JP2003524743A5 - - Google Patents

Download PDF

Info

Publication number
JP2003524743A5
JP2003524743A5 JP2000508631A JP2000508631A JP2003524743A5 JP 2003524743 A5 JP2003524743 A5 JP 2003524743A5 JP 2000508631 A JP2000508631 A JP 2000508631A JP 2000508631 A JP2000508631 A JP 2000508631A JP 2003524743 A5 JP2003524743 A5 JP 2003524743A5
Authority
JP
Japan
Prior art keywords
bullet
water
extrudable
soluble
oxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000508631A
Other languages
Japanese (ja)
Other versions
JP2003524743A (en
JP4057779B2 (en
Filing date
Publication date
Priority claimed from US09/119,518 external-priority patent/US6170399B1/en
Application filed filed Critical
Priority claimed from PCT/US1998/015064 external-priority patent/WO1999011587A1/en
Publication of JP2003524743A publication Critical patent/JP2003524743A/en
Publication of JP2003524743A5 publication Critical patent/JP2003524743A5/ja
Application granted granted Critical
Publication of JP4057779B2 publication Critical patent/JP4057779B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Claims (34)

容器、該容器中に入れられている推進薬、及び照明弾の推進薬を点火するための押出成形された乾燥した点火用素子を含んでなる点火系を含む照明弾であって、該押出成形された乾燥した点火用素子は点火の際爆燃するものであり、乾燥した点火用素子を調合するための乾燥の前に成分として、水性溶液中に溶解した少なくとも1種の水溶性バインダー、少なくとも1種の酸化剤、少なくとも1種の燃料、及び任意に繊維を含んで成り、
該水溶性バインダーが、該押出成形可能な点火用組成物中の全乾燥した成分基準で約2重量%〜約10重量%の量で存在する、水溶性高分子バインダー、水溶性ガム、及び水溶性ゼラチンよりなる群から選択される少なくとも1種の員子を含んで成り、
該押出成形された乾燥した点火用素子の調合が、押出成形可能な水の組成物を乾燥することを含んで成る、照明弾。
Illumination bullet comprising an ignition system comprising a container, a propellant contained in the vessel, and an extruded dry igniter element for igniting the propellant of the illumination bullet, the extrusion bullet The dried igniter element is detonated upon ignition, and as a component prior to drying to prepare the dried igniter element, at least one water-soluble binder dissolved in an aqueous solution, at least one Comprising an oxidizing agent, at least one fuel, and optionally a fiber;
A water-soluble polymeric binder, a water-soluble gum, and a water-soluble binder, wherein the water-soluble binder is present in an amount of from about 2% to about 10% by weight based on the total dry ingredients in the extrudable ignition composition Comprising at least one member selected from the group consisting of sex gelatin,
A lighting bullet wherein the formulation of the extruded dry igniter element comprises drying the composition of extrudable water.
水溶性バインダーが、ポリ‐N‐ビニルピロリドン、ポリビニルアルコール、ポリ‐N‐ビニルピロリドンとポリビニルアルコールの共重合体、ポリアクリルアミド、ポリアクリル酸ナトリウム類、及びポリアクリルアミドとポリアクリル酸の共重合体よりなる群から選ばれる少なくとも1種の員子を含んでなる、請求項1の照明弾。Water-soluble binders are poly-N-vinyl pyrrolidone, polyvinyl alcohol, poly-N-vinyl pyrrolidone and polyvinyl alcohol copolymers, polyacrylamide, sodium polyacrylates, and polyacrylamide and polyacrylic acid copolymers The illuminating bullet according to claim 1, comprising at least one member selected from the group consisting of: 水溶性バインダーがポリ‐N‐ビニルピロリドンを含んでなる、請求項1の照明弾。The illuminating bullet of claim 1, wherein the water-soluble binder comprises poly-N-vinylpyrrolidone. 水溶性バインダーがポリビニルアルコールを含んでなる、請求項1の照明弾。The illuminating bullet of claim 1, wherein the water-soluble binder comprises polyvinyl alcohol. 水溶性バインダーがガムを含んでなる、請求項1の照明弾。The illuminating bullet of claim 1, wherein the water-soluble binder comprises gum. 水溶性高分子バインダーがポリアクリルアミドを含んでなる、請求項1の照明弾。The illumination bullet of claim 1, wherein the water-soluble polymer binder comprises polyacrylamide. 酸化剤が押出成形可能な点火用組成物の調合に用いられた乾燥した成分に対して約40重量%〜約90重量%の量で存在する、請求項1の照明弾。2. The bomb of claim 1 wherein the oxidant is present in an amount of about 40% to about 90% by weight relative to the dry ingredients used in the formulation of the extrudable ignition composition. 酸化剤が有機の酸化剤を含んでなる、請求項1の照明弾。The illumination bullet of claim 1, wherein the oxidant comprises an organic oxidant. 酸化剤が硝酸塩、亜硝酸塩、塩素酸塩、過塩素酸塩、過酸化物および超酸化物よりなる群から選ばれる少なくとも1種のイオン性種を含んでなる、請求項1の照明弾。The illuminating bullet of claim 1, wherein the oxidant comprises at least one ionic species selected from the group consisting of nitrates, nitrites, chlorates, perchlorates, peroxides and superoxides. 押出成形可能な点火用組成物が繊維を含有する、請求項1の照明弾。The illuminating bullet of claim 1, wherein the extrudable ignitable composition comprises fibers. 繊維がポリオレフィン繊維、ポリアミド繊維、ポリエステル繊維およびポリ(2,2’−(m−フェニレン)−5,5−ビスベンズイミダゾール)繊維の内の少なくとも1種を含んでなる、請求項10の照明弾。11. The illumination bullet of claim 10, wherein the fibers comprise at least one of polyolefin fibers, polyamide fibers, polyester fibers and poly (2,2 ′-(m-phenylene) -5,5-bisbenzimidazole) fibers. . バインダーがポリ‐N‐ビニルピロリドン、ポリビニルアルコール、その共重合体、およびガムからなる群から選択される少なくとも1種の員子を含んでなり;
酸化剤が押出成形可能な点火用組成物の調合に用いられた乾燥した成分に対して約40重量%〜約90重量%の量で存在し、そして該酸化剤が硝酸塩、亜硝酸塩、塩素酸塩、過塩素酸塩、過酸化物および超酸化物よりなる群から選ばれる少なくとも1種のイオン性種を含有し;
押出成形可能な点火用組成物が、ポリオレフィン繊維、ポリアミド繊維、ポリエステル繊維およびポリ(2,2’−(m−フェニレン)−5,5−ビスベンズイミダゾール)繊維の内の少なくとも1種を含んでなる、アスペクト比の小さい繊維を含有する、請求項1記載の照明弾。
The binder comprises at least one member selected from the group consisting of poly-N-vinylpyrrolidone, polyvinyl alcohol, copolymers thereof, and gums;
An oxidant is present in an amount of from about 40% to about 90% by weight based on the dry ingredients used in the formulation of the extrudable ignition composition, and the oxidant is nitrate, nitrite, chloric acid Containing at least one ionic species selected from the group consisting of salts, perchlorates, peroxides and superoxides;
The extrudable ignition composition comprises at least one of polyolefin fibers, polyamide fibers, polyester fibers and poly (2,2 ′-(m-phenylene) -5,5-bisbenzimidazole) fibers. The illumination bullet according to claim 1, comprising a fiber having a small aspect ratio.
該押出成形された点火用素子が、点火薬スティックとして形成されている、請求項1記載の照明弾。The illuminating bullet of claim 1, wherein the extruded igniter element is formed as an igniter stick. 該燃料がホウ素を含んでなり、該酸化剤が硝酸カリウムを含んでなる、請求項1記載の照明弾。The illuminating bullet of claim 1, wherein the fuel comprises boron and the oxidant comprises potassium nitrate. 水溶性高分子バインダーが、ポリアクリルアミド、ポリアクリル酸ナトリウム、およびそれらの共重合体よりなる群から選ばれる少なくとも1種の員子を含んでなる、請求項14記載の照明弾。The illumination bullet according to claim 14, wherein the water-soluble polymer binder comprises at least one member selected from the group consisting of polyacrylamide, sodium polyacrylate, and copolymers thereof. 該ホウ素が約5重量%〜約30重量%の量で存在し、硝酸カリウムが約40重量%〜約90重量%の量で存在し、該バインダーが約2重量%〜約10重量%の量で存在する、請求項15に記載の照明弾。The boron is present in an amount of about 5% to about 30% by weight, potassium nitrate is present in an amount of about 40% to about 90% by weight, and the binder is in an amount of about 2% to about 10% by weight. 16. A lighting bullet according to claim 15, present. 押出成形可能な点火用組成物がさらに、成分の1つとして、硝酸グアニジンを含んでなる請求項16記載の照明弾。The illuminating bullet of claim 16, wherein the extrudable ignition composition further comprises guanidine nitrate as one of the components. 容器、その容器中に入れられている推進薬、及びその照明弾の推進薬を点火するための点火の際爆燃する押出成形された乾燥した点火用素子を含んでなる点火系を含んでなる照明弾を製造する方法であって、
該押出成形された乾燥した点火用素子が押出成形可能な点火用組成物から調合され、該方法が
水性溶液中に少なくとも1種の水溶性バインダーを溶解すること、
該溶解したバインダーを該押出成形された点火用組成物に調合するために少なくとも1種の酸化剤、少なくとも1種の燃料、および任意に繊維と混合すること、および
該押出成形可能な点火用組成物を押出成形し乾燥すること、
を含んでなり、
水溶性バインダーが、押出成形可能な点火用組成物中の全乾燥した成分量基準で約2重量%〜約10重量%の量で存在する、水溶性高分子バインダー、水溶性ガム、及び水溶性ゼラチンよりなる群から選ばれる少なくとも1種の員子を含んでなる、
方法。
Illumination comprising an ignition system comprising a container, a propellant contained in the container, and an extruded dry ignition element that detonates upon ignition for igniting the propellant of the illumination bullet A method of manufacturing a bullet,
The extruded dry ignition element is formulated from an extrudable ignition composition and the method dissolves at least one water-soluble binder in an aqueous solution;
Mixing the melted binder with at least one oxidant, at least one fuel, and optionally fibers to formulate the extruded ignition composition, and the extrudable ignition composition Extruding and drying the product,
Comprising
Water-soluble polymeric binder, water-soluble gum, and water-soluble, wherein the water-soluble binder is present in an amount of from about 2% to about 10% by weight based on the amount of all dry ingredients in the extrudable ignition composition Comprising at least one member selected from the group consisting of gelatin,
Method.
水溶性バインダーが、ポリ‐N‐ビニルピロリドン、ポリビニルアルコール、ポリ‐N‐ビニルピロリドンとポリビニルアルコールの共重合体、ポリアクリルアミド、ポリアクリル酸ナトリウム類、及びポリアクリルアミドとポリアクリル酸の共重合体よりなる群から選ばれる少なくとも1種の員子を含んでなる、請求項18に記載の照明弾を製造する方法。Water-soluble binders are poly-N-vinyl pyrrolidone, polyvinyl alcohol, poly-N-vinyl pyrrolidone and polyvinyl alcohol copolymers, polyacrylamide, sodium polyacrylates, and polyacrylamide and polyacrylic acid copolymers The method for producing an illumination bullet according to claim 18, comprising at least one member selected from the group consisting of: 水溶性バインダーがポリ‐N‐ビニルピロリドンを含んでなる、請求項18に記載の照明弾を製造する方法。19. A method for producing a light bullet according to claim 18, wherein the water-soluble binder comprises poly-N-vinylpyrrolidone. 水溶性バインダーがポリビニルアルコールを含んでなる、請求項18に記載の照明弾を製造する方法。The method for producing an illumination bullet according to claim 18, wherein the water-soluble binder comprises polyvinyl alcohol. 水溶性バインダーがガムを含んでなる、請求項18に記載の照明弾を製造する方法。The method for producing a light bullet according to claim 18, wherein the water-soluble binder comprises gum. 水溶性高分子バインダーがポリアクリルアミドを含んでなる、請求項18に記載の照明弾を製造する方法。The method for producing an illumination bullet according to claim 18, wherein the water-soluble polymer binder comprises polyacrylamide. 酸化剤が押出成形可能な点火用組成物の調合に用いられた乾燥した成分に対して約40重量%〜約90重量%の量で存在する、請求項18に記載の照明弾を製造する方法。19. The method of making a light bullet according to claim 18, wherein the oxidant is present in an amount of about 40% to about 90% by weight relative to the dry ingredients used in the formulation of the extrudable ignition composition. . 酸化剤が有機の酸化剤を含んでなる、請求項18に記載の照明弾を製造する方法。The method of manufacturing a light bullet according to claim 18, wherein the oxidant comprises an organic oxidant. 酸化剤が硝酸塩、亜硝酸塩、塩素酸塩、過塩素酸塩、過酸化物および超酸化物よりなる群から選ばれる少なくとも1種のイオン性種を含んでなる、請求項18に記載の照明弾を製造する方法。The illuminating bullet of claim 18, wherein the oxidant comprises at least one ionic species selected from the group consisting of nitrate, nitrite, chlorate, perchlorate, peroxide and superoxide. How to manufacture. 押出成形可能な点火用組成物が繊維を含有する、請求項18に記載の照明弾を製造する方法。The method for producing a light bullet according to claim 18, wherein the extrudable ignition composition contains fibers. 繊維がポリオレフィン繊維、ポリアミド繊維、ポリエステル繊維およびポリ(2,2’−(m−フェニレン)−5,5−ビスベンズイミダゾール)繊維の内の少なくとも1種を含んでなる、請求項18に記載の照明弾を製造する方法。19. The fiber of claim 18, wherein the fiber comprises at least one of polyolefin fiber, polyamide fiber, polyester fiber, and poly (2,2 '-(m-phenylene) -5,5-bisbenzimidazole) fiber. A method of manufacturing a lighting bullet. バインダーがポリ‐N‐ビニルピロリドン、ポリビニルアルコール、その共重合体、およびガムからなる群から選択される少なくとも1種の員子を含んでなり;
酸化剤が押出成形可能な点火用組成物の調合に用いられた乾燥した成分に対して約40重量%〜約90重量%の量で存在し、そして該酸化剤が硝酸塩、亜硝酸塩、塩素酸塩、過塩素酸塩、過酸化物および超酸化物よりなる群から選ばれる少なくとも1種のイオン性種を含有し;
押出成形可能な点火用組成物が、ポリオレフィン繊維、ポリアミド繊維、ポリエステル繊維およびポリ(2,2’−(m−フェニレン)−5,5−ビスベンズイミダゾール)繊維の内の少なくとも1種を含んでなる、アスペクト比の小さい繊維を含有する、請求項18に記載の照明弾を製造する方法。
The binder comprises at least one member selected from the group consisting of poly-N-vinylpyrrolidone, polyvinyl alcohol, copolymers thereof, and gums;
An oxidant is present in an amount of from about 40% to about 90% by weight based on the dry ingredients used in the formulation of the extrudable ignition composition, and the oxidant is nitrate, nitrite, chloric acid Containing at least one ionic species selected from the group consisting of salts, perchlorates, peroxides and superoxides;
The extrudable ignition composition comprises at least one of polyolefin fibers, polyamide fibers, polyester fibers and poly (2,2 ′-(m-phenylene) -5,5-bisbenzimidazole) fibers. The method for producing an illumination bullet according to claim 18, comprising a fiber having a low aspect ratio.
該押出成形された点火用素子が、点火薬スティックとして形成されている、請求項18に記載の照明弾を製造する方法。The method of manufacturing a light bullet according to claim 18, wherein the extruded igniter element is formed as an igniter stick. 該燃料がホウ素を含んでなり、該酸化剤が硝酸カリウムを含んでなる、請求項18に記載の照明弾を製造する方法。The method of manufacturing a light bomb according to claim 18, wherein the fuel comprises boron and the oxidant comprises potassium nitrate. 水溶性高分子バインダーが、ポリアクリルアミド、ポリアクリル酸ナトリウム、およびその共重合体よりなる群から選ばれる少なくとも1種の員子を含んでなる、請求項18に記載の照明弾を製造する方法。The method for producing an illumination bullet according to claim 18, wherein the water-soluble polymer binder comprises at least one member selected from the group consisting of polyacrylamide, sodium polyacrylate, and a copolymer thereof. 該ホウ素が約5重量%〜約30重量%の量で存在し、硝酸カリウムが約40重量%〜約90重量%の量で存在し、該バインダーが約2重量%〜約10重量%の量で存在する、請求項18に記載の照明弾を製造する方法。The boron is present in an amount of about 5% to about 30% by weight, potassium nitrate is present in an amount of about 40% to about 90% by weight, and the binder is in an amount of about 2% to about 10% by weight. 19. A method of manufacturing a lighting bullet as claimed in claim 18 present. 押出成形可能な点火用組成物がさらに、成分の1つとして、硝酸グアニジンを含んでなる請求項18に記載の照明弾を製造する方法。The method for producing a light bullet according to claim 18, wherein the extrudable ignition composition further comprises guanidine nitrate as one of the components.
JP2000508631A 1997-09-04 1998-07-22 Illumination bullet with igniter prepared from an extrudable igniter composition Expired - Lifetime JP4057779B2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US5750197P 1997-09-04 1997-09-04
US60/057,501 1997-09-04
US09/119,518 US6170399B1 (en) 1997-08-30 1998-07-21 Flares having igniters formed from extrudable igniter compositions
US09/119,518 1998-07-21
PCT/US1998/015064 WO1999011587A1 (en) 1997-09-04 1998-07-22 Flares having igniters formed from extrudable igniter compositions

Publications (3)

Publication Number Publication Date
JP2003524743A JP2003524743A (en) 2003-08-19
JP2003524743A5 true JP2003524743A5 (en) 2005-04-14
JP4057779B2 JP4057779B2 (en) 2008-03-05

Family

ID=26736572

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000508631A Expired - Lifetime JP4057779B2 (en) 1997-09-04 1998-07-22 Illumination bullet with igniter prepared from an extrudable igniter composition

Country Status (10)

Country Link
EP (1) EP1015401B1 (en)
JP (1) JP4057779B2 (en)
KR (1) KR100545187B1 (en)
CN (1) CN100537492C (en)
AU (1) AU750304B2 (en)
BR (1) BR9812622A (en)
CA (1) CA2302359C (en)
DE (1) DE69828068T2 (en)
IL (1) IL134859A (en)
WO (1) WO1999011587A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7469640B2 (en) 2006-09-28 2008-12-30 Alliant Techsystems Inc. Flares including reactive foil for igniting a combustible grain thereof and methods of fabricating and igniting such flares
EP2305624B1 (en) * 2009-10-01 2017-09-27 Maxamcorp Holding, S.L. Self-degradable explosive device
CN102320906B (en) * 2011-08-16 2013-03-06 湖北三江航天江河化工科技有限公司 Amide-type aid and preparation method thereof
CN110325814B (en) * 2016-12-01 2022-07-22 巴泰勒纪念研究所 Self-luminous material, tracer ammunition and lighting device
US10557696B2 (en) 2016-12-01 2020-02-11 Battelle Memorial Institute Self-glowing materials and tracer ammunition
JP7379142B2 (en) * 2019-12-23 2023-11-14 株式会社トクヤマ Metal nitride manufacturing method, igniter and igniter molded body
JP7312690B2 (en) * 2019-12-23 2023-07-21 株式会社トクヤマ Method for producing metal nitride, and ignition agent compact

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB566786A (en) * 1941-06-13 1945-01-15 Hugh Charles Hebard Improvements in or relating to fuzes for bombs, projectiles and the like
CH240427A (en) * 1943-05-28 1945-12-31 Siefvert & Fornander Ab Ignition means.
US2416639A (en) * 1944-07-08 1947-02-25 Ensign Bickford Co Slow-burning powder composition
US3257801A (en) * 1962-07-09 1966-06-28 North American Aviation Inc Pyrotechnic composition comprising solid oxidizer, boron and aluminum additive and binder
US3338764A (en) * 1965-08-19 1967-08-29 Du Pont Flexible detonating compositions containing high explosives and polymeric metallocarboxylates
GB1231181A (en) * 1967-05-05 1971-05-12
DE1771943C2 (en) * 1968-08-05 1975-03-27 Dynamit Nobel Ag, 5210 Troisdorf Ignition kit for propellants and rocket propellants
US3644602A (en) * 1968-08-05 1972-02-22 Fmc Corp Process for producing trialkyl phosphates
ZA734400B (en) * 1973-06-28 1975-02-26 African Explosives & Chem Improvements in the manufacture of safety fuse
US4220087A (en) * 1978-11-20 1980-09-02 Explosive Technology, Inc. Linear ignition fuse
DE3243425A1 (en) * 1982-11-24 1984-05-24 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München Igniter for propellant charges
SE460848B (en) * 1987-09-29 1989-11-27 Bofors Ab SET TO MAKE PYROTECHNICAL PRE-DRAWING AND RUNNING KITS
DE9416123U1 (en) * 1994-10-06 1994-12-08 Buck Werke GmbH & Co, 73337 Bad Überkingen Pyrotechnic pest control device
US5540154A (en) * 1995-06-06 1996-07-30 Oea Aerospace, Inc. Non-pyrolizing linear ignition fuse
US5610364A (en) * 1995-06-30 1997-03-11 Thiokol Corporation Nozzle plug for plume enhancement in a kinematic flare

Similar Documents

Publication Publication Date Title
CA2556595C (en) Priming mixtures for small arms
CA1061566A (en) Illuminating pyrotechnic composition
KR100318338B1 (en) Ignition Composition for Expansion Gas Generators
US6170399B1 (en) Flares having igniters formed from extrudable igniter compositions
US6997998B2 (en) Lead-and barium-free propellant charges
BR112012025036B1 (en) non-toxic heavy metal-free explosive sensitivity initiators and methods of preparing the same
CN1179928C (en) Primer mixture without toxicity
JP6059018B2 (en) Method for preparing a pyrotechnic composition, pyrotechnic composition, method for preparing a pyrotechnic, pyrotechnic, use of pyrotechnic and mixture for pyrotechnic
BG61604B1 (en) Non-toxic detonator mixtures
JP2003524743A5 (en)
KR100450704B1 (en) Automatically ignitable enhancer agent composition
EP1993978A1 (en) Ignition composition and applications
US5917146A (en) High-nitrogen energetic material based pyrotechnic compositions
TW589292B (en) Method for manufacturing explosive composition for fireworks
US6165294A (en) Pyrotechnical percussion combustion composition for small arms ammunition primers
JP4057779B2 (en) Illumination bullet with igniter prepared from an extrudable igniter composition
WO1986002347A1 (en) Explosive composition and method
USH285H (en) Oxygen rich igniter compositions
JPH07232987A (en) Igniter and its production
US3865008A (en) Manufacture of fuse heads
US456508A (en) Alfred nobel
AU577560B2 (en) Explosive composition and method
Young MILITARY EXPLOSIVES OF TO-DAY. Lecture II
BG64003B1 (en) Pyrotechnic smoke-forming composition
UA8430U (en) Pyrotechnical firework composition of green fire