JP2004353405A - Steel sheet pile anti-corrosive structure excellent in long-term durability - Google Patents
Steel sheet pile anti-corrosive structure excellent in long-term durability Download PDFInfo
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Abstract
Description
【0001】
【発明の属する技術分野】
本発明は、海浜の埋立地、廃棄物処理施設や港湾・河川の護岸などに用いられる鋼矢板の防食構造体に関するもので、さらに詳しくは、激しい腐食環境に曝される場合に、長期防食性を確保する鋼矢板からなる防食構造体に関する。
【0002】
【従来の技術】
激しい腐食環境に使用される鋼管杭、鋼管矢板、鋼矢板等の海洋鋼構造物は防食塗装が行われ、なかでも厚みが数mmに及ぶ重防食塗装が有効である。数十年に及ぶ長期耐久性が必要とされる場合、電気絶縁性、耐薬品性等の種々の防食性に優れ、安価な樹脂であるポリオレフィン、あるいはポリウレタンといった樹脂を被覆材とした重防食被覆鋼材が用いられている。
特許文献1、特許文献2、特許文献3には、それぞれ上記ポリオレフィン被覆やポリウレタン被覆の上に0.01から0.1mm厚のチタンの板を貼り付け、防食性や接着耐久性を向上させる方法に関して開示されている。また、特許文献4では、防食シートの上に各種耐食金属板を貼り付けた構造と防食方法について開示されている。
【0003】
【特許文献1】
特開2001−47550号公報
【特許文献2】
特開2001−113630号公報
【特許文献3】
特開2001−260271号公報
【特許文献4】
特開2001−81583号公報
【0004】
【発明が解決しようとする課題】
前記、防食技術のうち樹脂を被覆材とするものでは、有機樹脂そのものの耐久性に四、五十年程度の寿命であり、また、鉄と樹脂との接着力も時間の経過により低下する。接着力が低下すると被覆の端部や傷部から剥離が進行するため、鉄素地が露出した部分では次第に腐食が発生する。
一方、高耐食金属板を被覆する防食法を海岸環境で使用する鋼矢板にて適用する場合、爪の嵌合部まで高耐食金属板を被覆すると、打設時に高耐食金属板が破れる恐れがあることと、その時に鉄素地と高耐食金属板が接触して、電気化学的な反応である異種金属接触腐食が発生して露出した鉄素地が激しく腐食し、構造的な欠陥が生じる可能性がある。
【0005】
そこで、本発明は防食材料として高耐食金属板を被覆する従来技術の上記問題点を解決し、異種金属接触腐食が起きず、激しい腐食環境に曝されても長期防食性を確保できる長期耐久性防食構造体を提供することを目的とする。
【0006】
【課題を解決するための手段】
前記課題を解決するために本発明の長期耐久性に優れた鋼矢板防食構造体は以下の構造を持つ。
(1)鋼材面に防食有機樹脂層、有機樹脂製接着層、および高耐食性金属板とを順次積層してなる複数の鋼矢板を、当該鋼矢板の爪部によって嵌合してなる鋼矢板の構造体であって、前記嵌合部の被防食面側全面に対し、絶縁物を介して前記鋼矢板と絶縁した状態で高耐食金属板を被覆したことを特徴とする長期耐久性に優れた鋼矢板防食構造体。
(2)前記嵌合部に被覆する高耐食金属板に代えて、表面に高耐食金属板を張り付けた、あるいは、高耐食性金属膜を形成させた繊維強化プラスチック(FRP)を用いることを特徴とする長期耐久性に優れた鋼矢板防食構造体。
【0007】
即ち、本発明は、爪部を除く被防食面に有機樹脂製接着層を介して高耐食金属板(A)を積層してなる複数の鋼矢板を前記爪部で嵌合してなる鋼矢板の構造体であって、前記嵌合部の嵌合部全面に、鋼矢板に、防食が施される鋼矢板と高耐食金属部材(B)の電気的な導通を防止して異種金属接触腐食を防止するために樹脂絶縁物を介して高耐食金属板(B)をボルトなどで固定する。鋼矢板上の高耐食金属板(A)と高耐食金属部材(B)の隙間からの水・酸素・塩素等の腐食要因の進入を防止するために接着層、ゴムシール層、または溶接シームを設けることを特徴とする。
【0008】
【発明の実施の形態】
本発明で用いる鋼矢板は、鋼矢板の爪部を除く被防食面に、必要に応じ接着剤を塗布し防食有機樹脂層を施し、更に有機樹脂の接着層を介して高耐食性金属板(A)を積層する。その断面構成例を図1に示す。図において、1が鋼矢板、2が防食有機樹脂層、3が接着層、4が高耐食金属板である。図2は、鋼矢板の爪部に高耐食金属板を取り付ける構造の一例を示した図である。図2に示すように鋼矢板の爪の被防食全面には予めナット構造5を形成しておく。ナット構造内部は搬送中や打設後の腐蝕防止のために軟質充填剤6などで充填しておくと良い。ここで、被防食面とは、護岸用の土留め壁として鋼矢板を使用する場合には、土側ではなく、海水に面する片面を言う。
【0009】
さらに本発明では、これらの鋼矢板を打設後に波打ち際を中心した範囲の高さの爪部を覆う形状の高耐食金属板(B)を有機樹脂製の充填接着剤、あるいはシール剤をはさんで、電気絶縁体を介してボルトで固定する。このような長期耐久性防食構造体、ならびにこのような構造体を形成せしめる構造を規定する。その構造体の断面構成例を図3に示す。7が高耐食金属板(B)であり、8が有機樹脂製の接着充填剤、またはゴムシールである。9がナット構造5と結合するボルトである。9のボルトは7の高耐食金属板を固定する目的のものであるが、互いに電気的に接触しないように、10の絶縁及び防食樹脂を間に介して固定を行う。図3の構造例では7の高耐食金属板にも強度が必要となるため、金属板厚みは0.5mm程度以上必要である。あるいは、高耐食金属板のコストと剛性に問題が生じる場合は図4の方法を用いると良い。すなわち、絶縁構造と強度部材として11のFRP(繊維強化プラスチック)を用い、その表面に7の高耐食金属板を貼り付けるかあるいは金属の薄膜を形成する。FRPは絶縁材として機能するため、9のボルトの絶縁構造を省略することが出来る。更に、ボルト9の腐食を防止するために12の防食カバーを設ける。
【0010】
本発明においては、鋼矢板の打設法を規定するものではないが、あらかじめ被覆した高耐食金属板(A)に傷をつけないよう注意をする必要がある。さらに、本発明における高耐食金属板(A)、(B)は、特に規定するものではないが、海水中での腐食速度が実用的に小さい、すなわち10μm/年以下であり、かつ隙間腐食などが起き難い材料が好ましく、モリブデンを2%以上含む海水環境でも耐食性の高いステンレス鋼、Ni基の耐食合金、チタンが望ましい。さらに、高耐食金属板(A)、(B)は同種の金属であることが望ましい。さらに、高耐食金属板の厚みについて特に規定するものではないが、0.1mm以上1.5mm未満が望ましい。0.1mm以下であると、打設時などに金属板が剥離する場合が多く実用的でない。また、1.5mmを超えると加工性が劣り、曲げ部などで腰折れや密着不良が起きやすくなる。また、高耐食金属板を接着する有機樹脂の厚みに関しては、特に規定するものではないが、高耐食金属板と鋼矢板素地とは電気的に絶縁されていることが必須になり、加工時や打設時の機械的な衝撃により絶縁破壊を起こさないために、0.3mm以上の厚みが望ましい。また、厚い方では、コストと耐久性とのバランスもあり、5mm以下が望ましい。有機樹脂との接着層には、例えば変性ポリオレフィン、ウレタン、エポキシ樹脂等の接着剤を用いる。さらに安価で接着層の厚みを大きくするために、ウレタンエラストマーや発泡性ウレタン樹脂層を介することも可能である。
【0011】
本発明は、爪部に嵌合後に高耐食金属カバーを取り付ける方法として、特に限定するものではない。従って、図2の様にナットを鋼矢板側に溶接固定するのではなく、鋼矢板にスタッドボルトを溶接しておいて、ナットで固定しても良い。但し、スタッドボルトを用いる方法では、搬送時にボルトの破損が生じやすいので注意が必要である。高耐食金属板(A)と(B)はエポキシパテによる接着剤、あるいは、ゴム、シリコン等のシール構造によってシールされる構造を持つが、更に、信頼性を高めたい場合には、耐食金属同士の溶接を行っても良い。この際、耐食金属がチタンや耐海水ステンレス鋼である場合には、通電加熱によるシーム溶接、TIG溶接などが適用可能である。さらに、カバーの内部に有機樹脂充填剤を注入することが望ましい。充填剤を用いると、カバーの上下端部からの水や酸素の侵入を抑制することが出来るので、耐久性寿命が大幅に増加する。
【0012】
【実施例】
以下に実施例を用いて本発明を詳細に説明する。
JIS規格SY295のU型鋼矢板、長さ10mに、干満帯に相当する3mの部分をグリッドブラスト処理し、スケール等を除去した後、プライマーとしてポリオールとイソシアネート硬化剤による2液混合硬化型のウレタン樹脂塗料を15〜60μm膜厚となるようにスプレー塗布して硬化させた。次いで、その表面にカオリンクレー微粉末を含有する2液硬化ウレタンエラストマーをミキサーで混合してスプレー塗装を行い、3mm厚みのポリウレタン重防食被覆を行った。この後、この表面に熱硬化性のイソシアネート硬化型ウレタン樹脂を塗布して半硬化した状態で0.3mm厚のチタン板をロールで圧着しながら表面に貼り付けた。貼り付けた面は、鋼矢板の凸面を3体、ならびに凹面を2体である。凹面の鋼矢板の1体は爪部に予め図2の断面で示されるナット構造を20cmピッチで設け、もう1体は比較例としてナット構造を設けなかった。これらを海浜部の試験個所にてバイブルハンマーにより打設した後、ナットを溶接した爪部の片側には図3の構造で本発明のボルト固定構造で、爪部に高耐食金属を被覆した。また、もう片側には図4のFRPを用いた固定構造を被覆した。なお、高耐食金属板(B)の上下端は水浸入を防ぐためにエポキシ充填剤で完全にシールを行った。ナットを溶接していない爪部は比較として、ボルト固定構造を設けずに接着充填剤によって高耐食金属板を接着固定した場合と、耐食金属を被覆しない場合でのケースとした。
【0013】
施工後、6ヶ月経過し、外観の変化を観察した。比較例である未処理の爪部は塗装が及んでいない部分でさびが発生していた。また、ボルトを用いずに接着剤のみで耐食金属を固定したものは、嵌合部の耐食金属カバーの端部に浮きが発生していた。また、端部にたがねを入れて耐食金属板(B)を除去すると、容易に剥離することが出来た。しかしながら、その耐食金属被覆下の爪部については腐蝕発生は見られなかった。それ以外の本発明例では、浮きは発生しておらず、極めて良好な外観であると同時に、端部にたがねを差し込んでもボルトを除去しない状態では剥離させることは出来なかった。また、ボルト除去によって高耐食金属板を除去した状態で観察を行っても、ナット部分を含めて腐蝕発生は見られず健全な状態であり、本発明の効果が実証できた。
【0014】
【発明の効果】
本発明により、美麗で長期の耐久性能を持つ鋼矢板護岸を作製することが可能である。加えて、従来の重防食では被覆が行われていなかった嵌合部の長期耐久性にも優れることから、維持管理費の低減が可能である。
【図面の簡単な説明】
【図1】本発明の打設前の鋼矢板凸面への防食断面例。
【図2】本発明の打設前の鋼矢凹面への防食断面及び固定構造例。
【図3】本発明の高耐食金属板(B)を用いた防食構造体の嵌合部の断面例。
【図4】本発明の高耐食金属板(B)とFRPの複合体を用いた防食構造体の嵌合部の断面例。
【符号の説明】
1:鋼矢板
2:有機樹脂防食層
3:有機樹脂接着層
4:高耐食金属板(A)
5:ナット構造
6:有機樹脂充填剤
7:高耐食金属板(B)
8:充填接着剤又はゴムシール
9:ボルト
10:電気絶縁構造
11:FRP
12:防食キャップ[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an anticorrosion structure made of steel sheet piles used for landfills on beaches, waste treatment facilities and seawalls of rivers and harbors, and more particularly, to a long-term anticorrosion structure when exposed to a severely corrosive environment. The present invention relates to an anticorrosion structure made of a steel sheet pile that ensures the above.
[0002]
[Prior art]
Marine steel structures such as steel pipe piles, steel pipe sheet piles, steel sheet piles, and the like used in severely corrosive environments are subjected to anticorrosion coating. Above all, heavy anticorrosion coating with a thickness of several mm is effective. When long-term durability for several decades is required, a heavy-duty anti-corrosion coating using a resin such as polyolefin or polyurethane, which is an inexpensive resin with excellent anti-corrosion properties such as electrical insulation and chemical resistance, is used. Steel materials are used.
[0003]
[Patent Document 1]
JP 2001-47550 A [Patent Document 2]
JP 2001-113630 A [Patent Document 3]
JP 2001-260271 A [Patent Document 4]
Japanese Patent Application Laid-Open No. 2001-81583
[Problems to be solved by the invention]
Among the above anticorrosion techniques, those using a resin as a coating material have a life of about forty to fifty years due to the durability of the organic resin itself, and the adhesive force between iron and the resin also decreases with time. When the adhesive strength is reduced, the peeling proceeds from the end portion or the scratched portion of the coating, so that the corrosion gradually occurs in the portion where the iron base is exposed.
On the other hand, when the anticorrosion method of coating a high corrosion-resistant metal plate is applied to steel sheet piles used in coastal environments, if the high corrosion-resistant metal plate is covered up to the fitting portion of the claws, the high corrosion-resistant metal plate may be broken during casting. There is a possibility that the iron base and the highly corrosion-resistant metal plate will contact each other at that time, and the corrosion of the dissimilar metal, which is an electrochemical reaction, will occur, and the exposed iron base will be severely corroded, causing structural defects. There is.
[0005]
Therefore, the present invention solves the above-mentioned problems of the prior art of coating a high corrosion-resistant metal plate as an anticorrosion material, does not cause dissimilar metal contact corrosion, and ensures long-term corrosion resistance even when exposed to a severe corrosive environment. An object of the present invention is to provide an anticorrosion structure.
[0006]
[Means for Solving the Problems]
In order to solve the above problems, a steel sheet pile anticorrosion structure of the present invention having excellent long-term durability has the following structure.
(1) A steel sheet pile obtained by fitting a plurality of steel sheet piles in which a corrosion-resistant organic resin layer, an organic resin adhesive layer, and a highly corrosion-resistant metal sheet are sequentially laminated on a steel material surface by claws of the steel sheet pile. The structure is excellent in long-term durability, in which the entire corrosion-protected surface of the fitting portion is covered with a high corrosion-resistant metal plate in a state insulated from the steel sheet pile via an insulator. Steel sheet pile anticorrosion structure.
(2) Instead of the high corrosion-resistant metal plate covering the fitting portion, a fiber-reinforced plastic (FRP) having a high corrosion-resistant metal plate adhered to the surface or having a high corrosion-resistant metal film formed thereon is used. Steel sheet pile anticorrosion structure with excellent long-term durability.
[0007]
That is, the present invention provides a steel sheet pile formed by stacking a plurality of steel sheet piles formed by laminating a highly corrosion-resistant metal plate (A) on an anticorrosion surface excluding a claw portion via an organic resin adhesive layer with the claw portion. The steel sheet pile is provided with corrosion protection on the entire surface of the fitting section of the fitting section to prevent electrical conduction between the steel sheet pile to be subjected to corrosion protection and the highly corrosion-resistant metal member (B), thereby preventing dissimilar metal contact corrosion. In order to prevent this, a highly corrosion-resistant metal plate (B) is fixed with a bolt or the like via a resin insulator. An adhesive layer, a rubber seal layer, or a welded seam is provided to prevent corrosion factors such as water, oxygen, and chlorine from entering through a gap between the highly corrosion-resistant metal sheet (A) and the highly corrosion-resistant metal member (B) on the steel sheet pile. It is characterized by the following.
[0008]
BEST MODE FOR CARRYING OUT THE INVENTION
The steel sheet pile used in the present invention is provided with an anti-corrosion organic resin layer by applying an adhesive as necessary to the corrosion-protected surface excluding the claws of the steel sheet pile, and furthermore, a highly corrosion-resistant metal sheet (A ). FIG. 1 shows an example of the cross-sectional configuration. In the figure, 1 is a steel sheet pile, 2 is an anticorrosion organic resin layer, 3 is an adhesive layer, and 4 is a high corrosion resistant metal plate. FIG. 2 is a diagram showing an example of a structure for attaching a highly corrosion-resistant metal plate to a claw portion of a steel sheet pile. As shown in FIG. 2, a
[0009]
Further, in the present invention, a high corrosion-resistant metal plate (B) having a shape covering a claw portion having a height centered on a wavy edge after the steel sheet pile is driven is sandwiched with a filling adhesive or a sealing agent made of an organic resin. Then, it is fixed with bolts via an electrical insulator. Such a long-term durable anticorrosion structure and a structure for forming such a structure are defined. FIG. 3 shows an example of a cross-sectional configuration of the structure.
[0010]
In the present invention, a method for driving steel sheet piles is not specified, but care must be taken not to damage the highly corrosion-resistant metal sheet (A) previously coated. Furthermore, the high corrosion-resistant metal sheets (A) and (B) in the present invention are not particularly limited, but have a practically low corrosion rate in seawater, that is, 10 μm / year or less, and have crevice corrosion. It is preferable to use a stainless steel, a Ni-based corrosion-resistant alloy, or titanium having high corrosion resistance even in a seawater environment containing 2% or more of molybdenum. Further, it is desirable that the high corrosion-resistant metal plates (A) and (B) are the same type of metal. Further, the thickness of the highly corrosion-resistant metal plate is not particularly specified, but is preferably 0.1 mm or more and less than 1.5 mm. If the thickness is less than 0.1 mm, the metal plate often peels off during casting or the like, which is not practical. On the other hand, when the thickness exceeds 1.5 mm, workability is poor, and buckling or poor adhesion is likely to occur at a bent portion or the like. The thickness of the organic resin for bonding the high corrosion-resistant metal plate is not particularly specified, but it is essential that the high corrosion-resistant metal plate and the steel sheet pile base be electrically insulated. A thickness of 0.3 mm or more is desirable in order not to cause dielectric breakdown due to mechanical impact at the time of casting. In the case of a thicker member, it is desirable that the thickness be 5 mm or less because there is a balance between cost and durability. For the adhesive layer with the organic resin, for example, an adhesive such as a modified polyolefin, urethane, or epoxy resin is used. Further, in order to increase the thickness of the adhesive layer at low cost, it is possible to interpose a urethane elastomer or a foamable urethane resin layer.
[0011]
The present invention is not particularly limited as a method of attaching the high corrosion resistant metal cover after fitting to the claw portion. Therefore, instead of welding and fixing the nut to the steel sheet pile as shown in FIG. 2, a stud bolt may be welded to the steel sheet pile and fixed with the nut. However, in the method using stud bolts, care must be taken because the bolts are liable to be damaged during transportation. The high corrosion-resistant metal plates (A) and (B) have a structure sealed by an adhesive made of epoxy putty or a seal structure made of rubber, silicon, or the like. Welding may be performed. At this time, when the corrosion-resistant metal is titanium or seawater-resistant stainless steel, seam welding by electric heating, TIG welding, or the like can be applied. Further, it is desirable to inject an organic resin filler into the inside of the cover. When a filler is used, the penetration of water or oxygen from the upper and lower ends of the cover can be suppressed, so that the durability life is greatly increased.
[0012]
【Example】
Hereinafter, the present invention will be described in detail with reference to Examples.
U-type steel sheet pile of JIS standard SY295, 10m long, 3m part corresponding to the tidal zone is grid blasted, scale is removed, etc. Then, two-part mixture-curable urethane resin with polyol and isocyanate curing agent as primer The paint was spray-coated to a thickness of 15 to 60 μm and cured. Next, a two-component curable urethane elastomer containing fine kaolin clay powder was mixed with a mixer on the surface thereof, spray-coated, and a 3 mm-thick polyurethane heavy anticorrosion coating was performed. Thereafter, a thermosetting isocyanate-curable urethane resin was applied to the surface, and in a semi-cured state, a 0.3 mm-thick titanium plate was adhered to the surface while being pressed with a roll. The attached surfaces are three convex surfaces of steel sheet pile and two concave surfaces. One of the concave steel sheet piles was previously provided with a nut structure shown in a cross section in FIG. 2 at a pitch of 20 cm on the claws, and the other was not provided with a nut structure as a comparative example. These were cast at a test location on the beach with a bible hammer, and one side of the nail to which the nut was welded was coated with a highly corrosion-resistant metal by the bolt fixing structure of the present invention in the structure of FIG. 3 on one side. The other side was covered with a fixing structure using the FRP shown in FIG. The upper and lower ends of the highly corrosion-resistant metal plate (B) were completely sealed with an epoxy filler to prevent water from entering. For comparison, the claw portions where the nuts were not welded were the cases where a high corrosion resistant metal plate was bonded and fixed with an adhesive filler without providing a bolt fixing structure and where the corrosion resistant metal was not coated.
[0013]
Six months after the construction, changes in the appearance were observed. In the untreated nail portion of the comparative example, rust was generated in a portion where the coating did not reach. In the case where the corrosion-resistant metal is fixed only with the adhesive without using the bolt, the end of the corrosion-resistant metal cover at the fitting portion has a floating. Further, when the corrosion-resistant metal plate (B) was removed by inserting a chisel at the end, it could be easily peeled off. However, no corrosion was observed in the claws under the corrosion-resistant metal coating. In the other examples of the present invention, no lifting occurred, the appearance was extremely good, and at the same time, the bolt could not be peeled off without removing the bolt even if a chisel was inserted into the end. In addition, even when the observation was performed in a state where the highly corrosion-resistant metal plate was removed by removing the bolts, no corrosion was observed including the nut portion, and the state was sound, thus demonstrating the effect of the present invention.
[0014]
【The invention's effect】
According to the present invention, it is possible to manufacture a steel sheet pile revetment having beautiful and long-term durability performance. In addition, since the fitting portion, which has not been coated in the conventional heavy-duty corrosion protection, is excellent in long-term durability, it is possible to reduce the maintenance cost.
[Brief description of the drawings]
FIG. 1 is a cross-sectional example of anticorrosion of a steel sheet pile convex surface before casting according to the present invention.
FIG. 2 shows an example of a corrosion prevention cross-section and a fixing structure of a steel arrow concave surface before casting according to the present invention.
FIG. 3 is a cross-sectional example of a fitting portion of an anticorrosion structure using a highly corrosion-resistant metal plate (B) of the present invention.
FIG. 4 is a cross-sectional example of a fitting portion of an anticorrosion structure using a composite of a highly corrosion-resistant metal plate (B) of the present invention and FRP.
[Explanation of symbols]
1: Steel sheet pile 2: Organic resin anticorrosion layer 3: Organic resin adhesive layer 4: High corrosion resistant metal plate (A)
5: Nut structure 6: Organic resin filler 7: High corrosion resistant metal plate (B)
8: Filling adhesive or rubber seal 9: Bolt 10: Electrical insulation structure 11: FRP
12: Anticorrosion cap
Claims (2)
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JP2003155126A JP2004353405A (en) | 2003-05-30 | 2003-05-30 | Steel sheet pile anti-corrosive structure excellent in long-term durability |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008248578A (en) * | 2007-03-30 | 2008-10-16 | Nippon Steel Corp | Structure of double anticorrosive-coated steel sheet pile superior in joint part anti-corrosiveness and steel sheet pile used for its structure |
JP2014037699A (en) * | 2012-08-14 | 2014-02-27 | Giken Seisakusho Co Ltd | Cut-off structure and cut-off method for sheet pile joint part |
JP2014070271A (en) * | 2012-10-02 | 2014-04-21 | Nakabohtec Corrosion Protecting Co Ltd | Covering corrosion protection method for steel structure, and covering corrosion protection structure |
WO2019224420A1 (en) * | 2018-05-23 | 2019-11-28 | Eco-Explosion Oy | Seal for a retaining wall |
-
2003
- 2003-05-30 JP JP2003155126A patent/JP2004353405A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008248578A (en) * | 2007-03-30 | 2008-10-16 | Nippon Steel Corp | Structure of double anticorrosive-coated steel sheet pile superior in joint part anti-corrosiveness and steel sheet pile used for its structure |
JP2014037699A (en) * | 2012-08-14 | 2014-02-27 | Giken Seisakusho Co Ltd | Cut-off structure and cut-off method for sheet pile joint part |
JP2014070271A (en) * | 2012-10-02 | 2014-04-21 | Nakabohtec Corrosion Protecting Co Ltd | Covering corrosion protection method for steel structure, and covering corrosion protection structure |
WO2019224420A1 (en) * | 2018-05-23 | 2019-11-28 | Eco-Explosion Oy | Seal for a retaining wall |
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