JP2003290782A - Catalytic reaction apparatus - Google Patents
Catalytic reaction apparatusInfo
- Publication number
- JP2003290782A JP2003290782A JP2002097017A JP2002097017A JP2003290782A JP 2003290782 A JP2003290782 A JP 2003290782A JP 2002097017 A JP2002097017 A JP 2002097017A JP 2002097017 A JP2002097017 A JP 2002097017A JP 2003290782 A JP2003290782 A JP 2003290782A
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- Prior art keywords
- catalyst
- guide plate
- inclined guide
- treatment tank
- catalytic reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、過酸化水素等の水
溶性過酸化物を含有する排水を処理する触媒反応装置に
関する。TECHNICAL FIELD The present invention relates to a catalytic reactor for treating wastewater containing a water-soluble peroxide such as hydrogen peroxide.
【０００２】[0002]
【従来の技術】水溶性過酸化物を含有する排水、例えば
食品製造装置の殺菌等に用いられる過酢酸を含有する排
水や、半導体製造工程により排出される過酸化水素を含
有する排水は、従来から、活性炭や酸化マンガン粒子等
の粒状触媒を用いた還元処理が行われている。2. Description of the Related Art Wastewater containing water-soluble peroxide, for example, wastewater containing peracetic acid used for sterilization of food manufacturing equipment, and wastewater containing hydrogen peroxide discharged from semiconductor manufacturing processes have been conventionally used. Therefore, reduction treatment using a granular catalyst such as activated carbon or manganese oxide particles is performed.
【０００３】このような粒状の触媒を用いた触媒反応装
置には、例えば、特開平６−９１２５８号公報、特開平
１１−１９７６８４号公報、特開２０００−１３５４９
２号公報等に記載のものが知られている。これらの公報
に記載の触媒反応装置は、処理槽内に触媒からなる触媒
層を備えており、排水をこの触媒層に通すことで排水中
の過酸化物を分解させ、発生する酸素ガスを処理槽から
放散させると共に、処理水を処理槽から流出させるよう
になっている。Catalytic reactors using such granular catalysts include, for example, JP-A-6-91258, JP-A-11-197684, and JP-A-2000-13549.
Those described in Japanese Patent No. 2 etc. are known. The catalytic reactors described in these publications are provided with a catalyst layer made of a catalyst in a treatment tank, and decompose the peroxide in the wastewater by passing the wastewater through the catalyst layer to treat the oxygen gas generated. The water is discharged from the tank and the treated water is allowed to flow out from the tank.
【０００４】[0004]
【発明が解決しようとする課題】上述したような公報記
載の触媒反応装置では、反応効率を考慮して触媒は固定
せず、流動化させている。このため、触媒が処理水に随
伴するので、触媒、処理水及び発生ガスを分離が困難で
あり、また、触媒が処理水と共に排出された場合には、
触媒を回収するために別個の濾過装置（回収装置）が必
要である、という問題点があった。In the catalytic reaction apparatus described in the above publication, the catalyst is not fixed but fluidized in consideration of reaction efficiency. Therefore, since the catalyst accompanies the treated water, it is difficult to separate the catalyst, the treated water and the generated gas, and when the catalyst is discharged together with the treated water,
There is a problem that a separate filtration device (collection device) is required to recover the catalyst.
【０００５】本発明はかかる問題点を解決することので
きる触媒型の触媒反応装置を提供することを目的として
いる。An object of the present invention is to provide a catalyst type catalytic reaction apparatus which can solve the above problems.
【０００６】[0006]
【課題を解決するための手段】上記目的を達成するため
に、本発明は、過酸化物を含有する排水を触媒に通し過
酸化物を還元処理するための触媒反応装置において、処
理槽と、処理槽内の中間部分に形成された、粒状の触媒
からなる触媒層と、処理槽内の、触媒層よりも下方の下
部部分に配置され、排水を処理槽内に導入する排水導入
管と、処理槽内の、触媒層よりも上方の上部部分に配置
され、下端部が処理槽の内面との間に所定の間隙を形成
するよう配置された傾斜案内板であって、触媒層からの
処理水及び触媒層の還元処理により発生するガスを受け
て上方に案内する案内経路を画成する傾斜案内板と、一
端が処理槽の内面に固定され他端が傾斜案内板の下端部
よりも下方であって、前記下端部と同じ水平位置又はそ
れよりも前記処理槽の内側に、離隔配置されている傾斜
バッフル板であって、前記一端から前記他端にかけて下
方に傾斜している傾斜バッフル板とを備えることを特徴
としている。In order to achieve the above object, the present invention provides a catalytic reaction apparatus for reducing peroxide by passing wastewater containing peroxide through a catalyst, and a treatment tank, A catalyst layer formed in the middle part of the treatment tank, which is composed of a granular catalyst, and a wastewater introduction pipe which is disposed in a lower portion of the treatment tank below the catalyst layer and introduces wastewater into the treatment tank, An inclined guide plate that is disposed in an upper portion of the treatment tank above the catalyst layer and has a lower end portion that forms a predetermined gap with the inner surface of the treatment tank. An inclined guide plate that defines a guide path that guides upward by receiving water and gas generated by the reduction treatment of the catalyst layer, and one end fixed to the inner surface of the processing tank and the other end lower than the lower end of the inclined guide plate. And the same horizontal position as the lower end portion or the treatment Inside of a slanted baffle plate being spaced, is characterized in that it comprises an inclined baffle plate which is inclined downward toward the other end from the one end.
【０００７】かかる構成においては、傾斜案内板の内外
で処理水の密度差が生じ、傾斜案内板の案内経路を通過
した触媒含有処理水は、傾斜案内板の下方に流れていこ
うとする。この作用により、触媒は傾斜案内板の下方に
回収されて触媒層に戻り、外部に排出されることはな
い。In such a construction, a difference in density of treated water occurs inside and outside the inclined guide plate, and the catalyst-containing treated water that has passed through the guide path of the inclined guide plate tries to flow below the inclined guide plate. Due to this action, the catalyst is recovered below the inclined guide plate, returns to the catalyst layer, and is not discharged to the outside.
【０００８】なお、傾斜案内板は、下方ほど拡径された
逆漏斗形状とし、処理槽内に同軸に配置することが好ま
しい。It is preferable that the inclined guide plate has an inverted funnel shape in which the diameter is increased toward the lower side and is coaxially arranged in the processing tank.
【０００９】また、傾斜案内板の上方に所定の間隔を置
いて傾斜板を配置することも有効である。傾斜板と傾斜
案内板との間に流路を形成することで、触媒を伴う処理
水を確実に下方に案内することができるからである。It is also effective to dispose the inclined plates above the inclined guide plates with a predetermined space. By forming the flow path between the inclined plate and the inclined guide plate, the treated water accompanied by the catalyst can be surely guided downward.
【００１０】[0010]
【発明の実施の形態】以下、図面を参照して本発明の好
適な実施形態について詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings.
【００１１】図１は、本発明による触媒反応装置の一実
施形態を示す概略断面図である。この触媒反応装置１０
は、食品製造工程で生じた過酢酸を含む排水、半導体製
造工程や超純粋設備の配管洗浄工程において生じた過酸
化水素を含む排水、有機物酸化分解のために酸化剤（過
酸化水素、オゾン、次亜塩素酸ソーダ等）を注入する処
理工程において生じた、目的物の処理後に残留する酸化
剤を含有する排水等、種々の過酸化物が溶融した排水を
処理するのに適用可能なものである。FIG. 1 is a schematic sectional view showing an embodiment of the catalytic reaction apparatus according to the present invention. This catalytic reaction device 10
Is a wastewater containing peracetic acid generated in a food manufacturing process, a wastewater containing hydrogen peroxide generated in a semiconductor manufacturing process or a pipe cleaning process of ultrapure equipment, and an oxidizer (hydrogen peroxide, ozone, It can be applied to treat wastewater containing various oxidizing agents, such as wastewater containing oxidizer remaining after the treatment of the object, which is generated in the treatment process of injecting sodium hypochlorite, etc. is there.
【００１２】図１に示すように、この触媒反応装置１０
は、装置本体として略円筒形の処理槽１２を備えてい
る。この処理槽１２の頂部には、還元処理により発生す
る酸素が放散されるガス口１４が形成されている。As shown in FIG. 1, this catalytic reactor 10
Is provided with a substantially cylindrical processing tank 12 as an apparatus main body. A gas port 14 is formed at the top of the processing tank 12 to release oxygen generated by the reduction process.
【００１３】処理槽１２の下部部分には、排水を処理槽
１２の内部に導入するための排水導入管１６が略水平に
配置されている。排水導入管１６の下面側には多数の小
孔が形成されており、排水が処理槽１２の内部に可能な
限り均等に分配供給されるようになっている。なお、図
１においては、排水導入管１６は１本の直管の如く示さ
れているが、例えば、排水が送り込まれる１本の主管
と、この主管から分岐して延びる複数本の副管とからな
るものが、より均等に排水を導入することができるので
好ましい。また、排水導入管は、螺旋状や円板状のもの
であってもよい。At the lower portion of the treatment tank 12, a wastewater introduction pipe 16 for introducing wastewater into the treatment tank 12 is arranged substantially horizontally. A large number of small holes are formed on the lower surface side of the waste water introduction pipe 16 so that the waste water is distributed and supplied into the treatment tank 12 as uniformly as possible. Although the drainage introduction pipe 16 is shown as one straight pipe in FIG. 1, for example, one main pipe into which drainage is sent and a plurality of sub-pipes branched from the main pipe and extended. What is consisted of is preferable because the wastewater can be introduced more uniformly. Further, the drainage introducing pipe may have a spiral shape or a disc shape.
【００１４】処理槽１２の下部部分には砂利が充填され
ている。この砂利層１８では、砂利間に比較的大きな空
間が形成されるので、排水導入管１６からの排水は砂利
層１８を通り処理槽１２の上方へと流れることができ
る。The lower part of the processing tank 12 is filled with gravel. Since a relatively large space is formed between the gravel layers 18 in the gravel layer, the drainage water from the drainage introduction pipe 16 can flow through the gravel layer 18 and above the treatment tank 12.
【００１５】処理槽１２の中間部分には、粒状の活性炭
や酸化マンガン粒子等の粒状触媒が充填され、これによ
り触媒層２０が形成されている。触媒層２０は砂利層１
８の上に配置され、砂利層１８は触媒層２０の支持層と
して機能する。なお、触媒が活性炭の場合、約２ｍｍ程
度の粒径のものが還元反応に適していることが判ってい
る。A granular catalyst such as granular activated carbon or manganese oxide particles is filled in the middle portion of the processing tank 12, and a catalyst layer 20 is formed by this. The catalyst layer 20 is the gravel layer 1
The gravel layer 18 functions as a support layer for the catalyst layer 20. In addition, when the catalyst is activated carbon, it is known that a particle having a particle size of about 2 mm is suitable for the reduction reaction.
【００１６】更に、処理槽１２の上部部分には傾斜案内
板２２が配設されている。この傾斜案内板２２は、その
中間部分が下方ほど内径が大きくなっている逆漏斗形な
いしは略切頭円錐形の傾斜部分２４となっている。ま
た、傾斜案内板２２の下部部分は円筒部分２６となって
いる。この円筒部分２６の外径は処理槽１２の内径より
も小さい、傾斜案内板の上部部分は前記円筒部分２６よ
りも小径の円筒部分２８となっている。このような傾斜
案内板２２は処理槽１２内に同軸に配置され、その下端
部は触媒層２０に対向して配置され且つ処理槽１２の内
周面との間に環状間隙を形成する。Further, an inclined guide plate 22 is arranged on the upper portion of the processing tank 12. The inclined guide plate 22 is an inverted funnel-shaped or substantially frusto-conical inclined portion 24 having an inner diameter that increases toward the bottom. The lower portion of the inclined guide plate 22 is a cylindrical portion 26. The outer diameter of the cylindrical portion 26 is smaller than the inner diameter of the processing tank 12, and the upper portion of the inclined guide plate is a cylindrical portion 28 having a smaller diameter than the cylindrical portion 26. Such an inclined guide plate 22 is coaxially arranged in the processing tank 12, and its lower end portion is arranged so as to face the catalyst layer 20 and forms an annular gap with the inner peripheral surface of the processing tank 12.
【００１７】傾斜案内板２２の下端部と処理槽１２の内
周面との間の間隙には、傾斜バッフル板３０が配置され
ている。この傾斜バッフル板３０は環状板であり、内側
ほど下方に傾斜している。傾斜バッフル板３０の外側端
部（外縁）は処理槽１２の内周面に固着されている。ま
た、傾斜バッフル板３０の内径は、傾斜案内板２２の下
端部、すなわち下部円筒部分２６の外径と同一、好まし
くは下部円筒部分２６の内径よりも小さい。そして、傾
斜バッブル板３０の内側部分が傾斜案内板２２の下端部
よりも下方に僅かな間隙をもって離隔配置されている。An inclined baffle plate 30 is arranged in the gap between the lower end of the inclined guide plate 22 and the inner peripheral surface of the processing tank 12. The inclined baffle plate 30 is an annular plate and is inclined downward toward the inside. The outer end (outer edge) of the inclined baffle plate 30 is fixed to the inner peripheral surface of the processing tank 12. The inner diameter of the inclined baffle plate 30 is the same as the lower end of the inclined guide plate 22, that is, the outer diameter of the lower cylindrical portion 26, and preferably smaller than the inner diameter of the lower cylindrical portion 26. The inner portion of the slanted bobble plate 30 is disposed below the lower end of the slanted guide plate 22 with a slight gap.
【００１８】また、処理槽１２の内周面の上部にはトラ
フ（樋状部材）３２が設けられており、このトラフ３２
は処理槽１２の側壁に形成された処理水取出口３４に連
通している。このトラフ３２の垂直部分３３の上端は、
傾斜案内板２２の上端、すなわち円筒部分の２８の上端
よりも僅かに高い位置にある。これによって、処理槽１
２内で処理水が増加すると、その処理水はトラフ３２の
垂直部分３３を越え、処理水取出口３４から外部に流出
する。そして、処理槽１２内の水位は、排水が導入され
続けている限り、垂直部分３３の上端と同一高さとな
り、傾斜案内板２２の上端は処理水に完全に浸漬された
状態となる。A trough (gutter-shaped member) 32 is provided on the upper part of the inner peripheral surface of the processing tank 12, and the trough 32 is provided.
Communicates with a treated water outlet 34 formed on the side wall of the treatment tank 12. The upper end of the vertical portion 33 of the trough 32 is
It is located slightly higher than the upper end of the inclined guide plate 22, that is, the upper end of the cylindrical portion 28. As a result, the processing tank 1
When the amount of the treated water increases in 2, the treated water flows over the vertical portion 33 of the trough 32 and flows out through the treated water outlet 34. The water level in the treatment tank 12 is at the same height as the upper end of the vertical portion 33 as long as the drainage is continuously introduced, and the upper end of the inclined guide plate 22 is completely immersed in the treated water.
【００１９】本実施形態の触媒反応装置１０は、更に、
傾斜案内板２２の上方に配置された傾斜板３６を備えて
いる。この傾斜板３６は、傾斜案内板２２の傾斜部分２
４と略平行に離隔配置された略切頭円錐形の傾斜部分３
８と、この傾斜部分３８の上端から垂直上方に延び、傾
斜案内板２２の上部円筒部分２８を間隙をもって囲む円
筒部分４０とから構成されている。円筒部分４０の上端
は、トラフ３２の垂直部分３３の上端よりも高い位置に
配置されている。The catalytic reaction device 10 of the present embodiment further includes
The tilting plate 36 is provided above the tilting guide plate 22. This inclined plate 36 is the inclined portion 2 of the inclined guide plate 22.
4 is a substantially frustoconical inclined portion 3 which is spaced apart substantially in parallel with 4
8 and a cylindrical portion 40 extending vertically upward from the upper end of the inclined portion 38 and surrounding the upper cylindrical portion 28 of the inclined guide plate 22 with a gap. The upper end of the cylindrical portion 40 is located higher than the upper end of the vertical portion 33 of the trough 32.
【００２０】このような構成おいて、過酸化物を含有す
る排水を排水導入管１６を経て処理槽１２内に導入する
と、その排水は砂利槽１８を通り触媒層２０へと上昇し
ていく。排水は触媒層２０において触媒と接触し、排水
中の過酸化物は分解反応を起こし、発生した酸素ガスは
触媒層２０を通過して処理槽１２の上部部分に浮上す
る。この際、触媒層２０の触媒は固定されていないの
で、流動状態にあり、排水との接触効率が良好であり、
よって分解反応も効率よく行われる。When the waste water containing the peroxide is introduced into the treatment tank 12 through the waste water introducing pipe 16 with such a structure, the waste water rises to the catalyst layer 20 through the gravel tank 18. The wastewater comes into contact with the catalyst in the catalyst layer 20, the peroxide in the wastewater causes a decomposition reaction, and the generated oxygen gas passes through the catalyst layer 20 and floats to the upper portion of the processing tank 12. At this time, since the catalyst of the catalyst layer 20 is not fixed, it is in a fluidized state and has a good contact efficiency with the drainage,
Therefore, the decomposition reaction is also efficiently performed.
【００２１】過酸化物の触媒による分解反応処理が行わ
れた排水は触媒層２０を上昇し、処理水として処理槽１
２の上部部分に至る。この処理水には、前述の酸素ガス
と、粒状触媒が随伴される。触媒と酸素ガスを含む処理
水は、処理槽１２の上部部分内の傾斜案内板２２の下端
部からその内部に流入する。この際、傾斜バッフル板３
０の存在により、触媒・ガス含有処理水は、傾斜案内板
２２の外側を通ことはなく、確実に傾斜案内板２２の内
部に誘導される。そして、傾斜案内板２２の内部の案内
経路に沿って処理水は上昇していき、酸素ガスは傾斜案
内板２２の上端部から放散され、処理槽１２のガス口１
４から外部に放出される。Wastewater which has been decomposed by a catalyst of peroxide rises in the catalyst layer 20 and is treated as treated water in the treatment tank 1.
To the upper part of 2. This treated water is accompanied by the oxygen gas and the granular catalyst. The treated water containing the catalyst and oxygen gas flows into the inside of the upper portion of the treatment tank 12 from the lower end portion of the inclined guide plate 22. At this time, the inclined baffle plate 3
Due to the presence of 0, the catalyst / gas-containing treated water does not pass through the outside of the inclined guide plate 22 and is reliably guided to the inside of the inclined guide plate 22. Then, the treated water rises along the guide path inside the inclined guide plate 22, oxygen gas is diffused from the upper end portion of the inclined guide plate 22, and the gas port 1 of the treatment tank 12 is discharged.
4 is released to the outside.
【００２２】一方、ガスが抜けた処理水は、触媒を伴っ
た状態で、傾斜案内板２２の上端部から処理槽１２のト
ラフ３２に向かって外方に進もうとするが、傾斜板３６
の存在により、処理槽１２の内周面に向かって下方に偏
向される。On the other hand, the treated water from which the gas has escaped tries to move outward from the upper end of the inclined guide plate 22 toward the trough 32 of the treatment tank 12 with the catalyst, but the inclined plate 36.
Due to the existence of the above, the downward deflection is made toward the inner peripheral surface of the processing tank 12.
【００２３】ここで、傾斜案内板２２の内側と外側とで
はガスの有無の違いにより処理水に密度差が生じてい
る。すなわち、傾斜案内板２２の内側における処理水の
密度は、外側の処理水の密度よりも小さい。その結果と
して、傾斜案内板２２の上端部から流出した処理水は、
傾斜バッフル板３０と傾斜案内板２２の下端部との間の
間隙を介して傾斜案内板２２内側へと流れようとする。
また、上述したように傾斜板３６が設けられているため
に、触媒を含む処理水は、より確実に傾斜バッフル板３
０と傾斜案内板２２の下端部との間の間隙に案内され
る。Here, there is a density difference in the treated water between the inside and outside of the inclined guide plate 22 due to the presence or absence of gas. That is, the density of the treated water inside the inclined guide plate 22 is smaller than the density of the treated water outside. As a result, the treated water flowing out from the upper end of the inclined guide plate 22 is
The inclined baffle plate 30 and the lower end portion of the inclined guide plate 22 tend to flow toward the inside of the inclined guide plate 22 through the gap.
Further, since the inclined plate 36 is provided as described above, the treated water containing the catalyst can be more reliably supplied to the inclined baffle plate 3.
0 and the lower end of the inclined guide plate 22 are guided in the gap.
【００２４】このようにして処理水中に随伴した触媒は
傾斜案内板２２の下方に集められるので、やがて自重に
より触媒層２０に戻る。一方、触媒を含まない処理水の
上澄み水がトラフ３２から取出口３４を通って外部に排
出される。The catalyst thus entrained in the treated water is collected below the inclined guide plate 22, and eventually returns to the catalyst layer 20 by its own weight. On the other hand, the supernatant water of the treated water containing no catalyst is discharged from the trough 32 to the outside through the outlet 34.
【００２５】以上、本発明の好適な実施形態について詳
細に説明したが、本発明は上記実施形態に限定されない
ことはいうまでもない。The preferred embodiments of the present invention have been described above in detail, but it goes without saying that the present invention is not limited to the above embodiments.
【００２６】例えば、上記実施形態では、傾斜案内板２
２の上方に傾斜板３６を設けているが、この傾斜板３６
は必須のものではない。For example, in the above embodiment, the inclined guide plate 2
2 is provided above the slant plate 36.
Is not mandatory.
【００２７】また、傾斜案内板２２の形状等についても
上記実施形態のものに限られない。The shape of the inclined guide plate 22 is not limited to that of the above embodiment.
【００２８】[0028]
【発明の効果】以上述べたように、本発明によれば、触
媒、発生ガス及び処理水を触媒反応装置内で確実に分離
させることができ、触媒は触媒反応装置内に残し、処理
水及びガスは外部に排出することができる。よって、触
媒回収用の濾過装置等を別個に設ける必要がなく、排水
処理施設のスペースを小さくすることができ、また、触
媒回収に伴う手間も解消することができる。As described above, according to the present invention, the catalyst, the generated gas, and the treated water can be reliably separated in the catalytic reaction device, and the catalyst remains in the catalytic reaction device and the treated water and The gas can be discharged to the outside. Therefore, it is not necessary to separately provide a filter device or the like for recovering the catalyst, the space of the wastewater treatment facility can be reduced, and the trouble associated with recovering the catalyst can be eliminated.
【図１】本発明による触媒反応装置を示す概略断面図で
ある。FIG. 1 is a schematic sectional view showing a catalytic reactor according to the present invention.
１０…触媒反応装置、１２…処理槽、１４…ガス口、１
６…排水導入管、１８…砂利層、２０…触媒層、２２…
傾斜案内板、３０…傾斜バッフル板、３２…トラフ、３
４…処理水取出口、３６…傾斜板。10 ... Catalytic reaction device, 12 ... Treatment tank, 14 ... Gas port, 1
6 ... Wastewater introduction pipe, 18 ... Gravel layer, 20 ... Catalyst layer, 22 ...
Inclined guide plate, 30 ... Inclined baffle plate, 32 ... Trough, 3
4 ... Treated water outlet, 36 ... Inclined plate.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4D038 AA08 AB09 AB26 AB27 AB39 BA02 BB20 4G070 AA03 AB01 AB06 BA08 BB05 BB32 CA09 CA13 CA17 CB19 ─────────────────────────────────────────────────── ─── Continued front page F-term (reference) 4D038 AA08 AB09 AB26 AB27 AB39 BA02 BB20 4G070 AA03 AB01 AB06 BA08 BB05 BB32 CA09 CA13 CA17 CB19
Claims (3)
記過酸化物を還元処理するための触媒反応装置であっ
て、 処理槽と、 前記処理槽内の中間部分に形成された、粒状の触媒から
なる触媒層と、 前記処理槽内の、前記触媒層よりも下方の下部部分に配
置され、前記排水を前記処理槽内に導入する排水導入管
と、 前記処理槽内の、前記触媒層よりも上方の上部部分に配
置され、下端部が前記処理槽の内面との間に所定の間隙
を形成するよう配置された傾斜案内板であって、前記触
媒層からの処理水及び前記触媒層の還元処理により発生
するガスを受けて上方に案内する案内経路を画成する前
記傾斜案内板と、 一端が前記処理槽の内面に固定され、他端が前記傾斜案
内板の前記下端部よりも下方であって、前記下端部と同
じ水平位置又はそれよりも前記処理槽の内側に、離隔配
置されている傾斜バッフル板であって、前記一端から前
記他端にかけて下方に傾斜している前記傾斜バッフル板
とを備える触媒反応装置。1. A catalytic reaction device for reducing the peroxide by passing wastewater containing the peroxide through a catalyst, the granular material being formed in a treatment tank and an intermediate portion in the treatment tank. A catalyst layer composed of the catalyst of, a wastewater introduction pipe that is disposed in a lower portion of the treatment tank below the catalyst layer and that introduces the wastewater into the treatment tank, and the catalyst in the treatment tank. An inclined guide plate arranged in an upper portion above the bed, the lower end portion being arranged to form a predetermined gap with the inner surface of the treatment tank, the treated water from the catalyst layer and the catalyst. The inclined guide plate defining a guide path for guiding upward by receiving gas generated by the layer reduction process; one end fixed to the inner surface of the processing tank and the other end from the lower end of the inclined guide plate. Is at the same horizontal position as the lower end or Inside the remote the processing bath, a slanted baffle plate being spaced a catalytic reactor and a the inclined baffle plate which is inclined downward toward the other end from the one end.
逆漏斗形状であり、前記処理槽内に同軸に配置されてい
ることを特徴とする請求項１に記載の触媒反応装置。2. The catalytic reaction device according to claim 1, wherein the inclined guide plate has an inverted funnel shape in which the diameter is increased toward the lower side, and is arranged coaxially in the processing tank.
いて配置された傾斜板を更に備える請求項１又は２に記
載の触媒反応装置。3. The catalytic reaction device according to claim 1, further comprising an inclined plate disposed above the inclined guide plate with a predetermined interval.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002097017A JP2003290782A (en) | 2002-03-29 | 2002-03-29 | Catalytic reaction apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002097017A JP2003290782A (en) | 2002-03-29 | 2002-03-29 | Catalytic reaction apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003290782A true JP2003290782A (en) | 2003-10-14 |
Family
ID=29239784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002097017A Pending JP2003290782A (en) | 2002-03-29 | 2002-03-29 | Catalytic reaction apparatus |
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| Country | Link |
|---|---|
| JP (1) | JP2003290782A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008246341A (en) * | 2007-03-29 | 2008-10-16 | Hiroshima Univ | Fluid supply apparatus and system provided with the same |
| JP2013233506A (en) * | 2012-05-09 | 2013-11-21 | Swing Corp | Method and apparatus for treating peracetic acid-containing wastewater |
| CN113683153A (en) * | 2021-08-06 | 2021-11-23 | 沈阳工业大学 | Device for treating waste water by utilizing photocatalytic reaction |
| CN114917810A (en) * | 2022-05-13 | 2022-08-19 | 江苏妙卫纸业有限公司 | Mixing arrangement is used in household paper production |
-
2002
- 2002-03-29 JP JP2002097017A patent/JP2003290782A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008246341A (en) * | 2007-03-29 | 2008-10-16 | Hiroshima Univ | Fluid supply apparatus and system provided with the same |
| JP2013233506A (en) * | 2012-05-09 | 2013-11-21 | Swing Corp | Method and apparatus for treating peracetic acid-containing wastewater |
| CN113683153A (en) * | 2021-08-06 | 2021-11-23 | 沈阳工业大学 | Device for treating waste water by utilizing photocatalytic reaction |
| CN114917810A (en) * | 2022-05-13 | 2022-08-19 | 江苏妙卫纸业有限公司 | Mixing arrangement is used in household paper production |
| CN114917810B (en) * | 2022-05-13 | 2023-02-28 | 江苏妙卫纸业有限公司 | Mixing arrangement is used in household paper production |
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