JP2002192118A - Treating method and device for waste material - Google Patents
Treating method and device for waste materialInfo
- Publication number
- JP2002192118A JP2002192118A JP2000397929A JP2000397929A JP2002192118A JP 2002192118 A JP2002192118 A JP 2002192118A JP 2000397929 A JP2000397929 A JP 2000397929A JP 2000397929 A JP2000397929 A JP 2000397929A JP 2002192118 A JP2002192118 A JP 2002192118A
- Authority
- JP
- Japan
- Prior art keywords
- waste
- chlorine
- dust
- heavy metal
- rotary kiln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims description 16
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 55
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000000460 chlorine Substances 0.000 claims abstract description 36
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 36
- 239000000428 dust Substances 0.000 claims description 32
- 238000004056 waste incineration Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000011362 coarse particle Substances 0.000 claims description 7
- 239000010419 fine particle Substances 0.000 claims description 7
- 238000010304 firing Methods 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 2
- 239000010813 municipal solid waste Substances 0.000 abstract description 8
- 238000002844 melting Methods 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000004568 cement Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 102100033007 Carbonic anhydrase 14 Human genes 0.000 description 1
- 101000867862 Homo sapiens Carbonic anhydrase 14 Proteins 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Fire-Extinguishing Compositions (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】この発明は、都市ごみ焼却
灰、または重金属及び塩素を含有する廃棄物の再資源化
処理方法及び装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for recycling incinerated ash from municipal waste or waste containing heavy metals and chlorine.
【０００２】[0002]
【従来の技術】都市ごみ焼却灰は、１９９２年の「廃棄
物の処理及び清掃に関する法律」の改正により特別一般
廃棄物の指定を受け、中間処理が義務づけられている。
それらの中間処理方法としては、セメントあるいは薬剤
を用いた不溶化処理法、電気炉を用いた溶融固化法、溶
媒注出法等がある。また、２０００年の改正により処理
方法に「焼成」が追加された。このうち、最も一般的な
処理方法は、セメント固化剤等による不溶化処理後に管
理型の最終処理場にて処分するものである。しかし、現
在では最終処理地も不足しており、その対策が急務にな
っている。また、溶融固化法による減容化処理も盛んに
試みられているが、減容化は処分場の延命策にはなり得
ても、根本的な解決にはなり得ない。都市ごみ焼却灰の
処理における最大の課題は、いかに再資源化するかとい
う点にある。2. Description of the Related Art Municipal refuse incineration ash has been designated as special municipal waste by the revision of the "Law on the Treatment and Cleaning of Waste" in 1992, and intermediate treatment is obligatory.
Examples of the intermediate treatment methods include an insolubilization treatment method using cement or a chemical, a melt solidification method using an electric furnace, and a solvent pouring method. In addition, "Baking" was added to the treatment method by the revision in 2000. Of these, the most common treatment method is to dispose at a controlled final treatment plant after insolubilization treatment with a cement solidifying agent or the like. However, there is now a shortage of final disposal sites, and measures are urgently needed. In addition, volume reduction by the melt-solidification method has been actively attempted, but even if volume reduction can be a measure to extend the life of a disposal site, it cannot be a fundamental solution. The biggest challenge in municipal solid waste incineration is how to recycle it.
【０００３】[0003]
【発明が解決しようとする課題】この発明は、都市ごみ
焼却灰、または重金属及び塩素を含有する廃棄物から重
金属と塩素を分離することにより、都市ごみ焼却灰、ま
たは重金属及び塩素を含有する廃棄物を再資源化すると
共に分離した重金属を再資源化の容易な状態で回収する
ことを目的とする。SUMMARY OF THE INVENTION The present invention separates heavy metal and chlorine from municipal waste incineration ash or heavy metal and chlorine-containing waste, thereby producing municipal waste incineration ash or heavy metal and chlorine-containing waste. It is an object of the present invention to recycle materials and to recover separated heavy metals in an easily recyclable state.
【０００４】[0004]
【課題を解決するための手段】上記目的を達成するため
のこの発明の方法は、都市ごみ焼却灰、または重金属及
び塩素を含有する廃棄物をロータリーキルン内で焼成す
ることにより重金属及び塩素を揮発させると共に焼成物
を半溶融状態のまま造粒し、粒状の焼成物を骨材として
再資源化することを特徴とする。焼成温度は８００〜１
５００℃とする。さらに、揮発した重金属及び塩素を急
冷してダストとし、これを捕集することで重金属を再資
源化が容易な状態で回収することができる。また、重金
属及び塩素を含むダストを分級し、微粒側のダスト中の
重金属濃度を高めた上で回収し、粗粒側のダストはロー
タリーキルンに戻すことが好ましい。粒状の焼成物を所
定の粒径に粗粉砕して骨材として利用することもでき
る。また、粒状の焼成物を篩い分けし、所定の粒径のも
のを骨材として利用すると共に残りをロータリーキルン
に戻すようにすることもできる。SUMMARY OF THE INVENTION In order to achieve the above object, a method of the present invention is to volatilize heavy metals and chlorine by burning municipal solid waste incineration ash or waste containing heavy metals and chlorine in a rotary kiln. At the same time, the fired product is granulated in a semi-molten state, and the granulated fired material is recycled as aggregate. Firing temperature is 800 ~ 1
500 ° C. Further, the volatile heavy metal and chlorine are rapidly cooled to form dust, and by collecting this, the heavy metal can be recovered in a state where it can be easily recycled. Further, it is preferable to classify dust containing heavy metal and chlorine, increase the concentration of heavy metal in dust on the fine particle side, collect the dust, and return the dust on the coarse particle side to the rotary kiln. The granular fired product may be roughly pulverized to a predetermined particle size and used as an aggregate. Further, it is also possible to sieve the granular fired product, to use the one having a predetermined particle size as an aggregate, and to return the rest to a rotary kiln.
【０００５】装置の形態としては、都市ごみ焼却灰、ま
たは重金属及び塩素を含有する廃棄物の投入装置を有す
ると共に廃棄物を焼成することにより重金属及び塩素を
揮発させると共に焼成物を半溶融状態のまま造粒するロ
ータリーキルンと、揮発した重金属及び塩素を急冷して
ダストとする冷却手段と、重金属及び塩素を含むダスト
を捕集する集塵装置とを備えたことを特徴とする。ま
た、ダストを微粒側と粗粒側に分級する分級装置を冷却
手段と集塵装置との間に配置し、粗粒側のダストをロー
タリーキルンに戻すことが好ましい。[0005] As a form of the apparatus, there is provided a device for injecting municipal waste incineration ash or a waste containing heavy metal and chlorine, and by firing the waste, the heavy metal and chlorine are volatilized and the burned material is semi-molten. It is characterized by comprising a rotary kiln that granulates as it is, cooling means for rapidly cooling volatile heavy metals and chlorine to produce dust, and a dust collector for collecting dust containing heavy metals and chlorine. Further, it is preferable that a classifier for classifying the dust into a fine particle side and a coarse particle side is disposed between the cooling means and the dust collector, and the coarse particle side dust is returned to the rotary kiln.
【０００６】[0006]
【発明の実施の形態】以下、この発明の実施の形態を添
付図面に基づいて説明する。図１にこの発明の実施の形
態に係る廃棄物の処理装置のシステムフロー図を示す。
ロータリーキルン１の窯尻に原料送入用スクリューコン
ベヤ等の搬送手段を介して廃棄物貯蔵タンク２が接続さ
れている。一方、ロータリーキルン１の窯前には、焼成
物を冷却するクーラー３が連結されると共にバーナー４
が設けられている。ロータリーキルン１の窯尻にはイン
レットフッド５を介して冷却装置６が接続され、冷却装
置６に分級装置７、集塵装置８及び排ガス処理装置９を
介して煙突１０が接続されている。また、集塵装置８に
重金属濃縮装置１１が接続されている。Embodiments of the present invention will be described below with reference to the accompanying drawings. FIG. 1 shows a system flow diagram of a waste treatment apparatus according to an embodiment of the present invention.
A waste storage tank 2 is connected to the kiln bottom of the rotary kiln 1 via a conveyance means such as a screw conveyor for feeding raw materials. On the other hand, in front of the kiln of the rotary kiln 1, a cooler 3 for cooling the fired material is connected and a burner 4 is provided.
Is provided. A cooling device 6 is connected to the kiln bottom of the rotary kiln 1 via an inlet hood 5, and a chimney 10 is connected to the cooling device 6 via a classification device 7, a dust collection device 8 and an exhaust gas treatment device 9. The heavy metal concentrating device 11 is connected to the dust collecting device 8.
【０００７】次に、この実施の形態に係る廃棄物の処理
装置の動作について説明する。廃棄物貯蔵タンク２内に
都市ごみ焼却灰、または重金属及び塩素を含有する廃棄
物が貯蔵されるが、廃棄物の状態によっては、乾燥、粉
砕等の前処理を行った上で廃棄物貯蔵タンク２内に収容
することが好ましい。この廃棄物貯蔵タンク２から廃棄
物が搬送手段によってロータリーキルン１内に搬送さ
れ、ここで焼成される。Next, the operation of the waste disposal apparatus according to this embodiment will be described. Municipal solid waste incineration ash or waste containing heavy metals and chlorine is stored in the waste storage tank 2. Depending on the state of the waste, the waste storage tank is subjected to pretreatment such as drying and pulverization. It is preferable to house it in the housing 2. The waste is transported from the waste storage tank 2 into the rotary kiln 1 by the transporting means, where it is fired.
【０００８】廃棄物がロータリーキルン１内を通過する
間に、廃棄物に含有されている重金属は同じく重金属に
含有されている塩素と結合し、揮発しやすい塩化物とな
って排ガスと共にロータリーキルン１の外部に排出され
る。また、重金属と結合しなかった塩素もアルカリ等と
結合して塩化物となり、揮発して排ガスと共にロータリ
ーキルン１の外部に排出される。廃棄物は、ロータリー
キルン１を６０〜９０分以上かけて通過するため、重金
属及び塩素が十分に揮発した状態で焼成され、連続的な
処理が可能である。なお、焼成温度は８００〜１５００
℃とするが、Ｐｂ等の重金属を揮発させるためには、１
１００〜１５００℃とすることが望ましい。廃棄物の成
分によって焼成温度は影響を受けるが、例えば石灰石を
添加することにより焼成温度を高めることができる。While the waste passes through the rotary kiln 1, the heavy metal contained in the waste combines with the chlorine also contained in the heavy metal to become a volatile chloride, which together with the exhaust gas is discharged outside the rotary kiln 1. Is discharged. In addition, chlorine that has not been combined with heavy metals is combined with alkali or the like to form chlorides, which are volatilized and discharged to the outside of the rotary kiln 1 together with exhaust gas. Since the waste passes through the rotary kiln 1 for 60 to 90 minutes or more, the waste is fired in a state where the heavy metal and chlorine are sufficiently volatilized, and continuous treatment is possible. The firing temperature is 800 to 1500
° C, but in order to volatilize heavy metals such as Pb,
It is desirable that the temperature be 100 to 1500 ° C. Although the firing temperature is affected by the components of the waste, the firing temperature can be increased by, for example, adding limestone.
【０００９】揮発により重金属及び塩素が十分に除去さ
れた廃棄物はロータリーキルン１内で焼成されて半溶融
状態のまま造粒され、ある程度粒径のそろった粒状の焼
成物となる。この焼成物は、クーラー３で冷却された
後、コンクリート用あるいは路盤材等の骨材として使用
可能となる。粒状の焼成物の粒径が大きい場合には、汎
用の粉砕装置を用いて所定の粒径に粗粉砕し、これを骨
材として利用することもできる。また、粒状の焼成物を
汎用の篩装置で篩い分けし、所定の粒径のものを骨材と
して利用すると共に残りを再びロータリーキルン１に戻
すようにすることもできる。さらに、粒状の焼成物をま
ず粉砕装置で粗粉砕し、その後篩装置で篩い分けして、
所定の粒径のものを骨材として利用すると共に残りを再
びロータリーキルン１に戻してもよい。The waste from which the heavy metals and chlorine have been sufficiently removed by volatilization is fired in the rotary kiln 1 and granulated in a semi-molten state, thereby obtaining a granular fired product having a uniform particle size to some extent. After being cooled by the cooler 3, the fired product can be used as an aggregate for concrete or a roadbed material. When the particle size of the granular fired product is large, it can be roughly pulverized to a predetermined particle size using a general-purpose pulverizer, and this can be used as an aggregate. Alternatively, the granular fired product can be sieved with a general-purpose sieving apparatus, and a material having a predetermined particle size can be used as an aggregate, and the remainder can be returned to the rotary kiln 1 again. Furthermore, the granular fired product is first coarsely pulverized by a pulverizer, and then sieved by a sieve,
It is also possible to use the particles having a predetermined particle size as aggregate and return the remainder to the rotary kiln 1 again.
【００１０】焼成物は重金属の大部分が揮発し、一部残
留している重金属も焼成によって生成した鉱物の中に取
り込まれて安定化する。重金属及び塩素を含有する廃棄
物から重金属、塩素及びアルカリが揮発した焼成物は、
主に塩化物のダストとなり、集塵装置８で捕集される。
捕集されたダストは、高濃度の重金属を含有しているた
め、重金属抽出等の重金属濃縮装置１１で処理すること
で、重金属精錬の原料に提供できるだけの品質を有する
重金属産物として再資源化が可能である。In the fired product, most of the heavy metal is volatilized, and a part of the heavy metal remaining therein is incorporated into the mineral generated by the firing and stabilized. Burned material in which heavy metals, chlorine and alkalis are volatilized from wastes containing heavy metals and chlorine,
It mainly becomes chloride dust and is collected by the dust collecting device 8.
Since the collected dust contains a high concentration of heavy metal, it can be recycled as a heavy metal product having a quality that can be provided as a raw material for heavy metal refining by treating it with a heavy metal concentrator 11 such as heavy metal extraction. It is possible.
【００１１】ロータリーキルン１から排出されるダスト
中には、投入された廃棄物の一部がそのまま飛散して混
入している。廃棄物の飛散が多量に及ぶ場合には、集塵
装置８で捕集されたダストの重金属濃度が低下するた
め、重金属濃縮処理を施しても再資源化に堪えうる品質
を確保することができない。その場合、分級装置７でダ
ストを分級し、粒度の細かい塩化物のダストを微粒側、
粒度の粗いダストを粗粒側に分離することで、微粒側の
ダスト中の重金属濃度を上げることが望ましい。粗粒側
のダストは再びロータリーキルン１に戻される。In the dust discharged from the rotary kiln 1, a part of the input waste is scattered and mixed as it is. When a large amount of waste is scattered, the concentration of heavy metals in the dust collected by the dust collecting device 8 decreases, so that even if the heavy metal concentration treatment is performed, a quality that can withstand recycling cannot be ensured. . In that case, the dust is classified by the classifier 7 and the chloride dust having a fine particle size is finely divided into fine particles.
It is desirable to increase the concentration of heavy metals in the dust on the fine particle side by separating the coarse-grain dust into the coarse particle side. The dust on the coarse side is returned to the rotary kiln 1 again.
【００１２】廃棄物貯蔵タンク２内に貯蔵される廃棄物
の組成としては、都市ごみ焼却灰のみ、都市ごみ焼却灰
以外の重金属及び塩素を含む廃棄物のみ、都市ごみ焼却
灰とその他の廃棄物との混合物等、各種のものを用いる
ことができる。ただし、都市ごみ焼却灰、または重金属
及び塩素を含有する廃棄物の割合が少なくとも５０重量
％を超えるものを用いることが好ましい。近年、都市ご
み焼却灰の再資源化が各方面で試みられているが、この
発明によれば、１００％都市ごみ焼却灰からなる廃棄物
を骨材として再資源化することもでき、極めて有用な廃
棄物処理であることは言うまでもない。The composition of the waste stored in the waste storage tank 2 includes only municipal waste incineration ash, only waste containing heavy metals and chlorine other than municipal waste incineration ash, municipal waste incineration ash and other wastes. And the like can be used. However, it is preferable to use incinerated ash from municipal solid waste or waste containing at least 50% by weight of waste containing heavy metals and chlorine. In recent years, recycling of municipal waste incineration ash has been attempted in various fields. According to the present invention, waste consisting of 100% municipal waste incineration ash can also be recycled as aggregate, which is extremely useful. Needless to say, it is waste disposal.
【００１３】[0013]
【発明の効果】以上説明したように、この発明によれ
ば、都市ごみ焼却灰、または重金属及び塩素を含有する
廃棄物をロータリーキルン内で焼成して重金属と塩素を
揮発させ、焼成物を半溶融状態のまま造粒することで、
粒状の焼成物を骨材として再資源化することが可能であ
る。また、分離した重金属も再資源化が容易な状態で回
収することができ、新たな廃棄物を出すことがない。従
って、新たに環境を汚染することがなく、埋め立て等の
最終処分を必要としない完全な廃棄物処理が可能であ
る。As described above, according to the present invention, municipal solid waste incineration ash or heavy metal and chlorine-containing waste is fired in a rotary kiln to volatilize heavy metal and chlorine, and the fired material is semi-melted. By granulating as it is,
The granular fired material can be recycled as aggregate. Further, the separated heavy metal can be recovered in a state where it can be easily recycled, and no new waste is generated. Therefore, it is possible to completely treat the waste without newly polluting the environment and not requiring final disposal such as landfill.
【図１】この発明の実施の形態に係る廃棄物の処理装置
のシステムフロー図である。FIG. 1 is a system flow diagram of a waste treatment apparatus according to an embodiment of the present invention.
１ ロータリーキルン、２ 廃棄物貯蔵タンク、３ ク
ーラー、４ バーナー、５ インレットフッド、６ 冷
却装置、７ 分級装置、８ 集塵装置、９ 排ガス処理
装置、１０ 煙突、１１ 重金属濃縮装置。1 Rotary kiln, 2 waste storage tank, 3 cooler, 4 burner, 5 inlet hood, 6 cooling system, 7 classifier, 8 dust collector, 9 exhaust gas treatment system, 10 chimney, 11 heavy metal concentrator.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 田中 宜久 千葉県佐倉市大作二丁目４番２号 太平洋 セメント株式会社中央研究所内 Ｆターム(参考） 2E191 BA02 BA12 BB00 BC01 BD12 4D004 AA36 AA46 AB03 AB06 BA02 CA04 CA08 CA14 CA28 CA29 CA32 CA42 CB09 CB34 CB44 CC11 DA03 DA06 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Yoshihisa Tanaka 2-4-2, Daisaku, Sakura City, Chiba Pref. Pacific Rental Co., Ltd. Central Research Laboratory F-term (reference) 2E191 BA02 BA12 BB00 BC01 BD12 4D004 AA36 AA46 AB03 AB06 BA02 CA04 CA08 CA14 CA28 CA29 CA32 CA42 CB09 CB34 CB44 CC11 DA03 DA06
Claims (8)
を含有する廃棄物をロータリーキルン内で焼成すること
により重金属及び塩素を揮発させると共に焼成物を半溶
融状態のまま造粒し、粒状の焼成物を骨材として再資源
化することを特徴とする廃棄物の処理方法。An incinerated ash from municipal waste or a waste containing heavy metals and chlorine is burned in a rotary kiln to volatilize heavy metals and chlorine, and the burned material is granulated in a semi-molten state. A method for treating waste, characterized in that the waste is recycled as aggregate.
徴とする請求項１に記載の廃棄物の処理方法。2. The method for treating waste according to claim 1, wherein the firing is performed at 800 to 1500 ° C.
トとし、これを捕集することで重金属を再資源化が容易
な状態で回収することを特徴とする請求項１または２に
記載の廃棄物の処理方法。3. The disposal according to claim 1, wherein the volatile heavy metal and chlorine are rapidly cooled to form dust, and the collected heavy metal is recovered in an easily recyclable state. How to handle things.
微粒側を回収し、粗粒側をロータリーキルンに戻すこと
を特徴とする請求項３に記載の廃棄物の処理方法。4. Classifying dust containing heavy metals and chlorine,
The method for treating waste according to claim 3, wherein the fine particle side is collected and the coarse particle side is returned to the rotary kiln.
骨材として利用することを特徴とする請求項１〜４のい
ずれか一項に記載の廃棄物の処理方法。5. The method for treating waste according to claim 1, wherein the granular fired product is roughly pulverized to a predetermined particle size and used as an aggregate.
のものを骨材として利用すると共に残りをロータリーキ
ルンに戻すことを特徴とする請求項１〜４のいずれか一
項に記載の廃棄物の処理方法。6. The method according to any one of claims 1 to 4, wherein the granular fired product is sieved, a material having a predetermined particle size is used as an aggregate, and the remainder is returned to a rotary kiln. Waste treatment method.
を含有する廃棄物の投入装置を有すると共に廃棄物を焼
成することにより重金属及び塩素を揮発させると共に焼
成物を半溶融状態のまま造粒するロータリーキルンと、 揮発した重金属及び塩素を急冷してダストとする冷却手
段と、 重金属及び塩素を含むダストを捕集する集塵装置とを備
えたことを特徴とする廃棄物の処理装置。7. A waste incineration ash or a waste material containing heavy metal and chlorine is provided, and the waste is calcined to volatilize the heavy metal and chlorine and granulate the burned material in a semi-molten state. An apparatus for treating waste, comprising: a rotary kiln; cooling means for rapidly cooling volatile heavy metals and chlorine to produce dust; and a dust collector for collecting dust containing heavy metals and chlorine.
つダストを微粒側と粗粒側に分級する分級装置を備え、 粗粒側のダストをロータリーキルンに戻すことを特徴と
する請求項７に記載の廃棄物の処理装置。8. A classifier disposed between the cooling means and the dust collecting device for classifying dust into fine particles and coarse particles, wherein the coarse particles are returned to the rotary kiln. A waste treatment apparatus according to claim 7.
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| JP2000397929A JP4443031B2 (en) | 2000-12-27 | 2000-12-27 | Waste treatment method and apparatus |
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|---|---|---|---|
| JP2000397929A JP4443031B2 (en) | 2000-12-27 | 2000-12-27 | Waste treatment method and apparatus |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005288434A (en) * | 2004-03-12 | 2005-10-20 | Mitsubishi Heavy Ind Ltd | Detoxifying treatment method for heavy metal-containing substance, apparatus therefor and the system |
| JP2005288433A (en) * | 2004-03-12 | 2005-10-20 | Mitsubishi Heavy Ind Ltd | Detoxifying treatment method for heavy metal-containing substance and apparatus therefor |
| CN114034047A (en) * | 2021-12-22 | 2022-02-11 | 天津壹鸣环境科技股份有限公司 | High-chlorine incineration residue chlorine salt and heavy metal synergistic volatilization reduction treatment method |
-
2000
- 2000-12-27 JP JP2000397929A patent/JP4443031B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005288434A (en) * | 2004-03-12 | 2005-10-20 | Mitsubishi Heavy Ind Ltd | Detoxifying treatment method for heavy metal-containing substance, apparatus therefor and the system |
| JP2005288433A (en) * | 2004-03-12 | 2005-10-20 | Mitsubishi Heavy Ind Ltd | Detoxifying treatment method for heavy metal-containing substance and apparatus therefor |
| JP4678762B2 (en) * | 2004-03-12 | 2011-04-27 | 三菱重工環境・化学エンジニアリング株式会社 | Method and apparatus for detoxifying heavy metal-containing substances |
| CN114034047A (en) * | 2021-12-22 | 2022-02-11 | 天津壹鸣环境科技股份有限公司 | High-chlorine incineration residue chlorine salt and heavy metal synergistic volatilization reduction treatment method |
| CN114034047B (en) * | 2021-12-22 | 2024-02-23 | 天津壹鸣环境科技股份有限公司 | Synergistic volatilization reduction treatment method for chlorine salt and heavy metal of high-chlorine incineration residue |
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