JP2002179971A - Printing ink - Google Patents
Printing inkInfo
- Publication number
- JP2002179971A JP2002179971A JP2000383036A JP2000383036A JP2002179971A JP 2002179971 A JP2002179971 A JP 2002179971A JP 2000383036 A JP2000383036 A JP 2000383036A JP 2000383036 A JP2000383036 A JP 2000383036A JP 2002179971 A JP2002179971 A JP 2002179971A
- Authority
- JP
- Japan
- Prior art keywords
- printing ink
- printing
- present
- parts
- zein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 36
- 229920000704 biodegradable plastic Polymers 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 6
- 229940099898 chlorophyllin Drugs 0.000 claims abstract description 5
- 235000019805 chlorophyllin Nutrition 0.000 claims abstract description 5
- 239000003086 colorant Substances 0.000 claims abstract description 4
- 239000000976 ink Substances 0.000 claims description 27
- 239000000975 dye Substances 0.000 claims description 13
- 229920002494 Zein Polymers 0.000 claims description 9
- 239000005019 zein Substances 0.000 claims description 9
- 229940093612 zein Drugs 0.000 claims description 9
- 239000002985 plastic film Substances 0.000 claims description 5
- 229930182559 Natural dye Natural products 0.000 claims description 3
- 239000000978 natural dye Substances 0.000 claims description 3
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- JVOGSHDZLOJKKR-MXFMKSRJSA-I [Na+].[Na+].[Na+].[Mg++].CCc1c(C)c2cc3[n-]c(c(C)c3C=C)c(C)c3nc(C[C@H]3CCC([O-])=O)c(CC([O-])=O)c3[n-]c(cc1n2)c(C)c3C([O-])=O Chemical compound [Na+].[Na+].[Na+].[Mg++].CCc1c(C)c2cc3[n-]c(c(C)c3C=C)c(C)c3nc(C[C@H]3CCC([O-])=O)c(CC([O-])=O)c3[n-]c(cc1n2)c(C)c3C([O-])=O JVOGSHDZLOJKKR-MXFMKSRJSA-I 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- -1 polybutylene succinate Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 235000012665 annatto Nutrition 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZVKOASAVGLETCT-UOGKPENDSA-N Norbixin Chemical compound OC(=O)/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C(O)=O ZVKOASAVGLETCT-UOGKPENDSA-N 0.000 description 2
- JERYLJRGLVHIEW-UENHKZIGSA-N Norbixin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C(=O)O)C=CC=CC=CC(=O)O JERYLJRGLVHIEW-UENHKZIGSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- ZVKOASAVGLETCT-UOAMSCJGSA-N all-trans norbixin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C(=O)O)C=CC=C(/C)C=CC(=O)O ZVKOASAVGLETCT-UOAMSCJGSA-N 0.000 description 2
- 239000001670 anatto Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004631 polybutylene succinate Substances 0.000 description 2
- 229920002961 polybutylene succinate Polymers 0.000 description 2
- 229920009537 polybutylene succinate adipate Polymers 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 244000017106 Bixa orellana Species 0.000 description 1
- 244000163122 Curcuma domestica Species 0.000 description 1
- 235000003392 Curcuma domestica Nutrition 0.000 description 1
- 240000001972 Gardenia jasminoides Species 0.000 description 1
- 108010068370 Glutens Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 241000123069 Ocyurus chrysurus Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000086363 Pterocarpus indicus Species 0.000 description 1
- 235000009984 Pterocarpus indicus Nutrition 0.000 description 1
- 241000245165 Rhododendron ponticum Species 0.000 description 1
- 241000238371 Sepiidae Species 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000010362 annatto Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000003373 curcuma longa Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 235000021312 gluten Nutrition 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 239000004630 polybutylene succinate adipate Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 235000013976 turmeric Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は印刷インキに関し、
更に詳細には、環境負荷の少ない印刷インキに関する。The present invention relates to a printing ink,
More specifically, the present invention relates to a printing ink having a low environmental load.
【0002】[0002]
【従来の技術】従来、印刷インキは、専ら顔料をバイン
ダーと溶剤からなるビヒクルに分散させて使用されてき
た。印刷インキのバインダーは、ウレタン樹脂、アクリ
ル樹脂、アルキッド樹脂等の合成樹脂、又はロジン変性
フェノール樹脂、ニトロセルロース等の天然物を原料と
する変性樹脂が使用されているが、これらのバインダー
に使用される樹脂は、生分解性はほとんど認められてい
ない。2. Description of the Related Art Conventionally, printing inks have been used by dispersing a pigment exclusively in a vehicle comprising a binder and a solvent. As the binder of the printing ink, a synthetic resin such as a urethane resin, an acrylic resin, or an alkyd resin, or a modified resin made of a natural material such as a rosin-modified phenol resin or nitrocellulose is used. Resin has little biodegradability.
【0003】又、顔料は化学的に安定な化学合成物であ
って、水や有機溶剤に溶解せず、耐候性等の耐性にも優
れているため、廃棄された場合の生分解性も期待できな
いものであった。特に、緑色は環境保護を表す色彩とし
てのイメージが社会的に定着しており、多くの団体が
「緑」、「グリーン」の語を含む名称で活動し、又、環
境保護を推進するために緑色で彩色されたシンボルマー
クが使用されている。しかしながら、印刷インキの緑色
は、フタロシアニングリーンを顔料とするものがほとん
どであった。フタロシアニングリーンは銅フタロシアニ
ン環を高塩素化した化学構造をしており、環境中に放置
しても生分解性はほとんど期待できないばかりか、環境
中に多量の放置すれば重金属である銅による環境汚染の
原因となる等の問題点があった。又、塩素含有物質であ
るため焼却した場合はその条件によっては人体有害物質
を発生する可能性があった。[0003] In addition, pigments are chemically synthesized chemically stable, do not dissolve in water or organic solvents, and have excellent resistance to weathering and the like. Therefore, biodegradability when discarded is expected. It was impossible. In particular, the image of green as a color that represents environmental protection has become established in society, and many organizations operate under the name containing the words "green" and "green". The symbol mark colored in green is used. However, most of the green color of the printing ink uses phthalocyanine green as a pigment. Phthalocyanine Green has a chemical structure in which the copper phthalocyanine ring is highly chlorinated, so that it can hardly be expected to be biodegradable even when left in the environment. There were problems such as causing the problem. Moreover, since it is a chlorine-containing substance, there is a possibility that harmful substances may be generated depending on the conditions when incinerated.
【0004】一方、生分解性プラスチックは、微生物に
対する分解性を有し、合成樹脂フィルムに比較して環境
への負荷が小さい素材であるという特徴を生かしてゴミ
袋、レジ袋などへの用途開発が進められている。このよ
うな生分解性プラスチックフィルム製品は、環境対応型
であることが認定されると、そのシンボルマークが表面
に印刷されることがある。しかしながら、印刷の施され
た生分解性プラスチックフィルム製品を土中に廃棄した
場合、生分解性プラスチックフィルムは分解して消滅す
るが、印刷成分は生分解性がないため環境に蓄積されて
しまうという問題点を有していた。[0004] On the other hand, biodegradable plastics are degradable against microorganisms and have low environmental impact compared to synthetic resin films. Is being promoted. If such a biodegradable plastic film product is certified to be environmentally friendly, the symbol mark may be printed on the surface. However, when a printed biodegradable plastic film product is discarded in soil, the biodegradable plastic film decomposes and disappears, but the printing components are not biodegradable and accumulate in the environment. Had problems.
【0005】[0005]
【発明が解決しようとする課題】本発明は、印刷物が環
境に廃棄されても、環境汚染の心配のない印刷インキを
提供する。SUMMARY OF THE INVENTION The present invention provides a printing ink which does not cause environmental pollution even if the printed matter is discarded in the environment.
【0006】[0006]
【課題を解決するための手段】本発明は、天然色素を着
色剤成分とし、ゼインをバインダー成分とすることを特
徴とする印刷インキに関する。SUMMARY OF THE INVENTION The present invention relates to a printing ink comprising a natural pigment as a colorant component and zein as a binder component.
【0007】更に本発明は、天然色素がクロロフィリン
系色素である上記印刷インキに関する。Further, the present invention relates to the above printing ink, wherein the natural dye is a chlorophyllin dye.
【0008】更に本発明は、印刷インキが生分解性プラ
スチックフィルム印刷用である上記印刷インキに関す
る。。[0008] The present invention further relates to the above printing ink, wherein the printing ink is for printing biodegradable plastic films. .
【0009】[0009]
【発明の実施の形態】本発明の天然色素は、天然物由来
の色素であり、クロロフィリン色素、コチニール色素、
ラック色素、ベニコウジ色素、クチナシ色素、ウコン色
素、アナトー色素、コウリャン色素、シタン色素、アカ
ネ色素、イカスミ色素、ノルビキシンカリウム、ノルビ
キシンナトリウム、シコン色素などが挙げられる。なか
でも、クロロフィリンナトシウム、銅クロロフィリンナ
トリウム、鉄クロロフィリンナトリウム等のクロロフィ
リン色素は、防黴性、抗菌性も有しているため好適に用
いられる。BEST MODE FOR CARRYING OUT THE INVENTION The natural pigment of the present invention is a pigment derived from a natural product, and includes chlorophyllin pigment, cochineal pigment,
Examples include lac dyes, rhododendron dyes, gardenia dyes, turmeric dyes, annatto dyes, gourang dyes, rosewood dyes, madder dyes, cuttlefish dyes, norbixin potassium, norbixin sodium, and sicon dyes. Among them, chlorophyllin pigments such as chlorophyllin sodium, copper chlorophyllin sodium and iron chlorophyllin sodium are preferably used because they also have fungicidal properties and antibacterial properties.
【0010】本発明のゼインは、トウモロコシ或いはコ
ーングルテンミールを含水エタノールで抽出し、精製し
たものであり、たんぱく質を主成分とするものであり、
ゼインはたんぱく質からなるものなので環境中で容易に
生分解される。The zein of the present invention is obtained by extracting corn or corn gluten meal with ethanol containing water and purifying the zein, which contains protein as a main component.
Because zein is made of protein, it is easily biodegraded in the environment.
【0011】本発明の印刷インキに使用される溶剤は、
ゼインを溶解するものであれば制限されないが、エタノ
ール/水混合溶剤が好ましく使用される。エタノールと
水の混合比率は重量比でエタノール:水が90〜60:
10〜40であることが好ましい。The solvent used in the printing ink of the present invention is
There is no limitation as long as it dissolves zein, but an ethanol / water mixed solvent is preferably used. The mixing ratio of ethanol and water is 90-60:
It is preferably from 10 to 40.
【0012】本発明の印刷インキにはプロピレングリコ
ール、グリセリンなどのゼインに相溶性のある成分を配
合することができる。The printing ink of the present invention may contain zein-compatible components such as propylene glycol and glycerin.
【0013】本発明の印刷インキの各配合成分は、天然
色素3〜15重量%、ゼイン10〜30重量%、溶剤1
5〜70重量%、プロピレングリコールまたはグリセリ
ンを好ましくは0〜5重量%、更に好ましくは0.1〜
5重量%とすることが好ましい。Each of the components of the printing ink of the present invention comprises 3 to 15% by weight of a natural dye, 10 to 30% by weight of zein,
5 to 70% by weight, preferably 0 to 5% by weight of propylene glycol or glycerin, more preferably 0.1 to 5% by weight.
Preferably it is 5% by weight.
【0014】本発明に係る生分解性プラスチックとは、
ポリ(3−ヒドロキシブタン酸)、ポリ(3−ヒドロキ
シブタン酸−co−3−ヒドロキシ吉草酸)、ポリカプ
ロラクトン、ポリブチレンサクシネート、ポリ(ブチレ
ンサクシネート−co−アジペート)、ポリエチレンサ
クシネート、ポリ乳酸、ポリビニルアルコール、澱粉・
ポリビニルアルコール、澱粉/変性ポリビニルアルコー
ル等がある。本発明ではこれらの生分解性プラスチック
を10〜30μmにフィルム成形したものが使用され
る。The biodegradable plastic according to the present invention is:
Poly (3-hydroxybutanoic acid), poly (3-hydroxybutanoic acid-co-3-hydroxyvaleric acid), polycaprolactone, polybutylene succinate, poly (butylene succinate-co-adipate), polyethylene succinate, poly Lactic acid, polyvinyl alcohol, starch
Polyvinyl alcohol, starch / modified polyvinyl alcohol, and the like. In the present invention, those biodegradable plastics formed into a film of 10 to 30 μm are used.
【0015】本発明の印刷インキが採用できる印刷方式
は、グラビア方式、フレキソ方式、スタンプ方式等があ
る。The printing method in which the printing ink of the present invention can be used includes a gravure method, a flexo method, and a stamp method.
【0016】[0016]
【実施例】以下、実施例により本発明を説明する。例
中、部とは重量部を、%とは重量%をそれぞれ表わす。The present invention will be described below with reference to examples. In the examples, “parts” means “parts by weight” and “%” means “% by weight”.
【0017】 実施例1 銅クロロフィリンナトリウム 4部 水 12部 エタノール 70部 ゼイン 12部 プロピレングリコール 2部 以上の原料を混合、溶解して印刷インキを得た。Example 1 Copper chlorophyllin sodium 4 parts Water 12 parts Ethanol 70 parts Zein 12 parts Propylene glycol 2 parts The above ingredients were mixed and dissolved to obtain a printing ink.
【0018】この印刷インキを版新深25〜35μmの
グラビア印刷機にてポリブチレンサクシネートフィルム
上に印刷したところ、実用的な剥離強度に有する印刷物
を得た。When this printing ink was printed on a polybutylene succinate film using a gravure printing machine having a new plate depth of 25 to 35 μm, a printed material having practical peel strength was obtained.
【0019】 実施例2 イカスミ色素 8部 水 11部 エタノール 66.5部 ゼイン 12部 ダカグリセリンモノカプリレート 0.5部 プロピレングリコール 2部 以上の原料を混合、溶解して印刷インキを得た。Example 2 Ikasumi Dye 8 parts Water 11 parts Ethanol 66.5 parts Zein 12 parts Dakaglycerin monocaprylate 0.5 parts Propylene glycol 2 parts The above ingredients were mixed and dissolved to obtain a printing ink.
【0020】この印刷インキを版新深25〜35μmの
グラビア印刷機にてポリブチレンサクシネート−アジペ
ートフィルム上に印刷したところ、実用的な剥離強度に
有する印刷物を得た。When this printing ink was printed on a polybutylene succinate-adipate film by a gravure printing machine having a printing depth of 25 to 35 μm, a printed material having practical peel strength was obtained.
【0021】[0021]
【発明の効果】本発明の印刷インキは、天然物由来の着
色剤とバインダーを構成成分としているので、環境中に
廃棄されても印刷インキ成分が生分解される。したがっ
て、本発明の印刷インキを生分解性プラスチック製品用
の印刷インキとして使用した場合、生分解性プラスチッ
クの生分解とともに印刷インキ成分も生分解され、環境
への負荷を一層低減することができる。As described above, the printing ink of the present invention contains a colorant and a binder derived from a natural product as constituents, so that the printing ink component is biodegraded even when disposed in the environment. Therefore, when the printing ink of the present invention is used as a printing ink for a biodegradable plastic product, the printing ink component is biodegraded together with the biodegradation of the biodegradable plastic, and the burden on the environment can be further reduced.
Claims (3)
インダー成分とすることを特徴とする印刷インキ。1. A printing ink comprising a natural pigment as a colorant component and zein as a binder component.
請求項1記載の印刷インキ。2. The printing ink according to claim 1, wherein the natural dye is a chlorophyllin dye.
ルム印刷用である請求項1または2記載の印刷インキ。3. The printing ink according to claim 1, wherein the printing ink is for printing biodegradable plastic films.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000383036A JP2002179971A (en) | 2000-12-18 | 2000-12-18 | Printing ink |
Applications Claiming Priority (1)
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2004035699A1 (en) * | 2002-10-12 | 2004-04-29 | Avecia Limited | Ink comprising casein |
GB2413558A (en) * | 2002-10-12 | 2005-11-02 | Avecia Inkjet Ltd | Use of casein for improving ozone fastness of a colorant |
JP2006291061A (en) * | 2005-04-12 | 2006-10-26 | Toyo Ink Mfg Co Ltd | Marking method of egg, and marked egg |
WO2006120227A1 (en) * | 2005-05-13 | 2006-11-16 | Imaje S.A. | Ingestible or nutritional liquid ink composition for ink jet printing |
GB2456564A (en) * | 2008-01-18 | 2009-07-22 | Sun Chemical Ltd | Environmentally friendly printing ink compositions |
WO2020142888A1 (en) * | 2019-01-08 | 2020-07-16 | 上海交通大学 | Ink material used for 3d printing, preparation method and use |
JP2020117589A (en) * | 2019-01-22 | 2020-08-06 | 東洋インキScホールディングス株式会社 | Aqueous gravure ink and its usage |
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2000
- 2000-12-18 JP JP2000383036A patent/JP2002179971A/en active Pending
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004035699A1 (en) * | 2002-10-12 | 2004-04-29 | Avecia Limited | Ink comprising casein |
GB2408743A (en) * | 2002-10-12 | 2005-06-08 | Avecia Ltd | Ink comprising casein |
GB2413558A (en) * | 2002-10-12 | 2005-11-02 | Avecia Inkjet Ltd | Use of casein for improving ozone fastness of a colorant |
GB2408743B (en) * | 2002-10-12 | 2006-01-11 | Avecia Ltd | Process for improving ozone fastness |
JP2006291061A (en) * | 2005-04-12 | 2006-10-26 | Toyo Ink Mfg Co Ltd | Marking method of egg, and marked egg |
JP4696653B2 (en) * | 2005-04-12 | 2011-06-08 | 東洋インキ製造株式会社 | Egg marking method and marked egg |
FR2885619A1 (en) * | 2005-05-13 | 2006-11-17 | Imaje Sa Sa | LIQUID, FOOD, INGERABLE INK COMPOSITION FOR INKJET IMPRISONMENT |
WO2006120227A1 (en) * | 2005-05-13 | 2006-11-16 | Imaje S.A. | Ingestible or nutritional liquid ink composition for ink jet printing |
US8167990B2 (en) | 2005-05-13 | 2012-05-01 | Markem-Imaje | Ingestible or nutritional liquid ink composition for ink jet printing |
GB2456564A (en) * | 2008-01-18 | 2009-07-22 | Sun Chemical Ltd | Environmentally friendly printing ink compositions |
WO2020142888A1 (en) * | 2019-01-08 | 2020-07-16 | 上海交通大学 | Ink material used for 3d printing, preparation method and use |
JP2020117589A (en) * | 2019-01-22 | 2020-08-06 | 東洋インキScホールディングス株式会社 | Aqueous gravure ink and its usage |
JP7205246B2 (en) | 2019-01-22 | 2023-01-17 | 東洋インキScホールディングス株式会社 | Aqueous gravure ink and its use |
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