JP2008161619A - Low-humidity purification unit - Google Patents
Low-humidity purification unit Download PDFInfo
- Publication number
- JP2008161619A JP2008161619A JP2006357472A JP2006357472A JP2008161619A JP 2008161619 A JP2008161619 A JP 2008161619A JP 2006357472 A JP2006357472 A JP 2006357472A JP 2006357472 A JP2006357472 A JP 2006357472A JP 2008161619 A JP2008161619 A JP 2008161619A
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- Prior art keywords
- air
- desiccant
- humidity
- titanium oxide
- low
- Prior art date
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- Pending
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- 238000000746 purification Methods 0.000 title abstract 2
- 239000002274 desiccant Substances 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 230000001699 photocatalysis Effects 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 238000007146 photocatalysis Methods 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 abstract description 3
- 239000011941 photocatalyst Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 description 10
- 239000012535 impurity Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000007791 dehumidification Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000003230 hygroscopic agent Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
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- Ventilation (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Drying Of Gases (AREA)
- Catalysts (AREA)
Abstract
Description
本発明は低湿作用と清浄作用の相互相乗利用によりその効果を一層と高めた低湿清浄庫に関する。The present invention relates to a low-humidity purifier that further enhances its effect by synergistic use of low-humidity action and cleaning action.
従来庫内を低湿度に保つ方式として、タイマーによる自動制御で乾燥剤の加熱・再生を行い庫内湿度を10%とか30%に保つ方式は公知としてあり、また酸化チタンと紫外線による光触媒作用を行う方式も公知として知られる。Conventionally, as a method of keeping the inside of the cabinet at a low humidity, a method of heating and regenerating the desiccant by automatic control by a timer and keeping the inside humidity at 10% or 30% is known, and photocatalytic action by titanium oxide and ultraviolet rays is known. The method of performing is also known.
ただそれらを合体した相乗効果を利用して、本発明は低湿と清浄を最も効率の良い方式でかつ、従来方式とほぼ同じ構造体をユニット内に組込むコンパクト設計により、高機能機種としては実用的かつ進歩的なものである。However, utilizing the synergistic effect of combining them, the present invention is the most efficient method for low humidity and cleanliness, and is practical as a high-functional model due to the compact design that incorporates almost the same structure as the conventional method in the unit. And progressive.
本発明は従来の除湿機能をする装置(以下除湿ユニットと称する)内の水蒸気分圧の差に起因する空気層の変化に着目して、この空気分圧の差を利用して有機不純物を吸引・分解・除去することにより、除湿ユニットの外形寸法・形状変化なしで小型低湿作用と清浄作用を両立したものである。The present invention focuses on the change in the air layer caused by the difference in water vapor partial pressure in a conventional device that performs a dehumidifying function (hereinafter referred to as a dehumidifying unit), and sucks organic impurities using the difference in air partial pressure.・ By disassembling / removing, the small dehumidifying action and cleaning action are compatible without changing the external dimensions and shape of the dehumidifying unit.
上述の課題を解決するための方法として、光触媒には、酸化チタンとアパタイトの混合、ナノ単位の微細化等公知の技術を活用するとともに低湿作用のもつ空気内の水蒸気分圧の差は乾燥剤のもつ吸湿作用により誘起されるので、その圧力差に着目して、空気流の移動により生じた変化、即ち水蒸気分圧差の流れを最大活用する除湿ユニット内に酸化チタンを主体する有機不純物の分解・除去作用を行う光触媒機能を配置したことが本発明の大きな特徴である。
水蒸気分圧の差とは一例を説明すれば、庫内温度24℃、湿度60%において水蒸気分圧は空気線図より明らかに13.4mmHgである。これに対し温度は同じく24℃において乾燥剤表面の水蒸気分圧は湿度0.5%の場合(実際は更に低い)で0.5mmHgであり、その差は12.9mmHgになる。この圧力差により水蒸気を含む空気層はゆるやかな移動を生じる。この空気層の流れを利用するのが本発明の特徴である。As a method for solving the above-mentioned problems, the photocatalyst utilizes a known technique such as mixing of titanium oxide and apatite, miniaturization of nano units, and the difference in the water vapor partial pressure in the air having a low humidity action is a desiccant. Because it is induced by the moisture-absorbing action of water, paying attention to the pressure difference, the change caused by the movement of air flow, that is, the decomposition of organic impurities mainly composed of titanium oxide in the dehumidification unit that makes the best use of the flow of water vapor partial pressure difference -It is a great feature of the present invention that a photocatalytic function for performing a removing action is arranged.
To explain an example of the difference in water vapor partial pressure, the water vapor partial pressure is apparently 13.4 mmHg from the air diagram at an internal temperature of 24 ° C. and a humidity of 60%. On the other hand, at a temperature of 24 ° C., the water vapor partial pressure on the surface of the desiccant is 0.5 mmHg when the humidity is 0.5% (actually lower), and the difference is 12.9 mmHg. This pressure difference causes the air layer containing water vapor to move slowly. It is a feature of the present invention that this air layer flow is utilized.
即ち、本発明によれば庫内の空気中の水蒸気圧の差によって生じる空気中に酸化チタンベースの光触媒作用を導入するべく、各種酸化チタン担持の方法かつ空気流を阻害しない配置によって、低湿作用と清浄作用が相乗効果を促進させて、庫内の低湿・清浄の目的を達成したものである。That is, according to the present invention, a low-humidity action is achieved by various titanium oxide-supporting methods and arrangements that do not inhibit the air flow in order to introduce a titanium oxide-based photocatalytic action into the air generated by the difference in water vapor pressure in the air in the warehouse. The purifying action promotes a synergistic effect and achieves the purpose of low humidity and cleaning in the cabinet.
それによる効果として、民生用としてはカメラ・レンズのカビ防止が従来庫内湿度の低湿化(約30〜40%)で行われたが、光触媒作用効果により空気中に含まれている微細有機物(0.1〜数μm)を分解・除去する作用により、近時発達したデジタル1眼レフカメラのレンズと共に撮像素子(CCD)の不純物の付着防止及び除去に効果的である。不純物質に対しては各カメラメーカーも対策として超音波振動等の特殊装置を必要とし、コスト面で不合理であった。これらを本発明低湿清浄庫によって問題である不純物のクリーン化に成功した。As a result of this, for consumer use, camera / lens prevention was done by reducing the humidity in the cabinet (about 30-40%), but fine organic substances contained in the air due to the photocatalytic effect ( 0.1 to several μm) is effective in preventing and removing impurities on the image pickup device (CCD) together with a recently developed digital single lens reflex camera lens. Each camera manufacturer required special equipment such as ultrasonic vibration as a countermeasure against the impurity, which was unreasonable in terms of cost. These were successfully cleaned of impurities, which is a problem, by the low-humidity clean box of the present invention.
また産業用分野においては、上記CCDの製造工程中の保管、またはカメラメーカー工程中の保管に必須なものである。In the industrial field, it is essential for storage during the manufacturing process of the CCD or during the camera manufacturer process.
更に半導体工程、ウェハーの収納、またその搬送中にもクリーンルーム内においても、多数浮遊している有機不純物の除去対策として極めて有効である。Furthermore, it is extremely effective as a countermeasure for removing a large number of floating organic impurities in both a semiconductor process, wafer storage, and transfer and in a clean room.
以下本発明の要旨を実施形式図面により具体的に説明する。The gist of the present invention will be specifically described below with reference to the drawings of the embodiment.
図1の本発明の側断図で示す如く、本装置ユニット1は密閉式扉付キャビネット8の背面側9に通常設けられる。ユニット1には、基本構成に除湿機能をもつため上部に排気口4′に設け、下部に吸気口7′を設けてある。その内部はほぼ中間にゼオラム・シリカゲル等で代表される吸湿剤3が設けられており、この吸湿剤は周囲を通気性ある小穴開孔容器2またはネット状容器で構成されている。これらはタイマー等(図省略)の制御によって、一定時間ごとに再成され排出水分は上4′吸気は下7′のシャッターより、吸排出され乾燥剤再成後は、バネ5により復元される。As shown in the side sectional view of the present invention in FIG. 1, the
一方上記シャッター4′、7′の閉じたときは、庫内側シャッター4.7が連動して開かれ、庫内空気の吸湿作用が行われる(約6時間)この時、活性化された乾燥剤3は吸湿作用を行い、庫内空気取り入れ口シャッター7から、水蒸気分圧の差により庫内空気が吸引され、乾燥剤3を経て、即ち脱湿作用を経て、水蒸気分圧差によって上方シャッターから庫内に流入する、これを6時間にわたり、連続して行われる。On the other hand, when the shutters 4 'and 7' are closed, the inner shutter 4.7 is opened in conjunction with the moisture absorption of the internal air (about 6 hours). At this time, the activated desiccant is activated. 3 absorbs moisture from the interior
この空気の流れの過程を図1の空気回路に酸化チタン担持のスクリーンを設ける、これにLED11の小型照明により酸化チタン表面層に対応して、250〜350nm波長の光、または可視光対応の400〜450nm波長の光を照射して、光触媒作用を行うものである。This air flow process is provided with a titanium oxide-supported screen in the air circuit of FIG. 1, and a light having a wavelength of 250 to 350 nm, or 400 corresponding to visible light, corresponding to the titanium oxide surface layer by small illumination of the LED 11. Irradiates light with a wavelength of ˜450 nm to perform photocatalysis.
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JP2006357472A JP2008161619A (en) | 2006-12-26 | 2006-12-26 | Low-humidity purification unit |
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JP2006357472A JP2008161619A (en) | 2006-12-26 | 2006-12-26 | Low-humidity purification unit |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018105609A (en) * | 2016-12-28 | 2018-07-05 | 東洋リビング株式会社 | Storage |
CN112717666A (en) * | 2020-12-09 | 2021-04-30 | 南京大学 | Granular quicklime fixed bed dehydration and deodorization system and operation method thereof |
-
2006
- 2006-12-26 JP JP2006357472A patent/JP2008161619A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018105609A (en) * | 2016-12-28 | 2018-07-05 | 東洋リビング株式会社 | Storage |
CN112717666A (en) * | 2020-12-09 | 2021-04-30 | 南京大学 | Granular quicklime fixed bed dehydration and deodorization system and operation method thereof |
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