JP2003284510A - Composition having anti-alcohol property, anti-acidity and anti-salt property and use of the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a composition maintaining a stable solubilized, emulsified and dispersed condition and having excellent anti-alcohol property, anti-acidity and anti-salt property each required when added to drinks and food by solubilizing, emulsifying or dispersing a water-insoluble substance in alcohol- containing drinks and food. <P>SOLUTION: This solubilized, emulsified, or dispersed composition is obtained by formulating (A) polyglyceryl fatty acid ester, (B) sucrose fatty acid ester, (C) the water-insoluble substance and (D) water or multivalent alcohol. The composition having anti-alcohol property is such that the change by particle size measurement with a laser from (1) the particle size of the composition to (2) the particle size thereof two days after being added to a 20% alcohol solution is (a) less than ±10 nm when the particle size of the composition is below 100 nm and (b) less than ±10% when the particle size of the composition is more than 100 nm. <P>COPYRIGHT: (C)2004,JPO

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a composition obtained by solubilizing, emulsifying or dispersing a water-insoluble substance, which has alcohol resistance, acid resistance and salt resistance. It also relates to beverages and foods containing the composition.

[0002]

2. Description of the Related Art Heretofore, in order to enhance the stability of alcoholic beverages, Japanese Patent Application Laid-Open No. 8-173135 discloses a technique of using microcrystalline cellulose as a dispersant for fruit fibers and calcium carbonate. However, the liquid substance was not stably dispersed. In addition, JP-A-5
-219885 discloses the use of sucrose palmitate and / or sucrose stearate,
Techniques for stabilizing cream liquor compositions are disclosed. However, the cream liquor composition has not been stabilized under strongly acidic conditions such as fruit juice drinks or under conditions of high salt concentration. Further, Japanese Patent Application Laid-Open No. 7-241458 discloses a technique for stably emulsifying a drug in an aqueous solution containing 5 to 80% by weight of alcohol, but as an emulsifier, polyoxypropylene polyoxyethylene addition type surface active agent is used. It is not suitable for drinks and foods because it uses a drug. Further, Japanese Patent Laid-Open No. 2000-253817 discloses a preparation in which a sucrose fatty acid ester composition is mixed with alcohol or alcohol and water. However, precipitation of sucrose fatty acid ester in an aqueous solution in a wide pH range is disclosed. The effect is that it does not occur, and as an emulsifier, stable emulsification in an alcohol solution was not obtained. Further, JP-A-60-102139 discloses an alcohol-resistant composition using a polyglycerin fatty acid ester, which is a composition for kneading water when making udon noodles. The target was low alcohol concentration of about%, and a stable emulsion at high alcohol concentration was not obtained.

Therefore, in the prior art, a composition having excellent acid resistance and salt resistance required for addition to beverages and foods, and alcohol resistance, is used to solubilize a water-insoluble substance or No sufficiently satisfactory composition has been obtained as a composition for stably maintaining the emulsified or dispersed state.

[0004]

The first object of the present invention is to provide a composition in which a water-insoluble substance is solubilized or emulsified or dispersed by using a specific surfactant, so that a stable composition can be obtained. Another object of the present invention is to provide a composition which maintains excellent solubilization, emulsification and dispersion state and which has excellent alcohol resistance, acid resistance and salt resistance required when added to beverages and foods. A second object of the present invention is to provide a beverage or a food in which a water-insoluble substance is stably solubilized, emulsified and dispersed by blending the composition.

[0005]

Means for Solving the Problems The inventors of the present invention have completed the present invention as a result of extensive studies to solve the above problems. That is, the present invention is the following [1] to [19]. [1] (A) Polyglycerin fatty acid ester, (B)
Sucrose fatty acid ester, (C) water-insoluble substance, (D)
A composition which is solubilized, emulsified or dispersed by blending water or a polyhydric alcohol, wherein (a) the particle size of the composition and (b) the composition by the particle size measurement using a laser. The change in particle size after 2 days when added to a 20% alcohol solution is within ± 10 nm when the particle size of the composition (a) is less than 100 nm, and when the particle size of the composition (b) is 100 nm or more. A composition having an alcohol resistance of less than ± 10%. [2] The composition having alcohol resistance according to the above [1], further comprising particle size measurement using a laser,
(A) Particle size of the composition and (b) 1 when the composition was added to a citric acid aqueous solution having a pH of 3 and heated at 85 ° C. for 30 minutes
The change in particle size after day is (a) the particle size of the composition is 100 nm
A composition having an acid resistance of less than ± 10 nm when it is less than or less than ± 10% when the particle size of the composition (b) is 100 nm or more. [3] The composition having alcohol resistance according to the above [1], further comprising particle size measurement using a laser,
(A) The particle size of the composition, and (b) the composition was added to a 5% saline solution and heated for 1 hour at 85 ° C. If the diameter is less than 100 nm, it is within ± 10 nm, and the particle size of the composition (b) is 100 n.
A composition having a salt resistance of ± 10% or less when m or more. [4] The composition having alcohol resistance and acid resistance according to the above [2], further comprising: (a) a particle size of the composition measured by a particle size using a laser and (b) a composition. Add 5% saline solution adjusted to pH 3 with acid to 85
The change in particle size after 1 day when heated at ℃ for 30 minutes
(A) ± 10 when the particle size of the composition is less than 100 nm
A composition having a salt resistance of not more than 10 nm and within ± 10% when the particle diameter of the composition (b) is not less than 100 nm.

[5] By blending (A) polyglycerin fatty acid ester, (B) sucrose fatty acid ester, (E) organic acid monoglyceride, (C) water-insoluble substance, (D) water or polyhydric alcohol Which is a solubilized, emulsified or dispersed composition, wherein the particle size of (a) the composition and the (b) composition are 30% by particle size measurement using a laser.
The change in particle size after 2 days when added to the alcohol solution
(A) ± 10 when the particle size of the composition is less than 100 nm
The composition is within the range of nm, and within the range of ± 10% when the particle size of the composition (b) is 100 nm or more. [6] The composition having alcohol resistance according to the above [5], further comprising particle size measurement using a laser,
(A) Particle size of the composition and (b) 1 when the composition was added to a citric acid aqueous solution having a pH of 3 and heated at 85 ° C. for 30 minutes
The change in particle size after day is (a) the particle size of the composition is 100 nm
A composition having an acid resistance of less than ± 10 nm when it is less than or less than ± 10% when the particle size of the composition (b) is 100 nm or more. [7] The composition having alcohol resistance according to the above [5], further comprising particle size measurement using a laser,
(A) The particle size of the composition and (b) The composition of (a) composition changes after one day when the composition is added to a 5% saline solution and heated at 85 ° C. for 30 minutes. If the diameter is less than 100 nm, it is within ± 10 nm, and the particle size of the composition (b) is 100 n.
A composition having a salt resistance of ± 10% or less when m or more. [8] The composition having alcohol resistance and acid resistance according to the above [6], wherein the particle size of the (a) composition and the (b) composition are citric acid measured by particle size measurement using a laser. Was added to a 5% saline solution adjusted to pH 3 with a solution of
The change in particle size after 1 day when heated for 0 minutes is (a)
Within ± 10 nm when the particle size of the composition is less than 100 nm, and within ± 10 nm when the particle size of the composition (b) is 100 nm or more.
A composition having a salt resistance of 10% or less.

[9] 1 to 50% by weight of the component (A), 0.5 to 15% by weight of the component (B), 0.1 to 40% by weight of the water-insoluble substance of the component (C), Component (D) containing water or a polyhydric alcohol of 95% by weight or less
The composition according to any one of [1] to [4]. [10] 1 to 50% by weight of component (A), 0.5 to 15% by weight of component (B), 0.1 to 40% by weight of water-insoluble substance of component (C), (D) Component water or polyhydric alcohol 95% by weight or less, component (E) emulsifier 0.1
The composition according to any one of the above [5] to [8], containing 10 to 10% by weight. [11] The above-mentioned [1] wherein the emulsifier of the component (A) is one or more polyglycerin fatty acid ester selected from a mono- or diester with a fatty acid having a polymerization degree of 5 to 15 and a carbon number of 8 to 22. ~ The composition according to any one of [10]. [12] The emulsifier of the component (B) is a sucrose fatty acid ester containing 70% by weight or more of a monoester of one or more fatty acids selected from fatty acids having 8 to 22 carbon atoms and sucrose. The composition according to any one of 1] to [10]. [13] The non-water-soluble substance of the component (C) includes fats and oils, oil-soluble vitamins, oil-soluble flavors, lipids, and coenzyme Q10,
The composition according to any one of [1] to [10] above, which is a substance insoluble or hardly soluble in water. [14] The composition according to any one of the above [1] to [10], wherein the substance of the component (D) is a polyhydric alcohol such as water and liquid sugar. [15] The composition according to any one of [5] to [8] or [10], wherein the emulsifier of the component (E) is an ester or derivative of an organic acid such as citric acid, succinic acid, tartaric acid and glycerin. . [16] The component (A) polyglycerin fatty acid ester is 10 to 20% by weight of decaglycerin monooleate, the component (B) sucrose fatty acid ester is 3 to 7% by weight, and ) Component organic acid monoglyceride is 1 to 3% by weight of succinic acid monoglyceride, and component (C) is a water-insoluble substance.
A composition comprising 50% to 80% by weight of water or polyhydric alcohol as the component (D), water or fructose-glucose liquid sugar or saccharified reduced starch, and wherein the composition is solubilized, emulsified or dispersed. The composition according to any one of [5] to [8] or [10].

[17] A beverage comprising the composition having alcohol resistance according to any one of [1] to [16]. [18] A food containing the composition having alcohol resistance according to any one of [1] to [16]. [19] The liquid sugar containing a composition having alcohol resistance and alcohol are mixed and diluted with hot water or water
The beverage according to [17].

[0009]

BEST MODE FOR CARRYING OUT THE INVENTION The composition having alcohol resistance of the present invention comprises (A) polyglycerin fatty acid ester,
(B) sucrose fatty acid ester, (C) water-insoluble substance,
(D) A solubilized, emulsified or dispersed composition prepared by blending water or a polyhydric alcohol, wherein the particle size of the composition (a) is measured by particle size measurement using a laser;
(B) The change in particle size after 2 days when the composition is added to a 20% alcohol solution is within ± 10 nm when the particle size of the (a) composition is less than 100 nm, and (b) particle of the composition Diameter is 1
The composition is characterized in that it has an alcohol resistance of ± 10% or less when it is 00 nm or more. The component (A) polyglycerin fatty acid ester used in the present invention is a polyglycerin fatty acid ester that can be used in foods. Specifically, for example, the average degree of polymerization 5 to 15,
Preferably, polyglycerin having an average degree of polymerization of 5 to 10,
Fatty acids having 8 to 22 carbon atoms, preferably 14 to 18 carbon atoms
It is a polyglycerin fatty acid ester consisting of a mono- or diester with the fatty acid of. When the average degree of polymerization of the polyglycerin fatty acid ester is less than 5, the stability of the water-soluble composition is poor, and those having an average degree of polymerization of more than 15 are difficult to obtain. Similarly, when the carbon number is less than 8, the stability of the water-soluble composition is poor, and when the carbon number exceeds 22, it is difficult to obtain. The amount of polyglycerin fatty acid ester is usually 1
-50% by weight, preferably 5-30% by weight, more preferably 10-20% by weight. If the content of the polyglycerin fatty acid ester is less than 1% by weight, it is difficult to obtain the effect of the emulsifier, and if it exceeds 50% by weight, when the water-soluble composition is added to the beverage or food, the taste peculiar to the emulsifier is obtained. It is not preferable because it affects the taste.

The sucrose fatty acid ester of the component (B) used in the present invention is a monoester of sucrose with a fatty acid having 8 to 22 carbon atoms, preferably a fatty acid having 14 to 18 carbon atoms.
The content is at least wt%. When the carbon number is less than 8, the stability of the water-soluble composition is poor, and when the carbon number exceeds 22, it is difficult to obtain. The content of the sucrose fatty acid ester is usually 0.5 to 15% by weight, preferably 1 to 10% by weight, more preferably 3 to 7% by weight. If the content of the sucrose fatty acid ester is less than 0.5% by weight, it is difficult to obtain the effect of the emulsifier, and if it exceeds 15% by weight, the viscosity of the water-soluble composition becomes high and it is difficult to handle.

The water-insoluble substance as the component (C) used in the present invention is a substance which is insoluble or sparingly soluble in water. For example, oils and fats, oil-soluble vitamins, oil-soluble flavors, lipids and coenzymes used in foods. Examples include Q10. Here, the fats and oils include fats and oils derived from animals, plants, and microorganisms, such as unpurified products or purified products obtained by pressing these fats and oils,
Furthermore, hydrogenated oils and fats and the like can be mentioned. Further, a synthetic oil obtained by reacting a fatty acid with glycerin can be mentioned. Specifically, for example, lard, beef tallow, chicken oil, whale oil, tuna oil, sardine oil, mackerel oil, saury oil, bonito oil, herring oil, liver oil, soybean oil, cottonseed oil, safflower oil, rice oil, corn. Oils, rapeseed oil, palm oil, perilla oil, perilla oil, cocoa butter, peanut oil, coconut oil, evening primrose oil, borage oil, jojoba oil, and the like, and oils and fats such as synthetic triglycerides such as medium-chain fatty acid triglyceride are included. Specific examples of oil-soluble vitamins include vitamin A, vitamin D, vitamin E, vitamin K, and vitamin P. As the oil-soluble fragrance, specifically, for example,
Examples thereof include menthol, orange oil, lemon oil, yuzu oil, perilla oil, and essential oils of lemon, orange, yuzu, perilla extracted from natural products. Specific examples of other lipids include squalene, squalane, lanolin, liquid paraffin, glycosylceramide, octacosanol, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, phytosterols, coenzyme Q10, lycopene, beta carotene. , Lutein and minerals. The water-insoluble or slightly water-soluble substance may be used alone, or 2
You may use it in combination of 1 or more types as appropriate. The amount of the substance insoluble or slightly soluble in water is usually 0.1 to 40% by weight, preferably 1 to 25% by weight, more preferably 5-1.
It is 5% by weight. When the amount of the water-insoluble or sparingly-soluble substance is less than 0.1% by weight, the amount of the water-soluble composition added to the beverage or food is large, which adversely affects the state or taste of the beverage or food. It is not preferable because it is given. If it exceeds 40% by weight, it is difficult to obtain a stable water-soluble composition, which is not preferable. If necessary, an emulsifier or thickener suitable for mixing can be used. Further, it may be only edible oil or a food additive added.

The water or polyhydric alcohol of the component (D) used in the present invention is not particularly limited as long as it is water that can be blended into foods and drinks. It may be water. Food additives include emulsifiers, stabilizers, seasonings, acids, salts and the like.
The polyhydric alcohol is an alcohol having two or more hydroxyl groups in one molecule, and specific examples thereof include propylene glycol, glycerin, maltitol, reduced starch syrup, lactitol, palatinit, erythritol and sorbitol. , And sugar alcohols such as mannitol, and these may be used alone or in combination of two or more kinds. More preferred are glycerin, reduced starch syrup, and sorbitol. Water and / or polyhydric alcohol is usually 95% by weight
Below, preferably 30 to 90% by weight, more preferably 5
It is 0 to 80% by weight. If the blending amount of water and / or polyhydric alcohol exceeds 95% by weight, the blending amount of an emulsifier or a substance insoluble or hardly soluble in water is small and it is difficult to obtain a composition, which is not preferable.

Examples of the organic acid monoglycerin ester as the component (E) used in the present invention include citric acid,
Examples thereof include esters of glycerin with organic acids such as succinic acid and tartaric acid. Moreover, the derivative | guide_body of the ester of the said organic acid and glycerin can also be mentioned. The amount of the organic acid glycerin ester is usually 0.1 to 10% by weight,
Preferably 1-5% by weight, more preferably 1-3% by weight
Is. The amount of organic acid glycerin ester is 0.1
If it is less than 10%, it is difficult to obtain the effect of the emulsifier, and it is 10% by weight.
When it exceeds, the taste peculiar to the emulsifier affects the taste of the beverage or food when the water-soluble composition is added to the beverage or food, which is not preferable.

In addition to the above emulsifier, the composition of the present invention comprises:
One or more emulsifiers selected from lecithin, enzymatically decomposed lecithin, monoglycerin fatty acid ester, propylene glycol fatty acid ester, polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester and the like can be appropriately used. Further, the above emulsifier may be highly purified by distillation or the like, or may be a reaction mixture. Moreover, an acid or a salt can also be used. Specific examples of the acid include ascorbic acid, citric acid, succinic acid, acetic acid, carbonic acid, malic acid and the like. As the salt, specifically, for example, sodium ascorbate, potassium chloride, calcium chloride,
Examples thereof include sodium chloride, potassium carbonate, calcium carbonate, sodium carbonate, monosodium succinate, disodium succinate, sodium acetate, calcium citrate, potassium lactate, calcium lactate and the like. These acids,
You may use 1 type, or 2 or more types of salt.

A method for producing the composition will be described. The composition of the present invention is a liquid obtained by blending the above-mentioned components, and is a liquid which is stabilized in a solubilized, emulsified or dispersed state in water or a polyhydric alcohol (abbreviated as a water-soluble composition). A homogenizer such as a colloid mill, a high pressure homogenizer, a microfluidizer, an optimizer, or a nanomizer can be used for the production of the above-mentioned composition, and thereby a water-soluble composition in a homogeneous state is obtained. be able to. This homogenizing treatment may be performed twice or more in order to further stabilize the water-soluble composition. In addition to the above homogenizers, homogenizers such as ultrasonic emulsifiers and homomixers such as TK homomixer, ajihomomixer, ultramixer and clearmix can be used for the homogenization treatment. In the case of the above emulsification or dispersion, as the emulsification method, a natural emulsification method, a phase inversion emulsification method, a gel emulsification method, a D phase emulsification method, or the like can be used.
Further, these methods may be combined with a mechanical emulsification method such as the homogenization treatment. By cooling after emulsification and storing in a cold place, a part of the liquid oily component having a high melting point is solidified and becomes a dispersed state.

The beverage containing the water-soluble composition of the present invention is a beverage containing one or more selected from minerals such as salt, acidulants, sweeteners, alcohols, vitamins, flavors and fruit juices, for example. Examples thereof include sports drinks, fruit juice drinks, lactic acid bacteria drinks, alcoholic drinks, vitamin drinks and mineral drinks. Further, processed milk, soy milk, beverages for improving physical constitution and the like can be mentioned. In particular, it is suitable for heating alcoholic beverages because of its effects of alcohol resistance and heat resistance.

Foods containing the water-soluble composition of the present invention include breads and confectioneries such as bread, donuts, cakes, cookies, biscuits, candies, jellies and chocolates; milk processed foods such as yogurt; hams and the like. Meat processed foods; Satsuma fried foods, chikuwa, kamaboko and other fish paste products; seasonings such as soy sauce, miso, sauces, sauces, dressings; pickles such as takuan, nara pickles, lightly pickled and bran pickles; margarines, fat spreads, shortenings, etc. Examples thereof include processed oils and fats; powdered foods and beverages such as powdered drinks and powdered soups; capsule-shaped, tablet-shaped, powdered, and granular health foods and dietary supplements.

[0018]

INDUSTRIAL APPLICABILITY The water-soluble composition of the present invention has alcohol resistance, and even when mixed with a highly concentrated alcohol solution of 20 to 30%, the water-insoluble substance does not precipitate or float. Stable solubilization, emulsification, and dispersion can be maintained, and a homogeneous and stable state can be maintained even after long-term storage. Beverages containing the water-soluble composition of the present invention,
It also has excellent alcohol resistance, acid resistance, and salt resistance, and can maintain stability even when an alcohol, acid, or salt is added. In addition, sterilization treatment at 60 to 100 ° C or 10 if necessary
High temperature sterilization or sterilization treatment at 0 to 150 ° C. can be performed, it is stable against heating at this time, and it can maintain a uniform state even when stored for a long period of time. The food containing the water-soluble composition of the present invention has excellent alcohol resistance, acid resistance, and salt resistance, and can maintain stability even when an alcohol, an acid, or a salt is added. Further, sterilization treatment at 60 to 100 ° C or high temperature sterilization or sterilization treatment at 100 to 150 ° C can be performed if necessary, and it is stable against heating at this time, and can be stored for a long time. A uniform state can be maintained.

[0019]

The present invention will be described in more detail with reference to specific examples. Example 1 As shown in Table 1, decaglycerin monooleate [trade name: Sunsoft Q-17S, Taiyo Kagaku Co., Ltd.] 100
g, sucrose myristate ester [trade name: Ryoto sugar ester M-1695, Mitsubishi Chemical Foods Co., Ltd.]
Made] 50 g, water 200 g, glucose fructose syrup [Product name:
KM-F55, manufactured by Nippon Feed Industry Co., Ltd.] (600 g) was added, and the mixture was heated to be completely dissolved and used as an aqueous phase portion. As the oil phase part, 50 g of rapeseed white squeezing oil is gradually mixed and stirred into the previous water phase part, and then homogenized by a high pressure homogenizer,
A homogeneous water-soluble composition was obtained. The evaluation results are shown in Table 2. Example 2 50 g of sucrose myristic acid ester of Example 1 was added to 50 g of sucrose stearate [trade name: Ryoto Sugar Ester S-1170, manufactured by Mitsubishi Chemical Foods Co., Ltd.].
Except for the above, the same operation as in Example 1 was performed to obtain a uniform water-soluble composition. The evaluation results are shown in Table 2. Example 3 Decaglycerin monooleate [Product name: Sunsoft Q-
17S, Taiyo Kagaku Co., Ltd.] 200 g, sucrose stearate [Product name: Ryoto Sugar Ester S
-1670, manufactured by Mitsubishi Chemical Foods Co., Ltd.] 100 g, water 1
50 g of glucose and fructose corn syrup [trade name: KM-F55, manufactured by Nippon Feed Industry Co., Ltd.] were added and heated to be completely dissolved to obtain an aqueous phase. As an oil phase part, 200 g of orange oil [manufactured by Nagaoka Koryo Co., Ltd.] was gradually mixed and stirred in the above water phase part, and then homogenized by a high pressure homogenizer to obtain a uniform water-soluble composition. Table 2 shows the evaluation results
Shown in.

Comparative Example 1 100 g of decaglycerin monooleate and 50 g of sucrose myristate ester of Example 1 were replaced with 150 g of decaglycerin monooleate [trade name: Sunsoft Q-17S, Taiyo Kagaku Co., Ltd.]. The same operation as in Example 1 was performed to obtain a uniform water-soluble composition. The evaluation results are shown in Table 2. Comparative Example 2 100 g of decaglycerin monooleate of Example 1 and 50 g of sucrose myristic acid ester were mixed with sucrose laurate [trade name: Ryoto Sugar Ester L-169.
5, manufactured by Mitsubishi Chemical Foods Co., Ltd.]
The same operation as in Example 1 was performed to obtain a uniform water-soluble composition. The evaluation results are shown in Table 2. Comparative Example 3 200 g of decaglycerin monooleate of Example 3 and 100 g of sucrose stearate were used as 200 g of decaglycerin stearate [trade name: Sunsoft Q-18S, Taiyo Kagaku Co., Ltd.], water 150 g, glucose fructose syrup Sugar [trade name: KM-F55, manufactured by Nippon Feed Industry Co., Ltd.] 3
Except for using 50 g of water and 100 g of glucose-fructose syrup 500 g, the same procedure as in Example 3 was carried out to obtain a uniform water-soluble composition. The evaluation results are shown in Table 2.

Example 4 As shown in Table 3, decaglycerin monooleate [trade name: Sunsoft Q-17S, manufactured by Taiyo Kagaku Co., Ltd.] 100
g, sucrose stearate [Product name: Ryoto Sugar Ester S-1670, Mitsubishi Kagaku Foods Co., Ltd.]
30 g, monoglyceride citric acid [trade name: Sunsoft No. 621B, manufactured by Taiyo Kagaku Co., Ltd.] 20 g, water 2
00g, high-fructose corn syrup [Product name: New Fract F
0, Showa Sangyo Co., Ltd.] 600 g was added, heated and completely dissolved to form an aqueous phase. Oilseed rape oil 5 as the oil phase
0 g of the above aqueous phase was gradually mixed and stirred, and then homogenized by a high pressure homogenizer to obtain a uniform water-soluble composition. The evaluation results are shown in Table 4. Example 5 Citric acid monoglyceride of Example 1 [trade name: Sunsoft No. 621D, manufactured by Taiyo Kagaku Co., Ltd.], 20 g of succinic acid monoglyceride [trade name: Sunsoft No. 681N
U, manufactured by Taiyo Kagaku Co., Ltd.]
The same procedure as above was performed to obtain a uniform water-soluble composition. The evaluation results are shown in Table 4. Example 6 Decaglycerin monooleate [Product name: Sunsoft Q-
17S, manufactured by Taiyo Kagaku Co., Ltd.] 100 g, emulsifying agent of sucrose fatty acid ester and organic acid monoglyceride [Product name:
SEM-70, manufactured by Mitsubishi Chemical Foods Co., Ltd.] 50 g, water 200 g, glucose fructose syrup [trade name: New Fract F0, manufactured by Showa Sangyo Co., Ltd.] 600 g, heated and completely dissolved, water Aibe. As an oil phase part, 50 g of lemon oil [manufactured by Ogawa Fragrance Co., Ltd.] was gradually mixed into the above water phase part and stirred, and then homogenized by a high pressure homogenizer to obtain a uniform water-soluble composition. . Table 4 shows the evaluation results
Shown in.

Comparative Example 4 A uniform water-soluble composition was obtained in the same manner as in Example 4, except that 100 g of decaglycerin monooleate and 30 g of sucrose stearate of Example 4 were changed to 130 g of decaglycerin monooleate. It was The evaluation results are shown in Table 4. Comparative Example 5 A uniform water-soluble composition was obtained in the same manner as in Example 4, except that 100 g of decaglycerin monooleate and 30 g of sucrose stearate of Example 4 were changed to 130 g of sucrose stearate. The evaluation results are shown in Table 4. Comparative Example 6 100 g of decaglycerin monooleate of Example 6, 50 g of a compounding emulsifier of sucrose fatty acid ester and organic acid monoglyceride, 140 g of decaglycerin monooleate, enzymatically decomposed soybean lecithin [Sanlecithin A, manufactured by Taiyo Kagaku Co., Ltd.]
A uniform water-soluble composition was obtained in the same manner as in Example 4 except that the amount was 10 g. The evaluation results are shown in Table 4. Comparative Example 7 Except that 100 g of decaglycerin monooleate, 30 g of sucrose stearate ester, and 20 g of citric acid monoglyceride of Example 4 were changed to 1500 g of monoglycerin stearate [trade name: Emulge MS, manufactured by Riken Vitamin Co., Ltd.]. The same operation as in Example 4 was carried out, but the water-soluble composition containing a homogeneous plant sterol could not be obtained because it was separated immediately after the preparation. The evaluation results are shown in Table 4. Comparative Example 8 100 g of decaglycerin monooleate of Example 4, 30 g of sucrose stearate, and 20 g of citric acid monoglyceride were added to 150 g of tetraglycerin monostearate [trade name: MS-310, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.].
The same operation as in Example 4 was carried out except that the above was followed, but the separation was carried out immediately after the preparation, and a homogeneous plant sterol-containing water-soluble composition could not be obtained. The evaluation results are shown in Table 4.

The particle size measuring method, alcohol resistance test, acid resistance / heat resistance test, salt resistance / heat resistance test will be described below. Measuring method of particle size For measuring the particle size, a particle size distribution measuring device N4-SD type (manufactured by Beckman Coulter, Inc.) capable of measuring a range of several nm or more by a photon correlation method is used. Alcohol resistance test The prepared water-soluble composition is mixed with a high-concentration aqueous alcohol solution having an alcohol concentration of 20% and / or 30%, and the average particle size of the solution after 2 days is measured. The unit of the average particle size is nm, and the evaluation is performed according to the following evaluation criteria. ◯: ± 10 n when the particle size of the composition is less than 100 nm
within 1 m, ± 1 when the particle size of the composition is 100 nm or more
The stability is good within 0%. Δ: ± 20n when the particle size of the composition is less than 100 nm
within 2 m, ± 2 when the composition particle size is 100 nm or more
Within 0%, the stability is a little poor, x: The stability is poor, and changes of ◯ and Δ above are observed.

Acid resistance / heat resistance test The prepared water-soluble composition is mixed with a high-concentration aqueous alcohol solution having an alcohol concentration of 20% and / or 30%, and the solution after 2 days is adjusted to pH 3 or less with citric acid. 1% of a water-soluble composition is added to the purified water, an acidic aqueous solution containing the composition of the present invention is boiled, and heat treatment is performed for 30 minutes from the time when the liquid temperature reaches 85 ° C. Then, the mixture is allowed to cool at room temperature, the average particle size after one day is measured, and evaluated according to the same evaluation criteria as in the alcohol resistance test.

Salt resistance / heat resistance test The prepared water-soluble composition was mixed with a highly concentrated aqueous alcohol solution having an alcohol concentration of 20% and / or 30%, and the solution after 2 days was dissolved in purified water containing 5% of salt. 1% of the composition is added, and a saline solution containing the composition of the present invention is boiled in water and heat-treated for 30 minutes from the time when the liquid temperature reaches 85 ° C. Then, the mixture is allowed to cool at room temperature, the average particle size after one day is measured, and evaluated according to the same evaluation criteria as in the alcohol resistance test.

[0026]

[Table 1]

[0027]

[Table 2]

[0028]

[Table 3]

[0029]

[Table 4]

From Tables 1 and 2, as compared with Examples 1 to 3,
In Comparative Examples 1 and 3 in which the component (B) was not blended and Comparative Example 2 in which the component (A) was not blended, the evaluation of the alcohol resistance test was x. From Tables 3 and 4, Examples 4 to 6
Comparative Example 4 containing no component (B),
Comparative Example 5, (B), (E) containing no component (A)
In Comparative Example 6 in which the components were not blended, the result of the alcohol resistance test was Δ or ×. Also, (A), (B),
Regarding Comparative Examples 7 and 8 in which the component (E) was not mixed,
Both were separated immediately after preparation, and a homogeneous solution could not be obtained. From the above, it is understood that the compositions of Examples 1 to 6 of the present invention are excellent in alcohol resistance, and have acid resistance / heat resistance and salt resistance / heat resistance. In addition, the compositions of Examples 1 to 6 were blended with a shochu stock solution having an alcohol concentration of 20%, and the mixture was added at 40 ° C.
It was confirmed that it was uniformly dissolved, emulsified or dispersed, and there was no separation when it was prepared by pouring in hot water.

   ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4B015 LH12                 4B017 LC08 LC10 LK09 LK11 LL06                 4B035 LC04 LC05 LG05 LG09 LG18                       LK13                 4D077 AA02 AB08 BA07 BA15 DC02Y                       DC34Y DC36Y DD36Y DE07Y                       DE08Y DE09Y

Claims (19)

[Claims] 1. A polyglycerin fatty acid ester (A),
(B) sucrose fatty acid ester, (C) water-insoluble substance,
(D) A solubilized, emulsified or dispersed composition prepared by blending water or a polyhydric alcohol, wherein the particle size of the composition (a) is measured by particle size measurement using a laser;
(B) The change in particle size after 2 days when the composition is added to a 20% alcohol solution is within ± 10 nm when the particle size of the (a) composition is less than 100 nm, and (b) particle of the composition Diameter is 1
A composition having an alcohol resistance of ± 10% or less when the thickness is 00 nm or more. 2. A composition having alcohol resistance according to claim 1, further comprising: (a) the particle size of the composition and (b) the composition having a pH of 3 measured by particle size measurement using a laser. The change in particle size after 1 day when heated at 85 ° C. for 30 minutes in addition to the citric acid aqueous solution was as follows:
A composition having an acid resistance of less than ± 10 nm when it is less than 10 nm, and within ± 10% when the particle diameter of the composition (b) is 100 nm or more. 3. The composition having alcohol resistance according to claim 1, further comprising 5% of the particle size of (a) composition and (b) composition measured by particle size measurement using a laser. The change in particle size after 1 day when heated at 85 ° C. for 30 minutes in addition to the saline solution is within ± 10 nm when the particle size of the composition (a) is less than 100 nm, and within (b) of the composition Particle size is 10
A composition having a salt resistance of ± 10% or less in the case of 0 nm or more. 4. The composition having alcohol resistance and acid resistance according to claim 2, further comprising: (a) the particle size of the composition by particle size measurement using a laser; and (b) the composition. Add to 5% saline solution adjusted to pH 3 with citric acid,
When the particle size of (a) the composition is less than 100 nm, the change in particle size after 1 day when heated at 85 ° C. for 30 minutes is ±
A composition having a salt resistance of 10 nm or less and (b) ± 10% or less when the particle size of the composition is 100 nm or more. 5. A polyglycerin fatty acid ester (A),
(B) a sucrose fatty acid ester, (E) an organic acid monoglyceride, (C) a water-insoluble substance, (D) water or a polyhydric alcohol, which is a solubilized, emulsified or dispersed composition Then, the change in the particle size of the (a) composition and the particle size after 2 days when the (b) composition was added to the 30% alcohol solution by the particle size measurement using a laser is (a)
Within ± 10 nm when the particle size of the composition is less than 100 nm, and within ± 10 nm when the particle size of the composition (b) is 100 nm or more.
Composition within 10%. 6. The composition having alcohol resistance according to claim 5, further comprising: (a) the particle size of the composition and (b) the composition having a pH of 3 measured by particle size measurement using a laser. The change in particle size after 1 day when heated at 85 ° C. for 30 minutes in addition to the citric acid aqueous solution was as follows:
A composition having an acid resistance of less than ± 10 nm when it is less than 10 nm, and within ± 10% when the particle diameter of the composition (b) is 100 nm or more. 7. The composition having alcohol resistance according to claim 5, further comprising 5% of the particle size of (a) composition and (b) composition measured by particle size measurement using a laser. The change in particle size after 1 day when heated at 85 ° C. for 30 minutes in addition to the saline solution is within ± 10 nm when the particle size of the composition (a) is less than 100 nm, and within (b) of the composition Particle size is 10
A composition having a salt resistance of ± 10% or less in the case of 0 nm or more. 8. The composition having alcohol resistance and acid resistance according to claim 6, wherein the particle size of the composition (a) and the composition (b) are measured by particle size measurement using a laser. Add 5% saline solution adjusted to pH 3 with acid to 85
The change in particle size after 1 day when heated at ℃ for 30 minutes
(A) ± 10 when the particle size of the composition is less than 100 nm
A composition having a salt resistance of not more than 10 nm and within ± 10% when the particle diameter of the composition (b) is not less than 100 nm. 9. An emulsifier of component (A) 1 to 50% by weight,
Component (B) containing 0.5 to 15% by weight of an emulsifier, component (C) of 0.1 to 40% by weight of a water-insoluble substance, and component (D) of 95% by weight or less of water or polyhydric alcohol. Item 1
5. The composition according to any one of 4 to 4. 10. An emulsifier of component (A) 1 to 50% by weight,
0.5 to 15% by weight of an emulsifier as the component (B), 0.1 to 40% by weight of a water-insoluble substance as the component (C), 95% by weight or less of water or a polyhydric alcohol as the component (D), (E). Composition according to any one of claims 5 to 8 containing 0.1 to 10% by weight of the component emulsifier. 11. The component (A) emulsifier is one or more polyglycerin fatty acid ester selected from mono- or diesters with a degree of polymerization of 5 to 15 and a fatty acid having 8 to 22 carbon atoms. The composition according to any one of 1 to 10. 12. The sucrose fatty acid ester wherein the emulsifier of the component (B) contains 70% by weight or more of a monoester of one or more fatty acids selected from fatty acids having 8 to 22 carbon atoms and sucrose. The composition according to any one of claims 1 to 10. 13. The water-insoluble substance as the component (C) is a fat or oil,
Oil-soluble vitamins, oil-soluble flavors, lipids, coenzyme Q1
1 to 10 is a substance which is insoluble or hardly soluble in water.
The composition according to any one of 1. 14. The composition according to claim 1, wherein the substance as the component (D) is a polyhydric alcohol such as water and liquid sugar. 15. The composition according to claim 5, wherein the emulsifier as the component (E) is an ester or derivative of glycerin with an organic acid such as citric acid, succinic acid or tartaric acid. object. 16. The polyglycerin fatty acid ester of component (A) is decaglycerin monooleate 10-2.
0% by weight, (B) component sucrose fatty acid ester is 3 to 7% by weight sucrose stearate, and (E) component organic acid monoglyceride is succinic acid monoglyceride 1.
3% by weight, the water-insoluble substance of the component (C) is an oily fragrance 5
˜15% by weight, component (D) water or polyhydric alcohol is water or fructose glucose syrup or reduced starch saccharified product 50˜
A composition comprising 80% by weight, and solubilized, emulsified or dispersed therein.
0. The composition according to any one of 0. 17. A beverage containing the composition having alcohol resistance according to any one of claims 1 to 16. 18. A food comprising the composition having alcohol resistance according to any one of claims 1 to 16. 19. The beverage according to claim 17, wherein liquid sugar containing a composition having alcohol resistance is mixed with alcohol and diluted with hot water or water.