JP2004306005A - Cleaning and drying apparatus - Google Patents

Cleaning and drying apparatus Download PDF

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Publication number
JP2004306005A
JP2004306005A JP2003136583A JP2003136583A JP2004306005A JP 2004306005 A JP2004306005 A JP 2004306005A JP 2003136583 A JP2003136583 A JP 2003136583A JP 2003136583 A JP2003136583 A JP 2003136583A JP 2004306005 A JP2004306005 A JP 2004306005A
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JP
Japan
Prior art keywords
desiccant
drying agent
titanium oxide
cabinet
action
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003136583A
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Japanese (ja)
Inventor
Tadaichi Ushida
唯一 牛田
Takao Yuasa
孝雄 湯浅
Takao Yasuda
孝夫 安田
Takahiro Oshida
隆博 押田
Yoko Fujie
洋子 藤江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Living Co Ltd
Original Assignee
Toyo Living Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Living Co Ltd filed Critical Toyo Living Co Ltd
Priority to JP2003136583A priority Critical patent/JP2004306005A/en
Publication of JP2004306005A publication Critical patent/JP2004306005A/en
Pending legal-status Critical Current

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  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleaning and drying apparatus in which a cleaning and reduction of damp in a sealed cabinet are compatible. <P>SOLUTION: As a normal drying means, a method of dehumidifying wherein a drying agent is contained in a case, by opening a cabinet inward shutter and closing a shutter outside the cabinet, the drying agent sufficiently adsorbs the moisture inside, and thereafter, the opening and closing of the shutters are reversed to heat for reproduction for a certain hour and discharge the adsorbed moisture outside the cabinet is provided. In the apparatus, in order to make the best use of characters of the drying agent and perform the dehumidification action, and the decomposition and removing action of the contaminants due to a titanium oxide photocatalyst at the same time, a light such as an LED is irradiated to the drying agent such as silica gel, with the titanium oxide photocatalyst attached, except the time of heating and reproducing of the drying agent. The apparatus has the action and effects of best of both worlds, that the inside of the sealed cabinet is maintained low in the humidity by using the large surface area of the drying agent with this photocatalyst and the light transmitting action and by circulating the flowing air of the periphery of the drying agent in the cabinet, and the decomposition and the removal of the contaminants are performed. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
近時技術の高度化により光学レンズや半導体ウエハ等においては気体中に含まれる分子レベルのガス状物質の除去が一層重要になってきた。例えばクリーンルーム空気中にウエハを暴露すると数から数十ng/cmの有機性ガスがウエハ表面に付着しこれらは半導体のゲート膜破壊や酸化防止膜耐圧の劣化等生産性の低下をもたらしていた。
本発明はそれらを除湿作用と清浄作用とを同一装置にて対応するものである。
【0002】
【従来の技術】
従来は乾燥装置として密閉キャビネット内を低湿度(例えば3〜10%)に保つ装置として乾燥剤を低時間再生(通常30分)しその後は庫内・庫外のシャッター切り替えにより吸湿作用(通常5〜6時間)を行い、これを繰り返し作用させ庫内湿度を低湿度に保つ装置があった。
【0003】
一方光触媒としては酸化チタンを各種材料に混合し、大陽光または紫外線照射、または・一般光源により、気体(液体)中の不純物質を分解する。
【0004】
即ち、乾燥剤による乾燥機能と酸化チタンによる清浄作用は構成、用途作用の全ての面で異なるものであった。
【0005】
【発明が解決しようとする課題】
前述の如く、従来全く異なる装置であったが、酸化チタン光触媒による汚染物質の分解・除去効果(効力)を上げるためには出来るだけ表面積を大きくする必要があった。一方、乾燥剤としてシリカゲル等は粒状構成において分子レベルの細孔で構成され極めて大きな表面積を有していた。
【0006】
故にこれら相互の粒状を生かすことにより、即ち乾燥剤に酸化チタンを付着させることにより、吸湿作用と空気の清浄作用の両立を兼ね備える画期的作用が達成でき、しかもその効果作用は光学レンズやウエハ−の二つの最大課題である湿度による吸湿と空気中の汚れによる不良原因を同時に除く効果を示し、構成上のメリットと作用効果上のメリットが同時達成できる画期的な装置である。
【0007】
【課題を解決するための手段】
前期の目的と効果を達成するための構成上の特徴は次の通りである。
【0008】
従来、乾燥剤は自動的に加熱再生と吸湿作用を行い、密閉キャビネット内を低湿に保ち、防カビ、防錆等の効果作用を目的としていた。また、酸化チタン光触媒は、タイル・ガラスなど各種構造体及びセラミック等に混合ないし表面コーティングにより、防汚染効果を行ってきた。
【0009】
上記作用効果を1つの要求即ち、乾燥剤に酸化チタンを含浸させることにより、乾燥(=低湿化)作用と防汚染(=クリーン)効果の2つの効果作用を時間差を設けて設置して複合的に達成したものである。
【0010】
【発明の実施の形態】
以下具体的実施例により評価証明する。
この除湿・清浄装置は第1図の正面断面図・第2図の側面断面図で示す如く、密閉キャビネット18に装着し、ケース19内に全ての機構が内包されている。この種、乾燥装置のみは既に実用化されている通り、定時間制御タイマーにより、通常約30分間乾燥剤2,3に熱的に接した加熱体1により、加熱される。この時同時に作用するシャッター制御タイマー17により、上下の各シャッター9,10は排気開孔口7と外気吸入開孔口8が開くように支点15を中心に作動する。ネット状乾燥箱4内の乾燥剤2,3を定時間(30分間)加熱後、制御タイマー17により、通電を停止し上下の各シャッター9,10は記憶合金又は電磁弁16等の駆動源により反転し、庫外側吸排気口7,8を閉じ庫内側開孔口13,14を開く。
これにより、加熱再生、即ち吸着水分排湿後の乾燥剤は吸湿能力により庫内空気を順次低湿化する。乾燥剤下部のファン6により、効果は促進される。
【0011】
即ち、吸湿状態のシャッター開孔状態かつ、乾燥剤吸湿状態になった時乾燥剤吸湿状態になった時、ネット状乾燥箱4下辺に配置したLED照明ランプ5が乾燥剤に照射される。これらは制御タイマー17により行われる。この吸湿及びLED照射時間は約5〜6時間であり、これら乾燥剤加熱再生と吸湿及びLED照明をサイクルとして(通常6時間)として繰り返し行い、低湿作用と汚染物質の分解・除去を行うものである。
【0012】
【発明の効果】
以上で説明したこの発明の効果は次の通りである。
【0013】
(1)低湿作用と汚染物質の分解・除去作用を1つの装置として達成した。
【0014】
(2)従来はそれぞれ基本構造が別個として製作されていたのに対し、低湿と清浄の作用機能は相乗作用として、超精密高度化した光学レンズ、半導体ウエハにとって最高の複合的効果をもたらす。
【0015】
(3)その作用も低湿と清浄を1つの物質として多孔質の乾燥剤(シリカゲル,ゼオライト)によって行うことによりそれぞれの作用効果を損なうことなく、用途的に極めて高い複合的相乗効果をもたらす。
【0016】
(4)この効果は単に光学レンズ・ウエハーに止まらず、防カビ、防汚染の基本環境要素である低湿度と分子レベルのクリーンはそれぞれ単独では達成できない効果を一つの酸化チタン吸着多孔質乾燥剤で達成し得た。
【0017】
具体的応用例としては乾燥食品の単なる低湿保管から、清浄化を加えたことにより衛生的なもので、薬品・バイオ等応用範囲は極めて多岐にわたる。
【0018】
また当然のこととして臭いと清浄では乾燥剤の代わりに活性炭等の多孔質材料によっても達成でき、これら複合作用効果を一つの装置で成し得た効果は極めて応用範囲の広いものである。
【0010】
【図面の簡単な説明】
【図1】本発明の低湿・清浄装置の正面断面図
【図2】本発明の低湿・清浄装置の側面断面図(吸湿時)
【図3】本発明の低湿・清浄装置の側面断面図(加熱再生時)
【符号の説明】
1.乾燥剤加熱源
2.乾燥剤(光触媒シリカゲル)
3.乾燥剤(ゼオライト)
4.ネット状乾燥剤ケース
5.LED照明
6.ファン
7.排湿開孔口
8.外気吸入開孔口
9.上部シャッター
10.下部シャッター
11.庫内
12.庫外
13.排気口
14.庫内空気吸入口
15.シャッター支点
16.シャッター開閉駆動源(ソレノイド)
17.制御タイマー
18.キャビネット
19.装置の外側ケース
[0001]
TECHNICAL FIELD OF THE INVENTION
In recent years, removal of molecular-level gaseous substances contained in gas has become more important in optical lenses, semiconductor wafers, and the like due to advancement of technology. For example, when a wafer is exposed to air in a clean room, organic gas of several to several tens of ng / cm 2 adheres to the wafer surface, and these cause a decrease in productivity such as breakdown of a gate film of a semiconductor and deterioration of breakdown voltage of an antioxidant film. .
In the present invention, the dehumidifying action and the cleaning action are performed by the same device.
[0002]
[Prior art]
Conventionally, a desiccant is regenerated for a short period of time (normally 30 minutes) as a device for keeping the inside of a closed cabinet at a low humidity (for example, 3 to 10%) as a drying device. 66 hours), and there was a device that keeps the inside humidity low by making this work repeatedly.
[0003]
On the other hand, as a photocatalyst, titanium oxide is mixed with various materials, and impurities in a gas (liquid) are decomposed by sunlight or ultraviolet irradiation, or by a general light source.
[0004]
That is, the drying function by the desiccant and the cleaning action by the titanium oxide were different in all aspects of the constitution and the application action.
[0005]
[Problems to be solved by the invention]
As described above, conventionally, the apparatus was completely different, but it was necessary to increase the surface area as much as possible in order to increase the effect of decomposing / removing pollutants (effectiveness) by the titanium oxide photocatalyst. On the other hand, silica gel or the like as a desiccant had a very large surface area composed of pores at a molecular level in a granular structure.
[0006]
Therefore, by making use of the mutual granularity, that is, by attaching titanium oxide to the desiccant, an epoch-making action having both a moisture absorbing action and an air cleaning action can be achieved, and the effect action is achieved by an optical lens or a wafer. This is an epoch-making device that shows the two biggest problems of eliminating moisture absorption due to humidity and the cause of defects due to contamination in the air at the same time, and achieves both structural advantages and operational advantages at the same time.
[0007]
[Means for Solving the Problems]
The structural features to achieve the objectives and effects of the first half are as follows.
[0008]
Conventionally, a desiccant has been intended to automatically perform heating and regeneration and absorb moisture, keep the inside of a closed cabinet at a low humidity, and have effects such as mold prevention and rust prevention. In addition, the titanium oxide photocatalyst has been effective in preventing contamination by mixing or surface coating various structures such as tiles and glass and ceramics.
[0009]
One of the above-mentioned effects is required, namely, by impregnating the drying agent with titanium oxide, the two effects of a drying (= low humidity) effect and an anti-contamination (= clean) effect are installed with a time difference provided to provide a complex effect. Is achieved.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, evaluation and certification will be made by specific examples.
The dehumidifying / cleaning device is mounted on a closed cabinet 18 as shown in a front sectional view of FIG. 1 and a side sectional view of FIG. 2, and all mechanisms are included in a case 19. This type of drying device alone is heated by a constant-time control timer, usually for about 30 minutes, by the heating element 1 which is in thermal contact with the desiccants 2 and 3 as already practically used. At this time, the upper and lower shutters 9 and 10 are operated about the fulcrum 15 so that the exhaust opening 7 and the outside air intake opening 8 are opened by the shutter control timer 17 which operates simultaneously. After heating the desiccants 2 and 3 in the net-shaped drying box 4 for a fixed time (30 minutes), the control timer 17 stops the energization, and the upper and lower shutters 9 and 10 are driven by a memory alloy or a driving source such as a solenoid valve 16. It turns over and closes the outside air intake and exhaust ports 7 and 8 and opens the inside holes 13 and 14 inside the warehouse.
As a result, the desiccant after the heat regeneration, that is, after the adsorbed moisture is dehumidified, sequentially reduces the humidity of the air in the refrigerator due to the moisture absorbing ability. The effect is promoted by the fan 6 below the desiccant.
[0011]
That is, when the shutter is opened in the moisture absorbing state and when the desiccant is absorbed, the LED illumination lamp 5 arranged on the lower side of the net-shaped drying box 4 irradiates the desiccant. These are performed by the control timer 17. The moisture absorption and LED irradiation time are about 5 to 6 hours. These drying agent heating regeneration and moisture absorption and LED illumination are repeated as a cycle (usually 6 hours) to perform a low humidity action and decompose and remove contaminants. is there.
[0012]
【The invention's effect】
The effects of the present invention described above are as follows.
[0013]
(1) The low humidity action and the action of decomposing and removing pollutants are achieved as one device.
[0014]
(2) Conventionally, the basic structures are separately manufactured, but the functions of low humidity and cleanliness are synergistically exerted to provide the best combined effect for an ultra-precise optical lens and a semiconductor wafer.
[0015]
(3) As for the action, by using a porous desiccant (silica gel, zeolite) as low humidity and cleansing as one substance, a very high synergistic effect can be obtained without impairing the respective effects.
[0016]
(4) This effect is not limited to optical lenses and wafers, and low humidity and molecular level cleanliness, which are basic environmental factors for mold and contamination, cannot be achieved by themselves. Could be achieved.
[0017]
Specific examples of applications are from simple low-humidity storage of dried foods to sanitary ones by adding purification, and the application range of medicines and biotechnology is extremely wide.
[0018]
Naturally, odor and cleaning can also be achieved by a porous material such as activated carbon instead of a desiccant, and the effects obtained by combining these effects with a single device are extremely wide.
[0010]
[Brief description of the drawings]
FIG. 1 is a front cross-sectional view of the low-humidity / cleaning device of the present invention. FIG. 2 is a side cross-sectional view of the low-humidity / cleaning device of the present invention (when moisture is absorbed).
FIG. 3 is a side sectional view of the low-humidity / cleaning apparatus of the present invention (at the time of heat regeneration).
[Explanation of symbols]
1. 1. desiccant heating source Desiccant (photocatalytic silica gel)
3. Desiccant (zeolite)
4. 4. Net-like desiccant case LED lighting6. Fan7. 7. Dehumidification opening 8. Open port for outside air intake Upper shutter 10. Lower shutter 11. Inside the refrigerator 12. Outside the warehouse 13. Exhaust port 14. 14. Air intake port inside the refrigerator Shutter fulcrum 16. Shutter open / close drive source (solenoid)
17. Control timer 18. Cabinet 19. Outer case of device

Claims (4)

乾燥剤により密閉庫内を除湿(=低湿)し、当該乾燥剤を一定時間加熱再生と吸・排湿シャッターの切替作用をタイマー等で制御する乾燥手段において、当該乾燥剤の一部又は全てに酸化チタン光触媒を付着させ、加熱再生時は加熱体により吸着した水分の排出作用を行い、吸湿時間帯(非加熱時)にはLED等の光照射により酸化チタン光触媒によるクリーン作用を行う如く、吸湿作用と汚染物質の分解・除去作用を行う乾燥剤で構成したクリーン・ドライ装置The drying means dehumidifies (= low humidity) the inside of the closed chamber with a desiccant and controls the regenerating operation of the desiccant by heating for a certain period of time and the switching operation of the absorption and dehumidification shutters with a timer or the like. The titanium oxide photocatalyst is adhered, and during heating and regeneration, the adsorbed water is discharged by the heating element, and during the period of moisture absorption (when not heated), the titanium oxide photocatalyst is cleaned by irradiation with light from an LED or the like. Clean and dry equipment composed of a desiccant that acts and decomposes and removes pollutants 前記LED等の光源は加熱再生時に熱を受け難い乾燥剤の下方、またはケース機材の反射により温度上昇を受けない位置に配置をしたクリーン・ドライ装置The light source such as the LED is disposed under a desiccant that is hardly subjected to heat at the time of heating / regenerating, or at a position where the temperature does not rise due to reflection of a case device. 前記光照射側は、酸化チタンを付着したシリカゲルなど透光性多孔質吸着剤、非照明側にはゼオライトなど低湿での吸湿効果の高い多孔質吸着剤を配置することにより、汚染物質の分解・除去効果と低湿効果効果を発揮するクリーン・ドライ装置The light irradiation side is provided with a translucent porous adsorbent such as silica gel to which titanium oxide is attached, and the non-illuminated side is provided with a porous adsorbent having a high moisture absorbing effect at low humidity such as zeolite to decompose and decompose pollutants. Clean and dry device that exhibits removal and low humidity effects 前記乾燥手段を用いた乾燥剤の入った箱の外面や除湿ユニットの内面に酸化チタン光触媒を塗布した構造で、光照射により汚染物質を分解・除去を行うクリーン・ドライ装置A clean / dry apparatus that has a structure in which a titanium oxide photocatalyst is applied to the outer surface of a box containing a desiccant or the inner surface of a dehumidifying unit using the drying means, and decomposes and removes contaminants by light irradiation.
JP2003136583A 2003-04-08 2003-04-08 Cleaning and drying apparatus Pending JP2004306005A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008224113A (en) * 2007-03-12 2008-09-25 Tokyo Electric Power Co Inc:The Desiccant air-conditioning system and moisture absorbing/desorbing method
CN107062454A (en) * 2017-04-05 2017-08-18 东华大学 A kind of defogging disappears haze multistage purification tower and its method of work

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008224113A (en) * 2007-03-12 2008-09-25 Tokyo Electric Power Co Inc:The Desiccant air-conditioning system and moisture absorbing/desorbing method
CN107062454A (en) * 2017-04-05 2017-08-18 东华大学 A kind of defogging disappears haze multistage purification tower and its method of work

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