JP2004508434A - ジリチウム化開始剤の調製方法およびアニオン重合方法 - Google Patents

ジリチウム化開始剤の調製方法およびアニオン重合方法 Download PDF

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Publication number
JP2004508434A
JP2004508434A JP2002525242A JP2002525242A JP2004508434A JP 2004508434 A JP2004508434 A JP 2004508434A JP 2002525242 A JP2002525242 A JP 2002525242A JP 2002525242 A JP2002525242 A JP 2002525242A JP 2004508434 A JP2004508434 A JP 2004508434A
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JP
Japan
Prior art keywords
initiator
preparing
dilithiation
prepared
reacting
Prior art date
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JP2002525242A
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English (en)
Japanese (ja)
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JP2004508434A5 (enExample
Inventor
ロベール　ピエール
フラディン　コア　コリン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA France
Societe de Technologie Michelin SAS
Original Assignee
Michelin Recherche et Technique SA France
Societe de Technologie Michelin SAS
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Application filed by Michelin Recherche et Technique SA France, Societe de Technologie Michelin SAS filed Critical Michelin Recherche et Technique SA France
Publication of JP2004508434A publication Critical patent/JP2004508434A/ja
Publication of JP2004508434A5 publication Critical patent/JP2004508434A5/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C08F4/486—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium at least two metal atoms in the same molecule
    • C08F4/488—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium at least two metal atoms in the same molecule at least two lithium atoms in the same molecule

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2002525242A 2000-09-11 2001-08-27 ジリチウム化開始剤の調製方法およびアニオン重合方法 Pending JP2004508434A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0011617 2000-09-11
PCT/EP2001/009856 WO2002020623A1 (fr) 2000-09-11 2001-08-27 Procede de preparation d'un initiateur dilithie et procede de polymerisation anionique

Publications (2)

Publication Number Publication Date
JP2004508434A true JP2004508434A (ja) 2004-03-18
JP2004508434A5 JP2004508434A5 (enExample) 2009-01-08

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ID=8854214

Family Applications (1)

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JP2002525242A Pending JP2004508434A (ja) 2000-09-11 2001-08-27 ジリチウム化開始剤の調製方法およびアニオン重合方法

Country Status (9)

Country Link
US (1) US6562923B1 (enExample)
EP (1) EP1237941B1 (enExample)
JP (1) JP2004508434A (enExample)
AT (1) ATE329935T1 (enExample)
BR (1) BR0107199B1 (enExample)
CA (1) CA2391136A1 (enExample)
DE (1) DE60120631T2 (enExample)
ES (1) ES2263679T3 (enExample)
WO (1) WO2002020623A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8178641B2 (en) * 2007-10-30 2012-05-15 Jsr Corporation Amino group-containing conjugated diene polymer and method for producing the same, and block copolymer and method for producing the same
EP2070983B1 (en) * 2007-12-14 2017-05-24 Continental Reifen Deutschland GmbH Vulcanizable rubber mixture and its use for rubber products
ES2635133T3 (es) 2013-07-22 2017-10-02 Trinseo Europe Gmbh Iniciadores de la polimerización
CN106117405A (zh) * 2016-08-04 2016-11-16 苏州双湖化工技术有限公司 一种单分散低灰分的聚烯烃树脂的制备方法
CN106243258A (zh) * 2016-08-04 2016-12-21 苏州双湖化工技术有限公司 一种聚烯烃树脂及其制备方法与应用
CN108178819B (zh) * 2016-12-08 2020-11-10 中国石油化工股份有限公司 一种h型聚合物及其制备方法
FR3060573A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de synthese de polymeres dieniques modifies par des groupements derive d'un hydrocarbure aromatique polycyclique, produit issu de ce procede et composition le contenant.
FR3068356B1 (fr) 2017-06-30 2019-07-19 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un copolymere statistique a base de monomere dienique acyclique et de monomere dienique cyclique, copolymeres et compositions les comprenant
WO2019115470A1 (fr) 2017-12-11 2019-06-20 Compagnie Generale Des Etablissements Michelin Procédé de synthèse d'un polymère fonctionnel ou non à structure particulière
FR3123915B1 (fr) 2021-06-15 2024-07-26 Michelin & Cie Synthèse de polymères à blocs à base de 1,3-diène et d’éthylène
CN116253835A (zh) 2021-12-10 2023-06-13 台橡股份有限公司 共轭二烯系聚合物的制造方法及其得到的共轭二烯系聚合物、橡胶及轮胎
WO2024168332A2 (en) * 2023-02-10 2024-08-15 Bridgestone Corporation Method for preparing monomodal polyisoprene with dilithium initiators
FR3161986A1 (fr) 2024-05-02 2025-11-07 Compagnie Generale Des Etablissements Michelin membrane polymère échangeuse de protons et son procédé de synthèse par bombardement électronique
WO2025228711A1 (fr) 2024-05-02 2025-11-06 Compagnie Generale Des Etablissements Michelin Membrane polymère échangeuse d'anions et son procédé de synthèse par bombardement électronique

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58136603A (ja) * 1982-02-09 1983-08-13 Asahi Chem Ind Co Ltd 貯蔵安定性に優れる高濃度高純度ジリチウム触媒およびその製造方法
JPH0848709A (ja) * 1994-06-27 1996-02-20 Shell Internatl Res Maatschappij Bv 工業的に適用可能な二官能価アニオン重合イニシエーターの製造方法及び該イニシエーターの使用
JPH08225603A (ja) * 1994-11-18 1996-09-03 Asahi Chem Ind Co Ltd 有機金属錯体を用いた重合方法
JP2002527541A (ja) * 1998-10-09 2002-08-27 クレイトン・ポリマーズ・リサーチ・ベー・ベー ジリチウム開始剤の製造方法及びその使用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3674895A (en) * 1969-05-12 1972-07-04 Phillips Petroleum Co Polymerization of 1-olefins with multifunctional initiator systems
US4196154A (en) 1977-10-11 1980-04-01 The Dow Chemical Company Soluble multifunctional lithium containing initiator
US4172100A (en) 1977-10-11 1979-10-23 The Dow Chemical Company 1,3-Bis[1-(4-methylphenyl)ethenyl]benzene
US4172190A (en) * 1977-10-11 1979-10-23 The Dow Chemical Company Soluble multifunctional lithium containing initiator
US4960842A (en) 1987-11-16 1990-10-02 The Dow Chemical Company Amine containing initiator system for anionic polymerization
DE3886702T2 (de) * 1987-11-16 1994-07-14 Dow Chemical Co Amine, einen Initiator für die anionische Polymerisation enthaltend.
US5464914A (en) 1994-06-29 1995-11-07 The Dow Chemical Company Preparation of a low polydisperse polymer
US5595951A (en) * 1995-03-16 1997-01-21 The Goodyear Tire & Rubber Company Process for preparing a multilithio initiator for improved tire rubbers
US5561210A (en) * 1995-05-30 1996-10-01 Dow Corning Corporation Synthesis of siloxane-functional telechelic hydrocarbon polymers

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58136603A (ja) * 1982-02-09 1983-08-13 Asahi Chem Ind Co Ltd 貯蔵安定性に優れる高濃度高純度ジリチウム触媒およびその製造方法
JPH0848709A (ja) * 1994-06-27 1996-02-20 Shell Internatl Res Maatschappij Bv 工業的に適用可能な二官能価アニオン重合イニシエーターの製造方法及び該イニシエーターの使用
JPH08225603A (ja) * 1994-11-18 1996-09-03 Asahi Chem Ind Co Ltd 有機金属錯体を用いた重合方法
JP2002527541A (ja) * 1998-10-09 2002-08-27 クレイトン・ポリマーズ・リサーチ・ベー・ベー ジリチウム開始剤の製造方法及びその使用

Also Published As

Publication number Publication date
BR0107199A (pt) 2002-07-02
EP1237941A1 (fr) 2002-09-11
DE60120631D1 (de) 2006-07-27
EP1237941B1 (fr) 2006-06-14
DE60120631T2 (de) 2007-06-06
ATE329935T1 (de) 2006-07-15
BR0107199B1 (pt) 2010-11-16
CA2391136A1 (fr) 2002-03-14
WO2002020623A1 (fr) 2002-03-14
US6562923B1 (en) 2003-05-13
WO2002020623A9 (fr) 2002-09-19
ES2263679T3 (es) 2006-12-16

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