JP2003040705A - Rod material having pollution-preventing function - Google Patents

Rod material having pollution-preventing function

Info

Publication number
JP2003040705A
JP2003040705A JP2001226135A JP2001226135A JP2003040705A JP 2003040705 A JP2003040705 A JP 2003040705A JP 2001226135 A JP2001226135 A JP 2001226135A JP 2001226135 A JP2001226135 A JP 2001226135A JP 2003040705 A JP2003040705 A JP 2003040705A
Authority
JP
Japan
Prior art keywords
wire
preventing
pollution
function
antifouling agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001226135A
Other languages
Japanese (ja)
Inventor
Rikio Tomita
力雄 冨田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nichimo Co Ltd
Original Assignee
Nichimo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nichimo Co Ltd filed Critical Nichimo Co Ltd
Priority to JP2001226135A priority Critical patent/JP2003040705A/en
Publication of JP2003040705A publication Critical patent/JP2003040705A/en
Pending legal-status Critical Current

Links

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  • Treatment Of Fiber Materials (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a rod material having a pollution-preventing function, capable of surely exhibiting a pollution-preventing function by a pollution- preventing agent in water, and surely preventing the attachment of algae or dusts by using it as a part of a fishery tool, etc. SOLUTION: This rod material 1 is made from a resin 2 containing the pollution-preventing agents 3 (magnesium oxide, magnesium hydroxide, copper, silver, etc.), for preventing the attachment of polluting materials, and the pollution-preventing agents are exposed by roughing its surface.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、汚染防止機能を有
する線材に係り、特に水中に使用されて藻やゴミ等から
なる汚染物質の付着を防止することのできる汚染防止機
能を有する線材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wire having a pollution preventing function, and more particularly to a wire having a pollution preventing function capable of preventing adhesion of pollutants such as algae and dust used in water.

【0002】[0002]

【従来の技術と発明が解決しようとする課題】一般に、
生け簀や海苔網等の海中に設置される漁具においては、
網やロープ等に藻やゴミ等の汚染物質が付着してしま
い、生け簀内の魚類の棲息環境を悪化させたり、海苔に
病気が発生したり、海苔以外の不純物としての藻が収穫
された海苔に含まれてしまう等の不都合が発生してい
た。
2. Description of the Related Art Generally,
For fishing gear installed in the sea such as cages and seaweed nets,
Contaminants such as algae and dust adhere to nets and ropes, worsening the habitat environment of fish in cages, causing diseases in seaweed, and seaweed from which algae as impurities other than seaweed are harvested There was an inconvenience such as being included in.

【0003】そのために、従来よりこれらの汚染物質の
付着を防止する種々の提案がなされているが、その代表
的なものとして樹脂製の繊維中に酸化チタン等の光触媒
の微粒子や微粉末等を混入した線材が提案されている。
For this reason, various proposals have been made to prevent the adhesion of these pollutants, and as a typical example thereof, fine particles or fine powders of photocatalyst such as titanium oxide are contained in resin fibers. A mixed wire is proposed.

【0004】しかしながら、線材の表面に樹脂のスキン
層が形成されてしまい、線材内に混入された光触媒が表
面に露出していないので、肝心の防汚機能が全く発揮さ
れなかったり、発揮されたとしても不十分なものであっ
た。
However, since the resin skin layer is formed on the surface of the wire and the photocatalyst mixed in the wire is not exposed on the surface, the essential antifouling function is not exerted or is exerted. However, it was insufficient.

【0005】本発明はこれらの点に鑑みてなされたもの
であり、水中において防汚剤による汚染防止機能が確実
に発揮され、漁具等の一部に用いられることにより藻や
ゴミの付着を確実に防止することのできる汚染防止機能
を有する線材を提供することを目的とする。
The present invention has been made in view of these points, and the function of preventing pollution by an antifouling agent is surely exhibited in water, and by being used as a part of fishing gear, etc., the adhesion of algae and dust is ensured. It is an object of the present invention to provide a wire rod having a pollution prevention function that can prevent the above.

【0006】[0006]

【課題を解決するための手段】前記目的を達成するため
に本発明の汚染防止機能を有する線材は、汚染物質の付
着を防止する防汚剤を含有する樹脂製の線材であって、
表面が荒らされて前記防汚剤が露出させられていること
を特徴とする。
In order to achieve the above-mentioned object, a wire rod having a pollution preventing function of the present invention is a resin wire rod containing an antifouling agent for preventing adhesion of contaminants,
The surface is roughened so that the antifouling agent is exposed.

【0007】このように構成されている本発明によれ
ば、樹脂製の線材の表面に露出している防汚剤がその防
汚機能を発揮して、汚染物質の付着が確実に防止され
る。
According to the present invention having such a configuration, the antifouling agent exposed on the surface of the resin wire exerts its antifouling function, and the adhesion of contaminants is surely prevented. .

【0008】また、本発明においては、前記樹脂製の線
材は、ポリプロピレンとポリエチレンとの混合物であ
り、前記ポリプロピレンが65重量%以上含有されてお
り、表面をささくれさせることにより荒らされているこ
とを特徴とする。
Further, in the present invention, the resin wire is a mixture of polypropylene and polyethylene, and contains 65% by weight or more of the polypropylene and is roughened by burring the surface. Characterize.

【0009】このように構成されている本発明によれ
ば、ポリプロピレンとポリエチレンとの混合物からなる
樹脂製の線材であって、ポリプロピレンが65重量%以
上含有されていると、線材の表面がささくれ易くなるた
めに、表面が荒らされ防汚剤が当該表面から露出するこ
ととなり、防汚機能が確実に発揮されて、汚染物質の付
着が確実に防止される。
According to the present invention thus constructed, a wire made of a resin made of a mixture of polypropylene and polyethylene, in which if the content of polypropylene is 65% by weight or more, the surface of the wire is apt to fray. Therefore, the surface is roughened and the antifouling agent is exposed from the surface, so that the antifouling function is surely exhibited, and the adherence of the pollutant is surely prevented.

【0010】また、本発明においては、前記防汚剤とし
ては、光触媒、酸化マグネシウム、水酸化マグネシウ
ム、銅、銀、酸性素材、アルカリ性素材、高濃度塩化ナ
トリウムの1種若しくは複数種を用いるとよい。これら
の防汚剤はそれぞれ優れた防汚機能を有しているので、
汚染物質の付着が確実に防止される。
In the present invention, as the antifouling agent, one or more of photocatalyst, magnesium oxide, magnesium hydroxide, copper, silver, acidic material, alkaline material, and high concentration sodium chloride may be used. . Since each of these antifouling agents has an excellent antifouling function,
Adherence of contaminants is reliably prevented.

【0011】[0011]

【発明の実施の形態】以下、本発明の実施の形態を図1
について説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to FIG.
Will be described.

【0012】図1は本発明の線材を1実施形態を示して
いる。
FIG. 1 shows a wire rod according to one embodiment of the present invention.

【0013】本実施形態の線材1は、通常の樹脂繊維を
製造する工程と同様にして、樹脂材2の中に粒子状およ
びまたは粉末状の防汚剤3を混合して溶融させ、その後
に長尺な繊維として紡糸し、その後に繊維の表面を荒ら
して、防汚剤3を表面に露出させて形成されている。
In the wire rod 1 of this embodiment, the particulate and / or powdery antifouling agent 3 is mixed and melted in the resin material 2 in the same manner as in the ordinary process for producing resin fibers, and thereafter, It is formed by spinning as a long fiber and then roughening the surface of the fiber to expose the antifouling agent 3 on the surface.

【0014】この線材1の素材としての樹脂材として
は、表面を荒らすことが容易なものであればどのような
組成であってもよい。例えば、線材3として、ポリプロ
ピレンとポリエチレンとの混合物とし、ポリプロピレン
が65重量%以上含有されているような組成とすること
により、繊維を割繊して表面をささくれさせることによ
り荒すことができる。ポリプロピレンが65重量%より
少なくなると、繊維を割繊しても表面を荒らすことがで
きない。
The resin material as the material of the wire 1 may have any composition as long as the surface can be easily roughened. For example, when the wire 3 is made of a mixture of polypropylene and polyethylene and has a composition containing 65% by weight or more of polypropylene, the fibers can be split and the surface can be roughened to roughen the surface. If the polypropylene content is less than 65% by weight, the surface cannot be roughened even if the fibers are split.

【0015】また、防汚剤としては、藻やゴミ等の汚染
物質の付着を防止できるものであればどのような成分の
ものでも用いることができる。このような防汚剤として
は、例えば、防汚機能を有する素材として公知な素材か
らなる光触媒、酸化マグネシウム、水酸化マグネシウ
ム、銅、銀、酸性素材(例えば、スルフォン酸等)、ア
ルカリ性素材(例えば、硼砂等)、高濃度塩化ナトリウ
ムの1種若しくは複数種を用いるとよい。
As the antifouling agent, any component can be used as long as it can prevent the attachment of contaminants such as algae and dust. Examples of such an antifouling agent include a photocatalyst made of a material known as a material having an antifouling function, magnesium oxide, magnesium hydroxide, copper, silver, an acidic material (for example, sulfonic acid), an alkaline material (for example, , Borax, etc.) and one or more of high-concentration sodium chloride.

【0016】次に、本発明の実施例を説明する。Next, examples of the present invention will be described.

【0017】実施例1、2および比較例 実施例1、2および比較例について、線材の樹脂の組成
として、ポリプロピレンとポリエチレンとを7:3、
8:2および4:6の重量比で混合し、防汚剤として平
均粒径が約2.1μmの酸化マグネシウムを樹脂に対し
て3〜20重量部混入させて、繊維に紡糸して線材を作
成し、それぞれの線材に対して割繊を施して線材の表面
を荒らすことができるか否かを試験し、その後それぞれ
の線材を海中に60日間浸漬して藻およびゴミの付着状
態を試験して、結果を表1に示した。
Examples 1 and 2 and Comparative Example In Examples 1 and 2 and Comparative Example, polypropylene and polyethylene were 7: 3 as the resin composition of the wire.
Mixing in a weight ratio of 8: 2 and 4: 6, mixing 3 to 20 parts by weight of magnesium oxide having an average particle size of about 2.1 μm as an antifouling agent with respect to the resin, and spinning the fibers to form a wire rod. Created, tested to see if each wire can be split to roughen the surface of the wire, and then each wire is immersed in the sea for 60 days to test the adhesion state of algae and dust. The results are shown in Table 1.

【0018】[0018]

【表1】 [Table 1]

【0019】表1より、ポリプロピレンとポリエチレン
との混合重量比を7:3および8:2とした実施例1お
よび2において線材の割繊を十分に行うことができ、線
材の表面をささくれさせて荒らすことができ、その結果
表面に防汚剤を露出させることができ、これにより藻等
の汚染物質の付着を確実に防止できることがわかった。
From Table 1, in Examples 1 and 2 in which the mixing weight ratio of polypropylene and polyethylene was 7: 3 and 8: 2, the wire could be sufficiently split, and the surface of the wire was blunted. It has been found that it can be roughened, and as a result, an antifouling agent can be exposed on the surface, which can reliably prevent adhesion of pollutants such as algae.

【0020】これに対してポリプロピレンとポリエチレ
ンとの混合重量比を4:6とした比較例においては、線
材の割繊を行うことができず、浸漬開始後10日に藻の
付着が認められ、汚染物質の付着を防止できないことが
わかった。
On the other hand, in the comparative example in which the mixing weight ratio of polypropylene and polyethylene was 4: 6, splitting of the wire could not be performed, and adhesion of algae was observed 10 days after the start of immersion, It was found that the attachment of pollutants cannot be prevented.

【0021】[0021]

【発明の効果】本発明の汚染防止機能を有する線材は、
このように構成され作用するものであるから、樹脂製の
線材の表面に露出している防汚剤がその防汚機能を発揮
して、汚染物質の付着が確実に防止される。従って、本
発明の線材を素材として海中に設置される海苔網等の網
糸を作成すれば、海苔以外の藻の付着繁殖を確実に防止
して、海苔のみを繁殖させることができ、更に藻やゴミ
の付着を確実に防止することができるために、海苔の病
気発生をも確実に防止することができ、良質な海苔の養
殖が可能となる。
The wire having the function of preventing pollution of the present invention is
With this structure and function, the antifouling agent exposed on the surface of the resin wire exhibits its antifouling function, and the adhesion of contaminants is reliably prevented. Therefore, by creating a net thread such as a nori net to be installed in the sea using the wire material of the present invention as a raw material, it is possible to reliably prevent the adhesion and propagation of algae other than the seaweed, and to propagate only the seaweed. Since it is possible to reliably prevent the adhesion of dirt and dust, it is possible to reliably prevent the occurrence of nori disease, and it is possible to culture good-quality nori.

【0022】また、本発明においては、線材を構成する
樹脂をポリプロピレンとポリエチレンとの混合とすると
ともに、ポリプロピレンを65重量%以上含有させるこ
とにより、線材の表面がささくれ易くなり、表面が荒ら
され防汚剤が当該表面から露出し、防汚機能が確実に発
揮されて、汚染物質の付着が確実に防止される。
Further, in the present invention, the resin constituting the wire is mixed with polypropylene and polyethylene, and the content of polypropylene is 65% by weight or more, so that the surface of the wire is easily rubbed and the surface is prevented from being roughened. The fouling agent is exposed from the surface, the antifouling function is reliably exerted, and the adhesion of contaminants is reliably prevented.

【0023】また、本発明において防汚剤として、光触
媒、酸化マグネシウム、水酸化マグネシウム、銅、銀の
1種若しくは複数種を用いると、これらの防汚剤がそれ
ぞれ優れた防汚機能を有しているので、汚染物質の付着
が確実に防止される。
When one or more kinds of photocatalyst, magnesium oxide, magnesium hydroxide, copper, and silver are used as the antifouling agent in the present invention, each of these antifouling agents has an excellent antifouling function. Therefore, the adherence of pollutants is reliably prevented.

【0024】なお、本発明は前記実施の形態および実施
例に限定されるものではなく、必要に応じて変更するこ
とができる。
The present invention is not limited to the above-described embodiments and examples, but can be modified as necessary.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の汚染防止機能を有する線材の概略構
成を示す拡大斜視図
FIG. 1 is an enlarged perspective view showing a schematic configuration of a wire rod having a pollution prevention function of the present invention.

【符号の説明】[Explanation of symbols]

1 線材 2 樹脂 3 防汚剤 1 wire rod 2 resin 3 Antifouling agent

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) A01N 59/20 A01N 59/20 Z C08K 3/00 C08K 3/00 C08L 23/12 C08L 23/12 D01F 1/10 D01F 1/10 6/46 6/46 B C // D06C 11/00 D06C 11/00 A (C08L 23/12 C08L 23:06 23:06) Fターム(参考) 3B154 AA06 AB01 BA60 BF12 DA30 4H011 AA02 AD01 BA01 BB18 BC19 DA10 DD01 DF06 DH02 4J002 BB151 DA076 DE077 DK006 EV236 FD186 4L035 AA05 CC20 EE11 EE20 FF02 JJ01 JJ04 JJ05 KK01 KK05 LA02 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) A01N 59/20 A01N 59/20 Z C08K 3/00 C08K 3/00 C08L 23/12 C08L 23/12 D01F 1 / 10 D01F 1/10 6/46 6/46 B C // D06C 11/00 D06C 11/00 A (C08L 23/12 C08L 23:06 23:06) F term (reference) 3B154 AA06 AB01 BA60 BF12 DA30 4H011 AA02 AD01 BA01 BB18 BC19 DA10 DD01 DF06 DH02 4J002 BB151 DA076 DE077 DK006 EV236 FD186 4L035 AA05 CC20 EE11 EE20 FF02 JJ01 JJ04 JJ05 KK01 KK05 LA02

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 汚染物質の付着を防止する防汚剤を含有
する樹脂製の線材であって、表面が荒らされて前記防汚
剤が露出させられていることを特徴とする汚染防止機能
を有する線材。
1. A wire rod made of a resin containing an antifouling agent for preventing adhesion of contaminants, the surface of which is roughened to expose the antifouling agent. Wire rods to have.
【請求項2】 前記樹脂製の線材は、ポリプロピレンと
ポリエチレンとの混合物であり、前記ポリプロピレンが
65重量%以上含有されており、表面をささくれさせる
ことにより荒らされていることを特徴とする請求項1に
記載の汚染防止機能を有する線材。
2. The resin wire is a mixture of polypropylene and polyethylene, contains 65% by weight or more of the polypropylene, and is roughened by flapping the surface. A wire rod having the function of preventing contamination according to 1.
【請求項3】 前記防汚剤は、光触媒、酸化マグネシウ
ム、水酸化マグネシウム、銅、銀、酸性素材、アルカリ
性素材、高濃度塩化ナトリウムの1種若しくは複数種か
らなることを特徴とする請求項1または請求項2に記載
の汚染防止機能を有する線材。
3. The antifouling agent comprises one or more of a photocatalyst, magnesium oxide, magnesium hydroxide, copper, silver, an acidic material, an alkaline material, and high-concentration sodium chloride. Alternatively, a wire rod having the function of preventing pollution according to claim 2.
JP2001226135A 2001-07-26 2001-07-26 Rod material having pollution-preventing function Pending JP2003040705A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001226135A JP2003040705A (en) 2001-07-26 2001-07-26 Rod material having pollution-preventing function

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001226135A JP2003040705A (en) 2001-07-26 2001-07-26 Rod material having pollution-preventing function

Publications (1)

Publication Number Publication Date
JP2003040705A true JP2003040705A (en) 2003-02-13

Family

ID=19059009

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001226135A Pending JP2003040705A (en) 2001-07-26 2001-07-26 Rod material having pollution-preventing function

Country Status (1)

Country Link
JP (1) JP2003040705A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006104605A (en) * 2004-10-04 2006-04-20 Japan Exlan Co Ltd Functional fiber having photocatalyst activity
JP2006265811A (en) * 2005-02-28 2006-10-05 Japan Exlan Co Ltd Volatile organic compound removing fiber
JP2006291391A (en) * 2005-04-11 2006-10-26 Japan Exlan Co Ltd Deodorizing fiber structure
JP2007046178A (en) * 2005-08-08 2007-02-22 Japan Exlan Co Ltd Stainproof fiber structural product
JP2007197337A (en) * 2006-01-24 2007-08-09 Hiroto Maeda Pollutive organism-controlling agent

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006104605A (en) * 2004-10-04 2006-04-20 Japan Exlan Co Ltd Functional fiber having photocatalyst activity
JP4560778B2 (en) * 2004-10-04 2010-10-13 日本エクスラン工業株式会社 Functional fiber with photocatalytic activity
JP2006265811A (en) * 2005-02-28 2006-10-05 Japan Exlan Co Ltd Volatile organic compound removing fiber
JP4560795B2 (en) * 2005-02-28 2010-10-13 日本エクスラン工業株式会社 Volatile organic compound removal fiber structure
JP2006291391A (en) * 2005-04-11 2006-10-26 Japan Exlan Co Ltd Deodorizing fiber structure
JP4560787B2 (en) * 2005-04-11 2010-10-13 日本エクスラン工業株式会社 Deodorant fiber structure
JP2007046178A (en) * 2005-08-08 2007-02-22 Japan Exlan Co Ltd Stainproof fiber structural product
JP4560791B2 (en) * 2005-08-08 2010-10-13 日本エクスラン工業株式会社 Method for imparting antifouling property to the entire fiber structure
JP2007197337A (en) * 2006-01-24 2007-08-09 Hiroto Maeda Pollutive organism-controlling agent

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