JP2003105098A - Thermoplastic resin molded product with excellent conductivity - Google Patents
Thermoplastic resin molded product with excellent conductivityInfo
- Publication number
- JP2003105098A JP2003105098A JP2001297286A JP2001297286A JP2003105098A JP 2003105098 A JP2003105098 A JP 2003105098A JP 2001297286 A JP2001297286 A JP 2001297286A JP 2001297286 A JP2001297286 A JP 2001297286A JP 2003105098 A JP2003105098 A JP 2003105098A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic resin
- conductive agent
- metal
- resin molded
- molded product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Conductive Materials (AREA)
- Fuel Cell (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、熱可塑性樹脂成形
体に関するものであり、更には導電性に加え、耐熱性と
耐蝕性に優れた熱可塑性樹脂成形体に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thermoplastic resin molded product, and more particularly to a thermoplastic resin molded product excellent in heat resistance and corrosion resistance in addition to conductivity.
【０００２】[0002]
【従来の技術】近代のエレクトロニクス分野において、
高分子材料に求められる主要特性は製品や用途によって
様々であるが、成形性、耐熱性、耐久性、高導電性、耐
蝕性、リサイクル性であり、これらの要求を箇々に満足
させる樹脂としては、エポキシ樹脂、フェノール樹脂等
に代表される熱硬化性樹脂や、ポリフェニレンオキサイ
ド、液晶ポリマー、ポリイミド、ポリカーボネート等に
代表されるエンジニアリングプラスチック等が用いられ
ている。2. Description of the Related Art In the modern electronics field,
Although the main characteristics required for polymer materials vary depending on the product and application, they are moldability, heat resistance, durability, high conductivity, corrosion resistance, and recyclability, and as a resin that satisfies these requirements individually Thermosetting resins typified by epoxy resins and phenol resins, and engineering plastics typified by polyphenylene oxide, liquid crystal polymers, polyimides, polycarbonates, and the like are used.
【０００３】しかしながら、上記に挙げた各機能を総合
的に具備した材料に対する要望は強いものがあるが、技
術的に困難であり、価格面で不利となることが多いとい
う問題があった。そのような技術課題のひとつに導電性
があり、更に耐熱性と耐蝕性を兼ね備えた高分子材料の
開発が求められている。特に固体高分子型燃料電池を構
成するセパレータは、固体高分子型燃料電池に使用され
ている高分子電解質がプロトン伝導性を有し、強い酸性
を呈するため、高導電性と耐酸性が要求される。However, although there are strong demands for materials that comprehensively have the above-mentioned functions, there is a problem that they are technically difficult and often disadvantageous in terms of price. There is a demand for the development of a polymer material having conductivity, which is one of such technical problems, and further having both heat resistance and corrosion resistance. In particular, the separator that constitutes the polymer electrolyte fuel cell is required to have high conductivity and acid resistance because the polymer electrolyte used in the polymer electrolyte fuel cell has proton conductivity and exhibits strong acidity. It
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は、導電
性に優れ、耐熱性及び耐蝕性に優れた熱可塑性樹脂成形
体を提供することにある。SUMMARY OF THE INVENTION It is an object of the present invention to provide a thermoplastic resin molded product having excellent conductivity, heat resistance and corrosion resistance.
【０００５】[0005]
【課題を解決するための手段】本発明は上述の問題点を
解消できる熱可塑性樹脂成形体を見出したものであり、
その要旨とするところは、熱可塑性樹脂に導電剤を含む
成形体であって、その体積抵抗値が０．５Ωｃｍ以下で
あることを特徴とする熱可塑性樹脂成形体にある。上記
熱可塑性樹脂がフッ素樹脂、フッ素ゴム、ポリオレフィ
ン及びポリオレフィンエラストマーから選ばれてなるこ
とを含み、また、導電剤が、カーボン、金属炭化物、金
属酸化物、金属窒化物、金属粉末及び金属繊維から選ば
れてなること、熱可塑性樹脂成形体の厚みが０．２ｍｍ
〜２ｍｍであること、熱可塑性樹脂と導電剤の割合が、
熱可塑性樹脂／導電剤＝５／９５〜５０／５０（重量
比）であること、及び熱可塑性樹脂成形体が燃料電池用
セパレータであることを含んでいる。DISCLOSURE OF THE INVENTION The present invention has found a thermoplastic resin molding capable of solving the above-mentioned problems.
The gist thereof is a molded product containing a conductive agent in a thermoplastic resin and having a volume resistance value of 0.5 Ωcm or less. The thermoplastic resin comprises a fluororesin, a fluororubber, a polyolefin and a polyolefin elastomer, and the conductive agent is selected from carbon, metal carbide, metal oxide, metal nitride, metal powder and metal fiber. The thickness of the thermoplastic resin molding is 0.2 mm
~ 2 mm, the ratio of the thermoplastic resin and the conductive agent,
It is included that the thermoplastic resin / conductive agent = 5/95 to 50/50 (weight ratio), and that the thermoplastic resin molded body is a fuel cell separator.
【０００６】[0006]
【発明の実施の形態】以下、本発明を詳細に説明する。
本発明の熱可塑性樹脂成形体に使用する熱可塑性樹脂と
しては耐薬品性の点からフッ素樹脂、フッ素ゴム、ポリ
オレフィン及びポリオレフィンエラストマーが好適に使
用できる。フッ素樹脂、フッ素ゴムの具体例としては、
ＰＴＦＥ（ポリテトラフルオロエチレン）、ＰＦＡ（テ
トラフルオロエチレン−パーフルオロアルキルビニルエ
ーテル共重合体）、ＦＥＰ（テトラフルオロエチレン−
ヘキサフルオロプロピレン共重合体）、ＥＰＥ（テトラ
フルオロエチレン−ヘキサフルオロプロピレン−パーフ
ルオロアルキルビニルエーテル共重合体）、ＥＴＦＥ
（テトラフルオロエチレン−エチレン共重合体）、ＰＣ
ＴＦＥ（ポリクロロトリフルオロエチレン）、ＥＣＴＦ
Ｅ（クロロトリフルオロエチレン−エチレン共重合
体）、ＰＶＤＦ（ポリフッ化ビニリデン）、ＰＶＦ（ポ
リビニルフルオライド）、ＴＨＶ（テトラフルオロエチ
レン−ヘキサフルオロプロピレン−フッ化ビニリデン共
重合体）、ＶＤＦ−ＨＦＰ（フッ化ビニリデン−ヘキサ
フルオロプロピレン共重合体）、ＴＦＥ−Ｐ（フッ化ビ
ニリデン−プロピレン共重合体）、BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
From the viewpoint of chemical resistance, fluororesins, fluororubbers, polyolefins and polyolefin elastomers can be preferably used as the thermoplastic resin used in the thermoplastic resin molding of the present invention. Specific examples of fluororesin and fluororubber include
PTFE (polytetrafluoroethylene), PFA (tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer), FEP (tetrafluoroethylene-
Hexafluoropropylene copolymer), EPE (tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer), ETFE
(Tetrafluoroethylene-ethylene copolymer), PC
TFE (polychlorotrifluoroethylene), ECTF
E (chlorotrifluoroethylene-ethylene copolymer), PVDF (polyvinylidene fluoride), PVF (polyvinyl fluoride), THV (tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride copolymer), VDF-HFP (fluorine) Vinylidene fluoride-hexafluoropropylene copolymer), TFE-P (vinylidene fluoride-propylene copolymer),
【０００７】含フッ素シリコーン系ゴム、含フッ素ビニ
ルエーテル系ゴム、含フッ素フォスファゼン系ゴム、含
フッ素熱可塑性エラストマーからなる少なくとも１種類
以上のフッ素樹脂又はフッ素ゴムが使用できる。上記例
示した樹脂では、成形性の点から特にフッ化ビニリデン
を含むＰＶＤＦ、ＴＨＶ、ＶＤＦ−ＨＦＰ及びＴＦＥ−
Ｐが好ましい。At least one type of fluororesin or fluororubber composed of fluorosilicone rubber, fluorovinyl ether rubber, fluorophosphazene rubber, and fluorothermoplastic elastomer can be used. Among the above-exemplified resins, PVDF, THV, VDF-HFP and TFE-containing vinylidene fluoride are particularly preferable from the viewpoint of moldability.
P is preferred.
【０００８】ポリオレフィン及びポリオレフィンエラス
トマーの具体例としては、ポリエチレン、ポリプロピレ
ン、ポリブテン、ポリ４メチル１ペンテン、ポリヘキセ
ン、ポリオクテン、Specific examples of polyolefins and polyolefin elastomers include polyethylene, polypropylene, polybutene, poly-4-methyl-1-pentene, polyhexene, polyoctene,
【０００９】水素添加スチレンブタジエンゴム、ＥＰＤ
Ｍ、ＥＰＭ、ＥＢＭからなる少なくとも１種類以上のポ
リオレフィン及びポリオレフィンエラストマーが使用で
きる。上記例示した樹脂では、耐熱性、成形性の点から
特にＥＰＤＭが好ましい。Hydrogenated styrene butadiene rubber, EPD
At least one or more polyolefins and polyolefin elastomers composed of M, EPM and EBM can be used. Of the resins exemplified above, EPDM is particularly preferable from the viewpoint of heat resistance and moldability.
【００１０】上記フッ素樹脂、フッ素ゴム、ポリオレフ
ィン及びポリオレフィンエラストマーには導電剤を混合
する必要があり、導電剤としては、カーボン、金属炭化
物、金属酸化物、金属窒化物、金属粉末及び金属繊維が
好適に使用できる。It is necessary to mix a conductive agent with the above-mentioned fluororesin, fluororubber, polyolefin and polyolefin elastomer, and as the conductive agent, carbon, metal carbide, metal oxide, metal nitride, metal powder and metal fiber are suitable. Can be used for
【００１１】カーボンとしては黒鉛、カーボンブラッ
ク、膨張黒鉛、炭素繊維、気相法炭素繊維、金属炭化物
としては炭化タングステン、炭化珪素、炭化カルシウ
ム、炭化ジルコニウム、炭化タンタル、炭化チタン、炭
化ニオブ、炭化モリブデン、炭化バナジウム、炭化クロ
ム、炭化ハフニウム、金属酸化物としては、酸化チタ
ン、酸化ルテニウム、酸化インジウム、酸化錫、酸化亜
鉛、金属窒化物としては窒化クロム、窒化アルミニウ
ム、窒化モリブデン、窒化ジルコニウム、窒化タンタ
ル、窒化チタン、窒化ガリウム、窒化ニオブ、窒化バナ
ジウム、窒化ホウ素、金属粉末としては、チタン粉、ニ
ッケル粉、錫紛、、銅粉、アルミ粉、亜鉛粉、銀粉タン
タル紛、ニオブ粉、金属繊維としては、鉄繊維、銅繊
維、ステンレス繊維が例示できる。上記の導電剤では、
特に金属炭化物が導電性、耐酸性に優れていることから
好適に使用できる。Carbon is graphite, carbon black, expanded graphite, carbon fiber, vapor grown carbon fiber, and metal carbide is tungsten carbide, silicon carbide, calcium carbide, zirconium carbide, tantalum carbide, titanium carbide, niobium carbide, molybdenum carbide. , Vanadium carbide, chromium carbide, hafnium carbide, titanium oxide, ruthenium oxide, indium oxide, tin oxide, zinc oxide as metal oxide, chromium nitride, aluminum nitride, molybdenum nitride, zirconium nitride, tantalum nitride as metal nitride , Titanium nitride, gallium nitride, niobium nitride, vanadium nitride, boron nitride, as metal powder, titanium powder, nickel powder, tin powder, copper powder, aluminum powder, zinc powder, silver powder tantalum powder, niobium powder, as metal fibers Can be exemplified by iron fiber, copper fiber, and stainless fiber. . In the above conductive agent,
In particular, metal carbides can be preferably used because they have excellent conductivity and acid resistance.
【００１２】熱可塑性樹脂成形体の厚みは、０．２ｍｍ
〜２．０ｍｍの範囲であることが望ましい。熱可塑性樹
脂成形体の厚みが０．２ｍｍ未満では脆く、割れやすい
ため取り扱いにくいという問題が生じ易い。また、特に
燃料電池セパレータに使用する場合は、厚みが２ｍｍを
越えるとセパレータが厚く、燃料電池が大きくなるとい
う問題がある。The thickness of the thermoplastic resin molding is 0.2 mm
It is desirable that the range is up to 2.0 mm. If the thickness of the thermoplastic resin molded product is less than 0.2 mm, it is brittle and easily cracked, which makes it difficult to handle. Further, particularly when used for a fuel cell separator, if the thickness exceeds 2 mm, the separator becomes thick and the fuel cell becomes large.
【００１３】熱可塑性樹脂と導電剤の割合は、熱可塑性
樹脂／導電剤＝５／９５〜５０／５０（重量比）、好ま
しくは熱可塑性樹脂／導電剤＝１０／９０〜４０／６０
（重量比）が良い。熱可塑性樹脂の割合が、５未満では
熱可塑性樹脂の割合が少ないので成形が困難となり、熱
可塑性樹脂が５０を越える場合では導電剤の割合が少な
いので導電性に劣るという問題がある。The ratio of thermoplastic resin to conductive agent is thermoplastic resin / conductive agent = 5/95 to 50/50 (weight ratio), preferably thermoplastic resin / conductive agent = 10/90 to 40/60.
(Weight ratio) is good. If the proportion of the thermoplastic resin is less than 5, the proportion of the thermoplastic resin is small and molding becomes difficult. If the proportion of the thermoplastic resin exceeds 50, the proportion of the conductive agent is small, resulting in poor conductivity.
【００１４】本発明の熱可塑性樹脂成形体の製造方法は
特に限定されないが、通常の押出成形、ロール成形法、
射出成形法又はトランスファー成形法によればよい。ま
た、燃料電池セパレータに使用する場合は、予め熱可塑
性樹脂と導電剤を２軸押出機等で混合した後、押出成
形、ロール成形法により、熱可塑性樹脂シートを製膜
し、セパレータ形状の彫り込まれたプレス金型の雄金型
と雌金型の間にシートを載置し、熱プレス法で突起部や
溝部を形成する方法が生産性等の点から好ましい。熱プ
レス法の条件は、加熱温度１２０℃〜３００℃、圧力
２．９×１０６Ｐａ〜１４．７×１０６Ｐａ（３０ｋｇ
ｆ／ｃｍ２〜１５０ｋｇｆ／ｃｍ２）程度にて行なえば
よい。The method for producing the thermoplastic resin molded article of the present invention is not particularly limited, but it may be a conventional extrusion molding, roll molding method,
An injection molding method or a transfer molding method may be used. When used for a fuel cell separator, a thermoplastic resin and a conductive agent are mixed in advance with a twin-screw extruder or the like, and then a thermoplastic resin sheet is formed into a film by extrusion molding or roll molding, and the separator shape is engraved. From the viewpoint of productivity and the like, a method of placing a sheet between the male die and the female die of the pressed die and forming the protrusions and grooves by the hot pressing method is preferable. Conditions of thermal press method, the heating temperature 120 ° C. to 300 ° C., a pressure 2.9 × 10 6 Pa~14.7 × 10 6 Pa (30kg
f / cm 2 to 150 kgf / cm 2 ).
【００１５】以下、実施例について説明するが、本発明
はこれに限定されるものではない。Examples will be described below, but the present invention is not limited thereto.
【実施例】［実施例１］フッ素樹脂（「住友スリーエム
（株）」製 ＴＨＶ２２０Ｇ）１０重量部と導電性フィ
ラー（炭化タングステン 「（株）アライドマテリア
ル」製 ＷＣ２０）９０重量部を２軸押出機（押出機温
度２５０℃）にて混合した。作成した混合物を、単軸押
出機（押出機温度２５０℃）にて口金から押出しシート
を作成した。得られた成形体の厚みは１．０ｍｍで、体
積抵抗値は０．０１０Ωｃｍであった。Examples [Example 1] 10 parts by weight of a fluororesin (THV220G manufactured by "Sumitomo 3M Ltd.") and 90 parts by weight of a conductive filler (WC20 manufactured by Tungsten Carbide "Allied Material") are twin-screw extruders. (Extruder temperature 250 ° C). The prepared mixture was extruded from a die with a single-screw extruder (extruder temperature: 250 ° C.) to prepare an extruded sheet. The obtained molded body had a thickness of 1.0 mm and a volume resistance value of 0.010 Ωcm.
【００１６】［実施例２］実施例１で得られたシート
を、セパレータ形状が彫り込まれたプレス金型の雄金型
と雌金型の間に載置し熱プレス法にて燃料電池セパレー
タを作成した。熱プレス法の条件は、加熱温度２２０
℃、圧力１４．７×１０６Ｐａ（１５０ｋｇｆ／ｃ
ｍ２）であった。得られた燃料電池セパレータの最大厚
みは１．２ｍｍ、最小厚みは０．４ｍｍであった。[Example 2] The sheet obtained in Example 1 was placed between a male die and a female die of a press die in which a separator shape was engraved, and a fuel cell separator was formed by a hot press method. Created. The conditions for the hot pressing method are a heating temperature of 220.
C, pressure 14.7 × 10 6 Pa (150 kgf / c
m 2 ). The obtained fuel cell separator had a maximum thickness of 1.2 mm and a minimum thickness of 0.4 mm.
【００１７】得られた上記のセパレータを用いて接触抵
抗を測定した。接触抵抗の評価は以下のように行った。
測定結果を図２のＮｏ．１サンプルで示した。
１． 測定装置
抵抗計：ＹＭＲ−３型（（株）山崎精機研究所社製）
負荷装置：ＹＳＲ−８型（（株）山崎精機研究所社製）
電極：真鍮製平板２枚（面積１平方インチ、鏡面仕上
げ）
２． 測定条件
方法：４端子法
印加電流：１０ｍＡ（交流、２８７Ｈｚ）
開放端子電圧：２０ｍＶピーク以下
カーボンペーパー：東レ社製ＴＧＰ−Ｈ−０９０（厚み
０．２８ｍｍ）The contact resistance was measured using the obtained separator. The contact resistance was evaluated as follows.
The measurement results are shown in FIG. One sample is shown. 1. Measuring device Resistance meter: YMR-3 type (manufactured by Yamazaki Seiki Kenkyusho Co., Ltd.) Load device: YSR-8 type (manufactured by Yamazaki Seiki Kenkyusho Co., Ltd.) Electrode: Two brass flat plates (area 1 square inch) , Mirror finish) 2. Measurement condition method: 4-terminal method Applied current: 10 mA (AC, 287 Hz) Open terminal voltage: 20 mV peak or less Carbon paper: Toray TGP-H-090 (thickness 0.28 mm)
【００１８】３．測定方法 図１に示した測定装置により測定した。3. Measuring method The measurement was performed using the measuring device shown in FIG.
【００１９】上記方法で評価したセパレータの接触抵抗
値を図２のグラフに示した。比較のために東海カーボン
社製樹脂含浸黒鉛Ｇ３４７Ｂ（Ｎｏ．２）も評価した。The contact resistance value of the separator evaluated by the above method is shown in the graph of FIG. For comparison, resin impregnated graphite G347B (No. 2) manufactured by Tokai Carbon Co., Ltd. was also evaluated.
【００２０】図２のグラフに示す通り、フッ素樹脂１０
重量部と導電性フィラー（炭化タングステン）９０重量
部からなる燃料電池セパレータＮｏ．１は、Ｎｏ．２の
樹脂含浸黒鉛とほぼ同等の接触抵抗値であった。As shown in the graph of FIG.
Fuel cell separator No. 1 comprising 90 parts by weight of a conductive filler (tungsten carbide). No. 1 is No. The contact resistance value was almost the same as that of the resin-impregnated graphite of No. 2.
【００２１】[0021]
【発明の効果】上述したように、本発明の熱可塑性樹脂
成形体は、導電性が高く、耐熱性と耐蝕性を兼ね備えた
高分子材料である。特に、電極との接触抵抗が小さく、
耐食性に優れ、比較的低コストで生産可能なことから、
長時間の運転が可能な燃料電池用としての利用性が大き
い。As described above, the thermoplastic resin molding of the present invention is a polymer material having high conductivity and having both heat resistance and corrosion resistance. In particular, the contact resistance with the electrode is small,
Since it has excellent corrosion resistance and can be produced at a relatively low cost,
It is highly useful for fuel cells that can be operated for a long time.
【図１】接触抵抗の測定方法を示す装置の概略図。FIG. 1 is a schematic view of an apparatus showing a method for measuring contact resistance.
【図２】接触荷重と接触抵抗値の関係を示すグラフ。FIG. 2 is a graph showing the relationship between contact load and contact resistance value.
１：真鍮製電極 ２：カーボンペーパー ３：セパレータ 1: Brass electrode 2: Carbon paper 3: Separator
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０８Ｌ 101/00 Ｃ０８Ｌ 101/00 Ｈ０１Ｂ 1/20 Ｈ０１Ｂ 1/20 Ｚ Ｈ０１Ｍ 8/02 Ｈ０１Ｍ 8/02 Ｂ // Ｈ０１Ｍ 8/10 8/10 Ｆターム(参考） 4F071 AA13 AA15 AA20 AA21 AA26 AB03 AB06 AB11 AB18 AB22 AD01 AE15 AF02 AF37 AF45 AH15 BA01 BB03 BB05 BB06 BC01 BC07 4J002 AC081 BB031 BB121 BB151 BD121 DA026 DA036 DA066 DB016 DE096 DF016 FA046 FD116 GQ02 5G301 DA02 DA18 DA22 DA23 DA24 DA42 DA43 DA47 DD10 5H026 AA06 CX02 EE02 EE11 EE12 EE18 HH03 HH05 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C08L 101/00 C08L 101/00 H01B 1/20 H01B 1/20 Z H01M 8/02 H01M 8/02 B / / H01M 8/10 8/10 F Term (reference) 4F071 AA13 AA15 AA20 AA21 AA26 AB03 AB06 AB11 AB18 AB22 AD01 AE15 AF02 AF37 AF45 AH15 BA01 BB03 BB05 BB06 BC01 BC07 4J002 AC081 BB031 BB121 BB151 BD121 DA016 DB0 DA026 DA026 DA026 DA026 DA026 DA026 DA026 DA026 DA026 GQ02 5G301 DA02 DA18 DA22 DA23 DA24 DA42 DA43 DA47 DD10 5H026 AA06 CX02 EE02 EE11 EE12 EE18 HH03 HH05
Claims (6)
体であって、その体積抵抗値が０．５Ωｃｍ以下である
ことを特徴とする熱可塑性樹脂成形体。1. A molded product comprising a thermoplastic resin and a conductive agent, wherein the volume resistance value is 0.5 Ωcm or less.
ゴム、ポリオレフィン及びポリオレフィンエラストマー
から選ばれてなることを特徴とする請求項１記載の熱可
塑性樹脂成形体。2. The thermoplastic resin molding according to claim 1, wherein the thermoplastic resin is selected from fluororesins, fluororubbers, polyolefins and polyolefin elastomers.
金属酸化物、金属窒化物、金属粉末及び金属繊維から選
ばれてなることを特徴とする請求項１又は２記載の熱可
塑性樹脂成形体。3. The conductive agent is carbon, metal carbide,
The thermoplastic resin molding according to claim 1 or 2, which is selected from metal oxides, metal nitrides, metal powders, and metal fibers.
〜２ｍｍであることを特徴とする請求項１乃至３のいず
れか１項記載の熱可塑性樹脂成形体。4. The thickness of the thermoplastic resin molding is 0.2 mm.
It is -2 mm, The thermoplastic resin molded body of any one of Claim 1 thru | or 3 characterized by the above-mentioned.
性樹脂／導電剤＝５／９５〜５０／５０（重量比）であ
ることを特徴とする請求項１乃至４のいずれか１項記載
の熱可塑性樹脂成形体。5. The ratio of thermoplastic resin to conductive agent is thermoplastic resin / conductive agent = 5/95 to 50/50 (weight ratio), according to any one of claims 1 to 4. The thermoplastic resin molding described.
ータであることを特徴とする請求項１乃至５のいずれか
１項記載の熱可塑性樹脂成形体。6. The thermoplastic resin molded article according to claim 1, wherein the thermoplastic resin molded article is a fuel cell separator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001297286A JP2003105098A (en) | 2001-09-27 | 2001-09-27 | Thermoplastic resin molded product with excellent conductivity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001297286A JP2003105098A (en) | 2001-09-27 | 2001-09-27 | Thermoplastic resin molded product with excellent conductivity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003105098A true JP2003105098A (en) | 2003-04-09 |
Family
ID=19118392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001297286A Pending JP2003105098A (en) | 2001-09-27 | 2001-09-27 | Thermoplastic resin molded product with excellent conductivity |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003105098A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005353585A (en) * | 2004-05-14 | 2005-12-22 | Showa Denko Kk | Conductive structure, method for manufacturing the same and separator for fuel cell |
| US7816432B2 (en) | 2002-12-24 | 2010-10-19 | Showa Denko K.K. | Curable composition, cured product thereof, molded product thereof and use as fuel cell separator |
| JP2012051375A (en) * | 2004-05-14 | 2012-03-15 | Showa Denko Kk | Conductive structure, method for manufacturing the same, and separator for fuel cell |
| KR20210146663A (en) * | 2020-05-27 | 2021-12-06 | 주식회사 아이에스시 | Connector for electrical connection |
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|---|---|---|---|---|
| JPS62223255A (en) * | 1986-03-25 | 1987-10-01 | Asahi Glass Co Ltd | Tetrafluoroethylene polymer composition |
| JPH01112606A (en) * | 1987-07-15 | 1989-05-01 | Nippon Steel Chem Co Ltd | High toughness conductive resin sheet |
| WO1998040435A1 (en) * | 1997-03-11 | 1998-09-17 | Nippon Zeon Co., Ltd. | Conductive elastomer film, method for production thereof, and conductive elastomer composition |
| JP2000348739A (en) * | 1999-06-04 | 2000-12-15 | Mitsubishi Plastics Ind Ltd | Resin composition for fuel cell separator |
| JP2001126744A (en) * | 1999-10-28 | 2001-05-11 | Osaka Gas Co Ltd | Separator for fuel cell and fabricating method therefor |
-
2001
- 2001-09-27 JP JP2001297286A patent/JP2003105098A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62223255A (en) * | 1986-03-25 | 1987-10-01 | Asahi Glass Co Ltd | Tetrafluoroethylene polymer composition |
| JPH01112606A (en) * | 1987-07-15 | 1989-05-01 | Nippon Steel Chem Co Ltd | High toughness conductive resin sheet |
| WO1998040435A1 (en) * | 1997-03-11 | 1998-09-17 | Nippon Zeon Co., Ltd. | Conductive elastomer film, method for production thereof, and conductive elastomer composition |
| JP2000348739A (en) * | 1999-06-04 | 2000-12-15 | Mitsubishi Plastics Ind Ltd | Resin composition for fuel cell separator |
| JP2001126744A (en) * | 1999-10-28 | 2001-05-11 | Osaka Gas Co Ltd | Separator for fuel cell and fabricating method therefor |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7816432B2 (en) | 2002-12-24 | 2010-10-19 | Showa Denko K.K. | Curable composition, cured product thereof, molded product thereof and use as fuel cell separator |
| US8053501B2 (en) | 2002-12-24 | 2011-11-08 | Showa Denko K.K. | Curable composition, cured product thereof, molded product thereof and use as fuel cell separator |
| JP2005353585A (en) * | 2004-05-14 | 2005-12-22 | Showa Denko Kk | Conductive structure, method for manufacturing the same and separator for fuel cell |
| JP2012051375A (en) * | 2004-05-14 | 2012-03-15 | Showa Denko Kk | Conductive structure, method for manufacturing the same, and separator for fuel cell |
| KR20210146663A (en) * | 2020-05-27 | 2021-12-06 | 주식회사 아이에스시 | Connector for electrical connection |
| KR102466241B1 (en) * | 2020-05-27 | 2022-11-14 | 주식회사 아이에스시 | Connector for electrical connection |
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