JP2004216303A - Method and apparatus for making effective use of slag - Google Patents

Method and apparatus for making effective use of slag Download PDF

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Publication number
JP2004216303A
JP2004216303A JP2003007898A JP2003007898A JP2004216303A JP 2004216303 A JP2004216303 A JP 2004216303A JP 2003007898 A JP2003007898 A JP 2003007898A JP 2003007898 A JP2003007898 A JP 2003007898A JP 2004216303 A JP2004216303 A JP 2004216303A
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Japan
Prior art keywords
slag
fine
melting furnace
exhaust gas
incinerator
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JP2003007898A
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JP4307087B2 (en
Inventor
Ryoji Samejima
良二 鮫島
Masaaki Kurata
昌明 倉田
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Takuma Co Ltd
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Takuma Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method and an apparatus for making effective use of slag, each of which is applied to wastes disposal equipment for disposing wastes into molten slag like an ash melting furnace or a gasifying/melting furnace placed side by side with a waste incinerator for burning wastes such as general waste and industrial waste and in which fine-grained slag can be also used effectively. <P>SOLUTION: This apparatus for making effective use of slag is provided with a crusher 12 for crushing the molten slag C, a sieving machine 13 for sorting the slag crushed by the crusher 12, and a pneumatic conveying means 14 for blowing the fine-grained slag D pneumatically to inlets of bag filters 4, 10 being exhaust gas treatment facilities of the incinerator 2 and the melting furnace 6 so that the fine-grained slag D obtained by crushing the slag C is used in the bag filters 4, 10 as a reaction assistant B. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、例えば一般廃棄物や産業廃棄物等のごみを焼却するごみ焼却炉に灰溶融炉が併設されたものやガス化溶融炉の様にごみを処理して溶融スラグにするごみ処理設備に適用されるスラグの有効利用方法及びその装置の改良に関する。
【0002】
【従来の技術】
一般に、ごみを処理して溶融スラグにするごみ処理設備としては、ごみ焼却炉に灰溶融炉を併設したものやガス化溶融炉があり、とりわけ、ごみ焼却炉に灰溶融炉を併設したものとしては、例えば図3に示すものが知られている(特許文献1乃至7参照)。
【0003】
当該ごみ処理設備50は、ごみを焼却する焼却炉51と、これから排出される排ガスの熱を回収する廃熱ボイラ52と、これからの排ガス中に含まれている飛灰を捕集するバグフィルタ53と、これからの排ガスを誘引する誘引通風機54と、これからの排ガスを大気に放出する煙突55と、焼却炉51からの焼却灰とバクフィルタ53からの飛灰とを溶融する溶融炉56と、これからの排ガスを燃焼させる燃焼室57と、これからの排ガスを減温する減温塔58と、これからの排ガス中に含まれている溶融飛灰を捕集するバグフィルタ59と、これからの排ガスを誘引して煙突55から排出させる誘引通風機60とを備えている。
バグフィルタ53,59は、焼却炉51及び溶融炉56の乾式の排ガス処理設備を為し、その入口側には、消石灰等のアルカリ剤(中和剤)Aと反応助剤Bとが一緒に供給される。アルカリ剤Aは、バグフィルタ53,59への排ガスを中和する為に投入される。反応助剤Bは、バグフィルタ53,59のフィルタ上での圧力損失の上昇を抑制すると共に、酸性ガスの除去効率を高める為に投入される。
【0004】
而して、ごみ処理設備50は、溶融炉56からの溶融スラグCを破砕する破砕機61と、これからのスラグを細粒スラグDとそれ以外の粗粒スラグEに分別する篩い機62とを備えている。篩い機62は、篩い目が0.075mmにされている。
篩い機62で分別された篩い目より大きい篩い上の粗粒スラグEは、道路の路盤材等に有効利用されると共に、篩い目より小さい篩い下の細粒スラグDは、埋立処分される。
【0005】
【特許文献1】
特開昭56−115401号公報
【特許文献2】
特開平7−204604号公報
【特許文献3】
特許第3146919号公報
【特許文献4】
特開平10−77602号公報
【特許文献5】
特開平10−227431号公報
【特許文献6】
特開2000−205536号公報
【特許文献7】
特開2001−276774号公報
【0006】
【発明が解決しようとする課題】
要するに、溶融炉から発生する溶融スラグは、道路の路盤材等に有効利用する為に破砕機で破砕されるが、その際に発生する細粒スラグは、飛散する恐れがあったので、除去されて居り、利用する用途がなかった。
【0007】
本発明は、叙上の問題点に鑑み、これを解消する為に創案されたもので、その課題とする処は、細粒スラグの利用用途を解決する様にしたスラグの有効利用方法及びその装置を提供するにある。
【0008】
【課題を解決するための手段】
本発明のスラグの有効利用方法は、基本的には、溶融スラグを破砕した後にできる細粒スラグをごみ焼却炉及び溶融炉の排ガス処理設備であるバクフィルタで反応助剤として使用する様にした事に特徴が存する。
【0009】
本発明のスラグの有効利用装置は、溶融スラグを破砕する破砕機と、これからのスラグを分別する篩い機と、これからの細粒スラグをごみ焼却炉及び溶融炉の排ガス処理設備であるバクフィルタの入口側に吹き込む空気輸送手段とを備えている事に特徴が存する。
【0010】
溶融炉からの溶融スラグは、破砕機に依り破砕された後、篩い機に依り細粒スラグと粗粒スラグに分別される。粗粒スラグは、従来と同様に道路の路盤材等に有効利用される。細粒スラグは、空気輸送手段に依り焼却炉及び溶融炉の排ガス処理設備であるバクフィルタの入口側に反応助剤としてアルカリ剤と一緒に吹き込まれる。従って、従来では埋立処分していた細粒スラグを反応助剤として有効利用する事ができる。その結果、反応助剤のコストの低減を図る事ができる。
【0011】
細粒スラグを更に粉砕するのが好ましい。この様にすれば、バグフィルタの濾布上の払い落とし性及びアルカリ剤の反応性の向上を図る事ができる。
【0012】
【発明の実施の形態】
以下、本発明の実施の形態を、図面に基づいて説明する。
図1は、本発明の第一例に係るスラグの有効利用方法を採用するに好適なごみ処理設備を示す概要図である。
【0013】
ごみ処理設備1は、ごみを焼却する焼却炉2と、これから排出される排ガスの熱を回収する廃熱ボイラ3と、これからの排ガス中に含まれている飛灰を捕集するバグフィルタ4と、これからの排ガスを誘引する誘引通風機5と、これからの排ガスを大気に放出する煙突6と、焼却炉2からの焼却灰とバクフィルタ4からの飛灰とを溶融する溶融炉7と、これからの排ガスを燃焼させる燃焼室8と、これからの排ガスを減温する減温塔9と、これからの排ガス中に含まれている溶融飛灰を捕集するバグフィルタ10と、これからの排ガスを誘引して煙突6から排出させる誘引通風機11とを備えている。
【0014】
而して、ごみ処理設備1は、溶融炉7からの溶融スラグCを破砕する破砕機12と、これからのスラグを細粒スラグDとそれ以外の粗粒スラグEに分別する篩い機13と、これからの細粒スラグDを焼却炉2及び溶融炉7の乾式の排ガス処理設備であるバクフィルタ4,10の各入口側にアルカリ剤Aと一緒に吹き込む空気輸送手段14とを備え、これらに依り所謂スラグの有効利用装置を為している。
【0015】
篩い機13は、篩い目が0.075mmの篩いが用いられて居り、篩い下にはこれより小さい細粒スラグDが、篩い上にはこれより大きな粗粒スラグEが分別される様になっている。
【0016】
空気輸送手段14は、図略しているが、篩い機13からの細粒スラグDを貯留するサイロと、ここに貯溜された細粒スラグDを定量つづ送出する定量供給機と、これからの細粒スラグDを焼却炉2及び溶融炉7のバグフィルタ4,10の入口側(入口ダクト)に導くダクトと、これを通じて細粒スラグDをバグフィルタ4,10の入口側へ空気輸送して吹き込むブロワ等を備えている。
【0017】
次に、この様な構成に基づいてその作用を述解する。
ごみは、焼却炉2に投入されて焼却される。焼却炉2からの排ガスは、廃熱ボイラ3に依り熱回収された後に、この中に含まれている飛灰(塵埃や固形化合物や重金属類)がバグフィルタ4に依り捕集される。バグフィルタ4からの排ガスは、誘引通風機5に依り誘引されて煙突6から大気に放出される。
焼却炉2から排出された焼却灰とバクフィルタ4からの飛灰は、溶融炉7に送られてここで溶融される。溶融炉7からの排ガスは、燃焼室8に依り燃焼されて減温塔9に依り減温され、この中に含まれている溶融飛灰がバグフィルタ10により捕集される。バグフィルタ10からの排ガスは、誘引通風機11に依り誘引されて煙突6から大気に排出される。
【0018】
溶融炉7から排出された溶融スラグCは、破砕機12に依り破砕された後、篩い機13に依り篩い上の細粒スラグDと篩い下の粗粒スラグEに分別される。粗粒スラグEは、従来と同様に道路の路盤材等に有効利用される。細粒スラグDは、空気輸送手段14に依り焼却炉2及び溶融炉7の排ガス処理設備であるバクフィルタ4,10の入口側に反応助剤Bとしてアルカリ剤Aと一緒に吹き込まれる。
【0019】
ところで、消石灰等のアルカリ剤Aを乾式の排ガス処理設備に使用する際には、フィルタ上での圧力損失の上昇を抑制すると共に、酸性ガスの除去効率を高める為に、反応助剤Bを使用する事が多い。
反応助剤Bとしては、ケイ素(Si)、アルミニウム(Al)が主成分のものが使用される。これに対して、溶融スラグCを破砕して篩い分けした細粒スラグDは、主成分がケイ素(Si)、アルミニウム(Al)、カルシウム(Ca)であり、ガラス状であるので、反応性や吸湿性がない等、通常用いられている反応助剤と物理的な諸性状が似ている為に利用が可能である。
従って、従来では埋立処分していた細粒スラグDを反応助剤Bとして有効利用する事ができる。その結果、反応助剤のコストの低減を図る事ができる。
【0020】
次に、本発明の第二例を、図2に基づいて説明する。
図2は、本発明の第二例に係るスラグの有効利用方法を採用するに好適なごみ処理設備を示す概要図である。
【0021】
第二例は、篩い機13と空気輸送手段14との間に細粒スラグDを更に細かく粉砕する粉砕機15を設けた点、が第一例と異なり、その他は、第一例と同様である。
粉砕機15は、篩い機13からの細粒スラグDを平均20〜30μm程度に粉砕するものにしてある。
この様なものは、細粒スラグDが更に細かくなっているので、バグフィルタ4,10の濾布上の払い落とし性及びアルカリ剤Aの反応性の向上を図る事ができる。
【0022】
尚、篩い機13は、先の例では、篩い目が0.075mmであったが、これに限らず、例えばこれ以外の大きさでも良い。
空気輸送手段14は、先の例では、サイロと定量供給機とダクトとブロワ等を備えたものであったが、これに限らず、例えば他の構造のものでも良い。
【0023】
【発明の効果】
以上、既述した如く、本発明に依れば、次の様な優れた効果を奏する事ができる。
(1) 溶融スラグを破砕した後にできる細粒スラグを焼却炉及び溶融炉の排ガス処理設備であるバクフィルタで反応助剤として使用する様にしたので、細粒スラグの有効利用が可能になる。
(2) 細粒スラグを反応助剤として使用する様にしたので、反応助剤のコストの低減を図る事ができる。
【図面の簡単な説明】
【図1】本発明の第一例に係るスラグの有効利用方法を採用するに好適なごみ処理設備を示す概要図。
【図2】本発明の第二例に係るスラグの有効利用方法を採用するに好適なごみ処理設備を示す概要図。
【図3】従来のごみ処理設備を示す概要図。
【符号の説明】
1,50…ごみ処理設備、2,51…焼却炉、3,52…廃熱ボイラ、4,10,53,59…バグフィルタ、5,11,54,60…誘引通風機、6,55…煙突、7,56…溶融炉、8,57…燃焼室、9,58…減温塔、12,61…破砕機、13,62…篩い機、14…空気輸送手段、15…粉砕機、A…アルカリ剤、B…反応助剤、C…溶融スラグ、D…細粒スラグ、E…粗粒スラグ。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention provides, for example, a refuse incinerator for incinerating refuse such as general waste or industrial waste, which is provided with an ash melting furnace, or a refuse treatment facility for processing refuse like a gasification melting furnace to form slag. The present invention relates to a method of effectively using slag applied to a device and an improvement of the device.
[0002]
[Prior art]
In general, there are refuse treatment facilities that combine ash with a refuse incinerator and gasification and melting furnaces. For example, those shown in FIG. 3 are known (see Patent Documents 1 to 7).
[0003]
The refuse treatment equipment 50 includes an incinerator 51 for incinerating refuse, a waste heat boiler 52 for recovering heat of exhaust gas discharged from the incinerator 51, and a bag filter 53 for collecting fly ash contained in the exhaust gas from now on. And an induction ventilator 54 for inducing future exhaust gas, a chimney 55 for discharging future exhaust gas to the atmosphere, a melting furnace 56 for melting incineration ash from the incinerator 51 and fly ash from the back filter 53, A combustion chamber 57 for burning the future exhaust gas, a cooling tower 58 for reducing the temperature of the future exhaust gas, a bag filter 59 for collecting molten fly ash contained in the future exhaust gas, and an exhaust gas for the future. And an induction ventilator 60 for discharging from the chimney 55.
The bag filters 53 and 59 serve as dry exhaust gas treatment equipment for the incinerator 51 and the melting furnace 56. At the inlet side, an alkali agent (neutralizing agent) A such as slaked lime and a reaction assistant B are put together. Supplied. The alkaline agent A is supplied to neutralize the exhaust gas to the bag filters 53 and 59. The reaction aid B is added to suppress an increase in pressure loss on the bag filters 53 and 59 and to increase the efficiency of removing acidic gas.
[0004]
Thus, the waste treatment equipment 50 includes a crusher 61 for crushing the molten slag C from the melting furnace 56 and a sieving machine 62 for separating the slag from the slag into fine slag D and other coarse slag E. Have. The sieving machine 62 has a mesh of 0.075 mm.
The coarse slag E on the sieve larger than the sieve separated by the sieving machine 62 is effectively used for roadbed material and the like, and the fine slag D under the sieve smaller than the sieve is landfilled.
[0005]
[Patent Document 1]
JP-A-56-115401 [Patent Document 2]
JP-A-7-204604 [Patent Document 3]
Japanese Patent No. 3146919 [Patent Document 4]
Japanese Patent Application Laid-Open No. 10-77602 [Patent Document 5]
JP-A-10-227431 [Patent Document 6]
JP 2000-205536 A [Patent Document 7]
JP 2001-276774 A
[Problems to be solved by the invention]
In short, the molten slag generated from the melting furnace is crushed by a crusher in order to use it effectively for roadbed materials, etc., but the fine slag generated at that time was removed because it could be scattered. There was no use to use.
[0007]
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and has been made in order to solve the above problems. In providing the device.
[0008]
[Means for Solving the Problems]
The method for effectively utilizing the slag of the present invention is basically such that fine slag formed after crushing the molten slag is used as a reaction aid in a waste filter and a back filter which is an exhaust gas treatment facility of the melting furnace. There is a characteristic in the thing.
[0009]
The slag effective utilization device of the present invention is a crusher for crushing molten slag, a sieving machine for separating slag from the slag, and a fine filter slag for the garbage incinerator and a Baku filter which is an exhaust gas treatment facility of a melting furnace. It has a feature in that it is provided with a pneumatic transportation means that blows into the inlet side.
[0010]
The molten slag from the melting furnace is crushed by a crusher and then separated into fine slag and coarse slag by a sieving machine. Coarse-grain slag is effectively used for roadbed materials and the like as in the past. The fine slag is blown together with an alkali agent as a reaction aid into the inlet side of a back filter which is an exhaust gas treatment facility of an incinerator and a melting furnace by an air transport means. Therefore, fine-grain slag conventionally disposed in landfill can be effectively used as a reaction aid. As a result, the cost of the reaction aid can be reduced.
[0011]
Preferably, the fine slag is further pulverized. By doing so, it is possible to improve the wiping property of the bag filter on the filter cloth and the reactivity of the alkali agent.
[0012]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 is a schematic diagram showing a waste treatment facility suitable for adopting the slag effective use method according to the first example of the present invention.
[0013]
The refuse treatment facility 1 includes an incinerator 2 for incinerating refuse, a waste heat boiler 3 for recovering heat of exhaust gas discharged from the incinerator, and a bag filter 4 for collecting fly ash contained in the exhaust gas from now on. An induction ventilator 5 for inducing future exhaust gas, a chimney 6 for discharging the future exhaust gas to the atmosphere, a melting furnace 7 for melting incineration ash from the incinerator 2 and fly ash from the back filter 4, Combustion chamber 8 for combusting exhaust gas, temperature-reducing tower 9 for decreasing the temperature of the exhaust gas from now on, bag filter 10 for collecting molten fly ash contained in the exhaust gas from now on, and inducing exhaust gas from the future And an induction ventilator 11 for discharging air from the chimney 6.
[0014]
Thus, the refuse treatment facility 1 includes a crusher 12 for crushing the molten slag C from the melting furnace 7, a sifter 13 for separating the slag from the slag into fine slag D and other coarse slag E, Pneumatic transport means 14 for blowing fine slag D together with alkaline agent A at each inlet side of Bak filters 4 and 10 which are dry exhaust gas treatment facilities of the incinerator 2 and the melting furnace 7 are provided. This is a so-called slag effective utilization device.
[0015]
The sieving machine 13 uses a sieve having a sieve mesh of 0.075 mm, and a fine slag D smaller than this is separated below the sieve, and a coarse slag E larger than this is separated above the sieve. ing.
[0016]
Although not shown, the pneumatic transport means 14 includes a silo for storing the fine slag D from the sieving machine 13, a quantitative feeder for sending out the fine slag D stored here in a constant amount, and a fine granule from this. A duct for guiding the slag D to the inlet sides (inlet ducts) of the bag filters 4 and 10 of the incinerator 2 and the melting furnace 7, and a blower through which fine slag D is pneumatically transported and blown to the inlet sides of the bag filters 4 and 10. Etc. are provided.
[0017]
Next, the operation will be described based on such a configuration.
The garbage is put into the incinerator 2 and incinerated. Exhaust gas from the incinerator 2 is heat-recovered by the waste heat boiler 3, and fly ash (dust, solid compounds and heavy metals) contained therein is collected by the bag filter 4. Exhaust gas from the bag filter 4 is induced by the induction ventilator 5 and discharged from the chimney 6 to the atmosphere.
The incinerated ash discharged from the incinerator 2 and the fly ash from the back filter 4 are sent to a melting furnace 7 where they are melted. Exhaust gas from the melting furnace 7 is burned by the combustion chamber 8 and cooled by the cooling tower 9, and the molten fly ash contained therein is collected by the bag filter 10. Exhaust gas from the bag filter 10 is induced by the induction ventilator 11 and discharged from the chimney 6 to the atmosphere.
[0018]
The molten slag C discharged from the melting furnace 7 is crushed by the crusher 12 and then separated into fine slag D on the sieve and coarse slag E under the sieve by the sieving machine 13. Coarse-grain slag E is effectively used as a roadbed material or the like as in the related art. The fine slag D is blown together with the alkaline agent A as a reaction aid B into the inlet side of Bak filters 4 and 10 which are exhaust gas treatment facilities of the incinerator 2 and the melting furnace 7 by the pneumatic transportation means 14.
[0019]
By the way, when an alkaline agent A such as slaked lime is used in a dry-type exhaust gas treatment facility, a reaction aid B is used to suppress an increase in pressure loss on a filter and to increase the efficiency of acid gas removal. I often do.
As the reaction aid B, those mainly composed of silicon (Si) and aluminum (Al) are used. On the other hand, the fine slag D obtained by crushing and sieving the molten slag C is mainly composed of silicon (Si), aluminum (Al), and calcium (Ca), and is glassy. It can be used because it has similar physical properties to commonly used reaction auxiliaries, such as lack of hygroscopicity.
Therefore, the fine slag D which has conventionally been landfilled can be effectively used as the reaction aid B. As a result, the cost of the reaction aid can be reduced.
[0020]
Next, a second example of the present invention will be described with reference to FIG.
FIG. 2 is a schematic diagram showing a refuse treatment facility suitable for adopting the slag effective use method according to the second example of the present invention.
[0021]
The second example is different from the first example in that a crusher 15 for finely crushing the fine slag D is provided between the sieving machine 13 and the pneumatic transportation means 14, and the other is the same as the first example. is there.
The crusher 15 crushes the fine slag D from the sieving machine 13 to an average of about 20 to 30 μm.
In such a case, since the fine slag D is finer, it is possible to improve the wiping property of the bag filters 4 and 10 on the filter cloth and the reactivity of the alkaline agent A.
[0022]
In the above example, the sieving machine 13 has a sieve mesh of 0.075 mm, but is not limited thereto, and may have another size, for example.
In the above example, the pneumatic transportation means 14 includes a silo, a fixed-quantity supply device, a duct, a blower, and the like, but is not limited thereto, and may have another structure, for example.
[0023]
【The invention's effect】
As described above, according to the present invention, the following excellent effects can be obtained.
(1) The fine slag produced after crushing the molten slag is used as a reaction aid in a back filter which is an exhaust gas treatment facility of an incinerator and a melting furnace, so that the fine slag can be effectively used.
(2) Since fine slag is used as a reaction aid, the cost of the reaction aid can be reduced.
[Brief description of the drawings]
FIG. 1 is a schematic diagram showing a waste treatment facility suitable for adopting a slag effective use method according to a first example of the present invention.
FIG. 2 is a schematic diagram showing a waste treatment facility suitable for adopting a slag effective use method according to a second example of the present invention.
FIG. 3 is a schematic diagram showing a conventional waste treatment facility.
[Explanation of symbols]
1,50: Waste treatment equipment, 2,51: Incinerator, 3,52: Waste heat boiler, 4,10,53,59 ... Bag filter, 5,11,54,60 ... Induced ventilator, 6,55 ... Chimney, 7,56 melting furnace, 8,57 combustion chamber, 9,58 cooling tower, 12,61 crusher, 13,62 sieving machine, 14 air transport means, 15 crusher, A ... Alkali agent, B ... Reaction aid, C ... Molten slag, D ... Fine slag, E ... Coarse slag.

Claims (3)

溶融スラグを破砕した後にできる細粒スラグを焼却炉及び溶融炉の排ガス処理設備であるバクフィルタで反応助剤として使用する様にした事を特徴とするスラグの有効利用方法。A method for effectively utilizing slag, characterized in that fine slag formed after crushing molten slag is used as a reaction aid in a back filter which is an exhaust gas treatment facility of an incinerator and a melting furnace. 細粒スラグを更に粉砕する様にした請求項1に記載のスラグの有効利用方法。The effective use method of the slag according to claim 1, wherein the fine slag is further pulverized. 溶融スラグを破砕する破砕機と、これからのスラグを分別する篩い機と、これからの細粒スラグを焼却炉及び溶融炉の排ガス処理設備であるバクフィルタの入口側に吹き込む空気輸送手段とを備えている事を特徴とするスラグの有効利用装置。A crusher for crushing the molten slag, a sieving machine for separating the slag from now on, and pneumatic transport means for blowing fine slag from here on the inlet side of a back filter which is an exhaust gas treatment facility of an incinerator and a melting furnace are provided. An effective slag utilization device that is characterized by
JP2003007898A 2003-01-16 2003-01-16 Method and apparatus for effective use of slag Expired - Fee Related JP4307087B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110624506A (en) * 2019-10-24 2019-12-31 陕西利人之星环保科技有限公司 Method for preparing water purifying agent by utilizing coal gasification furnace slag and obtained water purifying agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110624506A (en) * 2019-10-24 2019-12-31 陕西利人之星环保科技有限公司 Method for preparing water purifying agent by utilizing coal gasification furnace slag and obtained water purifying agent
CN110624506B (en) * 2019-10-24 2022-04-08 陕西利人之星环保科技有限公司 Method for preparing water purifying agent by utilizing coal gasification furnace slag and obtained water purifying agent

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