JP2004073056A - Method for modifying health beverage, beverage and liquors using electrolysis and electrodialysis - Google Patents

Method for modifying health beverage, beverage and liquors using electrolysis and electrodialysis Download PDF

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JP2004073056A
JP2004073056A JP2002236632A JP2002236632A JP2004073056A JP 2004073056 A JP2004073056 A JP 2004073056A JP 2002236632 A JP2002236632 A JP 2002236632A JP 2002236632 A JP2002236632 A JP 2002236632A JP 2004073056 A JP2004073056 A JP 2004073056A
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drinking water
healthy
water
tank
coffee
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Japanese (ja)
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Hiroshi Tanaka
田中 博
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Individual
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  • Tea And Coffee (AREA)
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a modification and improvement method by which electrodes are directly brought into contact with an object solution such as health drinking water, a raw material solution of health drinking water, drinking water, refreshing beverage, mineral water, juice, coffee, milk, tea, green tea, their mixed solutions, liquors, and electrification is carried out. <P>SOLUTION: Voltage is applied to the electrodes 1 and 2 and the object solution is fed to an electrolytic bath. An electrochemical reaction (oxidation) occurring in an anode is isolated from an electrochemical reaction (reduction) occurring in a cathode by using a diaphragm such as a cation membrane 4. The kind and presence of the diaphragm differ in use according to the kind and the treatment purpose of the object solution. When treatment is carried out so as to improve reducing power of the object solution and to prevent oxidation as one example, a method by which the object solution is fed to a minus bath (reducing bath) and water of city water level is fed to an oxidizing bath is performed. When a metal such as vanadium, is used as the anode, vanadium is eluted and a vanadium ion is increased in the object solution. A desired metal ion is dissolved in the object solution by changing the substances of the anode. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明が属する技術分野】
本発明は、電解もしくは電気透析を応用した健康飲料および健康飲料の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類の改質を行ったり、その溶液の効果を向上させる装置とその方法に関するものである。
【0002】
【従来の技術】
従来の飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類や健康飲料水もしくは健康飲料水の原料溶液の改質や改善を行う為にたくさんの方法が使用されている。
【0003】
また、必要な金属イオンやミネラルの補給を目的として、金属やミネラルの添加を行う健康飲料や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類などもある。
【0004】
これらの健康飲料の製造は溶液に何らかの物質を添加する(混ぜる)事が基本となっている。その健康飲料の有効性は基本的に添加物質の濃度と添加する物質の質に依存する場合が多い。言い換えれば、その有効性を高めるためには
▲1▼添加濃度を上げる。
▲2▼添加物質の質もしくは種類を変える。
▲3▼複数の物質を効果的に調合する。
という方法などにより製造されている。
【0005】
金属イオンやミネラルなどを添加する場合も同様で添加濃度と添加する物質の質または種類を変えるなどの方法を用い基本的に製造されている。
【0006】
飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類は化学品などの添加剤を使用してpH調整、酸化防止等の処理を行う方法。熱により処理を行い、製品(飲料など)の改質等を行う方法。長期間タンクに溶液を溜置き熟成をさせる方法などが用いられている。
【0007】
【発明が解決しようとする課題】
健康飲料の製造では、より効果的な製品を製造するために、希少で高価な物質を使用するなどの方法も考えられているが、安価な健康飲料を製造するためにはコスト的な課題が生ずる。また現状使用されている原料物質の濃度を上げると人体への吸収率が下がったり、物質の人体に対する副作用などが問題となるなど、濃度と比例した効果を求めることはできない場合が多い。
【0008】
また、安価で効果(有効性)の高い物質の探求もいろいろな方面で行われているが、簡単にこのような物質を見つけることはできない事は言うまでもない。
【0009】
健康飲料または健康飲料の原料水(対象溶液)電解もしくは電気透析を行い、直接対象溶液に電流を流し電気化学反応(酸化、還元反応)を溶液内で起こし、効果の向上を行う事をこの発明の第1の課題とする。
【0010】
第2の課題として、金属イオンなどを健康水に容存させたい場合、その金属イオンを含む物質を添加する方法が一般的に行われているが、この発明では電解プロセスにおける電極の電気的な溶出を利用し、金属イオンを健康飲料に容存させる発明を第2の課題とする。
【0011】
飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類製造では、先ず問題となる事柄として酸化の問題がある。製品が酸化すると全般的に製品の質は低下する。飲料や酒類の製造においては化学品を使用することなく酸化、還元反応を溶液内で電気化学反応を起こし品質の向上を行う事をこの発明の第3の課題とする。
【0012】
また飲料や酒類のまろやかさなどの主観的な味の評価の源となる要素として水以外の成分の水和性が大きな要素となる。水以外の成分が水に良く溶け込んでいない場合は味自体にカドができ、良い品質の飲料とは言えない場合が多くある。まろやかさを向上させるためには水和性の向上(熟成)を図る必要がある。これをを第4の課題とする。
【0013】
【課題を解決するための手段】
この課題を解決する手段として、電解もしくは電気透析を用いる。健康飲料もしくは健康飲料の原料水や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類と電極を接触させ溶液に電圧を加える。その時に物理的に起こる電気化学的な酸化、還元反応などを応用する手段を用いる。
【0014】
健康飲料水における応用方法として健康飲料水に添加(使用)する物質は、既存に使用されている医薬品、天然抽出物などを使用し、電解もしくは電気透析処理を行うことにより、その物質の有効性の向上を図る。
【0015】
飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類における応用方法としては、同じように溶液に直接電圧を加え電解もしくは電気透析処理を行うことにより、溶液に還元反応(水素化反応)などを起こし酸化しにくい溶液の生成を行う。また水和性の向上については電解による水クラスターの変化などの現象を応用する。本発明では比較的処理電流が大きく処理電圧が小さい処理を電解と呼び、比較的処理電流が小さく処理電圧が大きな処理を電気透析と呼ぶ。
【0016】
また、金属イオンを健康飲料に容存させる方法として、電解プロセスにおける電極の溶出反応を利用する。容存させたい金属を陽極として用い、電解によりその金属を陽極から溶出させる手段を用いる。
【0017】
上記の様に健康飲料もしくは健康飲料の原料水や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類に直接電圧を加える方法は、溶液に電極を浸し、電極に電圧を加え溶液に電流を流す手段を用いる。各飲料水や酒類に直接電圧を加え、電流を溶液に流す部分を、本発明では電解槽もしくは電気透析槽と呼ぶ。電解槽もしくは電気透析槽の種類は体系的に図1の様になり対象溶液の違い、処理目的により電解槽もしくは電気透析槽の使い分けを行う。また各溶液に流す電流の大きさや波形(直流、脈流、パルス、交流とその周波数)、なども各溶液の質、処理目的などに合わせて調整や選択を行う。
【0018】
従来こうした電解処理もしくは電気透析処理は、飲料水(アルカリイオン水)の処理や、食塩水の電解で次亜塩素酸を生成するなど限られた溶液にしか使用されていなかった。この方法は健康飲料水もしくは健康飲料水の原料水や飲料水(清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など)及び酒類を直接電解槽、もしくは電気透析槽に流し込み電解処理を行い、その溶液の活性(還元性、酸化性、有効性など)を高める。
【0019】
また、この発明では金属イオンの溶出を目的として電解を行う事もこの発明に含まれる。具体的な方法として陽極に必要な金属電極を用い陽極を電解溶出させ、健康飲料水または健康飲料水の原料などの溶液に必要な金属イオンの容存率(濃度)を向上させる。溶出量は電極に加える電力と電解槽に流し込む溶液の量によりコントロールを行う。
【0020】
この処理方法の特徴として、有効物質の濃度(添加量)を変えることなく、電解もしくは電気透析により、その溶液(健康飲料もしくは健康飲料の原料水)の有効性を高める事が可能になる事である。電解還元反応、電解水素化反応、電解酸化反応、電解溶出反応、電気イオン移動反応などを電解もしくは電気透析により実行する。
【0021】
電解もしくは電気透析により起こる、これらの反応をこの発明では電気化学反応と呼ぶ事とする。電解もしくは電気透析の処理は溶液(健康飲料もしくは健康飲料の原料水や飲料水及び酒類)に与える電流、電圧の大きさで反応をコントロールすることが容易に行うことができるので制御性が良い事も特徴の一つである。
【0022】
また、陽極と陰極に間に設置する隔膜を配置し陽極槽と陰極槽に分離することにより電解還元反応と電解酸化反応を分離して行うことができる。
【0023】
また、電極からの金属溶出をさせたくないときは陽極に白金などの溶出しにくい電極を用い処理を行えば、この反応を最小にすることも可能である。従って電解もしくは電気透析により起こる各電気化学反応を用途により電解装置の構成(構造)を変えることで自由に選択できるところもこの発明の特徴となる。
【0024】
【発明の実施の形態】
次に、本発明の実施の形態について図を参照して説明する。図2は無隔膜電解槽に健康飲料水または健康飲料水の原料溶液や飲料水(清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など)及び酒類などを流入させる装置の電解槽もしくは電気透析槽である。溶液によっては、この方法で電解もしくは電気透析を行う事により、対象溶液の還元処理と酸化処理を行うことができる。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行う。溶出させたくない場合は白金、イリジューム、バラジュームなどやその酸化体などを電極として使用する。
【0025】
図3は有隔膜電解槽(中性膜)もしくは有隔膜電気透析槽(中性膜)に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を流入させる装置である。この装置は健康飲料もしくは健康飲料水の原料溶液を同時に電気化学的な酸化、還元処理を行い、溶液の陽イオン、陰イオンも同時に移動させる事ができる装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0026】
図4は有隔膜電解槽(カチオン膜)もしくは有隔膜電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を流入させる装置である。この装置は健康飲料もしくは健康飲料水の原料溶液を同時に電気化学的な酸化、還元処理を行う。マイナス槽に流入した溶液の陽イオンだけがマイナス槽からプラス槽に移動する。プラス槽に流入した溶液の陽イオン、陰イオンは移動が起こらないので流入した溶液の組成を変えることなく電気化学的な還元処理を行う装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0027】
図5は有隔膜電解槽(アニオン膜)もしくは有隔膜電気透析槽(アニオン膜)に健康飲料、もしくは健康飲料水の原料溶液や飲料水(清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など)及び酒類を流入させる装置である。この装置は健康飲料もしくは健康飲料水の原料溶液を同時に電気化学的な酸化、還元処理を行う。プラス槽に流入した溶液の陰イオンだけがプラス槽からマイナス槽に移動する。マイナス槽に流入した溶液の陽イオン、陰イオンは移動が起こらないので流入した溶液の組成を変えることなく電気化学的な酸化処理を行う装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行いその金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0028】
図6は有隔膜電解槽(隔膜の種類は問わない)もしくは有隔膜電気透析槽(隔膜の種類は問わない)の酸化槽と還元槽に同一の健康飲料もしくは健康飲料水の原料溶液や飲料水(清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など)及び酒類を流入させる装置である。同一の溶液に対して酸化と還元を同時に行うことが出来る装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0029】
図7は有隔膜電解槽(隔膜の種類は問わない)もしくは有隔膜電気透析槽の酸化槽と還元槽に、違う種類の健康飲料もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を流入させる装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0030】
図8は健康飲料もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類に電解処理を行う前に、必要な物質の添加を行う装置で、ミネラルなどの補強等の目的で添加を行う装置である。添加した物質も電解処理を行うので添加物質の活性等が高くなる装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0031】
図9は電解槽もしくは電気透析槽に流入させる健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類に電解処理を行った後に必要な物質の添加を行う装置で、ミネラルなどの補強や電解により物質の組成を変化させる事を望まない場合に使用する装置である。添加した物質は電解処理もしくは電気透析処理を行わないので変質等が起こりにくい装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、これを用い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0032】
図10は電解槽もしくは電気透析槽から流出した健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を再度、同じ方向の槽に流入させる装置で、還元槽、または酸化槽から流出した溶液を同じ槽に再度流入(循環)させる装置である。対象溶液により強い電解もしくは電気透析を与えたいとき等に用いる装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0033】
図11は酸化槽もしくは電気透析槽から流出した健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を再度、逆方向の槽に流入させる装置で、還元槽、または酸化槽から流出した溶液を他方の槽に再度流入(循環)させる装置である。酸化処理と還元処理を行いたい時にこの方法用いる。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0034】
図12はアニオン、カチオン膜を複合的に使用し健康飲料もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類を処理する装置で図中の健康飲料水Bはこの電解槽若しくは電気透析槽によりイオン濃度が低い飲料水に変化する。飲料水Aは陰イオンが増加し、飲料水Bは陽イオンが増加する。この方式の電解槽もしくは電気透析槽を用いる事で、これらの反応を電解槽もしくは電気透析槽で起こすことができる装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0035】
図3〜図12の装置を複合的に用い健康飲料もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類の改質改善を行う装置である。また必要な金属イオンの溶出を目的とする場合は陽極の金属の選定を行い、その金属を電極として用いる。溶出させたくない場合は白金などの溶出が極めて少ない金属を電極として使用する。
【0036】
図3〜図12の電解槽の図は構造がわかりやすいように、単板構造(陽極槽と陰極槽がそれぞれ一つある電解槽)の図を記述しているが、連装構造(複数の電解槽を連装した形)の電解槽もしくは電気透析槽の使用もこの発明に含まれる。
【0037】
【実施例】
図13はアスコルビン酸を図4の電解槽で電解したときのpHとORPの変化である。
【0038】
図14は電解処理を行う前のアスコルビン酸溶液を液クロマトグラフにより分析を行った結果である。図15は電解処理を行った後のアスコルビン酸液を液クロマトグラフにより分析を行った結果である。
【0039】
図13は電解によりpHがアルカリ側にシフトし、ORP(酸化還元電位)もより還元性を示すようになることが解る。
【0040】
図14と図15から、アスコルビン酸溶液が電解により変質たことをこの分析では明確にできない事を示している。
【0041】
図16は細管式電気泳動法により分析したアスコルビン酸の希釈水電解処理を行っていない溶液のアニオン物質の分析結果である。
【0042】
図17は細管式電気泳動法により分析したアスコルビン酸の希釈水に電解処理を行った溶液のアニオン物質の分析結果である。
【0043】
図16、図17から細管式電気泳動法による分析では電解処理を行うことによりアニオン類の状態が変化していることがわかる。
【0044】
図18はアスコルビン酸を還元槽で循環処理を行った時のpH変化とORP変化の表である。
【0045】
図19は陽極に亜鉛を使用し電解を行った時の溶液の亜鉛濃度を調べた表である。時間とともに溶液の亜鉛濃度が増えることがわかる。
【0046】
【発明の効果】
以上説明したように電解もしくは電気透析により、酸化還元反応を健康飲料水もしくは健康飲料水の原料溶液に与える事が可能であることがわかる。電解還元処理を例にとると、電解により電極から発生する微細な水素の気泡でいわゆる水素化反応が起こっている事がわかる。電解により発生する気泡は極めて微細で溶液との接触表面積が大きいため、通常の水素化反応より、より効果的に反応が進む。同時に、陰極槽内では陽極から溶液に電子が放出され、健康飲料水もしくは健康飲料水の原料液に含まれる物質(例えば各種のビタミンやアミノ酸などの還元物質が効果的)に電子を供給することとなる。一連のこうした電気化学反応により、溶液の還元力は向上する。 供給溶液に与える電気エネルギーのコントロールの方法として、電力などを変化させる方法以外に図18の結果からわかるように電解時間の変化により行うことも可能である。基本的に化学物質などを添加することなく電解(溶液への通電)により溶液の変化を起こすことができる。この方法で処理を行うと従来からの健康飲料や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これら混合液など及び酒類に使用してきた物質をそのまま使用し、より効果の高い健康飲料の製造が可能になる。 図19で明らかなように陽極から電流相当のイオンが溶出する。この技術を応用しバナジュウムなどの人体に有効であることがわかっている金属イオン水の生成ができる。
【図面の簡単な説明】
【図1】この発明で用いる電解槽の種類
【図2】無隔膜電解槽もしくは電気透析槽の断面図
【図3】中性隔膜電解槽もしくは中性膜電気透析槽の断面図と、健康飲料水もしくは健康飲料水の原料溶液を流したときの電解反応の様子
【図4】カチオン膜隔膜電解槽もしくはカチオン膜電気透析槽の断面図と、健康飲料水もしくは健康飲料水の原料溶液を流したときの電解反応の様子
【図5】アニオン膜隔膜電解槽もしくはアニオン膜電気透析槽の断面図と、健康飲料水もしくは健康飲料水の原料溶液を流したときの電解反応の様子
【図6】有隔膜電解槽もしくは有隔膜電気透析槽の還元槽、酸化槽に同じ溶液を流し込んだ図
【図7】有隔膜電解槽もしくは有隔膜電気透析槽の還元槽、酸化槽に違う種類の溶液を流し込んだ図
【図8】有隔膜電解槽もしくは有隔膜電気透析槽の入水側に補助剤の添加装置を付加した図
【図9】有隔膜電解槽もしくは有隔膜電気透析槽の出水側に補助剤の添加装置を付加した図
【図10】有隔膜電解槽もしくは有隔膜電気透析槽で循環電解を行う図(同じ槽で電解)
【図11】有隔膜電解槽若しくは有隔膜電気透析槽で循環電解を行う図(違う槽で電解)
【図12】複合有隔膜電解槽もしくは複合有隔膜電気透析槽の断面図と、飲料及び酒類を流したときの電解反応の様子
【図13】電解処理をしたアスコルビン酸溶液としていない溶液のpH、ORPの変化
【図14】電解還元処理を行ったアスコルビン酸の液クロマトグラフによる分析図
【図15】電解還元処理を行っていないアスコルビン酸の液クロマトグラフによる分析図
【図16】電解を行っていないアスコルビン酸溶液の細管式電気泳動法によるアニオン分析図
【図17】電解を行ったアスコルビン酸溶液の細管式電気泳動法によるアニオン分析図
【図18】アスコルビン酸溶液を循環還元電解を行った時のpHとORPの変化
【図19】亜鉛電極の溶出実験の表
【符号の説明】
1  プラス電極
2  マイナス電極
3  中性膜
4  カチオン膜
5  アニオン膜
6  隔膜(中性膜、カチオン膜、アニオン膜)
7  必要な物質の添加口
8  カチオン膜又は中性膜
9  アニオン膜又は中性膜
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to the modification of liquors and health drinks and health drinks and beverages, soft drinks, mineral water, juices, coffee, milk, black tea, green tea, mixed liquids thereof, and the like by applying electrolysis or electrodialysis. And a method and a method for improving the effect of the solution.
[0002]
[Prior art]
Conventional drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixtures of these, etc. The method is used.
[0003]
In addition, for the purpose of replenishing necessary metal ions and minerals, health drinks and drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, and mixtures of these, in which metals and minerals are added, and There are also liquors.
[0004]
The production of these health drinks is based on adding (mixing) some substance to a solution. In many cases, the effectiveness of the health drink basically depends on the concentration of the added substance and the quality of the added substance. In other words, in order to enhance its effectiveness, {circle around (1)} the concentration of addition is increased.
(2) Change the quality or type of the added substance.
{Circle around (3)} Compounding multiple substances effectively.
It is manufactured by such a method.
[0005]
The same applies to the case where metal ions or minerals are added, and it is basically manufactured using a method such as changing the addition concentration and the quality or type of the substance to be added.
[0006]
A method in which drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and liquor are subjected to treatment such as pH adjustment and antioxidation using additives such as chemicals. A method in which treatment is performed by heat to modify products (such as beverages). A method in which a solution is stored in a tank for a long period of time and aged is used.
[0007]
[Problems to be solved by the invention]
In the production of health drinks, there are methods to use rare and expensive substances to produce more effective products, but there are cost issues in producing cheap health drinks. Occurs. In addition, if the concentration of the currently used raw material is increased, the absorption rate to the human body decreases, and there are problems such as side effects of the substance on the human body.
[0008]
In addition, the search for inexpensive and highly effective substances has been conducted in various fields, but it goes without saying that such substances cannot be easily found.
[0009]
The present invention is to perform electrolysis or electrodialysis of healthy drink or raw material water (target solution) of health drink, and to apply an electric current directly to the target solution to cause an electrochemical reaction (oxidation, reduction reaction) in the solution to improve the effect. This is the first problem.
[0010]
As a second problem, when it is desired to store metal ions or the like in healthy water, a method of adding a substance containing the metal ions is generally performed. A second object of the present invention is to make use of the dissolution to allow metal ions to be contained in health drinks.
[0011]
In the production of drinking water, soft drink water, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages, there is an oxidation problem as a first problem. Oxidation of the product generally reduces the quality of the product. It is a third object of the present invention to improve the quality of beverages and alcoholic beverages by producing an oxidation and reduction reaction in a solution without using a chemical product by causing an electrochemical reaction in the solution.
[0012]
In addition, the hydration of components other than water is a major factor as a source of subjective taste evaluation such as mellowness of beverages and alcoholic beverages. When ingredients other than water are not well-dissolved in water, the taste itself may be curled, and in many cases it cannot be said to be a drink of good quality. In order to improve the roundness, it is necessary to improve hydration (ripening). This is the fourth problem.
[0013]
[Means for Solving the Problems]
Electrolysis or electrodialysis is used as a means for solving this problem. An electrode is brought into contact with a health drink or raw material water for a health drink, drinking water, soft drink water, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, or liquor, and a voltage is applied to the solution. At this time, means for applying an electrochemical oxidation or reduction reaction which physically occurs at that time is used.
[0014]
Substances added (used) to healthy drinking water as an application method for healthy drinking water are to use the existing drugs, natural extracts, etc., and to conduct the electrolysis or electrodialysis treatment to make the substance effective. To improve.
[0015]
The application method for drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, these mixed liquids, etc. and alcoholic beverages is similarly performed by applying voltage directly to the solution and performing electrolysis or electrodialysis treatment. Then, a reduction reaction (hydrogenation reaction) or the like is caused in the solution to generate a solution that is hardly oxidized. For improvement of hydration, phenomena such as changes in water clusters due to electrolysis are applied. In the present invention, a process with a relatively large processing current and a small processing voltage is called electrolysis, and a process with a relatively small processing current and a large processing voltage is called electrodialysis.
[0016]
In addition, as a method of allowing metal ions to be contained in a health drink, an elution reaction of an electrode in an electrolytic process is used. A metal to be retained is used as an anode, and a means for eluting the metal from the anode by electrolysis is used.
[0017]
As described above, the method of applying a voltage directly to a health drink or raw water for a health drink, drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages is performed by applying an electrode to the solution. And a means for applying a voltage to the electrode and flowing a current to the solution is used. In the present invention, a portion in which a voltage is directly applied to each drinking water or liquor and an electric current flows through the solution is referred to as an electrolytic cell or an electrodialysis cell. The type of the electrolytic cell or the electrodialysis cell is systematically as shown in FIG. 1, and the electrolytic cell or the electrodialysis cell is properly used depending on the target solution and the treatment purpose. In addition, the magnitude and waveform of the current flowing in each solution (DC, pulsating current, pulse, AC and its frequency), etc., are also adjusted and selected according to the quality of each solution, processing purpose, and the like.
[0018]
Conventionally, such electrolytic treatment or electrodialysis treatment has been used only for a limited solution such as treatment of drinking water (alkaline ionized water) or generation of hypochlorous acid by electrolysis of saline. In this method, healthy drinking water or raw water and drinking water (soft drinks, mineral water, juice, coffee, milk, black tea, green tea, etc.) and alcoholic beverages are directly electrolyzed or electrodialyzed. To increase the activity (reducing, oxidizing, effectiveness, etc.) of the solution.
[0019]
In the present invention, performing electrolysis for the purpose of eluting metal ions is also included in the present invention. As a specific method, a metal electrode required for the anode is used to electrolytically elute the anode, thereby improving the capacity (concentration) of metal ions required for a solution of healthy drinking water or a raw material of healthy drinking water. The elution amount is controlled by the electric power applied to the electrode and the amount of the solution poured into the electrolytic cell.
[0020]
One of the features of this treatment method is that it is possible to increase the effectiveness of the solution (healthy drink or raw water of healthy drink) by electrolysis or electrodialysis without changing the concentration (addition amount) of the active substance. is there. An electrolytic reduction reaction, an electrolytic hydrogenation reaction, an electrolytic oxidation reaction, an electrolytic elution reaction, an electric ion transfer reaction, and the like are performed by electrolysis or electrodialysis.
[0021]
These reactions that occur by electrolysis or electrodialysis are referred to as electrochemical reactions in the present invention. The electrolysis or electrodialysis treatment should have good controllability because the reaction can be easily controlled by the magnitude of the current and voltage applied to the solution (healthy drink or raw water for drinking or drinking water and alcoholic beverages). Is also one of the features.
[0022]
In addition, the electrolytic reduction reaction and the electrolytic oxidation reaction can be performed separately by arranging a diaphragm provided between the anode and the cathode and separating them into an anode tank and a cathode tank.
[0023]
If it is not desired to elute metal from the electrode, the reaction can be minimized by performing the treatment using an electrode such as platinum which does not easily elute as the anode. Therefore, a feature of the present invention is that each electrochemical reaction caused by electrolysis or electrodialysis can be freely selected by changing the configuration (structure) of the electrolysis apparatus according to the application.
[0024]
BEST MODE FOR CARRYING OUT THE INVENTION
Next, an embodiment of the present invention will be described with reference to the drawings. FIG. 2 shows that healthy drinking water or a raw material solution of healthy drinking water, drinking water (soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixed liquid thereof, etc.) and alcoholic beverages are flowed into a non-diaphragm electrolytic cell. This is the electrolysis or electrodialysis tank of the device. Depending on the solution, reduction or oxidation of the target solution can be performed by electrolysis or electrodialysis by this method. When the purpose is to elute necessary metal ions, the metal of the anode is selected. If you do not want to elute, use platinum, iridium, varium or the like or an oxidized form thereof as an electrode.
[0025]
Fig. 3 shows a healthy beverage or a raw solution of healthy drinking water, drinking water, soft drink, mineral water, juice, coffee, milk in a diaphragm electrolyzer (neutral membrane) or diaphragm electrodialysis tank (neutral membrane). , Black tea, green tea, a mixture thereof, and alcoholic beverages. This device is a device capable of simultaneously performing electrochemical oxidation and reduction treatment of a raw material solution of a health drink or health drinking water and simultaneously moving cations and anions of the solution. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0026]
Fig. 4 shows healthy drinks or raw material solutions and drinking water of healthy drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, etc. in a diaphragm electrolyzer (cation membrane) or diaphragm electrodialysis tank. It is a device for flowing mixed liquid and alcohol. This device simultaneously performs electrochemical oxidation and reduction of a raw material solution of a health drink or health drink water. Only the cations of the solution flowing into the minus tank move from the minus tank to the plus tank. Since the cations and anions of the solution flowing into the plus tank do not move, the apparatus performs an electrochemical reduction treatment without changing the composition of the flowing solution. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0027]
Fig. 5 shows a raw material solution of healthy drink or healthy drinking water or drinking water (soft drink water, mineral water, juice, coffee, milk, black tea) in a diaphragm electrolysis tank (anion membrane) or a diaphragm electrodialysis tank (anion membrane). , Green tea, a mixture thereof, etc.) and alcoholic beverages. This device simultaneously performs electrochemical oxidation and reduction of a raw material solution of a health drink or health drink water. Only the anions of the solution flowing into the plus tank move from the plus tank to the minus tank. Since the cations and anions of the solution flowing into the minus tank do not move, the apparatus performs an electrochemical oxidation treatment without changing the composition of the flowing solution. When the purpose is to elute necessary metal ions, a metal for the anode is selected and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0028]
FIG. 6 shows the same raw material solution or drinking water for the same health drink or healthy drinking water in the oxidation tank and the reduction tank of a diaphragm electrolyzer (irrespective of the type of diaphragm) or a diaphragm electrodialysis tank (irrespective of the type of diaphragm). It is a device for flowing soft drinks, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof and the like, and liquor. This is a device that can perform oxidation and reduction simultaneously on the same solution. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0029]
FIG. 7 shows different types of healthy drinks or raw material solutions of healthy drinking water, drinking water, soft drinks, minerals in the oxidation tank and the reduction tank of the diaphragm electrolyzer (regardless of the type of diaphragm) or the diaphragm electrodialysis tank. It is a device for flowing water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcohol. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0030]
Figure 8 shows the raw material solution of healthy drinks or healthy drinks, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixed liquids thereof, and other necessary substances before the electrolytic treatment of alcoholic beverages. Is an apparatus for adding minerals for the purpose of reinforcing minerals and the like. Since the added substance is also subjected to electrolytic treatment, the activity of the added substance is increased. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0031]
FIG. 9 shows the health drink or the raw material solution of the healthy drinking water flowing into the electrolysis tank or the electrodialysis tank, drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages. This is a device for adding a necessary substance after performing an electrolytic treatment, and is used when it is not desired to change the composition of the substance by reinforcing minerals or electrolysis. Since the added substance is not subjected to the electrolytic treatment or the electrodialysis treatment, it is a device in which deterioration or the like hardly occurs. When the purpose is to elute necessary metal ions, a metal for the anode is selected and used, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0032]
FIG. 10 shows a health drink or a source solution of health drinking water or a drinking water, a soft drink, a mineral water, a juice, a coffee, a milk, a black tea, a green tea, a mixed solution thereof and alcoholic beverages which flowed out of the electrolytic cell or the electrodialysis tank. This is a device for flowing again into the tank in the same direction, and a device for flowing (circulating) the solution flowing out of the reduction tank or the oxidation tank again into the same tank. This device is used when it is desired to give stronger electrolysis or electrodialysis to the target solution. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0033]
FIG. 11 shows the health drinks flowing out of the oxidation tank or the electrodialysis tank, or the raw material solution of the healthy drinking water, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, a mixed solution thereof, and alcoholic beverages. This is a device that flows into the tank in the opposite direction again, and the solution that flows out of the reduction tank or the oxidation tank flows again (circulates) into the other tank. Use this method when you want to perform oxidation and reduction. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0034]
FIG. 12 shows the use of anion and cation membranes in combination to form a raw material solution for healthy drinks or healthy drinks, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixed liquids thereof, and alcoholic beverages. In the processing apparatus, the healthy drinking water B in the figure is changed to drinking water having a low ion concentration by the electrolytic cell or the electrodialysis tank. In drinking water A, anions increase, and in drinking water B, cations increase. By using an electrolytic cell or an electrodialysis tank of this type, it is an apparatus capable of causing these reactions in the electrolytic cell or the electrodialysis tank. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0035]
The apparatus of FIGS. 3 to 12 is used in combination to improve the raw material solution of healthy beverage or healthy drinking water, drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages. This is a device for improving quality. When the purpose is to elute necessary metal ions, a metal for the anode is selected, and the metal is used as an electrode. If it is not desired to elute, use a metal such as platinum that has very little elution as the electrode.
[0036]
The drawings of the electrolyzers in FIGS. 3 to 12 illustrate the single-plate structure (the electrolyzer having one anode cell and one cathodic cell) for easy understanding of the structure. The present invention also includes the use of an electrolytic cell or an electrodialysis cell of a form in which a plurality of cells are connected.
[0037]
【Example】
FIG. 13 shows changes in pH and ORP when ascorbic acid is electrolyzed in the electrolytic cell shown in FIG.
[0038]
FIG. 14 shows the results of analyzing the ascorbic acid solution before the electrolytic treatment by liquid chromatography. FIG. 15 shows the results of analyzing the ascorbic acid solution after the electrolytic treatment by liquid chromatography.
[0039]
FIG. 13 shows that the pH shifts to the alkali side by electrolysis, and the ORP (oxidation-reduction potential) also shows a more reducing property.
[0040]
FIGS. 14 and 15 show that this analysis cannot clearly show that the ascorbic acid solution has been altered by electrolysis.
[0041]
FIG. 16 shows an analysis result of an anionic substance in a solution of ascorbic acid which has not been subjected to electrolysis treatment with diluted water, which was analyzed by a capillary electrophoresis method.
[0042]
FIG. 17 shows an analysis result of an anionic substance in a solution obtained by performing an electrolytic treatment on a dilution water of ascorbic acid analyzed by a capillary electrophoresis method.
[0043]
From FIGS. 16 and 17, it can be seen that in the analysis by the capillary electrophoresis, the state of the anions has changed by performing the electrolytic treatment.
[0044]
FIG. 18 is a table of pH change and ORP change when ascorbic acid is circulated in a reduction tank.
[0045]
FIG. 19 is a table examining the zinc concentration of the solution when electrolysis was performed using zinc as the anode. It can be seen that the zinc concentration of the solution increases with time.
[0046]
【The invention's effect】
As described above, it can be seen that it is possible to give an oxidation-reduction reaction to healthy drinking water or a raw material solution of healthy drinking water by electrolysis or electrodialysis. Taking the electrolytic reduction treatment as an example, it can be seen that a so-called hydrogenation reaction is occurring in fine hydrogen bubbles generated from the electrode by electrolysis. Since the bubbles generated by the electrolysis are extremely fine and have a large contact surface area with the solution, the reaction proceeds more effectively than a normal hydrogenation reaction. At the same time, electrons are emitted from the anode into the solution in the cathode tank, supplying electrons to the substances contained in the healthy drinking water or the raw liquid of the healthy drinking water (for example, reducing substances such as various vitamins and amino acids are effective). It becomes. Through a series of such electrochemical reactions, the reducing power of the solution is improved. As a method of controlling the electric energy applied to the supply solution, it is also possible to control the electric energy by changing the electrolysis time, as can be seen from the results of FIG. Basically, a change in the solution can be caused by electrolysis (energization of the solution) without adding a chemical substance or the like. When processed by this method, the substances used in conventional health drinks, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, these mixed liquids, etc. and alcoholic beverages are used as they are, Production of highly effective health drinks becomes possible. As is clear from FIG. 19, ions corresponding to the current elute from the anode. By applying this technology, it is possible to generate metal ion water such as vanadium which is known to be effective for the human body.
[Brief description of the drawings]
FIG. 1 is a sectional view of a non-diaphragm electrolytic cell or an electrodialysis tank. FIG. 3 is a cross-sectional view of a neutral diaphragm electrolytic cell or a neutral membrane electrodialysis tank, and a health drink. Electrolysis reaction when raw material solution of water or healthy drinking water is flown. [Fig. 4] Cross-sectional view of cationic membrane electrolyzer or cationic dialysis cell, and raw material solution of healthy drinking water or healthy drinking water is flowed. [Figure 5] Cross-sectional view of an anion membrane electrolyzer or an anion membrane electrodialyzer, and the state of electrolysis when healthy drinking water or a raw material solution of healthy drinking water flows [Figure 6] Diagram of the same solution being poured into the reducing and oxidizing tanks of a diaphragm electrolyzer or diaphragm electrodialysis tank. [Fig. 7] Different types of solutions being poured into the reducing and oxidizing tanks of a diaphragm electrolyzer or diaphragm electrodialysis tank. Figure [Figure 8] Separation membrane electrolysis Or, a diagram in which an auxiliary agent adding device is added to the water inlet side of the diaphragm electrodialysis tank [FIG. 9] A diagram in which an auxiliary agent adding device is added to the outlet side of the diaphragm electrolysis tank or the diaphragm electrodialysis tank [FIG. 10] Diagram of circulating electrolysis in a diaphragm electrolyzer or diaphragm electrodialysis tank (electrolysis in the same tank)
FIG. 11 is a diagram of performing circulating electrolysis in a diaphragm electrolysis tank or a diaphragm electrodialysis tank (electrolysis in a different tank).
FIG. 12 is a cross-sectional view of a composite diaphragm electrolyzer or a composite diaphragm electrodialyzer and the state of an electrolytic reaction when drinks and alcoholic beverages are flown. Change in ORP [Fig. 14] Analysis diagram of ascorbic acid subjected to electrolytic reduction treatment by liquid chromatography [Fig. 15] Analysis diagram of ascorbic acid not subjected to electrolytic reduction treatment by liquid chromatography [Fig. 16] Electrolysis is performed Anion analysis diagram by capillary electrophoresis of ascorbic acid solution without [Figure 17] Anion analysis diagram by capillary electrophoresis of ascorbic acid solution after electrolysis [Figure 18] When ascorbic acid solution was subjected to circulating reduction electrolysis Changes in pH and ORP of Fig. 19 Table of zinc electrode elution experiments [Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Positive electrode 2 Negative electrode 3 Neutral membrane 4 Cationic membrane 5 Anion membrane 6 Separator (neutral membrane, cation membrane, anion membrane)
7 Addition port of necessary substances 8 Cation membrane or neutral membrane 9 Anion membrane or neutral membrane

Claims (14)

無隔膜電解槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。A healthy drink or a raw material solution of healthy drinking water, drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture of these, etc., and alcoholic beverages are flowed into the non-diaphragm electrolysis tank, and the liquor is turned on. How to make quality improvements. イオン選択性のない膜を使用した有隔膜電解槽、もしくは無隔膜電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。In a diaphragm electrolysis tank using a membrane without ion selectivity or a non-diaphragm electrodialysis tank, a healthy drink or a raw material solution or drinking water of healthy drinking water, soft drink, mineral water, juice, coffee, milk, tea, A method in which green tea, a mixed solution thereof, and alcoholic beverages are flowed in, and electricity is supplied to improve reforming. イオン選択性のない膜を使用した有隔膜電解槽、もしくは有隔膜電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。Separation membrane electrolysis tank using membrane without ion selectivity, or health drink or raw material solution and drinking water of health drinking water, soft drink, mineral water, juice, coffee, milk, tea, A method in which green tea, a mixed solution thereof, and alcoholic beverages are flowed in, and electricity is supplied to improve reforming. 陽イオン交換膜を使用した有隔膜電解槽、もしくは有隔膜電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。Healthy drinks or raw material solutions and drinking water of healthy drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, etc. in a diaphragm electrolysis tank using a cation exchange membrane or a diaphragm electrodialysis tank A method for improving the reforming by flowing a mixture of these and the like and liquor and supplying electricity. 陰イオン交換膜を使用した有隔膜電解槽、もしくは有隔膜電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。In a diaphragm electrolysis tank using an anion exchange membrane or a diaphragm electrodialysis tank, a healthy drink or a raw solution or drinking water of healthy drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, A method for improving the reforming by flowing a mixture of these and the like and liquor and supplying electricity. 請求項1から3における装置で健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を電解槽、もしくは電気透析槽の酸化槽と還元槽に同一の健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類及びその他の溶液を流入させ通電を行い改質改善を行う方法。The apparatus according to claim 1, wherein a healthy beverage or a raw material solution or drinking water of a healthy drinking water, a soft drink, a mineral water, a juice, a coffee, a milk, a black tea, a green tea, a mixed solution thereof, etc. Or the same health drink or the same solution of healthy drinking water or drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, a mixture of these, etc. A method in which liquor and other solutions are flowed in and energized to improve reforming. 無隔膜電解槽、有隔膜電解槽及び電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類に必要な物質の添加を通電処理前に行い、添加後に通電処理を行う方法。Healthy drinks or raw material solutions of healthy drinking water, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixed liquids of these in non-diaphragm electrolysis tanks, diaphragm electrolysis tanks and electrodialysis tanks And a method in which a substance necessary for alcoholic beverages is added before the energization treatment, and the energization treatment is performed after the addition. 無隔膜電解槽、有隔膜電解槽及び電気透析槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類に必要な物質の添加を通電処理の後で行い改質改善を行う方法。Healthy drinks or raw material solutions of healthy drinking water, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixed liquids of these in non-diaphragm electrolysis tanks, diaphragm electrolysis tanks and electrodialysis tanks And a method of improving the reforming by adding a substance necessary for alcoholic beverages after the energization treatment. 有隔膜電解槽もしくは電気透析槽から出水した健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を再度電解槽、もしくは電気透析槽に流入させ通電を行う方法で、陰極槽または陽極槽から出水した健康飲料もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を同じ槽に流入させ通電処理を複数回行い改質改善を行う方法。Health drinks from the diaphragm electrolysis tank or electrodialysis tank, or raw material solutions of healthy drinking water, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages A method of flowing electricity into the electrolytic cell or the electrodialysis tank again and conducting electricity, and the raw material solution or drinking water, soft drink, mineral water, juice, coffee, milk of healthy drink or healthy drinking water discharged from the cathode tank or anode tank , Black tea, green tea, mixed liquids thereof, and alcoholic beverages are flowed into the same tank, and a current is applied a plurality of times to improve the reforming. 有隔膜電解槽もしくは有隔膜電気透析槽から出水した健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を再度電解槽、もしくは電気透析槽に流入させる方法で、陰極槽または陽極槽から出水した健康飲料もしくは健康飲料水の原料溶液を違う槽に流入させ通電処理を複数回行い改質改善を行う方法。Health drinks from a diaphragm electrolysis tank or a diaphragm electrodialysis tank, or raw material solutions of healthy drinking water, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, etc. In this method, liquor is allowed to flow again into the electrolytic cell or the electrodialysis tank, and the health drink or the raw material solution of the healthy drinking water discharged from the cathode tank or the anode tank is flowed into a different tank, and the current is treated a plurality of times to improve the reforming. Method. 陽イオン交換膜、陰イオン交換膜を複合的に使用した電解槽に健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類を流入させ通電を行い改質改善を行う方法。Healthy drinks or raw material solutions of healthy drinking water and drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, etc. in an electrolytic cell using a combination of cation exchange membrane and anion exchange membrane A method for improving the reforming by flowing a mixture of liquor and liquor and supplying electricity. 請求項1から請求項10を複合的に用い健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類の改質改善を行う方法。Claims 1 to 10 are used in combination for a health drink or a raw material solution or drink for health drink water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages. Method for improving the reforming of バッチ式電解槽、貯め置き式電解槽を用い健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類に通電処理を行い改質改善を行う方法。Using a batch-type electrolytic cell or a storage-type electrolytic cell, a health drink or a raw material solution of healthy drinking water, drinking water, soft drink, mineral water, juice, coffee, milk, black tea, green tea, a mixture thereof, and alcoholic beverages A method of improving the reforming by applying a current to the steel. 健康飲料、もしくは健康飲料水の原料溶液や飲料水、清涼飲料水、ミネラル水、ジュース、コーヒ、ミルク、紅茶、緑茶、これらの混合液など及び酒類に通電するために用いる電極から必要な金属イオン、ミネラルなどを健康飲料水などに溶出させその有効性を高める方法。Metal ions required to supply electricity to health drinks or health drinks, raw water solutions, drinking water, soft drinks, mineral water, juice, coffee, milk, black tea, green tea, mixtures thereof, etc., and alcoholic beverages Of minerals and minerals in healthy drinking water to enhance their effectiveness.
JP2002236632A 2002-08-14 2002-08-14 Method for modifying health beverage, beverage and liquors using electrolysis and electrodialysis Pending JP2004073056A (en)

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