JP2004161810A5 - - Google Patents
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- JP2004161810A5 JP2004161810A5 JP2002326188A JP2002326188A JP2004161810A5 JP 2004161810 A5 JP2004161810 A5 JP 2004161810A5 JP 2002326188 A JP2002326188 A JP 2002326188A JP 2002326188 A JP2002326188 A JP 2002326188A JP 2004161810 A5 JP2004161810 A5 JP 2004161810A5
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- ppm
- absorption peak
- 3ebicz
- bicarbazole
- carbazole
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Description
合成例３ モノマーのＮ，Ｎ´-ジ（２-エチルヘキシル）-３-エチニル-３´，６-ビカルバゾール（これを３ＥｂｉＣｚとも言う）の合成
原料の３´，６-ビカルバゾールを出発物質として、合成例２の場合と同様にして、Ｎ，Ｎ´-ジ（２-エチルヘキシル）-３-エチニル-３´，６-ビカルバゾール（３ＥｂｉＣｚ）を得た。なお、各工程はできるだけ反応が進行するように適宜反応温度を調整した。
得られた３ＥｂｉＣｚは、図５に示すとおりの、ＩＲスペクトルの吸収ピークにより同定された。すなわち、２１００ｃｍ-1、３２８０ｃｍ-1での吸収ピークはそれぞれＣ≡Ｃ、Ｃ≡Ｃ−Ｈに帰し、また１４８０ｃｍ-1、１６００ｃｍ-1、２９２０〜２９７０ｃｍ-1での吸収ピークはそれぞれ、カルバゾール環、カルバゾール環水素及び／又はカルバゾール側鎖のアルキル基の吸収ピークに帰する。
Synthesis Example 3 Synthesis of monomer N, N'-di (2-ethylhexyl) -3-ethynyl-3 ', 6-bicarbazole (also referred to as 3EbiCz) Starting material 3', 6-bicarbazole was used as a starting material. In the same manner as in Synthesis Example 2, N, N'-di (2-ethylhexyl) -3-ethynyl-3 ', 6-bicarbazole (3EbiCz) was obtained. In each step, the reaction temperature was appropriately adjusted so that the reaction proceeded as much as possible.
The obtained 3EbiCz was identified by the absorption peak of the IR spectrum as shown in FIG . That, 2100 cm -1, attributed each absorption peak at 3280 cm -1 C [identical to] C, to C [identical to] C-H, also 1480cm -1, 1600cm -1, respectively absorption peak at 2920~2970cm -1, carbazole ring Attributable to the absorption peak of the carbazole ring hydrogen and / or the alkyl group of the carbazole side chain.
実施例３のポリマーは、図１に実線で示すとおりの、その1ＨＮＭＲスペクトル（室温、重クロロホルム溶媒）により同定された。すなわち、図中、０．８〜１．４ｐｐｍ、３．５ｐｐｍ及び６．０ｐｐｍでの単一ピークは、それぞれ、ＣＨ3（３Ｈ）とＣＨ2（１２Ｈ）のアルキルプロトン、カルバゾール骨格のＮに置換するオクチル基の１位のＣＨ2プロトン及び＝ＣＨ（１Ｈ）に帰し、６．４〜７．４ｐｐｍの多重線ピークはカルバゾール環プロトンに帰する。
また、このポリマーは、ドープ前後で、ドーピングの程度を加減、調節するなどして、電気伝導度を約１０ 0.6 〜１０4Ｓ／ｃｍの範囲で変動させることができる。
The polymer of Example 3 was identified by its 1 H NMR spectrum (room temperature, deuterated chloroform solvent) as shown by the solid line in FIG. That is, in the figure, single peaks at 0.8 to 1.4 ppm, 3.5 ppm, and 6.0 ppm are substituted with alkyl protons of CH 3 (3H) and CH 2 (12H) and N of the carbazole skeleton, respectively. The multiplexed peak at 6.4 to 7.4 ppm is attributed to the carbazole ring proton due to the CH 2 proton at the 1-position of the octyl group and ＝ CH (1H).
Further, the electric conductivity of this polymer can be varied in the range of about 10 0.6 to 10 4 S / cm by adjusting and adjusting the degree of doping before and after doping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002326188A JP3968424B2 (en) | 2002-11-08 | 2002-11-08 | POLYACETYLENE POLYMER, PROCESS FOR PRODUCING THE SAME, AND CONDUCTIVE MATERIAL AND PRESSURE-SENSITIVE MATERIAL HAVING THE SAME |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002326188A JP3968424B2 (en) | 2002-11-08 | 2002-11-08 | POLYACETYLENE POLYMER, PROCESS FOR PRODUCING THE SAME, AND CONDUCTIVE MATERIAL AND PRESSURE-SENSITIVE MATERIAL HAVING THE SAME |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004161810A JP2004161810A (en) | 2004-06-10 |
| JP2004161810A5 true JP2004161810A5 (en) | 2006-01-26 |
| JP3968424B2 JP3968424B2 (en) | 2007-08-29 |
Family
ID=32805161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002326188A Expired - Lifetime JP3968424B2 (en) | 2002-11-08 | 2002-11-08 | POLYACETYLENE POLYMER, PROCESS FOR PRODUCING THE SAME, AND CONDUCTIVE MATERIAL AND PRESSURE-SENSITIVE MATERIAL HAVING THE SAME |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3968424B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2016632B1 (en) | 2006-09-26 | 2009-11-18 | Canon Kabushiki Kaisha | Device |
| JP4921126B2 (en) * | 2006-11-17 | 2012-04-25 | キヤノン株式会社 | Aromatic substituted acetylene copolymers |
| JP2009057528A (en) * | 2007-09-04 | 2009-03-19 | Nippon Shokubai Co Ltd | Carbazole group-containing polymer with high molecular weight |
| JP5980659B2 (en) * | 2012-11-13 | 2016-08-31 | 国立大学法人京都大学 | Polymer having carbazole group, monomer and compound having carbazole group |
| KR102588912B1 (en) * | 2015-10-21 | 2023-10-16 | 디아이씨 가부시끼가이샤 | Active energy ray curable composition and plastic lens |
| JP6187846B1 (en) * | 2015-10-21 | 2017-08-30 | Dic株式会社 | Active energy ray-curable composition and plastic lens |
-
2002
- 2002-11-08 JP JP2002326188A patent/JP3968424B2/en not_active Expired - Lifetime
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