JPH05112833A - Treatment of surface layer on trimmed waste of surface treated steel sheet - Google Patents

Treatment of surface layer on trimmed waste of surface treated steel sheet

Info

Publication number
JPH05112833A
JPH05112833A JP9562591A JP9562591A JPH05112833A JP H05112833 A JPH05112833 A JP H05112833A JP 9562591 A JP9562591 A JP 9562591A JP 9562591 A JP9562591 A JP 9562591A JP H05112833 A JPH05112833 A JP H05112833A
Authority
JP
Japan
Prior art keywords
waste
trimmed
steel sheet
treated steel
grit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9562591A
Other languages
Japanese (ja)
Inventor
Motofumi Kurahashi
基文 倉橋
Masakane Takemoto
雅謙 竹本
Naoki Oishi
直樹 大石
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP9562591A priority Critical patent/JPH05112833A/en
Publication of JPH05112833A publication Critical patent/JPH05112833A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Manufacture And Refinement Of Metals (AREA)

Abstract

PURPOSE:To remove a surface layer containing a plating layer a trimmed waste in high efficiency by projecting grinding grains to the trimmed waste continuously cut from a surface treaded steel sheet. CONSTITUTION:In a surface treating manufacturing equipment line for galvanizing, etc., before the traveled surface treated sheet 1 is coiled in a coiling machine 2, the edge parts in sheet width direction are trimmed by a trimmer 3. The cutoff trimmed waste 4 comes into a chamber 5. Grit is injected toward the surface of the traveled trimmed waste 4 in the chamber 5 from blast nozzles 6. The trimmed waste 4 is ground to remote the surface layer of the plating waste, etc. The injected grit is carried to a grit recovering vessel 8 and separated into the grit as possible to reuse and the grit as impossible to reuse and dust. The surface treated trimmed waste 4 is coiled in a hoop coiling machine 11 and incorporated in a waste receiver 13.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はメッキ等の表面処理をし
た鋼板(鋼帯を含む。以下同じ)をトリミングした後の
トリム屑を連続的に除去する方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for continuously removing trim scraps after trimming a steel sheet (including a steel strip; the same applies hereinafter) surface-treated by plating or the like.

【0002】[0002]

【従来の技術】圧延された冷延鋼板は、板幅エッジ部を
成形して所定の板幅にするためトリミングされる。裁断
されたトリム屑(鋼板のフープ状屑)はスクラップとし
て転炉等に装入し、再資源として利用されてきている。
近時、耐食性を高めたメッキ等で表面処理された鋼板の
需要が多くなり、メッキされたトリム屑もそれに従い増
加している。
2. Description of the Related Art A rolled cold-rolled steel sheet is trimmed in order to form an edge portion of the sheet width into a predetermined sheet width. Trimmed scraps (hoop-shaped scraps of steel plates) that have been cut are put into a converter or the like as scraps and used as resources.
Recently, the demand for steel sheets surface-treated by plating or the like with improved corrosion resistance has increased, and the amount of plated trim waste has also increased accordingly.

【0003】しかし、これをそのまま転炉に装入する
と、メッキ金属のヒュームが発生し、炉壁煉瓦を著しく
浸食すると同時に作業環境の悪化を招き、また溶鋼鋳造
時に鋳造欠陥の発生原因となることがある。そのためト
リム屑からメッキ層を含む表層を予め除去しなければな
らなず、低コストで、高効率の除去技術が要求されてい
る。
However, if this is charged into a converter as it is, fumes of plated metal are generated, which significantly corrodes furnace wall bricks and at the same time deteriorates the working environment, and also causes casting defects during molten steel casting. There is. Therefore, the surface layer including the plating layer must be removed from the trim scraps in advance, and a low-cost and highly efficient removal technique is required.

【0004】従来、Znメッキ鋼板屑の処理法として、
特開昭57−85916号公報では同メッキ鋼板屑をZ
nの沸点温度付近に加熱し、メッキされたZnを蒸発除
去する前処理法が開示されている。しかしこの方法では
蒸発Znの飛散を防止するため高温雰囲気にした密閉容
器内で処理しなければならず、設備、操業コストが高く
なると共にメッキ処理鋼板製造ラインに設置することも
困難である。また、特開昭63−96224号公報に
は、Znメッキ鋼板スクラップを700〜900℃に加
熱し、その温度に保持しながらショットブラスト処理す
ることが開示されている。この方法もZnを溶融する温
度に加熱するため、前記公報と共通した問題点を有して
いる。
Conventionally, as a method for treating Zn-plated steel scrap,
In Japanese Patent Laid-Open No. 57-85916, Z
A pretreatment method is disclosed in which the plated Zn is heated to a temperature near the boiling point of n to evaporate and remove the plated Zn. However, this method requires treatment in a closed container in a high temperature atmosphere in order to prevent scattering of evaporated Zn, which increases equipment and operating costs and makes it difficult to install it in a plated steel sheet production line. Further, Japanese Patent Laid-Open No. 63-96224 discloses that Zn-plated steel plate scrap is heated to 700 to 900 ° C. and shot-blasted while being kept at that temperature. This method also has a problem in common with the above-mentioned publication because it is heated to a temperature at which Zn is melted.

【0005】一方、一部薬液による溶解処理が検討され
ているが、これについても廃液処理などの新たな問題を
生じ、処理コストが増大することが予想されている。
On the other hand, although dissolution treatment using a partial chemical solution has been studied, it is expected that this also causes new problems such as waste liquid treatment and increases the treatment cost.

【0006】[0006]

【発明が解決しようとする課題】このような現状におい
て、表面処理鋼板のトリム屑の表層除去処理には適切な
方法がなく、スクラップヤードに野積したままにしてお
くか、転炉等の寿命低下を認容しながら再利用を実行し
なければならず、この再利用実現技術の要望は極めて大
きい。本発明は上記要望に応えるべく、表面処理鋼板の
トリム屑より、高効率、低コストで連続的に表層を除去
し、しかも、表面処理鋼板製造設備ライン内においてそ
の除去処理を可能とし、現状再利用の範囲から外れてい
たこのトリム屑を有効利用する方法を提供する事を目的
とするものである。
Under the present circumstances, there is no suitable method for removing the surface layer of trim scraps of the surface-treated steel sheet, and it is left in the scrap yard or the life of the converter is shortened. Reuse must be carried out while accepting, and the demand for this reuse realization technology is extremely large. In order to meet the above-mentioned demand, the present invention enables to continuously remove the surface layer from the trim scraps of the surface-treated steel sheet with high efficiency and low cost, and further enables the removal treatment in the surface-treated steel sheet manufacturing equipment line. The purpose of the present invention is to provide a method for effectively using this trim scrap that has been out of the range of use.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
に本発明は次の構成を要旨とする。すなわち、(1) 走行
する表面処理鋼板より連続的に裁断したトリム屑に、研
削粒子を投射し、トリム屑のメッキ層を含む表層を除去
することをと特徴とする表面処理鋼板トリム屑の表層処
理方法、および(2) 表面処理鋼板製造ラインにおいて、
コイル巻取機の前方に設けたトリマーにより、走行する
表面処理鋼板をトリミングし、連続的に裁断されたトリ
ム屑に研削粒子を投射し、トリム屑のメッキ層を含む表
層を除去することをと特徴とする表面処理鋼板トリム屑
の表層処理方法である。
In order to achieve the above object, the present invention has the following structure. That is, (1) the surface layer of surface-treated steel sheet trim scraps characterized in that grinding particles are projected onto the trim scraps continuously cut from the running surface-treated steel plate to remove the surface layer including the plating layer of the trim scraps. Treatment method, and (2) surface treated steel sheet production line,
A trimmer provided in front of the coil winder trims the traveling surface-treated steel sheet, projects abrasive particles on the continuously cut trim scraps, and removes the surface layer including the plating layer of the trim scraps. It is a characteristic surface treatment method for surface-treated steel sheet trim scraps.

【0008】以下に本発明を詳細に説明する。一般にメ
ッキ金属は軟らかく、鋼板表面からこれを除去するのに
バイトやフライス等の工具による切削加工では、刃先に
メッキ金属が溶着し切削能力は急速に低下するため、頻
繁な工具の交換が必要になる。またグラインダーによる
研削加工では、メッキ金属による目詰まりが著しく、頻
繁に交換するか、オンライン・ドレッシングなどの特別
な清掃処理を行わなければならない。
The present invention will be described in detail below. Generally, the plated metal is soft, and when removing it from the steel plate surface with a tool such as a bite or milling cutter, the plated metal is welded to the cutting edge and the cutting ability decreases rapidly, so frequent tool replacement is required. Become. Grinding with a grinder causes significant clogging by the plated metal, and must be replaced frequently or special cleaning treatment such as online dressing must be performed.

【0009】本発明は上記のような交換や目詰まりがな
く、しかも連続的に循環使用できる研削粒子(以下グリ
ッドという)を、表面処理鋼板製造設備ラインに設けた
表層除去装置により、裁断したトリム屑に連続して投射
する。図1は本発明方法を実施する装置であり、表面処
理(Znメッキ)製造設備ラインに設置した一例を示
す。すなわち、走行するZnメッキ鋼板1は巻取機2に
巻取られる前に、トリマー3により板幅方向エッジ部を
トリミングされ、切り離されたフープ状トリム屑4は走
行しながらチャンバー5に入り、ここでグリッド噴射で
研削され、メッキ層等の表層除去が行われる。チャンバ
ー5には、トリム屑フープ4を挟むように上下に対向し
てブラストノズル6を一対、あるいは複数対並列して設
置しており、該ノズル6より走行するトリム屑4面に向
けてグリッドを噴射する。噴射されたグリッドはチャン
バー5の下部シュートに研削ダストと共に収集し、高圧
空気或いは水を搬送媒体としてドラフトパイプ7からグ
リッド回収槽8に搬送回収される。グリッド回収槽8で
は、再使用可能なグリッドと、そうでないグリッドやダ
ストとを分離し、後者はダスト回収装置9に送られが、
前者は循環パイプ10を介して、高圧の空気または液体
を媒体としてブラストノズル6に供給され、該ノズル6
から高圧媒体と共に噴出する。再使用可能なグリッド量
が不足している場合には新しいグリッドを適宜補充すれ
ばよい。
According to the present invention, the trim particles, which are free from the above-mentioned replacement and clogging, and which can be continuously circulated (hereinafter referred to as a grid), are cut by a surface layer removing device provided in a surface-treated steel sheet manufacturing equipment line. Continuously project on scraps. FIG. 1 shows an apparatus for carrying out the method of the present invention, which is installed in a surface treatment (Zn plating) manufacturing facility line. That is, the running Zn-plated steel plate 1 is trimmed at the edge portion in the plate width direction by the trimmer 3 before being wound by the winder 2, and the separated hoop-shaped trim waste 4 enters the chamber 5 while running, Then, the surface is removed by plating with a grid and the plating layer and the like are removed. A pair of blast nozzles 6 or a plurality of blast nozzles 6 are installed in the chamber 5 so as to face each other so as to sandwich the trim scrap hoop 4, and a grid is placed from the nozzle 6 toward the surface of the trim scrap 4 running. To jet. The sprayed grid is collected together with the grinding dust in the lower chute of the chamber 5, and is transferred and collected from the draft pipe 7 to the grid recovery tank 8 using high pressure air or water as a transfer medium. In the grid collection tank 8, the reusable grid is separated from the non-reusable grid and dust, and the latter is sent to the dust collection device 9,
The former is supplied to the blast nozzle 6 through the circulation pipe 10 by using high pressure air or liquid as a medium.
Ejects together with the high pressure medium. If the amount of reusable grids is insufficient, new grids may be added as needed.

【0010】表層処理したトリム屑4はフープ巻取機1
1に適宜の大きさのコイル12に巻取られ、屑受け13
に収納する。14はカッターを示す。
The trimmed waste 4 which has been surface-treated is the hoop winder 1.
1 is wound on a coil 12 of an appropriate size, and a scrap receiver 13
To store. Reference numeral 14 represents a cutter.

【0011】ノズルから噴射されるグリッドはかなり高
速であるためノズル先端は摩耗を起こす。そのため少な
くともノズル先端は、アルミナ,SiC,サイアロン等
の耐摩耗製材料とするのがよい。
Since the grid jetted from the nozzle is considerably high speed, the tip of the nozzle is worn. Therefore, at least the tip of the nozzle is preferably made of wear-resistant material such as alumina, SiC, sialon.

【0012】研削に供するグリッド(粒子)は、限定す
るものでないがSiC,アルミナ,ガラスビーズ等の材
料からなることが好ましい。またその粒径は設備及び操
業に大いに影響を及ぼす。図2は、グリッド粒径(mm)と
研削量(mg/cm2 ・秒,実線)およびブラストノズル寿
命(hr,点線)との関係を示したものであり、グリッド粒
径が大きくなるにしたがって研削量は増大するもののノ
ズル寿命が低下する。ノズル寿命は長い程よいことは当
然であるが、少なくとも定期点検の周期(720時間)
は必要であり、また、研削量は設備コストの面から大き
い方がよく、一方ライン操業面から少なくとも1mg/cm
2 ・秒以上とする必要がある。そのために20μm以上
2mm以下のグリッド粒径とすることが好ましい。
The grid (particles) to be ground is preferably, but not limited to, SiC, alumina, glass beads or the like. In addition, the particle size greatly affects the equipment and operation. Fig. 2 shows the relationship between the grid grain size (mm), the grinding amount (mg / cm 2 · sec, solid line) and the blast nozzle life (hr, dotted line). The amount of grinding increases, but the nozzle life decreases. Naturally, the longer the nozzle life, the better, but at least the periodic inspection cycle (720 hours)
Is necessary, and the grinding amount should be large in terms of equipment cost, while at least 1 mg / cm from the line operation side.
It must be 2 seconds or more. Therefore, it is preferable that the grid grain size is 20 μm or more and 2 mm or less.

【0013】ノズルへのグリッド搬送媒体は空気又は水
等を用いるが、ノズルからの噴射は加圧空気によって噴
出する。この空気圧力が研削量及び設備コストに及ぼす
影響も大きい。図3はこれらの関係を示したものであり
(実線は研削量,点線は設備コスト,一点鎖線は両者の
平均値)、空気圧力を上げると研削力は高くなって研削
量は増大するが、ノズルの摩耗量が大きくなり寿命低下
による装置コスト増や加圧空気の製造コスト増などを招
くため、空気圧力は15kg/cm2 以下にすることが好ま
しく、また、研削量が少なくとも1mg/cm2 ・秒以上必
要であることから0.5kg/cm2 以上の空気圧力にする
のが良い。
Air or water is used as the grid carrier medium for the nozzle, and the jet from the nozzle is jetted by pressurized air. This air pressure has a great influence on the grinding amount and the equipment cost. FIG. 3 shows these relationships (solid line indicates grinding amount, dotted line indicates equipment cost, and one-dot chain line indicates average value of both). If the air pressure is increased, the grinding force increases and the grinding amount increases. The air pressure is preferably 15 kg / cm 2 or less, and the grinding amount is at least 1 mg / cm 2 because the amount of wear of the nozzle increases and the life of the nozzle increases and the cost of the device increases and the manufacturing cost of pressurized air increases.・ Air pressure of 0.5 kg / cm 2 or more is recommended because it requires more than a second .

【0014】本発明は、上記のように研削粒子の投射に
より鋼板表面のメッキ金属を除去することができるが、
さらに設備をコンパクト化し、若しくはより作業スピー
ドを向上するために、前記グリッド噴射加工に加えてバ
イトによる切削かグラインダー等による研削加工を組み
合わせて実施しても良い。これらの併用加工においては
メッキ金属は研削粒子の投射で大部分が除去されている
ため、工具寿命を低下することがない。
In the present invention, the plating metal on the surface of the steel sheet can be removed by projecting the abrasive particles as described above.
Further, in order to make the equipment compact or to further improve the work speed, cutting with a bite or grinding with a grinder or the like may be combined in addition to the grid injection processing. In these combined processes, most of the plated metal is removed by the projection of grinding particles, so the tool life is not reduced.

【0015】以下に本発明の実施例を説明する。Examples of the present invention will be described below.

【0016】[0016]

【実施例】表面処理鋼板製造設備において、Znメッキ
鋼板から連続的に発生するトリム屑を図1に示す装置に
より連続的に処理する試験を行った。試験条件およびグ
リッド噴射条件は下記の通りである。表層除去されたト
リム屑を溶解し、この時に発生したヒュームの発生状況
〔鉄1kg当りのヒューム発生量g(Zn)/kg(Fe)〕を調べ
た。その結果を表1に示す。
EXAMPLE A test for continuously treating trim scraps continuously generated from a Zn-plated steel sheet by the apparatus shown in FIG. 1 was carried out in a surface-treated steel sheet manufacturing facility. The test conditions and grid injection conditions are as follows. The trim scraps removed from the surface layer were melted, and the fume generation state at this time [fume generation amount g (Zn) / kg (Fe) per 1 kg of iron) was examined. The results are shown in Table 1.

【0017】 [試験条件] ライン速度 100m/分 トリム幅 10mm メッキ厚み 6μm [グリッド噴射条件] 搬送エア圧 3〜5kg/cm2 グリッド材質 SiC グリッド径 50〜800μm ノズル距離 30μm[Test conditions] Line speed 100 m / min Trim width 10 mm Plating thickness 6 μm [Grid injection conditions] Carrier air pressure 3 to 5 kg / cm 2 Grid material SiC grid diameter 50 to 800 μm Nozzle distance 30 μm

【0018】[0018]

【表1】 [Table 1]

【0019】表1から明らかのように、トリム屑を表層
処理しないでそのまま溶解した試料No.13の場合
は、付着するメッキ金属(Zn)の約50%がヒューム
となって発生するが、本発明方法によって表層処理した
No.1〜12のヒューム発生量は極めて少なく、N
o.13に対して最大1/680に押さえることができ
た。
As is clear from Table 1, the sample No. 1 in which the trim scraps were melted as they were without surface treatment was used. In the case of No. 13, about 50% of the deposited plating metal (Zn) is generated as fumes. Fume generation amount of 1 to 12 is extremely small, N
o. I was able to hold it down to 1/680 at the maximum.

【0020】[0020]

【発明の効果】以上のように、本発明は表面処理鋼板の
トリム屑より高効率、低コストで連続的に表層を除去
し、しかも、表面処理鋼板製造設備ライン内においてそ
の除去処理を可能とし、現状再利用の範囲から外れてい
たこのトリム屑を、転炉等に装入するスクラップとして
トラブルなく有効利用することが可能となり、その工業
的効は極めて大きい。
INDUSTRIAL APPLICABILITY As described above, according to the present invention, the surface layer can be continuously removed with higher efficiency and lower cost than the trim scraps of the surface-treated steel sheet, and the removal treatment can be performed in the surface-treated steel sheet manufacturing equipment line. It is possible to effectively use this trim waste, which is out of the range of reuse at present, as scrap to be charged into a converter or the like, and its industrial effect is extremely large.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明方法を実施する装置の一例を示す。1 shows an example of an apparatus for carrying out the method of the invention.

【図2】グリッド粒径(mm)と、研削量( 実線)および噴
射ノズル寿命(点線)との関係を示す。
FIG. 2 shows the relationship between the grid particle size (mm), the grinding amount (solid line), and the jet nozzle life (dotted line).

【図3】空気圧力と、研削量(実線)及び設備コスト
(点線)との関係を示す。
FIG. 3 shows the relationship between air pressure, grinding amount (solid line), and equipment cost (dotted line).

【符号の説明】[Explanation of symbols]

1:Znメッキ鋼板 2:巻取機 3:トリマー 4:トリム屑 5:チャンバー 6:ブラストノズル 7:ドラフトパイプ 8:グリッド回収槽 9:ダスト回収装置 10:循環パイプ 11:フープ巻取機 12:コイル 13:屑受け 14:カッター 1: Zn-plated steel plate 2: Winder 3: Trimmer 4: Trim scraps 5: Chamber 6: Blast nozzle 7: Draft pipe 8: Grid recovery tank 9: Dust recovery device 10: Circulation pipe 11: Hoop winder 12: Coil 13: Waste receiver 14: Cutter

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 走行する表面処理鋼板より連続的に裁断
したトリム屑に、研削粒子を投射し、トリム屑のメッキ
層を含む表層を除去することをと特徴とする表面処理鋼
板トリム屑の表層処理方法。
1. A surface layer of surface-treated steel plate trim scraps, characterized in that grinding particles are projected onto trim scraps continuously cut from a running surface-treated steel plate to remove a surface layer including a plating layer of the trim scraps. Processing method.
【請求項2】 表面処理鋼板製造ラインにおいて、コイ
ル巻取機の前方に設けたトリマーにより、走行する表面
処理鋼板をトリミングし、連続的に裁断されたトリム屑
に研削粒子を投射し、トリム屑のメッキ層を含む表層を
除去することをと特徴とする表面処理鋼板トリム屑の表
層処理方法。
2. In a surface-treated steel sheet production line, a trimmer provided in front of a coil winder trims a traveling surface-treated steel sheet and projects grinding particles onto continuously cut trim scraps to trim trim scraps. A surface treatment method for surface-treated steel sheet trim scraps, which comprises removing the surface layer including the plating layer.
JP9562591A 1991-04-25 1991-04-25 Treatment of surface layer on trimmed waste of surface treated steel sheet Pending JPH05112833A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9562591A JPH05112833A (en) 1991-04-25 1991-04-25 Treatment of surface layer on trimmed waste of surface treated steel sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9562591A JPH05112833A (en) 1991-04-25 1991-04-25 Treatment of surface layer on trimmed waste of surface treated steel sheet

Publications (1)

Publication Number Publication Date
JPH05112833A true JPH05112833A (en) 1993-05-07

Family

ID=14142714

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9562591A Pending JPH05112833A (en) 1991-04-25 1991-04-25 Treatment of surface layer on trimmed waste of surface treated steel sheet

Country Status (1)

Country Link
JP (1) JPH05112833A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000067942A1 (en) * 1999-05-10 2000-11-16 Alcan International Limited Recovery method
WO2015146943A1 (en) * 2014-03-27 2015-10-01 株式会社神戸製鋼所 Continuous surface treatment method for steel wire
KR20190124053A (en) * 2018-04-25 2019-11-04 (주)프로템 apparatus for coating the both side

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000067942A1 (en) * 1999-05-10 2000-11-16 Alcan International Limited Recovery method
WO2015146943A1 (en) * 2014-03-27 2015-10-01 株式会社神戸製鋼所 Continuous surface treatment method for steel wire
CN106132573A (en) * 2014-03-27 2016-11-16 株式会社神户制钢所 The continuous surface processing method of steel wire rod
US20180202049A1 (en) * 2014-03-27 2018-07-19 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Continuous surface treatment method for steel wire
KR20190124053A (en) * 2018-04-25 2019-11-04 (주)프로템 apparatus for coating the both side

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