JP2002322038A - Aerosol hair dye composition - Google Patents
Aerosol hair dye compositionInfo
- Publication number
- JP2002322038A JP2002322038A JP2001124258A JP2001124258A JP2002322038A JP 2002322038 A JP2002322038 A JP 2002322038A JP 2001124258 A JP2001124258 A JP 2001124258A JP 2001124258 A JP2001124258 A JP 2001124258A JP 2002322038 A JP2002322038 A JP 2002322038A
- Authority
- JP
- Japan
- Prior art keywords
- hair dye
- hair
- dye composition
- propellant
- aerosol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、空気中の酸素を利
用した、繰り返し使用しても染色力が維持される一剤式
エアゾール染毛剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a one-part type aerosol hair dye composition utilizing oxygen in the air and maintaining the dyeing power even when used repeatedly.
【０００２】[0002]
【従来の技術】５位及び６位に水酸基が置換したインド
リン誘導体及びインドール誘導体は、空気中の酸素によ
りメラニン色素に変換することが知られており、これら
の化合物を利用したクリーム状の空気酸化型染毛剤が市
販されている。しかし、このものは、一度包装を開封す
ると、上記インドリン誘導体又はインドール誘導体が空
気中の酸素と接触して酸化重合し、毛髪に染着できない
ものとなるため、日を置いて再度使用する場合、染色力
が低下してしまうという問題があった。2. Description of the Related Art It is known that indoline derivatives and indole derivatives in which hydroxyl groups are substituted at the 5- and 6-positions are converted to melanin pigment by oxygen in the air, and cream-like air oxidation using these compounds is known. Type hair dyes are commercially available. However, once the package is opened, the indoline derivative or indole derivative comes into contact with oxygen in the air and undergoes oxidative polymerization and cannot be dyed on hair. There was a problem that the dyeing power was reduced.
【０００３】[0003]
【発明が解決しようとする課題】従って本発明は、繰り
返し使用しても染色力が維持される空気酸化型染毛剤を
提供することを目的とする。SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide an air oxidation type hair dye which maintains its dyeing power even when used repeatedly.
【０００４】[0004]
【課題を解決するための手段】本発明者らは、酸化防止
剤を配合し、かつエアゾール形態とすることにより、繰
り返し使用した場合にも染色力が維持されるだけでな
く、他の形態、例えばクリーム、ゲル、ローション等と
した場合に比べ染色力が向上することを見出した。Means for Solving the Problems By blending an antioxidant and forming an aerosol form, the present inventors can maintain not only the dyeing power even when repeatedly used, but also other forms, For example, it has been found that the dyeing power is improved as compared with the case where cream, gel, lotion and the like are used.
【０００５】すなわち本発明は、成分(a)、(b)及び(c) (a) 次の一般式(1)That is, the present invention relates to the components (a), (b) and (c) (a)
【０００６】[0006]
【化２】 Embedded image
【０００７】〔式中、 Ｒ1、Ｒ4及びＲ5はそれぞれ水素
原子、炭素数１〜４のアルキル基又は炭素数２〜20のア
シル基を示し、Ｒ2及びＲ3はそれぞれ水素原子又は炭素
数１〜４のアルキル基を示す。〕で表されるインドリン
誘導体又はその塩 (b) アルカリ剤 (c) 酸化防止剤を含有しpHが８〜12である組成物、並び
に (d) 噴射剤からなる一剤式エアゾール染毛剤組成物を提
供するものである。Wherein R 1 , R 4 and R 5 each represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or an acyl group having 2 to 20 carbon atoms, and R 2 and R 3 each represent a hydrogen atom or It represents an alkyl group having 1 to 4 carbon atoms. (B) an alkaline agent; (c) a composition containing an antioxidant and having a pH of 8 to 12, and (d) a one-part aerosol hair dye composition comprising a propellant. To provide things.
【０００８】[0008]
【発明の実施の形態】成分(a)のインドリン誘導体(1)と
しては、5,6-ジヒドロキシインドリン、N-メチル-5,6-
ジヒドロキシインドリン、N-エチル-5,6-ジヒドロキシ
インドリン、N-ブチル-5,6-ジヒドロキシインドリン、5
-メトキシ-6-ヒドロキシインドリン、2-メチル-5,6-ジ
ヒドロキシインドリン、3-メチル-5,6-ジヒドロキシイ
ンドリン、5-ヒドロキシ-6-メトキシインドリン等が挙
げられ、なかでも5,6-ジヒドロキシインドリンが好まし
い。またこれらインドリン誘導体の塩としては、塩酸
塩、臭化水素酸塩、硫酸塩、リン酸塩、酢酸塩、プロピ
オン酸塩、乳酸塩、クエン酸塩等が挙げられ、なかでも
臭化水素酸塩が好ましい。すなわち、インドリン誘導体
(1)又はその塩の最も好ましいものとして、5,6-ジヒド
ロキシインドリンの臭化水素酸塩が挙げられる。なお、
5,6-ジヒドロキシインドリンは、5,6-ジアシルオキシイ
ンドリンの形で染毛剤組成物に配合し、塩基性条件下、
加水分解することにより生じさせてもよい。BEST MODE FOR CARRYING OUT THE INVENTION As the indoline derivative (1) of the component (a), 5,6-dihydroxyindoline, N-methyl-5,6-
Dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-butyl-5,6-dihydroxyindoline, 5
-Methoxy-6-hydroxyindoline, 2-methyl-5,6-dihydroxyindoline, 3-methyl-5,6-dihydroxyindoline, 5-hydroxy-6-methoxyindoline and the like, among which 5,6-dihydroxy Indoline is preferred. Examples of the salts of these indoline derivatives include hydrochlorides, hydrobromides, sulfates, phosphates, acetates, propionates, lactates, and citrates. Is preferred. That is, indoline derivatives
The most preferred (1) or a salt thereof is 5,6-dihydroxyindoline hydrobromide. In addition,
5,6-dihydroxyindoline is added to the hair dye composition in the form of 5,6-diacyloxyindoline, and under basic conditions,
It may be generated by hydrolysis.
【０００９】インドリン誘導体(1)又はその塩は、１種
以上を使用することができ、その含有量は、東洋人の白
髪を隠蔽するのに好適な赤みのない黒色に染色する点か
ら、噴射剤を除く全組成の0.01〜10重量％、特に0.1〜
５重量％が好ましい。The indoline derivative (1) or a salt thereof may be used in one or more kinds. The content of the indoline derivative (1) is high because it is suitable for concealing the gray hair of Oriental people by dyeing a reddish black. 0.01-10% by weight of the total composition excluding the agent, especially 0.1-
5% by weight is preferred.
【００１０】成分(b)のアルカリ剤としては、通常の染
毛剤に使用されるものを用いることができる。例えば、
アンモニア水；モノ−、ジ−及びトリエタノールアミン
及びそれらの誘導体等のアルカノールアミン類；ブチル
アミン、ベンジルアミン等のアルキル又はアラルキルア
ミン類；水酸化ナトリウム、水酸化カリウム、炭酸ナト
リウム、炭酸カリウム等の無機塩基類等が挙げられ、な
かでも染色力の点からモノエタノールアミン、イソプロ
パノールアミンが好ましい。As the alkaline agent of the component (b), those used in ordinary hair dyes can be used. For example,
Aqueous ammonia; alkanolamines such as mono-, di- and triethanolamine and their derivatives; alkyl or aralkylamines such as butylamine and benzylamine; inorganics such as sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate Bases and the like can be mentioned, and among them, monoethanolamine and isopropanolamine are preferable from the viewpoint of dyeing power.
【００１１】アルカリ剤は、１種以上を使用することが
でき、その含有量は、東洋人の白髪を隠蔽するのに好適
な赤みのない黒色に染色する点から、噴射剤を除く全組
成の0.01〜20重量％、特に0.1〜10重量％が好ましい。One or more alkaline agents can be used. The content of the alkaline agent is not limited to that of the propellant except that the alkaline agent is dyed black without redness, which is suitable for hiding the gray hair of Orientals. 0.01-20% by weight, especially 0.1-10% by weight is preferred.
【００１２】成分(c)の酸化防止剤としては、通常の染
毛剤に使用されるものを用いることができる。例えば、
亜硫酸ナトリウム、アスコルビン酸、チオグリコール酸
及びその塩、L-システイン及びその塩、N-アセチル-L-
システイン及びその塩が好ましいものとして挙げられ、
特に亜硫酸ナトリウムは、染料前駆物質の安定化に寄与
するだけでなく、染色力をも向上させるため、好まし
い。As the antioxidant of the component (c), those used in ordinary hair dyes can be used. For example,
Sodium sulfite, ascorbic acid, thioglycolic acid and its salts, L-cysteine and its salts, N-acetyl-L-
Cysteine and salts thereof are mentioned as preferred,
Particularly, sodium sulfite is preferable because it not only contributes to stabilization of the dye precursor but also improves dyeing power.
【００１３】酸化防止剤は、１種以上を使用することが
でき、その含有量は、東洋人の白髪を隠蔽するのに好適
な赤みのない黒色に染色する点から、噴射剤を除く全組
成の0.01〜２重量％、特に0.05〜１重量％が好ましい。One or more antioxidants can be used. The content of the antioxidant depends on the total composition except for the propellant, since the antioxidant is dyed black without redness, which is suitable for hiding the gray hair of Oriental people. Is preferably 0.01 to 2% by weight, particularly preferably 0.05 to 1% by weight.
【００１４】インドリン誘導体(1)又はその塩は、塩基
性条件で空気中の酸素と反応しメラニン色素に変換され
る。このため、成分(d)の噴射剤を除いた組成物のpH
は、８〜12の範囲、好ましくは９〜10.5の範囲に調整す
る。The indoline derivative (1) or a salt thereof reacts with oxygen in the air under basic conditions and is converted into a melanin pigment. For this reason, the pH of the composition excluding the propellant component (d)
Is adjusted in the range of 8 to 12, preferably in the range of 9 to 10.5.
【００１５】本発明の染毛剤組成物は、繰り返し使用し
ても染色力を維持し、また染色力を向上するため、エア
ゾールの形態とされる。本発明の染毛剤組成物をエアゾ
ール型とするには、噴射剤を除く組成物と共に、噴射剤
を、耐圧容器（エアゾール缶等）に充填すればよい。The hair dye composition of the present invention is in the form of an aerosol in order to maintain the dyeing power even when repeatedly used and to improve the dyeing power. In order to make the hair dye composition of the present invention an aerosol type, the propellant may be filled in a pressure-resistant container (such as an aerosol can) together with the composition excluding the propellant.
【００１６】成分(d)の噴射剤としては、一般にエアゾ
ール製品に用いられる圧縮ガス、液化ガス等が使用で
き、圧縮ガスとしては、窒素ガス、炭酸ガス、アルゴン
ガス等が、液化ガスとしては、液化石油ガス、低級飽和
炭化水素類、ジメチルエーテル等が挙げられる。これら
の噴射剤は、１種以上を使用でき、適度な噴射速度を得
るために、全組成中に１〜20重量％、特に３〜15重量％
含有させるのが好ましい。また充填後のエアゾール缶の
内圧が３〜５kg/cm2G（25℃）となるように調整するの
が好ましい。As the propellant of the component (d), a compressed gas, a liquefied gas or the like generally used for aerosol products can be used. As the compressed gas, a nitrogen gas, a carbon dioxide gas, an argon gas or the like can be used. Liquefied petroleum gas, lower saturated hydrocarbons, dimethyl ether and the like. One or more of these propellants can be used, and in order to obtain an appropriate injection speed, 1 to 20% by weight, particularly 3 to 15% by weight in the total composition.
It is preferable to include them. It is also preferable to adjust the internal pressure of the filled aerosol can to be 3 to 5 kg / cm 2 G (25 ° C.).
【００１７】製品充填時には、クリンプと同時に脱気を
行い、容器内部に残存する空気を減少させることが好ま
しく、このような脱気操作は内容物の安定化の点でより
効果的である。例えば、48kPa以下の圧力で脱気操作を
行うことが好ましい。When filling the product, it is preferable to perform degassing at the same time as crimping to reduce air remaining in the container. Such degassing operation is more effective in stabilizing the contents. For example, it is preferable to perform the deaeration operation at a pressure of 48 kPa or less.
【００１８】本発明の染毛剤組成物は、増粘しない場合
には軽い使用感が得られるが、増粘剤を添加して増粘さ
せることにより、染色力を損なうことなく、また液だれ
の心配なく使用することができる。粘度としては、噴出
剤を除く組成物の粘度として、500〜50000mm2/sが好ま
しい。増粘剤としては、ヒドロキシエチルセルロース、
ヒドロキシエチルセルロースとグリシジルトリメチルア
ンモニウムクロリドとのエーテル、メチルセルロース、
カルボキシメチルセルロース等のセルロース誘導体；キ
タンタンガム、グアーガム等の天然ガム類；ポリビニル
ピロリドン、架橋型ポリアクリル酸又はその塩、ポリア
クリル酸又はその塩、ポリアクリルアミド等の合成高分
子が挙げられる。The hair dye composition of the present invention can provide a light feeling of use when the viscosity is not increased. However, by adding a thickener to increase the viscosity, the dyeing power is not impaired, and the hair is dripped. Can be used without worry. The viscosity of the composition excluding the propellant is preferably 500 to 50,000 mm 2 / s. As a thickener, hydroxyethyl cellulose,
Ether of hydroxyethylcellulose and glycidyltrimethylammonium chloride, methylcellulose,
Cellulose derivatives such as carboxymethylcellulose; natural gums such as chitantan gum and guar gum; and synthetic polymers such as polyvinylpyrrolidone, cross-linked polyacrylic acid or a salt thereof, polyacrylic acid or a salt thereof, and polyacrylamide.
【００１９】また、本発明の染毛剤組成物には、起泡剤
及び／又は均一化剤として、非イオン界面活性剤を含有
させることができる。非イオン界面活性剤としては、ポ
リオキシエチレンオレイルエーテル、ポリオキシエチレ
ンステアリルエーテル等のポリオキシエチレンアルキル
エーテル；ポリオキシエチレンノニルフェニルエーテ
ル、ポリオキシエチレンオクチルフェニルエーテル等の
ポリオキシエチレンアルキルフェニルエーテル；ポリオ
キシエチレンソルビタン脂肪酸エステル、脂肪酸アルキ
ロールアミド、ポリオキシエチレン-sec-テトラデシル
エーテル等が挙げられる。非イオン界面活性剤の含有量
は、噴射剤を除く全組成の0.01〜30重量％、特に0.1〜1
0重量％が好ましい。Further, the hair dye composition of the present invention may contain a nonionic surfactant as a foaming agent and / or a homogenizing agent. Examples of the nonionic surfactant include polyoxyethylene alkyl ethers such as polyoxyethylene oleyl ether and polyoxyethylene stearyl ether; polyoxyethylene alkyl phenyl ethers such as polyoxyethylene nonyl phenyl ether and polyoxyethylene octyl phenyl ether; Oxyethylene sorbitan fatty acid esters, fatty acid alkylolamides, polyoxyethylene-sec-tetradecyl ether and the like can be mentioned. The content of the nonionic surfactant is 0.01 to 30% by weight of the total composition excluding the propellant, particularly 0.1 to 1%.
0% by weight is preferred.
【００２０】本発明の染毛剤組成物には、上記成分以外
に、通常の染毛剤に用いられる成分、例えば上記以外の
界面活性剤、安定化剤、緩衝剤、香料、感触向上剤、キ
レート剤、可溶化剤、防腐剤等を、目的に応じ、適宜配
合することができる。The hair dye composition of the present invention contains, in addition to the above-mentioned components, components used in ordinary hair dyes, for example, surfactants, stabilizers, buffers, fragrances, feel improvers other than those described above, A chelating agent, a solubilizing agent, a preservative, and the like can be appropriately added according to the purpose.
【００２１】本発明の染毛剤組成物は、室温で使用する
こともできるが、ドライヤーにより熱と酸素を供給する
ことにより、染色力を向上させることもできる。The hair dye composition of the present invention can be used at room temperature, but the dyeing power can be improved by supplying heat and oxygen with a dryer.
【００２２】[0022]
【実施例】以下の実施例及び比較例において、染色した
トレスを分光測色計（ミノルタ社製CM-2002）により測
色し、下式に従って算出した色差（ΔＥ）により評価し
た。EXAMPLES In the following Examples and Comparative Examples, the color of the dyed tress was measured with a spectrophotometer (CM-2002, manufactured by Minolta Co.), and the color difference (ΔE) calculated according to the following equation was evaluated.
【００２３】ΔＥ＝｛(Ｌ1−Ｌ0)2＋(ａ1−ａ0)2＋(ｂ1
−ｂ0)2｝1/2 （Ｌ0,ａ0,ｂ0）：染色前のヤギ毛トレスの測色値 （Ｌ1,ａ1,ｂ1）：染色後のヤギ毛トレスの測色値ΔE = ｛(L 1 −L 0 ) 2 + (a 1 −a 0 ) 2 + (b 1
−b 0 ) 2 ｝ 1/2 (L 0 , a 0 , b 0 ): Colorimetric value of goat hair tress before dyeing (L 1 , a 1 , b 1 ): Colorimetric measurement of goat hair tress after dyeing value
【００２４】実施例１，２及び比較例１，２ −剤型の
違いによる染色力の比較− 実施例１及び２の組成物（粘度18000mm2/s）を原液と
し、それぞれを噴射剤（LPG）と共にエアゾール容器に
充填した（原液：噴射剤＝90：10，重量比）。実施例１
及び２のエアゾール染毛剤と比較例１及び２のクリーム
状染毛剤をそれぞれ１ｇ（エアゾール染毛剤は原液換
算）白髪トレス１ｇに適用し、30℃、15分間染色した。
その後、水洗、シャンプー、ヘアリンス、次いで乾燥し
た。７日おきにこの操作を計５回繰り返した。染色前後
の色差（ΔＥ）を表１に示す。Examples 1 and 2 and Comparative Examples 1 and 2 -Comparison of dyeing power depending on the type of the preparation- The compositions (viscosity of 18000 mm 2 / s) of Examples 1 and 2 were used as stock solutions, each of which was a propellant (LPG). ) Together with an aerosol container (stock solution: propellant = 90: 10, weight ratio). Example 1
Each of the aerosol hair dyes of Comparative Examples 1 and 2 and the cream hair dyes of Comparative Examples 1 and 2 were applied to 1 g of a gray hair tress (aerosol hair dye was converted to a stock solution), and dyed at 30 ° C. for 15 minutes.
Then, it was washed with water, shampooed, hair rinsed and then dried. This operation was repeated 5 times every 7 days. Table 1 shows the color difference (ΔE) before and after dyeing.
【００２５】[0025]
【表１】 [Table 1]
【００２６】実施例３ −ドライヤーにより熱と酸素を
供給する染毛方法− 実施例１のエアゾール染毛剤１ｇ（原液換算）を白髪ト
レス１ｇに適用し、ドライヤーにて温風を15分間適用し
た。その後、水洗、シャンプー、ヘアリンス、次いで乾
燥した。７日おきにこの操作を計５回繰り返した。染色
前後の色差（ΔＥ）は48であった。Example 3-Hair Dyeing Method of Supplying Heat and Oxygen with Dryer-1 g of the aerosol hair dye of Example 1 (converted to a stock solution) was applied to 1 g of gray hair tress, and hot air was applied by a dryer for 15 minutes. . Then, it was washed with water, shampooed, hair rinsed and then dried. This operation was repeated 5 times every 7 days. The color difference (ΔE) before and after dyeing was 48.
【００２７】[0027]
【発明の効果】本発明の一剤式エアゾール染毛剤は、繰
り返し使用しても優れた染色力が維持される。The one-part aerosol hair dye of the present invention maintains excellent dyeing power even when used repeatedly.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4C083 AB352 AC542 AC851 AC852 AD352 AD642 BB43 BB47 BB49 CC36 DD08 EE26 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4C083 AB352 AC542 AC851 AC852 AD352 AD642 BB43 BB47 BB49 CC36 DD08 EE26
Claims (2)
１〜４のアルキル基又は炭素数２〜20のアシル基を示
し、Ｒ2及びＲ3はそれぞれ水素原子又は炭素数１〜４の
アルキル基を示す。〕で表されるインドリン誘導体又は
その塩 (b) アルカリ剤 (c) 酸化防止剤を含有しpHが８〜12である組成物、並び
に (d) 噴射剤からなる一剤式エアゾール染毛剤組成物。1. Components (a), (b) and (c) (a) The following general formula (1): [Wherein, R 1 , R 4 and R 5 each represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or an acyl group having 2 to 20 carbon atoms, and R 2 and R 3 each represent a hydrogen atom or 1 carbon atom. And represents alkyl groups 4 to 4. (B) an alkaline agent; (c) a composition containing an antioxidant and having a pH of 8 to 12, and (d) a one-part aerosol hair dye composition comprising a propellant. object.
用した後、ドライヤーにより熱と酸素を供給する染毛方
法。2. A hair dyeing method comprising applying heat and oxygen with a dryer after applying the hair dye composition according to claim 1 to hair.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001124258A JP4886117B2 (en) | 2001-04-23 | 2001-04-23 | Aerosol hair dye composition |
| EP20020008285 EP1254650B1 (en) | 2001-04-23 | 2002-04-22 | Hair dye composition |
| DE2002621179 DE60221179T2 (en) | 2001-04-23 | 2002-04-22 | Hair Dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001124258A JP4886117B2 (en) | 2001-04-23 | 2001-04-23 | Aerosol hair dye composition |
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| JP4886117B2 JP4886117B2 (en) | 2012-02-29 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007141918A1 (en) | 2006-06-07 | 2007-12-13 | Kao Corporation | One-pack hair dye composition |
| WO2007141919A1 (en) | 2006-06-07 | 2007-12-13 | Kao Corporation | One-pack hair dye composition |
| JP2007326802A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Aerosol type one-pack type hair dye composition |
| JP2007326813A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Hair cosmetic |
| JP2007326803A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | One-pack type hair dye composition |
| JP2007326811A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | One-pack type hair dye composition |
| JP2007326805A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Hair cosmetic |
| US7857863B2 (en) | 2006-06-07 | 2010-12-28 | Kao Corporation | One-part hair dye composition |
| JP2013534533A (en) * | 2010-07-15 | 2013-09-05 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Foam colorant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04227974A (en) * | 1990-05-31 | 1992-08-18 | L'oreal Sa | Dyeing composition containing 5,6- dihydroxyindoline as base and dyeing method of keratin fiber |
| JP2001064133A (en) * | 1999-06-22 | 2001-03-13 | Lion Corp | Hair dye composition |
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- 2001-04-23 JP JP2001124258A patent/JP4886117B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04227974A (en) * | 1990-05-31 | 1992-08-18 | L'oreal Sa | Dyeing composition containing 5,6- dihydroxyindoline as base and dyeing method of keratin fiber |
| JP2001064133A (en) * | 1999-06-22 | 2001-03-13 | Lion Corp | Hair dye composition |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007326805A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Hair cosmetic |
| WO2007141918A1 (en) | 2006-06-07 | 2007-12-13 | Kao Corporation | One-pack hair dye composition |
| JP2007326802A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Aerosol type one-pack type hair dye composition |
| JP2007326813A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | Hair cosmetic |
| JP2007326803A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | One-pack type hair dye composition |
| JP2007326811A (en) * | 2006-06-07 | 2007-12-20 | Kao Corp | One-pack type hair dye composition |
| WO2007141919A1 (en) | 2006-06-07 | 2007-12-13 | Kao Corporation | One-pack hair dye composition |
| US7857862B2 (en) | 2006-06-07 | 2010-12-28 | Kao Corporation | One-part hair dye composition |
| KR101441698B1 (en) | 2006-06-07 | 2014-09-17 | 카오카부시키가이샤 | One-pack hair dye composition |
| US7862625B2 (en) | 2006-06-07 | 2011-01-04 | Kao Corporation | One-part hair dye composition |
| US7857863B2 (en) | 2006-06-07 | 2010-12-28 | Kao Corporation | One-part hair dye composition |
| KR101441697B1 (en) | 2006-06-07 | 2014-09-17 | 카오카부시키가이샤 | One-pack hair dye composition |
| KR101441699B1 (en) | 2006-06-07 | 2014-09-17 | 카오카부시키가이샤 | One-pack hair dye composition |
| JP2013534533A (en) * | 2010-07-15 | 2013-09-05 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Foam colorant |
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