JP2001302456A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a cosmetic which gives a good refreshing touch, when coated on lip and skin, does not cause the unpleasant touches of the lip and the skin, such as the dryness, stiff touch and the like of the lip and the skin after coated, retains a moist touch, and has excellent storage stability, makeup effect retainability, especially an excellent transfer-preventing effect. SOLUTION: This cosmetic characterized by comprising a crosslinked organopolysiloxane, an organic silicone resin, a volatile silicone, a non-volatile liquid oil, an amorphous fine particle silica having particle diameters of 0.001 to 0.05 μm and a spherical powdery material having particle diameters of 0.1 to 30 μm, and not containing a solid wax.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

[0001] The present invention relates to cosmetics, and more specifically, to lipsticks, eye shadows, eyeliners, blushers,
And an oily cosmetic such as a foundation. In particular, the present invention provides a refreshing and good feeling of use when applied to skin such as lips, eyes, and cheeks, and also has an inconvenience such as dryness, firmness, and powdery feel of lips and skin after application. The present invention relates to a cosmetic composition which has no pleasure and has a long-lasting cosmetic effect, especially an excellent anti-transfer effect, and excellent storage stability.

[0002]

2. Description of the Related Art Oil-based cosmetics are widely used in lipsticks, eye shadows, eyeliners, blushers, foundations and the like because of their excellent adhesion, water resistance and covering power. In general, oily cosmetics comprise a pigment dispersed in an oily base composed of a liquid, semi-solid, or solid oil, or an oily base obtained by solidifying a liquid oil with a gelling agent.

[0003]

However, conventional oil-based cosmetics have disadvantages such as a feeling of stickiness and oiliness due to a large oil content. Therefore, in order to obtain a good feeling of use, gels of a silicone polymer having a three-dimensional cross-linked structure and a low-viscosity silicone (Japanese Patent No. 2105655, Japanese Patent No. 2561857, and Japanese Patent No. 256185)
No. 8 and Japanese Patent No. 25822275) have been proposed, but the stickiness and oiliness are eliminated, but the storage stability is poor such as separation of oil from the pigment-dispersed product. Had. In order to improve these, a large amount of cross-linked organopolysiloxane may be added, but there is a problem that the powder is dried and gives a powdery feeling of use.

[0004] Further, as an oil-based cosmetic having a long lasting cosmetic effect, especially an excellent anti-transfer effect, a makeup cosmetic containing an organic silicone resin, a volatile silicone oil and a powder (Japanese Patent Publication No. 6-15452). However, the feeling of use was not satisfactory. In particular, the silicone oil dries after being volatilized, has a powdery feel and a tight feeling of the film, and has a drawback that the gloss of the film is lost. To improve these, a large amount of non-volatile oil may be added, but there is a problem that the effect of preventing transfer is reduced.

[0005] Further, an oil-based cosmetic containing an organic silicone resin, a volatile silicone, a solid wax and a paste-like silicone, which has solved the above problem (Japanese Patent Laid-Open No. 9-17 / 1997).
No. 5990) has been proposed. Although this cosmetic had a moist feeling and an effect of preventing makeup collapse, the refreshing feel was lost and the feeling of use was unsatisfactory.

An object of the present invention is to solve the above-mentioned problems. That is, the present invention provides a refreshing and good feeling of use when applied to the skin such as the lips, and does not cause discomfort such as drying of the skin of the lips or the like after application, a feeling of tightness of the film, and a powdery finish, It is another object of the present invention to obtain a cosmetic composition that has a long lasting cosmetic effect, particularly an excellent anti-transfer effect, and excellent storage stability.

[0007]

According to the present invention, there is provided (1) a cross-linked organopolysiloxane, an organic silicone resin, a volatile silicone, a non-volatile liquid oil, and a particle size of 0.001. A cosmetic containing amorphous silica fine particles having a particle diameter of 0.1 to 30 μm and spherical powder having a particle diameter of 0.1 to 30 μm, and containing no solid wax;

(2) 0.01 to 20% by weight of a crosslinked organopolysiloxane and 1 to 30% of an organic silicone resin
%, Volatile silicone 10 to 60% by weight, non-volatile liquid oil 1 to 30% by weight, particle size 0.001 to 0.0
5 to 10% by weight of amorphous silica fine particles having a particle size of 0.1 to 30
(1) The cosmetic composition according to (1), wherein

(3) The cosmetic according to (1) or (2), wherein the crosslinked organopolysiloxane contains at least one selected from the group consisting of a crosslinked alkylaryl polysiloxane and a crosslinked dialkylpolysiloxane. ,

[0010] (4) the organic silicone resin, R ¹ ₃ SiO
R ¹ ₃ SiO _{1 wherein} the ratio of _1/2 unit (R ¹ is a hydrocarbon group having 1 to 6 carbon atoms or phenyl group) to SiO ₂ unit is in the range of 0.5 to 1.5: 1, (1)-(3) cosmetics comprising _{/ 2} units and SiO ₂ units, and

(5) The volatile silicone is selected from the group consisting of a low-molecular-weight linear polysiloxane represented by the general formula (1) and a low-molecular-weight cyclic polysiloxane represented by the general formula (2). At least one (1)
~ (4) cosmetics.

[0012]

Embedded image (However, R ² in the formula represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ² may be the same or different. M is 0. Represents an integer of 3 to 3)

[0013]

Embedded image

(Wherein, R ³ represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ³ may be the same or different. N is 4.
Represents an integer of from 6 to 6. )

[0015]

BEST MODE FOR CARRYING OUT THE INVENTION Cross-linked organopolysiloxane The cross-linked organopolysiloxane used in the present invention is a polymer obtained by cross-linking an organopolysiloxane, and has a three-dimensional structure partially or entirely.

The cross-linked organopolysiloxane used in the present invention includes (a) an organopolysiloxane having at least two lower alkenyl groups per molecule in the presence of a platinum catalyst, and (b) at least two silicon atoms per molecule. A crosslinked organopolysiloxane obtained by an addition reaction and a crosslinking reaction of an organopolysiloxane having a hydrogen atom bonded to an atom can be used. In addition, the following crosslinked organopolysiloxanes can also be used. (1) R ₂ SiO unit, RSiO _1.5 unit, R ₃ SiO _0.5 unit and SiO ₂
At least R ₂ SiO unit, RSiO _1.5 unit and R ₃ Si
O is a crosslinked organopolysiloxane containing _0.5 units, wherein R is each independently a hydrogen atom, an alkyl group such as a methyl group, an ethyl group, and a propyl group, or an aryl group such as a phenyl group and a trimethyl group, or A crosslinked organopolysiloxane which represents an unsaturated aliphatic group such as a vinyl group and has a weight ratio of R ₂ SiO units to RSiO _1.5 units in the range of 1 to 30: 1. (2) (c) an organohydropolysiloxane, and (d)
It can be obtained by addition with an organopolysiloxane having an unsaturated aliphatic group, and the amount of hydrogen or unsaturated aliphatic group in (c) and (d) is 1 when the organopolysiloxane is acyclic. A crosslinked organohydropolysiloxane in the range of 1 to 20 mol%, and 1 to 50 mol% when the organopolysiloxane is cyclic.

Suitable cross-linked organopolysiloxanes in the present invention include, for example, cross-linked alkylaryl polysiloxanes and cross-linked alkyl polysiloxanes. As the crosslinked alkylaryl polysiloxane, for example, an alkyl group having 1 to 5 carbon atoms and 6 carbon atoms
Examples thereof include crosslinked organopolysiloxanes having 10 to 10 aryl groups, and more specifically, for example, methylphenylpolysiloxane, ethylphenylpolysiloxane, and the like. Examples of the crosslinked alkylpolysiloxane include a crosslinked monoalkylpolysiloxane and a crosslinked dialkylpolysiloxane having an alkyl group having 1 to 5 carbon atoms, and more specifically, for example, a crosslinked monomethylpolysiloxane ,
Examples include cross-linked dimethylpolysiloxane, cross-linked monoethyl polysiloxane, cross-linked diethyl polysiloxane, cross-linked methyl ethyl polysiloxane, and the like. In the present invention, for example, paste-like KSG15 (Shin-Etsu Chemical Co., Ltd.), which is a mixture of decamethylcyclopentasiloxane and a crosslinked organopolysiloxane, and a low viscosity dimethylpolysiloxane and a crosslinked organopolysiloxane are used. Paste-like KS which is a mixture
Commercially available products such as G16 (Shin-Etsu Chemical Co., Ltd.) and KSG18 (Shin-Etsu Chemical Co., Ltd.), which is a mixture of methylphenylpolysiloxane and cross-linked organopolysiloxane, are used as cross-linked organopolysiloxane. You can also.

The crosslinked organopolysiloxane used in the present invention is excellent in oil gelling ability. They are,
Provides desirable cosmetic properties without drying the skin. The composition derived from this crosslinked organopolysiloxane is comfortable to use, soft, and non-sticky to the touch. The softness is due in part to the tissue structure of the crosslinked organopolysiloxane and the other is due to properties comparable to microsponges that trap oil. In addition, the non-volatile oil is confined, in particular, to the property of preventing color transfer.

The content of the crosslinked organopolysiloxane in the present invention is preferably from 0.01 to 20% by weight, particularly preferably from 0.1 to 15% by weight. In the present invention, the object of the present invention can be achieved by containing a crosslinked organopolysiloxane,
In the case of the above content, a refreshing feeling is obtained, and a glossy coating film can be obtained without drying the lips and skin.

2. The organic silicone resin to be used in the organosilicone resin invention R ¹ ₃ SiO
R ¹ ₃ SiO _{1 wherein} the ratio of _1/2 unit (R ¹ is a hydrocarbon group having 1 to 6 carbon atoms or phenyl group) to SiO ₂ unit is in the range of 0.5 to 1.5: 1, in _{/ 2} units and an organic silicone resin comprising SiO ₂ units, obtained by hydrolyzing the corresponding known silanes. Commercially available products include KF-7312F, an organic silicone resin diluted with octamethylcyclotetrasiloxane (Shin-Etsu Chemical Co., Ltd.), and KF-7312J, an organic silicone resin diluted with decamethylcyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) )), KF-7312K (Shin-Etsu Chemical Co., Ltd.) obtained by diluting an organic silicone resin with dimethylpolysiloxane, DC59
3, and BY11-018 (Dow Corning Toray Silicone Co., Ltd.).

The content of the organic silicone resin used in the present invention is preferably 1 to 30% by weight, and 5 to 25%.
Is particularly preferred. In the present invention, the object of the present invention can be achieved by containing the organic silicone resin. However, in the case of the above content, a good cosmetic continuation effect, particularly a good transfer prevention effect can be obtained.

3. Volatile Silicone The volatile silicone used in the present invention includes, for example, a low molecular weight linear polyorganosiloxane represented by the general formula (1) and a low molecular weight cyclic polysiloxane represented by the general formula (2). be able to.

[0023]

Embedded image (However, R ² in the formula represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ² may be the same or different. M is 0. Represents an integer of 3 to 3)

[0024]

Embedded image

(Wherein, R ³ represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ³ may be the same or different. N is 4.
Represents an integer of from 6 to 6. )

The above-mentioned linear organopolysiloxane and cyclic siloxane are volatile, having a molecular weight of 450 or less.

Examples of the linear organopolysiloxane include a linear alkylpolysiloxane having an alkyl group having 1 to 5 carbon atoms, an alkyl group having 1 to 5 carbon atoms and an aryl group having 6 to 10 carbon atoms. A linear alkylaryl polysiloxane having a group can be exemplified. As the linear alkyl polysiloxane, linear monomethyl polysiloxane, linear monoethyl polysiloxane, and linear monopropyl polysiloxane such as linear monoalkyl polysiloxane, and linear dimethyl polysiloxane, Examples include linear dialkyl polysiloxanes such as linear methyl ethyl polysiloxane, linear diethyl polysiloxane, and linear dipropyl polysiloxane. Examples of the linear alkylaryl polysiloxane include a linear methylphenyl polysiloxane and a linear ethylphenyl polysiloxane. Examples of the cyclic siloxane include a 4- to 6-membered cyclic siloxane containing an alkyl group having 1 to 5 carbon atoms as a substituent, and specific examples thereof include octamethylcyclotetrasiloxane and decamethylcyclosiloxane. Pentasiloxane and the like can be mentioned.

The volatile silicone content used in the present invention is preferably 10 to 60% by weight, and 20 to 50% by weight.
Is particularly preferred. In the present invention, the purpose of the present invention can be achieved well by containing a volatile silicone, but in the case of the above-mentioned content, in particular, a refreshing good feeling of use and a good makeup lasting effect are obtained. .

4. Non-volatile liquid oil Examples of the non-volatile liquid oil used in the present invention include liquid oils used in ordinary cosmetics and the like. For example,
Vegetable oils such as safflower oil, soybean oil, grape seed oil, sesame oil, wheat germ oil, avocado oil, olive oil, castor oil, macadamia nut oil, and medofoam oil, mink oil,
Turtle oil, animal oils such as liquid lanolin, liquid paraffin, squalane, heavy liquid isoparaffin, and hydrocarbons such as polybutene, isopropyl myristate,
Fatty acid esters of lower alcohols such as isopropyl isostearate and isopropyl lanolin fatty acid, 2-ethylhexyl isononanoate, octyldodecyl myristate, octyldodecyl oleate, cetyl 2-ethylhexanoate, isocetyl 2-ethylhexanoate, and isoisostearate Fatty acid esters of higher alcohols such as stearyl, oxyesters of higher alcohols such as diisostearyl malate and cetyl lactate, glyceryl tricaprylate, glyceryl tri-2-ethylhexanoate, glyceryl triisostearate, tri (caprylic caprin) Acid) glycerin, propylene glycol dicaprylate, propylene glycol di (caprylate / caprate), propylene glycol diisostearate, and 2-ethyl Fatty acid esters of polyhydric alcohols such as neopentyl glycol xanate, silicone oils such as methylpolysiloxane and methylphenylpolysiloxane, higher fatty acids such as oleic acid, erucic acid, linoleic acid and isostearic acid, oleyl alcohol, isostearyl Examples include higher alcohols such as alcohols, and fluoro oils such as perfluoropolyethers and perfluorocarbons.

In the present invention, it is prepared by using one or more of these nonvolatile liquid oils.

[0031] The content of the non-volatile liquid oil used in the present invention is preferably in the range of 1 to 30% by weight, particularly preferably in the range of 5 to 20% by weight, based on the total amount of the solid cosmetic. In the present invention, the object of the present invention can be achieved well by containing a non-volatile liquid oil.However, in the above-mentioned range, the skin such as lips, eyes and cheeks is not dried, and The film is shiny, and a good feeling of use is obtained.

5. Amorphous fine particle silicic acid Amorphous fine particle silicic acid used in the present invention,
0.001 to 0.01 μm, preferably 0.00
Amorphous silicic acid having a particle size in the range of 1 to 0.02 μm. In the case of the amorphous silica fine particles having a particle diameter within the above range, a good feeling of use without creaking and a good stability without separation of oil can be obtained. The particle size of the amorphous fine particles of silicic acid is measured by a transmission electron microscope.

The amorphous fine particles of silica used in the present invention include, for example, hydrophilic silica having a particle diameter in the above range, obtained by hydrolyzing ordinary silicon tetrachloride in a hydrogen / oxygen flame. The finely divided anhydrous silicic acid and the amorphous finely divided silica obtained by hydrophobizing the surface of the hydrophilic, irregularly shaped finely divided silica can be exemplified. The amorphous fine particles of silicic acid anhydride may be hydrophilic or hydrophobic.

As the method of the above-mentioned hydrophobizing treatment, trimethylsiloxylation treatment with trimethylsilyl chloride and hexamethyldisilazane, methylation treatment with dimethyldichlorosilane, coating baking treatment using methylhydrogenpolysiloxane, and dimethylpolysilicon Coating with siloxane, metal soap and the like.

Aerosil 200 (produced by Nippon Aerosil Co., Ltd.), Aerosil 300 (produced by Nippon Aerosil Co., Ltd.), Aerosil R97
2 (manufactured by Nippon Aerosil Co., Ltd.), Aerosil R974
Commercial products such as (Nippon Aerosil Co., Ltd.), Aerosil R202 (Nippon Aerosil Co., Ltd.), Aerosil RY200 (Nippon Aerosil Co., Ltd.), and Taranox 500 (Talco Co., Ltd.) are exemplified.

The content of the amorphous fine particles of silicic anhydride is preferably in the range of 0.1 to 10% by weight, particularly preferably in the range of 0.1 to 5% by weight, based on the total amount of the solid cosmetic. In the present invention, the object of the present invention can be achieved well by containing amorphous fine particles of silicic acid anhydride.However, in the case of the above-mentioned content, a good feeling of use without causing creaking and an oil component are separated. Good stability without the need to perform, and a good long-lasting cosmetic effect.

6. Spherical powder The spherical powder used in the present invention includes inorganic powders such as calcium silicate, magnesium silicate, and silicic anhydride, crystalline cellulose, poly (meth) acrylate (methyl, ethyl ester), nylon powder, And organic powders such as polyvinylpyrrolidone, and a siloxane bond having a three-dimensionally extended network structure,
There is a polymethylsilsesquioxane powder having an intermediate structure between an inorganic substance and an organic substance having a methyl group bonded thereto. As the spherical powder, both porous particles and non-porous particles can be used. Examples of the shape of the spherical powder include a true sphere and a shape similar to a sphere. In the cosmetic of the present invention, the surface may be either hydrophilic or hydrophobic. Examples of the method of the hydrophobizing treatment include a coating baking treatment using methyl hydrogen polysiloxane, coating with metal soap, fatty acid dextrin, trimethylsiloxysilicate, dimethylpolysiloxane, methylphenylpolysiloxane, and the like.

The spherical powder used in the present invention comprises:
It has a particle size in the range of 0.1 to 30 μm, particularly preferably in the range of 1 to 20 μm. Further, those having a particle size distribution within a range of ± 30% of the average particle size are preferable. When the particle diameter of the spherical powder is within the above range, the rolling effect of the spherical powder can be obtained, so that there is no creaking, good spreadability, and a refreshing usability can be obtained.

The content of the spherical powder is preferably in the range of 0.1 to 30% by weight based on the total amount of the solid cosmetic.
A range of 5 to 15% by weight is particularly preferred. In the present invention, the object of the present invention can be achieved well by containing a spherical powder, but in the case of the above range, since a sufficient rotary effect is obtained particularly by the spherical powder, there is no creaking. Good spreadability and refreshing feeling.

In the cosmetic of the present invention, in addition to the above-mentioned essential components, semi-solid hydrocarbons, esters, animal and vegetable oils, higher fatty acids, higher alcohols which are commonly used in cosmetics depending on the purpose of use. , Various polymer resins, polyhydric alcohol, purified water, humectant, ultraviolet absorber, pigment, pearl, extender, thickener, surfactant, antioxidant, preservative, intercellular lipid, vitamin Kinds, anti-inflammatory agents, fragrances and other drugs can be selected and blended in suitable ranges of types and contents as long as the object of the present invention is not impaired.

However, if solid wax is added, a refreshing feel is lost and the feeling of use becomes unsatisfactory, so it is necessary to add no solid wax. Therefore, a major feature of the cosmetic of the present invention is that it does not contain solid wax.

The form of the cosmetic of the present invention is not particularly limited as long as it is a gel, and can be widely used as various cosmetic bases. For example, it is particularly suitable for, but not limited to, lipstick, lip balm, foundation, blush, eye shadow, eyeliner, and the like.

[0043]

The present invention will be described in more detail with reference to the following Examples, which by no means limit the present invention. In addition, the compounding amount etc. are shown by weight% unless otherwise specified. The production method is described below.

(Production method of Examples 1 to 6) After uniformly mixing a crosslinked organopolysiloxane, an organic silicone resin, a volatile silicone oil, and a non-volatile liquid oil, the powder component was dispersed by a roll mill, and And a cosmetic (face color) was obtained. Table 1 shows the types and contents of the raw materials used as the components.

(Production method of Comparative Examples 1 to 7)
In any of Examples 4, 5, and 6, the crosslinked organopolysiloxane, the organic silicone resin, the volatile silicone oil, and the non-volatile liquid oil were uniformly mixed, and then the powder component was roll-milled. It was dispersed and filled in a container to obtain a cosmetic (face color). In Comparative Examples 2 and 7, after the non-volatile liquid oil and the wax were heated and dissolved, the powder component was dispersed by a roll mill, and an organic silicone resin and a volatile silicone oil were added. (Face color). Table 3 shows the types and contents of the raw materials used as the components.

Next, each of the cosmetics prepared in Examples 1 to 6 and Comparative Examples 1 to 7 was evaluated for feeling of use, persistence of cosmetic effects, and storage stability.

<Storage Stability Evaluation Test> The cosmetic was kept at a constant temperature of 25 ° C., a constant temperature of 50 ° C., and 40 ° C.
(Humidity 85%), kept at -5 ° C for 8 hours, and then kept at 20 ° C (85% humidity) for 4 hours,
Then, it is kept at 40 ° C. (85% humidity) for 8 hours,
The cosmetics stored for one month in each of the constant temperature baths whose internal atmosphere changes with a cycle of holding at 0 ° C. (humidity 85%) for 4 hours were evaluated for oil separation according to the following criteria. The results are shown in Tables 2 and 4.

(Evaluation Criteria) A: No change was observed in the cosmetics stored in any of the thermostats. ：: Separation of oil was observed after one week for the cosmetics stored in any of the thermostats. C: Separation of oil was observed after one day for the cosmetics stored in any of the thermostats. ×: Separation of oil was observed after 2 hours for the cosmetics stored in any of the thermostats.

<Sensory evaluation test of feeling of use> Regarding the feeling of use of the cosmetics of Examples 1 to 6 and Comparative Examples 1 to 7, the feeling of freshness at the time of use, the feeling of smoothness after application, the gloss of the coating film, Moist feeling was evaluated by 10 female subjects. The persistence of the cosmetic effect was determined by tissue-off 5 minutes after applying the cosmetic to the skin, and visually determining whether or not the cosmetic adhered to the tissue. The results of the test were evaluated according to the following evaluation criteria based on the average value of the evaluations of 10 persons.

The results are shown in Tables 1 and 2. (Evaluation criteria) Refreshing feeling at the time of use: No 0 ← 1 ← 2 → 3 → 4 Yes Tension after coating: Yes 0 ← 1 ← 2 → 3 → 4 No Moist feeling after coating: No 0 ← 1 ← 2 → 3 → 4 Yes Gloss of coating: No 0 ← 1 ← 2 → 3 → 4 Yes Transfer prevention effect: No 0 ← 1 ← 2 → 3 → 4 Yes 0: Very 1: Ratio 2: Neither can be 3: Ratio 4: Very (Symbols and their meanings described in Tables 1 and 2) 平均: Average of four-level evaluation of 10 persons is 3 or more and 4 or less ○: Average of four-level evaluation of 10 persons is 2 or more and 3 Less than Δ: The average value of the four-level evaluation of 10 persons is 1 or more and less than 2 ×: The average value of the four-level evaluation of 10 persons is 0 or more and less than 1

[0051]

[Table 1]

Crosslinked organopolysiloxane A: mixture of crosslinked methylpolysiloxane and decamethylcyclopentasiloxane, trade name KSG15, manufactured by Shin-Etsu Chemical Co., Ltd. Crosslinked organopolysiloxane B: crosslinked methylpolysiloxane Mixture of methylphenylpolysiloxane and methylpolysiloxane, trade name KSG16, manufactured by Shin-Etsu Chemical Co., Ltd. ・ Crosslinked organopolysiloxane C: mixture of crosslinked methylphenylpolysiloxane and methylphenylpolysiloxane, trade name KSG18, Shin-Etsu Chemical ( -Volatile silicone oil A: Decamethylcyclopentasiloxane-Non-volatile liquid oil A: Methylphenylpolysiloxane-Non-volatile liquid oil B: Squalane-Organic silicone resin A: Trimethylsiloxysilicic acid and decamethylcyclo Mixing with pentasiloxane , Trade name KF7312J, manufactured by Shin-Etsu Chemical Co., Ltd. ・ Organic silicone resin B: mixture of trimethylsiloxysilicic acid and octamethylcyclotetrasiloxane, trade name: KF7312F, manufactured by Shin-Etsu Chemical Co., Ltd. : Hydrophobic amorphous fine particle silicic anhydride, particle size 0.007 to 0.030 μm, trade name Aerosil R972, manufactured by Nippon Aerosil Co., Ltd. ・ Amorphous fine particle anhydrous silicic acid B: Amorphous fine particle anhydrous silicic acid, particle size 0.005 to 0.005 0.015 μm, trade name Aerosil 3
00, manufactured by Nippon Aerosil Co., Ltd. • Spherical powder A: hydrophobic spherical anhydrous silicic acid, particle size 1 to 16 μ
m, trade name: SI-SB-700, manufactured by Miyoshi Kasei Co., Ltd. ・ Spherical powder B: polymethylsilsesquioxane powder, particle diameter 3 to 6 μm, trade name: Tospearl 145, manufactured by Toshiba Silicone Co., Ltd.) ・ Spherical Powder: polymethyl methacrylate, particle size 5-10
μm, trade name Matsumoto Microsphere M-100,
Matsumoto Yushi Co., Ltd.

[0053]

[Table 2]

[0054]

[Table 3]

Non-volatile liquid oil C: methylpolysiloxane Organic silicone resin C: mixture of trimethylsiloxysilicic acid and dimethylpolysiloxane, trade name KF731
2K, manufactured by Shin-Etsu Chemical Co., Ltd. Non-volatile liquid oil D: neopentyl glycol dicaprate

[0056]

[Table 4]

As is clear from Table 2, the cosmetics of Examples 1 to 6 have a refreshing feeling when used, a refreshing feeling after application,
The moist feeling after application, the feeling of use such as gloss of the coating film, the persistence of the cosmetic effect, and the storage stability were all good.

On the other hand, as shown in Table 4, the cosmetic of Comparative Example 1 does not contain an organosilicone resin, so that the cosmetic effect is inferior in persistence. Since the cosmetic of Comparative Example 2 does not contain the crosslinked organopolysiloxane, the gloss of the coating film is inferior, a sense of tightness is obtained, and the sensory characteristics are inferior. Since the cosmetic of Comparative Example 3 does not contain volatile silicone oil, the cosmetic effect is inferior in persistence. Also, a refreshing feel cannot be obtained and the sensory characteristics are poor. Since the cosmetic of Comparative Example 4 does not contain a non-volatile oil, it does not provide a moist feeling after application and is inferior in sensory characteristics. Since the cosmetic of Comparative Example 5 does not contain the amorphous fine particles of silicic anhydride, oil components are easily separated, storage stability is poor, and cosmetic effect persistence is poor. Since the cosmetic of Comparative Example 6 does not contain a spherical powder, a refreshing feeling in use cannot be obtained and the sensory properties are inferior. Since the cosmetic of Comparative Example 7 contains wax, a refreshing feel cannot be obtained and the sensory evaluation is inferior.

Example 7 A gel-like lipstick was produced as follows. The amount and the production method are as follows. (Blending amount) ・ Crosslinked organopolysiloxane B 30 ・ Organic silicone resin B 25 ・ Volatile silicone A 11.8 ・ Amorphous fine particle anhydrous silicic acid A 1 ・ Non-volatile liquid oil B 5 ・ Spherical powder B 12 ・ Red No. 202 2 ・ Yellow No. 4 aluminum lake 1 ・ Titanium oxide 6 ・ Bengara 1 ・ Titanium mica 5 ・ Fragrance 0.1 ・ Antioxidant 0.1 (Production method) Cross-linked organopolysiloxane, organic silicone resin, volatile silicone oil After the non-volatile liquid oil was uniformly mixed, powder components other than titanium mica were dispersed by a roll mill, and then the mica titanium was mixed and filled in a container to obtain a gel-like lipstick.

The lipstick of Example 7 also had a refreshing and good use feeling when applied to the lips, and had the following problems. There is no pleasure, the moisture of the film is maintained,
In addition, it has a long lasting cosmetic effect, especially an excellent transfer prevention effect,
The result that it was excellent in storage stability was obtained.

[0061]

According to the present invention, when applied to the lips and skin, a refreshing good feeling is obtained, and
After application, there is no discomfort such as drying of lips and skin, and feeling of tightness of the film, and moisture is maintained. Further, there is provided a cosmetic which is excellent in persistence of a cosmetic effect, particularly excellent in anti-transfer effect, and excellent in storage stability.

Claims (5)

[Claims] 1. A crosslinked organopolysiloxane, an organosilicone resin, a volatile silicone, a non-volatile liquid oil, amorphous silica fine particles having a particle size of 0.001 to 0.05 μm, and a silica particle having a particle size of 0.1 to 0.05 μm. A cosmetic comprising a spherical powder of 1 to 30 μm and free of solid wax. 2. The method according to claim 1, wherein the crosslinked organopolysiloxane is 0.01%.
~ 20% by weight, 1-30% by weight of organic silicone resin,
10 to 60% by weight of a volatile silicone, 1 to 30% by weight of a non-volatile liquid oil, 0.01 to 10% by weight of amorphous fine silica particles having a particle diameter of 0.001 to 0.05 μm, and a particle diameter of 0.1 to 10%. 2. The cosmetic according to claim 1, wherein the cosmetic contains 0.1 to 30% by weight of spherical powder of 1 to 30 [mu] m. 3. The cross-linked organopolysiloxane according to claim 1, wherein the cross-linked organopolysiloxane contains at least one selected from the group consisting of cross-linked alkylaryl polysiloxane and cross-linked alkyl polysiloxane. The cosmetic according to any one of the above. Wherein said organic silicone resin, R ¹ ₃ SiO _1/2 units (R ¹ is a hydrocarbon group or a phenyl group with up to 6 carbon atoms) is the ratio between the SiO ₂ units 0.5-1 .5: present in 1, and cosmetic according to any one of the claims 1-3, characterized in that it consists of R ¹ ₃ SiO _1/2 units and SiO ₂ units. 5. The volatile silicone according to claim 1, wherein the volatile silicone is at least one selected from the group consisting of a low-molecular-weight linear polysiloxane represented by the general formula (1) and a low-molecular-weight cyclic polysiloxane represented by the general formula (2). The cosmetic according to any one of claims 1 to 4, wherein the cosmetic is a kind. Embedded image (However, R ² in the formula represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ² may be the same or different. M is 0. And an integer of from 3 to 3.) (However, in the formula, R ³ represents an alkyl group having 1 to 5 carbon atoms or an aryl group having 6 to 10 carbon atoms, and all R ³ may be the same or different. It represents an integer of 4 to 6.)