JP2003192560A - Cosmetic for repacking use - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To improve the storage stability such as perfume stability of a cosmetic for repacking use sealed in a thin-walled container made of a packaging material with aluminum vapor depositing layer. <P>SOLUTION: This cosmetic for repacking use sealed in the thin-walled container contains a ketone-based perfume 0.001-7 mmHg in vapor pressure at 25°C and 2.0-13.0 in HLB formulated therein. <P>COPYRIGHT: (C)2003,JPO

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improving the stability of a refill cosmetic material containing a packaging material having an aluminum vapor deposition layer, and more particularly to improving the aroma stability of the composition.

[0002]

2. Description of the Related Art In recent years, various proposals have been made for improving packaging materials. For example, a multilayer film including a PET film layer / light-shielding aluminum vapor deposition layer / ethylene-based film layer / thin paper layer, etc., which has improved light-shielding properties (Japanese Patent Laid-Open No. 20-200200).
01-121649), and a dealuminated packaging material excellent in content stability due to a transparent barrier film / printing ink layer / heat-sealing resin layer (Japanese Patent Laid-Open No. 2000-2803).
94), a packaging material comprising a sheet film excellent in oxygen and water vapor barrier properties and capable of sterilizing a retort / silicon oxide vapor deposition layer-formed ethylene-vinyl alcohol copolymer film / nylon film (JP-A-6-171034) and the like. . In addition, from the viewpoints of environmental issues, resource issues, and cost reduction, it is required to reduce the thickness of refill packaging containers for the purpose of saving plastic molding materials. There are also known aluminum vapor deposition packaging materials that can be folded and discarded so that they do not exist.

It has been conventionally known that a multilayer film having an aluminum layer has excellent airtightness and stability of contents. When this aluminum layer is removed and, for example, a silicon oxide-containing film is used instead of it,
The current situation is that it has not reached a level where the aluminum layer can be replaced.

Further, when the aluminum layer is reduced by a new technique of vapor deposition from a fraction of the conventional aluminum layer thickness to a few tens of minutes, gas permeability, ultraviolet rays, visible rays, infrared rays, etc. It is difficult to make the transmittance of the container equal to that of the conventional container, and the aroma stability, the oxidation stability, and other storage stability of the contents are likely to be lowered.

[0005]

DISCLOSURE OF THE INVENTION The present invention has the same contents even when the aluminum layer is vapor-deposited and sealed in a thin-walled container, as when sealed in a conventional non-thinned container. An object of the present invention is to provide a refill cosmetic having stability of fragrance and the like.

[0006]

In order to solve the above-mentioned problems, the present invention provides a container made of a packaging material having an aluminum vapor-deposited layer with a vapor pressure of 0.001 mmHg at 25 ° C.
A composition containing a ketone-based fragrance having a HLB of ˜7 mmHg and an HLB of 2.0 to 13.0 is sealed. Even if the ketone-based fragrance is intentionally blended, or if it is derived from other fragrance components, the effect does not change.

The above composition further comprises 0.1% by mass to 30% by mass.
It is preferable to add a mass% of polyol and / or its derivative.

Vapor pressure at 25 ° C. is 0.001 mmH
Examples of the ketone-based fragrance having g-7 mmHg and HLB of 2.0-13.0 include farnesylacetone, 2,
6,10-Trimethyl-1-acetyl-2,5,9-cyclododecatriene, 2-tridecanone, allyl α-ionone, α-iron, 6-methyl-α-ionone, α-
n-methylionone, β-n-methylionone, geranylacetone, 2,2,5-trimethyl-5-pentylcyclopentanone, 3-methyl-4- (2,4,6-trimethyl-3-cyclohexyl) -3- Buten-2-one, methylyriton, α-isomethylionone, γ-methylionone, β-isomethylionone, delta-methylionone, 2-undecanone, suedionone, isodamascon, trimethylcyclohexenylbuteneone,
α-damascon, α-dinascon, α-ionone, β
-Damascon, β-ionone, γ-ionone, δ-damascon, neron, ethylmenthenyl ketone, damascenone, (β-) 2-n-heptylcyclopentanone, acetylcedrene, dibenzyl ketone, 5 (6)- Acetyl-4-isopropyl-1-methylbicyclo [2.2.
2] Oct-2-ene, 5-phenyl-5-methyl-3
-Hexanone, 2-n-hexylcyclopentanone,
2,3,5-trimethylcyclohexyl-1-methyl ketone, methylcyclocitron, dihydrojasmon,
Isojasmon, 2-hexylidenecyclopentanone,
4-methylene-3,5,6,6-tetramethyl-2-
Heptone, cis-jasmone, 2-nonanone, p-te
rt. -Pentylcyclohexanone, 4-tert. Amylcyclohexanone, 4 (5) -acetyl-7,7,
9-Trimethylbicyclo [4.3.0] non-1-ene, Casimellan, Isolongiforanone, Isolongiforane ketone, Oxocedrean, 1-Acetyl-3,
3-dimethyl-1-cyclohexene, 2-amylcyclophentenone, 3-methyl-5-propyl-2-cyclohexen-1-one, oxocedrean, cedreon,
3-Methyl-4-phenyl-3-buten-2-one, meson, 2-sec-butylcyclohexanone, isomeson, 7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.2.2] oct. 2-ene, flavinone, dihydrocarbanone, d-dihydrocarbanone, d-pregon, fenchon, 2-acetyl, 3-dimethylnorbornane, butylideneacetone, p-methoxyphenylacetone, anisic ketone, β -Methylnaphthyl ketone, 2'-acetonaphthone, camphor, berbenone, mesityl oxydene, 3-acetyl-5-dimethylfuran, furfuran-acetone, 2-pentanone, 2-acetyl 1-5-methylfuran, methylisopropylketone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione 2-Acetylfuran, zingalone, 2,3-heptanedilone, methyltetrahydrofuranone, acetyl-isovaleryl, 5-hydroxy-4-octanone, butyroin, 2,3-hexanedione, 3,4-hexanedione, cyclotene (diketone type) ), Methylcyclopentenolone, and 2,3-pentanedione, and one or more of these are blended. The blending amount is preferably in the range of 0.005 mass% to 1.0 mass% with respect to the entire composition. More preferably, it is 0.01% by mass to 0.5% by mass. If the amount is less than 0.005% by mass, the stability of the composition may be insufficient, and if it exceeds 1.0% by mass, usability may be deteriorated.

As the polyol and the derivative of the polyol, glycerin, diglycerin, ethylene glycol, diethylene glycol, propylene glycol,
1,3-butylene glycol, isoprene glycol,
Sorbitol, maltitol, xylitol, glucose, erythritol, pentaerythritol, sucrose,
Mannitol, gluconic acid, dipropylene glycol,
Examples include hexylene glycol, polyphenol, glycerin fatty acid ester, erythritol fatty acid ester, mannitol fatty acid ester, glycolic acid fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, (POE) sorbitan fatty acid ester, sucrose fatty acid ester, and sorbitol fatty acid ester. These can be used alone or in combination of two or more.

The blending amount of the polyol and the polyol derivative is preferably 0.1% by mass to 30% by mass of the whole composition. More preferably, it is 0.2% by mass to 10% by mass. If the amount is less than 0.1% by mass, the stability of the composition may be insufficient, and if it exceeds 30% by mass, usability may be deteriorated.

The refill cosmetics of the present invention include compounding agents which are optional components used in cosmetics, such as surfactants, oils, alcohols, thickeners, antiseptic / sterilizing / antibacterial agents, and antioxidants. A chelating agent, a pH adjusting agent, a fragrance, a pigment, vitamins, amino acids, water and the like can be appropriately added according to the purpose. The optional components are not limited to these.

[0012]

Since the present invention is constructed as described above, it has the following effects. Originally, the packaging material containing the vapor-deposited aluminum layer is microscopically porous and permeable to water, ethanol and volatile fragrance components. When the amount of ethanol in the composition is high, it may absorb external moisture and dilute the contents in the long term. However, if the above-mentioned ketone-based fragrance is contained in the composition, it will be selectively adsorbed on the surface of the packaging material containing the aluminum vapor deposition layer and its porosity will be reduced. It was also found that the presence of polyol further enhances the effect.

The refill cosmetic composition of the present invention can be used in compositions of various dosage forms such as shampoo, hair water, hair foam, rinse, conditioner, treatment, cleansing gel, hand soap, body soap and the like. .

[0014]

The present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. The blending amount in each example is% by mass. [Examples and Comparative Examples] Cosmetics having the compositions shown in Tables 1 to 3 were produced and stretched nylon 15 μm / aluminum vacuum deposition (0.1 μm
m) Polyethylene terephthalate was filled in a bottle having a film layer of 12 μm / linear low-density polyethylene 150 μm and evaluated. After filling up with almost full volume of 95% level of content liquid and stoppering, store it in an air-cooled constant temperature bath at 50 ° C for 1 month or after sun exposure at 350 Langley on the roof of Hirai Research Building in Edogawa-ku, Tokyo. The stability was evaluated according to the following criteria by a specialized panel. The results are shown in each table. Evaluation method: Stability evaluation criteria (fragrance stability, oxidation stability, light stability) 5 points: No change. 4 points: Almost no change. 3 points: Some change. 2 points: There is a clear change. 1 point: There is a remarkable change.

[0015]

[Table 1]

[0016]

[Table 2]

[0017]

[Table 3]

[0018]

[Table 4]

[0019]

[Table 5] The pH of the shampoo described in this example is 3-7.5.
Is the range. 1) E. O. 3 mol, lauryl 2) lauroyl, triethanolamine salt 3) cocoyl, triethanolamine salt 4) C12-C18, sodium salt 5) lauryl 6) Yucaformer 204WL Packaging material: stretched nylon 15 μm / aluminum vacuum deposition (0.
5 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 80 μm

[Example 45] Medicinal hand soap red algae water extract 0.5 potassium laurate 5.0 potassium myristate 10.0 N-lauroyl N-methyl β-alanine potassium 2.0 N-lauroyl glutamate monopotassium 2.0 Glycerin 5.0 Propylene glycol 6.0 Coconut oil fatty acid diethanolamide 2.0 Lauryl amine oxide 2.0 Sorbitol 3.0 Cationized cellulose * 1 1.0 Alkyl methacrylate polymer (R = butyl / ethyl) 5.0 Hydroxyethanediphosphonic acid 0.1 Tetrasodium edetate tetrahydrate 0.2 Vegetable squalane 1.0 Potassium chloride 0.1 Triclosan-Bencre-SL complex 1.0 Potassium hydroxide Trace 5-phenyl- 5-methyl-3-hexanone 2.0 perfume 0.5 purified Balance Total 100.0% * 1 Lion Chemical Co. XM-503LN or Reogado GP or UCC Co. polymers -JR400 packaging orientated nylon 10MyuLm / aluminum vacuum evaporation (0.8 [mu] m) polyethylene terephthalate 12 [mu] m /
Linear low density polyethylene 100 μm

[Example 46] Medicinal hand soap red algae water extract 0.3 Potassium laurate 5.0 Potassium myristate 10.0 N-Lauroyl N-methyl β-alanine potassium 2.0 N-Lauroyl glutamate monopotassium 2.0 Glycerin 5.0 Propylene glycol 6.0 Coconut oil fatty acid diethanolamide 2.0 Lauryl amine oxide 2.0 Sorbitol 3.0 Cationized cellulose * 1 1.0 Alkyl methacrylate polymer (R = butyl / ethyl) 5.0 Hydroxyethanediphosphonic acid 0.1 Tetrasodium edetate tetrahydrate 0.2 Vegetable squalane 0.5 Dimethylpolysiloxane (100 cs) 0.5 Potassium chloride 0.1 Triclosan 0.2 Benclay 0.8 Water Trace amount of potassium oxide 5-phenyl-5-methyl -3-Hexanone 2.0 Purified water Residual total 100.0% * 1 Lion Chemical XM-503LN or Leoguard GP or UCC Polymer-JR400 Packaging: Stretched nylon 10 μm / aluminum vacuum deposition (0.
8 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 100 μm

[Example 47] Body soap red algae water extract 0.5 potassium laurate 10.0 potassium myristate 10.0 N-lauroyl N-methyl β-alanine potassium 2.0 N-lauroyl glutamic acid monopotassium 2 Coconut oil fatty acid diethanolamide 3.0 lauryl dimethylamine oxide 1.0 propylene glycol 6.0 hydroxypropylmethyl cellulose * 1 0.5 ethylene glycol distearate 1.0 cationized cellulose * 2 0.1 polystyrene polymer (n = 300) 0.1 Tetrasodium edetate tetrahydrate 0.1 Ciclopirox olamine-Veegum T complex 1.0 Isojasmon 0.8 Perfume 0.1 Purified water Balance 100.0% * 1 Shin-Etsu Chemical Co., Ltd. Metrose Co., Ltd. 65SH-1500 * 2 Lion Chemical XM-503LN or Rheogard GP or UCC Polymer-JR400 Packaging: Stretched nylon 10 μm / aluminum vacuum deposition (0.
08 μm) polyethylene terephthalate 11 μm / linear low-density polyethylene 150 μm

[Example 48] Body soap red algae water extract 1.0 potassium laurate 10.0 potassium myristate 10.0 N-lauroyl N-methyl β-alanine potassium 2.0 N-lauroyl glutamic acid monopotassium 2 Coconut oil fatty acid diethanolamide 3.0 lauryl dimethylamine oxide 1.0 propylene glycol 6.0 hydroxypropylmethyl cellulose * 1 0.5 ethylene glycol distearate 1.0 cationized cellulose * 2 0.1 polystyrene polymer (n = 300) 0.1 Tetrasodium edetate tetrahydrate 0.1 Ciclopirox olamine 0.2 Benclay 1.0 Isojasmon 0.8 Purified water Balance 100.0% * 1 Shin-Etsu Chemical Co., Ltd. Metroose 65SH -1500 * 2 Lion Chemistry XM-503LN or Rheogard GP or UCC Polymer-JR400 packaging material: stretched nylon 10 μm / aluminum vacuum deposition (0.
08 μm) polyethylene terephthalate 11 μm / linear low-density polyethylene 150 μm

[Example 49] Cleansing gel Red algae water extract 0.5 Triethanolamine myristate 6.0 N-lauroyl N-methyl β-alanine potassium 2.0 Coconut oil fatty acid diethanolamide (Homelead CD, Lion Chemical Co., Ltd. 3.0 Lauryl dimethylamine oxide (Aromox DM 12DW (C), Lion Chemical Co., Ltd.) 1.0 Polyoxyethylene behenyl alcohol (10.EO) (BHA-10, Nippon Emulsion Co., Ltd.) ) 3.0 Methyl polysiloxane (SH200C-30cs, Toray Dow Corning Silicone Co., Ltd.) 1.0 Isononyl isononanoate 2.0 Hydroxypropyl methylcellulose (Metrose HPMC 60SH-4000, Shin-Etsu Chemical Co., Ltd.) 0. 5 Methacrylic acid Kill polymer emulsion (Leo Earl MS-200, Lion Chemical Co., Ltd.) 0.3 Propylene glycol 5.0 Isopropylmethylphenol 0.1 Bentonite (LAPONITE XLG, Nippon Silica Co., Ltd.) 0.3 Polyethylene powder (average particle size) 100 μM) 0.3 Triethanolamine Adjusted to pH 8 Furfuran 1-acetone 2.0 Perfume 0.15 Purified water Balance 100.0% Packaging material: Stretched nylon 10 μm / aluminum vacuum deposition (0.
5 μm) polyethylene terephthalate 10 μm / linear low density polyethylene 78 μm

[Example 50] Cream-like detergent Red algae water extract 0.5 Lauric acid 2.0 Myristic acid 18.0 Palmitic acid 8.0 Stearic acid 8.0 N Lauroyl N-methyl β-alanine potassium 3.0 N sodium myristoyl glutamate (Amisoft MS-11, Ajinomoto Co., Inc.) 2.0 potassium hydroxide 5.5 glycerin 15.0 polyethylene glycol (# 4000) 5.0 sorbitol 6.0 oleyl alcohol 1.0 purified lanolin 0.0. 5 Vegetable squalane 0.5 0- [2-hydroxy-3- (trimethylammonium) propyl] hydroxyethyl cellulose chloride (Rheogard GP, Lion Chemicals Co., Ltd.) 0.5 Hydroxyethanediphosphonic acid 0.1 Tetrasodium edetate Tetrahydrate 0.2 Potassium chloride 0.2 d Dihydrogen carba Non 2.0 Purified water balance Total 100.0% packaging orientated nylon 15 [mu] m / Aluminum vacuum deposition (0.
7 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 120 μm

[Example 51] Creamy detergent Red algae water extract 0.3 Lauric acid 2.0 Myristic acid 18.0 Palmitic acid 8.0 Stearic acid 8.0 N-Lauroyl N-methyl β-alanine potassium 3.0 Sodium N-myristoyl glutamate (Amisoft MS-11, Ajinomoto Co., Inc.) 2.0 Potassium hydroxide 5.5 Glycerin 15.0 PEG4000 5.0 Sorbitol 6.0 Oleyl alcohol 1.0 Purified lanolin 0.5 Plant-based squalane 0.5 Methyl polysiloxane (SH200C-10,000cs, Toray Dow Corning Silicone Co., Ltd.) 0.5 0- [2-hydroxy-3- (trimethylammonium) propyl] hydroxyethyl cellulose chloride (Rheogard GP , Lion Kagaku Co., Ltd. 0.5 Roxyethanediphosphonic acid 0.1 Tetrasodium edetate tetrahydrate 0.2 Potassium chloride 0.2 Triclosan 0.2 Bentonite (Kunipia G, Kunimine Co., Ltd.) 0.8 d-Dihydrocarbanone 2.0 Perfume 0.1 Purified water Residual total 100.0% Packaging material: Stretched nylon 15 μm / Aluminum vacuum deposition (0.
7 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 120 μm

[Example 52] Water extract of Rhododendron chinensis 0.3 Hydroxybenzophenone 0.1 Isostearyl myristate 1.0 Cationized cellulose * 1 1.0 Stearyltrimethylammonium chloride 1.0 Stearyl alcohol 3.0 Polyoxyethylene (20EO) hydrogenated castor oil 1.0 propylene glycol 5.0 p-methoxyphenylacetone 0.2 purified water balance 100.0% * 2 Mitsubishi Yuka Yukaformer AM75201 packaging material: stretched nylon 15 μm / aluminum vacuum deposition (0.
8 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 100 μm

[Example 53] Water extract of Rhododendron chinensis 0.5 hydroxybenzophenone 0.005 4-tert-butyl-4'-methoxy-dibenzoylmethane 0.005 isostearyl myristate 1.0 cationized cellulose * 1 1.0 Stearyl trimethyl ammonium chloride 1.0 Stearyl alcohol 3.0 Polyoxyethylene (20 EO) Hydrogenated castor oil 1.0 Propylene glycol 5.0 p-Methoxyphenylacetone 2.0 Purified water Residual total 100 0.0% * 2 Yukaformer AM75201 manufactured by Mitsubishi Petrochemical Co., Ltd. Packaging material: stretched nylon 15 μm / aluminum vacuum deposition (0.
8 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 100 μm

Example 54 Conditioner 4-guanidinobutyllaurylamide 0.8 N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine 0.5 Polyethylene glycol (average molecular weight 5,000,000) ) 0.2 Behenic acid diethylaminoethylamide 0.2 Dimethyl silicon (viscosity 1 million cSt) 1.0 Dimethyl silicon (viscosity 100,000 cSt) 1.0 Dimethyl silicon (viscosity 50 cSt) 1.0 Diglycerin isopalmitate sebacin Acid condensate 1.0 Glycine 0.7 Cetanol 1.5 Behenyl alcohol 0.2 Oleyl alcohol 0.3 Oleic acid 0.2 Isostearic acid 0.2 Trimethylglycine 0.2 Arginine 0.3 Cysteine 0.3 Glyceryl monostearate 0.1 Sorbitan monolaurate 0.1 2,3-Pentanedione 0.01 Methyl paraoxybenzoate Suitable amount Propyl paraoxybenzoate Suitable amount Perfume Suitable amount Purified water balance 100.0% pH 3.4 Particle size 0.5 to 5 μm Viscosity 4500 cp / 25 ° C Packaging: Stretched nylon 15μm / Aluminum vacuum deposition (0.
2 μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 70 μm

Example 55 Treatment 4-guanidinobutyllaurylamide 1.5 Dimethylsilicone (viscosity 100,000 cSt) 1.0 Dimethylsilicone (viscosity 30 cSt) 1.5 Cetanol 1.5 Behenyl alcohol 3.0 Stearyl alcohol 2. 0 isostearic acid 0.2 glycerin 3.0 propylene glycol 5.0 glyceryl monostearate 0.1 sorbitan monolaurate 0.1 phosphoric acid appropriate amount methyl paraoxybenzoate appropriate amount propyl paraoxybenzoate appropriate amount flavinone 0.0003 perfume 0.3 purification Water balance 100.0% pH: 3.8 Particle size: 1 to 5 μm Viscosity: 130 cp / 25 ° C. Packaging material: Stretched nylon 14 μm / aluminum vacuum deposition (1 μ
m) polyethylene terephthalate 12 μm / linear low density polyethylene 50 μm

[Example 56] Treatment 4-guanidinobutyllaurylamide 1.5 Cetanol 1.6 Behenyl alcohol 0.2 Oleyl alcohol 0.2 Oleic acid 0.2 Isostearic acid 0.2 Oleyl oleate 0.2 Glycine 8 Trimethylglycine 0.2 Arginine 0.3 Cysteine 0.3 Glyceryl monostearate 0.1 Sorbitan monolaurate 0.1 Polyoxyethylene (40) hydrogenated castor oil 1.0 Phosphoric acid Suitable amount of methyl paraoxybenzoate Suitable amount of propyl paraoxybenzoate Appropriate amount L-meson 0.0005 Fragrance 0.2 Purified water Balance 100.0% Total pH: 3.4 Particle size: 0.01 to 5 μm Viscosity: 6500 cp / 25 ° C. Appearance: Transparent gel-like packaging material: Stretched nylon 15 μm / Aluminum vacuum deposition (2μ
m) polyethylene terephthalate 12 μm / linear low-density polyethylene 100 μm

Example 57 Hair Foam N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer 3.0 Polyoxyethylene-modified silicone 0.5 3 -Methyl-1,3-butanediol 2.0 Squalane 0.1 Stearyltrimethylammonium chloride 0.5 Methylparaben 0.3 Triethanolamine 0.1 Nerone 0.1 Ethanol 20.0 Liquefied petroleum gas 7.0 Purified water residue Part total 100.0% Packaging material: Stretched nylon 15 μm / Aluminum vacuum deposition (0.
05 μm) polyethylene terephthalate 22 μm / linear low-density polyethylene 100 μm

Example 58 Hair Foam Methyl Polysiloxane 5.0 Polyoxyethylene / Polyoxypropylene Modified Silicone 0.5 3-Methyl-1,3-butanediol 2.0 Cationized Cellulose 0.1 N-Palm Oil fatty acid-L-glutamic acid 0.5 Polyoxyethylene (40) hydrogenated castor oil 0.4 Methylparaben 0.3 Citric acid 0.1 β-Damascone 0.1 Ethanol 20.0 Liquefied petroleum gas 7.0 Perfume 0.05 Purified water Residual total 100.0% Packaging material: Stretched nylon 5 μm / Aluminum vacuum deposition (0.3
μm) polyethylene terephthalate 12 μm / linear low-density polyethylene 100 μm

Example 59 Hair Water Polyoxyethylene Modified Silicone 0.5 3-Methyl-1,3-butanediol 2.0 Stearyltrimethylammonium Chloride 0.5 Methyl Polysiloxane 3.0 Polyoxyethylene Lauryl Ether 0 .4 Lauryl dimethylamine oxide 0.2 Sodium pyrrolidonecarboxylate 1.0 Methylparaben 0.3 Sodium citrate 0.1 Hydroxymethoxybenzophenonesulfonic acid 0.1 Dihydrojasmon 0.1 Ethanol 20.0 Perfume 0.1 Purified water Remainder total 100.0% Packaging material: Stretched nylon 10 μm / Aluminum vacuum deposition (0.
2 μm) polyethylene terephthalate 11 μm / linear low-density polyethylene 110 μm

The cosmetics sealed in the packaging material having the aluminum vacuum deposition layer of Examples 34 to 59 had good aroma stability, oxidation stability and light stability.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) A61K 7/08 A61K 7/08 7/50 7/50 B65D 1/09 B65D 1/00 BF term (reference) ) 3E033 AA01 BA09 BA15 BA18 BA21 BB08 CA16 GA02 4C083 AA112 AB012 AB032 AB052 AB332 AB352 AB442 AC012 AC022 AC062 AC072 AC111 AC122 AC132 AC182 AC211 AC212 AC242 AC252 AC302 AC312 AC342 AC422 AC432 AC442 AC472 AC482 AC522 AC542 AC562 AC582 AC622 AC642 AC662 AC692 AC712 AC782 AC792 AC842 AC852 AC902 AD022 AD042 AD092 AD132 AD152 AD202 AD282 AD412 AD512 AD532 BB41 CC23 CC24 CC32 CC33 CC38 CC39 DD08 DD23 DD27 DD31 DD47 EE01 EE11 EE21 FF06

Claims (3)

[Claims] 1. A vapor pressure of 0.001 mmH at 25 ° C. in a container made of a packaging material having an aluminum vapor deposition layer.
A refill cosmetic, comprising a composition containing a ketone-based fragrance having a gLB of 7 mmHg and an HLB of 2.0 to 13.0, which is hermetically sealed. 2. The refill cosmetic material according to claim 1, wherein the amount of the ketone-based fragrance compounded is 0.005 mass% to 1.0 mass% of the entire composition. 3. The refill cosmetic composition according to claim 1, further comprising a polyol and / or a derivative thereof in an amount of 0.1% by mass to 30% by mass of the total composition.