JP2008161619A - Low-humidity purification unit - Google Patents

Low-humidity purification unit Download PDF

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Publication number
JP2008161619A
JP2008161619A JP2006357472A JP2006357472A JP2008161619A JP 2008161619 A JP2008161619 A JP 2008161619A JP 2006357472 A JP2006357472 A JP 2006357472A JP 2006357472 A JP2006357472 A JP 2006357472A JP 2008161619 A JP2008161619 A JP 2008161619A
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air
desiccant
humidity
titanium oxide
low
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JP2006357472A
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Japanese (ja)
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Tadaichi Ushida
唯一 牛田
Takao Yuasa
孝雄 湯浅
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Toyo Living Co Ltd
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Toyo Living Co Ltd
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Priority to JP2006357472A priority Critical patent/JP2008161619A/en
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Drying Of Gases (AREA)
  • Catalysts (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a compact low-humidity purification unit having almost the same structure as a conventional one and highly efficient in achieving low humidity and purity inside the unit. <P>SOLUTION: An air permeable material 10 carrying a titanium oxide that works as photocatalyst is provided in air flow passages in an automatic drier 1 within the unit for regenerating a drying agent 3 stored at part of a sealed cabinet 8. The surface of the air-permeable material 10 is irradiated with light of 250 to 450 nm to keep humidity within the cabinet low and decompose and remove organic substances with approximate 0.1 to 10 μm floating in air. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は低湿作用と清浄作用の相互相乗利用によりその効果を一層と高めた低湿清浄庫に関する。The present invention relates to a low-humidity purifier that further enhances its effect by synergistic use of low-humidity action and cleaning action.

従来庫内を低湿度に保つ方式として、タイマーによる自動制御で乾燥剤の加熱・再生を行い庫内湿度を10%とか30%に保つ方式は公知としてあり、また酸化チタンと紫外線による光触媒作用を行う方式も公知として知られる。Conventionally, as a method of keeping the inside of the cabinet at a low humidity, a method of heating and regenerating the desiccant by automatic control by a timer and keeping the inside humidity at 10% or 30% is known, and photocatalytic action by titanium oxide and ultraviolet rays is known. The method of performing is also known.

ただそれらを合体した相乗効果を利用して、本発明は低湿と清浄を最も効率の良い方式でかつ、従来方式とほぼ同じ構造体をユニット内に組込むコンパクト設計により、高機能機種としては実用的かつ進歩的なものである。However, utilizing the synergistic effect of combining them, the present invention is the most efficient method for low humidity and cleanliness, and is practical as a high-functional model due to the compact design that incorporates almost the same structure as the conventional method in the unit. And progressive.

本発明は従来の除湿機能をする装置(以下除湿ユニットと称する)内の水蒸気分圧の差に起因する空気層の変化に着目して、この空気分圧の差を利用して有機不純物を吸引・分解・除去することにより、除湿ユニットの外形寸法・形状変化なしで小型低湿作用と清浄作用を両立したものである。The present invention focuses on the change in the air layer caused by the difference in water vapor partial pressure in a conventional device that performs a dehumidifying function (hereinafter referred to as a dehumidifying unit), and sucks organic impurities using the difference in air partial pressure.・ By disassembling / removing, the small dehumidifying action and cleaning action are compatible without changing the external dimensions and shape of the dehumidifying unit.

上述の課題を解決するための方法として、光触媒には、酸化チタンとアパタイトの混合、ナノ単位の微細化等公知の技術を活用するとともに低湿作用のもつ空気内の水蒸気分圧の差は乾燥剤のもつ吸湿作用により誘起されるので、その圧力差に着目して、空気流の移動により生じた変化、即ち水蒸気分圧差の流れを最大活用する除湿ユニット内に酸化チタンを主体する有機不純物の分解・除去作用を行う光触媒機能を配置したことが本発明の大きな特徴である。
水蒸気分圧の差とは一例を説明すれば、庫内温度24℃、湿度60%において水蒸気分圧は空気線図より明らかに13.4mmHgである。これに対し温度は同じく24℃において乾燥剤表面の水蒸気分圧は湿度0.5%の場合(実際は更に低い)で0.5mmHgであり、その差は12.9mmHgになる。この圧力差により水蒸気を含む空気層はゆるやかな移動を生じる。この空気層の流れを利用するのが本発明の特徴である。
As a method for solving the above-mentioned problems, the photocatalyst utilizes a known technique such as mixing of titanium oxide and apatite, miniaturization of nano units, and the difference in the water vapor partial pressure in the air having a low humidity action is a desiccant. Because it is induced by the moisture-absorbing action of water, paying attention to the pressure difference, the change caused by the movement of air flow, that is, the decomposition of organic impurities mainly composed of titanium oxide in the dehumidification unit that makes the best use of the flow of water vapor partial pressure difference -It is a great feature of the present invention that a photocatalytic function for performing a removing action is arranged.
To explain an example of the difference in water vapor partial pressure, the water vapor partial pressure is apparently 13.4 mmHg from the air diagram at an internal temperature of 24 ° C. and a humidity of 60%. On the other hand, at a temperature of 24 ° C., the water vapor partial pressure on the surface of the desiccant is 0.5 mmHg when the humidity is 0.5% (actually lower), and the difference is 12.9 mmHg. This pressure difference causes the air layer containing water vapor to move slowly. It is a feature of the present invention that this air layer flow is utilized.

即ち、本発明によれば庫内の空気中の水蒸気圧の差によって生じる空気中に酸化チタンベースの光触媒作用を導入するべく、各種酸化チタン担持の方法かつ空気流を阻害しない配置によって、低湿作用と清浄作用が相乗効果を促進させて、庫内の低湿・清浄の目的を達成したものである。That is, according to the present invention, a low-humidity action is achieved by various titanium oxide-supporting methods and arrangements that do not inhibit the air flow in order to introduce a titanium oxide-based photocatalytic action into the air generated by the difference in water vapor pressure in the air in the warehouse. The purifying action promotes a synergistic effect and achieves the purpose of low humidity and cleaning in the cabinet.

それによる効果として、民生用としてはカメラ・レンズのカビ防止が従来庫内湿度の低湿化(約30〜40%)で行われたが、光触媒作用効果により空気中に含まれている微細有機物(0.1〜数μm)を分解・除去する作用により、近時発達したデジタル1眼レフカメラのレンズと共に撮像素子(CCD)の不純物の付着防止及び除去に効果的である。不純物質に対しては各カメラメーカーも対策として超音波振動等の特殊装置を必要とし、コスト面で不合理であった。これらを本発明低湿清浄庫によって問題である不純物のクリーン化に成功した。As a result of this, for consumer use, camera / lens prevention was done by reducing the humidity in the cabinet (about 30-40%), but fine organic substances contained in the air due to the photocatalytic effect ( 0.1 to several μm) is effective in preventing and removing impurities on the image pickup device (CCD) together with a recently developed digital single lens reflex camera lens. Each camera manufacturer required special equipment such as ultrasonic vibration as a countermeasure against the impurity, which was unreasonable in terms of cost. These were successfully cleaned of impurities, which is a problem, by the low-humidity clean box of the present invention.

また産業用分野においては、上記CCDの製造工程中の保管、またはカメラメーカー工程中の保管に必須なものである。In the industrial field, it is essential for storage during the manufacturing process of the CCD or during the camera manufacturer process.

更に半導体工程、ウェハーの収納、またその搬送中にもクリーンルーム内においても、多数浮遊している有機不純物の除去対策として極めて有効である。Furthermore, it is extremely effective as a countermeasure for removing a large number of floating organic impurities in both a semiconductor process, wafer storage, and transfer and in a clean room.

以下本発明の要旨を実施形式図面により具体的に説明する。The gist of the present invention will be specifically described below with reference to the drawings of the embodiment.

図1の本発明の側断図で示す如く、本装置ユニット1は密閉式扉付キャビネット8の背面側9に通常設けられる。ユニット1には、基本構成に除湿機能をもつため上部に排気口4′に設け、下部に吸気口7′を設けてある。その内部はほぼ中間にゼオラム・シリカゲル等で代表される吸湿剤3が設けられており、この吸湿剤は周囲を通気性ある小穴開孔容器2またはネット状容器で構成されている。これらはタイマー等(図省略)の制御によって、一定時間ごとに再成され排出水分は上4′吸気は下7′のシャッターより、吸排出され乾燥剤再成後は、バネ5により復元される。As shown in the side sectional view of the present invention in FIG. 1, the apparatus unit 1 is usually provided on the back side 9 of the cabinet 8 with a hermetic door. Since the unit 1 has a dehumidifying function, the unit 1 is provided with an exhaust port 4 'in the upper part and an intake port 7' in the lower part. The inside of the interior is provided with a hygroscopic agent 3 typified by zeolum silica gel or the like in the middle, and this hygroscopic agent is constituted by a small hole-opening container 2 or a net-like container which is air permeable. These are regenerated at regular intervals under the control of a timer or the like (not shown), and the discharged water is sucked and discharged from the upper 4 'intake by the lower 7' shutter, and is restored by the spring 5 after regenerating the desiccant. .

一方上記シャッター4′、7′の閉じたときは、庫内側シャッター4.7が連動して開かれ、庫内空気の吸湿作用が行われる(約6時間)この時、活性化された乾燥剤3は吸湿作用を行い、庫内空気取り入れ口シャッター7から、水蒸気分圧の差により庫内空気が吸引され、乾燥剤3を経て、即ち脱湿作用を経て、水蒸気分圧差によって上方シャッターから庫内に流入する、これを6時間にわたり、連続して行われる。On the other hand, when the shutters 4 'and 7' are closed, the inner shutter 4.7 is opened in conjunction with the moisture absorption of the internal air (about 6 hours). At this time, the activated desiccant is activated. 3 absorbs moisture from the interior air intake shutter 7 due to the difference in water vapor partial pressure, passes through the desiccant 3, that is, undergoes dehumidification, and stores from the upper shutter due to the water vapor partial pressure difference. This is done continuously for 6 hours.

この空気の流れの過程を図1の空気回路に酸化チタン担持のスクリーンを設ける、これにLED11の小型照明により酸化チタン表面層に対応して、250〜350nm波長の光、または可視光対応の400〜450nm波長の光を照射して、光触媒作用を行うものである。This air flow process is provided with a titanium oxide-supported screen in the air circuit of FIG. 1, and a light having a wavelength of 250 to 350 nm, or 400 corresponding to visible light, corresponding to the titanium oxide surface layer by small illumination of the LED 11. Irradiates light with a wavelength of ˜450 nm to perform photocatalysis.

図1.本発明ユニットの構成を示す側断面図の各部品 1.本発明除湿・清浄ユニット 2.乾燥剤収納容器(透湿穴形式) 3.乾燥剤 4.上部庫内空気排出側シャッター 4′上部庫外空気排出側シャッター 5.引張りバネ 6.上部シャッター開閉支点 7.下部庫内空気吸入側シャッター 7′下部庫外空気吸入側シャッター 8.密封キャビネット 9.同上背面 10.酸化チタン坦持通気性スクリーン 11.LED照明ランプ 12.下部シャッター開閉支点 13.本製造内側に酸化チタン層を配設FIG. Each part of the side sectional view showing the configuration of the unit of the present invention. 1. Dehumidification / cleaning unit of the present invention 2. Desiccant storage container (breathable hole format) Desiccant 4. 4. Upper internal air discharge side shutter 4 'Upper external air discharge side shutter 5. Tension spring 6. Upper shutter opening / closing fulcrum Lower air intake side shutter 7 'Lower external air intake side shutter 8' Sealed cabinet 9. Same as above 10. 10. Titanium oxide-carrying breathable screen LED lighting lamp 12. Lower shutter opening / closing fulcrum 13. Titanium oxide layer is placed inside the production 図2.キャビネットに本発明ユニット装着の側断面図 14.キャビネット密閉用扉 15.キャビネット庫内棚 16.キャビネット下部棚FIG. Side sectional view of mounting the unit of the present invention on a cabinet 14. Cabinet sealing door 15. Cabinet cabinet shelf 16. Cabinet lower shelf

Claims (2)

ゼオラムで代表される低湿時吸着能力の大きい乾燥剤の水蒸気分圧の差を利用し、乾燥剤と庫内流動空気相間に光触媒作用を行う、酸化チタン主体の触媒を乾燥剤容器表面、気相中間、上記を構成する製造の内層面にわたり光触媒酸化チタン層を設け、同時にLED、水銀灯の如き250nm〜450nmの波長をもつ光線を各酸化チタン層に照射する構成によるクリーン構造。Utilizing the difference in water vapor partial pressure of a desiccant with a large adsorption capacity at low humidity, such as Zeolum, a titanium oxide-based catalyst that performs photocatalysis between the desiccant and the flowing air phase in the cabinet is used as the surface of the desiccant container. A clean structure having a structure in which a photocatalytic titanium oxide layer is provided on the inner layer surface of the production that constitutes the above, and at the same time, each titanium oxide layer is irradiated with light having a wavelength of 250 nm to 450 nm, such as LED and mercury lamp. 上記において、光触媒作用を効果的にするため、乾燥剤により、誘起される水蒸気分圧による空気移動の最も良い位置として、本ユニット装置内の庫内空気の吸入口と排気口との中間に酸化チタンによる触媒を配置し、それに前記光を照射する装置。In the above, in order to make the photocatalytic effect effective, the best position for air movement by the water vapor partial pressure induced by the desiccant is oxidized in the middle of the air inlet and outlet in the unit device. An apparatus in which a catalyst made of titanium is arranged and irradiated with the light.
JP2006357472A 2006-12-26 2006-12-26 Low-humidity purification unit Pending JP2008161619A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018105609A (en) * 2016-12-28 2018-07-05 東洋リビング株式会社 Storage
CN112717666A (en) * 2020-12-09 2021-04-30 南京大学 Granular quicklime fixed bed dehydration and deodorization system and operation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018105609A (en) * 2016-12-28 2018-07-05 東洋リビング株式会社 Storage
CN112717666A (en) * 2020-12-09 2021-04-30 南京大学 Granular quicklime fixed bed dehydration and deodorization system and operation method thereof

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