JP2002118128A - Electronic component and manufacturing method thereof - Google Patents

Electronic component and manufacturing method thereof

Info

Publication number
JP2002118128A
JP2002118128A JP2001216365A JP2001216365A JP2002118128A JP 2002118128 A JP2002118128 A JP 2002118128A JP 2001216365 A JP2001216365 A JP 2001216365A JP 2001216365 A JP2001216365 A JP 2001216365A JP 2002118128 A JP2002118128 A JP 2002118128A
Authority
JP
Japan
Prior art keywords
substrate
plasma processing
electronic component
plasma
adhesion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001216365A
Other languages
Japanese (ja)
Other versions
JP3671879B2 (en
Inventor
Hiroshi Haji
宏 土師
Seiji Sakami
省二 酒見
Isamu Morisako
勇 森迫
Naohito Yoshida
尚人 吉田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2001216365A priority Critical patent/JP3671879B2/en
Publication of JP2002118128A publication Critical patent/JP2002118128A/en
Application granted granted Critical
Publication of JP3671879B2 publication Critical patent/JP3671879B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L24/85Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/45099Material
    • H01L2224/451Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
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    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
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    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48225Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/48227Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item
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    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/484Connecting portions
    • H01L2224/48463Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
    • H01L2224/48465Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond the other connecting portion not on the bonding area being a wedge bond, i.e. ball-to-wedge, regular stitch
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    • H01L2224/85009Pre-treatment of the connector or the bonding area
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    • H01L2224/85009Pre-treatment of the connector or the bonding area
    • H01L2224/8501Cleaning, e.g. oxide removal step, desmearing
    • H01L2224/85013Plasma cleaning
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    • H01L2224/85Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • H01L2224/8538Bonding interfaces outside the semiconductor or solid-state body
    • H01L2224/85399Material
    • H01L2224/854Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
    • H01L2224/85438Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/85444Gold (Au) as principal constituent
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    • H01L2224/85Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • H01L2224/85909Post-treatment of the connector or wire bonding area
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    • H01L2924/00014Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
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    • H01L2924/151Die mounting substrate
    • H01L2924/1517Multilayer substrate
    • H01L2924/15172Fan-out arrangement of the internal vias
    • H01L2924/15174Fan-out arrangement of the internal vias in different layers of the multilayer substrate

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  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Wire Bonding (AREA)
  • Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for manufacturing electronic components by which the adhesion of sealing region can be improved and to provide electronic components. SOLUTION: With respect to the method for manufacturing an electronic component by which a semiconductor device 41 is mounted on a substrate 31, and the semiconductor device 41 and electrodes 32 of the substrate 31 are connected by wire bonding, substances inhibiting the bonding which are generated on the surface of gold films 32c formed on nickel films 32b on the copper electrodes 32a by the heating operations during the adhesion of the semiconductor device are removed by a first plasma treatment with an argon gas, and the wire bonding performance is improved consequently, After that, the surface of the resist 34 exhibiting adhesion with a resin molded part 45 deteriorated by the first plasma treatment is improved by a second plasma treatment by using oxygen gas plasma, and the adhesion between the sealing resin and the resin molded part 45 is improved consequently.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、電子部品製造方法
および電子部品に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electronic component manufacturing method and an electronic component.

【0002】[0002]

【従来の技術】電子部品の種類としてBGA(Ball
Grid Array)パッケージなどのように半導
体素子を基板上に搭載し、半導体素子を基板に形成され
た銅電極にワイヤボンディングによって電気的に接続す
る構造のものが知られている。ところでこの銅電極の表
面は、ワイヤボンディングに用いられる金ワイヤとの接
合性を確保するため基板の製造過程において金メッキさ
れる。この金メッキに先立ち、金メッキ後に銅が金メッ
キ層内へ拡散するのを防ぐ目的で、銅電極上にニッケル
を含むバリアメタル層が形成される。
2. Description of the Related Art BGA (Ball) is a type of electronic component.
2. Description of the Related Art A structure in which a semiconductor element is mounted on a substrate, such as a Grid Array package, and the semiconductor element is electrically connected to a copper electrode formed on the substrate by wire bonding is known. By the way, the surface of the copper electrode is plated with gold in the process of manufacturing the substrate in order to secure the bonding property with the gold wire used for wire bonding. Prior to the gold plating, a barrier metal layer containing nickel is formed on the copper electrode for the purpose of preventing copper from diffusing into the gold plating layer after the gold plating.

【0003】そして半導体素子を基板に搭載した後に
は、半導体素子を基板に接着する熱硬化性接着剤を硬化
させるため熱処理が行われる。このとき、メッキ工程で
金メッキ層中に混入したニッケルが金メッキ層の表面で
空気に触れることにより酸化膜などのニッケル化合物が
生成される。ところが、このニッケル化合物はワイヤボ
ンディング時に金ワイヤと金メッキ層の表面との接合を
阻害する。
[0003] After the semiconductor element is mounted on the substrate, a heat treatment is performed to cure a thermosetting adhesive for bonding the semiconductor element to the substrate. At this time, nickel mixed in the gold plating layer in the plating step comes into contact with air on the surface of the gold plating layer, thereby generating a nickel compound such as an oxide film. However, this nickel compound hinders the bonding between the gold wire and the surface of the gold plating layer during wire bonding.

【0004】そこでワイヤボンディングに先立って、こ
の接合阻害物を除去してワイヤボンディング時の接合性
を向上させる目的で基板の上面をプラズマ処理すること
が行われる。このプラズマ処理は、減圧雰囲気中でプラ
ズマを発生させ、アルゴンなどのイオンを電子部品の上
面に衝突させることにより、スパッタリング効果で金メ
ッキ層表面の接合阻害物を除去するものである。このと
き、接合阻害物を十分に除去するためには、金メッキ層
の表面を50〜100オングストローム程度の厚さで除
去することが必要とされる。
Therefore, prior to the wire bonding, the upper surface of the substrate is subjected to plasma treatment for the purpose of removing the bonding obstacle and improving the bonding property at the time of the wire bonding. In this plasma treatment, a plasma is generated in a reduced-pressure atmosphere, and ions such as argon collide with the upper surface of the electronic component, thereby removing a bonding inhibitor on the surface of the gold plating layer by a sputtering effect. At this time, it is necessary to remove the surface of the gold plating layer with a thickness of about 50 to 100 angstroms in order to sufficiently remove the bonding inhibitor.

【0005】[0005]

【発明が解決しようとする課題】ところで、ワイヤボン
ディング後の電子部品は樹脂封止工程に送られ、エポキ
シ樹脂などの樹脂によって封止され樹脂モールドが形成
される。この樹脂モールドは半導体素子やボンディング
ワイヤを樹脂で完全に包み込むことにより、外力による
ダメージや異物の侵入から電子部品を保護するためのも
のであり、封止に用いられる樹脂と基板との密着性が良
好であることが求められる。
By the way, the electronic component after the wire bonding is sent to a resin sealing step, where it is sealed with a resin such as an epoxy resin to form a resin mold. This resin mold completely protects semiconductor elements and bonding wires with resin to protect electronic components from damage due to external force and penetration of foreign substances. It is required to be good.

【0006】ところが、基板のレジストの材質によって
は封止樹脂との密着性が必ずしも良好でなく、封止後に
レジストと封止樹脂の接着面から剥離を生じる場合があ
る。このレジストと封止樹脂の密着性を阻害する要因と
して、前述のプラズマ処理の条件が関係していると推測
される。以下、封止樹脂と基板の密着性とプラズマ処理
条件との相関関係を見いだすために行った実験について
説明する。
However, depending on the material of the resist on the substrate, the adhesiveness with the sealing resin is not always good, and peeling may occur from the bonding surface between the resist and the sealing resin after sealing. It is presumed that the above-described conditions of the plasma processing are related to the factor that hinders the adhesion between the resist and the sealing resin. Hereinafter, an experiment performed to find a correlation between the adhesion between the sealing resin and the substrate and the plasma processing conditions will be described.

【0007】図10(a)、(b)は実験対象基板のレ
ジスト表面と封止樹脂の密着性を示すグラフ、図11
(a)は実験対象基板の平断面図、図11(b)は同側
断面図である。図10は、プラズマ発生用ガスとしてア
ルゴンガスを用いた場合の、基板のレジストと封止樹脂
の密着性と、プラズマ処理時間および高周波電源出力と
の関係を示したものである。図10(a)、および
(b)は、それぞれ高周波電源出力が50W、および5
00Wの場合の、密着性(縦軸)とプラズマ処理時間
(横軸)をグラフに示している。
FIGS. 10A and 10B are graphs showing the adhesion between the resist surface of the test object substrate and the sealing resin, and FIGS.
FIG. 11A is a plan sectional view of the test target substrate, and FIG. 11B is a side sectional view of the same. FIG. 10 shows the relationship between the adhesion between the resist on the substrate and the sealing resin, the plasma processing time, and the output of the high-frequency power supply when an argon gas is used as the plasma generating gas. FIGS. 10A and 10B show that the high-frequency power output is 50 W and 5 W, respectively.
In the case of 00 W, the graph shows the adhesion (vertical axis) and the plasma processing time (horizontal axis).

【0008】ここで、図11(a)、(b)を参照して
この実験で採用されている封止樹脂の密着性の評価方法
について説明する。図11(a)の電子部品の平面図に
おいて、基板1の表面にはリード状の電極2が形成され
ている。図11(b)の断面図に示すように基板1の表
面は電極2の表面も含めてレジスト3によって被覆され
ている。このレジスト3上に封止樹脂の樹脂モールド4
が形成される。この樹脂モールド4に外力が加えられた
場合には、樹脂モールド4は基板1の表面から剥離する
が、このとき樹脂モールド4とレジスト3の密着度によ
って、剥離の態様が異なる。
Here, a method for evaluating the adhesion of the sealing resin employed in this experiment will be described with reference to FIGS. 11 (a) and 11 (b). In the plan view of the electronic component in FIG. 11A, a lead-shaped electrode 2 is formed on the surface of the substrate 1. As shown in the cross-sectional view of FIG. 11B, the surface of the substrate 1 is covered with the resist 3 including the surface of the electrode 2. A resin mold 4 of a sealing resin is formed on the resist 3.
Is formed. When an external force is applied to the resin mold 4, the resin mold 4 peels off from the surface of the substrate 1, but at this time, the manner of peeling differs depending on the degree of adhesion between the resin mold 4 and the resist 3.

【0009】即ち、樹脂モールド4とレジスト3の密着
性が良好な場合には、樹脂モールド4に外力を加えた場
合の剥離面はレジスト3と基板1表面との接着面B(も
しくはレジスト3と電極2との接着面B’)となり、樹
脂モールド4とレジスト3の密着性が不良の場合には、
剥離は樹脂モールド4とレジスト3の接着面Cに発生す
る。ここで、基板1の表面とレジスト3の表面は色彩が
全く異なるので、外力を加えて樹脂モールド4を剥離さ
せたときに、どの接着面から剥離したかを目視により明
瞭に判別することができる。
That is, when the adhesiveness between the resin mold 4 and the resist 3 is good, the peeling surface when an external force is applied to the resin mold 4 becomes the adhesive surface B between the resist 3 and the surface of the substrate 1 (or the resist 3 When the adhesive surface between the resin mold 4 and the resist 3 is poor,
Peeling occurs on the bonding surface C between the resin mold 4 and the resist 3. Here, since the surface of the substrate 1 and the surface of the resist 3 are completely different in color, when the resin mold 4 is peeled off by applying an external force, it is possible to visually determine from which adhesive surface the resin mold 4 has been peeled off. .

【0010】したがって、全剥離面(図11(a)に鎖
線にて示すA)に占める接着面B(またはB’)の剥離
面の割合、もしくは接着面Cの剥離面の割合を観察する
ことにより、樹脂モールド4とレジスト3面との密着度
を判断することができる。図11(a)では、全剥離面
Aのうち、BまたはB’での剥離面(斜線部で示してお
り、電極2が露呈している)が約40%であり、その他
の部分ではレジスト3が基板1上に残留して電極2が覆
われたままとなっている。
Therefore, it is necessary to observe the ratio of the peeled surface of the adhesive surface B (or B ') or the ratio of the peeled surface of the adhesive surface C to the total peeled surface (A shown by a chain line in FIG. 11A). Thereby, the degree of adhesion between the resin mold 4 and the surface of the resist 3 can be determined. In FIG. 11 (a), of all the peeled surfaces A, the peeled surface at B or B '(shown by hatching and the electrode 2 is exposed) is about 40%, and the resist is 3 remains on the substrate 1 and the electrode 2 remains covered.

【0011】この実験では、前記剥離面の割合を目視に
より0から5までの6段階で評価している。剥離面の1
00%が接着面B,B’で剥離している場合(すなわ
ち、接着面Cは全く剥離しておらず、樹脂モールド4と
レジスト3の密着性が最良の場合)を評価5、100〜
80%を評価4、80〜50%を評価3、50〜20%
を評価2、20〜0%を評価1、0%を評価0と定義し
ている。図11(a)に示す例では、B、B’での剥離
面が約40%であり、したがって評価2となる。
In this experiment, the ratio of the peeled surface was visually evaluated on a scale of 0 to 5. Release surface 1
Evaluation of the case where 00% peeled off at the bonding surfaces B and B '(that is, the case where the bonding surface C was not peeled at all and the adhesion between the resin mold 4 and the resist 3 was the best) was evaluated.
80% evaluated 4, 80-50% evaluated 3, 50-20%
Is defined as evaluation 2, 20 to 0% as evaluation 1, and 0% as evaluation 0. In the example shown in FIG. 11A, the peeled surfaces at B and B ′ are about 40%, and accordingly, the evaluation is 2.

【0012】ここで再び図10に戻り、プラズマ処理に
よる接着面Cの剥離度合いの変化を説明する。図10
(a)に示すように、プラズマ処理を行わない場合には
接着面Cの密着度を示す剥離度合いは最悪の評価0であ
るが、高周波電源出力50Wで5秒程度プラズマ処理を
行うことにより評価は5まで上昇する。そしてプラズマ
処理を30秒継続して行った場合でもこの結果は変わら
ない。
Here, returning to FIG. 10 again, the change in the degree of peeling of the bonding surface C due to the plasma processing will be described. FIG.
As shown in (a), when the plasma processing is not performed, the peeling degree indicating the degree of adhesion of the bonding surface C is the worst evaluation 0, but is evaluated by performing the plasma processing for about 5 seconds at a high frequency power output of 50 W. Rises to 5. This result does not change even when the plasma processing is performed continuously for 30 seconds.

【0013】これに対し、図10(b)に示す高周波電
源出力が500Wの例では、プラズマ処理を行わない場
合に評価0であったサンプルが、プラズマ処理時間5秒
程度で評価5まで上昇する点では高周波電源出力50W
の場合と同様であるが、高周波電源出力500Wの場合
にはプラズマ処理時間が10秒程度になると評価は急激
に低下し0となる。すなわち、ある程度以上の出力で所
定時間以上プラズマ処理を行うと樹脂モールド4とレジ
スト3の密着性は悪化する。なお、プラズマ処理の条件
を変えることにより、どのようなメカニズムで密着性に
悪影響を及ぼすかについてはまだ明確に解明されていな
い。
On the other hand, in the example shown in FIG. 10B in which the high-frequency power supply output is 500 W, the sample which was evaluated 0 when the plasma processing was not performed rises to the evaluation 5 in about 5 seconds of the plasma processing time. In terms of high frequency power output 50W
However, in the case of the high-frequency power supply output of 500 W, the evaluation drops sharply to 0 when the plasma processing time is about 10 seconds. That is, if the plasma processing is performed for a predetermined time or more with an output of a certain level or more, the adhesion between the resin mold 4 and the resist 3 deteriorates. The mechanism by which the conditions of the plasma treatment are changed to adversely affect the adhesiveness has not yet been clearly elucidated.

【0014】これらの結果から、樹脂モールド4とレジ
スト3の密着性を確保するためにはプラズマ処理の条件
を低出力もしくは高出力・短時間に限定すればよいよう
に見えるが、しかしながら、樹脂モールド4とレジスト
3の密着性が低下しないプラズマ処理条件(図10
(a)の例)では、高周波電源出力が不足しているため
スパッタリング効果が小さく、プラズマ処理の目的であ
る電極2上の接合阻害物の除去という目的が達成できな
い。
From these results, it seems that in order to secure the adhesion between the resin mold 4 and the resist 3, it is sufficient to limit the conditions of the plasma processing to low output or high output for a short time. Plasma treatment conditions under which the adhesion between the resist 4 and the resist 3 does not decrease (FIG. 10)
In example (a), the output of the high-frequency power supply is insufficient, so that the sputtering effect is small, and the object of the plasma treatment, that is, the removal of the bonding obstacle on the electrode 2 cannot be achieved.

【0015】そして、この接合阻害物除去のために十分
な高周波電源出力の条件、すなわち500W、10秒以
上(図10(b)の例)では、上述のように樹脂モール
ド4を形成する封止樹脂とレジスト3面の密着性が阻害
される。このように、従来の電子部品製造方法では、電
極2上の接合阻害物除去のためのプラズマ処理を行うと
基板1のレジスト3と樹脂モールド4の密着性が低下
し、樹脂封止後に剥離を生じることがあるという問題点
があった。
Under the condition of high-frequency power output sufficient for removing the joining obstacle, that is, 500 W, 10 seconds or more (example of FIG. 10B), the sealing for forming the resin mold 4 as described above is performed. Adhesion between the resin and the resist 3 surface is hindered. As described above, in the conventional electronic component manufacturing method, when plasma processing is performed to remove a bonding inhibitor on the electrode 2, the adhesion between the resist 3 on the substrate 1 and the resin mold 4 is reduced, and peeling after resin sealing is performed. There is a problem that it may occur.

【0016】そこで本発明は、基板のレジストと樹脂モ
ールドとの密着性を向上させることができる電子部品製
造方法および電子部品を提供することを目的とする。
Accordingly, an object of the present invention is to provide an electronic component manufacturing method and an electronic component that can improve the adhesion between a resist on a substrate and a resin mold.

【0017】[0017]

【課題を解決するための手段】請求項1記載の電子部品
製造方法は、基板に半導体素子を搭載して両者を電気的
に接続し、その後基板上の半導体素子を樹脂封止する電
子部品製造方法であって、基板の電極表面上の接合阻害
物をスパッタリングにより除去する第1のプラズマ処理
工程と、前記第1のプラズマ処理後の基板のレジスト表
面を改質する第2のプラズマ処理工程とを含み、前記第
1のプラズマ処理工程は、少なくとも基板と半導体素子
とを電気的に接続する前に行い、前記第2のプラズマ処
理工程は第1のプラズマ処理を行った後、樹脂封止を行
う前に行うようにした。
According to a first aspect of the present invention, there is provided a method of manufacturing an electronic component, comprising mounting a semiconductor element on a substrate, electrically connecting the two, and then sealing the semiconductor element on the substrate with a resin. A first plasma processing step of removing a bonding inhibitor on an electrode surface of a substrate by sputtering, and a second plasma processing step of modifying a resist surface of the substrate after the first plasma processing. The first plasma processing step is performed at least before electrical connection between the substrate and the semiconductor element, and the second plasma processing step is performed after performing the first plasma processing, and then performing resin sealing. It was done before doing.

【0018】請求項2記載の電子部品製造方法は、請求
項1記載の電子部品製造方法であって、前記第2のプラ
ズマ処理工程において、酸素、塩素、臭素もしくはフッ
素の少なくとも1つ以上を含んだガスを用いたプラズマ
で基板のレジスト表面を改質するようにした。
According to a second aspect of the present invention, there is provided the electronic component manufacturing method according to the first aspect, wherein the second plasma processing step includes at least one of oxygen, chlorine, bromine, and fluorine. The resist surface of the substrate is modified by plasma using a gas.

【0019】請求項3記載の電子部品は、基板に半導体
素子を搭載して両者を電気的に接続し、その後基板上の
半導体素子を樹脂封止して成る電子部品であって、基板
の電極表面上の接合阻害物をスパッタリングにより除去
する第1のプラズマ処理工程と、前記第1のプラズマ処
理後の基板のレジスト表面を改質する第2のプラズマ処
理工程とを含み、前記第1のプラズマ処理工程は、少な
くとも基板と半導体素子とを電気的に接続する前に行
い、前記第2のプラズマ処理工程は第1のプラズマ処理
を行った後、樹脂封止を行う前に行う電子部品製造方法
によって製造された。
According to a third aspect of the present invention, there is provided an electronic component comprising a semiconductor element mounted on a substrate, electrically connecting the two, and then sealing the semiconductor element on the substrate with a resin. A first plasma processing step of removing a bonding inhibitor on a surface by sputtering, and a second plasma processing step of modifying a resist surface of the substrate after the first plasma processing, wherein the first plasma The processing step is performed at least before electrical connection between the substrate and the semiconductor element, and the second plasma processing step is performed after performing the first plasma processing and before performing resin sealing. Manufactured by.

【0020】本発明によれば、基板の電極の金膜表面に
生成された接合阻害物をスパッタリングにより除去する
第1のプラズマ処理後に、基板のレジスト表面を改質す
る第2のプラズマ処理工程を設けることにより、ワイヤ
ボンディング後に行われる樹脂封止時の、基板のレジス
ト表面と封止樹脂との密着性を向上させることができ
る。
According to the present invention, after the first plasma treatment for removing a bonding inhibitor generated on the gold film surface of the electrode of the substrate by sputtering, the second plasma treatment step for modifying the resist surface of the substrate is performed. By providing this, it is possible to improve the adhesion between the resist surface of the substrate and the sealing resin during resin sealing performed after wire bonding.

【0021】[0021]

【発明の実施の形態】(実施の形態1)図1は本発明の
実施の形態1の電子部品のプラズマ処理装置の断面図、
図2、図3、図4は本発明の実施の形態1の電子部品の
断面図、図5は本発明の実施の形態1の基板のレジスト
表面と封止樹脂との密着性を示すグラフ、図6、図7、
図8は本発明の実施の形態1の電子部品の断面図であ
る。
(Embodiment 1) FIG. 1 is a sectional view of an electronic component plasma processing apparatus according to Embodiment 1 of the present invention.
2, 3, and 4 are cross-sectional views of an electronic component according to the first embodiment of the present invention. FIG. 5 is a graph illustrating adhesion between a resist surface of a substrate and a sealing resin according to the first embodiment of the present invention. 6, 7,
FIG. 8 is a sectional view of the electronic component according to the first embodiment of the present invention.

【0022】まず図1を参照して電子部品のプラズマ処
理装置について説明する。図1において、真空チャンバ
11は上部ケーシング12および下部ケーシング13に
より形成される。下部ケーシング13の内部には、下部
電極14が配設されており、下部電極14上には基板と
半導体素子より成る電子部品15が載置される。下部電
極14は高周波電源16と接続されており、高周波電源
16は高周波電源制御部17によって制御される。また
上部ケーシング12には上部電極18が装着され、上部
電極18は接地部19に接続された接地電極となってい
る。
First, a plasma processing apparatus for electronic components will be described with reference to FIG. In FIG. 1, a vacuum chamber 11 is formed by an upper casing 12 and a lower casing 13. A lower electrode 14 is provided inside the lower casing 13, and an electronic component 15 including a substrate and a semiconductor element is mounted on the lower electrode 14. The lower electrode 14 is connected to a high-frequency power supply 16, which is controlled by a high-frequency power control unit 17. An upper electrode 18 is mounted on the upper casing 12, and the upper electrode 18 is a ground electrode connected to a grounding portion 19.

【0023】下部ケーシング13には、真空排気部2
0、第1のガス供給部21、第2のガス供給部22およ
び大気開放弁23がそれぞれ管路により接続されてい
る。真空排気部20は真空チャンバ11内を吸引し、排
気する。第1のガス供給部21、第2のガス供給部22
はプラズマガス供給手段であり、それぞれ異る種類のプ
ラズマ発生用ガスを真空チャンバ11に供給する。大気
開放弁23は真空チャンバ11内に大気を導入し、真空
を破壊する。制御部24は、真空排気部20、第1のガ
ス供給部21、第2のガス供給部22、大気開放弁23
および高周波電源制御部17を制御する。
The lower casing 13 has a vacuum exhaust unit 2
0, a first gas supply unit 21, a second gas supply unit 22, and an atmosphere release valve 23 are respectively connected by pipes. The vacuum exhaust unit 20 sucks and exhausts the inside of the vacuum chamber 11. First gas supply unit 21, second gas supply unit 22
Is a plasma gas supply means for supplying different types of plasma generation gases to the vacuum chamber 11. The atmosphere release valve 23 introduces the atmosphere into the vacuum chamber 11 and breaks the vacuum. The control unit 24 includes a vacuum exhaust unit 20, a first gas supply unit 21, a second gas supply unit 22, an atmosphere release valve 23
And the high-frequency power supply controller 17.

【0024】この電子部品のプラズマ処理装置は上記の
様に構成されており、以下この電子部品のプラズマ処理
装置を使用した電子部品製造方法について各図を参照し
て説明する。図2において、基板31の上面には電極3
2が、また下面には電極33が形成されており、基板3
1の表面はエポキシ樹脂などの樹脂より成るレジスト3
4で被覆されている。電極32は銅電極32a上にバリ
アメタル層としてニッケル膜32bをニッケルメッキに
よりコーティングし、更にニッケル膜32bの上面に金
膜32cを金メッキによりコーティングして形成されて
いる。また電極33も同様に銅電極33a、ニッケル膜
33bおよび金膜33cより成る。電極32と電極33
は、内部回路37によって接続されている。
The plasma processing apparatus for an electronic component is configured as described above. Hereinafter, a method for manufacturing an electronic component using the plasma processing apparatus for an electronic component will be described with reference to the drawings. In FIG. 2, an electrode 3 is provided on the upper surface of a substrate 31.
2 and an electrode 33 is formed on the lower surface.
The surface of the resist 1 is made of a resin such as an epoxy resin.
4. The electrode 32 is formed by coating a nickel film 32b as a barrier metal layer on the copper electrode 32a by nickel plating, and further coating a gold film 32c on the upper surface of the nickel film 32b by gold plating. The electrode 33 also includes a copper electrode 33a, a nickel film 33b, and a gold film 33c. Electrode 32 and electrode 33
Are connected by an internal circuit 37.

【0025】次に図3に示すように、基板31上に半導
体素子41が基板31上面に予め塗布された接着剤42
によって接着される。接着剤42は熱硬化型であり、半
導体素子41が搭載された基板31を熱処理することに
より接着剤42は硬化し、半導体素子41は基板31に
固定される。
Next, as shown in FIG. 3, a semiconductor element 41 is provided on the substrate 31 with an adhesive 42 applied on the upper surface of the substrate 31 in advance.
Glued by The adhesive 42 is a thermosetting type, and the adhesive 42 is cured by heat-treating the substrate 31 on which the semiconductor element 41 is mounted, and the semiconductor element 41 is fixed to the substrate 31.

【0026】図4はこの熱処理後の基板31の電極3
2,33の断面図である。金膜32c,33c表面には
ニッケル化合物35,36が生じている。このニッケル
化合物35,36は、メッキ工程で金膜32c,33c
中に混入したニッケルのうち、金膜32cの表層付近に
あるものが、熱処理中に金膜32c,33cの表面で空
気と接触することによって生じるものである。このニッ
ケル化合物35、36のうち、上面の電極32上のニッ
ケル化合物35は後工程のワイヤボンディングにおい
て、金ワイヤと金膜32cとの接合性を阻害する。
FIG. 4 shows the electrode 3 of the substrate 31 after this heat treatment.
It is sectional drawing of 2,33. Nickel compounds 35 and 36 are formed on the surfaces of the gold films 32c and 33c. The nickel compounds 35 and 36 are used as gold films 32c and 33c in the plating process.
Of the nickel mixed in, the one near the surface layer of the gold film 32c is generated by coming into contact with air on the surfaces of the gold films 32c and 33c during the heat treatment. Among the nickel compounds 35 and 36, the nickel compound 35 on the electrode 32 on the upper surface hinders the bondability between the gold wire and the gold film 32c in the wire bonding in a later step.

【0027】次にこの接合性阻害物であるニッケル化合
物35を除去するため、第1のプラズマ処理が行われ
る。基板31を半導体素子41の面を上向きにして図1
に示す真空チャンバ11内の下部電極14上に載置す
る。真空チャンバ11を閉じた後、真空排気部20を駆
動して真空チャンバ11内を真空排気する。次いで第1
のガス供給部21を駆動して真空チャンバ11内にプラ
ズマ発生用のアルゴンガスを供給する。この後高周波電
源16を駆動して下部電極14に高周波電圧を印加する
ことにより、真空チャンバ11内にプラズマ放電を発生
させる。これにより真空チャンバ11内にはプラズマが
発生し、この結果アルゴンイオンや電子が電子部品15
の上面に衝突する。
Next, a first plasma treatment is performed in order to remove the nickel compound 35 which is a bonding inhibitor. FIG. 1 shows the semiconductor device 41 with the substrate 31 facing upward.
Is placed on the lower electrode 14 in the vacuum chamber 11 shown in FIG. After closing the vacuum chamber 11, the vacuum exhaust unit 20 is driven to evacuate the vacuum chamber 11. Then the first
Is driven to supply an argon gas for plasma generation into the vacuum chamber 11. Thereafter, the high-frequency power supply 16 is driven to apply a high-frequency voltage to the lower electrode 14, thereby generating a plasma discharge in the vacuum chamber 11. As a result, plasma is generated in the vacuum chamber 11, and as a result, argon ions and electrons are generated in the electronic component 15.
Collides with the upper surface of.

【0028】この第1のプラズマ処理における処理条件
は、プラズマ発生用ガスとしてのアルゴンガスの流量が
5cc/min、真空チャンバ11内のプラズマ発生用
ガスの圧力が10Pa、高周波電源出力が500W、プ
ラズマ処理時間は10秒である。このプラズマ処理によ
り電極32の表面のニッケル化合物35は除去される
が、前述のようにこのままの状態では封止樹脂とレジス
ト34表面との密着性が悪く、封止のための樹脂モール
ド形成後に剥離を生じやすい。
The processing conditions in the first plasma processing are as follows: the flow rate of argon gas as a plasma generating gas is 5 cc / min, the pressure of the plasma generating gas in the vacuum chamber 11 is 10 Pa, the high frequency power output is 500 W, the plasma Processing time is 10 seconds. Although the nickel compound 35 on the surface of the electrode 32 is removed by this plasma treatment, the adhesion between the sealing resin and the surface of the resist 34 is poor in this state as described above. Tends to occur.

【0029】そこで、引き続き基板31の表面を改質す
るための第2のプラズマ処理を行う。この第2のプラズ
マ処理における処理条件は、プラズマ発生用ガスとして
第2のガス供給部22から供給される酸素ガスを用い、
酸素ガス流量が50cc/min、真空チャンバ11内
のプラズマ発生用ガスの圧力が30Pa、高周波電源出
力が20W、である。この条件で第二のプラズマ処理を
行った場合の樹脂モールド4の密着性確認のための実験
の結果を図5に示す。
Then, a second plasma process for modifying the surface of the substrate 31 is performed. The processing conditions in the second plasma processing use oxygen gas supplied from the second gas supply unit 22 as a plasma generation gas,
The oxygen gas flow rate is 50 cc / min, the pressure of the plasma generating gas in the vacuum chamber 11 is 30 Pa, and the high frequency power output is 20 W. FIG. 5 shows the results of an experiment for confirming the adhesion of the resin mold 4 when the second plasma treatment was performed under these conditions.

【0030】図5に示すように、第1のプラズマ処理を
行っただけのサンプルでは、密着性の評価は0であり樹
脂モールド4とレジスト3の密着性は悪いが、酸素ガス
による第2のプラズマ処理を5秒行うと、密着性の評価
は5に上昇する。そして同一条件で処理時間を30秒ま
で延長しても密着性の評価は変わらない。このように、
第1のプラズマ処理によって密着性が低下した基板31
の表面に上述の条件で第2のプラズマ処理を行うことに
より、基板31のレジスト34の表面が改質され後工程
での樹脂モールドとの密着性を向上させることができ
る。
As shown in FIG. 5, in the sample subjected to only the first plasma treatment, the evaluation of the adhesiveness is 0, and the adhesiveness between the resin mold 4 and the resist 3 is poor. When the plasma treatment is performed for 5 seconds, the evaluation of the adhesion increases to 5. Even if the processing time is extended to 30 seconds under the same conditions, the evaluation of the adhesion does not change. in this way,
Substrate 31 having reduced adhesion due to first plasma processing
By performing the second plasma treatment on the surface of the substrate under the above-described conditions, the surface of the resist on the substrate 31 is modified, and the adhesion to the resin mold in a later step can be improved.

【0031】次に図6に示すように、電子部品5はワイ
ヤボンディング装置に送られ、半導体素子41の電極4
3と基板31の電極32を金ワイヤ44で接続する。こ
れにより、半導体41と電極32が電気的に接続され
る。このとき、電極32の金膜32cの表面は第1のプ
ラズマ処理によりニッケル化合物の接合阻害物が除去さ
れているので、金ワイヤ44は電極32上に良好にボン
ディングされる。
Next, as shown in FIG. 6, the electronic component 5 is sent to a wire bonding apparatus,
3 and the electrode 32 of the substrate 31 are connected by a gold wire 44. Thereby, the semiconductor 41 and the electrode 32 are electrically connected. At this time, since the surface of the gold film 32 c of the electrode 32 has been subjected to the first plasma treatment to remove the bonding inhibitor of the nickel compound, the gold wire 44 is favorably bonded onto the electrode 32.

【0032】次に電子部品15は樹脂封止される。図7
に示すように、半導体素子41と金ワイヤ44はエポキ
シ樹脂によって封止され樹脂モールド45が形成され
る。このとき、基板31のレジスト34の表面は第2の
プラズマ処理によって改質されているので、封止樹脂で
あるエポキシ樹脂との密着性が改善されており、密着性
のよい良好な耐剥離性を有する樹脂モールド45を形成
することができる。
Next, the electronic component 15 is sealed with a resin. FIG.
As shown in (1), the semiconductor element 41 and the gold wire 44 are sealed with an epoxy resin to form a resin mold 45. At this time, since the surface of the resist 34 on the substrate 31 has been modified by the second plasma treatment, the adhesion with the epoxy resin as the sealing resin is improved, and the separation resistance is good with good adhesion. Can be formed.

【0033】この後、図8に示すように基板31の下面
の電極33上に半田バンプ46が形成されて電子部品1
5が完成する。このとき、電極33の金膜33cの表面
にはニッケル化合物が存在しているが、半田バンプ46
の形成に際してはフラックス47が塗布されてニッケル
化合物は還元されるため半田接合性を損なうことはな
い。なお実施の形態1では、第2のプラズマ処理のプラ
ズマ発生用ガスとして酸素を用いているが、塩素やフッ
素、臭素を用いてもよく、またはこれらを混合したもの
でも良い。
Thereafter, as shown in FIG. 8, a solder bump 46 is formed on the electrode 33 on the lower surface of the substrate 31 so that the electronic component 1
5 is completed. At this time, although the nickel compound exists on the surface of the gold film 33c of the electrode 33, the solder bump 46
When the flux 47 is formed, the flux 47 is applied and the nickel compound is reduced, so that the soldering property is not impaired. Note that in Embodiment 1, oxygen is used as the plasma generation gas in the second plasma treatment, but chlorine, fluorine, or bromine may be used, or a mixture of these may be used.

【0034】(実施の形態2)図9は本発明の実施の形
態2の電子部品のプラズマ処理装置の断面図である。こ
こで図1に示す実施の形態1と同様の要素には同符号を
付して説明を省略する。本実施の形態2では、プラズマ
ガス供給手段として、ガス供給部50と流量制御部51
を備えている。すなわち、プラズマガス発生用ガスの種
類は1つであり、このガスの真空チャンバ11への供給
流量を制御部24により制御するようになっている。
(Embodiment 2) FIG. 9 is a sectional view of a plasma processing apparatus for electronic components according to Embodiment 2 of the present invention. Here, the same elements as those of the first embodiment shown in FIG. In the second embodiment, as the plasma gas supply means, the gas supply unit 50 and the flow control unit 51
It has. That is, the type of the plasma gas generating gas is one, and the flow rate of the gas supplied to the vacuum chamber 11 is controlled by the control unit 24.

【0035】次に本実施の形態2の電子部品の製造方法
について説明する。ここで基板31上に半導体素子41
を搭載する工程までは、実施の形態1の図2〜図4に示
す工程と同様である。この後に行われる第1および第2
のプラズマ処理について説明する。図9において、真空
チャンバ1内に電子部品15を搬入した後、真空チャン
バ11内にはプラズマ発生用ガスとして酸素ガスが供給
される。次いで高周波電源16を駆動して下部電極14
に高周波電圧を印加することにより、真空チャンバ11
内には酸素のプラズマが発生し、発生した酸素イオンや
酸素ラジカルのスパッタリング効果により電子部品15
の表面のプラズマ処理を行う。この第1のプラズマ処理
で適用される処理条件は、電極32の金膜32c上面の
ニッケル化合物を除去するのに十分なスパッタリング効
果を生じるプラズマ処理条件であり、この結果電極32
の金膜32c表面のニッケル化合物43が除去される。
Next, a method for manufacturing an electronic component according to the second embodiment will be described. Here, the semiconductor element 41 is provided on the substrate 31.
The steps up to the step of mounting are the same as the steps shown in FIGS. The first and second
Will be described. In FIG. 9, after the electronic component 15 is carried into the vacuum chamber 1, oxygen gas is supplied into the vacuum chamber 11 as a plasma generating gas. Next, the high frequency power supply 16 is driven to drive the lower electrode 14.
By applying a high-frequency voltage to the vacuum chamber 11
Oxygen plasma is generated inside the electronic component 15 due to the sputtering effect of generated oxygen ions and oxygen radicals.
Of the surface of is performed. The processing conditions applied in the first plasma processing are plasma processing conditions that produce a sputtering effect sufficient to remove the nickel compound on the upper surface of the gold film 32c of the electrode 32. As a result, the electrode 32
The nickel compound 43 on the surface of the gold film 32c is removed.

【0036】次に、基板31の表面を改質するための第
2のプラズマ処理が行われる。ここではプラズマ発生用
ガスとして引き続き酸素ガスが使用されるが、酸素ガス
の流量が流量制御弁51によって制御され、第1のプラ
ズマ処理時のガス供給量より少ない流量のガスが真空チ
ャンバ11に供給される。また高周波電源16の出力も
第1のプラズマ処理よりも低い処理条件に設定され、具
体的には、実施の形態1における第2のプラズマ処理の
条件と同様である。
Next, a second plasma treatment for modifying the surface of the substrate 31 is performed. Here, oxygen gas is continuously used as the plasma generation gas. The flow rate of the oxygen gas is controlled by the flow control valve 51, and a gas having a flow rate smaller than the gas supply amount during the first plasma processing is supplied to the vacuum chamber 11. Is done. The output of the high-frequency power supply 16 is also set to a processing condition lower than that of the first plasma processing, and specifically, is the same as the condition of the second plasma processing in the first embodiment.

【0037】これにより、実施の形態1と同様に基板3
1のレジスト34の表面が改質され、樹脂封止時のエポ
キシ樹脂との密着性が向上する。なお、プラズマ発生用
ガスとして本実施の形態2では酸素を用いているが、塩
素やフッ素、臭素を用いてもよく、またはこれらを混合
したものを用いることもできる。これ以降の工程につい
ては、実施の形態1と同様である。
Thus, as in the first embodiment, the substrate 3
The surface of the first resist 34 is modified, and the adhesion to the epoxy resin during resin sealing is improved. Although oxygen is used as the plasma generation gas in the second embodiment, chlorine, fluorine, or bromine may be used, or a mixture of these may be used. The subsequent steps are the same as in the first embodiment.

【0038】本発明は上記実施の形態1、2に限定され
ないのであって、例えば上記実施の形態1、2では第1
および第2のプラズマ処理を同一のプラズマ処理装置を
用いて連続して行うようにしているが、これらを分離し
1つのプラズマ処理装置にて第1のプラズマ処理を行
い、その後ワイヤボンディングを行った後に他のプラズ
マ処理装置にて第2のプラズマ処理を行うようにしても
よい。このようにすることにより、プラズマ処理条件を
その都度切り換える必要がなく、連続して効率よくプラ
ズマ処理を行うことができる。さらに、基板と半導体素
子を電気的に接続する工程として、ワイヤボンディング
を例に説明したが、ワイヤ以外の接合材(半田、導電性
接着材、異方性導電材等)を使用したフェイスダウンボ
ンディングでもよい。
The present invention is not limited to the first and second embodiments. For example, in the first and second embodiments, the first
And the second plasma processing are continuously performed using the same plasma processing apparatus. However, these are separated, the first plasma processing is performed in one plasma processing apparatus, and then the wire bonding is performed. The second plasma processing may be performed later by another plasma processing apparatus. By doing so, it is not necessary to switch the plasma processing conditions each time, and the plasma processing can be continuously and efficiently performed. Further, wire bonding has been described as an example of a process for electrically connecting a substrate and a semiconductor element. However, face-down bonding using a bonding material other than wires (solder, conductive adhesive, anisotropic conductive material, etc.) May be.

【0039】[0039]

【発明の効果】本発明によれば、基板の電極の金膜表面
に生成された接合阻害物をスパッタリングにより除去す
る第1のプラズマ処理後に、基板のレジスト表面を改質
する第2のプラズマ処理工程を設けるようにしたので、
電極のワイヤボンディング性の向上目的に行われる第1
のプラズマ処理によって基板のレジスト表面が過剰処理
された場合でも、基板のレジストの樹脂材料に応じて第
2のプラズマ処理の条件を適切に設定することにより、
基板のレジストと封止樹脂との密着性を向上させること
ができる。したがって従来は電極上の接合阻害物除去の
ためのプラズマ処理後に密着性が低下することを理由と
して選択することができなかった材質でも、第2のプラ
ズマ条件の設定によって選択が可能となり、基板や封止
材の樹脂材料の選択の自由度を拡大することができる。
According to the present invention, after the first plasma treatment for removing the bonding inhibitor generated on the surface of the gold film of the electrode of the substrate by sputtering, the second plasma treatment for modifying the resist surface of the substrate. Since we set up a process,
The first is performed for the purpose of improving the wire bonding property of the electrode.
Even if the resist surface of the substrate is excessively treated by the plasma treatment, by appropriately setting the conditions of the second plasma treatment according to the resin material of the resist of the substrate,
The adhesion between the resist on the substrate and the sealing resin can be improved. Therefore, even a material which could not be selected conventionally because the adhesion is reduced after the plasma treatment for removing the bonding inhibitor on the electrode can be selected by setting the second plasma condition, and the substrate and the The degree of freedom in selecting a resin material for the sealing material can be increased.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の形態1の電子部品のプラズマ処
理装置の断面図
FIG. 1 is a cross-sectional view of an electronic component plasma processing apparatus according to a first embodiment of the present invention.

【図2】本発明の実施の形態1の電子部品の断面図FIG. 2 is a cross-sectional view of the electronic component according to the first embodiment of the present invention.

【図3】本発明の実施の形態1の電子部品の断面図FIG. 3 is a cross-sectional view of the electronic component according to the first embodiment of the present invention.

【図4】本発明の実施の形態1の電子部品の断面図FIG. 4 is a cross-sectional view of the electronic component according to the first embodiment of the present invention.

【図5】本発明の実施の形態1の基板のレジスト表面と
封止樹脂の密着性を示すグラフ
FIG. 5 is a graph showing the adhesion between the resist surface of the substrate and the sealing resin according to the first embodiment of the present invention.

【図6】本発明の実施の形態1の電子部品の断面図FIG. 6 is a sectional view of the electronic component according to the first embodiment of the present invention.

【図7】本発明の実施の形態1の電子部品の断面図FIG. 7 is a sectional view of the electronic component according to the first embodiment of the present invention.

【図8】本発明の実施の形態1の電子部品の断面図FIG. 8 is a sectional view of the electronic component according to the first embodiment of the present invention.

【図9】本発明の実施の形態2の電子部品のプラズマ処
理装置の断面図
FIG. 9 is a sectional view of a plasma processing apparatus for an electronic component according to a second embodiment of the present invention.

【図10】(a)実験対象基板のレジスト表面と封止樹
脂の密着性を示すグラフ (b)実験対象基板のレジスト表面と封止樹脂の密着性
を示すグラフ
10A is a graph showing the adhesion between the resist surface of the test target substrate and the sealing resin, and FIG. 10B is a graph showing the adhesion between the resist surface of the test target substrate and the sealing resin.

【図11】(a)実験対象基板の平断面図 (b)実験対象基板の側断面図FIG. 11A is a cross-sectional plan view of the test target substrate. FIG.

【符号の説明】 11 真空チャンバ 14 下部電極 15 電子部品 16 高周波電源 17 高周波電源制御部 20 真空排気部 21 第1のガス供給部 22 第2のガス供給部 31 基板 32、33 電極 34 レジスト 32a、33a 銅電極 32b、33b ニッケル膜 32c、33c 金膜 35、36 ニッケル化合物 41 半導体素子 44 金ワイヤ 45 樹脂モールドDESCRIPTION OF SYMBOLS 11 Vacuum chamber 14 Lower electrode 15 Electronic component 16 High frequency power supply 17 High frequency power supply control unit 20 Vacuum exhaust unit 21 First gas supply unit 22 Second gas supply unit 31 Substrate 32, 33 Electrode 34 Resist 32a, 33a Copper electrode 32b, 33b Nickel film 32c, 33c Gold film 35, 36 Nickel compound 41 Semiconductor element 44 Gold wire 45 Resin mold

───────────────────────────────────────────────────── フロントページの続き (72)発明者 森迫 勇 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 (72)発明者 吉田 尚人 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 Fターム(参考) 5F044 AA03 CC01 CC02 JJ03 5F061 AA01 BA03 CB02 CB12  ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Isamu Morisako 1006 Kadoma Kadoma, Osaka Prefecture Inside Matsushita Electric Industrial Co., Ltd. F term (reference) 5F044 AA03 CC01 CC02 JJ03 5F061 AA01 BA03 CB02 CB12

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】基板に半導体素子を搭載して両者を電気的
に接続し、その後基板上の半導体素子を樹脂封止する電
子部品製造方法であって、基板の電極表面上の接合阻害
物をスパッタリングにより除去する第1のプラズマ処理
工程と、前記第1のプラズマ処理後の基板のレジスト表
面を改質する第2のプラズマ処理工程とを含み、前記第
1のプラズマ処理工程は、少なくとも基板と半導体素子
とを電気的に接続する前に行い、前記第2のプラズマ処
理工程は第1のプラズマ処理を行った後、樹脂封止を行
う前に行うことを特徴とする電子部品製造方法。
1. A method for manufacturing an electronic component, comprising mounting a semiconductor element on a substrate, electrically connecting the two, and then sealing the semiconductor element on the substrate with a resin. A first plasma processing step of removing by sputtering, and a second plasma processing step of modifying the resist surface of the substrate after the first plasma processing, wherein the first plasma processing step includes at least An electronic component manufacturing method, wherein the method is performed before electrical connection with a semiconductor element, and the second plasma processing step is performed after performing the first plasma processing and before performing resin sealing.
【請求項2】前記第2のプラズマ処理工程において、酸
素、塩素、臭素もしくはフッ素の少なくとも1つ以上を
含んだガスを用いたプラズマで基板のレジスト表面を改
質することを特徴とする請求項1記載の電子部品製造方
法。
2. The method according to claim 1, wherein in the second plasma processing step, the resist surface of the substrate is modified with plasma using a gas containing at least one of oxygen, chlorine, bromine and fluorine. 2. The electronic component manufacturing method according to 1.
【請求項3】基板に半導体素子を搭載して両者を電気的
に接続し、その後基板上の半導体素子を樹脂封止して成
る電子部品であって、基板の電極表面上の接合阻害物を
スパッタリングにより除去する第1のプラズマ処理工程
と、前記第1のプラズマ処理後の基板のレジスト表面を
改質する第2のプラズマ処理工程とを含み、前記第1の
プラズマ処理工程は、少なくとも基板と半導体素子とを
電気的に接続する前に行い、前記第2のプラズマ処理工
程は第1のプラズマ処理を行った後、樹脂封止を行う前
に行う電子部品製造方法によって製造されたことを特徴
とする電子部品。
3. An electronic component comprising a semiconductor element mounted on a substrate, electrically connecting the two, and then sealing the semiconductor element on the substrate with a resin. A first plasma processing step of removing by sputtering, and a second plasma processing step of modifying the resist surface of the substrate after the first plasma processing, wherein the first plasma processing step includes at least The semiconductor device is manufactured by an electronic component manufacturing method which is performed before electrical connection with a semiconductor element, and wherein the second plasma processing step is performed after performing the first plasma processing and before performing resin sealing. And electronic components.
JP2001216365A 2001-07-17 2001-07-17 Electronic component manufacturing method and electronic component Expired - Fee Related JP3671879B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006098949A (en) * 2004-09-30 2006-04-13 Sumitomo Bakelite Co Ltd Semiconductor device
JP2008066754A (en) * 2007-11-22 2008-03-21 Sanyo Electric Co Ltd Method for manufacturing circuit device
US7364941B2 (en) 2002-12-04 2008-04-29 Sanyo Electric Co., Ltd. Circuit device manufacturing method
JP2009231680A (en) * 2008-03-25 2009-10-08 Panasonic Corp Surface treatment method and surface treatment device of substrate, and method of manufacturing semiconductor package
CN114823970A (en) * 2022-03-25 2022-07-29 昆明物理研究所 Method for increasing adhesiveness of photoresist on superlattice infrared focal plane chip

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0837182A (en) * 1994-07-22 1996-02-06 Mitsubishi Electric Corp Semiconductor device and manufacture thereof
JPH08153833A (en) * 1994-11-29 1996-06-11 Sanyo Electric Co Ltd Manufacturing method of semiconductor device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0837182A (en) * 1994-07-22 1996-02-06 Mitsubishi Electric Corp Semiconductor device and manufacture thereof
JPH08153833A (en) * 1994-11-29 1996-06-11 Sanyo Electric Co Ltd Manufacturing method of semiconductor device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7364941B2 (en) 2002-12-04 2008-04-29 Sanyo Electric Co., Ltd. Circuit device manufacturing method
JP2006098949A (en) * 2004-09-30 2006-04-13 Sumitomo Bakelite Co Ltd Semiconductor device
JP2008066754A (en) * 2007-11-22 2008-03-21 Sanyo Electric Co Ltd Method for manufacturing circuit device
JP4642061B2 (en) * 2007-11-22 2011-03-02 三洋電機株式会社 Circuit device manufacturing method
JP2009231680A (en) * 2008-03-25 2009-10-08 Panasonic Corp Surface treatment method and surface treatment device of substrate, and method of manufacturing semiconductor package
CN114823970A (en) * 2022-03-25 2022-07-29 昆明物理研究所 Method for increasing adhesiveness of photoresist on superlattice infrared focal plane chip

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