JP2003105087A5 - - Google Patents

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Publication number
JP2003105087A5
JP2003105087A5 JP2002178213A JP2002178213A JP2003105087A5 JP 2003105087 A5 JP2003105087 A5 JP 2003105087A5 JP 2002178213 A JP2002178213 A JP 2002178213A JP 2002178213 A JP2002178213 A JP 2002178213A JP 2003105087 A5 JP2003105087 A5 JP 2003105087A5
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JP
Japan
Prior art keywords
polyarylene sulfide
sulfide resin
film
fiber
mol
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JP2002178213A
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Japanese (ja)
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JP4039137B2 (en
JP2003105087A (en
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Priority to JP2002178213A priority Critical patent/JP4039137B2/en
Priority claimed from JP2002178213A external-priority patent/JP4039137B2/en
Publication of JP2003105087A publication Critical patent/JP2003105087A/en
Publication of JP2003105087A5 publication Critical patent/JP2003105087A5/ja
Application granted granted Critical
Publication of JP4039137B2 publication Critical patent/JP4039137B2/en
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Expired - Fee Related legal-status Critical Current

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Claims (6)

ポリハロゲン芳香族化合物とスルフィド化剤とを極性有機溶媒中で反応させてポリアリーレンスルフィド樹脂を重合する際に、該スルフィド化剤1モル当たり、該極性有機溶媒を3.2〜5.5モル使用して重合を行い、該重合を有機カルボン酸のアルカリ金属塩の存在下で行い、かつ、該有機カルボン酸のアルカリ金属塩の量を、該スルフィド化剤1モル当たり、0.3〜0.6モルに制御し、該重合途中で、該スルフィド化剤1モル当たり、水を0.2〜10モル添加することを特徴とするフィルムまたは繊維用ポリアリーレンスルフィド樹脂の製造方法。When the polyarylene sulfide resin is polymerized by reacting the polyhalogen aromatic compound and the sulfidizing agent in a polar organic solvent, the polar organic solvent is added in an amount of 3.2 to 5.5 mol per mol of the sulfidizing agent. there rows polymerized using performs polymerization in the presence of an alkali metal salt of an organic carboxylic acid, and the amount of the alkali metal salts of organic carboxylic acids, the sulfidizing agent per mole, 0.3 A method for producing a polyarylene sulfide resin for a film or fiber, comprising controlling to 0.6 mol, and adding 0.2 to 10 mol of water per mol of the sulfiding agent during the polymerization . 該重合の際に、該スルフィド化剤1モル当たり、該極性溶媒を3.5〜5.5モル使用して重合を行うことを特徴とする請求項1に記載のフィルムまたは繊維用ポリアリーレンスルフィドの製造方法。  The polyarylene sulfide for film or fiber according to claim 1, wherein the polymerization is carried out using 3.5 to 5.5 mol of the polar solvent per mol of the sulfidizing agent. Manufacturing method. 該重合後、得られたポリアリーレンスルフィド樹脂を有機溶媒で洗浄することを特徴とする請求項1〜のいずれかに記載のフィルムまたは繊維用ポリアリーレンスルフィド樹脂の製造方法。 3. The method for producing a polyarylene sulfide resin for a film or fiber according to claim 1, wherein the polyarylene sulfide resin obtained is washed with an organic solvent after the polymerization. 請求項1〜のいずれかに記載の方法により製造されたポリアリーレンスルフィド樹脂であって、210℃以下の降温結晶化温度を有するものであるフィルムまたは繊維用ポリアリーレンスルフィド樹脂。 A polyarylene sulfide resin for a film or a fiber, which is a polyarylene sulfide resin produced by the method according to any one of claims 1 to 3 , and has a temperature-falling crystallization temperature of 210 ° C or lower . 請求項記載のフィルムまたは繊維用ポリアリーレンスルフィド樹脂を用いて製造されたことを特徴とするフィルム Film characterized by being manufactured with claim 4, wherein the film or fiber for polyarylene sulfide resin. 請求項記載のフィルムまたは繊維用ポリアリーレンスルフィド樹脂を用いて製造されたことを特徴とする繊維 Fiber characterized in that it is manufactured by using a fourth aspect of the film or fiber for polyarylene sulfide resin.
JP2002178213A 2001-07-26 2002-06-19 Method for producing polyarylene sulfide resin, film and fiber Expired - Fee Related JP4039137B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002178213A JP4039137B2 (en) 2001-07-26 2002-06-19 Method for producing polyarylene sulfide resin, film and fiber

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2001-226058 2001-07-26
JP2001226058 2001-07-26
JP2002178213A JP4039137B2 (en) 2001-07-26 2002-06-19 Method for producing polyarylene sulfide resin, film and fiber

Publications (3)

Publication Number Publication Date
JP2003105087A JP2003105087A (en) 2003-04-09
JP2003105087A5 true JP2003105087A5 (en) 2005-10-13
JP4039137B2 JP4039137B2 (en) 2008-01-30

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ID=26619323

Family Applications (1)

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JP2002178213A Expired - Fee Related JP4039137B2 (en) 2001-07-26 2002-06-19 Method for producing polyarylene sulfide resin, film and fiber

Country Status (1)

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JP (1) JP4039137B2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4736353B2 (en) * 2003-06-05 2011-07-27 東レ株式会社 Laser-welded polyphenylene sulfide resin composition and composite molded body using the same
JP2005232254A (en) * 2004-02-18 2005-09-02 Toray Ind Inc Polyarylene sulfide resin and extruded molding artice
CN101084274B (en) 2004-12-21 2010-06-16 宝理塑料株式会社 Polyarylene sulfide resin composition and method for producing same
JP5189293B2 (en) * 2004-12-21 2013-04-24 株式会社クレハ Branched polyarylene sulfide resin, process for producing the same, and use thereof as a polymer modifier
JP5176344B2 (en) * 2007-03-07 2013-04-03 東レ株式会社 Method for producing polyarylene sulfide resin particles and method for producing polyarylene sulfide resin pellets
CN108976421A (en) * 2018-07-26 2018-12-11 四川中科兴业高新材料有限公司 A kind of preparation method of film-grade PPS resin
CN112334514A (en) * 2018-07-31 2021-02-05 株式会社吴羽 Method for producing polyarylene sulfide

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04255722A (en) * 1991-02-07 1992-09-10 Toray Philips Petroleum Kk Production of polyarylene sulfide
JP3099984B2 (en) * 1991-11-08 2000-10-16 東レ株式会社 Method for producing polyphenylene sulfide
JPH06107794A (en) * 1992-09-29 1994-04-19 Toray Ind Inc Polyphenylene sulfide composition
JP3568054B2 (en) * 1994-12-28 2004-09-22 呉羽化学工業株式会社 Method for producing polyphenylene sulfide
JP4256506B2 (en) * 1998-12-24 2009-04-22 株式会社クレハ Process for producing polyarylene sulfide

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