JP2003172584A5 - - Google Patents
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- JP2003172584A5 JP2003172584A5 JP2002288116A JP2002288116A JP2003172584A5 JP 2003172584 A5 JP2003172584 A5 JP 2003172584A5 JP 2002288116 A JP2002288116 A JP 2002288116A JP 2002288116 A JP2002288116 A JP 2002288116A JP 2003172584 A5 JP2003172584 A5 JP 2003172584A5
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- Prior art keywords
- oxygen
- source
- comparative examples
- powder
- refining
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Description
【0037】
なお、燃料流体としては、LNGのほか、LPG(液化石油ガス)、CO、H 2 、CO/H 2 混合ガスが使用できる。また、重油、灯油などの液体燃料を用いることもできる。[0037]
In addition to LNG, LPG (Liquefied Petroleum Gas), CO, H 2 and CO / H 2 mixed gas can be used as fuel fluid. Moreover, liquid fuels, such as heavy oil and kerosene, can also be used.
【0045】
溶解工程では、1≦酸素比<3を満たすようにするのが好ましい。これによって、固体原料の溶断、溶解を促すとともに、炉内で発生する一酸化炭素などの可燃成分を燃焼させることができる。
なお酸素比とは、燃料流体の完全燃焼に必要な酸素量に対して供給する酸素量の比をいう。
溶落ち以降の精錬工程では、燃料流体供給量を大幅に低く、好ましくは酸素比が3以上となるようにし、支燃性流体(酸素)を高速で吹き込むことによって、脱炭反応およびスラグフォーミングを促進しつつ、固体原料を溶解させることができる。[0045]
In the dissolution step, it is preferable to satisfy 1 ≦ oxygen ratio <3. Thus, melting and melting of the solid raw material can be promoted, and combustible components such as carbon monoxide generated in the furnace can be burned.
The oxygen ratio refers to the ratio of the amount of oxygen supplied to the amount of oxygen required for the complete combustion of the fuel fluid.
In the refining process after the meltdown, the decarburizing reaction and the slag forming can be performed by setting the fuel fluid supply amount significantly lower, preferably the oxygen ratio to be 3 or more, and blowing the flame retardant fluid (oxygen) at high speed. While promoting, solid raw materials can be dissolved.
【0050】
副原料としては、コークス、石炭などの固体炭素源:プラスチックなどの炭化水素源:CaO、CaCO 3 等を含む石灰源:MgO、MgCO 3 等を含むマグネシウム源:Al、Al 2 O 3 等を含むアルミニウム源:鉄鉱石:マンガン鉱石:合金のうち1種以上を挙げることができる。
固体炭素源、炭化水素源、アルミニウム源は、燃料源として作用する。
上記副原料は、通常、上方から自然落下させることによって添加される。副原料は、溶解性、反応性を高めるため、粒径の小さい粉体とすることが好ましいが、酸素を供給する場合には排ガスによって粉体が飛散しやすくなる。
このため、粒径数十mm以上のものが使用されるが、溶解性、反応性は損なわれる。[0050]
As secondary materials, solid carbon sources such as coke and coal: hydrocarbon sources such as plastics: lime sources including CaO, CaCO 3 etc. magnesium sources including MgO, MgCO 3 etc: Al, Al 2 O 3 etc. Aluminum source: iron ore: manganese ore: one or more of alloys can be mentioned.
A solid carbon source, a hydrocarbon source, an aluminum source act as a fuel source.
The above-mentioned auxiliary raw material is usually added by dropping naturally from above. The auxiliary material is preferably a powder having a small particle size in order to enhance solubility and reactivity, but when oxygen is supplied, the powder is likely to be scattered by the exhaust gas.
For this reason, although a particle size of several tens of mm or more is used, solubility and reactivity are impaired.
【0054】
本発明の精錬方法は、脱珪、脱燐、脱硫、脱炭、昇温、熱付加、スクラップ溶解、合金溶解、還元処理、脱ガスのうち1種以上に適用することができる。
熱付加は、鉄源や合金源添加時の熱補償のために行われる。還元処理は、鉄鉱石、マンガン鉱石などを用いて行われる。
精錬の際に用いる精錬剤は、精錬の目的に応じて選択使用すればよい。例えば、脱珪や脱燐では、酸素との反応で生成する珪酸や燐酸をスラグとして安定化する必要があるため、安定化効果のある石灰源などを精錬剤として用いるのが好ましい。
石灰源は、CaOとCaCO 3 のうち少なくとも一方を主成分とするものを用いると、迅速に溶融、スラグ化させることができるため好ましい。[0054]
The refining method of the present invention can be applied to at least one of desiliconization, dephosphorization, desulfurization, decarburization, temperature increase, heat addition, scrap melting, alloy melting, reduction treatment, and degassing.
Heat addition is performed for heat compensation when adding an iron source or an alloy source. The reduction treatment is performed using iron ore, manganese ore or the like.
The refining agent used in refining may be selected and used according to the purpose of the refining. For example, in desiliconization and dephosphorization, since it is necessary to stabilize silicic acid and phosphoric acid generated by reaction with oxygen as slag, it is preferable to use a lime source having a stabilizing effect as a refining agent.
It is preferable to use a lime source having at least one of CaO and CaCO 3 as the main component because it can be rapidly melted and slagged.
【0083】
【表4】
[0083]
[Table 4]
【0086】
(比較例7〜10)
比較例7、8では、粉体吹込み装置を使用せず、石灰またはコークスを炉上部のシューターから投入し、ランスを用いて純酸素のみを供給した。
比較例9、10では、比較例4で用いた装置を用いた。
30分間で溶解できたスクラップ量を測定した。試験結果を表5に示す。[0086]
( Comparative Examples 7 to 10 )
In Comparative Examples 7 and 8 , lime or coke was charged from a shooter at the top of the furnace without using a powder injection device, and only pure oxygen was supplied using a lance.
In Comparative Examples 9 and 10 , the apparatus used in Comparative Example 4 was used.
The amount of scrap that could be dissolved in 30 minutes was measured. The test results are shown in Table 5.
【0087】
【表5】
[0087]
[Table 5]
【0090】
(比較例11〜14)
比較例11、12では、粉体吹込み装置を使用せず、プラスチックを炉上部のシューターから投入し、ランスを用いて純酸素のみを供給した。
比較例13、14では、比較例4で用いた装置を用いた。
8分間の処理を行った際の試験結果を表6に示す。[0090]
( Comparative Examples 11 to 14 )
In Comparative Examples 11 and 12 , the plastic was charged from the shooter at the top of the furnace without using the powder injection device, and only pure oxygen was supplied using the lance.
In Comparative Examples 13 and 14 , the apparatus used in Comparative Example 4 was used.
The test results when treated for 8 minutes are shown in Table 6.
【0091】
【表6】
[0091]
[Table 6]
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002288116A JP4019117B2 (en) | 2001-09-28 | 2002-09-30 | Powder blowing apparatus and refining method |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2001302734 | 2001-09-28 | ||
JP2001-302734 | 2001-09-28 | ||
JP2002288116A JP4019117B2 (en) | 2001-09-28 | 2002-09-30 | Powder blowing apparatus and refining method |
Publications (3)
Publication Number | Publication Date |
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JP2003172584A JP2003172584A (en) | 2003-06-20 |
JP2003172584A5 true JP2003172584A5 (en) | 2004-07-08 |
JP4019117B2 JP4019117B2 (en) | 2007-12-12 |
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Family Applications (1)
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JP2002288116A Expired - Lifetime JP4019117B2 (en) | 2001-09-28 | 2002-09-30 | Powder blowing apparatus and refining method |
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Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4845078B2 (en) * | 2003-12-16 | 2011-12-28 | Jfeスチール株式会社 | Hot metal desulfurization method |
JP5031977B2 (en) * | 2004-05-31 | 2012-09-26 | Jfeスチール株式会社 | Hot metal dephosphorization method |
JP2006291334A (en) * | 2005-04-14 | 2006-10-26 | Sumitomo Metal Ind Ltd | Method for recycling dust at pretreatment of molten iron |
JP4735169B2 (en) * | 2005-09-30 | 2011-07-27 | Jfeスチール株式会社 | Hot metal dephosphorization method |
JP5087955B2 (en) * | 2006-03-23 | 2012-12-05 | Jfeスチール株式会社 | Melting reduction method |
JP5286768B2 (en) * | 2007-06-06 | 2013-09-11 | Jfeスチール株式会社 | Burner lance for charging granular material in smelting reduction furnace and method for producing molten metal by smelting reduction |
KR101144057B1 (en) * | 2008-12-19 | 2012-05-22 | 주식회사 태성산전 | Lime injector |
JP5481894B2 (en) * | 2009-03-18 | 2014-04-23 | Jfeスチール株式会社 | Melting reduction method |
JP5609081B2 (en) * | 2009-12-01 | 2014-10-22 | Jfeスチール株式会社 | Hot metal desulfurization method |
JP5707702B2 (en) * | 2010-01-29 | 2015-04-30 | Jfeスチール株式会社 | Hot metal dephosphorization method |
WO2012095471A2 (en) * | 2011-01-15 | 2012-07-19 | DÖRING-FREISSMUTH, Mechthilde | Agent for treating molten metals, method for the production and use thereof |
JP5962156B2 (en) * | 2011-04-12 | 2016-08-03 | Jfeスチール株式会社 | Method for refining molten iron |
JP2013209738A (en) * | 2011-04-27 | 2013-10-10 | Jfe Steel Corp | Method of manufacturing molten steel |
JP2013209737A (en) * | 2011-04-27 | 2013-10-10 | Jfe Steel Corp | Method for producing molten steel |
JP5870771B2 (en) * | 2011-05-23 | 2016-03-01 | Jfeスチール株式会社 | Manufacturing method of molten steel |
JP2013047371A (en) * | 2011-07-27 | 2013-03-07 | Jfe Steel Corp | Method for refining molten iron |
JP5870868B2 (en) * | 2011-07-29 | 2016-03-01 | Jfeスチール株式会社 | Method of refining hot metal in converter |
JP5928094B2 (en) * | 2012-03-30 | 2016-06-01 | Jfeスチール株式会社 | Method for refining molten iron |
JP5365678B2 (en) * | 2011-10-17 | 2013-12-11 | Jfeスチール株式会社 | Powder blowing lance with burner function, molten iron refining method and molten metal smelting reduction method using the powder blowing lance |
JP5928095B2 (en) * | 2012-03-30 | 2016-06-01 | Jfeスチール株式会社 | Method for refining molten iron |
US9580764B2 (en) | 2011-10-17 | 2017-02-28 | Jfe Steel Corporation | Top-blowing lance and method for refining molten iron using the same |
JP6051561B2 (en) * | 2012-03-30 | 2016-12-27 | Jfeスチール株式会社 | Manufacturing method of molten steel |
JP5949627B2 (en) * | 2013-03-28 | 2016-07-13 | Jfeスチール株式会社 | Method of refining hot metal in converter |
MX2022004852A (en) * | 2019-11-06 | 2022-05-19 | Jfe Steel Corp | Method for producing molten iron using electric furnace. |
CN114410883B (en) * | 2021-12-30 | 2023-03-03 | 钢铁研究总院 | Oxygen lance for cooperatively injecting oxygen, powder and inert gas and injection method |
-
2002
- 2002-09-30 JP JP2002288116A patent/JP4019117B2/en not_active Expired - Lifetime
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