JP2003180165A - Plant nitric acid-reducing agent - Google Patents

Plant nitric acid-reducing agent

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Publication number
JP2003180165A
JP2003180165A JP2001384756A JP2001384756A JP2003180165A JP 2003180165 A JP2003180165 A JP 2003180165A JP 2001384756 A JP2001384756 A JP 2001384756A JP 2001384756 A JP2001384756 A JP 2001384756A JP 2003180165 A JP2003180165 A JP 2003180165A
Authority
JP
Japan
Prior art keywords
nitric acid
plant
reducing agent
acid
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001384756A
Other languages
Japanese (ja)
Inventor
Michinobu Takagi
道信 高木
Tsukasa Bodai
司 菩提
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eisai Seikaken Co Ltd
Original Assignee
Eisai Seikaken Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eisai Seikaken Co Ltd filed Critical Eisai Seikaken Co Ltd
Priority to JP2001384756A priority Critical patent/JP2003180165A/en
Publication of JP2003180165A publication Critical patent/JP2003180165A/en
Pending legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a plant nitric acid-reducing agent which can reduce the nitric acid content of a plant without causing growth retardation and yield reduction of the plant. <P>SOLUTION: This plant nitric acid-reducing agent is characterized by containing a water-soluble molybdic acid compound, an amino acid and a nucleic acid as main components. The plant nitric acid-reducing agent preferably further contains a part or all of nitrogen, phosphoric acid, potassium, manganese, boron, iron, copper, and zinc. It is preferable to apply a proper amount of the plant nitric acid-reducing agent to the leaves of plants. <P>COPYRIGHT: (C)2003,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、植物の硝酸低減剤
に関するものであり、さらに詳しくは植物、特に葉菜類
に含有している硝酸含量を低減させることができる植物
の硝酸低減剤に関するものである。
TECHNICAL FIELD The present invention relates to a plant nitric acid reducing agent, and more particularly to a plant nitric acid reducing agent capable of reducing the nitric acid content of plants, especially leaf vegetables. .

【0002】最近、地下水の硝酸汚染が問題となってお
り、同時に食品に含まれる硝酸についても消費者の関心
が高まってきている。硝酸による障害は、ヒト体内で還
元されて亜硝酸となり、ヘモグロビンと結合して酸素が
運搬できなくなるメトヘモグロビン血症があり、アメリ
カ、ヨーロッパなどでブルーベイビーとして報告されて
いる。また、牛でも同様な症状が問題となっており、硝
酸を多量に蓄積した飼料を食べた乳牛が脈拍や呼吸の上
昇、筋肉の痙攣を呈し、重症になると死に至ることも報
告されている。
Recently, nitric acid contamination of groundwater has become a problem, and at the same time, consumers are also interested in nitric acid contained in foods. The damage caused by nitric acid is methemoglobinemia, which is reduced in the human body to become nitrite, which binds to hemoglobin and cannot carry oxygen, and is reported as blue baby in the United States and Europe. It has also been reported that the same symptom also becomes a problem in cattle, and that dairy cattle fed with a feed in which a large amount of nitric acid is accumulated exhibit increased pulse and respiration, muscle spasms, and death in severe cases.

【0003】[0003]

【従来の技術】植物は、土壌に含まれる硝酸を吸収して
生育するため、窒素肥料の施用量が植物の硝酸含量に大
きく影響することは知られている。
2. Description of the Related Art Since plants grow by absorbing nitric acid contained in soil, it is known that the amount of nitrogen fertilizer applied greatly affects the nitrate content of plants.

【0004】一方、硝酸は、植物の生長には不可欠な栄
養素である。植物は、生長に必要な蛋白質を体内で合成
するため、硝酸を好んで吸収する。吸収された硝酸はア
ンモニアになり、光合成で合成された有機酸と反応して
アミノ酸となり、蛋白質となる。
On the other hand, nitric acid is an essential nutrient for plant growth. Plants prefer to absorb nitric acid because they synthesize the proteins necessary for growth in the body. The absorbed nitric acid becomes ammonia, which reacts with the organic acid synthesized by photosynthesis to become an amino acid and becomes a protein.

【0005】窒素肥料の施用量を極端に減らすことで、
植物の硝酸は減少するが、生育の遅延、収量の低下など
が発生する。したがって、生育遅延および収量低下を発
生させることなく、植物の硝酸含量を低減させることは
困難であった。
By extremely reducing the application rate of nitrogen fertilizer,
Nitric acid in plants decreases, but growth retardation and decrease in yield occur. Therefore, it was difficult to reduce the nitrate content of plants without causing growth delay and yield reduction.

【0006】植物の硝酸低減剤としては、様々な硝酸低
減剤が提案されている。具体的には、例えば特許第2793
583号の特許公報には、紅藻または緑藻からの抽出物、
カルシウム化合物、有機酸、およびリン酸化合物を含有
する硝酸態窒素濃度低減剤が提案されており、モリブデ
ンを利用する方法として、特開平10-218713号公報に
は、モリブデン、アンモニア態窒素およびキトサンを含
有する植物用葉面散布剤が提案されている。
Various nitric acid reducing agents have been proposed as a nitric acid reducing agent for plants. Specifically, for example, Patent No. 2793
Patent publication No. 583 describes extracts from red algae or green algae,
A nitrate nitrogen concentration reducing agent containing a calcium compound, an organic acid, and a phosphoric acid compound has been proposed, and as a method of using molybdenum, Japanese Patent Laid-Open No. 10-218713 discloses molybdenum, ammoniacal nitrogen and chitosan. A foliar spray for plants containing it has been proposed.

【0007】しかし、前記の特許第2793583号の特許公
報、特開平10-218713号公報のいずれにも、アミノ酸お
よび核酸を硝酸低減に適用することに関する記載はな
い。
[0007] However, there is no description concerning application of amino acids and nucleic acids to nitric acid reduction in the above-mentioned Japanese Patent No. 2793583 and Japanese Patent Laid-Open No. 10-218713.

【0008】[0008]

【発明が解決しようとする課題】本発明の目的は植物の
生育遅延および収量低下を発生させることなく、植物の
硝酸含量を低減させることができる植物の硝酸低減剤を
提供することである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a plant nitric acid reducing agent which can reduce the nitric acid content of a plant without causing growth delay and reduction of the yield of the plant.

【0009】[0009]

【課題を解決するための手段】本発明者等は、前記課題
を解決すべく鋭意研究に努めた結果、水溶性モリブデン
酸化合物、アミノ酸および核酸を主成分として含有する
資材を植物に葉面散布することにより、生育遅延および
収量低下を発生させることなく、植物の硝酸含量を低減
できることを見いだし、本発明を完成するに至った。
Means for Solving the Problems As a result of intensive research to solve the above-mentioned problems, the inventors of the present invention sprayed a plant with a material containing a water-soluble molybdate compound, an amino acid and a nucleic acid as main components. By doing so, it was found that the nitrate content of the plant can be reduced without causing growth delay and reduction in yield, and the present invention has been completed.

【0010】すなわち、本発明の請求項1に記載した植
物の硝酸低減剤は、水溶性モリブデン酸化合物、アミノ
酸および核酸を含有することを特徴とする。
That is, the plant nitric acid reducing agent according to claim 1 of the present invention is characterized by containing a water-soluble molybdate compound, an amino acid and a nucleic acid.

【0011】本発明の請求項2に記載の植物の硝酸低減
剤は、請求項1記載の植物の硝酸低減剤において、アミ
ノ酸および核酸は、有機物の抽出物からなることを特徴
とする。
The plant nitric acid reducing agent according to claim 2 of the present invention is characterized in that, in the plant nitric acid reducing agent according to claim 1, the amino acid and the nucleic acid are composed of an extract of organic matter.

【0012】本発明の請求項3に記載の植物の硝酸低減
剤は、請求項2記載の植物の硝酸低減剤において、アミ
ノ酸および核酸が含まれる有機物は、魚または/および
酵母に由来するものであることを特徴とする。
The plant nitric acid reducing agent according to claim 3 of the present invention is the plant nitric acid reducing agent according to claim 2, wherein the organic matter containing amino acids and nucleic acids is derived from fish or / and yeast. It is characterized by being.

【0013】本発明の請求項4に記載の植物の硝酸低減
剤は、請求項1〜3のいずれかに記載の植物の硝酸低減
剤において、葉面散布剤であることを特徴とする。
The plant nitric acid reducing agent according to claim 4 of the present invention is the plant nitric acid reducing agent according to any one of claims 1 to 3, which is a foliar spraying agent.

【0014】[0014]

【発明の実施の形態】次に本発明の内容を詳細に説明す
る。本発明は、前記のように本発明者等により、水溶性
モリブデン酸化合物、アミノ酸および核酸を植物に葉面
散布することにより、植物の生育遅延および収量低下を
発生させることなく、植物の硝酸含量を低減できるとい
う新しい機能を有することを初めて見いだしたことに基
づいて成されたものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the contents of the present invention will be described in detail. As described above, the present inventors have applied the water-soluble molybdate compound, amino acid and nucleic acid to plants by foliar application as described above, without causing plant growth retardation and yield decrease, and the nitrate content of the plants. It was made based on the first discovery of having a new function that can reduce the.

【0015】本発明で用いる水溶性モリブデン酸化合物
は水溶性を有するモリブデン酸化合物であればよく、特
に限定されるものではなく、具体的には、例えばアンモ
ニウム、カリウム、ナトリウムなどの化合物として販売
されている市販品を挙げることができる。これらの市販
品は安定的に容易に入手できる資材であるので好ましく
使用できる。
The water-soluble molybdic acid compound used in the present invention is not particularly limited as long as it is a water-soluble molybdic acid compound, and specifically, it is sold as a compound such as ammonium, potassium or sodium. There are commercially available products. Since these commercially available products are stable and easily available materials, they can be preferably used.

【0016】これらに加えて本発明で用いるアミノ酸お
よび核酸についても特に限定されるものではない。本発
明で用いるアミノ酸および核酸としては、具体的には、
例えばアミノ酸および核酸を含む魚や酵母などの有機物
の抽出物を挙げることができる。これらの有機物の抽出
物は安定的に容易に入手でき、かつ安価であり、製剤化
も容易で利用しやすい資材であるので好ましく使用でき
る。
In addition to these, the amino acids and nucleic acids used in the present invention are not particularly limited. As the amino acids and nucleic acids used in the present invention, specifically,
Examples thereof include extracts of organic substances such as fish and yeast containing amino acids and nucleic acids. Extracts of these organic substances can be used preferably because they are stable and easily available, inexpensive, easy to formulate and easy to use.

【0017】本発明の植物の硝酸低減剤における作用機
作は、まだ解明されていない。本発明の植物の硝酸低減
剤には、水溶性モリブデン酸化合物を使用している。一
方、植物の硝酸還元酵素にはモリブデンイオンが含まれ
ており、この酵素が充分に働かないと、植物体内の硝酸
を還元できずに蓄積される。このことから、本発明の植
物の硝酸低減剤には、硝酸還元酵素に含まれるモリブデ
ンイオンを水溶性モリブデン酸化合物として含有し、さ
らに、水溶性モリブデン酸化合物の水溶液を単独で使用
した以上に植物の硝酸含量を低減する効果があった。こ
れは、水溶性モリブデン酸化合物と、アミノ酸および核
酸との相乗効果による未解明の作用機作があると考えら
れる。勿論本発明の植物の硝酸低減剤における作用機作
はこの考え方に限定されるものではない。
The mechanism of action of the plant nitric acid reducing agent of the present invention has not yet been elucidated. A water-soluble molybdic acid compound is used as the plant nitric acid reducing agent. On the other hand, plant nitrate reductase contains molybdenum ions. If this enzyme does not work sufficiently, nitrate in the plant cannot be reduced and is accumulated. From this, the plant nitric acid reducing agent of the present invention contains molybdenum ions contained in nitrate reductase as a water-soluble molybdate compound, and further, the aqueous solution of the water-soluble molybdate compound is used alone as a plant. It had the effect of reducing the nitric acid content of. It is considered that there is an unclear mechanism of action due to the synergistic effect of the water-soluble molybdate compound and amino acids and nucleic acids. Of course, the mechanism of action of the plant nitric acid reducing agent of the present invention is not limited to this idea.

【0018】本発明の植物の硝酸低減剤は、水溶性モリ
ブデン酸化合物、アミノ酸および核酸を含有した製剤で
ある。本発明でいう製剤とは、水溶液などの液状物、顆
粒剤、錠剤、パック剤、粉末、カプセルなどを包含す
る。
The plant nitric acid reducing agent of the present invention is a preparation containing a water-soluble molybdate compound, an amino acid and a nucleic acid. The term “formulation” as used in the present invention includes liquid substances such as aqueous solutions, granules, tablets, packs, powders and capsules.

【0019】本発明の植物の硝酸低減剤には、さらに、
植物の栄養素である窒素、リン酸、カリウムを適宜加え
ることができる。さらに、植物の代謝を潤滑にするため
にマンガン、鉄、銅、亜鉛、ホウ素などのミネラルを適
宜加えることができる。
The plant nitric acid reducing agent of the present invention further includes
Nitrogen, phosphoric acid, and potassium, which are plant nutrients, can be appropriately added. Further, minerals such as manganese, iron, copper, zinc, and boron can be appropriately added to lubricate the metabolism of plants.

【0020】本発明の植物の硝酸低減剤には、さらに、
製剤の沈殿や変質を防ぐためにエチレンジアミン四酢酸
・四ナトリウムなどのキレート剤を必要に応じて、適宜
加えることができる。さらに、製剤を植物の葉に展着、
浸透させ、吸収しやすくするために、糖や界面活性剤を
必要に応じて、適宜加えることができる。
The plant nitric acid reducing agent of the present invention further includes
A chelating agent such as ethylenediaminetetraacetic acid / tetrasodium can be appropriately added as necessary in order to prevent precipitation or deterioration of the preparation. Furthermore, spread the formulation on the leaves of the plant,
If necessary, sugar or a surfactant may be appropriately added in order to permeate and facilitate absorption.

【0021】本発明の植物の硝酸低減剤には、水溶性モ
リブデン酸化合物、アミノ酸および核酸の3成分が含有
されることが肝要であり、これらの成分の内の1成分あ
るいは2成分のみでは植物の生育遅延および収量低下を
発生させることなく、植物の硝酸含量を低減するという
優れた効果を得ることができない。
It is essential that the plant nitric acid reducing agent of the present invention contains three components of a water-soluble molybdic acid compound, an amino acid and a nucleic acid, and only one or two of these components are used for the plant. It is not possible to obtain the excellent effect of reducing the nitric acid content of the plant without causing the growth delay and the decrease in the yield.

【0022】水溶性モリブデン酸化合物、アミノ酸およ
び核酸の3成分の配合割合は特に限定されるものではな
い。しかし、通常、水溶性モリブデン酸化合物中のモリ
ブデン:アミノ酸:核酸の質量比は1:0.1〜2:
0.01〜1の範囲であることが好ましい。この範囲外
であると本発明の効果が小さくなる恐れがある。
The mixing ratios of the three components of the water-soluble molybdic acid compound, amino acid and nucleic acid are not particularly limited. However, the mass ratio of molybdenum: amino acid: nucleic acid in the water-soluble molybdate compound is usually 1: 0.1-2:
It is preferably in the range of 0.01 to 1. If it is out of this range, the effect of the present invention may be reduced.

【0023】本発明の植物の硝酸低減剤の使用方法は特
に限定されないが、植物の地上部への散布であり、その
濃度は使用に際して、水で希釈してモリブデンの濃度が
植物の硝酸低減剤全体に対して10〜200ppm(質
量)、好ましくは30〜100ppm(質量)になるよ
うに調節して、植物に葉面散布することが好ましい。1
0ppm未満であると植物の硝酸低減効果が出ない恐れ
があり、200ppmを超えると植物に害を与える恐れ
があるので好ましくない。
The method of using the plant nitric acid reducing agent of the present invention is not particularly limited, but it is spraying to the aerial part of the plant, and the concentration thereof is diluted with water at the time of use so that the molybdenum concentration is a plant nitric acid reducing agent. It is preferable to adjust to 10 to 200 ppm (mass), preferably 30 to 100 ppm (mass) with respect to the whole, and to spray the leaves on plants. 1
If it is less than 0 ppm, the nitric acid reducing effect of the plant may not be obtained, and if it exceeds 200 ppm, the plant may be damaged, which is not preferable.

【0024】本発明の植物の硝酸低減剤の使用時期は特
に限定されないが、例えば葉菜類の収穫2週間前から収
穫までに1〜3回、好ましくは2〜3回使用できる。
The use period of the plant nitric acid reducing agent of the present invention is not particularly limited. For example, it can be used 1 to 3 times, preferably 2 to 3 times from 2 weeks before the harvest of leaf vegetables to the harvest.

【0025】[0025]

【実施例】以下、実施例および比較例により本発明を説
明するが、本発明はこれらの実施例により何ら限定され
るものではない。なお以下の実施例、比較例に記載の
%、ppmは、質量%、質量ppmをそれぞれ示す。 (実施例1) (本発明の植物の硝酸低減剤の調製)モリブデン酸アン
モニウムをMoとして2.0%、酵母抽出物(アミノ酸
を27%、核酸を7%含む)を2.0%になるように水
溶液を作り、この水溶液を安定させるためにエチレンジ
アミン四酢酸・四ナトリウムを適量加え、さらに葉面散
布の効果を高めるために糖と界面活性剤を適量加えた水
溶液を調製して、本発明の植物の硝酸低減剤1を作成し
た。
The present invention will be described below with reference to examples and comparative examples, but the present invention is not limited to these examples. In the following Examples and Comparative Examples,% and ppm indicate mass% and mass ppm, respectively. (Example 1) (Preparation of plant nitric acid reducing agent of the present invention) Ammonium molybdate is 2.0% as Mo, and yeast extract (27% amino acids and 7% nucleic acids are included) is 2.0%. As described above, an aqueous solution is prepared by adding an appropriate amount of ethylenediaminetetraacetic acid / tetrasodium to stabilize the aqueous solution, and further adding an appropriate amount of sugar and a surfactant to enhance the foliar spraying effect. A plant nitric acid reducing agent 1 was prepared.

【0026】このようにして調製した植物の硝酸低減剤
1を300倍に希釈(モリブデン濃度は67ppm)し
た水溶液を、ホウレンソウ(品種はアクティブ)に7日
間隔で2回葉面散布した。ホウレンソウはガラスハウス
内で栽培し、最後の葉面散布から1週間後に、ホウレン
ソウの地上部を採取し、硝酸含量を調査した。その結果
を表1に示す。
An aqueous solution prepared by diluting the plant nitric acid reducing agent 1 thus prepared 300 times (molybdenum concentration: 67 ppm) was sprayed onto spinach (variety: active) twice every 7 days. The spinach was cultivated in a glass house, and one week after the last foliar application, the above-ground part of the spinach was collected and the nitric acid content was investigated. The results are shown in Table 1.

【0027】(比較例1)葉面散布しないホウレンソウ
を実施例1と同様に硝酸含量を調査した。その結果を実
施例1に加えて表1に示す。
Comparative Example 1 Spinach without foliar application was examined for nitric acid content as in Example 1. The results are shown in Table 1 in addition to Example 1.

【0028】(比較例2)本発明の植物の硝酸低減剤1
を用いる替わりに、モリブデン酸アンモニウムをMoと
して67ppmになるように水溶液を作り、この水溶液
を安定させるためにエチレンジアミン四酢酸・四ナトリ
ウムを適量加え、さらに葉面散布の効果を高めるために
糖と界面活性剤を適量加えた水溶液をホウレンソウに7
日間隔で2回葉面散布した。このホウレンソウを実施例
1と同様に硝酸含量を調査した。その結果を実施例1に
加えて表1に示す。
Comparative Example 2 Plant Nitric Acid Reducing Agent 1 of the Present Invention
Instead of using ammonium molybdate, prepare an aqueous solution so that the molybdenum content is 67 ppm, add an appropriate amount of ethylenediaminetetraacetic acid / tetrasodium to stabilize the aqueous solution, and add sugar and an interface to enhance the effect of foliar application. Spinach with an aqueous solution containing an appropriate amount of activator
Foliar spray was applied twice at daily intervals. The nitric acid content of this spinach was investigated in the same manner as in Example 1. The results are shown in Table 1 in addition to Example 1.

【0029】[0029]

【表1】 [Table 1]

【0030】表1に示したように、比較例2のモリブデ
ン酸アンモニウム水溶液を葉面散布したホウレンソウ
は、比較例1の無散布に比べ、硝酸をあまり低減しない
ことが判る。
As shown in Table 1, it is understood that the spinach on which the aqueous solution of ammonium molybdate of Comparative Example 2 was sprayed on the leaves did not reduce nitric acid so much as compared with the non-spreading of Comparative Example 1.

【0031】一方、本発明の植物の硝酸低減剤1を用い
た場合、比較例1の無散布に比べ、硝酸含量が少なく、
生育が遅延することなく、ホウレンソウの硝酸を低減で
きることが判る。さらに、比較例2のモリブデン酸アン
モニウム水溶液を葉面散布したホウレンソウに比べて
も、明らかに硝酸含量が少ないことが判る。
On the other hand, when the plant nitric acid reducing agent 1 of the present invention was used, the nitric acid content was smaller than that of the non-sprayed product of Comparative Example 1,
It can be seen that nitric acid in spinach can be reduced without delaying growth. Further, it can be seen that the nitric acid content is obviously lower than that of spinach in which the aqueous solution of ammonium molybdate of Comparative Example 2 is sprayed on the leaves.

【0032】(実施例2)植物の硝酸低減剤1を300
倍に希釈(モリブデン濃度は67ppm)した水溶液
を、ホウレンソウ(品種はソロモン)に7日間隔で2回
葉面散布した。ホウレンソウはビニルハウス内で栽培
し、最後の葉面散布から8日後に、ホウレンソウの地上
部を採取し、硝酸含量を調査した。その結果を表2に示
す。
(Example 2) 300 nitric acid reducing agent 1 for plants
An aqueous solution diluted twice (molybdenum concentration: 67 ppm) was sprayed on spinach (Solomon cultivar) twice at 7-day intervals. The spinach was cultivated in a vinyl house, and 8 days after the last foliar application, the above-ground part of the spinach was collected and the nitric acid content was investigated. The results are shown in Table 2.

【0033】(比較例3)葉面散布しないホウレンソウ
を実施例2と同様に硝酸含量を調査した。その結果を実
施例2に加えて表2に示す。
Comparative Example 3 Spinach which was not sprayed on leaves was examined for nitric acid content in the same manner as in Example 2. The results are shown in Table 2 in addition to Example 2.

【0034】(比較例4)本発明の植物の硝酸低減剤1
を用いる替わりに、酵母抽出物(アミノ酸を27%、核
酸を7%含む)を2.0%になるように水溶液を作り、
この水溶液を安定させるためにエチレンジアミン四酢酸
・四ナトリウムを適量加え、さらに葉面散布の効果を高
めるために糖と界面活性剤を適量加えた水溶液をホウレ
ンソウに7日間隔で2回葉面散布した。このホウレンソ
ウを実施例2と同様に硝酸含量を調査した。その結果を
実施例2に加えて表2に示す。
(Comparative Example 4) Nitric acid reducing agent 1 for plants of the present invention
Instead of using, make an aqueous solution of yeast extract (containing 27% amino acids and 7% nucleic acids) to 2.0%,
An appropriate amount of ethylenediaminetetraacetic acid / tetrasodium was added to stabilize this aqueous solution, and an aqueous solution containing an appropriate amount of sugar and a surfactant to further enhance the effect of foliar application was applied to spinach twice at 7-day intervals. . The nitric acid content of this spinach was investigated in the same manner as in Example 2. The results are shown in Table 2 in addition to Example 2.

【0035】[0035]

【表2】 [Table 2]

【0036】表2に示したように、比較例4の酵母抽出
物水溶液を葉面散布したホウレンソウは、比較例3の無
散布に比べ、硝酸をあまり低減しないことが判る。
As shown in Table 2, the spinach on which the yeast extract aqueous solution of Comparative Example 4 was sprayed on the leaves did not reduce nitric acid so much as compared to the non-spreading of Comparative Example 3.

【0037】一方、本発明の植物の硝酸低減剤1を用い
た場合、比較例3の無散布に比べ、硝酸含量が少なく、
生育が遅延することなく、ホウレンソウの硝酸を低減で
きることが判る。さらに、比較例4の酵母抽出物水溶液
を葉面散布したホウレンソウに比べても、明らかに硝酸
含量が少ないことが判る。
On the other hand, when the plant nitric acid reducing agent 1 of the present invention was used, the nitric acid content was smaller than that of the non-sprayed product of Comparative Example 3,
It can be seen that nitric acid in spinach can be reduced without delaying growth. Further, it is clear that the nitric acid content is obviously lower than that of spinach in which the aqueous solution of the yeast extract of Comparative Example 4 was sprayed on the leaves.

【0038】(実施例3) (本発明の植物の他の硝酸低減剤の調製)モリブデン酸
アンモニウムをMoとして2.0%、魚抽出物(アミノ
酸を35%、核酸を1%含む)を5.0%、リン酸をP
25として10.0%、カリウムをK2Oとして9.0
%、マンガンをMnOとして0.07%、ホウ素をB2
3として0.2%、鉄をFeとして0.08%、銅を
Cuとして0.05%、亜鉛をZnとして0.05%に
なるように水溶液を作り、この水溶液を安定させるため
にエチレンジアミン四酢酸・四ナトリウムを適量加え、
さらに葉面散布の効果を高めるために糖と界面活性剤を
適量加えた水溶液を調製して、本発明の植物の硝酸低減
剤2を作成した。
(Example 3) (Preparation of another plant nitric acid reducing agent of the present invention) 2.0% ammonium molybdate and 5% fish extract (containing 35% amino acid and 1% nucleic acid) 0.0%, phosphoric acid P
10.0% as 2 O 5 , 9.0 as potassium K 2 O
%, Manganese as MnO 0.07%, boron as B 2
O 3 was 0.2%, iron was 0.08%, Cu was 0.05%, and zinc was 0.05%. Ethylenediamine was added to stabilize the aqueous solution. Add an appropriate amount of tetraacetic acid / tetrasodium,
Further, in order to enhance the effect of foliar application, an aqueous solution containing an appropriate amount of sugar and a surfactant was prepared to prepare a plant nitric acid reducing agent 2 of the present invention.

【0039】植物の硝酸低減剤2を300倍に希釈(モ
リブデン濃度は67ppm)した水溶液を、ホウレンソ
ウ(品種はソロモン)に8日間隔で2回葉面散布した。
ホウレンソウはビニルハウス内で栽培し、最後の葉面散
布から6日後に、ホウレンソウの地上部を採取し、硝酸
含量を調査した。その結果を表3に示す。
An aqueous solution prepared by diluting the plant nitric acid reducing agent 2 by 300 times (molybdenum concentration: 67 ppm) was sprayed onto spinach (Solomon variety) twice every 8 days.
The spinach was cultivated in a vinyl house, and 6 days after the last foliar application, the above-ground part of the spinach was collected and the nitric acid content was investigated. The results are shown in Table 3.

【0040】(比較例5)葉面散布しないホウレンソウ
を実施例3と同様に硝酸含量を調査した。その結果を実
施例3に加えて表3に示す。
Comparative Example 5 Spinach which was not sprayed on leaves was examined for nitric acid content in the same manner as in Example 3. The results are shown in Table 3 in addition to Example 3.

【0041】(比較例6)本発明の植物の硝酸低減剤2
を用いる替わりに、モリブデン酸アンモニウムをMoと
して2.0%、ゼラチン加水分解物(アミノ酸を40%
含む)を5.0%、リン酸をP25として10.0%、
カリウムをK2Oとして9.0%、マンガンをMnOと
して0.07%、ホウ素をB23として0.2%、鉄を
Feとして0.08%、銅をCuとして0.05%、亜
鉛をZnとして0.05%になるように水溶液を作り、
この水溶液を安定させるためにエチレンジアミン四酢酸
・四ナトリウムを適量加え、さらに葉面散布の効果を高
めるために糖と界面活性剤を適量加えた水溶液をホウレ
ンソウに8日間隔で2回葉面散布した。このホウレンソ
ウを実施例3と同様に硝酸含量を調査した。その結果を
実施例3に加えて表3に示す。
COMPARATIVE EXAMPLE 6 The plant nitric acid reducing agent 2 of the present invention
Instead of using ammonium molybdate as Mo, 2.0%, gelatin hydrolyzate (40% amino acid
5.0%, including phosphoric acid as P 2 O 5 10.0%,
Potassium as K 2 O 9.0%, manganese as MnO 0.07%, boron as B 2 O 3 0.2%, iron as Fe 0.08%, copper as Cu 0.05%, Make an aqueous solution so that zinc is 0.05%, and
An appropriate amount of ethylenediaminetetraacetic acid / tetrasodium was added to stabilize this aqueous solution, and an aqueous solution containing an appropriate amount of sugar and a surfactant to further enhance the effect of foliar application was applied to spinach twice on foliar leaves at 8-day intervals. . The nitric acid content of this spinach was investigated in the same manner as in Example 3. The results are shown in Table 3 in addition to Example 3.

【0042】[0042]

【表3】 [Table 3]

【0043】表3に示したように、比較例6のモリブデ
ン酸アンモニウム、ゼラチン加水分解物水溶液を葉面散
布したホウレンソウは、比較例5の無散布に比べ、硝酸
をあまり低減しないことが判る。
As shown in Table 3, it is understood that the spinach on which the aqueous solution of ammonium molybdate and gelatin hydrolyzate of Comparative Example 6 was sprayed on the leaves did not reduce nitric acid so much as compared to the non-sprayed product of Comparative Example 5.

【0044】一方、本発明の植物の硝酸低減剤2を用い
た場合、比較例5の無散布に比べ、硝酸含量が少なく、
生育が遅延することなく、ホウレンソウの硝酸を低減で
きることが判る。さらに、比較例6のモリブデン酸アン
モニウム、ゼラチン加水分解物水溶液を葉面散布したホ
ウレンソウに比べても、明らかに硝酸含量が少ないこと
が判る。
On the other hand, when the plant nitric acid reducing agent 2 of the present invention was used, the nitric acid content was lower than that of the non-sprayed product of Comparative Example 5,
It can be seen that nitric acid in spinach can be reduced without delaying growth. Further, it is clear that the nitric acid content is obviously smaller than that of the spinach in which the aqueous solution of ammonium molybdate and gelatin hydrolyzate of Comparative Example 6 was sprayed on the leaves.

【0045】(実施例4) (本発明の植物の他の硝酸低減剤の調製)モリブデン酸
アンモニウムをMoとして2.0%、酵母抽出物(アミ
ノ酸を27%、核酸を7%含む)を2.0%、リン酸を
25として10.0%、カリウムをK2Oとして9.
0%、マンガンをMnOとして0.07%、ホウ素をB
2 3として0.2%、鉄をFeとして0.08%、銅を
Cuとして0.05%、亜鉛をZnとして0.05%に
なるように水溶液を作り、この水溶液を安定させるため
にエチレンジアミン四酢酸・四ナトリウムを適量加え、
さらに葉面散布の効果を高めるために糖と界面活性剤を
適量加えた水溶液を調製して、本発明の植物の硝酸低減
剤3を作成した。
(Example 4) (Preparation of other nitric acid reducing agents for plants of the present invention) Molybdic acid
2.0% ammonium as Mo, yeast extract (ami
Noic acid 27%, nucleic acid 7% included) 2.0%, phosphoric acid
P2OFiveAs 10.0%, potassium as K2As O 9.
0%, manganese as MnO 0.07%, boron as B
2O 30.2%, iron as Fe 0.08%, copper
Cu as 0.05%, Zn as 0.05%
In order to stabilize this aqueous solution,
Add an appropriate amount of ethylenediaminetetraacetic acid / tetrasodium,
In addition, sugar and a surfactant are used to enhance the effect of foliar application.
Nitric acid reduction of the plant of the present invention by preparing an appropriate amount of aqueous solution
Agent 3 was prepared.

【0046】このようにして調製した植物の硝酸低減剤
3を300倍に希釈(モリブデン濃度は67ppm)し
た水溶液を、コマツナ(品種は楽天)に7日間隔で2回
葉面散布した。コマツナはビニルハウス内で栽培し、最
後の葉面散布から1週間後に、コマツナの地上部を採取
し、硝酸含量を調査した。その結果を表4に示す。
An aqueous solution prepared by diluting the plant nitric acid reducing agent 3 thus prepared 300 times (molybdenum concentration: 67 ppm) was sprayed twice on foliage at intervals of 7 days to Komatsuna (cultivar: Rakuten). Komatsuna was cultivated in a vinyl house, and one week after the last foliar application, the aerial part of the Komatsuna was collected and the nitric acid content was investigated. The results are shown in Table 4.

【0047】(比較例7)葉面散布しないコマツナを実
施例4と同様に硝酸含量を調査した。その結果を実施例
4に加えて表4に示す。
(Comparative Example 7) Komatsuna which was not sprayed on leaves was examined for nitric acid content in the same manner as in Example 4. The results are shown in Table 4 in addition to Example 4.

【0048】[0048]

【表4】 [Table 4]

【0049】表4に示したように、比較例7に比べ、本
発明の植物の硝酸低減剤3を用いた場合、生育が遅延す
ることなく、コマツナの硝酸を低減できることが判る。
As shown in Table 4, as compared with Comparative Example 7, it was found that when the plant nitric acid reducing agent 3 of the present invention was used, the nitric acid in komatsuna could be reduced without delaying the growth.

【0050】[0050]

【発明の効果】本発明の請求項1に記載した植物の硝酸
低減剤は、水溶性モリブデン酸化合物、アミノ酸および
核酸を含有するので、これらの相乗効果により植物の生
育遅延および収量低下を発生させることなく、植物の硝
酸含量を低減させることができるという顕著な効果を奏
する。
The plant nitric acid reducing agent according to claim 1 of the present invention contains a water-soluble molybdic acid compound, an amino acid and a nucleic acid. Therefore, the synergistic effect of these causes a delay in plant growth and a decrease in yield. Without this, the remarkable effect that the nitric acid content of the plant can be reduced is exhibited.

【0051】本発明の請求項2に記載の植物の硝酸低減
剤は、請求項1記載の植物の硝酸低減剤において、アミ
ノ酸および核酸は、有機物の抽出物からなるので、請求
項1記載の植物の硝酸低減剤と同じ効果を奏する上、有
機物の抽出物は安定的に容易に入手でき、製剤化も容易
で利用しやすいというさらなる効果を奏する。
The plant nitric acid reducing agent according to claim 2 of the present invention is the plant nitric acid reducing agent according to claim 1, wherein the amino acid and the nucleic acid consist of an extract of an organic matter. In addition to having the same effect as the nitric acid reducing agent, the extract of organic matter can be stably and easily obtained, and can be easily formulated and used.

【0052】本発明の請求項3に記載の植物の硝酸低減
剤は、請求項2記載の植物の硝酸低減剤において、アミ
ノ酸および核酸が含まれる有機物は、魚または/および
酵母に由来するものであるので、請求項2記載の植物の
硝酸低減剤と同じ効果を奏する上、魚や酵母はより容易
に入手でき、安価で利用しやすいというさらなる効果を
奏する。
The plant nitric acid reducing agent according to claim 3 of the present invention is the plant nitric acid reducing agent according to claim 2, wherein the organic matter containing amino acids and nucleic acids is derived from fish or / and yeast. Therefore, in addition to the same effect as the plant nitric acid reducing agent according to the second aspect, fish and yeast can be obtained more easily, and further, cheap and easy to use.

【0053】本発明の請求項4に記載の植物の硝酸低減
剤は、請求項1〜3のいずれかに記載の植物の硝酸低減
剤において、葉面散布剤であるので、請求項1〜3記載
の植物の硝酸低減剤と同じ効果を奏する上、植物に適用
し易く、効果が得られ易いというさらなる効果を奏す
る。
The plant nitric acid reducing agent according to claim 4 of the present invention is the foliar spray agent in the plant nitric acid reducing agent according to any one of claims 1 to 3, In addition to exhibiting the same effect as the plant nitric acid reducing agent described above, it further exerts the further effect of being easily applied to plants and easily obtaining the effect.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 水溶性モリブデン酸化合物、アミノ酸お
よび核酸を含有することを特徴とする植物の硝酸低減
剤。
1. A plant nitric acid reducing agent, which comprises a water-soluble molybdate compound, an amino acid and a nucleic acid.
【請求項2】 アミノ酸および核酸は、有機物の抽出物
からなることを特徴とする請求項1に記載の植物の硝酸
低減剤。
2. The plant nitric acid reducing agent according to claim 1, wherein the amino acid and the nucleic acid are extracts of an organic matter.
【請求項3】 アミノ酸および核酸が含まれる有機物
は、魚または/および酵母に由来するものであることを
特徴とする請求項2に記載の植物の硝酸低減剤。
3. The plant nitric acid reducing agent according to claim 2, wherein the organic matter containing amino acids and nucleic acids is derived from fish and / or yeast.
【請求項4】 葉面散布剤であることを特徴とする請求
項1〜3のいずれかに記載の植物の硝酸低減剤。
4. The plant nitric acid reducing agent according to claim 1, which is a foliar spray agent.
JP2001384756A 2001-12-18 2001-12-18 Plant nitric acid-reducing agent Pending JP2003180165A (en)

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ID=27594408

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Country Link
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006265199A (en) * 2005-03-25 2006-10-05 Oita Univ Foliar-surface spraying agent and method for producing the same
JP2007063213A (en) * 2005-09-01 2007-03-15 Oita Univ Foliar-surface spraying agent for reducing residual nitric acid in plant body
JP2007143506A (en) * 2005-11-29 2007-06-14 Kagoshima Univ Method for modifying color of flower of garden product using metal ion
JP2007222123A (en) * 2006-02-27 2007-09-06 National Agriculture & Food Research Organization Quality improvement and nitric acid-reducing technique for edible plant by supply of peptides
JP2008044854A (en) * 2006-08-10 2008-02-28 Kyoei Seika:Kk Plant growth activator and method for growing plant using the same plant growth activator
JP2011036226A (en) * 2009-08-18 2011-02-24 Akita Prefectural Univ Low potassium-containing leaf vegetable and method for cultivating the same
JP2011250744A (en) * 2010-06-02 2011-12-15 Aichi Steel Works Ltd Material for reducing cadmium, method for reducing cadmium using the same
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006265199A (en) * 2005-03-25 2006-10-05 Oita Univ Foliar-surface spraying agent and method for producing the same
JP4560723B2 (en) * 2005-03-25 2010-10-13 国立大学法人 大分大学 Foliar spray and method for producing the same
JP2007063213A (en) * 2005-09-01 2007-03-15 Oita Univ Foliar-surface spraying agent for reducing residual nitric acid in plant body
JP4565238B2 (en) * 2005-09-01 2010-10-20 国立大学法人 大分大学 Foliar spray for reducing residual nitric acid in plants
JP2007143506A (en) * 2005-11-29 2007-06-14 Kagoshima Univ Method for modifying color of flower of garden product using metal ion
JP2007222123A (en) * 2006-02-27 2007-09-06 National Agriculture & Food Research Organization Quality improvement and nitric acid-reducing technique for edible plant by supply of peptides
JP2008044854A (en) * 2006-08-10 2008-02-28 Kyoei Seika:Kk Plant growth activator and method for growing plant using the same plant growth activator
JP2011036226A (en) * 2009-08-18 2011-02-24 Akita Prefectural Univ Low potassium-containing leaf vegetable and method for cultivating the same
JP2011250744A (en) * 2010-06-02 2011-12-15 Aichi Steel Works Ltd Material for reducing cadmium, method for reducing cadmium using the same
JP2020514213A (en) * 2016-12-19 2020-05-21 ダンスター フェルマン アーゲー Methods and compositions for improving plant growth
US11377393B2 (en) 2016-12-19 2022-07-05 Danstar Ferment Ag Method and composition for improving plant growth
JP7138640B2 (en) 2016-12-19 2022-09-16 ダンスター フェルマン アーゲー Methods and compositions for enhancing plant growth

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