JP2004359480A - Transfer sheet - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a transfer sheet that can form a thick layer of a functional component except a glass component and can transfer a printed layer without causing stripping and collapse after transferring and calcining. <P>SOLUTION: The transfer sheet has a state of lamination in which a first glass layer 3, a functional layer 4 and a second glass layer 5 are laminated in order after transferring. The first glass layer is brought into contact with the surface of a pottery 8 when the transfer sheet is transferred to the pottery 8 to be an object of transfer. The transferred components have strong adhesiveness and do not exfoliate because the first glass layer 3 comprises the glass component and does not comprises the functional component. Further, the transferred components are not collapsed and stripped even if the functional layer is thickly formed because the second glass layer 5 can cover the first glass layer 3 and the functional layer 4. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a transfer paper, and more particularly, to a transfer paper that transfers a printing layer that does not collapse or peel after firing.
[0002]
[Prior art]
As a conventional transfer paper, there is one described in JP-A-2000-263996. This conventional transfer paper includes a mount, a fluorescent agent layer containing a fluorescent pigment formed on the surface of the mount via a water-soluble film, and an inner surface or a surface of the fluorescent agent layer directly or light-transmitting. A luminous pigment containing a luminescent pigment formed indirectly via a substance. As described above, according to the conventional transfer paper, the luminous agent layer and the fluorescent agent layer can be easily printed, and as a result, a large number of high-quality designs can be transferred to the surface of the porcelain.
[0003]
[Patent Document 1] Japanese Patent Application Laid-Open No. 2000-263996
[Problems to be solved by the invention]
Since the conventional transfer is configured as described above, by changing the fluorescent pigment used in the fluorescent agent layer, it is possible to emit bright light other than green or blue visible light emitted from the luminous agent layer. However, if the phosphorescent agent layer and the fluorescent agent layer are thickened and transferred to ceramic to increase the light emission amount, the phosphorescent agent layer and the fluorescent agent layer formed on the ceramic cannot maintain their shapes. There is a problem that the phosphorescent agent layer and the fluorescent agent layer are separated due to collapse or poor adhesion between the ceramic and the phosphorescent agent layer and the fluorescent agent layer.
[0005]
The present invention has been made to solve the above problems, and provides a transfer paper capable of forming a thick layer of a functional component other than a glass component, transferring the printed layer, and transferring a printed layer without peeling or collapse after firing. The purpose is to:
[0006]
[Means for Solving the Problems]
The transfer paper according to the present invention includes a water-soluble film, a first glass layer composed of a glass component, a functional layer composed of a glass component and a functional component other than the glass component, and a second layer composed of a glass component. It consists of a glass layer and a vinyl coat layer. As described above, in the present invention, the first glass layer, the functional layer, and the second glass layer are laminated in this order after the transfer, so that the first glass layer is transferred to the surface of the ceramic to be transferred. The layer comes into contact with the surface of the porcelain, but the first glass layer is made of a glass component and does not contain a functional component, has high adhesion and does not peel off, and further, the second glass layer forms the first glass layer and the functional layer. It can be covered, and does not collapse or peel even if the functional layer is formed thick. Although the function layer depends on the functional component, the functional layer becomes uneven due to the particles of the functional component and irregular reflection easily occurs. However, since the second glass layer is formed, the second glass layer is formed so as to fill in the unevenness of the functional layer. Since the glass component of the second glass layer enters and covers the second glass layer, the second glass layer becomes a surface layer, so that irregular reflection hardly occurs.
[0007]
In the transfer paper according to the present invention, the functional layer includes a plurality of layers as necessary. As described above, in the present invention, since the functional layer is formed from a plurality of layers, the functional layer is formed through a plurality of times when forming the transfer paper, and the functional layer can be formed reliably and appropriately thickly. The composition ratio between the glass component and the functional component of each layer can be changed, and transfer paper suitable for various uses can be provided.
[0008]
Further, in the transfer paper according to the present invention, as necessary, the constituent ratio of the glass component is larger in the order in which each of the functional layers is closer to the mount. As described above, in the present invention, since the constituent ratio of the glass component is larger in the order of each layer of the functional layer being closer to the mount, the first glass layer and each layer having the highest constituent ratio of the glass component in each layer are adjacent to each other. Adhering well and suppressing peeling, each layer adjacent to each layer has a close glass composition ratio, and subsequently each adjacent layer has a close glass composition ratio, and the glass component composition ratio Closeness means that the shape is hardly affected by the coefficient of thermal expansion when fired, so that collapse and peeling can be suppressed.
[0009]
Further, in the transfer paper according to the present invention, if necessary, the functional component of the functional layer is a luminous agent. As described above, in the present invention, since the functional component of the functional layer is a luminous agent, the functional layer can be formed much thicker than before, so that the luminous agent is appropriately suppressed from peeling or collapsing. A printing layer containing a large amount can be formed, and can have a remarkably high light storage power and afterglow luminance.
[0010]
Further, in the transfer paper according to the present invention, if necessary, the functional component of the functional layer is a pigment. As described above, in the present invention, since the functional component of the functional layer is a pigment, the functional layer can be formed much thicker than before, so that a large amount of a large amount of Pigments can be included to produce more vivid shades. Furthermore, a functional layer can be formed by combining a luminous agent and a pigment, and a vivid print layer can be formed even when the luminous agent is included. Here, conventionally, there is a printer having a printing layer in which a luminous agent and a pigment are combined, but a functional layer cannot be formed thick, and only a simple color combination exists. For example, a tile having a printed layer that accurately duplicates a painting can be created.
[0011]
Further, the processing method according to the present invention is characterized in that the first glass layer, the functional layer, the second glass layer, and the vinyl coat layer are transferred to ceramic using the transfer paper, and then the third glass layer made of a glass component is transferred. Is formed on at least the vinyl coat layer, coarse glass particles are sprayed on the third glass layer, and firing is performed at a firing temperature at which the coarse glass particles are fused to the third glass layer. As described above, in the present invention, since the third glass layer is provided and the coarse glass particles are scattered after the printing layer is transferred by the transfer paper, the coarse glass particles are embedded in the third glass layer after the scatter. In this state, the glass component and the coarse glass particles of the third glass layer were melted and fused, and the surface became uneven to have a certain degree of resistance, and became non-slip. By using the tile, the pedestrian can walk safely. Also, even if the coarse glass particles have sharp protrusions, the sharp protrusions due to firing become dull, and it is not always necessary to perform special treatment to make them dull, even if the pedestrian falls, the skin is sharp. It is safe with no injuries like cutting. The third glass layer was formed because the vinyl coat layer was dry and coarse glass particles were not embedded, and the glass layer was provided as an interposition for stabilizing the glass particles.
[0012]
In the ceramic according to the present invention, a first glass layer composed of a glass component, a functional layer composed of a glass component and a functional component other than the glass component, and a second glass layer composed of a glass component are arranged in this order from the ceramic surface. They are stacked.
[0013]
In the ceramics according to the present invention, the functional layer may be composed of a plurality of layers as necessary.
Further, in the ceramic according to the present invention, the constituent ratio of the glass component in each of the functional layers is larger in the order closer to the mount, if necessary.
In the ceramics according to the present invention, the functional component of the functional layer is a luminous agent, if necessary.
[0014]
In the ceramic according to the present invention, the functional component of the functional layer is a pigment, if necessary.
Further, the ceramic according to the present invention has coarse glass particles fused on the second glass layer as needed.
[0015]
Further, the printing layer forming method according to the present invention includes, in order from the ceramic surface, a first glass layer composed of a glass component, a functional layer composed of a glass component and a functional component other than the glass component, and a first glass layer composed of a glass component. The second glass layer is formed. As described above, in the present invention, since the first glass layer, the functional layer, and the second glass layer are formed in order from the ceramic surface, the transfer paper is used without forming the vinyl coat layer. To form a print layer similar to that used to form a print layer. Since the layer is formed directly without using transfer paper, the object to be formed is required to be flat.
[0016]
In addition, the processing method according to the present invention includes forming a first glass layer, a functional layer, and a second glass layer on a ceramic using the printing layer forming method, and then forming coarse glass particles on the second glass layer. And firing at a firing temperature at which the coarse glass particles fuse to the second glass layer.
[0017]
Further, the processing method according to the present invention is characterized in that the first glass layer, the functional layer, and the vinyl coat layer are transferred to ceramic using the transfer paper having no second glass layer, and then the second glass layer is formed. A glass layer is formed at least on the vinyl coat layer, coarse glass particles are sprayed on the second glass layer, and the glass particles are fired at a firing temperature at which the coarse glass particles are fused to the second glass layer. . As described above, in the present invention, since the second glass layer is provided and the coarse glass particles are scattered after the printing layer is transferred by the transfer paper, the coarse glass particles are embedded in the second glass layer after the scatter. In this state, the glass component and the coarse glass particles of the second glass layer were melted and fused, and the surface became uneven to have a certain degree of resistance and became non-slip. By using the tile, the pedestrian can walk safely. Also, even if the coarse glass particles have sharp protrusions, the sharp protrusions due to firing become dull, and it is not always necessary to perform special treatment to make them dull, even if the pedestrian falls, the skin is sharp. It is safe with no injuries like cutting. The second glass layer was formed because the vinyl coat layer was dry and coarse glass particles were not embedded, and the glass layer was provided as an intervening member for stabilizing the glass particles.
[0018]
BEST MODE FOR CARRYING OUT THE INVENTION
(First embodiment of the present invention)
A transfer sheet according to a first embodiment of the present invention will be described with reference to FIGS. FIG. 1 is a cross-sectional view of the transfer paper according to the present embodiment and an explanatory view during transfer. FIG. 2 is a cross-sectional view of a main part of the transfer paper according to the present embodiment after a printing layer is transferred to the ceramic and after firing. FIG. 3 is a graph showing the afterglow luminance and elapsed time according to the present embodiment.
[0019]
In FIG. 1A, the transfer paper according to the present embodiment includes a water-soluble film 2, a first glass layer 3 made of a glass component, a functional layer 4 made of a glass component and a fluorescent agent, in this order from the surface of the mount 1. It comprises a second glass layer 5 made of a glass component and a vinyl coat layer 6. In addition, the first glass layer 3, the functional layer 4, the second glass layer 5, and the vinyl coat layer 6 excluding the mount 1 and the water-soluble film 2 are referred to as a print layer 7.
The water-soluble film 2 dissolves upon contact with water. The glass component is mainly composed of frit, and has a particle size of, for example, 30 to 40 [μm]. The first glass layer 3 and the second glass 5 are a mixture of a glass component and a resin.
[0020]
The functional layer 4 is composed of a plurality of layers, and each layer has a configuration in which the composition ratio of the glass component is larger in the order closer to the mount. Here, as an example, the functional layer according to the present embodiment is composed of six layers, the thickness of each layer is equal to 120 [μm], the first layer 41 closest to the mount is the functional component 20 [%], and then The near second layer has a functional component of 30 [%], the next closest third layer has a functional component of 40 [%], the next closest fourth layer has a functional component of 50 [%], and the next closest layer has a functional component of 50 [%]. It is assumed that the fifth layer has a functional component of 60 [%], and the next closest sixth layer has a functional component of 70 [%].
The functional component of the functional layer 4 is a luminous agent, and the particle size of the luminous agent is, for example, 10 to 50 [μm] (particle size distribution 25.6 [μm]). The vinyl coat layer 6 is a layer made of resin.
[0021]
The transfer paper forming operation according to the present embodiment is performed by forming the water-soluble film 2 on the mount 1, forming the first glass layer 3, and then drying the first glass layer 3 to form the first layer. 41, the first layer 41 is dried to form a second layer 42, the second layer 42 is dried to form a third layer 43, and the third layer 43 is dried. Forming a fourth layer 44, drying the fourth layer 44 to form a fifth layer 45, drying the fifth layer 45 to form a sixth layer 46, and forming a sixth layer 46; Is dried to form a second glass layer 5, and the second glass layer 5 is dried to form a vinyl coat layer 6. Here, the first glass layer 3, the first layer 41, the second layer 42, the third layer 43, the fourth layer 44, the fifth layer 45, the sixth layer 46, and the second glass Since the layer 5 is formed on the mount 1 after being dissolved in a solvent of alcohols, a drying step is required. As described above, each layer of the functional layer 4 is equally 120 [μm], but the first glass layer 3 is 40 [μm], the second glass layer 5 is 240 [μm], and the vinyl coat layer is 20 [μm]. [Μm]. In order to form the respective layers, a method of forming the layers by solid coating can be used. However, in order to form the layers with high accuracy, it is preferable to use silk screen process printing (so-called silk screen). As another method, there is a method in which each layer is formed by spraying with a spray, or a sheet of each layer is formed, and the sheet is attached and formed.
[0022]
The operation of using the transfer paper according to the present embodiment is as follows. First, the transfer paper is immersed in water to dissolve the water-soluble film 1 and peel off the print layer 7 (see FIG. 1B). Is placed on the surface of the ceramic 8 to be transferred (see FIG. 2C). Next, the pottery 8 is put in a pot and baked at 400 [° C.] for 6 hours. As the time elapses, the thermosetting resin of the print layer 7 hardens, and by the time the firing time elapses, the water content of the binder evaporates, and the print layer 7 is baked on the ceramic 8 (FIG. 2). (D)).
[0023]
The printing layer 7 transferred and baked using the transfer paper according to the present embodiment has a high afterglow luminance as can be read from a curve a in the graph shown in FIG. 3 and emits afterglow for a long time. are doing. As a comparative example of the transfer paper according to the present embodiment, a print layer transferred and baked using a transfer paper having no first glass layer 3 and second glass layer 5 and having four functional layers is shown in FIG. As can be read from the curve b in the graph shown in FIG. 3, the afterglow hardness and the afterglow time (the time from the start of the afterglow until the afterglow stops) are remarkably worse as compared with the case where the transfer paper according to the present embodiment is used. The result was. Here, the functional component was set to 50% for each of the four functional layers. It should be noted that the number of the functional layers is four, but if the number of layers is more than this, as described above, the fluorescent material layer, that is, the functional layer, cannot maintain its shape and breaks down, and the ceramic layer 8 and the functional layer are broken. This is because the functional layer is peeled off due to poor adhesion. FIG. 3 is a graph showing the afterglow luminance and the elapsed time. In the graph, a curve a indicates that the ceramic 8 on which the printing layer 7 was transferred using the transfer paper according to the present embodiment was sufficiently irradiated with light, and then left in the dark. Is a measurement result of the afterglow luminance when the measurement is performed, and a curve b is a measurement result of the comparative example.
[0024]
As described above, according to the transfer paper according to the present embodiment, the water-soluble film 2, the first glass layer 3 made of a glass component, the functional layer 4 made of a glass component and a fluorescent agent, the glass component Since the second glass layer 5 and the vinyl coat layer 6 are composed of the functional layer 4 having a plurality of layers and the composition ratio of the glass component is larger in the order closer to the mount 1, the transfer paper is transferred. In a state where the printing layer 7 is placed on the ceramics 8, the first glass layer 3 made of a glass component having no functional component adheres well to the ceramics 8, and the first glass layer 3 adheres well to the ceramics 8. The first layer 41 having the least functional component is formed as compared with each layer of the other functional layers 4 and adheres well, and each layer is successively formed in ascending order of the functional component, and the glass component is formed between the respective layers. And the functional component are relatively close It is hardly affected by thermal expansion at the time of formation, is firmly formed and hardly collapses, and the printed layer 7 (excluding the second glass layer 5) is covered with the second glass layer 5 and peeled off. In addition, a thicker functional layer 4 can be formed, and if the functional component is a luminous agent, the printed layer 7 having a very high luminous power can be formed.
[0025]
In the present embodiment, the printing layer is formed using transfer paper. However, the first glass layer 3, the functional layer 4, and the second glass layer 5 can be formed directly on the ceramic surface in order. A similar print layer 7 can be formed without forming the vinyl coat layer 6. That is, this is a method of forming each layer one by one on the ceramics 8 irrespective of transfer. When this method is used, the surface of the ceramic 8 to be formed is preferably flat.
[0026]
(Second embodiment of the present invention)
A processing method using transfer paper according to the second embodiment of the present invention will be described with reference to FIG. 4 or FIG. FIG. 4 is an explanatory diagram of a processing method using transfer paper according to the present embodiment, and FIG. 5 is an explanatory diagram of a processing method using no transfer paper according to the embodiment.
[0027]
The processing method using the transfer paper according to the present embodiment uses the transfer paper according to the first embodiment without the second glass layer 5, the first glass layer 3, the functional layer 4, and the vinyl coat layer. After transferring 6 to porcelain (see FIG. 4 (a)), a second glass layer 5 made of a glass component is formed so as to cover the vinyl coat layer 6 (see FIG. 4 (b)). The coarse glass particles 9 are scattered on the second glass layer 5 (see FIG. 4C), and fired at a firing temperature at which the coarse glass particles 9 fuse to the second glass layer 5 (FIG. 4D). See) Configuration.
[0028]
The coarse glass particles 9 preferably have a particle size of 0.3 [mm] to 3 [mm] in the case of a tile for walking and have a plurality of particle sizes, that is, irregularities. Resistance can be obtained. The constant resistance is dangerous when walking, when the resistance is almost negligible, it is slippery, whereas when the resistance is too high, it may be good when only moving forward, but it stops suddenly from walking Sometimes there is too much resistance and there is a danger of falling over without stepping on.In addition, high resistance means that there is a danger of being injured by the surface when falling, such as a rough surface, It is resistance that does not hinder the raising of the foot and requires more physical strength than necessary to walk. However, this is related to walking and does not apply when a special use can be assumed. After the coarse glass particles 9 are sprayed, the ceramic layer 8 is fired at 400 [° C.] for 6 hours to fire the printing layer 7, and then the corners of the coarse glass particles 9 are cut and fused with the second glass layer 5. The firing is performed at 700 ° C. to 800 ° C. for several tens of minutes. Here, comparing FIG. 4 (c) with FIG. 4 (d), in FIG. 4 (c), the coarse glass particles 9 have sharp angles, whereas in FIG. There are no sharp corners and they are round.
[0029]
The larger the particle size of the coarse glass particles 9, the higher the firing temperature for the coarse glass particles 9 or the longer the firing time. The requirement that the particle size be irregular is that, when coarse glass particles 9 having a uniform particle size are used, the height of adjacent coarse glass particles 9 becomes the same in a state in which the corners after firing are rounded, and are constant. This is because it is difficult to obtain the resistance.
[0030]
As described above, according to the processing method using the transfer paper according to the present embodiment, after the print layer 7 is transferred from the transfer paper, the second glass layer 5 is formed and the coarse glass particles 9 are dispersed, and the ceramic 8 Is placed in a kettle and fired for the printing layer 7. After firing, the printing layer 7 is fired at a firing temperature at which the coarse glass particles 9 are fused to the second glass layer 5. The surface of the coarse glass particles 9 is melted by the firing for the coarse glass particles 9 to form an angle and is fused with the second glass layer 5 in contact with the second glass layer 5. For example, when used as a walking tile, it is possible to produce a safe tile that is not injured on a cornerless surface, has a certain resistance, and does not slip.
[0031]
In the processing method according to the present embodiment, the transfer paper according to the first embodiment can be used, and the first glass layer 3 and the functional layer 4 can be used by using the transfer paper according to the first embodiment. After transferring the second glass layer 5 and the vinyl coat layer 6 to the porcelain, a third glass layer made of a glass component is formed on at least the second glass layer 5, and the third glass layer is formed on the third glass layer. By spraying coarse glass particles and firing at a firing temperature at which the coarse glass particles fuse to the third glass layer, a tile similar to that of the present embodiment can be produced. However, the thickness is increased by the formation of the third glass layer.
[0032]
Further, in the processing method of the present embodiment, the printing layer is formed using the transfer paper, but the first glass layer 3, the functional layer 4, and the second glass layer 5 are formed directly on the ceramic surface in order (see FIG. 5 (a)), scatter coarse glass particles 9 on the second glass layer 5 (see FIG. 5 (b)), and fire at a firing temperature at which the coarse glass particles are fused to the second glass layer. By doing so (see FIG. 5C), a tile similar to the present embodiment can be made without forming the vinyl coat layer 6.
[0033]
【The invention's effect】
As described above, in the present invention, the first glass layer, the functional layer, and the second glass layer are stacked in this order after the transfer, so that the first glass layer, the functional layer, and the second glass layer are transferred to the surface of the ceramic to be transferred. The glass layer is in contact with the surface of the porcelain, but the first glass layer is made of a glass component and does not contain a functional component and has high adhesion and does not peel off. Further, the second glass layer is formed of the first glass layer and the functional layer. Can be covered, and there is an effect that even if the functional layer is formed thick, it does not collapse or peel off. Although the function layer depends on the functional component, the functional layer becomes uneven due to the particles of the functional component and irregular reflection easily occurs. However, since the second glass layer is formed, the second glass layer is formed so as to fill in the unevenness of the functional layer. Since the glass component of the second glass layer enters and covers the second glass layer, the second glass layer becomes the surface layer, so that an effect is obtained that irregular reflection hardly occurs.
[0034]
Further, in the present invention, since the functional layer is formed from a plurality of layers, the functional layer is formed through a plurality of times when forming the transfer paper, so that the functional layer can be formed reliably and appropriately thick, and each layer can be formed. It is also possible to change the composition ratio of the glass component and the functional component, and it is possible to provide transfer paper suitable for various uses.
[0035]
Further, in the present invention, since the constituent ratios of the glass components are larger in the order of the layers of the functional layer being closer to the mount, the layers having the highest constituent ratios of the glass components in the first glass layer and the respective layers are adjacent to each other. The layers adjacent to the respective layers have a glass composition ratio close to each other, and the adjacent layers have a similar glass composition ratio thereafter, and the glass component composition ratio is low. Closeness means that the shape is hardly affected by the coefficient of thermal expansion when fired, and has an effect that collapse and peeling can be suppressed.
[0036]
Further, in the present invention, since the functional component of the functional layer is a luminous agent, the functional layer can be formed much thicker than before, so that the amount of the luminous agent is increased after appropriately suppressing peeling and collapse. It is possible to form a printed layer containing the same, which has the effect of having a remarkably high luminous power and afterglow luminance.
[0037]
Further, in the present invention, since the functional component of the functional layer is a pigment, the functional layer can be formed much thicker than before, so that a large amount of various kinds of pigments can be appropriately suppressed on peeling and collapse. And a more vivid color tone can be produced. Furthermore, a functional layer can be formed by combining a luminous agent and a pigment, and even if a luminous agent is included, a vivid print layer can be formed.
[0038]
Further, in the present invention, since the third glass layer is provided and the coarse glass particles are scattered after the printing layer is transferred by the transfer paper, the coarse glass particles are embedded in the third glass layer after the scatter, In this state, the glass component of the third glass layer and the coarse glass particles are melted and fused, and the surface becomes uneven to have a certain degree of resistance, so that the tile becomes non-slip. The effect that a pedestrian can walk safely by using is provided.
[0039]
Further, in the present invention, the first glass layer, the functional layer, and the second glass layer are formed in order from the ceramic surface, so that the transfer paper is used without forming the vinyl coat layer. This has the effect that a printing layer similar to the formation of a printing layer can be formed.
[0040]
Further, in the present invention, since the second glass layer is provided and the coarse glass particles are scattered after the printing layer is transferred by the transfer paper, the coarse glass particles are embedded in the second glass layer after the scatter, In this state, the glass component of the second glass layer and the coarse glass particles are melted and fused, and the surface becomes uneven to have a certain degree of resistance and becomes non-slip. The effect that a pedestrian can walk safely by using is provided.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a transfer sheet according to a first embodiment of the present invention and an explanatory view during transfer.
FIGS. 2A and 2B are a cross-sectional view of a main part of the ceramic after a transfer layer according to the first embodiment of the present invention is transferred to a ceramic, and a cross-sectional view of the main part after firing.
FIG. 3 is a graph illustrating the afterglow luminance and elapsed time according to the first embodiment of the present invention.
FIG. 4 is an explanatory diagram of a processing method using transfer paper according to a second embodiment of the present invention.
FIG. 5 is an explanatory diagram of a processing method without using transfer paper according to a second embodiment of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Mount 2 Water-soluble film 3 1st glass layer 4 Functional layer 41 1st layer 42 2nd layer 43 3rd layer 44 4th layer 45 5th layer 46 6th layer 5 2nd glass Layer 6 Vinyl coat layer 7 Printing layer 8 Ceramics 9 Coarse glass particles 10 Water 11 Container for water

Claims (15)

A water-soluble film, a first glass layer composed of a glass component, a functional layer composed of a glass component and a functional component other than the glass component, a second glass layer composed of a glass component, and a vinyl coat layer in this order from the surface of the mount. Transfer paper comprising: The transfer paper according to claim 1,
Transfer paper, wherein the functional layer comprises a plurality of layers. The transfer paper according to claim 2, wherein
A transfer paper, wherein the constituent ratio of the glass component is larger in the order in which each of the functional layers is closer to the mount. The transfer paper according to claim 1, wherein
Transfer paper, wherein the functional component of the functional layer is a luminous agent. The transfer paper according to claim 1, wherein
Transfer paper, wherein the functional component of the functional layer is a pigment. After transferring the first glass layer, the functional layer, the second glass layer, and the vinyl coat layer to the ceramic using the transfer paper according to any one of claims 1 to 5, at least a third glass layer made of a glass component is formed. Forming on the vinyl coat layer, spraying coarse glass particles on the third glass layer, and firing at a firing temperature at which the coarse glass particles fuse to the third glass layer. . A first glass layer composed of a glass component, a functional layer composed of a glass component and a functional component other than the glass component, and a second glass layer composed of a glass component are laminated in order from the ceramic surface. China. The ceramic according to claim 7,
Ceramics characterized in that said functional layer comprises a plurality of layers. The porcelain according to claim 8, wherein
Ceramics, wherein the constituent ratio of the glass component in each of the functional layers is larger in the order closer to the mount. The ceramics according to claim 7, wherein:
Ceramics wherein the functional component of the functional layer is a luminous agent. The ceramics according to claim 7, wherein
Ceramics wherein the functional component of the functional layer is a pigment. The ceramics according to claim 7, wherein
Ceramics, wherein coarse glass particles are fused on the second glass layer. A first glass layer made of a glass component, a functional layer made of a glass component and a functional component other than the glass component, and a second glass layer made of a glass component are formed in this order from the ceramic surface. Printing layer forming method. After forming the first glass layer, the functional layer, and the second glass layer on the ceramic using the printing layer forming method according to claim 13, coarse glass particles are sprayed on the second glass layer, A processing method characterized by firing at a firing temperature at which the coarse glass particles are fused to the second glass layer. A second glass layer made of a glass component after transferring the first glass layer, the functional layer, and the vinyl coat layer to the ceramic using the transfer paper according to any one of claims 1 to 5 without the second glass layer. Is formed on at least the vinyl coat layer, and coarse glass particles are sprayed on the second glass layer, and fired at a firing temperature at which the coarse glass particles fuse to the second glass layer. Processing method.

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