JP2004204111A - Film forming composition - Google Patents
Film forming composition Download PDFInfo
- Publication number
- JP2004204111A JP2004204111A JP2002376332A JP2002376332A JP2004204111A JP 2004204111 A JP2004204111 A JP 2004204111A JP 2002376332 A JP2002376332 A JP 2002376332A JP 2002376332 A JP2002376332 A JP 2002376332A JP 2004204111 A JP2004204111 A JP 2004204111A
- Authority
- JP
- Japan
- Prior art keywords
- forming composition
- film forming
- agent
- coating film
- volatile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000003039 volatile agent Substances 0.000 claims abstract description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 17
- -1 glycol ethers Chemical class 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims description 24
- 238000000576 coating method Methods 0.000 claims description 24
- 239000000417 fungicide Substances 0.000 claims description 8
- 239000000077 insect repellent Substances 0.000 claims description 6
- 239000002781 deodorant agent Substances 0.000 claims description 4
- 230000000855 fungicidal effect Effects 0.000 claims description 4
- 239000005871 repellent Substances 0.000 claims description 4
- 230000002940 repellent Effects 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract 2
- 239000003814 drug Substances 0.000 description 11
- 229940079593 drug Drugs 0.000 description 11
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000007721 medicinal effect Effects 0.000 description 4
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920001800 Shellac Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 description 2
- MMKRHZKQPFCLLS-UHFFFAOYSA-N ethyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OCC MMKRHZKQPFCLLS-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
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- 239000000796 flavoring agent Substances 0.000 description 2
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- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- ZAZKJZBWRNNLDS-UHFFFAOYSA-N methyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OC ZAZKJZBWRNNLDS-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 2
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 2
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- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 2
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- 235000013874 shellac Nutrition 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
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- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- PRBXPAHXMGDVNQ-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]acetic acid Chemical compound OCCOCCOCC(O)=O PRBXPAHXMGDVNQ-UHFFFAOYSA-N 0.000 description 1
- SKVCWXRLKHBEKW-UHFFFAOYSA-N 2-methylpropyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(C)C SKVCWXRLKHBEKW-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
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- 229920001817 Agar Polymers 0.000 description 1
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- 244000037364 Cinnamomum aromaticum Species 0.000 description 1
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- 241000282375 Herpestidae Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
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- 229960003500 triclosan Drugs 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、揮散性薬剤を含んだ塗膜形成組成物に関し、さらに詳しくは、揮散性薬剤の揮散量を向上させた塗膜形成組成物に関する。
【０００２】
【従来の技術】
従来から揮散性の防虫剤、防かび剤等の薬剤を混合させた塗料等の塗膜形成組成物が知られている。ところが塗膜内に混在させた薬剤は適切な揮散量が得られにくく目的とする薬効が得られないことがあった。そのため塗膜内にある種の徐放成分を共存させて薬剤を適切に揮散させるための手段が検討されている（例えば、特許文献１参照。）。
【０００３】
【特許文献１】
特公平４−３９３２４号公報（第１−６頁）
【０００４】
【発明が解決しようとする課題】
しかしながら、塗膜内に混在させた薬剤の揮散量を向上させるには従来の技術では十分とは言えず、検討の余地があった。そこで本発明の課題は、揮散性薬剤の揮散量を向上させ目的とする薬効を得ることができる塗膜形成組成物を提供することである。
【０００５】
【課題を解決するための手段】
本発明者らは上記の課題を満足するために鋭意検討した結果、塗膜形成剤と揮散性薬剤とを含んだ塗膜形成組成物に、前記揮散性薬剤の揮散調整剤として、グリコールエーテル又はエーテル系界面活性剤から選ばれる１種又は２種以上を含有させると、前記揮散性薬剤の揮散量が明らかに向上されることを見出し本発明を完成するに至った。すなわち本発明は以下の塗膜形成組成物により達成されるものである。
（１）塗膜形成剤と揮散性薬剤とを含んだ塗膜形成組成物であって、前記揮散性薬剤の揮散調整剤として、グリコールエーテル又はエーテル系界面活性剤から選ばれる１種又は２種以上を含有させたことを特徴とする塗膜形成組成物。
（２）塗膜形成剤が、分子量７００以上の高分子化合物であることを特徴とする（１）記載の塗膜形成組成物。
（３）揮散性薬剤が、２０℃における蒸気圧が０．１ｍＰａ以上であることを特徴とする（１）又は（２）記載の塗膜形成組成物。
（４）揮散性薬剤が、防虫剤、殺虫剤、防かび剤、香料、消臭剤、殺菌剤、又は忌避剤からなる群から選ばれる１種又は２種以上であることを特徴とする（１）乃至（３）のいずれか１つに記載の塗膜形成組成物。
【０００６】
【発明の実施の形態】
本発明の塗膜形成組成物は、塗膜形成剤と揮散性薬剤とを含み、さらに揮散調整剤としてグリコールエーテル又はエーテル系界面活性剤から選ばれる１種又は２種以上を含有させたものであり、グラビア印刷等が可能であるので各種部材に容易に塗布することができる。
【０００７】
揮散性薬剤の揮散量を向上させる作用を有する揮散調整剤としては、エチレングリコールエーテル（付加エーテルがモノブチル、モノフェニル等）、ジエチレングリコールエーテル（付加エーテルがモノブチル、モノフェニル等）、トリエチレングリコールエーテル（付加エーテルがモノブチル、モノフェニル等）、トリプロピレングリコールエーテル（付加エーテルがモノブチル、モノフェニル等）等のグリコールエーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレンジアルキルエーテル等のエーテル系界面活性剤が挙げられる。これらは１種又は２種以上を組み合わせて用いてもよく、塗膜形成組成物中に０．１〜５０重量％、好ましくは５〜２０重量％となるように含有させるのがよい。
【０００８】
塗膜形成剤としては、分子量７００以上の高分子化合物を用いるのがよく、具体的には、スチレン・無水マレイン酸共重合体、Ｎ−ビニルピロリドン・無水マレイン酸共重合体、酢酸ビニル・無水マレイン酸共重合体、イソブチレン・無水マレイン酸共重合体、及びこれらの共重合体の長鎖（炭素数１０〜２２）一価アルコールとの反応物、アクリルポリオール樹脂、塩化ビニル・酢酸ビニル共重合体、スチレン・α−メチルスチレン・アクリル酸共重合体、その他のアクリル酸ターポリマー、ポリエチレン、ポリプロピレン、ポリ塩化ビニル、ポリスチレン、ウレタン樹脂、ポリエステル樹脂等の樹脂類、デンプン、ニカワ、カゼイン、セラック、ロジン等の天然高分子類、寒天、グアガム、キサンタンガム、セルロース等の多糖類等が挙げられる。これらは１種又は２種以上を組み合わせて用いてもよい。
【０００９】
揮散性薬剤としては、２０℃における蒸気圧が０．１ｍＰａ以上、好ましくは０．１〜３０ｍＰａの各種薬剤を用いることができ、防虫剤、殺虫剤、防かび剤、香料、消臭剤、殺菌剤、忌避剤等の有効成分が挙げられる。具体的には、エンペンスリン、トランスフルトリン、テラレスリン、メトフルスリン、ジノテフラン、ハイドロプレン、メトプレン、プロポクスル、アミドフルメット、Ｓ−１８６４（住友化学工業社製）等の防虫剤（殺虫剤）、イソプロピルメチルフェノール、オルトフェニルフェノール、トリブロムフェノール、パラクロロメタキシレノール、パラヒドロキシ安息香酸エステル、トリクロサン、ヒノキチオール、チモール、アリルイソチオシアネート等の防かび剤（殺菌剤）、Ｎ，Ｎ−ジエチル−ｍ−トルアミド、カラン−３，４−ジオール等の忌避剤、グリオキザール、アビエチン酸、ラウリルメタクリレート、フラボノイド、ポリフェノール等の消臭剤、ローズ油、ラベンダー油、ジャスミン油、パーチュリー油、カーネーション油、レモン油、オレンジ油、レモングラス油、ベルガモット油、ベチュバ油、チョウジ油、セダー油、ビャクダン油、ユーカリ油、カッシヤ油、ショウノウ油、イランイラン油、シトロネラー油、ゼラニウム油等の精油、ジャコウ、シベット油、ウミダヌキ油、アンバーグリス油等の動物性香料、バニリン、サリチル酸メチル、シンナミルアルデヒド、フェニルエチルアルコール、ゲラニオール、オキシシトロネラール、フェニルアセトアルデヒド、ピペロナール等の合成香料、これらを調合した調合香料等の香料等が挙げられる。
【００１０】
これらは１種又は２種以上を組み合わせて用いてもよく、塗膜形成組成物中に５〜８０重量％、好ましくは１０〜５０重量％となるように含有させるのがよい。
【００１１】
本発明の塗膜形成組成物には、発明の効果を奏する限り必要に応じて、ＢＨＴ、ＢＨＡ等の酸化防止剤、セラック、ＰＰパウダー等の抗ブロッキング剤、界面活性剤等の帯電防止剤、脂肪酸、他のカルボン酸等のブリード促進剤、紫外線吸収剤、滑剤、顔料、造核剤等を併用してもよい。
【００１２】
また塗膜形成組成物を調製する際に、メタノール、エタノール、トルエン、キシレン、酢酸エチル、酢酸ブチル等の溶剤を用いることもできる。
【００１３】
さらに本発明の塗膜形成組成物にミリスチン酸イソプロピル、ミリスチン酸メチル、ミリスチン酸エチル、ミリスチン酸イソブチル、ミリスチン酸ｎ−ブチル、ラウリン酸ヘキシル、パルミチン酸エチル、ラウリン酸ｎ−ブチル、イソノナン酸イソノニル等の脂肪酸エステル、ジメチルシリコン、環状ジメチルシリコン等のシリコン化合物、ノルマルパラフィン、イソパラフィン等のパラフィン等の揮散性成分を混在させて塗膜を濁らせ、前記揮散性成分が経時的に揮散することで濁りが消失することで経過期間が確認できるようなインジケーター機能をもたせてもよい。このようなインジケーター機能をもたせる際には、塗膜形成組成物をフィルム上にアルミニウムを蒸着又はラミネートした部材に塗布すると特に白濁の場合には濁りが明確になることから好ましい。
【００１４】
本発明の塗膜形成組成物は、１０〜１００μｍ程度の膜厚となるように所望の部材に塗布すればよく、ＰＥＴ、ＰＰ、ＰＥ等のプラスチック、金属等のフィルム、シート、容器等に適用できる。これらの部材は前記薬剤による薬効を備えたカバー、シート、袋、プレート、バルーン、ロール状シート等として用いることができ、これらを巻いたり、重ねたりして保管することで保管時の薬剤の揮散を抑えることができる。
【００１５】
【実施例】
以下に実施例によって本発明をさらに詳しく説明するが、本発明はこれらに限定されるものではない。
【００１６】
試験例１
表１記載の塗膜形成組成物を調製し、ガラス板に膜厚９４μｍ、塗布面積７ｃｍ2となるように塗布した。そして４０℃条件下に置き、１３日間での薬剤の揮散量を調べて揮散率（％）を求めた。試験の結果は表１に併せて記載した。本発明の実施例１は比較例１と比べて薬剤（エンペンスリン）の揮散率が明らかに向上していることが確認された。
【００１７】
【表１】
試験例２
表２記載の塗膜形成組成物を調製し、ＰＥＴシートに膜厚７５μｍ、塗布面積４．５ｃｍ2となるように塗布した。そして４０℃条件下に置き、１３日間での薬剤の揮散量を調べて揮散率（％）を求めた。試験の結果は表２に併せて記載した。本発明の実施例２は比較例２と比べて薬剤（エンペンスリン）の揮散率が明らかに向上していることが確認された。
【００１９】
【表２】
【発明の効果】
本発明によって、含有された揮散性薬剤の揮散量が向上された塗膜形成組成物とすることができる。そして揮散性薬剤として防虫剤、防かび剤等を用いることで優れた防虫、防かび等の薬効を各種部材に容易に塗布することができる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a film-forming composition containing a volatile agent, and more particularly, to a film-forming composition in which the amount of a volatile agent volatilized is improved.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, a film-forming composition such as a paint in which a chemical such as a volatile insect repellent or a fungicide is mixed has been known. However, it was difficult to obtain an appropriate amount of volatilization of a drug mixed in the coating film, and the desired medicinal effect was not obtained in some cases. Therefore, means for coexisting certain types of sustained-release components in the coating film to appropriately volatilize the drug have been studied (for example, see Patent Document 1).
[0003]
[Patent Document 1]
Japanese Patent Publication No. 4-39324 (pages 1-6)
[0004]
[Problems to be solved by the invention]
However, the conventional technique is not sufficient to improve the volatilization amount of the drug mixed in the coating film, and there is room for study. Therefore, an object of the present invention is to provide a coating film forming composition capable of improving the volatilization amount of a volatile chemical and obtaining a desired medicinal effect.
[0005]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to satisfy the above-mentioned problems, and as a result, a film-forming composition containing a film-forming agent and a volatile agent, as a volatilizing agent for the volatile agent, glycol ether or The inventor has found that when one or more selected from ether-based surfactants are contained, the volatilization amount of the volatile agent is clearly improved, and the present invention has been completed. That is, the present invention is achieved by the following coating composition.
(1) A film-forming composition containing a film-forming agent and a volatile agent, wherein one or two selected from glycol ethers or ether-based surfactants are used as the volatilization regulator of the volatile agent. A coating film forming composition comprising the above.
(2) The coating film forming composition according to (1), wherein the coating film forming agent is a polymer compound having a molecular weight of 700 or more.
(3) The coating film forming composition according to (1) or (2), wherein the volatile agent has a vapor pressure at 20 ° C. of 0.1 mPa or more.
(4) The volatile agent is one or more selected from the group consisting of insect repellents, insecticides, fungicides, fragrances, deodorants, fungicides, and repellents ( The coating film forming composition according to any one of 1) to (3).
[0006]
BEST MODE FOR CARRYING OUT THE INVENTION
The film-forming composition of the present invention contains a film-forming agent and a volatile agent, and further contains one or more selected from glycol ethers or ether surfactants as a volatile modifier. In addition, since gravure printing or the like is possible, it can be easily applied to various members.
[0007]
Examples of the volatilization modifier having an effect of improving the volatilization amount of the volatile chemical include ethylene glycol ether (additional ether is monobutyl, monophenyl, etc.), diethylene glycol ether (additional ether is monobutyl, monophenyl, etc.), triethylene glycol ether ( Glycol ethers such as monobutyl and monophenyl as addition ethers and tripropylene glycol ethers (monobutyl and monophenyl as addition ethers); polyoxyethylene alkyl ethers; polyoxyethylene alkylphenyl ethers; polyoxyethylene polyoxypropylene alkyl ethers And ether-based surfactants such as polyoxyethylene dialkyl ether. These may be used alone or in combination of two or more, and may be contained in the coating film forming composition in an amount of 0.1 to 50% by weight, preferably 5 to 20% by weight.
[0008]
As the coating film forming agent, a high molecular compound having a molecular weight of 700 or more is preferably used, and specifically, a styrene / maleic anhydride copolymer, an N-vinylpyrrolidone / maleic anhydride copolymer, a vinyl acetate / anhydride Maleic acid copolymer, isobutylene / maleic anhydride copolymer, and a reaction product of these copolymers with a long-chain (10 to 22 carbon atoms) monohydric alcohol, acrylic polyol resin, vinyl chloride / vinyl acetate copolymer Coalescence, styrene / α-methylstyrene / acrylic acid copolymer, other acrylic acid terpolymer, resins such as polyethylene, polypropylene, polyvinyl chloride, polystyrene, urethane resin, polyester resin, starch, glue, casein, shellac, Examples include natural polymers such as rosin, polysaccharides such as agar, guar gum, xanthan gum, and cellulose. It is. These may be used alone or in combination of two or more.
[0009]
As the volatile chemicals, various chemicals having a vapor pressure at 20 ° C. of 0.1 mPa or more, preferably 0.1 to 30 mPa can be used, and insect repellents, insecticides, fungicides, fragrances, deodorants, sterilizers And active ingredients such as repellents. Specifically, insect repellents (pesticides) such as empenthrin, transfluthrin, teralesulin, metofluthrin, dinotefuran, hydroprene, methoprene, propoxur, amidoflumet, S-1864 (manufactured by Sumitomo Chemical Co., Ltd.), isopropylmethylphenol, Fungicides (bactericides) such as orthophenylphenol, tribromophenol, parachlorometaxylenol, parahydroxybenzoic acid ester, triclosan, hinokitiol, thymol, allyl isothiocyanate, N, N-diethyl-m-toluamide, curan- Repellents such as 3,4-diol, deodorants such as glyoxal, abietic acid, lauryl methacrylate, flavonoids, polyphenols, rose oil, lavender oil, jasmine oil, parturi oil, carnation oil Essential oils such as lemon oil, orange oil, lemongrass oil, bergamot oil, bechuba oil, clove oil, cedar oil, sandalwood oil, eucalyptus oil, cassia oil, camphor oil, ylang ylang oil, citronella oil, geranium oil, musk, civet Animal flavors such as oil, sea urchin oil, ambergris oil, etc .; synthetic flavors such as vanillin, methyl salicylate, cinnamylaldehyde, phenylethyl alcohol, geraniol, oxycitronellal, phenylacetaldehyde, piperonal, etc .; And the like.
[0010]
These may be used alone or in combination of two or more, and may be contained in the coating film forming composition in an amount of 5 to 80% by weight, preferably 10 to 50% by weight.
[0011]
In the coating film forming composition of the present invention, an antioxidant such as BHT and BHA, an anti-blocking agent such as shellac and PP powder, an antistatic agent such as a surfactant, etc. Bleed accelerators such as fatty acids and other carboxylic acids, ultraviolet absorbers, lubricants, pigments, nucleating agents and the like may be used in combination.
[0012]
In preparing the coating film forming composition, a solvent such as methanol, ethanol, toluene, xylene, ethyl acetate, and butyl acetate can be used.
[0013]
Further, isopropyl myristate, methyl myristate, ethyl myristate, isobutyl myristate, n-butyl myristate, hexyl laurate, ethyl palmitate, n-butyl laurate, isononyl isononanoate, etc. Fatty acid ester, dimethyl silicon, silicon compounds such as cyclic dimethyl silicon, normal paraffin, paraffin such as isoparaffin and the like, and volatilizable components such as paraffin are mixed to make the coating film turbid. An indicator function may be provided so that the elapsed period can be confirmed by disappearance. In order to provide such an indicator function, it is preferable to apply the coating film forming composition to a member obtained by evaporating or laminating aluminum on a film, particularly in the case of cloudiness, since the cloudiness becomes clear.
[0014]
The coating film forming composition of the present invention may be applied to a desired member so as to have a thickness of about 10 to 100 μm, and is applied to films, sheets, containers, and the like of plastics such as PET, PP, and PE, metals, and the like. it can. These members can be used as a cover, a sheet, a bag, a plate, a balloon, a roll-shaped sheet, etc. having a medicinal effect by the drug, and the volatilization of the drug at the time of storage by storing these in a rolled or stacked state. Can be suppressed.
[0015]
【Example】
Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto.
[0016]
Test example 1
The coating film forming composition shown in Table 1 was prepared and applied to a glass plate so as to have a thickness of 94 μm and an application area of 7 cm 2 . Then, it was placed under a condition of 40 ° C., and the volatilization amount (%) of the drug was determined by examining the volatilization amount of the drug in 13 days. The test results are shown in Table 1. In Example 1 of the present invention, it was confirmed that the volatilization rate of the drug (empensulin) was clearly improved as compared with Comparative Example 1.
[0017]
[Table 1]
Test example 2
The coating film forming composition shown in Table 2 was prepared and applied to a PET sheet so as to have a thickness of 75 μm and an application area of 4.5 cm 2 . Then, it was placed under a condition of 40 ° C., and the volatilization amount (%) of the drug was determined by examining the volatilization amount of the drug in 13 days. The test results are also shown in Table 2. In Example 2 of the present invention, it was confirmed that the volatilization rate of the drug (empensulin) was clearly improved as compared with Comparative Example 2.
[0019]
[Table 2]
【The invention's effect】
According to the present invention, a coating film forming composition in which the volatilization amount of the contained volatile agent is improved can be obtained. By using an insect repellent, a fungicide or the like as a volatile agent, excellent medicinal properties such as insect repellency and fungicide can be easily applied to various members.
Claims (4)
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| JP2002376332A JP4443111B2 (en) | 2002-12-26 | 2002-12-26 | Coating film forming composition |
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| JP2002376332A JP4443111B2 (en) | 2002-12-26 | 2002-12-26 | Coating film forming composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1992229A1 (en) * | 2007-05-14 | 2008-11-19 | Sara Lee/DE N.V. | Sustained released insecticidal compositions |
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| JPH0632999A (en) * | 1992-07-20 | 1994-02-08 | Fukuvi Chem Ind Co Ltd | Insect-repellent coating material |
| JPH07179313A (en) * | 1993-12-21 | 1995-07-18 | Dainippon Jochugiku Co Ltd | Insecticide composition |
| JPH07187908A (en) * | 1993-12-27 | 1995-07-25 | Yuukou Yakuhin Kogyo Kk | Surface-treatment of horticultural tool |
| JPH08310907A (en) * | 1995-05-18 | 1996-11-26 | Dainippon Jochugiku Co Ltd | Aqueous insecticide for thermal transpiration and killing of insect |
| JPH10182304A (en) * | 1996-12-26 | 1998-07-07 | Fumakilla Ltd | Mothproofing agent |
| JPH1135405A (en) * | 1997-07-24 | 1999-02-09 | Daiwa Kagaku Kogyo Kk | Coating material for controlling insect pest |
| JP2001002503A (en) * | 1999-06-24 | 2001-01-09 | Shintoo Fine Kk | Putty and sealing material for insect control |
| JP2001302980A (en) * | 2000-04-19 | 2001-10-31 | Asahi Kasei Corp | Hinokitiol-containing coating |
| JP2003300802A (en) * | 2002-04-08 | 2003-10-21 | Asahi Kasei Corp | Heat-transpiring insect pest expellant |
-
2002
- 2002-12-26 JP JP2002376332A patent/JP4443111B2/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS636099B2 (en) * | 1982-02-16 | 1988-02-08 | Takasago Perfumery Co Ltd | |
| JPH04231058A (en) * | 1990-06-20 | 1992-08-19 | Kuraray Co Ltd | Composition putting out aromatic substance in a small quantity with controlled vaporization speed and air aromatic substance dispenser putting out it in a small quantity |
| JPH0532509A (en) * | 1991-07-30 | 1993-02-09 | Earth Chem Corp Ltd | Mite control composition |
| JPH0632999A (en) * | 1992-07-20 | 1994-02-08 | Fukuvi Chem Ind Co Ltd | Insect-repellent coating material |
| JPH07179313A (en) * | 1993-12-21 | 1995-07-18 | Dainippon Jochugiku Co Ltd | Insecticide composition |
| JPH07187908A (en) * | 1993-12-27 | 1995-07-25 | Yuukou Yakuhin Kogyo Kk | Surface-treatment of horticultural tool |
| JPH08310907A (en) * | 1995-05-18 | 1996-11-26 | Dainippon Jochugiku Co Ltd | Aqueous insecticide for thermal transpiration and killing of insect |
| JPH10182304A (en) * | 1996-12-26 | 1998-07-07 | Fumakilla Ltd | Mothproofing agent |
| JPH1135405A (en) * | 1997-07-24 | 1999-02-09 | Daiwa Kagaku Kogyo Kk | Coating material for controlling insect pest |
| JP2001002503A (en) * | 1999-06-24 | 2001-01-09 | Shintoo Fine Kk | Putty and sealing material for insect control |
| JP2001302980A (en) * | 2000-04-19 | 2001-10-31 | Asahi Kasei Corp | Hinokitiol-containing coating |
| JP2003300802A (en) * | 2002-04-08 | 2003-10-21 | Asahi Kasei Corp | Heat-transpiring insect pest expellant |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1992229A1 (en) * | 2007-05-14 | 2008-11-19 | Sara Lee/DE N.V. | Sustained released insecticidal compositions |
| WO2008140304A3 (en) * | 2007-05-14 | 2009-10-22 | Sara Lee/ De N.V. | Sustained release insecticidal compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4443111B2 (en) | 2010-03-31 |
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