纺纤维。作为纤维基材为无纺布时的纤维,可例示出聚乙烯、聚丙烯、聚烯烃、聚对苯二甲酸乙二醇酯、聚四氟乙烯、玻璃及人造丝。
纤维布帛的厚度并无特别限定,通常为0.01~5mm。
作为物品的处理方法,为可以将拒水拒油剂组合物附着于被处理物品的方法即可,例如,本组合物包含液体介质时,可举出在通过涂布、浸渗、浸渍、喷雾、刷洗、填充、施胶压榨、辊等公知的涂覆方法在物品上处理本分散液后,进行干燥的方法。
被处理物品上附着的拒水拒油剂组合物中的固体成分的量并无特别限定,例如在纤维布帛的情况下,相对于纤维布帛的单位质量,优选为0.001~1.0g/g,更优选为0.001~0.5g/g,特别优选为0.001~0.05g/g。
干燥可以在常温下进行也可进行加热,优选进行加热。加热时,加热温度优选为40~200℃。另外,拒水拒油剂组合物含有交联剂时,若必要,则优选加热至前述交联剂的交联温度以上进行固化(curing)。
(作用机制)
对于以上说明的本发明的物品,由于使用了包含具有单元a的聚合物(A)的本组合物进行处理,因此拒水拒油性不易因碱等降低。
并且,对于本发明的物品,由于使用了包含构成的单元a、单元b及单元c的比例在特定的范围内的聚合物(A)的本组合物进行处理,因此拒水性及其耐久性优异。
实施例
以下,通过实施例对本发明进行详细说明,但本发明并不限定于这些。
例1~13为实施例,例14~21为比较例。
(单体单元的比例)
从各例得到的含氟聚合物分散液中去除表面活性剂及溶剂后,根据基于1H-NMR、及各例得到的含氟聚合物分散液的气相色谱的各单体的反应率,计算构成含氟聚合物的各单体单元相对于全部单元的比例。
(转化率)
根据由原料的投入量计算的含氟聚合物分散液的固体成分浓度的理论值、和含氟聚合物分散液的固体成分浓度的实测值,通过实测值/理论值×100,求出单体成分向含氟聚合物转化的转化率。以转化率90%以上为A(良)、80%以上且小于90%为B(可)、小于80%为C(不可)。
(平均分子量)
<含氟聚合物的回收>
将各例得到的含氟聚合物分散液6g滴加在己烷6g与2-丁醇54g的混合液60g中,搅拌使固体析出。以3000rpm进行5分钟离心分离后,将得到的固体分离。向所分离的固体中添加异丙醇改性醇(Imazu公司制、制品名:95%IPA改性醇)30g、和离子交换水30g,充分搅拌。以3000rpm进行5分钟离心分离后,将得到的固体从上清液中分离,在35℃下真空干燥一夜,从而得到含氟聚合物。
<Mn及Mw的测定>
使回收的含氟聚合物溶解于含氟溶剂(AGC株式会社制品名、AK-225)/四氢呋喃(以下记作“THF”。)=6/4(体积比)的混合溶剂,制成固体成分浓度0.5质量%的溶液,通过0.2μm的过滤器,制成分析样品。对于分析样品,利用GPC测定测定Mn及Mw。测定条件如下所述。
装置:东曹株式会社制、HLC-8320GPC、
柱:Polymer laboratories公司制、MIXED-C长度300mm、内径7.5mm膜厚5μm、
流动相:AK-225/THF=6/4(体积比)、
流速:1.0mL/分钟、
烘箱温度:37℃、
试样浓度:1.0质量%、
注入量:50μL、
检测器:RI、
分子量标准:聚甲基丙烯酸甲酯(Mp=2136000、955000、569000、332800、121600、67400、31110、13300、7360、1950、1010、及550)。
(拒水性)
按照JIS L 1092:1998的喷雾试验,以1~5的五个阶段的等级评价制造的试验布的拒水性。等级越大,则表示拒水性越良好。等级中记载的+(-)表示拒水性与该等级相比稍好(差)。
(拒水性的洗涤耐久性)
对于进行了上述拒水性评价的试验布,按照AATCC Monograph 6-2016的洗涤方法,重复10次或20次洗涤。洗涤后,按照AATCC Monograph 6-2016的转鼓式干燥方法使其干燥后,评价上述拒水性。
(拒油性)
静置石蜡油(nujol)的液滴(直径5mm),通过目视观察60秒后的液滴的变化,根据有无浸渗判断拒油性。将60秒后液滴保持球形的情况评价为“A”,将完全浸渗至试验布中的情况评价为“C”。
(单体a)
C6OLF:CH2=CH-(CF2)5CF3(东京化成工业株式会社制)
(单体b)
StV:硬脂酸乙烯酯(东京化成工业株式会社制)
PaV:棕榈酸乙烯酯(东京化成工业株式会社制)
MyV:肉豆蔻酸乙烯酯(东京化成工业株式会社制)
(单体c)
VCM:CH2=CHCl(横浜化学株式会社制)
(单体d)
4-HBVE:4-羟基丁基乙烯基醚(富士胶片和光纯药株式会社制)
EGMAE:乙二醇单烯丙基醚(东京化成工业株式会社制)
(单体e)
LaV:月桂酸乙烯酯(东京化成工业株式会社制)
AcV:乙酸乙烯酯(东京化成工业株式会社制)
(表面活性剂)
PEL-12:聚氧乙烯月桂基醚(环氧乙烷约12摩尔加成物、PEL-12、花王株式会社制、EMULGEN 120)的10质量%水溶液
PEO-30:聚氧乙烯油基醚(环氧乙烷约30摩尔加成物、PEO-30、花王株式会社制、EMULGEN 430)的10质量%水溶液
P104:环氧乙烷与环氧丙烷的聚合物(平均分子量1670、含有40质量%环氧乙烷、日油株式会社制品名、PLONON#104)的10质量%水溶液。
P204:环氧乙烷与环氧丙烷的聚合物(平均分子量3330、含有40质量%环氧乙烷、日油株式会社制品名、PLONON#204)
STMAC:氯化烷基(碳数:16~18)三甲基氯化铵(STMAC)的63质量%水及异丙醇溶液(Lion Specialty Chemicals Co.,Ltd.制、LIPOQUAD 18-63)
(介质)
水:离子交换水
DPG:二丙二醇
(聚合引发剂)
VA-061A乙酸盐:2,2’-偶氮双[2-(2-咪唑啉-2-基)丙烷](VA-061、富士胶片和光纯药株式会社制)乙酸盐(VA-061A、VA-061:乙酸=1:0.8(质量比))的20质量%水溶液
(例1~21)
在玻璃制容器中加入表1~2示出的单体(其中AcV及VCM除外。)、表面活性剂及介质,以55℃加温30分钟后,使用均质混合器(株式会社日本精机制作所制、Bio mixer)混合,从而得到混合液。边将得到的混合液保持在55℃,边使用高压乳化机(APV LANIER公司制、Minilab),以10MPa进行前乳化后,以40MPa进行处理,从而得到乳化液。将得到的乳化液加入不锈钢制反应器中,冷却至30℃以下。在其中添加表1~2示出的聚合引发剂,对气相进行氮置换后,导入表1~2示出的量的AcV、VCM,边搅拌边在55℃下使其聚合24小时,从而得到包含含氟聚合物的分散液。将单体向含氟聚合物转化的转化率、分散液的固体成分浓度、分散液中的含氟聚合物的Mn及Mw示于表1~2。
表1~2中,单体b、e一栏中,各单体(羧酸乙烯酯)的右侧的括号内的数值为羧酸乙烯酯具有的烷基的碳数。表面活性剂及聚合引发剂的投入量(g)为包含介质的质量在内的总量。
用自来水稀释含氟聚合物分散液,将固体成分浓度调节为2.0质量%后,添加异氰酸酯系交联剂(明成化学工业株式会社制、MEIKANATE TP-10)以使其浓度为1.0质量%,得到拒水拒油剂组合物。
在得到的拒水拒油剂组合物中浸渍聚对苯二甲酸乙二醇酯(PET)羊毛塔夫绸、尼龙塔丝隆塔夫绸、或阔幅棉布,拧干而使得纤维吸液率(wet pickup)在PET羊毛塔夫绸中为50~60质量%、在尼龙塔丝隆塔夫绸中为55~65质量%、在阔幅棉布中为60~65质量%。将其以110℃加热90秒后,以170℃干燥60秒,接着在23℃、湿度50%的房间中静置一夜,作为试验布。
使用制造的试验布,通过上述的评价方法,评价拒水性(初始)、拒水性的洗涤耐久性(洗涤10次后的拒水性(也记作“HL10”。)、洗涤20次后的拒水性(也记作“HL20”。))、拒油性(初始)。将评价结果示于表3~4。
[表1]
[表2]
[表3]
[表4]
使用包含以特定的比例具有单元a、单元b及单元c的含氟聚合物的组合物进行了处理的例1~13的物品具有充分的拒油性,并且拒水性及其耐久性(拒水性的洗涤耐久性)优异。
例14中,含氟聚合物中的单元a小于15摩尔%,因此物品的拒油性与例1~13相比较差。
例15及21中,含氟聚合物中的单元a大于35摩尔%,因此物品的拒水性及其耐久性(拒水性的洗涤耐久性)不充分。
例21中,物品的拒油性与例1~13相比较差。
例16及19中,含氟聚合物中的单元b小于30摩尔%,因此物品的拒水性及其耐久性(拒水性的洗涤耐久性)不充分。
例17及18中,含氟聚合物具有基于具有碳数小于12的烷基的羧酸乙烯酯的单元代替单元b,因此物品的拒水性及其耐久性(拒水性的洗涤耐久性)不充分。
例20中,含氟聚合物中的单元a大于35摩尔%,且含氟聚合物具有基于具有碳数小于12的烷基的羧酸乙烯酯的单元代替单元b,因此物品的拒水性及其耐久性(拒水性的洗涤耐久性)不充分。
需要说明的是,将2019年10月2日申请的日本专利申请2019-182132号的说明书、权利要求、附图、及摘要的全部内容引用于此,作为本发明的说明书的公开内容并入。
Claims (11)
1.一种拒水拒油剂组合物,其包含含氟聚合物,所述含氟聚合物具有:基于下式(1)所示的含氟烯烃的单元、基于具有碳数12以上的烷基的羧酸乙烯酯的单元、和基于除所述含氟烯烃以外的卤代烯烃或其衍生物的单元,
相对于构成所述含氟聚合物的全部单元,基于所述含氟烯烃的单元的比例为15~35摩尔%,基于所述羧酸乙烯酯的单元的比例为30~60摩尔%,基于所述卤代烯烃或其衍生物的单元的比例为5~55摩尔%,
CH2=CH-Rf (1)
其中,Rf为碳数1~8的全氟烷基。
2.根据权利要求1所述的拒水拒油剂组合物,其中,所述式(1)中的Rf为碳数1~6的全氟烷基。
3.根据权利要求1或2所述的拒水拒油剂组合物,其中,所述羧酸乙烯酯具有碳数12以上的直链的烷基。
4.根据权利要求1或2所述的拒水拒油剂组合物,其中,所述羧酸乙烯酯具有碳数12~30的烷基。
5.根据权利要求1或2所述的拒水拒油剂组合物,其中,所述羧酸乙烯酯具有碳数16~20的烷基。
6.根据权利要求1~5中任一项所述的拒水拒油剂组合物,其中,基于除所述含氟烯烃以外的卤代烯烃或其衍生物的单元为基于氯乙烯或偏二氯乙烯的单元。
7.根据权利要求1~6中任一项所述的拒水拒油剂组合物,其中,所述含氟聚合物还具有基于具有反应性基团的交联性单体的单元,
相对于构成所述含氟聚合物的全部单元,基于所述交联性单体的单元的比例为0.1~20摩尔%。
8.根据权利要求7所述的拒水拒油剂组合物,其中,所述反应性基团为羟基、环氧基或氨基。
9.根据权利要求7或8所述的拒水拒油剂组合物,其中,所述交联性单体为乙烯基醚或烯丙基醚。
10.一种拒水拒油剂组合物的制造方法,其中,在包含水性介质、单体成分、表面活性剂及聚合引发剂的乳化液中对所述单体成分进行聚合,从而制造包含含氟聚合物的拒水拒油剂组合物,
所述单体成分包含下式(1)所示的含氟烯烃、具有碳数12以上的烷基的羧酸乙烯酯、和除所述含氟烯烃以外的卤代烯烃或其衍生物,
相对于所述单体成分总体,所述含氟烯烃的比例为15~35摩尔%,所述羧酸乙烯酯的比例为30~60摩尔%,所述卤代烯烃或其衍生物的比例为5~55摩尔%,
CH2=CH-Rf (1)
其中,Rf为碳数1~8的全氟烷基。
11.一种物品,其使用权利要求1~9中任一项所述的拒水拒油剂组合物进行了处理。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85109162A (zh) * | 1984-11-22 | 1986-10-01 | 大金工业株式会社 | 制备全氟烷基乙烯基聚合物的方法及其用途 |
CN103080267A (zh) * | 2010-08-11 | 2013-05-01 | 旭硝子株式会社 | 拒水拒油剂组合物和物品 |
CN105765026A (zh) * | 2013-11-26 | 2016-07-13 | 旭硝子株式会社 | 拒水拒油剂组合物、物品和物品的制造方法 |
CN107709505A (zh) * | 2015-05-27 | 2018-02-16 | 旭硝子株式会社 | 拒水拒油剂组合物、其制造方法及物品 |
CN109072048A (zh) * | 2016-04-15 | 2018-12-21 | Agc株式会社 | 拒水剂组合物、及带透湿防水膜的物品的制造方法 |
TW201936667A (zh) * | 2018-01-15 | 2019-09-16 | 日商Agc股份有限公司 | 含氟共聚物分散液、其製造方法及物品 |
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JP2013100493A (ja) | 2011-10-19 | 2013-05-23 | Daikin Industries Ltd | 表面処理剤組成物およびその用途 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85109162A (zh) * | 1984-11-22 | 1986-10-01 | 大金工业株式会社 | 制备全氟烷基乙烯基聚合物的方法及其用途 |
CN103080267A (zh) * | 2010-08-11 | 2013-05-01 | 旭硝子株式会社 | 拒水拒油剂组合物和物品 |
CN105765026A (zh) * | 2013-11-26 | 2016-07-13 | 旭硝子株式会社 | 拒水拒油剂组合物、物品和物品的制造方法 |
CN107709505A (zh) * | 2015-05-27 | 2018-02-16 | 旭硝子株式会社 | 拒水拒油剂组合物、其制造方法及物品 |
CN109072048A (zh) * | 2016-04-15 | 2018-12-21 | Agc株式会社 | 拒水剂组合物、及带透湿防水膜的物品的制造方法 |
TW201936667A (zh) * | 2018-01-15 | 2019-09-16 | 日商Agc股份有限公司 | 含氟共聚物分散液、其製造方法及物品 |
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