JP2002316912A - Oily solid cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily solid cosmetic having good usability, capable of giving excellent luster after applied to the skin, and capable of excellently keeping an effect of preventing secondary adhesion and a cosmetic effect. SOLUTION: This oily solid cosmetic contains the following components (a) to (c): (a) a fluorine-modified silicone; (b) an acrylic silicone-based graft copolymer which is obtained by copolymerizing an organopolysiloxane compound having a radical-polymerizing group at one of its polymer chain ends with a radical-polymerizing monomer consisting mainly of a 16-22C alkyl(meth) acrylate; and (c) a volatile silicone. The cosmetic preferably contains the components (a), (b), and (c) in amounts of 1-40 wt.%, 0.5-40 wt.%, and 0.1-40 wt.%, respectively. Further, the cosmetic preferably contains a silicone resin as the other component (d). The cosmetic is preferably used as a lipstick.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oily solid cosmetic, particularly a lipstick, containing a fluorine-modified silicone, a specific acrylic-silicone-based graft copolymer and a volatile silicone. The present invention relates to an oily solid cosmetic which has excellent luster after application, and also has an excellent secondary adhesion preventing effect and a long lasting cosmetic effect.

[0002]

2. Description of the Related Art Conventionally, oil-based solid cosmetics such as lipsticks, foundations, and the like are composed of wax, oil, and powder as main skeleton components, and various qualities can be obtained by changing the types and amounts of these components. Embodied. In these oil-based solid cosmetics, especially in lipstick compositions, there is a problem in that, after being applied to the lips, the lipstick is transferred to a cup, clothing, or the like, so-called secondary adhesion occurs. Further, even in recent years, foundations with enhanced makeup persistence have had a problem of secondary adhesion of the foundation to clothes and the like.

[0003] For this reason, a number of techniques have been developed for oil-based solid cosmetics such as lipsticks, which are excellent in the effect of preventing secondary adhesion and also in the persistence of makeup. Specifically, a technique of forming a silicone resin film on the lip surface by applying a silicone resin dissolved in a volatile silicone to a lip, applying the volatile silicone to the volatile lip, and then drying the volatile silicone, followed by drying. For improving the water and oil repellency of the decorative film by blending a fluorine-based oil such as fluorine-modified silicone or perfluoropolyether in which fluorine has been introduced into a silicone chain in the form of a brush. In addition, these technologies
It was also used in foundations.

[0004]

However, the technique of blending silicone resin and volatile silicone with lipstick is as follows.
With the drying of the volatile silicone, the gloss of the decorative film sometimes decreased. In addition, the technology of blending a silicone resin and a volatile silicone in the foundation causes the makeup film to shrink as the volatile silicone dries, causing the skin to be pulled (so-called tension) and the flexibility of the makeup film to decrease. There was a case. Furthermore, the technique of blending a fluorine-modified silicone or perfluoropolyether in which fluorine is introduced into a linear silicone chain sometimes causes poor spread and poor adhesion. For this reason,
It has been desired to develop an oil-based solid cosmetic which has good usability, has excellent gloss after application, and has an excellent secondary adhesion preventing effect and a long lasting cosmetic effect.

[0005]

Under such circumstances, the present inventors have conducted intensive studies and have found that a specific fluorine-modified silicone, an organopolysiloxane compound having a radical polymerizable group at one terminal of a molecular chain, and a C 16 -carbon compound. An oil-based solid cosmetic containing an acrylic-silicone-based graft copolymer obtained by copolymerizing a radical polymerizable monomer mainly composed of an alkyl (meth) acrylate and a volatile silicone, and an oil-based solid cosmetic comprising: The inventors have found that the present invention can be solved, and have completed the present invention.

That is, the present invention relates to a component (a) to component (c); (a) a fluorine-modified silicone represented by the following general formula (1):

Embedded image (B) Acrylic-silicone obtained by copolymerizing an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain with a radical polymerizable monomer mainly composed of alkyl (meth) acrylate having 16 to 22 carbon atoms. The present invention provides an oil-based solid cosmetic containing a graft copolymer (c) volatile silicone. In addition, 1 to 40% by mass of the component (a) and 0.5% of the component (b)
The oily solid cosmetic containing 0.1 to 40% by mass and 0.1 to 40% by mass of the component (c), and any one of the oily solid cosmetics containing a silicone resin as the component (d). . Further, the present invention provides any one of the above oily solid cosmetics, wherein the oily solid cosmetic is lipstick.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The component (a) used in the present invention is a component that prevents secondary adhesion and maintains gloss after application in the oil-based solid cosmetic of the present invention, and is a cyclic fluorine compound obtained by introducing a fluorine atom into a cyclic silicone compound. It is a modified silicone, and examples thereof include compounds represented by the following general formula (1).

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More specifically, examples of the fluorine-modified silicone of the component (a) include compounds represented by the following formulas (2) to (9).

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The content of the component (a) in the oily solid cosmetic of the present invention is 1 to 40% by mass (hereinafter simply referred to as “%”).
Abbreviated. ) Is preferable, and 5 to 30% is particularly preferable. When used in this range, it is possible to obtain an oily solid cosmetic having good usability while maintaining good luster.

The component (b) used in the present invention is a component that prevents secondary adhesion and enhances the persistence of the cosmetic effect in the oil-based solid cosmetic of the present invention. An acrylic-silicone graft copolymer obtained by copolymerizing an organopolysiloxane compound having a group and a radical polymerizable monomer mainly composed of an alkyl (meth) acrylate having 16 to 22 carbon atoms. 162442, JP-A-4-342513
Examples described in Japanese Unexamined Patent Publication (Kokai) No. HEI 10-301 are exemplified. Specifically, for example, an organopolysiloxane compound having radical polymerizability at one end of a molecular chain is represented by the following general formula (10)
Can be exemplified.

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On the other hand, a radical polymerizable monomer mainly composed of an alkyl (meth) acrylate having 16 to 22 carbon atoms means a compound having one radical polymerizable unsaturated bond in a molecule. Examples of the alkyl (meth) acrylates Nos. To 22 include palmityl acrylate, palmityl methacrylate, stearyl acrylate, stearyl methacrylate, isostearyl acrylate, isostearyl methacrylate, behenyl acrylate, and behenyl methacrylate. Further, in the radical polymerizable monomer mainly comprising an alkyl (meth) acrylate having 16 to 22 carbon atoms in the present invention, in addition to the alkyl (meth) acrylate having 16 to 22 carbon atoms, other than the above-described alkyl (meth) acrylate having 1 to 22 carbon atoms,
To 30 alkyl (meth) acrylates, styrene, substituted styrene, vinyl acetate, acrylic acid, methacrylic acid,
Maleic anhydride, maleic acid ester, fumaric acid ester, vinyl chloride, vinylidene chloride, ethylene, propylene, butadiene, acrylonitrile, fluorinated olefin, N-vinylpyrrolidone and the like can be used as required.

A dimethylpolysiloxane compound (A) having a radically polymerizable group at one end of a molecular chain and a compound having 16 to 16 carbon atoms
The copolymerization with the radical polymerizable monomer (B) mainly containing alkyl (meth) acrylate No. 22 is carried out at a polymerization ratio ((A) / (B)) within the range of 1/19 to 2/1, and the benzoyl par Oxide, lauroyl peroxide,
The polymerization is carried out in the presence of a usual radical polymerization initiator such as azobisisobutyronitrile, and any polymerization method such as a solution polymerization method, an emulsion polymerization method, a suspension polymerization method, and a bulk polymerization method can be applied. Commercially available products include KP561 and KP562 (both manufactured by Shin-Etsu Chemical Co., Ltd.).

The content of the component (b) in the oily solid cosmetic of the present invention is preferably 0.5 to 40%,
30% is particularly preferred. When used in this range, an oily solid cosmetic having particularly good secondary adhesion preventing effect and good usability can be obtained.

The component (c) used in the present invention is a component which improves the usability and the effect of preventing secondary adhesion in the oily solid cosmetic of the present invention, and has a low molecular weight such as dimethylpolysiloxane and cyclic silicone. Is mentioned. Specific examples include methylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, and decamethylcyclopentasiloxane having a viscosity of 5 cps or less, and one or more of these can be used.

[0015] The content of the component (c) in the oily solid cosmetic of the present invention is preferably 1 to 40%, more preferably 5 to 30%.
Is particularly preferred. When used in this range, an oily solid cosmetic having good usability can be obtained.

The effect of preventing secondary adhesion can be further enhanced by further adding a silicone resin as component (d) to the oily solid cosmetic of the present invention in addition to the above components. As the silicone resin used as the component (d), trimethylsiloxysilicic acid, highly polymerized methylpolysiloxane, highly polymerized methylphenylpolysiloxane,
Examples thereof include cross-linked methyl polysiloxane, cross-linked methyl phenyl polysiloxane, cross-linked polyether-modified silicone, methacryl-modified methyl polysiloxane, and polyvinylpyrrolidone-modified methyl polysiloxane, and one or more of these can be used. Among these silicone resins, silicone resins such as trimethylsiloxysilicic acid, methacryl-modified methylpolysiloxane, and polyvinylpyrrolidone-modified methylpolysiloxane having high film-forming properties are particularly preferable from the viewpoint of the effect of preventing secondary adhesion.

[0017] The content of the component (d) in the oily solid cosmetic of the present invention is preferably 0.5 to 30%,
1-20% is particularly preferred. When used in this range, it is possible to obtain an oil-based solid cosmetic having good gloss after application and good usability.

The oily solid cosmetic of the present invention contains, in addition to the above components, oils other than the components (a) and (c) for the purpose of a solidifying agent, an emollient, a hardness or a regulator, and the like. be able to. Specifically, it is not limited to the origin of animal oils, vegetable oils, synthetic oils and the like, and properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc., and is an oil agent usually used in cosmetics, and hydrocarbons. , Oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils,
Oil agents such as fluorinated oils and lanolin derivatives are exemplified. More specifically, liquid paraffin, α-olefin oligomer, squalane, petrolatum and other hydrocarbons, olive oil, castor oil, jojoba oil, mink oil, oils and fats such as macadamian nut oil, polyethylene wax, microcrystalline wax, Ethylene propylene copolymer wax, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, triisostearic acid Esters such as diglyceryl, glyceryl tribehenate, and pentaerythritol rosin acid; di (phytostearyl.2-N-lauroyl-L-glutamate); Kuchirudodeshiru), N- lauroyl -L- glutamic acid di (cholesteryl behenyl
Amino acid oils such as octyldodecyl) and di (cholesteryl octyldodecyl) N-lauroyl-L-glutamate; stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, and 12-hydroxystearic acid. Fatty acids, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, higher alcohols such as isostearyl alcohol, behenyl alcohol, low polymerization degree dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified polysiloxane, polyoxyalkylene alkylmethyl Silicones such as polysiloxane / methylpolysiloxane copolymers, alkoxy-modified polysiloxanes,
Fluorinated oils such as perfluorodecane, perfluorooctane, and perfluoropolyether; lanolin derivatives such as lanolin, lanolin acetate, isopropyl lanolin fatty acid, and lanolin alcohol; dextrin fatty acid esters; sucrose fatty acid esters; starch fatty acid esters; and aluminum stearate. And oil-based gelling agents such as calcium stearate. One or more of these can be used. The blending amount of these oil agents in the oily solid cosmetic of the present invention is generally 1 to 80%.
Among the above oil agents, it is preferable to mix waxes as a solidifying agent from the viewpoint of usability and stability over time. In this case, the compounding amount of the wax is generally 1 to 30%.
It is.

The oil-based solid cosmetic of the present invention may further comprise the above-mentioned components, if necessary, as long as the effects of the present invention are not impaired.
Powder, surfactant and benzophenone, paraaminobenzoic acid, cinnamic acid, salicylic acid, 4-tert
UV absorbers such as -butyl-4'-methoxydibenzoylmethane and oxinzone; humectants such as glycerin, protein, mucopolysaccharide, collagen, and elastin; vitamins such as vitamin E and vitamin C acid; anti-inflammatory agents; Beauty ingredients, preservatives such as p-hydroxybenzoic acid ester and phenoxyethanol, water-soluble polymers such as methylcellulose, hydroxymethylcellulose, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, xanthan gum, carrageenan, guar gum, agar, pectin, water, fragrance, etc. They can be appropriately blended.

The powder that can be blended with the oily solid cosmetic of the present invention imparts a coloring effect, an ultraviolet blocking effect, a makeup effect, and the like. , Spherical, plate-like, needle-like, etc., fume-like, fine particles, particle size such as pigment grade, porous, non-porous etc. , Organic powders, dye powders, metal powders, composite powders and the like. Specifically, titanium oxide, zinc oxide, cerium oxide, white inorganic pigments such as barium sulfate, iron oxide, carbon black, chromium oxide, chromium hydroxide,
Navy blue, ultramarine blue and other colored inorganic pigments, talc, muscovite, phlogopite, rhombite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, Aluminum oxide,
White body powder such as magnesium oxide, zirconium oxide, antimony oxide, sodium silicate, aluminum silicate, aluminum magnesium magnesium silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, etc. Body, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, iron oxide mica titanium, navy blue treated mica titanium, carmine treated mica titanium, brilliant powder such as fish scale foil, polyamide resin, polyethylene resin, Polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acryl copolymer resin, polypropylene resin, silicone resin, organic polymer resin powder such as urethane resin, S Alin zinc, N- organic low molecular powders such as acyl-lysine, starch, silk powder, natural organic powders such as cellulose powder, Red No. 201, Red 202
, Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, etc., Red No. 3, Red No. 104, Red No. 10
No. 6, orange No. 205, yellow No. 4, yellow No. 5, green No. 3,
Organic pigment powders such as zirconium, barium or aluminum lake such as Blue No. 1, metal powders such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated mica titanium, Composite powders such as titanium oxide-containing silicon dioxide and zinc oxide-containing silicon dioxide can be used, and one or more of these can be used. In addition, these powders are fluorine compounds, silicone compounds, metal soaps, lecithin,
Surface treatment may be performed using one or more of hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. In the oily solid cosmetic of the present invention, the compounding amount of these powders varies depending on the compounding purpose of the powders and the like,
It is approximately 0.1 to 60%.

In the oily solid cosmetic of the present invention, a surfactant can be blended for the purpose of a dispersant, a wetting agent and the like. As the surfactant used here, any surfactant may be used as long as it is a surfactant commonly used in cosmetics. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants Activators and the like.
Specifically, examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester And an alkylene glycol adduct thereof, a fatty acid ester of sorbitol and an alkylene glycol adduct thereof, a polyalkylene glycol fatty acid ester, a sucrose fatty acid ester, a polyoxyalkylene alkyl ether, a glycerin alkyl ether, a polyoxyethylene alkylphenyl ether, and a polyoxyethylene cured castor. Oil, lanolin alkylene glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether modified Silicone and the like, can be used more than those one or two. Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonated fatty acid salts , Acylmethyltaurine salt, N-methyl-N-alkyltaurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkylphenyl Ether phosphate, N-acyl amino acid salt, N-acyl-
Examples thereof include N-alkylamino acid salts, o-alkyl-substituted malates, alkylsulfosuccinates, and the like, and one or more of these can be used. Examples of the cationic surfactant include alkylamine salts, polyamine and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, cyclic quaternary ammonium salts, and the like, and one or more of these can be used.
Ampholytic surfactants include amino acid type and betaine type carboxylic acid type, sulfate ester type, sulfonic acid type,
There is a phosphoric ester type, and those safe for the human body can be used. For example, N-alkyl-N, N
-Dimethyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylenecarboxylic acid, N, N, N-trialkyl-N-sulfoalkyleneammonium betaine, N, N-dialkyl-N, N
-Bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, lecithin and the like, and one or more of these can be used. The amount of the surfactant in the oily solid cosmetic of the present invention varies depending on the purpose of the surfactant, but is generally about 0.01 to 10%.

The oily solid cosmetic of the present invention is applied to lipsticks, foundations, eye shadows, blushers, etc., and the cosmetics in which the effects of the present invention are remarkable are lipsticks. The form of the oily solid cosmetic of the present invention is in the form of a stick, cake or the like.

[0023]

EXAMPLES Next, the present invention will be further described with reference to examples, but the present invention is not limited to these examples.

Examples 1 to 11 and Comparative Examples 1 to 4: Stick lipsticks Stick lipsticks having the compositions shown in Tables 1 and 2 were prepared by the following production method, and were used for elongation and spread, gloss after application, and the like. Each item of secondary adhesion prevention effect and cosmetic effect persistence was evaluated by the following evaluation methods, and the results were combined together in Table 1.
And Table 2.

[0025]

[Table 1]

[0026]

[Table 2]

[0027]

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(Manufacturing method) A: Components 1 to 9 are mixed and dissolved. B: Components 10 to 11 are added to A and mixed. C: Components 12 to 18 are added to B and uniformly dispersed. D: After dissolving and defoaming C, poured into a container and cooled to room temperature to obtain a stick-like lipstick.

(Evaluation method of usability) Fifty women with a makeup history of 10 years or more used the lipsticks of the above Examples and Comparative Examples, and evaluated "usability", "gloss after application", and "secondary". For each item of "adhesion prevention effect" and "persistence of makeup effect", judgment was made based on the following criteria from the number of people who felt that the items were good. In addition, the item of the continuation of the cosmetic effect was evaluated by the state 6 hours after application. [Judgment] [Number of people who felt good]: 40 or more ○: 30 to 39 △: 20 to 29 ×: 10 to 19 XX: 9 or less

As is clear from the results in Tables 1 and 2,
The lipsticks of the examples according to the present invention were superior to the lipsticks of the comparative examples in all items of usability such as spread and spread, gloss after application, secondary adhesion preventing effect, and cosmetic effect. On the other hand, in Comparative Example 1 in which the component (a) was not blended, a secondary adhesion preventing effect and usability were observed, and in Comparative Example 2 in which the component (b) was not blended, gloss after application was low. In Comparative Examples 3 and 4 in which a linear fluorine-modified silicone or perfluoropolyether was used instead of the component (a), the secondary adhesion preventing effect and the usability were inferior to those of the Examples. No item satisfying the items was obtained.

Example 12: Cake-like foundation (component) (% by mass) Candelilla wax 5 2. Microcrystalline wax 10 3. Fluorine-modified silicone (Note 7) 24. 4. Polyglyceryl triisostearate 10 Decamethylcyclopentasiloxane 15 6. Silicone resin (Note 6) 3 7. 7. N-lauroyl-L-glutamic acid di (cholesteryl behenyl octyldodecyl) 8. Tri (caprylic / capric acid) glyceride balance Acrylic-silicone-based graft copolymer (Note 8) 10 10. Fine particle titanium oxide 1 11. Fine particle zinc oxide 1 12. Titanium oxide 8 13. Barium sulfate 2 14. Sericite 15 15. Bengara 1 16. Yellow iron oxide 2 17. Black iron oxide 0.5 18. Aloe extract 0.1 19. Appropriate amount of fragrance Note 7: Fluorine-modified silicone represented by formula (4) Note 8: KP-562 (trade name, manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method) A: Components 1 to 9 are mixed and dissolved. B: Components 10 to 19 are added to A and uniformly dispersed. C: After dissolving and defoaming B, poured into a dish container and cooled to room temperature to obtain a cake-like foundation. The cake-like foundation of Example 12 was excellent in all of the usability such as spread and spread, gloss after application, secondary adhesion preventing effect, and cosmetic effect.

Example 13: Cake-like eyeshadow (component) (% by mass) Microcrystalline wax 5 2. Ceresin wax 10 3. 3. Polyglyceryl triisostearate 4 Vaseline 5 5. Silicone resin (Note 6) 2.5 6. Decamethylcyclopentasiloxane 5 7. 7. Fluorine-modified silicone (Note 1) 8. Squalane remaining amount Propylene glycol caprate 15 10. Acrylic-silicone graft copolymer (Note 5) 15 11. Spherical nylon powder 5 12. Silicone treated talc 10 13. Red No. 202 0.514. Blue No. 404 1 15. Siliconized titanium oxide 2 16. Carboxyvinyl polymer 2 17. Collagen aqueous solution 0.1 18. Appropriate amount of fragrance

(Production method) A: Components 1 to 10 are mixed and dissolved. B: Components 11 to 18 are added to A and uniformly dispersed. C: After dissolving and defoaming B, poured into a dish container and cooled to room temperature to obtain a cake-like eyeshadow. The cake-like eyeshadow of Example 13 was excellent in all of usability such as spread and spread, gloss after application, secondary adhesion preventing effect, and cosmetic effect.

Example 14: Cake-like blusher (ingredient) (% by mass) Carnauba wax 10 2. Polyethylene polypropylene copolymer 10 3. Pentaerythrosin rosinate 7 4. Glyceryl triisooctanoate 5 5. Silicone resin (Note 6) 5 6. Polyglyceryl diisostearate 5 7. 7. Decamethylcyclopentasiloxane 2.5 Fluorine-modified silicone (Note 1) 1 9 Fluorine-modified silicone (Note 2) 2 10 Liquid paraffin balance 11. Acrylic-silicone graft copolymer (Note 8) 10 12. Spherical polystyrene powder 4 13. Sericite 15 14. Talc 10 15. Organically modified clay mineral 0.5 16. Red No. 226 1 17. Yellow No. 4 aluminum lake 2 18. Black iron oxide 0.2 19. Alkyl-modified carboxyvinyl polymer 0.05 20. Rosemary extract 0.1 21. Appropriate amount of fragrance

(Production method) A: Components 1 to 11 are mixed and dissolved. B: Components 12 to 21 are added to A and uniformly dispersed. C: After dissolving and defoaming B, poured into a dish container and cooled to room temperature to obtain a cake-like rouge. The cake-like blusher of Example 14 has usability such as stretching and spreading,
It was excellent in all items of gloss after application, secondary adhesion prevention effect, and makeup effect.

[0037]

As described in detail above, the oily solid cosmetic of the present invention has good usability, excellent gloss after application, and excellent secondary adhesion preventing effect and long lasting cosmetic effect. It was an oily solid cosmetic.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification code FI Theme coat ゛ (Reference) A61K 7/031 A61K 7/031 7/032 7/032 F term (Reference) 4C083 AA112 AA122 AB212 AB232 AB242 AB362 AB432 AB442 AC012 AC022 AC422 AC442 AC482 AC792 AC812 AC852 AC862 AC932 AD022 AD072 AD152 AD161 AD162 AD171 AD172 AD432 AD492 AD662 CC01 CC12 CC13 CC14 DD23 DD30 EE06 EE07

Claims (4)

[Claims] 1. Components (a) to (c): (a) a fluorine-modified silicone represented by the following general formula (1): (B) Acrylic-silicone obtained by copolymerizing an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain with a radical polymerizable monomer mainly composed of alkyl (meth) acrylate having 16 to 22 carbon atoms. An oil-based solid cosmetic comprising: (c) a volatile silicone. 2. Component (a) is 1 to 40% by mass, component (b) is 0.5 to 40% by mass, and component (c) is 0.1 to 4% by mass.
The oil-based solid cosmetic according to claim 1, which contains 0% by mass. 3. The oil-based solid cosmetic according to claim 1, further comprising a silicone resin as the component (d). 4. The oily solid cosmetic according to claim 1, wherein the oily solid cosmetic is lipstick.