JP2002011473A - Water treatment device - Google Patents

Water treatment device

Info

Publication number
JP2002011473A
JP2002011473A JP2000196246A JP2000196246A JP2002011473A JP 2002011473 A JP2002011473 A JP 2002011473A JP 2000196246 A JP2000196246 A JP 2000196246A JP 2000196246 A JP2000196246 A JP 2000196246A JP 2002011473 A JP2002011473 A JP 2002011473A
Authority
JP
Japan
Prior art keywords
water
treated
tank
electrolytic cell
treatment apparatus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000196246A
Other languages
Japanese (ja)
Other versions
JP3902386B2 (en
Inventor
Motoki Kawachi
基樹 河内
Tamotsu Kawamura
保 川村
Yozo Kawamura
要藏 河村
Tatsuya Hirota
達哉 廣田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Priority to JP2000196246A priority Critical patent/JP3902386B2/en
Publication of JP2002011473A publication Critical patent/JP2002011473A/en
Application granted granted Critical
Publication of JP3902386B2 publication Critical patent/JP3902386B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a water treatment device with which leak of water to be treated flowing in an electrolytic cell can be prevented. SOLUTION: A water-discharge channel is provided in the electrolytic cell. Thereby, excess water to be treated is discharged to the outside when the water level in the electrolytic cell becomes higher than the prescribed water level due to an accident of a water level control means.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、プール、浴場の浴槽
といった大型の水槽から、ビルの屋上などに配置される
給水槽、一般家庭用の浴槽といった小型の水槽まで、種
々の水槽に貯留された被処理水を滅菌処理することがで
きる、新規な水処理装置に関するものである。
The present invention relates to various types of water tanks, from large water tanks such as pools and bathtubs to small water tanks such as water tanks arranged on the roof of buildings and bathtubs for general households. The present invention relates to a novel water treatment apparatus capable of sterilizing treated water.

【0002】[0002]

【従来の技術】たとえば屋内外に設置されたプール、あ
るいは旅館の浴場や公衆浴場における浴槽などは、その
水質を維持するために定期的に、いわゆる(サラシ粉、
高度サラシ粉)や次亜塩素酸ソーダ(NaCIO)の水
溶液を投入して滅菌処理をする必要がある。しかし従来
は、この作業を、プールや浴場の従業者などが手作業で
行っており、しかもカルキや次亜塩素酸ソーダの水溶液
は刺激性を有するため、とくに営業時間内に投入する際
には十分に注意しながら作業を行わねばならないなど、
処理をするのに大変な労力を要するという問題があっ
た。
2. Description of the Related Art For example, pools installed indoors and outdoors, or bathtubs in inns and public baths are regularly maintained in order to maintain the quality of the water.
It is necessary to throw in an aqueous solution of high-grade salmon powder) or sodium hypochlorite (NaCIO) for sterilization. In the past, however, this work was done manually by employees of pools and baths, and since aqueous solutions of khaki and sodium hypochlorite were irritating, especially when throwing in during business hours, You have to be careful with your work,
There is a problem that it takes a lot of labor to perform the processing.

【0003】またとくにカルキは固形粉末であるため、
投入後、溶解して濃度が均一になるまでに時間を要し、
その間、プールや浴槽を使用できないという問題もあっ
た。また、ビルの屋上などに配置される給水槽や、ある
いは一般家庭用の浴槽の場合は、水道水中に含まれる塩
素イオンの滅菌力のみに頼っているのが現状であり、と
くに給水槽の場合には、内部に藻が繁殖するなどして水
質が悪化することが1つの社会問題ともなっている。
[0003] In particular, since khaki is a solid powder,
After injection, it takes time to dissolve and make the concentration uniform,
During that time, there was a problem that the pool and bathtub could not be used. In addition, in the case of a water tub placed on the roof of a building or a bath tub for ordinary households, the current state of the art only depends on the sterilizing power of chlorine ions contained in tap water, especially in the case of a water tub. One of the social problems is that the water quality deteriorates due to the propagation of algae inside.

【0004】また、一般家庭用の浴槽の場合は通常、ほ
ぼ1〜2日ごとに水を入れ替えるため水質の点で問題は
ないように思われがちであるが、浴槽に接続されたボイ
ラー内は頻繁に清掃できないために雑菌やかびなどが繁
殖しやすく、やはり水質の悪化が懸念される。
[0004] In addition, in the case of a general home tub, it seems that there is usually no problem in terms of water quality because water is replaced approximately every one to two days. Since cleaning cannot be performed frequently, various bacteria and fungi easily propagate, and there is a concern that the water quality may deteriorate.

【0005】この発明の目的は、上記のような種々の水
槽に貯留された被処理水を、簡単かつ効率的に滅菌処理
することができる、新規な水処理装置を提供することに
ある。
An object of the present invention is to provide a novel water treatment apparatus capable of easily and efficiently sterilizing the water to be treated stored in the various water tanks as described above.

【0006】[0006]

【発明が解決しようとする課題】そこで、本願出願人
は、上述のような各水槽に貯留された被処理水を電解槽
に導き、電気化学反応により滅菌処理する水処理装置を
発明した。この発明した水処理装置では、電極を有する
電解槽へ被処理水を供給し、被処理水に対して電気化学
反応(いわゆる電気分解)を施す。施された電気化学反
応により、次亜塩素酸イオン、塩素ガス、HCIO等が
発生し、それらが被処理水に溶けることによって、被処
理水が滅菌されるようになっている。
Therefore, the applicant of the present invention has invented a water treatment apparatus for guiding the water to be treated stored in each of the above-mentioned water tanks to an electrolytic tank and sterilizing the water by an electrochemical reaction. In the water treatment apparatus according to the present invention, the water to be treated is supplied to the electrolytic cell having the electrodes, and the water to be treated is subjected to an electrochemical reaction (so-called electrolysis). Hypochlorite ions, chlorine gas, HCIO, and the like are generated by the applied electrochemical reaction, and these are dissolved in the water to be treated, whereby the water to be treated is sterilized.

【0007】このように電解槽を用い、電気化学反応に
より滅菌をする水処理装置においては、電解槽内の被処
理水の水位を一定範囲に制御すべく、水槽内の水位をフ
ロートスイッチ等を利用して検知し、電解槽への被処理
水の流入量を調整している。
In such a water treatment apparatus that uses an electrolytic cell to sterilize by an electrochemical reaction, the water level in the water tank is controlled by a float switch or the like in order to control the level of the water to be treated in the electrolytic cell within a certain range. Utilization is used to detect and adjust the flow rate of the water to be treated into the electrolytic cell.

【0008】ところが、フロートスイッチが故障した
り、制御装置が誤動作等すると、電解槽内の水位を一定
範囲に制御できなくなり、被処理水が電解槽から溢れ出
す問題があった。
However, if the float switch breaks down or the control device malfunctions, the water level in the electrolytic cell cannot be controlled within a certain range, and the water to be treated overflows from the electrolytic cell.

【0009】被処理水が漏れ出すと、短絡や漏電の心配
がある。とくに、被処理水には高濃度の含塩素化合物が
含まれているので、腐食の問題も懸念され、このような
課題を解決するような水処理装置にする必要があった。
この発明は、上述のような課題を解決し、安全かつ良好
に滅菌処理をすることのできる新規な水処理装置を提供
することを目的とする。
[0009] If the water to be treated leaks, there is a risk of short-circuit and electric leakage. In particular, since the water to be treated contains a high concentration of a chlorine-containing compound, there is a concern about corrosion, and it is necessary to provide a water treatment apparatus that can solve such a problem.
An object of the present invention is to solve the problems described above and to provide a novel water treatment apparatus that can perform sterilization safely and favorably.

【0010】[0010]

【課題を解決するための手段および発明の効果】請求項
1に記載の発明は、被処理水を貯留する水槽と、当該水
槽から導入された被処理水を電気化学反応によって滅菌
する電解槽と、前記被処理水を水槽から電解槽に導入
し、かつ滅菌処理後に水槽に還流させる水処理経路と、
電解槽内の被処理水の水位を検知して電解槽への被処理
水の流入量を調節し、当該電解槽の水位を所定水位に保
つ水位制御手段とを備えた水処理装置において、前記電
解槽は、水位制御手段の故障により電解槽内の水位が前
記所定の水位を超えた場合に、余剰処理水を外部へ排出
する排水経路を有していることを特徴とする水処理装置
である。
According to the first aspect of the present invention, there is provided a water tank for storing water to be treated, and an electrolytic tank for sterilizing the water to be treated introduced from the water tank by an electrochemical reaction. A water treatment path for introducing the water to be treated from the water tank to the electrolytic tank, and for returning the water to the water tank after sterilization;
A water treatment apparatus comprising: a water level control unit configured to detect a water level of the water to be treated in the electrolytic cell, adjust an inflow amount of the water to be treated into the electrolytic cell, and maintain a water level of the electrolytic cell at a predetermined water level. An electrolyzer is a water treatment apparatus characterized by having a drainage path for discharging excess treated water to the outside when the water level in the electrolyzer exceeds the predetermined water level due to failure of the water level control means. is there.

【0011】請求項2の発明は、被処理水を貯留する水
槽と、当該水槽から導入された被処理水を電気化学反応
によって滅菌する電解槽と、前記被処理水を水槽から電
解槽に導入し、かつ滅菌処理後に水槽に還流させる水処
理経路とを備えた水処理装置において、前記電解槽は、
電解槽内の水位が所定の水位を超えた場合に、余剰処理
水を外部へ排出する排水経路を有していることを特徴と
する水処理装置である。
The invention according to claim 2 is a water tank for storing the water to be treated, an electrolytic tank for sterilizing the water to be treated introduced from the water tank by an electrochemical reaction, and introducing the water to be treated from the water tank to the electrolytic tank. And a water treatment path having a water treatment path for returning to the water tank after the sterilization treatment, wherein the electrolytic cell comprises:
A water treatment apparatus characterized by having a drainage path for discharging excess treated water to the outside when the water level in the electrolytic cell exceeds a predetermined water level.

【0012】請求項3の発明は、請求項1又は2記載の
水処理装置において、排水経路は、所定水位を越えた余
剰水のみが流れ出し、電解槽上部内のガスが漏れないよ
うに、一方の端部が電解槽の被処理水中で開口した逆U
字型に屈曲形成された経路を備えていることを特徴とす
る水処理装置である。
According to a third aspect of the present invention, in the water treatment apparatus according to the first or second aspect, the drainage path is provided so that only excess water exceeding a predetermined water level flows out and gas in the upper part of the electrolytic cell does not leak. U whose end is open in the water to be treated in the electrolytic cell
A water treatment apparatus comprising a path bent in a letter shape.

【0013】請求項4の発明は、請求項3記載の水処理
装置において、排水経路の前記逆U字部分の頂部を前記
電解槽の上端開口より若干上方に位置させたことを特徴
とする水処理装置である。
According to a fourth aspect of the present invention, in the water treatment apparatus according to the third aspect, the top of the inverted U-shaped portion of the drainage path is located slightly above the upper end opening of the electrolytic cell. Processing device.

【0014】請求項5の発明は、請求項3に記載の水処
理装置において、排水経路を構成する配管の少なくとも
被処理水と接触する内面を、電気化学反応によって発生
する含塩素化合物に対して耐食性を有する材料にて形成
したことを特徴とする水処理装置である。
According to a fifth aspect of the present invention, in the water treatment apparatus according to the third aspect, at least an inner surface of the pipe constituting the drainage path, which is in contact with the water to be treated, is treated with respect to a chlorine-containing compound generated by an electrochemical reaction. A water treatment apparatus formed of a material having corrosion resistance.

【0015】請求項6の発明は、請求項3に記載の水処
理装置において、排水経路を通じて、オーバーフローし
た被処理水の有無を検知する溢水検知手段を有し、溢水
検知手段の信号に基づいて、被処理水のオバーフローを
検知したら報知動作を行うことを特徴とする水処理装置
である。請求項1又は2の構成によれば、フロートスイ
ッチの故障等により、電解槽の被処理水の水位を所定水
位に維持できなくなった場合でも、所定の水位を超えた
被処理水は排水経路へオーバーフローさせ、ドレン口へ
送られるようになる。従って、溢れた被処理水による短
絡や漏電などのおそれを最小限に抑えることができる。
According to a sixth aspect of the present invention, there is provided the water treatment apparatus according to the third aspect, further comprising an overflow detecting means for detecting the presence or absence of the water to be treated, which overflows through the drainage path, based on a signal from the overflow detecting means. A water treatment apparatus that performs an alerting operation when an overflow of water to be treated is detected. According to the configuration of claim 1 or 2, even when the level of the water to be treated in the electrolytic cell cannot be maintained at the predetermined level due to a failure of the float switch, the water to be treated exceeding the predetermined level is transferred to the drainage path. It overflows and is sent to the drain port. Therefore, it is possible to minimize the risk of a short circuit or a short circuit due to overflowing water to be treated.

【0016】また、請求項3に記載したように、排水経
路を逆U字形状に屈曲させ、一方の端部を電解槽の被処
理水中に開口することによって、排水経路は一方端が常
に被処理水にて閉ざされるので、電気分解で発生した水
素ガスなどが、排水経路に漏洩することがない。これに
より、ガスが不所望に排水経路を通じてドレン口に流入
するおそれがなく、安全性をより一層向上させることが
できるようになる。
Further, as described in claim 3, the drainage path is bent into an inverted U-shape and one end is opened into the water to be treated in the electrolytic cell, so that one end of the drainage path is always covered. Since it is closed with treated water, hydrogen gas generated by electrolysis does not leak to the drainage passage. Thus, there is no possibility that the gas undesirably flows into the drain port through the drain passage, so that the safety can be further improved.

【0017】また、請求項4の構成によれば、排水経路
の逆U字形部分の頂部が電解槽の上端開口より上方に位
置するようになる、これによって、オーバーフロー水が
サイフォン作用を起こさない。従って、所定水位を越え
た余剰水のみ排水でき、サイフォン作用によって不必要
に大量の被処理水が排出されるのを防止できる。
Further, according to the structure of the fourth aspect, the top of the inverted U-shaped portion of the drainage path is located above the upper end opening of the electrolytic cell, whereby overflow water does not cause a siphon action. Therefore, only the surplus water exceeding the predetermined water level can be drained, and it is possible to prevent an undesirably large amount of water to be discharged by the siphon action.

【0018】また、請求項5の構成によれば、排水経路
を構成する配管の少なくとも被処理水と接触する内面
を、電気化学反応によって発生する含塩素化合物に対し
て耐食性を有する材料にて形成しているため、これらの
部材の腐食を防ぎ、水漏れしにくい水処理装置とするこ
とができる。
According to the fifth aspect of the present invention, at least the inner surface of the pipe constituting the drainage path, which is in contact with the water to be treated, is formed of a material having corrosion resistance to chlorine-containing compounds generated by an electrochemical reaction. Therefore, it is possible to prevent the corrosion of these members and to provide a water treatment apparatus that is less likely to leak water.

【0019】また、請求項6の構成によれば、被処理水
が排水経路を通じて、オーバーフローするとブザー等に
より報知されるようになる。ユーザーは報知動作を確認
することにより、電解槽の水位制御の故障に気づき、装
置を停止させたり、故障箇所を応急修理するなど適切な
処置を迅速に行うことができるようになり、万一の水位
制御の故障による被害を最小限度に留めることができ
る。
Further, according to the configuration of claim 6, when the water to be treated overflows through the drainage path, it is notified by a buzzer or the like. By confirming the notification operation, the user becomes aware of a malfunction in the water level control of the electrolytic cell, and can take appropriate measures such as shutting down the device or repairing the faulty part promptly. Damage due to water level control failure can be minimized.

【0020】[0020]

【発明の実施の形態】以下には、図面を参照して、この
発明の実施形態について具体的に説明する。図1は、こ
の発明の一実施形態にかかる水処理装置1を、プールや
浴場の浴槽などの大型の水槽2に組みこんだ構造を簡略
化して示す図である。
Embodiments of the present invention will be specifically described below with reference to the drawings. FIG. 1 is a simplified view showing a structure in which a water treatment apparatus 1 according to an embodiment of the present invention is incorporated in a large water tank 2 such as a pool or a bath tub.

【0021】図に見るように水槽2には、砂ろ過のため
のフィルター21を組みこんだ、循環ポンプ22によっ
て多量の被処理水Wを常時、図中二重実線の矢印で示す
方向に循環させるための主循環経路20が設置されてお
り、水処理装置1の水処理経路10は、図中実線の矢印
で示すように、上記主循環経路20の、フィルター21
より下流側の分岐点J1から分岐して、複数枚の電極板
110…からなる電極組11と、微細気泡除去用のフィ
ルター12とを内蔵した、電解槽を兼ねる気液分離槽1
3を経たのち、上記分岐点J1より下流側の合流点J2
で、再び上記主循環経路20に合流するように接続され
ている。上記水処理経路10の、分岐点J1から気液分
離槽13に至る途上には順に、開閉弁B1、流量調整の
ための調整弁B2、流量計S1、電磁弁B3、および被
処理水をろ過して有機物などを除去するためのフィルタ
ー14が配置されている。
As shown in the figure, a large amount of water W to be treated is always circulated in a water tank 2 by a circulation pump 22 incorporating a filter 21 for sand filtration in the direction indicated by a double solid line arrow in the figure. A main circulation path 20 is provided for the water treatment apparatus 1. The water treatment path 10 of the water treatment apparatus 1 is provided with a filter 21 of the main circulation path 20 as shown by a solid-line arrow in the figure.
A gas-liquid separation tank 1 that also functions as an electrolytic cell and has a built-in electrode set 11 composed of a plurality of electrode plates 110 and a filter 12 for removing fine bubbles, branched from a branch point J1 on the further downstream side.
3 and a junction J2 downstream of the branch point J1.
, So that it is connected again to the main circulation path 20. On the way of the water treatment path 10 from the branch point J1 to the gas-liquid separation tank 13, the on-off valve B1, the regulating valve B2 for adjusting the flow rate, the flow meter S1, the solenoid valve B3, and the water to be treated are sequentially filtered. And a filter 14 for removing organic substances and the like.

【0022】また電磁弁B3とフィルター14との間に
は、被処理水の水圧を測定するための圧力計S3が接続
されている。
A pressure gauge S3 for measuring the pressure of the water to be treated is connected between the solenoid valve B3 and the filter 14.

【0023】この圧力計S3と前記流量計S1とは主
に、主循環経路20から水処理経路10への被処理水の
供給が何らかの原因でストップしたり減少したりして、
気液分離槽13内の水位が所定量以上に低下した際に、
電極組11や、後述する送出用ポンプP1への通電を停
止して運転を停止することで、これらの部材の破損を未
然に防止するために設けられている。
The pressure gauge S3 and the flow meter S1 mainly stop or decrease the supply of the water to be treated from the main circulation path 20 to the water treatment path 10 for some reason.
When the water level in the gas-liquid separation tank 13 drops below a predetermined amount,
It is provided to prevent damage to these members by stopping the operation by stopping the power supply to the electrode set 11 and a delivery pump P1 described later.

【0024】水処理経路10の、気液分離槽13から合
流点J2に至る途上には順に、気液分離槽13内から被
処理水を送出することで、被処理水Wを水処理経路10
内で循環させるためのための送出用ポンプP1、流量計
S4、逆流防止のための逆止弁B7、流量調整のための
調整弁B8、B9、および開閉弁B10が配置されてお
り、また流量計S4と逆止弁B7との間には被処理水の
水圧を測定するための圧力計S5が接続されている。
In the water treatment path 10, the water to be treated is sent out from the gas-liquid separation tank 13 in order on the way from the gas-liquid separation tank 13 to the junction J 2, so that the water to be treated W is transferred to the water treatment path 10.
A pump P1 for circulation in the inside, a flow meter S4, a check valve B7 for preventing backflow, regulating valves B8 and B9 for adjusting flow rate, and an on-off valve B10 are arranged. A pressure gauge S5 for measuring the pressure of the water to be treated is connected between the gauge S4 and the check valve B7.

【0025】この圧力計S5と上記流量計S4とは主
に、水処理経路10から主循環経路20への被処理水の
還流が何らかの原因でストップしたり減少したりして、
気液分離槽13内の水位が所定量以上に上昇した際に、
気液分離槽13の空気導入口131aなどから水が溢れ
るのを防止すべく、開閉弁B1、B10を閉じて、水処
理経路10を主循環経路20から遮断するために設けら
れている。
The pressure gauge S5 and the flow meter S4 mainly stop or decrease the reflux of the water to be treated from the water treatment path 10 to the main circulation path 20 for some reason.
When the water level in the gas-liquid separation tank 13 rises above a predetermined amount,
The opening / closing valves B1 and B10 are closed to shut off the water treatment path 10 from the main circulation path 20 in order to prevent water from overflowing from the air inlet 131a of the gas-liquid separation tank 13.

【0026】気液分離槽13は、図2にも示すように、
その主体をなす箱状の槽本体130と、この槽本体13
0の上部開口130cを塞いで気液分離槽13の上面部
を構成する大蓋体131とで構成されており、このうち
槽本体130内は、前述した微細気泡除去用のフィルタ
ー12によって、2つの気液分離領域130a、130
bに区画されている。
The gas-liquid separation tank 13 is, as shown in FIG.
A box-shaped tank body 130 serving as the main body, and the tank body 13
And a large lid 131 which forms the upper surface of the gas-liquid separation tank 13 by closing the upper opening 130c of the gas tank. The inside of the tank body 130 is formed by the filter 12 for removing fine bubbles. Gas-liquid separation areas 130a, 130
It is divided into b.

【0027】そしてこの2つの気液分離領域130a、
130bのうち、最上流側の気液分離領域130a内
に、前述した複数枚の電極板からなる電極組11が配置
されて、気液分離槽13が、電気化学反応のための電解
槽として兼用されている。また最下流側の気液分離領域
130bの底部には、被処理水の送出口130dが形成
されており、この送出口130dからの、水処理経路1
0の後半部分を形成する配管101上に、前述した送出
用ポンプP1が配置されている。
The two gas-liquid separation areas 130a,
The electrode set 11 composed of a plurality of electrode plates described above is arranged in the gas-liquid separation region 130a on the most upstream side of 130b, and the gas-liquid separation tank 13 also serves as an electrolytic tank for an electrochemical reaction. Have been. Further, an outlet 130d for water to be treated is formed at the bottom of the gas-liquid separation region 130b on the most downstream side, and the water treatment path 1 from this outlet 130d is formed.
The above-mentioned delivery pump P1 is arranged on the pipe 101 forming the latter half of the zero.

【0028】一方、上記気液分離槽13内の、各気液分
離領域130a、130bにおける被処理水Wの水面よ
り上側で、かつフィルター12の上辺より上側には、大
蓋体131との間に隙間が形成されており、それによっ
て気液分離槽13内に、図中一点鎖線の矢印で示すよう
に、上記各気液分離領域130a、130bに亘るガス
流通路13aが形成されている。
On the other hand, in the gas-liquid separation tank 13, above the surface of the water W to be treated in each of the gas-liquid separation regions 130 a and 130 b and above the upper side of the filter 12, A gas flow passage 13a is formed in the gas-liquid separation tank 13 over the gas-liquid separation regions 130a and 130b, as indicated by a dashed line arrow in the drawing.

【0029】また大蓋体131のうち、水流に対するフ
ィルター12の抵抗の影響で、図に見るようにその水位
が最も低くなり、それによって水面上に十分な空間のあ
る、最下流側の気液分離領域130bの直上位置には、
フィルター12で被処理水Wから分離された、微細気泡
に起源するガスを槽外へ強制的に排出するための、吸い
込み型のブロアF1を途中に配置した排気管F2が接続
されており、一方、最上流側の気液分離領域130aの
直上位置には、上記ブロアF1によって、槽外へ排出さ
れるガスに代えて、槽内に空気を導入するための、空気
導入口131aが形成されているとともに、水処理経路
10の前半部分を形成する配管100が接続されてい
る。
In the large lid 131, due to the effect of the resistance of the filter 12 on the water flow, the water level becomes lowest as shown in the figure, whereby the most downstream gas-liquid having a sufficient space above the water surface is provided. At a position immediately above the separation region 130b,
An exhaust pipe F2 in which a suction-type blower F1 is disposed in the middle for forcibly discharging gas originating in fine bubbles separated from the water W to be treated by the filter 12 to the outside of the tank is connected. An air inlet 131a for introducing air into the tank instead of the gas discharged to the outside of the tank is formed by the blower F1 just above the gas-liquid separation area 130a on the most upstream side. In addition, a pipe 100 forming the first half of the water treatment path 10 is connected.

【0030】また、大蓋体131にはフィルター12を
保持した小蓋体132が、大蓋体から分離可能な状態で
配置されている。この小蓋体132はフィルター12の
メンテナンスを行うときに利用される。小蓋体132と
大蓋体の間は図示しないシール部材が設けられていて、
隙間から被処理水やガスが漏れないようにシールされて
いる。
A small lid 132 holding the filter 12 is arranged on the large lid 131 so as to be separable from the large lid. The small lid 132 is used when performing maintenance on the filter 12. A seal member (not shown) is provided between the small lid 132 and the large lid,
Sealed so that water and gas to be treated do not leak from the gap.

【0031】また、大蓋体131の略中央位置には、気
液分離領域130a内の水位を一定範囲に制御する水位
制御手段としてのフロートスイッチSWが、その水位検
知部SW1を、気液分離領域130a内に挿入するよう
に配置されている。
At a substantially central position of the large lid 131, a float switch SW as a water level control means for controlling the water level in the gas-liquid separation area 130a to a certain range is provided. It is arranged to be inserted into the area 130a.

【0032】フロートスイッチSWは、水位検知部SW
1で検知した、最上流側の気液分離領域130a内の、
被処理水Wの水位を検知して、開閉弁B1の開閉や、調
整弁B2による流量の調整を行うことで、槽13への被
処理水の流入量を調整し、それによって、当該領域13
0aの被処理水Wの水位を所定水位に制御するものであ
る。
The float switch SW is provided with a water level detector SW
In the gas-liquid separation region 130a on the most upstream side, which is detected in 1,
By detecting the water level of the water to be treated W and opening and closing the on-off valve B1 and adjusting the flow rate by the regulating valve B2, the inflow of the water to be treated into the tank 13 is adjusted.
The water level of the water W to be treated 0a is controlled to a predetermined water level.

【0033】さらに、気液分離槽の最上流側の側壁に
は、オーバーフローした被処理水を排水する排水管30
が接続されている。この排水管30は側面視逆U字形状
に屈曲形成されており、一方の端部30aが図示しない
ドレン口に接続され、他方の端部30bが気液分離槽の
側壁であって、被処理水に水没する位置に接続されてい
る。他方の端部30bは常に被処理水に水没しているの
で、被処理水Wから分離され槽上部空間に漂っている、
微細気泡に起源するガス等が排水管30へ侵入するのを
防いでいる。
Further, a drain pipe 30 for draining overflowed water to be treated is provided on the most upstream side wall of the gas-liquid separation tank.
Is connected. The drain pipe 30 is bent in an inverted U-shape when viewed from the side. One end 30a is connected to a drain port (not shown), and the other end 30b is a side wall of the gas-liquid separation tank. It is connected to a position submerged in water. Since the other end 30b is always submerged in the water to be treated, it is separated from the water to be treated W and floats in the space above the tank.
This prevents gas or the like originating from the fine bubbles from entering the drain pipe 30.

【0034】また、排水管30は、逆U字部分の内面に
おける下側頂部(図2のA)がフロートスイッチSWで
制御される所定水位時の水面より若干上方に位置し、か
つ、気液分離槽13の上端開口130cより下方に位置
するように配設されている。フロートスイッチSWや開
閉弁B1、調整弁B2の動作不良、制御装置の故障等に
よって、気液分離槽13に流入する被処理水の流入量が
調節できなくなり、気液分離槽13の被処理水Wの水位
を所定水位に制御不能になった場合は、所定水位を超え
て流入する被処理水は、気液分離槽13の上端開口13
0cから溢れる前に排水管30へオーバーフローし、図
示しないドレン口へ排出されるようになる。
The drain pipe 30 has a lower apex (A in FIG. 2) on the inner surface of the inverted U-shaped portion located slightly above the water surface at a predetermined water level controlled by the float switch SW, and The separation tank 13 is disposed below the upper end opening 130c. Due to malfunction of the float switch SW, the opening / closing valve B1, and the regulating valve B2, a failure of the control device, and the like, the inflow amount of the water to be treated flowing into the gas-liquid separation tank 13 cannot be adjusted. When the water level of W becomes uncontrollable to the predetermined water level, the water to be treated that flows in beyond the predetermined water level flows into the upper end opening 13 of the gas-liquid separation tank 13.
Before overflowing from 0c, the water overflows to the drain pipe 30 and is discharged to a drain port (not shown).

【0035】排水管30の逆U字部分内面における上側
頂部(図2のB)は、気液分離槽130の上端開口13
0cより上方位置になるように配設されているので、オ
ーバーフロー水がサイフォン作用を起こさない。これに
より、所定水位を越えた余剰水のみ排水でき、サイフォ
ン作用によって不必要に大量の被処理水が排出されるの
を防止できる。
The upper top (B in FIG. 2) of the inner surface of the inverted U-shaped portion of the drain pipe 30 is provided at the upper end opening 13 of the gas-liquid separation tank 130.
Since it is arranged so as to be located above 0c, the overflow water does not cause a siphon action. Thereby, only the surplus water exceeding the predetermined water level can be drained, and it is possible to prevent an unnecessarily large amount of water to be discharged by the siphon action.

【0036】配管100から気液分離槽13に流入する
被処理水の最大流入量に比べて、排水管30が処理でき
るオーバーフロー水の排水量が多くなるように排水管3
0の断面積を大きくしても、サイフォン作用を防止でき
る。
The drain pipe 3 is set so that the amount of overflow water that can be treated by the drain pipe 30 is larger than the maximum flow rate of the water to be treated flowing into the gas-liquid separation tank 13 from the pipe 100.
Even if the cross-sectional area of 0 is increased, the siphon effect can be prevented.

【0037】また、排水管30の一方端30aの近傍に
は、排水管内に被処理水がオーバーフローしてきたこと
を検知する溢水検知手段39が設けられている。溢水検
知手段39は図3に示すように、例えば、マイクロスイ
ッチ36と排水管30内に挿入された水受板37とから
なり、排水管30内にオーバーフローした被処理水が流
れ込んでくると、被処理水の流入圧力で水受板が押し下
げられることにより、マイクロスイッチ36がONし、
溢水の検知が行われる。38は、水受板37と排水管の
隙間を塞ぐシール材である。
Near the one end 30a of the drain pipe 30, an overflow detecting means 39 for detecting that the water to be treated has overflowed into the drain pipe is provided. As shown in FIG. 3, the overflow detecting means 39 includes, for example, a micro switch 36 and a water receiving plate 37 inserted into the drain pipe 30, and when the water to be treated overflows into the drain pipe 30, When the water receiving plate is pushed down by the inflow pressure of the water to be treated, the micro switch 36 is turned on,
Overflow detection is performed. Reference numeral 38 denotes a seal member that closes a gap between the water receiving plate 37 and the drain pipe.

【0038】溢水検知手段39が、被処理水のオーバー
フローを検知すると、図示しないブザーや表示部等に通
電され、ユーザーに報知される。水位制御の故障によ
り、排水管30内に被処理水がオーバーフローしている
ことは、外部からは容易に察知することができなかった
が、本願では被処理水がオーバーフローするとブザーや
表示部等により報知されるようになる。ユーザーは報知
動作を確認することにより、気液分離槽13の水位制御
の故障に気づき、装置を停止させたり、故障箇所を応急
修理するなど適切な処置を迅速に行うことができるよう
になり、万一の水位制御の故障による被害を最小限度に
留めることができる。
When the overflow detecting means 39 detects the overflow of the water to be treated, a buzzer (not shown) and a display section are energized to notify the user. The fact that the water to be treated overflows in the drain pipe 30 due to the failure of the water level control could not be easily detected from the outside, but in the present application, when the water to be treated overflows, the buzzer, the display unit, or the like is used. Be informed. By confirming the notification operation, the user becomes aware of a failure in the water level control of the gas-liquid separation tank 13 and can quickly take appropriate measures such as stopping the device or repairing the failed part as soon as possible. Damage caused by a failure in water level control can be minimized.

【0039】尚、図示しないが、上記気液分離槽13の
下側に、漏れた被処理水の受け皿を配置させてもよい。
万が一、気液分離槽13で水漏れが発生したとしても、
漏れた被処理水による短絡や漏電などのおそれを、最小
限に抑えることができる。
Although not shown, a tray for leaking water to be treated may be arranged below the gas-liquid separation tank 13.
Even if a leak occurs in the gas-liquid separation tank 13,
The risk of a short circuit or a short circuit due to leaked water to be treated can be minimized.

【0040】電極組11を構成する電極板110として
は、例えばチタン(Ti)製の基板の表面全面に金(A
u)、白金(Pt)、パラジウム(Pd)、白金−イリ
ジウム(Pt−Ir)などの貴金属の薄膜を、めっき法
や焼成処理によってコーティングしたものなどが使用さ
れる。
The electrode plate 110 constituting the electrode set 11 is made of, for example, gold (A) on the entire surface of a titanium (Ti) substrate.
u), a thin film of a noble metal such as platinum (Pt), palladium (Pd), or platinum-iridium (Pt-Ir), which is coated by a plating method or a baking treatment, is used.

【0041】微細気泡除去用のフィルター12や、有機
物等を除去するフィルター14としては、いずれも天然
あるいは化学繊維製の不織布などが使用される。中でも
特に微細気泡除去用のフィルター12としては、当該フ
ィルター12が、電極組11による電気化学反応の直後
に配置されるため、ポリプロピレン繊維などの、電気化
学反応によって発生する含塩素化合物や活性酸素等に対
して十分な耐性を有する繊維で形成され、しかも微細気
泡を容易に透過させないために、目の細かい不織布が好
適に使用される。
As the filter 12 for removing fine bubbles and the filter 14 for removing organic substances and the like, nonwoven fabrics made of natural or chemical fibers are used. Among them, particularly as the filter 12 for removing fine bubbles, since the filter 12 is disposed immediately after the electrochemical reaction by the electrode set 11, a chlorine-containing compound such as polypropylene fiber or active oxygen generated by the electrochemical reaction is used. A nonwoven fabric with a fine mesh is preferably used because it is formed of fibers having a sufficient resistance to water and does not easily transmit fine bubbles.

【0042】上記各部を備えた水処理装置1を用いて、
水槽2内の被処理水Wを滅菌処理するには、まず通常ど
おり循環ポンプ23を作動させて、主循環経路20内
を、図1に二重実線の矢印で示すように多量の被処理水
Wを常時、循環させながら、送出用ポンプP1を作動さ
せるとともに、開閉弁B1、B10を開く。そうする
と、主循環経路20内を循環している被処理水Wの一部
が、主に主循環経路20の内圧と、大気圧下にある気液
分離槽13との圧力差によって水処理経路10内に流入
して、まず調整弁B2を通って流量が調整され、ついで
流量計S1で流量が、残留塩素センサー(図示せず)で
残留塩素濃度が、そして圧力計S3で水圧が、それぞれ
測定されたのち、フィルター14に送られて有機物など
が除去される。上記調整弁B2による流量の調整は、流
量計S1の測定流量に応じて調整される。
Using the water treatment apparatus 1 having the above-mentioned components,
To sterilize the water W to be treated in the water tank 2, first, the circulation pump 23 is operated as usual, and a large amount of the water to be treated is passed through the main circulation path 20 as shown by a double solid line arrow in FIG. 1. While constantly circulating W, the delivery pump P1 is operated and the on-off valves B1, B10 are opened. Then, a part of the water to be treated W circulating in the main circulation path 20 is mainly changed by the pressure difference between the internal pressure of the main circulation path 20 and the gas-liquid separation tank 13 under atmospheric pressure. First, the flow rate is adjusted through a regulating valve B2, then the flow rate is measured by a flow meter S1, the residual chlorine concentration is measured by a residual chlorine sensor (not shown), and the water pressure is measured by a pressure gauge S3. After that, it is sent to the filter 14 to remove organic substances and the like. The adjustment of the flow rate by the adjustment valve B2 is adjusted according to the measured flow rate of the flow meter S1.

【0043】つぎに被処理水は、気液分離槽13の最上
流側の気液分離領域130aに送られて、当該領域13
0a内で、図示しない残留塩素センサーによって測定さ
れた残留塩素濃度の測定結果などに基づいて電極組11
に通電することで、電気化学反応によって滅菌処理され
たのち、フィルター12を透過して下流側の気液分離領
域130bに順次、送られて行く間に、前記の機構によ
って微細気泡が除去されて、見た目もきれいな澄んだ状
態とされる。
Next, the water to be treated is sent to the gas-liquid separation area 130a on the most upstream side of the gas-liquid separation tank 13, and
0a, the electrode set 11 based on the measurement result of the residual chlorine concentration measured by the residual chlorine sensor (not shown).
After being sterilized by an electrochemical reaction by passing electricity through, fine bubbles are removed by the above-described mechanism while being sent through the filter 12 and sequentially to the downstream gas-liquid separation region 130b. , It looks beautiful and clear.

【0044】またこの際に被処理水から除去された、微
細気泡に起源するガスは、ブロアF1を運転することで
発生する、空気導入口131aから吸い込み口131b
へ流れる空気の流れに乗って気液分離槽13内から除去
され、排気管F2を通って、図中黒矢印で示すように室
外や排気口など(図示せず)へ排出される。
At this time, the gas removed from the water to be treated and originating from the microbubbles is generated by operating the blower F1.
It is removed from inside the gas-liquid separation tank 13 along with the flow of air flowing to the outside, and is discharged through the exhaust pipe F2 to the outside of the room or an exhaust port (not shown) as shown by the black arrow in the figure.

【0045】一方、滅菌処理が完了し、微細気泡が除去
された被処理水は、送出用ポンプP1の働きによって、
最下流側の気液分離領域130dから、その底部に設け
た送出口130dを通って槽外に送出され、流量計S
4、逆止弁B7、調整弁B8、B9、および開閉弁B1
0を通って合流点J2で主循環経路20に戻され、水槽
2に還流される。
On the other hand, the water to be treated, from which the sterilization has been completed and from which the fine bubbles have been removed, is operated by the delivery pump P1.
From the gas-liquid separation region 130d on the most downstream side, the gas is sent out of the tank through a delivery port 130d provided at the bottom thereof, and the flow meter S
4. Check valve B7, regulating valves B8, B9, and on-off valve B1
The water is returned to the main circulation path 20 at the junction J2 through the zero, and is returned to the water tank 2.

【0046】上記各部を備えた水処理装置1は、実際に
は、図4に示すように上記各部やそれを駆動するための
電源装置31、制御装置(シーケンサー)32、気液分
離槽13、ブレーカ33等を、適当な大きさのキャビネ
ット34内に配置するとともに、上記各部のうちポンプ
類、フィルター類、圧力計等の、定期的な、あるいは不
定期のメンテナンスを行う必要がある部材をキャビネッ
ト34外に配置するなどしてユニット化した状態で、プ
ールなどの設備内に設置される。
As shown in FIG. 4, the water treatment apparatus 1 having the above-described components is actually a power supply device 31 for driving the components, a control device (sequencer) 32, a gas-liquid separation tank 13, The breaker 33 and the like are arranged in a cabinet 34 of an appropriate size, and the members, such as pumps, filters, and a pressure gauge, which need to be subjected to regular or irregular maintenance, such as pumps, filters, and pressure gauges, are installed in the cabinet. It is installed in a facility such as a pool in a unitized state, for example, by being placed outside the unit 34.

【0047】キャビネット34は一方の側面にメンテナ
ンス用の開口が設けられた箱体で形成されていて、前記
メンテナンス用開口には横開き式の扉35が設けられて
いる。キャビネット34内の上段位置には、制御装置3
2、ブレーカー33、電源装置31及び、図示しない計
器類や操作スイッチ等が配設されている、そして、下段
位置には、気液分離槽13がそのフィルター12が配置
されている側を扉35側に、電極が配置されている側を
奥側にして配設されている。
The cabinet 34 is formed of a box having a maintenance opening on one side, and a horizontal opening door 35 is provided in the maintenance opening. The control device 3 is located at the upper position in the cabinet 34.
2, a breaker 33, a power supply device 31, and instruments and operation switches (not shown) are provided. In the lower position, the gas-liquid separation tank 13 has a door 35 on the side where the filter 12 is disposed. On the side, the side on which the electrodes are arranged is arranged on the back side.

【0048】気液分離槽13においては、電極11に比
べてフィルター12の方がメンテナンスを必要とする頻
度が高く、気液分離槽13におけるフィルター12側を
キャビネット24の扉35側に配置することにより、メ
ンテナンスにおける作業性を向上させることができる。
この発明は、以上で説明した実施形態に限定されるもの
ではなく、請求項記載の範囲内において種々の変更が可
能である。
In the gas-liquid separation tank 13, the filter 12 requires maintenance more frequently than the electrode 11, and the filter 12 side of the gas-liquid separation tank 13 is arranged on the door 35 side of the cabinet 24. Thereby, workability in maintenance can be improved.
The present invention is not limited to the embodiments described above, and various changes can be made within the scope of the claims.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施形態にかかる水処理装置を簡略
化して示す図。
FIG. 1 is a simplified diagram showing a water treatment apparatus according to an embodiment of the present invention.

【図2】上記水処理装置の要部である、気液分離槽の概
略断面図。
FIG. 2 is a schematic sectional view of a gas-liquid separation tank, which is a main part of the water treatment apparatus.

【図3】溢水検知手段の構造を示す部分断面図。FIG. 3 is a partial cross-sectional view showing the structure of the overflow detecting means.

【図4】本発明の各部をキャビネットに配置した概略断
面図。
FIG. 4 is a schematic cross-sectional view in which components of the present invention are arranged in a cabinet.

【符号の説明】[Explanation of symbols]

1 水処理装置 13 電解槽(気液分離槽) 30 排水経路 SW 水位制御手段 DESCRIPTION OF SYMBOLS 1 Water treatment apparatus 13 Electrolysis tank (gas-liquid separation tank) 30 Drainage path SW Water level control means

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C02F 1/50 560 C02F 1/50 560F (72)発明者 河村 要藏 大阪府守口市京阪本通2丁目5番5号 三 洋電機株式会社内 (72)発明者 廣田 達哉 大阪府守口市京阪本通2丁目5番5号 三 洋電機株式会社内 Fターム(参考) 4D061 DA07 DB01 DB09 EA02 EB01 EB37 EB39 FA03 FA13 GA04 GC02 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C02F 1/50 560 C02F 1/50 560F (72) Inventor Kazura Kawamura 2-chome Keihanhondori, Moriguchi-shi, Osaka No. 5-5 Sanyo Electric Co., Ltd. (72) Inventor Tatsuya Hirota 2-5-5 Keihanhondori, Moriguchi-shi, Osaka F-term in Sanyo Electric Co., Ltd. 4D061 DA07 DB01 DB09 EA02 EB01 EB37 EB39 FA03 FA13 GA04 GC02

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】被処理水を貯留する水槽と、当該水槽から
導入された被処理水を電気化学反応によって滅菌する電
解槽と、前記被処理水を水槽から電解槽に導入し、かつ
滅菌処理後に水槽に還流させる水処理経路と、電解槽内
の被処理水の水位を検知して電解槽への被処理水の流入
量を調節し、当該電解槽の水位を所定水位に保つ水位制
御手段とを備えた水処理装置において、 前記電解槽は、水位制御手段の故障により電解槽内の水
位が前記所定の水位を超えた場合に、余剰処理水を外部
へ排出する排水経路を有していることを特徴とする水処
理装置。
1. A water tank for storing the water to be treated, an electrolytic tank for sterilizing the water to be treated introduced from the water tank by an electrochemical reaction, and introducing the water to be treated from the water tank into the electrolytic tank and performing a sterilization treatment. A water treatment path to be returned to the water tank later, and a water level control means for detecting the level of the water to be treated in the electrolytic cell and adjusting the inflow amount of the water to be treated into the electrolytic cell to keep the water level of the electrolytic cell at a predetermined level Wherein the electrolytic cell has a drainage path for discharging excess treated water to the outside when the water level in the electrolytic cell exceeds the predetermined water level due to a failure in water level control means. A water treatment apparatus, characterized in that:
【請求項2】被処理水を貯留する水槽と、当該水槽から
導入された被処理水を電気化学反応によって滅菌する電
解槽と、前記被処理水を水槽から電解槽に導入し、かつ
滅菌処理後に水槽に還流させる水処理経路とを備えた水
処理装置において、 前記電解槽は、電解槽内の水位が所定の水位を超えた場
合に、余剰処理水を外部へ排出する排水経路を有してい
ることを特徴とする水処理装置。
2. A water tank for storing the water to be treated, an electrolytic tank for sterilizing the water to be treated introduced from the water tank by an electrochemical reaction, and introducing the water to be treated into the electrolytic tank from the water tank and performing a sterilization treatment. In a water treatment apparatus provided with a water treatment path for returning to a water tank later, the electrolytic tank has a drainage path for discharging excess treated water to the outside when the water level in the electrolytic tank exceeds a predetermined water level. A water treatment apparatus, characterized in that:
【請求項3】前記排水経路は、所定水位を越えた余剰水
のみが流れ出し、電解槽上部内のガスが漏れないよう
に、一方の端部が電解槽の被処理水中で開口した逆U字
型に屈曲形成された経路を備えていることを特徴とする
請求項1又は2に記載の水処理装置。
3. An inverted U-shaped drain passage having one end opened in the water to be treated in the electrolytic cell so that only excess water exceeding a predetermined water level flows out and gas in the upper part of the electrolytic cell does not leak. The water treatment apparatus according to claim 1, further comprising a path bent in a mold.
【請求項4】前記排水経路の前記逆U字部分の頂部を前
記電解槽の上端開口より若干上方に位置させたことを特
徴とする請求項3に記載の水処理装置。
4. The water treatment apparatus according to claim 3, wherein the top of the inverted U-shaped portion of the drainage path is located slightly above an upper end opening of the electrolytic cell.
【請求項5】前記排水経路を構成する配管の少なくとも
被処理水と接触する内面を、電気化学反応によって発生
する含塩素化合物に対して耐食性を有する材料にて形成
したことを特徴とする請求項3に記載の水処理装置。
5. The pipe according to claim 1, wherein at least an inner surface of said pipe which is in contact with the water to be treated is made of a material having corrosion resistance to chlorine-containing compounds generated by an electrochemical reaction. 4. The water treatment device according to 3.
【請求項6】前記排水経路を通じて、オーバーフローし
た被処理水の有無を検知する溢水検知手段を有し、 溢水検知手段の信号に基づいて、被処理水のオバーフロ
ーを検知したら報知動作を行うことを特徴とする請求項
3に記載の水処理装置。
6. An overflow detecting means for detecting the presence or absence of water to be treated overflowing through the drainage path, and performing a notification operation when an overflow of the water to be treated is detected based on a signal from the overflow detecting means. The water treatment apparatus according to claim 3, wherein
JP2000196246A 2000-06-29 2000-06-29 Water treatment equipment Expired - Lifetime JP3902386B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000196246A JP3902386B2 (en) 2000-06-29 2000-06-29 Water treatment equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000196246A JP3902386B2 (en) 2000-06-29 2000-06-29 Water treatment equipment

Publications (2)

Publication Number Publication Date
JP2002011473A true JP2002011473A (en) 2002-01-15
JP3902386B2 JP3902386B2 (en) 2007-04-04

Family

ID=18694778

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000196246A Expired - Lifetime JP3902386B2 (en) 2000-06-29 2000-06-29 Water treatment equipment

Country Status (1)

Country Link
JP (1) JP3902386B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006247638A (en) * 2005-02-09 2006-09-21 Sanyo Electric Co Ltd Water treatment apparatus
JP2011072873A (en) * 2009-09-29 2011-04-14 Sumitomo Heavy Industries Marine & Engineering Co Ltd Ballast water treatment apparatus
JP2015192966A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator
JP2015192967A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator
JP2015192968A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006247638A (en) * 2005-02-09 2006-09-21 Sanyo Electric Co Ltd Water treatment apparatus
JP4557813B2 (en) * 2005-02-09 2010-10-06 三洋電機株式会社 Water treatment equipment
JP2011072873A (en) * 2009-09-29 2011-04-14 Sumitomo Heavy Industries Marine & Engineering Co Ltd Ballast water treatment apparatus
JP2015192966A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator
JP2015192967A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator
JP2015192968A (en) * 2014-03-31 2015-11-05 Toto株式会社 Sterilizing water generator

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