JP2003019750A - Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor - Google Patents

Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor

Info

Publication number
JP2003019750A
JP2003019750A JP2001209190A JP2001209190A JP2003019750A JP 2003019750 A JP2003019750 A JP 2003019750A JP 2001209190 A JP2001209190 A JP 2001209190A JP 2001209190 A JP2001209190 A JP 2001209190A JP 2003019750 A JP2003019750 A JP 2003019750A
Authority
JP
Japan
Prior art keywords
resin
heating
metal strip
metal
curved surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001209190A
Other languages
Japanese (ja)
Inventor
Shingo Kumamoto
晋吾 熊本
Yukiro Yoshimura
征郎 吉村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proterial Ltd
Original Assignee
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Metals Ltd filed Critical Hitachi Metals Ltd
Priority to JP2001209190A priority Critical patent/JP2003019750A/en
Publication of JP2003019750A publication Critical patent/JP2003019750A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a method for manufacturing a laminated metal strip with a resin capable of continuously performing pressurization and thermosetting treatment and the winding feed of the laminated metal strip with the resin and drastically enhancing the adhesion reliability of an adhesion interface, and a manufacturing apparatus suitable therefor. SOLUTION: In the method for manufacturing the laminated metal strip with the resin by bonding a second metal strip to the surface on the resin layer side of a metal strip with the resin having a first metal layer and a thermosetting resin layer, the metal strip with the resin and the second metal strip are superposed one upon another to be mated with the outer periphery of a heating curved surface and bonded under pressure while continuously heated on the outer periphery of a heating curved surface.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、例えば半導体装置
の配線基板用材料として用いられる、樹脂付き積層金属
帯の製造方法及び樹脂付き積層金属帯の製造装置に関す
るものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a laminated metal strip with a resin and an apparatus for producing a laminated metal strip with a resin, which are used as a material for a wiring board of a semiconductor device, for example.

【0002】[0002]

【従来の技術】半導体パッケージの配線基板用材料に
は、回路を形成する導電層、絶縁層から構成される樹脂
付き金属が多く用いられる。樹脂付き金属において導電
層は一般に金属からなり、電解銅箔、圧延銅箔、銅めっ
き等により形成される。また、絶縁層は一般に樹脂から
なり、半導体パッケージ製造工程に含まれるワイヤーボ
ンディング、ダイボンディング、モールド等の加熱工程
に耐えるため、熱可塑性樹脂ではなく耐熱性を有する熱
硬化性樹脂が多く使用されている。具体的には、エポキ
シ樹脂、ポリイミド樹脂、ポリアミドイミド樹脂等が用
いられる。これら樹脂付き金属は、溶剤に溶かした液状
樹脂を金属箔表面に塗布することにより製造することが
出来る。
2. Description of the Related Art As a material for a wiring board of a semiconductor package, a resin-coated metal composed of a conductive layer and an insulating layer forming a circuit is often used. In metal with resin, the conductive layer is generally made of metal and is formed by electrolytic copper foil, rolled copper foil, copper plating, or the like. In addition, the insulating layer is generally made of resin, and because it withstands heating processes such as wire bonding, die bonding, and mold included in the semiconductor package manufacturing process, thermosetting resin having heat resistance is often used instead of thermoplastic resin. There is. Specifically, an epoxy resin, a polyimide resin, a polyamideimide resin, or the like is used. These resin-coated metals can be manufactured by applying a liquid resin dissolved in a solvent onto the surface of the metal foil.

【0003】近年の半導体パッケージの薄型化に伴い樹
脂付き金属も薄型化が行われている。例えば導電層とな
る金属層の厚さは12〜35μm、絶縁層となる樹脂層の厚
さが30〜80μm程度にまで薄型化が行われており、その
結果、樹脂付き金属はそれ自体の剛性のみでは形状を保
持できなくなりつつある。そのためこれら板厚の薄い樹
脂付き金属においては、キャリア層となる20〜200μm
程度の厚さの金属を樹脂側に別途接合し、図3(b)に
一例を示す導体層/樹脂層(絶縁層)/キャリア層の積層構
造の材料が用いられている(以下、キャリア層を具備し
た樹脂付き金属を、樹脂付き積層金属と表記する)。上
述の樹脂付き積層金属は、導電層となる第一の金属層
と、キャリア層となる板材の第二の金属層は、必ずしも
同じ材質ではなく、例えば、第一の金属としては銅また
は銅合金が主に使用され、第二の金属としては銅、銅合
金、ステンレス鋼、鉄−ニッケル合金等が使用される。
With the recent reduction in the thickness of semiconductor packages, metal with resin has been reduced in thickness. For example, the thickness of the metal layer that becomes the conductive layer is 12 to 35 μm, and the thickness of the resin layer that becomes the insulating layer is about 30 to 80 μm. As a result, the metal with resin has its own rigidity. It is becoming difficult to maintain the shape by itself. Therefore, in these resin-coated metals with a thin plate thickness, the carrier layer is 20 to 200 μm.
A material having a laminated structure of a conductor layer / resin layer (insulating layer) / carrier layer whose example is shown in FIG. 3B is used by separately bonding a metal having a certain thickness to the resin side. The metal with resin having the above is referred to as a laminated metal with resin). In the above-mentioned laminated metal with resin, the first metal layer to be the conductive layer and the second metal layer of the plate material to be the carrier layer are not necessarily the same material, and for example, copper or copper alloy is used as the first metal. Is mainly used, and as the second metal, copper, copper alloy, stainless steel, iron-nickel alloy or the like is used.

【0004】この樹脂付き積層金属では、絶縁層である
樹脂層は、導体層とキャリア層を接合するための接合層
としての役割も有する。既述のように樹脂層には熱硬化
性樹脂が用いられるが、熱硬化性樹脂は熱硬化反応と共
に接着力が発現するため、十分な接着強度を得るには、
接合させる帯材を密着させた状態で加圧し、かつ加熱を
行いながら、30〜120s程度と熱可塑性樹脂と比較して長
時間保持(熱硬化処理)することが必要となる。そのた
め従来、例えば図5中に示した加熱プレス16で加圧可
能なサイズの板材を供給し、加圧および熱硬化処理が行
われている。ここで熱硬化処理としては、図5に示す装
置で接着と同時に行う方法の他、同装置で短時間の加圧
および加熱(5s〜)により仮接着を行った後、別途加熱
炉などで再度加熱保持し、熱硬化反応を進めて接着を完
了させる方法も取られている。
In this laminated metal with resin, the resin layer, which is an insulating layer, also serves as a joining layer for joining the conductor layer and the carrier layer. As described above, a thermosetting resin is used for the resin layer, but since the thermosetting resin develops an adhesive force with a thermosetting reaction, in order to obtain sufficient adhesive strength,
It is necessary to press the band material to be bonded in a closely contacted state and heat it for about 30 to 120 s for a long time (thermosetting treatment) as compared with the thermoplastic resin. Therefore, conventionally, for example, a plate material having a size pressurizable by the heating press 16 shown in FIG. 5 is supplied, and pressurization and thermosetting treatment are performed. Here, as the thermosetting treatment, in addition to the method of performing the bonding at the same time with the device shown in FIG. 5, temporary bonding is performed by the same device for a short time of pressurization and heating (5 s to), and then it is again heated in a separate heating furnace. There is also a method in which heating and holding are performed and a thermosetting reaction is promoted to complete the adhesion.

【0005】[0005]

【発明が解決しようとする課題】近年、半導体パッケー
ジの生産性向上のため、連続的な加工が可能な帯材の樹
脂付き積層金属、すなわち樹脂付き積層金属帯(図3に
例示する)が要求されている。ここで帯材とは、その幅
に対して長さが長く、コイル状に巻くことが可能な形態
を持つ板材を指す。図5に示す装置により樹脂付き積層
金属帯を製造する場合、加熱プレス16で部分的に加
圧、熱硬化処理した(図5(a))後、積層金属帯を巻
送り(図5(b))し、熱硬化処理済部の隣接部を順次
同様に加圧、熱硬化処理を繰り返すことにより行われ
る。この方法の場合、加熱プレス16の端で熱硬化処理
は不連続となり、境界部17が生じることは避けられな
い。その結果、境界部17において接着強さの変動やプ
レス痕発生の問題が生じ、樹脂付き積層金属帯を用いて
の半導体パッケージ生産時における材料歩留まりの低下
が懸念される。加えて図5の装置では、加熱プレス16
で熱硬化処理または仮接着中、材料の巻送りを一時停止
させる必要があり、生産性が低下することが問題とな
る。
In recent years, in order to improve the productivity of semiconductor packages, there is a demand for a resin-coated laminated metal of a band material that can be continuously processed, that is, a resin-laminated metal band (exemplified in FIG. 3). Has been done. Here, the band member refers to a plate member having a length that is longer than its width and that can be wound in a coil shape. In the case of producing a laminated metal strip with resin by the apparatus shown in FIG. 5, the laminated metal strip is wound (FIG. 5 (b) after being partially pressed by the heating press 16 and heat-cured (FIG. 5 (a)). )), The adjacent portions of the heat-cured portion are sequentially pressed and heat-cured in the same manner. In the case of this method, the thermosetting treatment becomes discontinuous at the end of the heating press 16 and the boundary 17 is unavoidable. As a result, there arises a problem of fluctuations in adhesive strength and generation of press marks at the boundary portion 17, and there is a concern that the material yield may be reduced during the production of semiconductor packages using the resin-coated laminated metal strip. In addition, in the apparatus shown in FIG.
Therefore, it is necessary to temporarily stop the winding of the material during the heat curing treatment or the temporary adhesion, which causes a problem that the productivity is lowered.

【0006】上記生産性の問題に対しては、ラミネータ
ー(laminator)として一般に用いられる装
置、例えば図6に示す水平方向に上下の圧着ロール8を
具備しており、圧着ロールまたは圧着ロールとは別体の
加熱装置を用いて、樹脂付き金属帯と第二の金属帯の両
方あるいは一方の加熱を行い、前述の圧着ロールにより
樹脂層を介して両者を連続して接合させる装置を適用す
ることも考えられる。しかしながらこのような装置で
は、樹脂付き金属帯と第二の金属帯が樹脂を介して加圧
される時間が、上下圧着ロール間を通過する一瞬であ
り、熱硬化性樹脂の硬化に対して十分な熱硬化処理時間
を確保することが非常に困難である。その結果、熱硬化
性樹脂の接着力不足という致命的な問題を生じ、仮接着
を目的とする場合であっても、仮接着後再度加熱保持す
る迄のハンドリングが可能な程度の仮接着力を得ること
が難しく、巻取り、熱硬化処理等のハンドリング時に剥
離してしまうような重大な問題を生じる。
To solve the above-mentioned problem of productivity, a device generally used as a laminator, for example, the upper and lower crimping rolls 8 in the horizontal direction shown in FIG. 6 is provided, which is different from the crimping roll or the crimping roll. It is also possible to apply a device for heating both or one of the metal band with resin and the second metal band by using the heating device for the body, and continuously joining the two through the resin layer by the above-mentioned pressure-bonding roll. Conceivable. However, in such an apparatus, the time when the resin-coated metal strip and the second metal strip are pressed through the resin is the moment when they pass between the upper and lower pressure bonding rolls, which is sufficient for curing the thermosetting resin. It is very difficult to secure a long heat curing treatment time. As a result, a fatal problem of insufficient adhesive strength of the thermosetting resin occurs, and even when the purpose is temporary adhesion, the temporary adhesive strength is such that it can be handled until it is heated and held again after temporary adhesion. It is difficult to obtain and causes a serious problem such as peeling at the time of handling such as winding and thermosetting.

【0007】本発明では、加圧、熱硬化処理と樹脂付き
積層金属帯の巻送りを連続的に行う事が可能で、かつ上
述した熱硬化性樹脂の仮接着力の確保も可能であり、接
着界面の接着信頼性を飛躍的に向上させた樹脂付き積層
金属帯の製造方法、及びそれに好適な製造装置を提供す
る。
In the present invention, it is possible to continuously carry out pressure and thermosetting treatment and winding of the resin-coated laminated metal strip, and it is also possible to secure the temporary adhesive force of the thermosetting resin described above. (EN) Provided are a method for manufacturing a laminated metal band with a resin, in which the bonding reliability of a bonding interface is dramatically improved, and a manufacturing apparatus suitable for the method.

【0008】[0008]

【課題を解決するための手段】本発明者らは、加熱曲面
の外周面に沿わせて樹脂付き積層金属帯を連続的に加熱
しながら圧接することで上記課題を解決できることを見
出し、本発明に想到した。
Means for Solving the Problems The present inventors have found that the above problems can be solved by pressing the resin-coated laminated metal strip while continuously heating it along the outer peripheral surface of the heating curved surface. Was conceived.

【0009】すなわち本発明の樹脂付き積層金属帯の製
造方法は、第一の金属層と熱硬化性の樹脂層との二層を
有する樹脂付き金属帯の樹脂層側表面に、第二の金属帯
を接合する樹脂付き積層金属帯の製造方法において、前
記樹脂付き金属帯と第二の金属帯とを重ね合わせて加熱
曲面の外周面に沿わせ、該加熱曲面の外周面上で前記樹
脂付き金属帯と第二の金属帯とを連続的に加熱しながら
圧接する製造方法である。
That is, the method for producing a laminated metal band with resin according to the present invention is such that the second metal is formed on the resin layer side surface of the metal band with resin having two layers of the first metal layer and the thermosetting resin layer. In the method for manufacturing a laminated metal band with resin for joining bands, the metal band with resin and a second metal band are superposed on each other along the outer peripheral surface of the heating curved surface, and the resin is attached on the outer peripheral surface of the heating curved surface. This is a manufacturing method in which the metal strip and the second metal strip are continuously heated and pressed together.

【0010】上記発明では、樹脂付き金属帯を加熱曲面
の外周面に沿わせる直前に、該樹脂付き金属帯を予熱す
ること、さらには樹脂付き金属帯を加熱曲面の外周面に
沿わせる直前に、加熱曲面と並列して設けられたガイド
ロールを通過させること、さらには樹脂付き金属帯を前
記ガイドロールにより予熱することを特徴とすることが
好ましい。
In the above invention, the resin-coated metal strip is preheated immediately before the resin-coated metal strip is placed along the outer peripheral surface of the heating curved surface, and further, immediately before the resin-coated metal strip is placed along the outer peripheral surface of the heated curved surface. Preferably, it is characterized by passing through a guide roll provided in parallel with the heating curved surface, and further preheating the metal band with resin by the guide roll.

【0011】また本発明の別の樹脂付き積層金属帯の製
造方法は、第一の金属帯と第二の金属帯とを熱硬化性の
樹脂帯を介して接合する樹脂付き積層金属帯の製造方法
において、第一の金属帯と樹脂帯と第二の金属帯とを重
ね合わせて加熱曲面の外周面に沿わせ、該加熱曲面の外
周面上で前記第一の金属帯と樹脂帯と第二の金属帯とを
連続的に加熱しながら圧接する製造方法である。
Another method of manufacturing a laminated metal band with a resin according to the present invention is a method for manufacturing a laminated metal band with a resin in which a first metal band and a second metal band are joined via a thermosetting resin band. In the method, the first metal strip, the resin strip, and the second metal strip are superposed on each other along the outer circumferential surface of the heating curved surface, and the first metal strip, the resin strip, and the second strip are formed on the outer circumferential surface of the heating curved surface. In this method, the second metal strip and the second metal strip are continuously heated and pressed together.

【0012】以上の発明では、加えて前記の接合は真空
槽内で行うことが好ましい。
In the above invention, in addition, it is preferable that the joining is performed in a vacuum chamber.

【0013】次に本発明の樹脂付き積層金属帯の製造装
置は、第一の金属層と熱硬化性の樹脂層との二層からな
る樹脂付き金属帯を巻出す巻出し手段と、第二の金属帯
を巻出す巻出し手段と、外周面を加熱可能な加熱曲面と
を具備し、前記樹脂付き金属帯と第二の金属帯とが加熱
曲面の外周面上に沿って重なり合った状態で移動する装
置である。
Next, the apparatus for producing a laminated metal band with resin according to the present invention comprises an unwinding means for unwinding a resin-coated metal band consisting of two layers of a first metal layer and a thermosetting resin layer, and a second In the state where the unwinding means for unwinding the metal strip and the heating curved surface capable of heating the outer peripheral surface are provided, and the metal strip with resin and the second metal strip are overlapped on the outer peripheral surface of the heating curved surface. It is a moving device.

【0014】上記製造装置では、加熱曲面と並列してガ
イドロールを具備し、該ガイドロールは樹脂付き金属帯
を加熱曲面へ供給する前に予熱するための加熱装置を具
備することが好ましい。
In the above-mentioned manufacturing apparatus, it is preferable that a guide roll is provided in parallel with the heating curved surface, and the guide roll is provided with a heating device for preheating the metal band with resin before supplying to the heating curved surface.

【0015】また本発明の別の樹脂付き積層金属帯の製
造装置は、第一の金属帯を巻出す巻出し手段と、熱硬化
性の樹脂帯を巻出す巻出し手段と、第二の金属帯を巻出
す巻出し手段と、外周面を加熱可能な加熱曲面とを具備
し、前記第一の金属帯と熱硬化性の樹脂帯と第二の金属
帯とが加熱曲面の外周面上に沿って重なり合った状態で
移動する製造装置である。
Another embodiment of the apparatus for producing a laminated metal strip with resin according to the present invention is: unwinding means for unwinding the first metal strip, unwinding means for unwinding the thermosetting resin strip, and second metal. The unwinding means for unwinding the strip and the heating curved surface capable of heating the outer peripheral surface are provided, and the first metal strip, the thermosetting resin strip, and the second metal strip are provided on the outer peripheral surface of the heating curved surface. It is a manufacturing device that moves in a state of being overlapped with each other.

【0016】以上の製造装置では、少なくとも前記加熱
曲面が真空槽内に配置されていることが好ましい。
In the above manufacturing apparatus, it is preferable that at least the heating curved surface is arranged in a vacuum chamber.

【0017】[0017]

【発明の実施の形態】上述したように、本発明の樹脂付
き積層金属帯の製造方法、及び製造装置の重要な特徴
は、樹脂付き金属帯と第二の金属帯を面状に接触させた
状態で加熱曲面の外周面上に巻き付けるように沿わせ
て、接着に必要な時間を確保したことにある。本発明で
加熱曲面とは、例えば円筒形の加熱ロールを用いること
ができる。また、面接触させた状態で接着に必要な時間
を確保できれば、加熱ロールに限定するものではなく、
加熱ベルトのようなものも採用できる。 具体的には、例えば本発明の一実施例である図1に記載
の装置により実施することが出来る。
BEST MODE FOR CARRYING OUT THE INVENTION As described above, an important feature of the method for producing a laminated metal strip with resin and the production apparatus of the present invention is that the metal strip with resin and the second metal strip are brought into planar contact with each other. The reason is that the time required for bonding is secured by winding it along the outer peripheral surface of the heating curved surface in this state. In the present invention, the heating curved surface may be, for example, a cylindrical heating roll. Also, if the time required for bonding can be secured in the state of surface contact, it is not limited to the heating roll,
A thing like a heating belt can also be adopted. Specifically, for example, the apparatus shown in FIG. 1 which is an embodiment of the present invention can be used.

【0018】図1において、巻出し機12aから巻出さ
れた樹脂付き金属帯1と巻出し機12bから巻出された
第二の金属帯3とは、回転する加熱ロール6の外周面上
の、圧接および加熱開始位置14で樹脂層を介して積層
される。その後、加熱ロール6の外周面に沿った状態で
加圧され、加熱ロールの回転に従って移動しながら圧
接、加熱される。圧接および加熱終了位置15まで達し
たところで、樹脂付き積層金属帯5は加熱ロールから離
れ、冷却ロールに沿って温度が低下した後、巻取り機1
3により巻き取られる。本発明の方法では、樹脂付き積
層金属帯を加熱ロールに沿わせるため、加熱ロールは圧
接および加熱開始位置14から圧接および加熱終了位置
15において加熱の機能を果たすのみならず、樹脂付き
金属帯1に付与される張力と協働して、樹脂付き金属帯
1を第二の金属帯3に押し付ける圧接力を付与する機能
も有する。
In FIG. 1, the resin-coated metal strip 1 unwound from the unwinder 12a and the second metal strip 3 unwound from the unwinder 12b are on the outer peripheral surface of the rotating heating roll 6. , The pressure contact and heating start positions 14 are laminated via the resin layer. After that, pressure is applied along the outer peripheral surface of the heating roll 6, and is pressed and heated while moving according to the rotation of the heating roll. When the pressure contact and heating end position 15 is reached, the laminated metal strip with resin 5 separates from the heating roll, the temperature decreases along the cooling roll, and then the winding machine 1
It is wound up by 3. In the method of the present invention, since the laminated metal strip with resin is along the heating roll, the heating roll not only performs the function of heating from the pressure contact and heating start position 14 to the pressure contact and heating end position 15, but also the resin-coated metal band 1 It also has a function of applying a pressure contact force for pressing the resin-coated metal strip 1 against the second metal strip 3 in cooperation with the tension applied to the.

【0019】図6に示す従来のラミネーターは、圧接お
よび加熱開始・終了位置がほぼ同じ位置であり、圧接・
加熱時間が極短時間であるのに対し、上述のように本発
明の方法によれば圧接および加熱開始位置14から圧接
および加熱終了位置15まで圧接・加熱の状態を維持す
ることができ、仮接着に十分な接着強度、さらには仮接
着後の再加熱を必要としない接着強度に達するまでの熱
硬化処理時間を確保することができる。その結果、本発
明の方法および装置では、樹脂層に用いる樹脂としてエ
ポキシ系、ポリイミド系、ポリアミド・イミド系、シリ
コーン系、アクリル系、ポリエステル系、ポリウレタン
系などの熱硬化性樹脂を必要に応じて選択できる。
In the conventional laminator shown in FIG. 6, the pressure contact and heating start / end positions are almost the same, and
While the heating time is extremely short, as described above, according to the method of the present invention, the pressure contact / heating state can be maintained from the pressure contact / heating start position 14 to the pressure contact / heating end position 15. It is possible to secure a sufficient adhesive strength for adhesion, and further a thermosetting treatment time until reaching an adhesive strength that does not require reheating after temporary adhesion. As a result, in the method and apparatus of the present invention, a thermosetting resin such as an epoxy resin, a polyimide resin, a polyamide-imide resin, a silicone resin, an acrylic resin, a polyester resin, or a polyurethane resin is used as the resin for the resin layer, if necessary. You can choose.

【0020】本発明の方法および装置において加熱する
時間は、加熱ロール上で樹脂付き金属帯と第二の金属帯
が接触している時間に依存するが、加熱ロールの回転速
度を調整することにより、加熱時間を調整可能である。
よって、仮接着を目的とした短時間の加熱から、熱硬化
処理を完了させる長時間の加熱まで、連続して加熱時間
を調節可能である。
The heating time in the method and apparatus of the present invention depends on the time during which the resin-coated metal strip and the second metal strip are in contact with each other on the heating roll, but by adjusting the rotation speed of the heating roll. The heating time can be adjusted.
Therefore, the heating time can be adjusted continuously from short-time heating for the purpose of temporary adhesion to long-time heating for completing the thermosetting treatment.

【0021】ここで、熱硬化性樹脂の接着力を発現させ
るためには、少なくとも1s以上の加熱時間が必要であ
る。また、10minより長く加熱した場合、熱硬化性樹脂
の架橋により加熱ロールに沿った状態で硬化してしま
い、接着後に長さ方向の反り形状が生じる場合がある。
よって、本発明の方法および装置を用いて樹脂付き積層
金属帯を製造する場合は、加熱時間を1s以上10min以下
として仮接着を行った後、別途加熱装置を用いて熱硬化
処理を行い、接着を完了させることが好ましい。別途行
う加熱装置としては、帯材を搬送可能な連続加熱炉が挙
げられる。また、仮接着後の樹脂付き積層金属帯を、直
径300mm以上の巻芯に巻き取ったコイルの状態で加熱
し、熱硬化処理を行った後、必要に応じてレベラー等を
用いた形状矯正を行うことにより、樹脂付き積層金属帯
の製造が可能である。
Here, in order to develop the adhesive force of the thermosetting resin, at least a heating time of 1 s or more is required. In addition, when the heating is performed for more than 10 minutes, the thermosetting resin may be cross-linked to cure along the heating roll, resulting in a warped shape in the length direction after bonding.
Therefore, when manufacturing a resin-coated laminated metal strip using the method and apparatus of the present invention, after performing temporary bonding with a heating time of 1 s or more and 10 min or less, a thermosetting process is separately performed using a heating device, and bonding is performed. Is preferably completed. As a heating device separately performed, a continuous heating furnace capable of transporting the strip material can be used. Also, the laminated metal band with resin after temporary adhesion is heated in the state of a coil wound around a core having a diameter of 300 mm or more, and subjected to thermosetting treatment, and if necessary, shape correction using a leveler or the like. By doing so, it is possible to manufacture a laminated metal strip with resin.

【0022】上述のように両者を密着させる圧力は、樹
脂付き金属帯の巻出しおよび樹脂付き積層金属帯の巻取
りによって、樹脂付き金属帯に掛かる張力により発生す
る。さらに密着させる圧力を確保するために、図1に示
すように圧接および加熱開始位置14以降に、圧着ロー
ル8を設置し、圧着ロール8と加熱ロール6で両者を加
圧することも有効である。圧着ロールは、樹脂付き金属
帯の金属表面を傷付けずに、均一に加圧するため、耐熱
ゴム等の軟らかい材質の使用が好ましい。
As described above, the pressure for bringing them into close contact with each other is generated by the tension applied to the resin-coated metal strip by unwinding the resin-coated metal strip and winding the resin-coated laminated metal strip. In order to secure the pressure for further contact, it is also effective to install a pressure roll 8 after the pressure contact and heating start position 14 as shown in FIG. 1 and press both of them with the pressure roll 8 and the heating roll 6. It is preferable to use a soft material such as heat resistant rubber for the pressure-bonding roll in order to uniformly press the metal surface of the resin-coated metal strip without damaging the metal surface.

【0023】本発明に用いる加熱ロールのロール材質
は、熱伝導性を考慮すると、銅製の加熱ロールを用いる
ことが出来る。ただし、銅製ロールは軟らかく、傷が付
き易く、また例えば大気中でロール温度を200℃以上昇
温する必要がある場合、表面の酸化に伴いロール表面が
粗くなり、供給した帯材を傷付ける恐れがある。よって
加熱ロールには、硬さがあり傷付きにくく、耐酸化性も
有するステンレス鋼の使用がより好ましい。ここでステ
ンレス鋼とは、クロムを質量パーセントで10%以上含む
鉄基の合金である。
As the roll material of the heating roll used in the present invention, a heating roll made of copper can be used in consideration of thermal conductivity. However, the copper roll is soft and easily scratched, and, for example, when it is necessary to raise the roll temperature to 200 ° C. or more in the atmosphere, the roll surface becomes rough due to the oxidation of the surface, and the supplied strip material may be damaged. is there. Therefore, for the heating roll, it is more preferable to use stainless steel which has hardness, is not easily scratched, and has oxidation resistance. Here, stainless steel is an iron-based alloy containing 10% or more chromium by mass.

【0024】既述のように樹脂付き金属帯には、非常に
薄い銅箔および樹脂等が用いられており、また樹脂付き
金属帯を構成する第一の金属帯層と樹脂層とでは熱膨張
係数が異なる。これらの理由から樹脂付き金属帯は、第
一の金属層および樹脂層の厚さや加熱ロールでの加熱温
度によっては、加熱時の熱膨張によりしわが生じる場合
がある。しわを発生させた状態で、圧着ロールを用いた
仮接着を行うと、しわを生じた部分は未接合部となり気
泡が残存する。気泡は、仮接着後の熱硬化処理または半
導体パッケージ工程での加熱において膨れを生じる、第
一の金属層とキャリア層の剥離が生じる等の要因とな
り、これらは重大な製品欠陥となる。このようなしわの
発生は、樹脂付き金属帯を加熱ロールの外周面に巻付け
る直前に予熱することにより低減することができる。
As already mentioned, a very thin copper foil, resin, etc. are used for the resin-coated metal strip, and the first metal strip layer and the resin layer constituting the resin-coated metal strip are thermally expanded. The coefficient is different. For these reasons, the metal band with resin may cause wrinkles due to thermal expansion during heating depending on the thickness of the first metal layer and the resin layer and the heating temperature of the heating roll. If temporary bonding is performed using a pressure roll with wrinkles generated, the wrinkled portions become unbonded portions and bubbles remain. Air bubbles cause swelling due to thermosetting treatment after temporary adhesion or heating in the semiconductor packaging process, separation of the first metal layer and carrier layer, and the like, which are serious product defects. The occurrence of such wrinkles can be reduced by preheating the resin-coated metal strip immediately before winding it on the outer peripheral surface of the heating roll.

【0025】予熱を行うことにより、加熱ロールの外周
面に巻付く前に第一の金属層と樹脂層を熱膨張させる。
予熱されて熱膨張した樹脂付き金属帯はしわを生じる
が、加熱ロール外周面上の圧接および加熱開始位置に達
する前に、樹脂付き金属帯に掛かる張力によりしわが伸
ばされた状態となる。この状態で加熱ロールに供給する
ことにより、加熱ロールで第二の金属帯と接着される
際、しわが無く両者を積層して接触させることができ、
その結果接着界面に欠陥を残す要因を低減できる。
By preheating, the first metal layer and the resin layer are thermally expanded before being wound around the outer peripheral surface of the heating roll.
The metal band with resin which has been preheated and thermally expanded causes wrinkles, but the wrinkles are stretched by the tension applied to the metal band with resin before the pressure contact and the heating start position on the outer peripheral surface of the heating roll. By supplying to the heating roll in this state, when being bonded to the second metal strip by the heating roll, it is possible to stack and contact both without wrinkles,
As a result, it is possible to reduce the factors that leave defects at the adhesive interface.

【0026】上記において、予熱した樹脂付き金属帯の
しわをさらに効果的に伸ばすためには、加熱ロールと並
列してガイドロールを設置し、ガイドロールを通過させ
た後に加熱ロールへ供給することが好ましい。樹脂付き
金属帯に掛かる張力との作用により、熱膨張に起因する
しわの大部分をガイドロールとの接触時に除去すること
ができ、接着界面に欠陥を残す要因を一層低減できる。
In the above, in order to more effectively spread the wrinkles of the preheated metal band with resin, a guide roll may be installed in parallel with the heating roll, and after passing through the guide roll, it may be supplied to the heating roll. preferable. Due to the effect of the tension applied to the resin-coated metal strip, most of the wrinkles caused by thermal expansion can be removed at the time of contact with the guide roll, and the factor that leaves a defect at the adhesive interface can be further reduced.

【0027】ガイドロールを用いて効果的に欠陥を低減
する為には、加熱ロールとガイドロールとの間隔が重要
である。ガイドロール通過後の樹脂付き金属帯は、ある
程度の長さでしわが伸ばされた形状を保つが、離れるに
従いしわが発生し易くなる。そこで、樹脂付き金属帯が
ガイドロールを離れ、加熱ロール上の第二の金属帯と接
触するまでの距離は、極力短い方が好ましい。具体的に
は、ガイドロールと加熱ロールの共通接線上において、
前記共通接線と前記ガイドロールおよび加熱ロールの接
点間の距離が0mmより大きく30mm未満とすることが好ま
しい。0mmではガイドロールと加熱ロールが接触し、樹
脂付き金属帯の第一の金属表面を傷付ける恐れがある。
また、ロールの熱膨張によりロール同士が接触し、素材
を圧下してしまう恐れがある。30mm以上離れると、伸ば
された形状を維持できず、しわが断続して発生する場合
があるのみならず、予熱した温度の低下も懸念される。
より好ましくは5mm以上25mm以下である。
In order to effectively reduce defects by using the guide roll, the distance between the heating roll and the guide roll is important. The metal band with resin after passing through the guide roll keeps the shape in which wrinkles are stretched for a certain length, but wrinkles are apt to occur as the distance increases. Therefore, it is preferable that the distance from the metal strip with resin leaving the guide roll to the contact with the second metal strip on the heating roll is as short as possible. Specifically, on the common tangent line of the guide roll and the heating roll,
The distance between the common tangent and the contact points of the guide roll and the heating roll is preferably more than 0 mm and less than 30 mm. At 0 mm, the guide roll and the heating roll may come into contact with each other, and the first metal surface of the resin-coated metal strip may be damaged.
In addition, the rolls may come into contact with each other due to the thermal expansion of the rolls, and the material may be rolled down. If it is separated by 30 mm or more, the stretched shape cannot be maintained, wrinkles may occur intermittently, and there is a concern that the preheated temperature may decrease.
More preferably, it is 5 mm or more and 25 mm or less.

【0028】本発明で樹脂付き金属帯の予熱は、樹脂付
き金属帯に直接温風加熱を行う、または赤外線ランプヒ
ーター等の輻射熱により直接加熱を行う等の他、ガイド
ロール自体を加熱することにより行うことが出来る。こ
のうち前者の二つのような加熱方法では、樹脂付き金属
帯は薄く熱容量が小さく外気の影響を受け易いため、温
度管理が困難な場合がある。そこで好ましくは、ガイド
ロールにより予熱を行う。
In the present invention, the resin-coated metal strip is preheated by heating the resin-coated metal strip directly with warm air, by directly heating with radiant heat from an infrared lamp heater, or by heating the guide roll itself. You can do it. In the former two heating methods, the metal band with resin is thin and has a small heat capacity and is easily affected by the outside air, so that temperature control may be difficult. Therefore, preferably, the guide roll is used for preheating.

【0029】ガイドロールにより樹脂付き金属帯を予熱
し、かつしわを伸ばした状態で加熱ロールに供給するこ
とにより、最も効果的に欠陥を抑制した接着が可能とな
る。ガイドロールと加熱ロールとは、上述した様に近接
して配置するため、移動中の温度低下も最小に抑えられ
る。ガイドロールの加熱方法としては、ガイドロール外
部からの加熱も行えるが、ガイドロールに加熱源を内蔵
させることが好ましい。この加熱源としては、熱線、誘
導加熱コイル、ガイドロール内部の伝熱媒体の移動等が
挙げられる。
By preheating the metal strip with resin by the guide roll and supplying it to the heating roll in the state where the wrinkles are extended, it is possible to most effectively perform the bonding with the defects suppressed. Since the guide roll and the heating roll are arranged close to each other as described above, the temperature drop during the movement can be minimized. As a method for heating the guide roll, heating from outside the guide roll can be performed, but it is preferable to incorporate a heating source in the guide roll. Examples of the heating source include a heat wire, an induction heating coil, and movement of a heat transfer medium inside the guide roll.

【0030】予熱温度は、加熱ロールの温度を基準とし
て、プラスマイナス50℃以内に管理することが好まし
い。50℃より低い場合、加熱ロールに接触した際、さら
に熱膨張が生じ、しわが発生する。50℃より高い場合、
逆に収縮が生じ、しわが発生する恐れがある。より好ま
しくは、加熱ロール接触時に、樹脂付き金属帯の温度が
加熱ロールとほぼ同一になるよう調節する。
The preheating temperature is preferably controlled within ± 50 ° C. with reference to the temperature of the heating roll. When it is lower than 50 ° C, when it comes into contact with a heating roll, further thermal expansion occurs and wrinkles occur. If higher than 50 ℃,
On the contrary, contraction may occur and wrinkles may occur. More preferably, at the time of contact with the heating roll, the temperature of the metal band with resin is adjusted to be substantially the same as that of the heating roll.

【0031】上記の他、効果的にしわの発生を抑制し欠
陥を低減する為には、圧接および加熱終了位置から離れ
た樹脂付き積層金属帯を冷却することが好ましい。樹脂
付き積層金属帯を、樹脂層のガラス転移温度(Tg)以
下に冷却することにより、樹脂層の流動性を著しく低下
することができ、圧接および加熱終了位置から離れた以
降のしわの発生を抑制することができる。 上記樹脂付き積層金属帯の冷却は、冷却ロールを用いる
ほか、ロール以外の冷却手段、例えば冷却空気の吹き付
けによる行うことができる。
In addition to the above, in order to effectively suppress the generation of wrinkles and reduce defects, it is preferable to cool the resin-coated laminated metal strip separated from the pressure welding and heating end position. By cooling the laminated metal band with resin to the glass transition temperature (Tg) or lower of the resin layer, the fluidity of the resin layer can be remarkably reduced, and wrinkles are generated after the press contact and the heating end position. Can be suppressed. The resin-coated laminated metal strip can be cooled by using a cooling roll or by cooling means other than the roll, for example, by blowing cooling air.

【0032】具体的には、本発明の装置の一実施例であ
る図1に記載の装置により実施することが出来る。本発
明に係る製造装置は、加熱ロール6に並列してガイドロ
ール7aを備える。樹脂付き金属帯1は、巻出し機12
aより巻出され、ガイドロール7aを通過後、加熱ロー
ル6に供給される。このとき樹脂付き金属帯1は、加熱
ロール5に供給される前に、ガイドロール7aにより予
熱される。樹脂付き積層金属帯1は加熱ロール外周上で
圧接および加熱され、圧接および加熱終了位置から離れ
た後、冷却ロール9により樹脂層のガラス転移温度(T
g)以下に冷却される。
Specifically, it can be carried out by the apparatus shown in FIG. 1 which is an embodiment of the apparatus of the present invention. The manufacturing apparatus according to the present invention includes a guide roll 7a in parallel with the heating roll 6. The metal strip 1 with resin is the unwinder 12
It is unwound from a, passes through the guide roll 7a, and then is supplied to the heating roll 6. At this time, the metal strip 1 with resin is preheated by the guide roll 7a before being supplied to the heating roll 5. The laminated metal strip with resin 1 is pressed and heated on the outer circumference of the heating roll, and after being separated from the position where the pressing and heating are finished, the glass roll temperature (T
g) Cooled below.

【0033】なお、図1に破線で示した別のガイドロー
ル7aを追加して加熱ロール上での加熱を調整すること
もでき、かつ、圧着ロールとして機能させても良い。ま
た第二の金属帯3は、巻出し機12bより巻出され、加
熱ロール6に供給されるが、ガイドロール7bを必要に
応じて配設しても良い。
The guide roll 7a shown by a broken line in FIG. 1 may be added to adjust the heating on the heating roll, and it may function as a pressure roll. Further, the second metal strip 3 is unwound from the unwinder 12b and supplied to the heating roll 6, but the guide roll 7b may be arranged if necessary.

【0034】前述の製造方法に加え、接合を真空槽内で
行うことが欠陥の低減に非常に有効である。偶発的な大
気の巻き込みによる欠陥を防止でき、加えて圧着ロール
8で気泡を押し潰すことも可能となる。真空槽の適用
は、加熱による樹脂付き金属帯および第二の金属帯の大
気酸化を低減させる効果もある。また、密閉した空間で
接着することにより、ちり、ほこり等の異物を巻き込む
危険性も大幅に低減する。圧接、加熱を行う真空層内の
真空度としては、102Pa以上105Pa以下が好ましい。102P
a以上としたのは、それ未満に減圧すると、加熱により
樹脂中の残存揮発成分の発泡、加熱分解の進行が懸念さ
れるからである。より好ましくは、103Pa以上104Pa以下
である。
In addition to the above-mentioned manufacturing method, it is very effective to reduce the defects by performing the bonding in a vacuum chamber. It is possible to prevent defects due to accidental entrainment of the atmosphere, and in addition, it is possible to crush the bubbles with the pressure bonding roll 8. The application of the vacuum chamber also has the effect of reducing atmospheric oxidation of the resin-coated metal strip and the second metal strip due to heating. In addition, by bonding in a closed space, the risk of entraining foreign matter such as dust and dust is greatly reduced. The degree of vacuum in the vacuum layer for pressure contact and heating is preferably 10 2 Pa or more and 10 5 Pa or less. 10 2 P
The reason why it is set to a or more is that if the pressure is reduced to less than that, there is concern that foaming of residual volatile components in the resin and progress of thermal decomposition may occur due to heating. More preferably, it is 10 3 Pa or more and 10 4 Pa or less.

【0035】上記本発明は具体的には、例えば本発明の
装置の一実施例である図2に記載の装置により実施する
ことが出来る。前述の加熱ロール6とガイドロール7
a,7bおよび圧着ロール8は、真空槽10内に配置さ
れる。巻出し機12a,12bおよび巻取り機13は真
空槽10の内部、外部のどちらに配しても良いが、内部
に配設した場合には材料のセット、取り出し時に真空槽
10を開放する必要が生じ、作業性が劣るため、巻出し
機および巻取り機は真空槽外へ設置することが好まし
い。この場合、常時排気が行われるサブチャンバ11
a,11bを設け、サブチャンバを介して帯材の搬送を
行うことにより、常時真空槽10の減圧雰囲気を保つこ
とができる。
The above-described present invention can be specifically implemented by, for example, the apparatus shown in FIG. 2 which is an embodiment of the apparatus of the present invention. The above-mentioned heating roll 6 and guide roll 7
The a and 7 b and the pressure bonding roll 8 are arranged in the vacuum chamber 10. The unwinders 12a and 12b and the winder 13 may be arranged inside or outside the vacuum tank 10. However, when they are arranged inside, it is necessary to open the vacuum tank 10 when setting and taking out materials. Therefore, it is preferable that the unwinder and the winder are installed outside the vacuum chamber because the workability is deteriorated. In this case, the sub-chamber 11 is constantly evacuated.
By providing a and 11b and carrying the strip material through the sub-chamber, the depressurized atmosphere of the vacuum chamber 10 can be always maintained.

【0036】以上に述べた製造方法、及び製造装置では
予め接合された樹脂付き金属帯1を用いたが、樹脂層を
樹脂帯として別途製造し、第一の金属帯2、樹脂層(樹
脂帯)4をそれぞれ別々の巻出し機から供給して、更に
別のリールから供給される第二の金属帯3とを合体し
て、一貫連続ラインで樹脂付き積層金属帯5を製造する
こともできる。
In the manufacturing method and the manufacturing apparatus described above, the resin-bonded metal strip 1 which has been bonded in advance is used. However, the resin layer is separately manufactured as the resin strip, and the first metal strip 2 and the resin layer (resin strip) are manufactured. It is also possible to manufacture the laminated metal strip 5 with resin in an integrated continuous line by supplying 4) from different unwinders and combining with the second metal strip 3 supplied from another reel. .

【0037】上記方法は、例えば図4に示す装置により
実施することが出来る。図4において、巻出し機12a
から巻出された第一の金属帯2と巻出し機12bから巻
出された第二の金属帯3と巻出し機12cから巻出され
た樹脂帯4は、回転する加熱ロール6の外周面上の圧接
および加熱開始位置14で樹脂層を介して積層される。
その後は既述の本発明の方法、及び装置と同様であり、
好ましい形態も同様である。
The above method can be carried out by the apparatus shown in FIG. 4, for example. In FIG. 4, the unwinding machine 12a
The first metal band 2 unwound from the second metal band 3, the second metal band 3 unwound from the unwinder 12b, and the resin band 4 unwound from the unwinder 12c are the outer peripheral surface of the rotating heating roll 6. At the upper pressure contact and heating start position 14, the resin layers are laminated.
After that, it is the same as the method and apparatus of the present invention described above,
The preferred form is also the same.

【0038】本発明の実施形態の例を示す図1、図2、
図4では金属帯及び樹脂付き金属帯等を加熱曲面(加熱
ロール)外周面上で重ね合わせているが、何れの製造方
法、製造装置においても、必ずしも加熱曲面の外周面上
で重ね合せる必要は無く、金属帯、樹脂付き金属帯等を
加熱曲面に達する前に重ね合わせた後、加熱曲面上で加
熱、圧接しても良い。
FIGS. 1 and 2 showing an example of an embodiment of the present invention.
In FIG. 4, the metal strip and the metal strip with resin are superposed on the outer peripheral surface of the heating curved surface (heating roll), but it is not always necessary to superimpose them on the outer peripheral surface of the heating curved surface in any manufacturing method and manufacturing apparatus. Alternatively, a metal band, a metal band with resin, etc. may be superposed before reaching the heating curved surface, and then heated and pressed on the heating curved surface.

【0039】[0039]

【実施例】表1に示す樹脂付き金属帯、および第二の金
属帯を図1に示す本発明の装置(加熱ロールφ250m
m)を用いて表2に示す条件で接合し、長さ5m、幅60mm
の樹脂付き積層金属帯を製造した。接合後の樹脂付き積
層金属帯から、長さ方向に1mの間隔で10×100mmの試料
を合計5ピース切りだし、JISC5016に定める180度方向
引き剥がしの方法により接着強度の測定を行った。比較
として図5、図6の装置を用いて表2に示す条件により
樹脂付き積層金属帯を製造し、同様に接着強度の測定、
外観観察を行った。接着強度の平均値と外観観察の結果
を表2に併せて示す。
EXAMPLES The resin-coated metal strip shown in Table 1 and the second metal strip shown in FIG.
m) under the conditions shown in Table 2, length 5m, width 60mm
A laminated metal strip with resin was manufactured. A total of 5 pieces of 10 × 100 mm samples were cut out from the laminated metal band with resin after joining at an interval of 1 m in the lengthwise direction, and the adhesive strength was measured by the 180 ° direction peeling method defined in JIS C5016. For comparison, resin-laminated metal strips were manufactured under the conditions shown in Table 2 using the apparatus shown in FIGS. 5 and 6, and the adhesive strength was measured in the same manner.
The appearance was observed. Table 2 also shows the average value of the adhesive strength and the result of the appearance observation.

【0040】本発明例1、2及び比較例1では仮接着に
充分な接着強度が得られたが、図6の装置を用いた比較
例2では0.1kN/m以下となった。比較例2では他と比べ1
/5以下の強度となり、仮接着に必要な接着強度が得られ
なかった。接着後の外観は、予熱を行わない本発明例1
では、部分的に僅かにすじ状の模様の発生が観察された
ものの、接合面での気泡は観察されなかった。ガイドロ
ールによる予熱を適用した本発明例2では、すじ状の模
様の発生などは観察されず、全面において接合面が密着
し、表面の平滑な樹脂付き積層金属帯を形成していた。
これに対し比較例1、2ではそれぞれプレス痕、気泡を
含むしわ状のふくれの発生が観察された。
In Examples 1 and 2 of the present invention and Comparative Example 1, sufficient adhesive strength for temporary adhesion was obtained, but in Comparative Example 2 using the apparatus of FIG. 6, it was 0.1 kN / m or less. In Comparative Example 2, 1 compared to others
The strength was / 5 or less, and the adhesive strength required for temporary adhesion could not be obtained. The appearance after adhesion is the same as Example 1 of the present invention in which preheating is not performed
On the other hand, although a slight streak-like pattern was partially observed, no bubbles were observed at the joint surface. In Example 2 of the present invention in which the preheating by the guide roll was applied, no generation of streak-like patterns was observed, and the bonding surface was in close contact with the entire surface to form the resin-laminated metal strip having a smooth surface.
On the other hand, in Comparative Examples 1 and 2, the generation of press marks and wrinkle-like blisters containing bubbles were observed.

【0041】[0041]

【表1】 [Table 1]

【0042】[0042]

【表2】 [Table 2]

【0043】[0043]

【発明の効果】本発明によれば、熱硬化性樹脂の接着強
度を確保し、接着信頼性を向上させた樹脂付き積層金属
帯を効率的に製造可能となりその工業的価値は大きい。
Industrial Applicability According to the present invention, it is possible to efficiently manufacture a resin-coated laminated metal strip in which the adhesive strength of a thermosetting resin is secured and the adhesive reliability is improved, which is of great industrial value.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一例を示す構成図である。FIG. 1 is a configuration diagram showing an example of the present invention.

【図2】本発明の一例を示す構成図である。FIG. 2 is a configuration diagram showing an example of the present invention.

【図3】本発明に係る樹脂付き積層金属帯の断面図であ
る。
FIG. 3 is a cross-sectional view of a laminated metal band with resin according to the present invention.

【図4】本発明の一例を示す構成図である。FIG. 4 is a configuration diagram showing an example of the present invention.

【図5】従来の装置の一例を示す構成図である。FIG. 5 is a configuration diagram showing an example of a conventional device.

【図6】従来の装置の一例を示す構成図である。FIG. 6 is a configuration diagram showing an example of a conventional device.

【符号の説明】[Explanation of symbols]

1 樹脂付き金属帯、2 第一の金属帯(第一の金属
層)、3 第二の金属帯、4 樹脂層(樹脂帯)、5
樹脂付き積層金属帯、6 加熱ロール、7a,7b ガ
イドロール、8 圧着ロール、9 冷却ロール、10
真空槽、11a,11b サブチャンバ、12a,12
b,12c 巻出し機、13 巻取り機、14 圧接お
よび加熱開始位置、15 圧接および加熱終了位置、1
6 加熱プレス、17 境界部
1 metal band with resin, 2 first metal band (first metal layer), 3 second metal band, 4 resin layer (resin band), 5
Laminated metal strip with resin, 6 heating rolls, 7a, 7b guide rolls, 8 pressure bonding rolls, 9 cooling rolls, 10
Vacuum chamber, 11a, 11b sub chambers, 12a, 12
b, 12c unwinder, 13 winder, 14 pressure contact and heating start position, 15 pressure contact and heating end position, 1
6 heating presses, 17 boundaries

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 第一の金属層と熱硬化性の樹脂層との二
層を有する樹脂付き金属帯の樹脂層側表面に、第二の金
属帯を接合する樹脂付き積層金属帯の製造方法におい
て、前記樹脂付き金属帯と第二の金属帯とを重ね合わせ
て加熱曲面の外周面に沿わせ、該加熱曲面の外周面上で
前記樹脂付き金属帯と第二の金属帯とを連続的に加熱し
ながら圧接することを特徴とする樹脂付き積層金属帯の
製造方法。
1. A method for producing a laminated metal band with resin, in which a second metal band is bonded to the resin layer side surface of a resin-coated metal band having two layers of a first metal layer and a thermosetting resin layer. In the above, the resin-coated metal strip and the second metal strip are superposed on each other along the outer peripheral surface of the heating curved surface, and the resin-coated metal strip and the second metal strip are continuously formed on the outer peripheral surface of the heating curved surface. A method for producing a laminated metal band with a resin, which comprises press-contacting while heating.
【請求項2】 樹脂付き金属帯を加熱曲面の外周面に沿
わせる直前に、該樹脂付き金属帯を予熱することを特徴
とする請求項1に記載の樹脂付き積層金属帯の製造方
法。
2. The method for producing a laminated metal band with resin according to claim 1, wherein the metal band with resin is preheated immediately before the metal band with resin is placed along the outer peripheral surface of the heating curved surface.
【請求項3】 樹脂付き金属帯を加熱曲面の外周面に沿
わせる直前に、加熱曲面と並列して設けられたガイドロ
ールを通過させることを特徴とする請求項2に記載の樹
脂付き積層金属帯の製造方法。
3. The laminated metal with resin according to claim 2, wherein a guide roll provided in parallel with the heating curved surface is passed through immediately before the metal strip with resin is laid along the outer peripheral surface of the heating curved surface. Method of manufacturing obi.
【請求項4】 樹脂付き金属帯を前記ガイドロールによ
り予熱することを特徴とする請求項3に記載の樹脂付き
積層金属帯の製造方法。
4. The method for producing a laminated metal band with resin according to claim 3, wherein the metal band with resin is preheated by the guide roll.
【請求項5】 第一の金属帯と第二の金属帯とを熱硬化
性の樹脂帯を介して接合する樹脂付き積層金属帯の製造
方法において、第一の金属帯と樹脂帯と第二の金属帯と
を重ね合わせて加熱曲面の外周面に沿わせ、該加熱曲面
の外周面上で前記第一の金属帯と樹脂帯と第二の金属帯
とを連続的に加熱しながら圧接することを特徴とする樹
脂付き積層金属帯の製造方法。
5. A method for producing a laminated metal band with resin, which comprises bonding a first metal band and a second metal band via a thermosetting resin band, wherein the first metal band, the resin band, and the second metal band And the metal strips of the above are overlapped with each other along the outer peripheral surface of the heating curved surface, and the first metal strip, the resin strip, and the second metal strip are pressed while being continuously heated on the outer peripheral surface of the heating curved surface. A method for producing a laminated metal strip with a resin, comprising:
【請求項6】 前記接合を真空槽内で行うことを特徴と
する請求項1乃至5の何れかに記載の樹脂付き積層金属
帯の製造方法。
6. The method for producing a laminated metal strip with resin according to claim 1, wherein the joining is performed in a vacuum chamber.
【請求項7】 第一の金属層と熱硬化性の樹脂層との二
層からなる樹脂付き金属帯を巻出す巻出し手段と、第二
の金属帯を巻出す巻出し手段と、外周面を加熱可能な加
熱曲面とを具備し、前記樹脂付き金属帯と第二の金属帯
とが加熱曲面の外周面上に沿って重なり合った状態で移
動することを特徴とする樹脂付き積層金属帯の製造装
置。
7. An unwinding means for unwinding a resin-coated metal strip composed of two layers of a first metal layer and a thermosetting resin layer, an unwinding means for unwinding a second metal strip, and an outer peripheral surface. And a heating curved surface capable of heating, wherein the metal band with resin and the second metal band move in a state of overlapping along the outer peripheral surface of the heating curved surface of a laminated metal band with resin. Manufacturing equipment.
【請求項8】 加熱曲面と並列してガイドロールを具備
し、該ガイドロールは樹脂付き金属帯を加熱曲面へ供給
する前に予熱するための加熱装置を具備することを特徴
とする請求項7に記載の樹脂付き積層金属帯の製造装
置。
8. A guide roll is provided in parallel with the heating curved surface, and the guide roll is provided with a heating device for preheating the metal strip with resin before being supplied to the heating curved surface. An apparatus for producing a laminated metal strip with a resin according to 1.
【請求項9】 第一の金属帯を巻出す巻出し手段と、熱
硬化性の樹脂帯を巻出す巻出し手段と、第二の金属帯を
巻出す巻出し手段と、外周面を加熱可能な加熱曲面とを
具備し、前記第一の金属帯と熱硬化性の樹脂帯と第二の
金属帯とが加熱曲面の外周面上に沿って重なり合った状
態で移動することを特徴とする樹脂付き積層金属帯の製
造装置。
9. An unwinding means for unwinding a first metal band, an unwinding means for unwinding a thermosetting resin band, an unwinding means for unwinding a second metal band, and an outer peripheral surface of which can be heated. A heat-curing curved surface, wherein the first metal strip, the thermosetting resin strip, and the second metal strip move in a state of overlapping along the outer peripheral surface of the heating curved surface. Device for manufacturing laminated metal strips.
【請求項10】 少なくとも前記加熱曲面が真空槽内に
配置されていることを特徴とする請求項7ないし請求項
9の何れかに記載の樹脂付き積層金属帯の製造装置。
10. The apparatus for manufacturing a laminated metal strip with resin according to claim 7, wherein at least the heating curved surface is arranged in a vacuum chamber.
JP2001209190A 2001-07-10 2001-07-10 Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor Pending JP2003019750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001209190A JP2003019750A (en) 2001-07-10 2001-07-10 Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001209190A JP2003019750A (en) 2001-07-10 2001-07-10 Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor

Publications (1)

Publication Number Publication Date
JP2003019750A true JP2003019750A (en) 2003-01-21

Family

ID=19044880

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001209190A Pending JP2003019750A (en) 2001-07-10 2001-07-10 Method for manufacturing laminated metal strip with resin and manufacturing apparatus therefor

Country Status (1)

Country Link
JP (1) JP2003019750A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107415353A (en) * 2016-05-31 2017-12-01 Skc株式会社 The preparation method and antenna equipment of electroconductive magnetic composite sheet
CN107452461A (en) * 2016-05-31 2017-12-08 Skc株式会社 Magnetic piece and the antenna equipment including magnetic piece
JP2018039251A (en) * 2016-05-31 2018-03-15 エスケイシー・カンパニー・リミテッドSkc Co., Ltd. Conductive magnetic composite sheet and method for manufacturing antenna and device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107415353A (en) * 2016-05-31 2017-12-01 Skc株式会社 The preparation method and antenna equipment of electroconductive magnetic composite sheet
CN107452461A (en) * 2016-05-31 2017-12-08 Skc株式会社 Magnetic piece and the antenna equipment including magnetic piece
JP2018039251A (en) * 2016-05-31 2018-03-15 エスケイシー・カンパニー・リミテッドSkc Co., Ltd. Conductive magnetic composite sheet and method for manufacturing antenna and device
US10479050B2 (en) 2016-05-31 2019-11-19 Skc Co., Ltd. Method of preparing conductive magnetic composite sheet and antenna device

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