JP2002020546A - High damping rubber composition for bearing - Google Patents
High damping rubber composition for bearingInfo
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- JP2002020546A JP2002020546A JP2000202214A JP2000202214A JP2002020546A JP 2002020546 A JP2002020546 A JP 2002020546A JP 2000202214 A JP2000202214 A JP 2000202214A JP 2000202214 A JP2000202214 A JP 2000202214A JP 2002020546 A JP2002020546 A JP 2002020546A
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- rubber
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- parts
- rubber composition
- bearing
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、高減衰支承用ゴム
組成物に関し、より詳しくは、減衰率および剪断弾性率
の歪み依存性が少ない高減衰支承用ゴム組成物に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a rubber composition for a high damping bearing, and more particularly to a rubber composition for a high damping bearing having little strain dependence of a damping rate and a shear modulus.
【0002】[0002]
【従来の技術】近年、震動エネルギーの吸収装置、すな
わち防震、除震、免震装置が急速に普及しつつある。例
えば、橋梁の支承やビルの基礎免震等には、ゴム組成物
と硬質板とを交互に積層した免震支承体が用いられてい
る。これはゴム組成物を硬質板との積層体とすることに
より、上下方向には非常に硬く、横方向には柔らかく、
即ち、剪断剛性を小さくして、建築物の固有震動周期を
地震の震動周期からずらすように作用させ、地震により
建物が受ける加速度を非常に小さくするものである。2. Description of the Related Art In recent years, seismic energy absorbing devices, that is, seismic isolation, seismic isolation, and seismic isolation devices are rapidly spreading. For example, a seismic isolation bearing in which a rubber composition and a hard plate are alternately laminated is used for a bearing of a bridge or a base seismic isolation of a building. This is a rubber composition and a laminate with a hard plate, very hard in the vertical direction, soft in the horizontal direction,
That is, the shear rigidity is reduced, and the natural vibration period of the building is made to be shifted from the vibration period of the earthquake, so that the acceleration received by the building due to the earthquake is extremely small.
【0003】高減衰支承の要求特性としては、振動をよ
り多く熱に変換して振動エネルギーを減衰させるという
高減衰性や、剪断弾性率が狙い通りであることが第1に
挙げられ、第2に、これらの特性の歪み依存性が小さい
ことが挙げられる。The first required characteristics of a high damping bearing include a high damping property in which vibration is converted to heat to attenuate vibration energy and a shear modulus of elasticity as intended. Another reason is that the distortion dependence of these characteristics is small.
【0004】ここで、添付の図面を参照して、高減衰支
承の特性として挙げられる減衰率および剪断弾性率の算
出方法を説明する。図1は、支承体に一方向から周期的
に剪断歪みを加えていき、剪断歪みに対して生じる支承
体の応力を、横軸に歪み(%)、縦軸に応力をとって示
したものである。支承体の減衰率(Heq)および剪断弾
性率(Geq)は、それぞれ、下記式(1)および式
(2)で表される。[0004] Here, a method of calculating a damping rate and a shear modulus, which are characteristics of the high damping bearing, will be described with reference to the accompanying drawings. FIG. 1 is a diagram in which a shear strain is periodically applied to a bearing from one direction, and the stress of the bearing caused by the shear strain is shown with strain (%) on the horizontal axis and stress on the vertical axis. It is. The damping rate (H eq ) and the shear modulus (G eq ) of the support are represented by the following equations (1) and (2), respectively.
【0005】[0005]
【数1】 (Equation 1)
【0006】式(1)中、△Wはヒステリシスループの
面積(図中、斜線部分)である。式(2)中、Keqは下
記式(3)で表され、Hは支承体中に積層されるゴム層
の合計の厚みを表し、Aはゴム層の断面積である。In equation (1), ΔW is the area of the hysteresis loop (the shaded area in the figure). In the equation (2), K eq is represented by the following equation (3), H represents the total thickness of the rubber layer laminated in the support, and A is the cross-sectional area of the rubber layer.
【0007】[0007]
【数2】 (Equation 2)
【0008】支承体の減衰率および剪断弾性率は、上式
からもわかるように、高歪み領域の応力の値に左右され
る。例えば、ヒステリシスループの面積がほとんど変わ
らないのにもかかわらず、高歪み領域における応力が急
激に高くなると、減衰率は低下し、剪断弾性率は大きく
なる。As can be seen from the above equation, the damping rate and the shear modulus of the bearing depend on the stress value in the high strain region. For example, if the area of the hysteresis loop hardly changes, but the stress in the high strain region sharply increases, the damping rate decreases and the shear modulus increases.
【0009】一般的に、剪断弾性率の低い支承において
は、歪み依存性を小さくすることは比較的容易であっ
た。しかし、橋梁用の支承等に使用されるゴム組成物と
いった、剪断弾性率の高い支承においては、高歪み領域
で、剪断方向の変形に伴う剪断剛性が急激に増大するい
わゆるハードニング現象の効果が大きく、剪断弾性率の
歪み依存性を小さくすることが困難であった。また、剪
断剛性の増加に伴い、減衰率が低下し、免震効果が十分
得られないという問題があった。In general, it has been relatively easy to reduce the strain dependency in a bearing having a low shear modulus. However, in a bearing having a high shear modulus, such as a rubber composition used for a bearing for a bridge, the effect of a so-called hardening phenomenon in which the shear rigidity accompanying the deformation in the shear direction rapidly increases in a high strain region. It was large, and it was difficult to reduce the strain dependence of the shear modulus. In addition, there is a problem that the damping rate decreases as the shear rigidity increases, and the seismic isolation effect cannot be sufficiently obtained.
【0010】[0010]
【発明が解決しようとする課題】本発明の目的は、上述
の従来技術の問題点を解決することにあり、高減衰性を
有しつつ、高歪み領域でのハードニング現象を抑制し
て、減衰率および剪断弾性率の歪み依存性を低減させた
高減衰支承用ゴム組成物を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the prior art, and has a high damping property while suppressing a hardening phenomenon in a high strain region. An object of the present invention is to provide a high damping bearing rubber composition in which the strain dependency of the damping rate and the shear modulus is reduced.
【0011】[0011]
【課題を解決するための手段】本発明者は、上記課題を
解決するため鋭意検討した結果、高減衰支承用ゴム組成
物に、CTAB吸着比表面積が120m2 /g以上であ
るカーボンブラックを含有させ、かつ、ゴム成分として
イソプレンゴムを使用し、または、補強効果の小さい無
機充填剤を使用することにより、支承体のハードニング
現象を抑制し、高い減衰を維持し、歪み依存性を低減で
きることを見出し、本発明を完成させた。The present inventors have conducted intensive studies to solve the above-mentioned problems. As a result, the rubber composition for high damping bearing contains carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more. By using isoprene rubber as a rubber component or using an inorganic filler having a small reinforcing effect, it is possible to suppress the hardening phenomenon of the support body, maintain high damping, and reduce strain dependence. And completed the present invention.
【0012】即ち、本発明の第1の態様に係る高減衰支
承用ゴム組成物は、ゴム成分100重量部に対して、C
TAB吸着比表面積が120m2 /g以上のカーボンブ
ラックを60重量部〜100重量部、および、補強効果
の少ない無機充填剤を10重量部以上を含有することを
特徴とするものである。That is, the rubber composition for a high-damping bearing according to the first embodiment of the present invention comprises a rubber component having 100 parts by weight of C.
It is characterized by containing 60 to 100 parts by weight of carbon black having a TAB adsorption specific surface area of 120 m 2 / g or more, and 10 parts by weight or more of an inorganic filler having a small reinforcing effect.
【0013】本発明の第2の態様に係る高減衰支承用ゴ
ム組成物は、ゴム成分として、少なくとも天然ゴムおよ
びイソプレンゴムを、重量比で、天然ゴム:イソプレン
ゴム=0〜50:100〜50となる範囲で含有し、か
つ、全ゴム成分100重量部に対して、CTAB吸着比
表面積が120m2 /g以上のカーボンブラックを60
重量部〜100重量部を含有することを特徴とするもの
である。[0013] The rubber composition for high damping bearing according to the second aspect of the present invention comprises at least natural rubber and isoprene rubber as rubber components in a weight ratio of natural rubber: isoprene rubber = 0 to 50: 100 to 50. And carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more based on 100 parts by weight of all rubber components.
It is characterized by containing from 100 parts by weight to 100 parts by weight.
【0014】本発明の第3の態様に係る高減衰支承用ゴ
ム組成物は、ゴム成分として、少なくとも天然ゴムおよ
びイソプレンゴムを、重量比で、天然ゴム:イソプレン
ゴム=0〜50:100〜50となる範囲で含有し、か
つ、全ゴム成分100重量部に対して、CTAB吸着比
表面積が120m2 /g以上のカーボンブラックを60
重量部〜100重量部、および、補強効果の少ない無機
充填剤を10重量部以上含有することを特徴とするもの
である。The rubber composition for a high-damping bearing according to the third aspect of the present invention comprises at least natural rubber and isoprene rubber as rubber components in a weight ratio of natural rubber: isoprene rubber = 0 to 50: 100 to 50. And carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more based on 100 parts by weight of all rubber components.
It is characterized by containing from 10 parts by weight to 100 parts by weight of an inorganic filler having a small reinforcing effect.
【0015】本発明において、これらの高減衰支承用ゴ
ム組成物は、前記ゴム成分として、ブタジエンゴムを含
有することが好ましい。In the present invention, these high damping bearing rubber compositions preferably contain butadiene rubber as the rubber component.
【0016】[0016]
【発明の実施の形態】以下、本発明について、詳細に説
明する。本発明の第1の態様に係る高減衰支承用ゴム組
成物(以下、第1の態様に係るゴム組成物という)は、
ゴム成分100重量部に対して、CTAB吸着比表面積
が120m2 /g以上のカーボンブラックを60重量部
〜100重量部、および補強効果の少ない無機充填剤を
10重量部以上を含有するものである。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. The rubber composition for high damping bearing according to the first aspect of the present invention (hereinafter referred to as the rubber composition according to the first aspect)
Based on 100 parts by weight of the rubber component, it contains 60 to 100 parts by weight of carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more, and 10 parts by weight or more of an inorganic filler having a small reinforcing effect. .
【0017】第1の態様に係るゴム組成物に用いられる
ゴム成分としては、ジエン系ゴムを用いることができ、
ジエン系ゴムとしては、例えば、天然ゴム(NR)、イ
ソプレンゴム(IR)、ブタジエンゴム(BR)、スチ
レン−ブタジエン共重合体ゴム(SBR)、アクリロニ
トリル・ブタジエン共重合ゴム(NBR)、ブチルゴム
(IIR)、ハロゲン化ブチルゴム(Br−IIR、C
l−IIR)、クロロプレンゴム(CR)等を挙げるこ
とができる。これらの中でも、減衰性、加工性等のバラ
ンスがよいことからNRが、支承体の減衰性、剪断弾性
率の歪み依存性を低減させる観点からIRが、それぞれ
好ましい。また、これらの中で、BRは、支承体の減衰
性、剪断弾性率の温度依存性を低減させるので好まし
い。特に、BRとして、シス1,4−結合量が90%以
上のシス1,4−ポリブタジエンゴム97重量%〜80
重量%と、シンジオタクティック1,2−ポリブタジエ
ン3重量%〜20重量%からなるBRを使用することが
好ましい。As the rubber component used in the rubber composition according to the first embodiment, a diene rubber can be used.
Examples of the diene rubber include natural rubber (NR), isoprene rubber (IR), butadiene rubber (BR), styrene-butadiene copolymer rubber (SBR), acrylonitrile / butadiene copolymer rubber (NBR), and butyl rubber (IIR). ), Halogenated butyl rubber (Br-IIR, C
1-IIR), chloroprene rubber (CR) and the like. Among them, NR is preferable because of good balance between damping property and workability, and IR is preferable from the viewpoint of reducing the damping property of the support and the strain dependency of the shear modulus. Of these, BR is preferable because it reduces the damping of the bearing and the temperature dependence of the shear modulus. In particular, as BR, 97% by weight to 80% of cis 1,4-polybutadiene rubber having a cis 1,4-bond amount of 90% or more.
It is preferable to use BR consisting of 3% by weight and 20% by weight of syndiotactic 1,2-polybutadiene.
【0018】第1の態様に係るゴム組成物において、充
填剤として、小粒径のカーボンブラックを使用する。こ
こで、使用するカーボンブラックは、CTAB吸着比表
面積が120m2 /g以上、好ましくは、130m2 /
g〜370m2 /gのカーボンブラックである。CTA
B(セチルトリメチルアンモニウムブロミド)比表面積
(以下、CTABと記す)は、カーボンブラックがゴム
分子との吸着に利用できる表面積をセチルトリメチルア
ンモニウムブロミドの吸着によって測定した値である。
CTABが上記範囲であれば、第1の態様に係るゴム組
成物を使用する支承体の減衰性を高く維持することがで
きる。このようなカーボンブラックとしては、例えば、
SAF、XCF、HCF、MCF等を挙げることができ
る。なお、CATB吸着比表面積は、ASTM D37
65−80に記載の方法により測定することができる。In the rubber composition according to the first embodiment, carbon black having a small particle diameter is used as a filler. Here, the carbon black used is, CTAB adsorption specific surface area of 120 m 2 / g or more, preferably, 130m 2 /
g to 370 m 2 / g of carbon black. CTA
B (cetyltrimethylammonium bromide) specific surface area (hereinafter referred to as CTAB) is a value obtained by measuring the surface area of carbon black available for adsorption to rubber molecules by adsorption of cetyltrimethylammonium bromide.
When the CTAB is within the above range, it is possible to maintain a high damping property of the support using the rubber composition according to the first embodiment. As such carbon black, for example,
SAF, XCF, HCF, MCF and the like can be mentioned. The CATB adsorption specific surface area is as per ASTM D37
It can be measured by the method described in 65-80.
【0019】また、減衰性を高く維持しつつ、減衰性、
剪断弾性率の歪み依存性を低減させる観点から、CTA
Bとよう素吸着量(IA)の比(CTAB/IA)が、
1.0以下であるカーボンブラックが好ましく、CTA
B/IAが0.5〜0.9であるカーボンブラックが更
に好ましい。なお、よう素吸着量は、JIS K 62
21に記載の方法により測定することができる。In addition, while maintaining high damping property, damping property,
From the viewpoint of reducing the strain dependence of the shear modulus, CTA
The ratio (CTAB / IA) of B and the iodine adsorption amount (IA) is
Carbon black of 1.0 or less, and CTA
Carbon black having a B / IA of 0.5 to 0.9 is more preferred. The amount of iodine adsorbed was measured according to JIS K62.
21 can be measured.
【0020】第1の態様に係るゴム組成物において、上
述したカーボンブラックの含有量は、ゴム成分100重
量部に対して、60重量部〜100重量部であり、好ま
しくは70〜90重量部である。含有量がこの範囲であ
ると、高剪断弾性率が確保でき、また、支承体の高減衰
性を確保できるからである。In the rubber composition according to the first embodiment, the content of the carbon black is 60 to 100 parts by weight, preferably 70 to 90 parts by weight, per 100 parts by weight of the rubber component. is there. If the content is within this range, a high shear modulus can be secured, and a high damping property of the bearing body can be secured.
【0021】第1の態様に係るゴム組成物は、補強効果
の少ない無機充填剤を含有する。ここで、補強効果の少
ない無機充填剤とは、加硫後のゴム組成物の力学的物性
を高める効果を特に有さず、補強性がほとんど期待でき
ない、ゴムに対して不活性な無機充填剤をいい、カーボ
ンブラックやシリカ以外の充填剤をいう。このような無
機充填剤を使用することにより、本態様のゴム組成物を
使用する支承体の歪み依存性を低減させることが可能と
なる。本態様に使用される補強効果の少ない無機充填剤
としては、例えば、T−クレー、カオリンクレー、ろう
石クレー、セリサイトクレー、焼成クレー等のソフトク
レー;けいそう土;重質炭酸カルシウム、炭酸マグネシ
ウム;等を挙げることができる。これらの中でも、減衰
性を高く保つという観点から、T−クレー、カオリンク
レーが好ましい。The rubber composition according to the first embodiment contains an inorganic filler having a small reinforcing effect. Here, the inorganic filler having a small reinforcing effect is an inorganic filler which is not particularly effective in enhancing the mechanical properties of the rubber composition after vulcanization, and hardly expected to have reinforcing properties, and is inert to rubber. And fillers other than carbon black and silica. By using such an inorganic filler, it becomes possible to reduce the strain dependency of the support using the rubber composition of the present embodiment. Examples of the inorganic filler having a small reinforcing effect used in the present embodiment include soft clays such as T-clay, kaolin clay, limestone clay, sericite clay and calcined clay; diatomaceous earth; Magnesium; and the like. Among these, T-clay and kaolin clay are preferred from the viewpoint of maintaining high attenuation.
【0022】第1の態様に係るゴム組成物において、補
強効果の少ない無機充填剤の含有量は、ゴム成分100
重量部に対して、10重量部以上であり、好ましくは1
5〜30重量部である。含有量がこの範囲であると、支
承体の減衰率、剪断弾性率の歪み依存性を低減でき、ま
た、高い減衰性を維持できるからである。In the rubber composition according to the first embodiment, the content of the inorganic filler having a small reinforcing effect is 100
10 parts by weight or more based on parts by weight, preferably 1 part by weight
5 to 30 parts by weight. When the content is within this range, the dependency of the damping rate and the shear modulus of the bearing on the strain can be reduced, and the high damping property can be maintained.
【0023】また、第1の態様に係るゴム組成物は、C
5 系の脂肪族不飽和炭化水素の重合体、C9 系の芳香族
不飽和炭化水素の重合体、あるいは、C5 系の脂肪族不
飽和炭化水素とC9 系の芳香族不飽和炭化水素との共重
合体である熱可塑性樹脂を含有しても良い。Further, the rubber composition according to the first embodiment is a rubber composition
Polymer of aliphatic unsaturated hydrocarbons of type 5 C, aromatic unsaturated hydrocarbons of type C 9 or aliphatic unsaturated hydrocarbons of type C 5 and aromatic unsaturated hydrocarbons of type C 9 And a thermoplastic resin which is a copolymer of the above.
【0024】C5 系の脂肪族不飽和炭化水素としては、
ナフサの熱分解により得られるC5留分中に含まれるペ
ンテン−(1)、ペンテン−(2)、2−メチルブテン
−(1)、3−メチルブテン−(1)、2−メチルブテ
−(2)等のオレフィン系炭化水素や、2−メチルブタ
ジエン−(1,3)、ペンタジエン−(1,2)、ペン
タジエン−(1,3)、3−メチルブタジエン−(1,
2)等のジオレフィン系炭化水素等があげられる。Examples of the C 5 aliphatic unsaturated hydrocarbon include:
Pentene contained in C 5 distillate obtained by thermal cracking of naphtha - (1), pentene - (2), 2-methylbutene - (1), 3-methylbutene - (1), 2- methylbut - (2) Olefinic hydrocarbons such as 2-methylbutadiene- (1,3), pentadiene- (1,2), pentadiene- (1,3), 3-methylbutadiene- (1,
And diolefin-based hydrocarbons such as 2).
【0025】C9 系の芳香族不飽和炭化水素としては、
ナフサの熱分解により得られるC9留分中に含まれるα
−メチルスチレン、o−ビニルトルエン、m−ビニルト
ルエン、p−ビニルトルエン等のビニル置換芳香族炭化
水素等があげられる。これらは、適当な触媒の存在下
で、フリーデル−クラフツ反応等により重合あるいは共
重合可能である。ここで、C9 系の芳香族不飽和炭化水
素の(共)重合体とは、一種のC9 系の芳香族不飽和炭
化水素の重合体と、二種以上のC9 系の芳香族不飽和炭
化水素の共重合体のいずれをもいう。The C 9 aromatic unsaturated hydrocarbon includes:
Α contained in the C 9 fraction obtained by pyrolysis of naphtha
And vinyl-substituted aromatic hydrocarbons such as -methylstyrene, o-vinyltoluene, m-vinyltoluene and p-vinyltoluene. These can be polymerized or copolymerized by a Friedel-Crafts reaction or the like in the presence of a suitable catalyst. Here, the (co) polymer of aromatic unsaturated hydrocarbons C 9 system, a polymer of aromatic unsaturated hydrocarbon kind of C 9, aromatic of two or more C 9 based not It refers to any of saturated hydrocarbon copolymers.
【0026】また、C9 系の芳香族不飽和炭化水素とC
5 系の脂肪族不飽和炭化水素との共重合体は、C9 系の
芳香族不飽和炭化水素ユニットが60モル%以上である
ものが好ましく、90モル%以上であるものがさらに好
ましい。C5 系の脂肪族不飽和炭化水素ユニットが多く
なるに従い、該共重合体の軟化点が低下する傾向にあ
る。上記熱可塑性炭化水素樹脂は、ゴム成分の物性に対
し、その分子量および二重結合の反応性が影響を与える
ので、軟化点(JIS K2207)が100℃以上の
ものが好ましく、120℃以上のものがより好ましい。Further, C 9 type aromatic unsaturated hydrocarbon and C 9
The copolymer with the penta-system aliphatic unsaturated hydrocarbon preferably has 60 mol% or more, and more preferably 90 mol% or more, of the C 9 -type aromatic unsaturated hydrocarbon unit. As the number of C 5 aliphatically unsaturated hydrocarbon units increases, the softening point of the copolymer tends to decrease. The thermoplastic hydrocarbon resin has a softening point (JIS K2207) of 100 ° C. or higher, preferably 120 ° C. or higher, since the molecular weight and the reactivity of the double bond affect the physical properties of the rubber component. Is more preferred.
【0027】第1の態様に係るゴム組成物に含有しても
よい上記樹脂の含有量は、ゴム成分100重量部に対
し、15〜60重量部が好ましく、20〜50重量部が
より好ましい。この範囲で上記樹脂を含有すると、得ら
れるゴム組成物の減衰性が高くなり、また、破断伸びに
も優れる。さらに、減衰率、剪断弾性率の温度依存性が
低減される。The content of the resin which may be contained in the rubber composition according to the first embodiment is preferably 15 to 60 parts by weight, more preferably 20 to 50 parts by weight, per 100 parts by weight of the rubber component. When the above resin is contained in this range, the obtained rubber composition has high damping property and excellent elongation at break. Further, the temperature dependency of the damping rate and the shear modulus is reduced.
【0028】第1の態様に係るゴム組成物には、上記成
分以外に、本発明の目的を損なわない範囲で、上述のカ
ーボンブラック以外のカーボンブラック、上述の補強効
果の少ない無機充填剤以外の充填剤を含有することもで
き、例えば、ヒュームドシリカ、焼成シリカ、沈降シリ
カ、粉砕シリカ、溶融シリカを挙げることができる。ま
た、その他の添加剤、例えば、硫黄、酸化亜鉛等の加硫
剤;TMTD等の有機含硫黄化合物、ジクミルペルオキ
シド等の有機過酸化物等;N−シクロヘキシル−2−ベ
ンゾチアゾールスルフェンアミド(CBS)等のスルフ
ェンアミド類、メルカプトベンゾチアゾール等のチアゾ
ール類、テトラメチルチウラムモノスルフィド等のチウ
ラム等の加硫促進剤;ステアリン酸等の加硫促進助剤、
TMDQ等のケトン・アミン縮合物、DNPD等のアミ
ン類、スチレン化フェノール等のモノフェノール類等の
老化防止剤;DBP、DOP等のフタール酸誘導体、D
BS等のセバシン酸誘導体、といったモノエステル類等
の可塑剤等を含有しても良い。In the rubber composition according to the first embodiment, in addition to the above-mentioned components, a carbon black other than the above-mentioned carbon black and an inorganic filler other than the above-mentioned inorganic filler having a small reinforcing effect, as long as the object of the present invention is not impaired. A filler can be contained, and examples thereof include fumed silica, calcined silica, precipitated silica, pulverized silica, and fused silica. Other additives, for example, vulcanizing agents such as sulfur and zinc oxide; organic sulfur-containing compounds such as TMTD; organic peroxides such as dicumyl peroxide; N-cyclohexyl-2-benzothiazole sulfenamide ( Vulcanization accelerators such as sulfenamides such as CBS), thiazoles such as mercaptobenzothiazole, thiuram such as tetramethylthiuram monosulfide; vulcanization accelerators such as stearic acid;
Antioxidants such as ketone-amine condensates such as TMDQ, amines such as DNPD, monophenols such as styrenated phenol; phthalic acid derivatives such as DBP and DOP;
It may contain a plasticizer such as monoesters such as sebacic acid derivatives such as BS.
【0029】本発明の第2の態様に係る高減衰支承用ゴ
ム組成物(以下、第2の態様に係るゴム組成物という)
は、ゴム成分として、少なくとも天然ゴムおよびイソプ
レンゴムを、重量比で、天然ゴム:イソプレンゴム=0
〜50:100〜50となる範囲で含有し、かつ、全ゴ
ム成分100重量部に対して、CTABにて120m 2
/g以上のカーボンブラックを60重量部〜100重量
部を含有するものである。A high-damping bearing bar according to a second aspect of the present invention.
Rubber composition (hereinafter, referred to as a rubber composition according to the second embodiment)
At least natural rubber and isop as rubber components.
Natural rubber: isoprene rubber = 0 by weight ratio
5050: contained in the range of 100 to 50, and
120m by CTAB for 100 parts by weight of Two
/ G or more of 60 parts by weight to 100 parts by weight of carbon black
Parts.
【0030】第2の態様に係るゴム組成物に含有される
ゴム成分は、少なくともNRとIRとを含み、NRとI
Rの含有割合が、重量比で、0〜50:100〜50で
ある。上記範囲内であると、減衰性と剪断弾性率の歪み
依存性がバランスよく低減されるからである。ゴム成分
中、NRとIRの含有量は、NRとIRの合計で、50
〜90重量%が好ましく、60〜90重量%がより好ま
しい。上記範囲であれば、得られるゴム組成物の減衰
性、加工性が良好となる。The rubber component contained in the rubber composition according to the second embodiment contains at least NR and IR, and NR and I
The content ratio of R is 0 to 50: 100 to 50 by weight ratio. This is because within the above range, the strain dependency of the damping property and the shear modulus is reduced in a well-balanced manner. In the rubber component, the content of NR and IR is 50 in total of NR and IR.
It is preferably from 90 to 90% by weight, more preferably from 60 to 90% by weight. When it is in the above range, the obtained rubber composition has good damping properties and processability.
【0031】NRとIR以外に含有することの出来るゴ
ムとしては、第1の態様に係るゴム組成物に用いられる
ジエン系ゴムとして例示されたゴムが例示される。例示
されるゴムの中で、減衰性、剪断弾性率の温度依存性を
低減させる観点から、BRを含有することが好ましい。
また、支承体の温度依存性を維持しつつ減衰性を高くす
る観点から、BRとしては、シス1,4−結合量が90
%以上のシス1,4−ポリブタジエンゴム97重量%〜
80重量%と、シンジオタクティック1,2−ポリブタ
ジエン3重量%〜20重量%からなるBRを使用するこ
とが好ましい。BRの含有量は、ゴム成分100重量部
中、10〜50重量部が好ましく、20〜40重量部で
あることが更に好ましい。Examples of the rubber that can be contained in addition to the NR and IR include the rubbers exemplified as the diene rubber used in the rubber composition according to the first embodiment. Among the exemplified rubbers, it is preferable to contain BR from the viewpoint of reducing the temperature dependency of the damping property and the shear modulus.
In addition, from the viewpoint of increasing the damping property while maintaining the temperature dependence of the support, BR has a cis 1,4-bond amount of 90%.
% Or more of cis 1,4-polybutadiene rubber 97% by weight or more
It is preferable to use a BR consisting of 80% by weight and 3% to 20% by weight of syndiotactic 1,2-polybutadiene. The content of BR is preferably from 10 to 50 parts by weight, more preferably from 20 to 40 parts by weight, based on 100 parts by weight of the rubber component.
【0032】第2の態様に係るゴム組成物に含有される
カーボンブラックとしては、第1の態様に係るゴム組成
物において例示したカーボンブラックと同様のものを例
示することが出来る。カーボンブラックの含有量は、ゴ
ム成分100重量部に対して、60重量部〜100重量
部であり、好ましくは70〜90重量部である。含有量
がこの範囲であると、高剪断弾性率が確保でき、また、
支承体の高減衰性を確保できるからである。As the carbon black contained in the rubber composition according to the second embodiment, those similar to the carbon black exemplified in the rubber composition according to the first embodiment can be exemplified. The content of carbon black is from 60 to 100 parts by weight, preferably from 70 to 90 parts by weight, based on 100 parts by weight of the rubber component. When the content is within this range, a high shear modulus can be secured, and
This is because high damping of the support body can be ensured.
【0033】第2の態様に係るゴム組成物は、熱可塑性
樹脂を配合することが出来、かかる樹脂としては、第1
の態様に係るゴム組成物に配合することのできる熱可塑
性樹脂として例示したものと同様の樹脂を例示できる。
例示される樹脂の配合量は、ゴム成分100重量部に対
し、15〜60重量部が好ましく、20〜50重量部が
より好ましい。この範囲で上記樹脂を含有すると、得ら
れるゴム組成物の減衰性が高くなり、また、破断伸びに
も優れる。さらに、減衰率、剪断弾性率の温度依存性が
低減される。The rubber composition according to the second embodiment can contain a thermoplastic resin.
The same resins as those exemplified as the thermoplastic resin that can be blended in the rubber composition according to the embodiment can be exemplified.
The compounding amount of the exemplified resin is preferably 15 to 60 parts by weight, more preferably 20 to 50 parts by weight, based on 100 parts by weight of the rubber component. When the above resin is contained in this range, the obtained rubber composition has high damping property and excellent elongation at break. Further, the temperature dependency of the damping rate and the shear modulus is reduced.
【0034】第2の態様に係るゴム組成物には、上記成
分以外に、本発明の目的を損なわない範囲で、その他の
添加剤、例えば、上記カーボンブラック以外の充填剤、
加硫剤、加硫促進剤、加硫促進助剤、老化防止剤、可塑
剤等を含有しても良い。これらの添加剤としては、第1
の態様に係るゴム組成物に配合することの出来る添加剤
として例示されたものと同様のものを例示することが出
来る。In the rubber composition according to the second embodiment, in addition to the above components, other additives such as a filler other than the above carbon black, as long as the object of the present invention is not impaired,
It may contain a vulcanizing agent, a vulcanization accelerator, an auxiliary vulcanization accelerator, an antioxidant, a plasticizer and the like. These additives include:
Examples of the additives that can be blended in the rubber composition according to the embodiment can be the same as those exemplified above.
【0035】本発明の第3の態様に係る高減衰支承用ゴ
ム組成物(以下、第3の態様に係るゴム組成物という)
は、ゴム成分として、少なくとも天然ゴムおよびイソプ
レンゴムを、重量比で、天然ゴム:イソプレンゴム=0
〜50:100〜50となる範囲で含有し、かつ、全ゴ
ム成分100重量部に対して、CTAB吸着比表面積が
120m2 /g以上のカーボンブラックを60重量部〜
100重量部、および、補強効果の少ない無機充填剤を
10重量部以上含有する高減衰支承用ゴム組成物であ
る。The rubber composition for high damping bearing according to the third embodiment of the present invention (hereinafter referred to as the rubber composition according to the third embodiment)
Means that at least natural rubber and isoprene rubber are used as rubber components in a weight ratio of natural rubber: isoprene rubber = 0.
50: 100 parts by weight of carbon rubber having a CTAB adsorption specific surface area of 120 m 2 / g or more based on 100 parts by weight of all rubber components.
It is a rubber composition for a high damping bearing containing 100 parts by weight and 10 parts by weight or more of an inorganic filler having a small reinforcing effect.
【0036】第3の態様に係るゴム組成物は、ゴム成分
として、少なくともNRとIRとを含み、NRとIRの
含有割合が、重量比で、0〜50:100〜50であ
る。上記範囲内であると、減衰性と剪断弾性率の歪み依
存性がバランスよく低減されるからである。ゴム成分
中、NRとIRの含有量は、NRとIRの合計で、50
〜90重量%が好ましく、60〜80重量%がより好ま
しい。上記範囲であれば、得られるゴム組成物の減衰
性、加工性が良好となる。The rubber composition according to the third aspect contains at least NR and IR as rubber components, and the content ratio of NR and IR is 0 to 50: 100 to 50 by weight. This is because within the above range, the strain dependency of the damping property and the shear modulus is reduced in a well-balanced manner. In the rubber component, the content of NR and IR is 50 in total of NR and IR.
It is preferably from 90 to 90% by weight, more preferably from 60 to 80% by weight. When it is in the above range, the obtained rubber composition has good damping properties and processability.
【0037】NRとIR以外に含有することの出来るゴ
ムとしては、第1、および第2の態様に係るゴム組成物
に用いられるジエン系ゴムとして例示されたゴムが例示
される。例示されるゴムの中で、減衰性、剪断弾性率の
温度依存性を低減させる観点から、BRを含有すること
が好ましい。BRとしては、支承体の温度依存性を維持
しつつ減衰性を高くするという観点から、第1、および
第2の態様に係るゴム組成物に配合するのが好ましいと
して例示されたBRと同種のものを配合するのが好まし
い。BRの含有量は、ゴム成分100重量部中、10〜
50重量部が好ましく、20〜40重量部であることが
更に好ましい。As rubbers that can be contained in addition to NR and IR, the rubbers exemplified as diene rubbers used in the rubber compositions according to the first and second embodiments are exemplified. Among the exemplified rubbers, it is preferable to contain BR from the viewpoint of reducing the temperature dependency of the damping property and the shear modulus. From the viewpoint of increasing the damping property while maintaining the temperature dependency of the support, the same BR as the BR exemplified as being preferably blended with the rubber composition according to the first and second aspects is used as the BR. It is preferable to mix them. The content of BR is 10 to 10 parts by weight of the rubber component.
It is preferably 50 parts by weight, more preferably 20 to 40 parts by weight.
【0038】第3の態様に係るゴム組成物に含有される
カーボンブラックとしては、第1、第2の態様に係るゴ
ム組成物において例示したカーボンブラックと同様のも
のを例示することが出来る。カーボンブラックの含有量
は、ゴム成分100重量部に対して、60重量部〜10
0重量部であり、好ましくは70〜90重量部である。
含有量がこの範囲であると、高剪断弾性率が確保でき、
また、支承体の高減衰性を確保できるからである。As the carbon black contained in the rubber composition according to the third embodiment, those similar to the carbon blacks exemplified in the rubber compositions according to the first and second embodiments can be exemplified. The content of carbon black is 60 parts by weight to 10 parts by weight based on 100 parts by weight of the rubber component.
0 parts by weight, preferably 70 to 90 parts by weight.
When the content is within this range, a high shear modulus can be secured,
In addition, high damping of the support body can be ensured.
【0039】第3の態様に係るゴム組成物は、補強効果
の少ない無機充填剤を含有する。このような無機充填剤
を使用することにより、減衰率、剪断弾性率の歪み依存
性を低減させることが可能となる。第3の態様に係るゴ
ム組成物に使用される補強効果の少ない無機充填剤とし
ては、第1の態様に係るゴム組成物に使用される補強効
果の少ない無機充填剤として例示された無機充填剤と同
様のものが例示される。第3の態様に係るゴム組成物に
おいて、補強効果の少ない無機充填剤の含有量は、ゴム
成分100重量部に対して、10重量部以上であり、好
ましくは15〜30重量部である。含有量がこの範囲で
あると、支承体の減衰率、剪断弾性率の歪み依存性を低
減でき、また、高い減衰性を維持できるからである。The rubber composition according to the third embodiment contains an inorganic filler having a small reinforcing effect. By using such an inorganic filler, it is possible to reduce the strain dependence of the damping rate and the shear modulus. Examples of the inorganic filler having a small reinforcing effect used in the rubber composition according to the third embodiment include inorganic fillers exemplified as the inorganic filler having a small reinforcing effect used in the rubber composition according to the first embodiment. The same thing as is illustrated. In the rubber composition according to the third aspect, the content of the inorganic filler having a small reinforcing effect is at least 10 parts by weight, preferably 15 to 30 parts by weight, based on 100 parts by weight of the rubber component. When the content is within this range, the dependency of the damping rate and the shear modulus of the bearing on the strain can be reduced, and the high damping property can be maintained.
【0040】第3の態様に係るゴム組成物は、熱可塑性
樹脂を配合することが出来、かかる樹脂としては、第
1、第2の態様に係るゴム組成物に配合することのでき
る熱可塑性樹脂として例示したものと同様の樹脂を例示
できる。例示される熱可塑性樹脂の配合量は、ゴム成分
100重量部に対し、15〜60重量部が好ましく、2
0〜50重量部がより好ましい。この範囲で上記樹脂を
含有すると、得られるゴム組成物の減衰性が高くなり、
また、破断伸びにも優れる。さらに、減衰率、剪断弾性
率の温度依存性が低減される。The rubber composition according to the third embodiment can be blended with a thermoplastic resin. As such a resin, a thermoplastic resin that can be blended with the rubber composition according to the first or second embodiment can be used. The same resins as those exemplified above can be exemplified. The amount of the exemplified thermoplastic resin is preferably 15 to 60 parts by weight with respect to 100 parts by weight of the rubber component,
0 to 50 parts by weight is more preferred. When the resin is contained in this range, the damping property of the obtained rubber composition is increased,
It is also excellent in elongation at break. Further, the temperature dependency of the damping rate and the shear modulus is reduced.
【0041】第3の態様に係るゴム組成物には、上記成
分以外に、本発明の目的を損なわない範囲で、その他の
添加剤、例えば、上記カーボンブラック以外の充填剤、
加硫剤、加硫促進剤、加硫促進助剤、老化防止剤、可塑
剤等を含有しても良い。これらの添加剤としては、第
1、第2の態様に係るゴム組成物に配合することの出来
る添加剤として例示されたものと同様のものを例示する
ことが出来る。In the rubber composition according to the third embodiment, in addition to the above components, other additives such as a filler other than the above carbon black, as long as the object of the present invention is not impaired,
It may contain a vulcanizing agent, a vulcanization accelerator, an auxiliary vulcanization accelerator, an antioxidant, a plasticizer and the like. Examples of these additives include those similar to the additives exemplified as the additives that can be blended in the rubber compositions according to the first and second embodiments.
【0042】第1〜3の態様において示した各成分を配
合した未加硫ゴム組成物を、適宜成形して公知の方法、
装置を用いて、130〜170℃で加熱加硫することに
より、本発明の第1〜3の態様に係るゴム組成物の加硫
物を得ることが出来る。The unvulcanized rubber composition containing the components shown in the first to third embodiments is appropriately molded and is subjected to a known method,
The vulcanized product of the rubber composition according to the first to third aspects of the present invention can be obtained by heating and vulcanizing at 130 to 170 ° C. using an apparatus.
【0043】上記構成を採ることにより、本発明の第1
〜3の態様に係る高減衰支承用ゴム組成物は、高歪み領
域でのハードニング現象が抑制され、減衰率および剪断
弾性率の歪み依存性が低い。ゴム成分として特定種類の
BRを含有する本発明の第1〜3の態様に係る高減衰支
承用ゴム組成物は、減衰率および剪断弾性率の温度依存
性が低い。By adopting the above configuration, the first aspect of the present invention is provided.
In the rubber compositions for high damping bearings according to the first to third aspects, the hardening phenomenon in the high strain region is suppressed, and the strain dependency of the damping rate and the shear modulus is low. The high damping bearing rubber compositions according to the first to third aspects of the present invention containing a specific type of BR as the rubber component have low temperature dependence of the damping rate and the shear modulus.
【0044】本発明の第1〜3の態様に係る高減衰支承
用ゴム組成物が用いられる支承体は、本発明の上記ゴム
組成物と、例えば、一般構造用鋼板、冷間圧延鋼板など
からなる硬質板とが、交互に積層されて構成される。支
承体を製造するには、成形、加硫して、シート状のゴム
組成物を得た後、接着剤により硬質板と接着してもよい
し、また、予め未加硫のゴム組成物をシート状に成形
し、硬質板と積層した後に加熱して加硫、接着を同時に
行って製造してもよい。このような支承体は、例えば、
道路や橋梁の支承や、ビルの基礎免震等の用途に好適に
用いることができる。The bearing body in which the rubber composition for high damping bearing according to the first to third aspects of the present invention is used comprises the above rubber composition of the present invention and, for example, a general structural steel sheet, a cold-rolled steel sheet or the like. And hard plates are alternately laminated. To manufacture the support, after molding and vulcanizing to obtain a sheet-like rubber composition, it may be adhered to a hard plate with an adhesive, or an unvulcanized rubber composition may be used in advance. It may be manufactured by forming into a sheet, laminating it on a hard plate, and then heating and vulcanizing and bonding at the same time. Such supports, for example,
It can be suitably used for applications such as bearing of roads and bridges and base isolation of buildings.
【0045】[0045]
【実施例】(ゴム組成物の調整) 実施例1〜6、比較例1〜2 下記第1表に記載の組成(単位は重量部)にて、加硫剤
を除く化合物を配合してB型バンバリーミキサーにて5
分間混練した。加硫剤は、8インチオープンロールにて
混練した。得られた未加硫ゴムを、148℃で45分プ
レス加硫した。Examples (Adjustment of rubber composition) Examples 1 to 6 and Comparative Examples 1 to 2 Compounds excluding the vulcanizing agent were blended with the compositions (units by weight) shown in Table 1 below to obtain B 5 with a Banbury mixer
Kneaded for minutes. The vulcanizing agent was kneaded with an 8-inch open roll. The obtained unvulcanized rubber was press-vulcanized at 148 ° C. for 45 minutes.
【0046】(ゴム組成物の物性)このようにして得ら
れたゴム組成物を、厚さ1mmのダンベル状試験片(J
IS3号)に切り出し、JIS K 6251に準拠し
て、100%モジュラス(M100 )〔MPa〕、300
%モジュラス(M300 )〔MPa〕、破断強度(T B )
〔MPa〕、破断伸び(EB )〔%〕を測定した。結果
を第1表に示す。(Physical Properties of Rubber Composition)
The rubber composition thus obtained was applied to a 1 mm-thick dumbbell-shaped test piece (J
IS No. 3) and conform to JIS K6251
And the 100% modulus (M100) [MPa], 300
% Modulus (M300) [MPa], breaking strength (T B)
[MPa], elongation at break (EB) [%] Was measured. result
Are shown in Table 1.
【0047】(ミニチュア積層体の調整)上記で得られ
た未加硫ゴム組成物を圧延し、表面をサンドブラストし
た後、未加硫ゴムと、金属接着剤を塗布した金属板(1
30mm×130mm×3.0mm)とを交互に積層
し、ゴム層が4層、金属板が3層となるように成型し
た。上下端のゴム層の表面をサンドブラストした後、金
属接着剤を塗布した端部鋼板(130mm×130mm
×30mm)2枚で上下を挟み、130℃で275分プ
レス加硫して、1層厚が3.0mmとなるミニチュア積
層体を作製した。(Preparation of Miniature Laminate) The unvulcanized rubber composition obtained above was rolled, the surface was sandblasted, and the unvulcanized rubber and a metal plate (1) coated with a metal adhesive were applied.
(30 mm × 130 mm × 3.0 mm) were alternately laminated, and molded so that four rubber layers and three metal plates were formed. After sandblasting the surfaces of the rubber layers at the upper and lower ends, an end steel plate (130 mm × 130 mm
(× 30 mm) sandwiched the upper and lower sides, and press-vulcanized at 130 ° C. for 275 minutes to produce a miniature laminate having one layer thickness of 3.0 mm.
【0048】(積層体の特性)剪断試験機にて、鉛直荷
重が5.88MPa、変形周波数が0.5Hz下での各
々の歪み (100%、175%、250%、300%)
での剪断特性値(Geq、Heq)を求めた。すなわち、剪
断特性試験にて得られたヒステリシスループより、
Geq、Heqを前記式(1)、(2)に従って算出した。
また、歪みが300%のときのGeq、Heqを、歪みが1
75%のときのGeq、Heqで割った値を計算し、歪み依
存性とした。結果を第1表に示す。(Characteristics of Laminate) Each strain at a vertical load of 5.88 MPa and a deformation frequency of 0.5 Hz using a shear tester (100%, 175%, 250%, 300%)
, The shear characteristic values (G eq , H eq ) were determined. That is, from the hysteresis loop obtained in the shear characteristic test,
G eq and H eq were calculated according to the above formulas (1) and (2).
In addition, G eq and H eq when the distortion is 300%, and the distortion is 1
The value divided by G eq and H eq at the time of 75% was calculated and defined as strain dependency. The results are shown in Table 1.
【0049】[0049]
【表1】 [Table 1]
【0050】<表中の成分> NR:TSR 20 IR:Nipol IR 2200、日本ゼオン社製 BR:UBEPOL VCR412、宇部興産社製(シ
ス1,4−結合量が98%のシス1,4−ポリブタジエ
ンゴム88重量%と、シンジオタクティック1,2−ポ
リブタジエン12重量%含有) ISAF:SHOBLACK N220、昭和キャボッ
ト社製(CTAB=118m2 /g、CTAB/IA=
1.02) SAF:ニテロン#410、新日化カーボン社製(CT
AB=143m2 /g、CTAB/IA=0.62) 樹脂:ハイレジン#120、東邦化学工業社製(C5 系
脂肪族不飽和炭化水素とC9 系芳香族不飽和炭化水素の
共重合体) CZ:ノクセラーCZ、大内新興化学(株)製(N−シ
クロヘキシル−2−ベンゾチアジルスルフェンアミド)<Components in Table> NR: TSR 20 IR: Nipol IR 2200, BR: UBEPOL VCR412 manufactured by Zeon Corporation, Ube Industries, Ltd. (cis 1,4-polybutadiene having 98% cis 1,4-bond amount) (88% by weight of rubber and 12% by weight of syndiotactic 1,2-polybutadiene) ISAF: SHOBLACK N220, manufactured by Showa Cabot Co. (CTAB = 118 m 2 / g, CTAB / IA =
1.02) SAF: Niteron # 410, manufactured by Shin-Nikka Carbon (CT
AB = 143 m 2 / g, CTAB / IA = 0.62) Resin: High Resin # 120, manufactured by Toho Chemical Industry Co., Ltd. (Copolymer of C 5 aliphatic unsaturated hydrocarbon and C 9 aromatic unsaturated hydrocarbon) CZ: Noxeller CZ, manufactured by Ouchi Shinko Chemical Co., Ltd. (N-cyclohexyl-2-benzothiazylsulfenamide)
【0051】[0051]
【発明の効果】本発明の高減衰支承用ゴム組成物は、減
衰率が高く、かつ、減衰率と剪断弾性率の歪み依存性が
低い。従って、本発明の高減衰支承用ゴム組成物は、各
種の振動エネルギー吸収装置(特に免震装置)に好適な
ゴム組成物である。The high damping bearing rubber composition of the present invention has a high damping rate and a low strain dependency between the damping rate and the shear modulus. Therefore, the rubber composition for a high damping bearing of the present invention is a rubber composition suitable for various vibration energy absorbing devices (particularly, seismic isolation devices).
【図1】 支承体のヒステリシス曲線を表したグラフで
ある。FIG. 1 is a graph showing a hysteresis curve of a bearing body.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C09K 3/00 C09K 3/00 P F16F 15/08 F16F 15/08 D ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C09K 3/00 C09K 3/00 P F16F 15/08 F16F 15/08 D
Claims (4)
吸着比表面積が120m2 /g以上のカーボンブラック
を60重量部〜100重量部、および、補強効果の少な
い無機充填剤を10重量部以上を含有することを特徴と
する高減衰支承用ゴム組成物。(1) CTAB is added to 100 parts by weight of a rubber component.
A rubber composition for a high-damping bearing, comprising 60 to 100 parts by weight of carbon black having an adsorption specific surface area of 120 m 2 / g or more and 10 parts by weight or more of an inorganic filler having a small reinforcing effect. .
びイソプレンゴムを、重量比で、天然ゴム:イソプレン
ゴム=0〜50:100〜50となる範囲で含有し、か
つ、全ゴム成分100重量部に対して、CTAB吸着比
表面積が120m2 /g以上のカーボンブラックを60
重量部〜100重量部を含有することを特徴とする高減
衰支承用ゴム組成物。2. A rubber component containing at least natural rubber and isoprene rubber in a weight ratio of natural rubber: isoprene rubber = 0 to 50: 100 to 50, and based on 100 parts by weight of all rubber components. On the other hand, carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more
A rubber composition for a high-damping bearing, comprising from 100 parts by weight to 100 parts by weight.
びイソプレンゴムを、重量比で、天然ゴム:イソプレン
ゴム=0〜50:100〜50となる範囲で含有し、か
つ、全ゴム成分100重量部に対して、CTAB吸着比
表面積が120m2 /g以上のカーボンブラックを60
重量部〜100重量部、および、補強効果の少ない無機
充填剤を10重量部以上含有することを特徴とする高減
衰支承用ゴム組成物。3. A rubber component containing at least natural rubber and isoprene rubber in a weight ratio of natural rubber: isoprene rubber = 0 to 50: 100 to 50, and 100 parts by weight of all rubber components. On the other hand, carbon black having a CTAB adsorption specific surface area of 120 m 2 / g or more
A rubber composition for a high-damping bearing, comprising from 100 parts by weight to 100 parts by weight, and 10 parts by weight or more of an inorganic filler having a small reinforcing effect.
有することを特徴とする請求項1〜3のいずれかに記載
の高減衰支承用ゴム組成物。4. The rubber composition for high damping bearing according to claim 1, wherein the rubber component contains butadiene rubber.
Priority Applications (2)
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JP2000202214A JP4595171B2 (en) | 2000-07-04 | 2000-07-04 | Rubber composition for high damping bearing |
TW90116038A TWI225879B (en) | 2000-07-04 | 2001-06-29 | High damping rubber composition for bearing |
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JP2000202214A JP4595171B2 (en) | 2000-07-04 | 2000-07-04 | Rubber composition for high damping bearing |
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JP2002020546A5 JP2002020546A5 (en) | 2006-09-28 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006226009A (en) * | 2005-02-18 | 2006-08-31 | Yokohama Rubber Co Ltd:The | Bridge fall prevention device |
JP2006265936A (en) * | 2005-03-24 | 2006-10-05 | Yokohama Rubber Co Ltd:The | Elastic bearing for bridge |
JP2006265935A (en) * | 2005-03-24 | 2006-10-05 | Yokohama Rubber Co Ltd:The | Bridge-falling preventive device |
JP2006274753A (en) * | 2005-03-30 | 2006-10-12 | Yokohama Rubber Co Ltd:The | Elastic bearing for bridge |
JP2006274752A (en) * | 2005-03-30 | 2006-10-12 | Yokohama Rubber Co Ltd:The | Elastic support for bridge |
JP2009269967A (en) * | 2008-05-02 | 2009-11-19 | Bridgestone Corp | Rubber composition for seismic isolation structure |
JP2013181155A (en) * | 2012-03-05 | 2013-09-12 | Nitto Denko Corp | Vibration damping sheet |
JP2013234269A (en) * | 2012-05-09 | 2013-11-21 | Yokohama Rubber Co Ltd:The | Rubber composition for high damping rubber support and high damping rubber support |
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WO1998032794A1 (en) * | 1997-01-22 | 1998-07-30 | The Yokohama Rubber Co., Ltd. | Rubber composition for seismic isolation laminates |
JP2000001576A (en) * | 1998-04-15 | 2000-01-07 | Yokohama Rubber Co Ltd:The | Rubber composition for base isolation laminate |
JP2000038476A (en) * | 1998-07-22 | 2000-02-08 | Yokohama Rubber Co Ltd:The | Rubber composition for high-attenuation laminate and rubber laminate using the same |
JP2000086820A (en) * | 1998-09-16 | 2000-03-28 | Nippon Zeon Co Ltd | Reinforcer-containing coupling treated diene type rubber composition |
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JPH0774292B2 (en) * | 1984-07-18 | 1995-08-09 | 株式会社ブリヂストン | Rubber composition |
JPH0940883A (en) * | 1995-07-27 | 1997-02-10 | Nippon Steel Chem Co Ltd | Carbon black and rubber composition |
JPH09124843A (en) * | 1995-10-31 | 1997-05-13 | Kinugawa Rubber Ind Co Ltd | Rubber composition having high attenuation |
JP3753493B2 (en) * | 1997-02-04 | 2006-03-08 | 横浜ゴム株式会社 | Rubber composition for high damping rubber bearing |
JP3234173B2 (en) * | 1997-05-30 | 2001-12-04 | 鬼怒川ゴム工業株式会社 | High damping rubber composition |
JPH11199714A (en) * | 1998-01-08 | 1999-07-27 | Toyo Tire & Rubber Co Ltd | High-damping rubber composition |
JPH11263879A (en) * | 1998-03-19 | 1999-09-28 | Yokohama Rubber Co Ltd:The | Rubber composition for high-damping laminate |
-
2000
- 2000-07-04 JP JP2000202214A patent/JP4595171B2/en not_active Expired - Fee Related
-
2001
- 2001-06-29 TW TW90116038A patent/TWI225879B/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998032794A1 (en) * | 1997-01-22 | 1998-07-30 | The Yokohama Rubber Co., Ltd. | Rubber composition for seismic isolation laminates |
JP2000001576A (en) * | 1998-04-15 | 2000-01-07 | Yokohama Rubber Co Ltd:The | Rubber composition for base isolation laminate |
JP2000038476A (en) * | 1998-07-22 | 2000-02-08 | Yokohama Rubber Co Ltd:The | Rubber composition for high-attenuation laminate and rubber laminate using the same |
JP2000086820A (en) * | 1998-09-16 | 2000-03-28 | Nippon Zeon Co Ltd | Reinforcer-containing coupling treated diene type rubber composition |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006226009A (en) * | 2005-02-18 | 2006-08-31 | Yokohama Rubber Co Ltd:The | Bridge fall prevention device |
JP2006265936A (en) * | 2005-03-24 | 2006-10-05 | Yokohama Rubber Co Ltd:The | Elastic bearing for bridge |
JP2006265935A (en) * | 2005-03-24 | 2006-10-05 | Yokohama Rubber Co Ltd:The | Bridge-falling preventive device |
JP4561424B2 (en) * | 2005-03-24 | 2010-10-13 | 横浜ゴム株式会社 | Elastic bearing for bridge |
JP4556129B2 (en) * | 2005-03-24 | 2010-10-06 | 横浜ゴム株式会社 | Fall bridge prevention device |
JP4552229B2 (en) * | 2005-03-30 | 2010-09-29 | 横浜ゴム株式会社 | Elastic bearing for bridge |
JP2006274752A (en) * | 2005-03-30 | 2006-10-12 | Yokohama Rubber Co Ltd:The | Elastic support for bridge |
JP2006274753A (en) * | 2005-03-30 | 2006-10-12 | Yokohama Rubber Co Ltd:The | Elastic bearing for bridge |
JP4561441B2 (en) * | 2005-03-30 | 2010-10-13 | 横浜ゴム株式会社 | Elastic bearing for bridge |
JP2009269967A (en) * | 2008-05-02 | 2009-11-19 | Bridgestone Corp | Rubber composition for seismic isolation structure |
JP2013181155A (en) * | 2012-03-05 | 2013-09-12 | Nitto Denko Corp | Vibration damping sheet |
WO2013133161A1 (en) * | 2012-03-05 | 2013-09-12 | 日東電工株式会社 | Vibration-damping sheet |
JP2013234269A (en) * | 2012-05-09 | 2013-11-21 | Yokohama Rubber Co Ltd:The | Rubber composition for high damping rubber support and high damping rubber support |
Also Published As
Publication number | Publication date |
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JP4595171B2 (en) | 2010-12-08 |
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