JP2004195624A - Metal sticking material removing method on plate glass surface - Google Patents

Metal sticking material removing method on plate glass surface Download PDF

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Publication number
JP2004195624A
JP2004195624A JP2002370092A JP2002370092A JP2004195624A JP 2004195624 A JP2004195624 A JP 2004195624A JP 2002370092 A JP2002370092 A JP 2002370092A JP 2002370092 A JP2002370092 A JP 2002370092A JP 2004195624 A JP2004195624 A JP 2004195624A
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JP
Japan
Prior art keywords
plate glass
metal
deposits
water
sticking material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2002370092A
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Japanese (ja)
Inventor
Shigeru Sakurai
茂 桜井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP2002370092A priority Critical patent/JP2004195624A/en
Publication of JP2004195624A publication Critical patent/JP2004195624A/en
Withdrawn legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for simply and easily removing a metal sticking material on a plate glass surface without damaging a metal unstuck part in a state of the plate glass being installed in a building. <P>SOLUTION: This removing method of the metal sticking material formed of molten metal stuck to a surface of the plate glass, while cooled and solidified, is characterized by spraying blast media mainly composed of water soluble inorganic salt such as sodium hydrogen carbonate having the prescribed average particle size by using a straight hydraulic blast device with compressed air having prescribed pressure as an injection medium. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、板ガラス表面の金属付着物除去方法に関する。
【0002】
【従来の技術】
建築物を建設する際には、外壁、外装、窓枠、窓ガラスなどの施工が必要である。かかる施工には、鉄骨などの金属を溶接、溶断する作業を伴うことが多く、この作業により高温の溶融金属が発生する。例えば、鉄骨の溶接により生じる溶融鉄の温度は1000℃程度である。
【0003】
一般に、高層建築物を建設する際には、下層階から順に施工していくため、施工完了後の下層階には、上層階の施工時に発生し、飛散した溶融金属が付着する。この付着を防止するため、施工の際には、施工完了部分を防火シートで覆うなどの処置が施されることが多いが、この処置によって隙間を完全に塞ぐことは困難である。
【0004】
上記溶融金属は高温のため、板ガラス表面に付着すると該表面を溶融させ、その一部が板ガラス内部に入り込んで冷却固化した金属付着物となる。そのため、該金属付着物は拭き取りなどによっては除去できない。
【0005】
一方、ガラス表面の研削や表面層の剥離などを行う方法として、固体粒子(ブラストメディア)を高速でガラスに噴射するブラスト処理が従来から用いられており、圧縮空気を噴射媒体としてケイ砂や長石を吹き付けるブラスト処理(特許文献1参照)や、高圧水の噴射(特許文献2参照)が提案されている。しかし、ケイ砂や長石などの粒子はモース硬度が6〜7程度と高いため、板ガラス(モース硬度:約6.5)表面に傷を付けやすい。特に、金属(鉄のモース硬度:約4.5)が付着していない部分にも傷を付けて美観を損なうおそれがあり、また粒子が飛散するためその回収にも問題がある。一方、高圧水を噴射すると板ガラスを破損するおそれがあるほか、水の飛散が望まれない建設現場では使用できないなど、使用が限定される。そのため、表面に上記のような金属付着物が付着した板ガラスは、取り替える以外に適当な方法が無いという問題があった。
【0006】
【特許文献1】
特開2000−141224号公報(特許請求の範囲)
【特許文献2】
特開平10−118583号公報(特許請求の範囲)
【0007】
【発明が解決しようとする課題】
そこで本発明は、板ガラスを建築物に取り付けたままの状態で、金属が付着していない部分には傷を付けずに、板ガラス表面の金属付着物を簡便かつ容易に除去する方法を提供することを目的とする。
【0008】
【課題を解決するための手段】
本発明は、板ガラスの表面に溶融金属が付着して冷却固化して形成される金属付着物を、水溶性無機塩を主体とするブラストメディアを吹き付けて除去することを特徴とする板ガラス表面の金属付着物除去方法を提供する。
【0009】
【発明の実施の形態】
本発明では、ブラストメディアとして炭酸水素ナトリウムや炭酸カルシウムなどの水溶性無機塩を用いることが好ましい。これらの水溶性無機塩はモース硬度が2〜3程度と、ケイ砂や長石と比較して低いため、板ガラスに高速で噴射しても板ガラス表面に傷を付けにくく、かつ、金属付着物に対して充分な除去効果が得られる。なかでも、水溶性無機塩として炭酸水素ナトリウムを用いると好ましい。炭酸水素ナトリウムは水に溶解してpH8.5程度の弱アルカリ性水溶液となるので、吹き付け後のブラストメディアを水に溶解させて水溶液として回収し、該水溶液中に存在する金属粉末をろ過などにより除去すれば排水として処理できる。
【0010】
また、本発明において、水溶性無機塩の平均粒径が0.01〜0.3mmであると、金属付着物を効果的に除去できるため好ましい。平均粒径が0.3mmを超えると微粒子状の金属付着物を除去しきれないおそれがあり、また、平均粒径が0.01mm未満の場合、金属付着物を除去するためのエネルギーが小さく、充分な除去効果が得られないおそれがあるため好ましくない。
【0011】
一般に、ブラスト処理する場合、ブラストメディアを噴射媒体とともに被処理物に吹き付ける。本発明では、上記のブラストメディアを、0.3〜0.8MPa(ゲージ圧、以下同様)の圧縮空気を噴射媒体として吹き付けると、金属付着物を充分に除去できるため好ましい。特に、圧縮空気の圧力が0.4〜0.6MPaであると、金属付着物を除去するためのエネルギーを適度に保つことができ好ましい。また、ブラスト処理に使用するメディア量は2〜6kg/m程度であると好ましい。メディア量が少なすぎるとメディア粒子と金属付着物との衝突頻度が小さくなり、金属付着物の除去に長時間を要するため好ましくない。一方、メディア量が多すぎると、噴射媒体からメディア粒子に与えるエネルギーが少なくなるほか、メディア粒子同士の衝突が発生して金属付着物の除去効率が低下するおそれがある。さらに、メディアを多量に使用することになるため経済的ではない。
【0012】
なお、吹き付けによる衝撃でメディア粒子が粉砕され、発塵するのを防ぐ目的で、少量の水を加えて吹き付けてもよい。水の使用が望まれない建築現場では水を使用しないドライブラスト処理を、粉塵の飛散を抑制したい場合は、噴射後のブラストメディアと剥離させた付着物とを吸引して回収するバキュームブラスト処理又は水を使用したウエットブラスト処理を行うことが好ましい。なお、吹き付けに用いるブラスト装置としては直圧式とサクション式の2種類が知られているが、本発明では、メディア粒子に金属付着物を除去するためのエネルギーを充分に持たせる観点から直圧式を用いることが好ましい。
【0013】
なお、本発明の方法を適用する板ガラスの種類は特に限定されず、種々の大きさ、厚さを有する板ガラスに適用できる。特に、フロート法により製造された建築用板ガラスに用いると好ましい。一方、紫外線カットなどを目的として、表面に金属被覆処理が施されたガラスに用いると、上記金属被覆も同時に除去されてしまい、目的とする機能が発現しなくなるおそれがあるため好ましくない。また、強化ガラスに用いると、金属付着物の除去後にガラス表面に残る、凹状の付着跡の存在により強度が劣化するおそれがあるため好ましくない。
【0014】
また、本発明の方法により除去する金属付着物の形状は特に限定されず、また、その形状によって除去の難易度が変わることもない。本発明によれば、金属の溶接などによって生じた数十μm〜1mm程度の大きさの溶融金属が板ガラス表面に付着し、球状や不定形となって冷却固化した付着物を特に良好に除去できる。本発明の方法は、建築物に取り付けた後の板ガラスに、鉄の溶接で発生した溶融鉄が付着して冷却固化した鉄付着物や、フロート法によりガラス基板を製造する際に用いる溶融金属錫が付着して冷却固化した錫付着物などの除去に好適に用いられる。
【0015】
【実施例】
以下、本発明を実施例(例1)及び比較例(例2)によって詳しく説明するが、本発明はこれらによって限定されない。
【0016】
[例1]
鉄骨の溶接作業により発生した溶融鉄が付着して冷却固化した約0.1〜0.5mm程度の鉄付着物を表面に有する、厚さ15mmの建築用板ガラスを20cm四方に切断したサンプルを準備した。該サンプルに対し、平均粒径220μmの炭酸水素ナトリウムを、0.6MPaの圧縮空気を噴射媒体として、株式会社エコグローバル研究所の直圧式ブラスト装置であるエコシャワーSB400を用いて吹き付けた。炭酸水素ナトリウムの使用量は4kg/mであった。
【0017】
吹き付け後のサンプル表面からは鉄付着物が完全に除去され、凹状の付着跡が観察された。鉄が付着していなかった部分を観察したが、傷は付いておらず、吹き付け後にもサンプルの強度は充分に維持されていた。
【0018】
[例2]
例1と同様のサンプルに対し、粒度0.07〜0.3mmの6号Aケイ砂を、0.4MPaの圧縮空気を噴射媒体として、厚地鉄工株式会社の直圧式ブラスト装置であるAC−1Pを用いて吹き付けた。6号Aケイ砂の使用量は4kg/mであった。
【0019】
吹き付け後のサンプル表面からは鉄付着物が完全に除去されたが、同時に、サンプル表面全体に無数の微細な傷が付いているのが観察された。そのため、サンプルの強度が劣化するとともに、美観を損なう結果となった。
【0020】
【発明の効果】
本発明によれば、板ガラスを建築物に取り付けたままの状態で、金属が付着していない部分には傷を付けずに、板ガラス表面の金属付着物を簡便かつ容易に除去できる。また、金属付着物の除去後にも板ガラスの強度を維持でき、美観も損なわないので、板ガラスを取り替えることによるコストを削減できる。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for removing metal deposits on a plate glass surface.
[0002]
[Prior art]
When constructing a building, construction of outer walls, exteriors, window frames, window glass, etc. is required. Such construction often involves the work of welding and fusing a metal such as a steel frame, and this work generates high-temperature molten metal. For example, the temperature of molten iron generated by welding steel frames is about 1000 ° C.
[0003]
Generally, when constructing a high-rise building, construction is performed in order from the lower floor, so that the molten metal generated and scattered during the construction of the upper floor adheres to the lower floor after completion of construction. In order to prevent this adhesion, a treatment such as covering the construction completion portion with a fireproof sheet is often performed during construction, but it is difficult to completely close the gap by this treatment.
[0004]
Since the molten metal adheres to the surface of the plate glass because of the high temperature, the surface is melted, and a part of the molten metal enters the inside of the plate glass and becomes a metal deposit that is cooled and solidified. Therefore, the metal deposit cannot be removed by wiping or the like.
[0005]
On the other hand, as a method of grinding the glass surface or peeling off the surface layer, blasting, in which solid particles (blasting media) are sprayed onto the glass at high speed, has been conventionally used. Have been proposed (see Patent Document 1) and high-pressure water injection (see Patent Document 2). However, since particles such as silica sand and feldspar have a high Mohs hardness of about 6 to 7, the surface of the plate glass (Mohs hardness: about 6.5) is likely to be damaged. In particular, there is a risk of damaging a portion where metal (iron Mohs hardness: about 4.5) is not attached to impair the appearance, and there is a problem in recovery because particles are scattered. On the other hand, if high-pressure water is injected, the glass sheet may be damaged, and the use is limited such that it cannot be used at construction sites where scattering of water is not desired. Therefore, there is a problem that there is no appropriate method other than replacing the plate glass having the above-mentioned metal deposit on the surface.
[0006]
[Patent Document 1]
JP 2000-141224 A (Claims)
[Patent Document 2]
Japanese Patent Application Laid-Open No. 10-118583 (Claims)
[0007]
[Problems to be solved by the invention]
Therefore, the present invention provides a method for easily and easily removing metal deposits on the surface of a plate glass without scratching a portion where the metal is not adhered, while the plate glass is still attached to a building. With the goal.
[0008]
[Means for Solving the Problems]
The present invention relates to a metal on the surface of a plate glass, characterized in that a metal deposit formed by adhering a molten metal to the surface of the plate glass and cooling and solidifying is removed by spraying a blast medium mainly composed of a water-soluble inorganic salt. A method for removing deposits is provided.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
In the present invention, it is preferable to use a water-soluble inorganic salt such as sodium hydrogen carbonate or calcium carbonate as the blast medium. Since these water-soluble inorganic salts have a Mohs hardness of about 2-3, which is low compared to silica sand and feldspar, even if they are sprayed onto the plate glass at high speed, the surface of the plate glass is hardly damaged, and against metal deposits Sufficient removal effect. Of these, sodium hydrogen carbonate is preferably used as the water-soluble inorganic salt. Sodium bicarbonate dissolves in water to form a weakly alkaline aqueous solution with a pH of about 8.5, so the blasting media after spraying is dissolved in water and recovered as an aqueous solution, and the metal powder present in the aqueous solution is removed by filtration or the like Can be treated as wastewater.
[0010]
Moreover, in this invention, since the average particle diameter of water-soluble inorganic salt is 0.01-0.3 mm, since a metal deposit can be removed effectively, it is preferable. If the average particle diameter exceeds 0.3 mm, there is a possibility that the particulate metal deposit cannot be completely removed, and if the average particle diameter is less than 0.01 mm, the energy for removing the metal deposit is small, This is not preferable because a sufficient removal effect may not be obtained.
[0011]
In general, when blasting is performed, blasting media is sprayed onto an object to be processed together with an ejection medium. In the present invention, it is preferable to blow the above blast media with compressed air of 0.3 to 0.8 MPa (gauge pressure, the same applies hereinafter) as an injection medium because metal deposits can be sufficiently removed. In particular, it is preferable that the pressure of the compressed air is 0.4 to 0.6 MPa because energy for removing metal deposits can be appropriately maintained. The amount of media used for blasting is preferably about 2 to 6 kg / m 2 . If the amount of media is too small, the collision frequency between the media particles and the metal deposits becomes small, and it takes a long time to remove the metal deposits, which is not preferable. On the other hand, if the amount of media is too large, energy given to the media particles from the ejection medium is reduced, and collision between the media particles may occur, which may reduce the efficiency of removing metal deposits. Furthermore, it is not economical because it uses a large amount of media.
[0012]
Note that a small amount of water may be added and sprayed for the purpose of preventing the media particles from being pulverized and generated by the impact of spraying. Drive blasting that does not use water at construction sites where water use is not desired, or vacuum blasting that sucks and collects the blasting media after spraying and the adhered material that has been peeled off if you want to suppress the scattering of dust. It is preferable to perform wet blasting using water. Two types of blasting devices used for spraying, the direct pressure type and the suction type, are known, but in the present invention, the direct pressure type is used from the viewpoint of giving the media particles sufficient energy for removing metal deposits. It is preferable to use it.
[0013]
In addition, the kind of plate glass which applies the method of this invention is not specifically limited, It can apply to the plate glass which has various magnitude | sizes and thickness. In particular, it is preferable to use it for an architectural plate glass produced by a float process. On the other hand, if it is used on a glass whose surface is subjected to a metal coating treatment for the purpose of cutting off ultraviolet rays or the like, the metal coating is also removed at the same time, so that the intended function may not be exhibited. Moreover, when it uses for tempered glass, since there exists a possibility that intensity | strength may deteriorate by presence of the concave-shaped adhesion trace which remains on the glass surface after removal of a metal deposit, it is unpreferable.
[0014]
Moreover, the shape of the metal deposit removed by the method of the present invention is not particularly limited, and the difficulty of removal does not change depending on the shape. According to the present invention, a molten metal having a size of about several tens of μm to 1 mm generated by metal welding or the like adheres to the surface of a plate glass, and the deposits that are cooled and solidified in a spherical shape or indefinite shape can be particularly well removed. . The method of the present invention is applied to a plate glass after being attached to a building, and an iron deposit on which molten iron generated by welding of iron adheres and solidifies by cooling, or a molten metal tin used when a glass substrate is manufactured by a float method. It is suitably used for removing tin deposits that have solidified by cooling.
[0015]
【Example】
EXAMPLES Hereinafter, although an Example (Example 1) and a comparative example (Example 2) demonstrate this invention in detail, this invention is not limited by these.
[0016]
[Example 1]
Prepared a sample of a 15mm thick plate glass cut into 20cm squares, which has about 0.1 to 0.5mm of iron deposit on the surface, which has been melted and solidified by molten iron generated by welding of steel did. The sample was sprayed with sodium hydrogen carbonate having an average particle size of 220 μm using Eco Shower SB400, which is a direct pressure blasting apparatus of Eco Global Research Institute, using 0.6 MPa compressed air as an injection medium. The amount of sodium hydrogen carbonate used was 4 kg / m 2 .
[0017]
Iron deposits were completely removed from the surface of the sample after spraying, and concave deposits were observed. The portion where the iron was not adhered was observed, but there was no scratch, and the strength of the sample was sufficiently maintained even after spraying.
[0018]
[Example 2]
AC-1P which is a direct pressure blasting device of Ajiji Iron Works Co., Ltd., using a No. 6 A silica sand with a particle size of 0.07 to 0.3 mm and a compressed air of 0.4 MPa for the same sample as in Example 1. Sprayed with. The amount of No. 6 A silica sand used was 4 kg / m 2 .
[0019]
Iron deposits were completely removed from the sample surface after spraying, but at the same time, countless fine scratches were observed on the entire sample surface. For this reason, the strength of the sample deteriorated and the aesthetic appearance was impaired.
[0020]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to this invention, the metal deposit | attachment on the surface of a plate glass can be removed easily and easily, without attaching a damage | wound to the part which the metal is not adhering in the state which attached the plate glass to the building. Further, the strength of the plate glass can be maintained even after the metal deposits are removed, and the aesthetic appearance is not impaired, so that the cost of replacing the plate glass can be reduced.

Claims (4)

板ガラスの表面に溶融金属が付着して冷却固化して形成される金属付着物を、水溶性無機塩を主体とするブラストメディアを吹き付けて除去することを特徴とする板ガラス表面の金属付着物除去方法。A method for removing metal deposits on a surface of a plate glass, wherein the metal deposit formed by adhering a molten metal to the surface of the plate glass and solidifying by cooling is removed by spraying a blast medium mainly composed of a water-soluble inorganic salt. . 前記水溶性無機塩が、0.01〜0.3mmの平均粒径を有する炭酸水素ナトリウム又は炭酸カルシウムである請求項1に記載の板ガラス表面の金属付着物除去方法。The method for removing metal deposits on the surface of a plate glass according to claim 1, wherein the water-soluble inorganic salt is sodium hydrogen carbonate or calcium carbonate having an average particle diameter of 0.01 to 0.3 mm. 前記ブラストメディアを、0.3〜0.8MPaの圧縮空気を噴射媒体として、直圧式ブラスト装置を用いて吹き付ける請求項1又は2に記載の板ガラス表面の金属付着物除去方法。The method for removing metal deposits on the surface of a plate glass according to claim 1 or 2, wherein the blasting medium is sprayed by using a direct pressure blasting apparatus using compressed air of 0.3 to 0.8 MPa as an injection medium. 前記板ガラスが建築用板ガラスである請求項1〜3のいずれかに記載の板ガラス表面の金属付着物除去方法。The said glass plate is a plate glass for construction, The metal deposit removal method of the plate glass surface in any one of Claims 1-3.
JP2002370092A 2002-12-20 2002-12-20 Metal sticking material removing method on plate glass surface Withdrawn JP2004195624A (en)

Priority Applications (1)

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Publications (1)

Publication Number Publication Date
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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007237389A (en) * 2006-03-03 2007-09-20 Ngk Insulators Ltd Blasting method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007237389A (en) * 2006-03-03 2007-09-20 Ngk Insulators Ltd Blasting method

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