JP2002205925A - Hair dye composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a hair dye composition having stability even without having a reducing agent, and when formulated with a peroxide immediately before use, capable of providing a strong dyeing and a glossy dyed hair in ranges of especially brown, purple, blue and red in a relatively short treatment time. SOLUTION: This water-soluble hair dye composition comprises an oxidation dye containing (A) at least one kind selected from tetraaminopyrimidine, triaminohydroxypyrimidine and their water-soluble salts and (B) at least one kind of coupling agent selected from 2-aminophenol, 3-aminophenol, 5-amino-2- methylphenol, 6-amino-2-methylphenol and 1-naphthol.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye composition containing an oxidation dye as a main component and applied to hair after being mixed with a peroxide composition, and a hair dyeing method using the same.

[0002]

2. Description of the Related Art In a hair dye composition containing an oxidation dye precursor, in order to stabilize these components and prevent them from being oxidized before use, ascorbic acid,
A reducing agent such as alkali sulfite is added (for example,
Grundlagen und Rezepturen der Kosmeti by K. Schrader
ka ", 2nd edition (1989), p. 786). However, this method has the disadvantage that it is difficult to be compatible with other components in the composition. In addition, the oxidation dye precursor composition usually consists of an aqueous solution, emulsion, dispersion or gel, and the hair dye mixture immediately before use for applying these usually offsets the antioxidant action of the reducing agent. Requires a substantial excess of peroxide. The hair dyeing effect is slowed down and also affects the quality of the dyeing obtained, especially its strength. Further, this hair dyeing method has a problem that a relatively long processing time is required.

[0003]

SUMMARY OF THE INVENTION An object of the present invention is to provide a hair dye composition which is stable without containing a reducing agent and which can obtain strong dyeing in a relatively short processing time.

[0004]

DISCLOSURE OF THE INVENTION The present inventors have made at least one compound selected from tetraaminopyrimidine, triaminohydroxypyrimidine and water-soluble salts thereof, and 2-aminophenol and 3-amino as coupling agents. Phenol, 5-amino-2-methylphenol, 6-
By combining at least one selected from amino-2-methylphenol and 1-naphthol, a hair dye composition that is stable even without a reducing agent and gives strong dyeing and luster in a relatively short processing time. It was found that a product was obtained.

The present invention relates to the following components (A) and (B): (A) at least one kind of coupling agent selected from tetraaminopyrimidine, triaminohydroxypyrimidine and water-soluble salts thereof, and at least one kind of coupling agent (B) 2-aminophenol, 3-aminophenol,
5-amino-2-methylphenol, 6-amino-2-
Containing an oxidation dye containing at least one coupling agent selected from methylphenol and 1-naphthol,
An object of the present invention is to provide a water-soluble hair dye composition containing no reducing agent.

[0006] The present invention also provides a hair dyeing method comprising mixing the hair dye composition with a water-soluble peroxide composition, applying the mixture to hair, and washing off the hair after treatment. Things.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The component (A) used in the present invention, tetraaminopyrimidine and triaminohydroxypyrimidine, are known as a vehicle for a hair dye composition. For example, it is described in European Patent No. 467026.

The tetraaminopyrimidine of the component (A) is preferably 2,4,5,6-tetraaminopyrimidine, and the triaminohydroxypyrimidine is 4-aminopyrimidine.
Hydroxy-2,5,6-triaminopyrimidine is preferred. As these water-soluble salts, hydrochlorides and sulfates are preferable.

The coupling agent of the component (B) used in the present invention is 2-aminophenol, 3-aminophenol,
5-amino-2-methylphenol, 6-amino-2-
It is selected from methylphenol and 1-naphthol.

[0010] The total content of the coloring material is usually about 0. 0 as a free base in the hair dye composition (excluding the oxidizing composition).
0.5 to 5% by weight, especially 0.1 to 4% by weight, further 0.25%
It is preferably between 0.5 and 0.5% by weight and between 2.5 and 3% by weight.

[0011] The content of the coupling agent in the hair dye composition (excluding the oxidizing agent composition) is usually about 0.05 to
It is preferably 5% by weight, especially 0.1-4% by weight, more preferably 0.5-3% by weight. In the hair dye composition of the present invention, the coupling agent is a reaction partner of the vehicle, and is preferably contained in the same molar ratio as the vehicle. That is, the molar ratio of the vehicle to the coupling agent is 1: 8 to 8: 1, particularly 1: 5 to 5: 1, and even 1:
Preferably it is in the range of 2 to 2: 1.

The hair dye composition of the present invention is obtained by blending these components with a usual base, is oxidized by peroxide, and can be treated in a relatively short processing time, particularly in the colors of brown, blue, purple and red. It gives a very strong and lasting dyeing in the range and can also be changed to other shades by combining various coupling agents.

The hair dye composition of the present invention may contain another oxidation dye precursor in addition to the above essential components. For example, 1-methoxy-2-amino-4- (β-hydroxyethylamino) benzene, 2-amino-3-hydroxypyridine, 2,5-diaminopyridine, 3-amino-2-methylamino-6-methoxypyridine , 2-
(Dimethylamino) -5-aminopyridine, 2-amino-5-N, N-diethylamino-toluene, 1,3-diaminobenzene, 2-amino-4-chlorophenol,
1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, resorcinol, 2-methylresorcinol, 4-chlororesorcinol, 5-amino-2-methoxyphenol, 2-methyl-5-hydroxyethylaminophenol, 4-amino- Examples include 3-methylphenol, 2-amino-4-β-hydroxyethylaminoanisole, and water-soluble salts thereof. In addition to these, other drawable substances and coupling agents can be used.

Further, the hair dye composition of the present invention can contain a direct dye, and is contained in an amount of about 0.005 to 5% by weight, especially 0.1 to 5% by weight in the total composition (excluding the oxidizing composition). 01 ~
The content is preferably 2.5% by weight, more preferably 0.1 to 1% by weight. Such direct dyes include cationic dyes and nitroaminobenzene dyes.

The cationic dye can be used without any particular limitation.
r) "Dye (Grundlagen und Rezepturen by K. Schrader
der Kosmetika, 2nd edition (1989), p. 811). Heretofore, these dyes have not been able to be incorporated into oxidation dye compositions containing reducing agents for compatibility reasons.

Particularly preferred cationic dyes include Basic Blue 6 (CI-No. 51,175), Basic Blue 7 (CI-No. 42,595) and Basic Blue 9 (CI-No.
52,015), Basic Blue 26 (CI-No.44,045),
Basic Blue 41 (CI-No.11,154), Basic Blue 99 (CI-No.56,059), Basic Brown 4
(CI-No.21,010), Basic Brown 16 (CI-N
o.12,250), Basic Brown 17 (CI-No.12,25)
1), Natural Brown 7 (CI-No. 75,500), Basic Green 1 (CI-No. 42,040), Basic Red 2 (CI-No. 50,240), Basic Red 12 (CI-No.
-No.48,070), Basic Red 22 (CI-No.11,05)
5), Basic Red 51, Basic Red 76
(CI-No.12,245), Basic Violet 1 (CI
-No.42,535), Basic Violet 3 (CI-No.4)
2,555), Basic Violet 10 (CI-No.45,17)
0), Basic Violet 14 (CI-No.42,51)
0), Basic Yellow 57 (CI-No. 12,719), Basic Yellow 87, Basic Orange 31 and the like. In addition, vegetable direct dyes can also be used.

Examples of the nitroaminobenzene dye include 2-
Amino-4,6-dinitrophenol, 2-amino-4
-Nitrophenol, 2-amino-5-nitrophenol, 4-hydroxyethylamino-3-nitrophenol, 4-hydroxypropylamino-3-nitrophenol, 2-amino-6-chloro-4-nitrophenol, 2- Chloro-6-ethylamino-4-nitrophenol, 2-amino-5- (2′-hydroxyethyl) aminonitrobenzene, 2-methylamino-5-bis (2′-hydroxyethyl) aminonitrobenzene,
-Chloro-6-methylamino-4-nitrophenol and the like. When such a nitroaminobenzene derivative is directly contained in the hair dye composition of the present invention containing an oxidation dye, the stability becomes higher even without containing a reducing agent.

Since the hair dye composition of the present invention does not contain a reducing agent, it is generally used for such a composition such as a basic substance or a conditioning agent. 2nd Edition (Huthig Buch Verlag, Heidelberg, 1989), pp. 782-81
It can contain components as described on page 5.

The hair dye composition of the present invention can be produced in the form of a solution, cream, gel, aerosol or the like using a commonly used water-soluble base composition.

The hair dye composition of the present invention containing the oxidation dye thus obtained is mixed with a water-soluble peroxide composition at the time of use. As the peroxide, hydrogen peroxide,
For example, hydrogen peroxide having a concentration of 2 to 6% by weight is preferable. Further, other peroxides such as urea peroxide and melamine peroxide can also be used.

The pH of the hair dye composition immediately before use mixed with peroxide is weakly acidic (ie, pH 5.5 to 6.9),
Alternatively, neutral to alkaline (that is, pH 7.1 to 1)
0).

The hair dye composition of the present invention comprises, as described above,
Immediately before use, it is mixed with the water-soluble peroxide composition, this mixture is applied to the hair, and after being treated for a predetermined period of time, it can be used by rinsing it, and it is possible to obtain strong dyeing and glossy hair.

[0023]

The hair dye composition of the present invention is stable without containing a reducing agent. If this is mixed with a peroxide immediately before use, it can be treated in a relatively short treatment time, Strong dyeing and glossy hair can be given in the range of brown, blue, purple and red. Further, by combining with various coupling agents, it is possible to change the color to another color.

[0024]

Example 1 A hair dye composition was prepared by adding a coloring material and a coupling agent shown in Tables 2 and 3 to a base having the composition shown in Table 1 and adjusting the amount of water. Was manufactured.

[0025]

[Table 1]

[0026]

[Table 2]

[0027]

[Table 3]

The resulting hair dye composition was mixed with a 6% hydrogen peroxide solution, and the mixture was applied to wool pieces and bleached hair tresses, treated at room temperature for 20 minutes, rinsed and dried. In the case of any of the hair dye compositions, Table 2
Dyeing of the color shown in Table 3 was obtained, and in particular, in the present invention products 1 to 6, stronger dyeing than the comparative product containing the reducing agent,
A more expressive luster was obtained. The dye of the present invention was obtained in a shorter time (about 15 minutes) than the comparative product. Furthermore, the product of the present invention was stable without any change even after storage at 40 ° C. for 3 months.

Example 2 A hair dye composition was prepared by adding a coloring material and a coupling agent shown in Tables 4 and 5 to a base having a composition shown in Table 1 and adjusting the blending amount of water. Manufactured.

[0030]

[Table 4]

[0031]

[Table 5]

The resulting hair dye composition was mixed with a 6% hydrogen peroxide solution, and the mixture was applied to wool pieces and bleached hair tresses, treated at room temperature for 20 minutes, rinsed and dried. Table 4 for all hair dye compositions.
~ Strong intense dyeing of the colors shown in Table 5 was obtained, and in particular, in the case of the present invention products 7 to 14, more intense dyeing and a more expressive luster were obtained. In addition, the product of the present invention achieved dyeing in a shorter time (about 15 minutes) than the comparative product containing a reducing agent. Furthermore, the product of the present invention was stable without any change after storage at 40 ° C. for 3 months, but the comparative product was no longer suitable for hair dyeing.

 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Klaus Kaffenberger, Germany 64665 Alsbach-Hahn Rein, Im Klingen 50 (72) Inventor Barbara Galbe, Germany 64625 Bensheim, Heinrich-Wintel-Weck 1F Term ( Reference) 4C083 AB082 AB332 AB352 AB412 AC072 AC122 AC182 AC242 AC392 AC472 AC532 AC551 AC552 AC642 AC731 AC732 AC762 AC782 AC851 AC852 AC902 AD412 AD642 CC36 DD23 EE26

Claims (5)

[Claims] 1. The following components (A) and (B): (A) at least one selected from tetraaminopyrimidine, triaminohydroxypyrimidine and water-soluble salts thereof, (B) 2-aminophenol, 3-aminophenol It contains an oxidation dye containing at least one coupling agent selected from aminophenol, 5-amino-2-methylphenol, 6-amino-2-methylphenol and 1-naphthol, and does not contain a reducing agent. Water-soluble hair dye composition. 2. The hair dye composition according to claim 1, further comprising (C) a cationic dye or a nitroaminobenzene dye. 3. The hair dye composition according to claim 1, wherein the component (A) is 2,4,5,6-tetraaminopyrimidine or a water-soluble salt thereof. 4. Component (A) is 4-hydroxy-2,
The hair dye composition according to claim 1 or 2, which is 5,6-triaminopyrimidine or a water-soluble salt thereof. 5. A hair dye composition according to claim 1, which is mixed with a water-soluble peroxide composition, the mixture is applied to the hair, and the hair is washed off after the treatment. How to dye hair.