JP2001216997A - Spiral electrode group for battery and battery using the same - Google Patents

Spiral electrode group for battery and battery using the same

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Publication number
JP2001216997A
JP2001216997A JP2000027693A JP2000027693A JP2001216997A JP 2001216997 A JP2001216997 A JP 2001216997A JP 2000027693 A JP2000027693 A JP 2000027693A JP 2000027693 A JP2000027693 A JP 2000027693A JP 2001216997 A JP2001216997 A JP 2001216997A
Authority
JP
Japan
Prior art keywords
active material
battery
positive electrode
electrode
core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000027693A
Other languages
Japanese (ja)
Other versions
JP3796087B2 (en
Inventor
Ryuichiro Ebi
龍一郎 海老
Kanehito Masumoto
兼人 増本
Takeji Nakanose
武治 中ノ瀬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2000027693A priority Critical patent/JP3796087B2/en
Publication of JP2001216997A publication Critical patent/JP2001216997A/en
Application granted granted Critical
Publication of JP3796087B2 publication Critical patent/JP3796087B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Secondary Cells (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a spiral electrode group for a battery which is improved in weight and volume energy densities as much as possible and a battery using the electrode group to improve the discharging characteristics. SOLUTION: One electrode plate 11 located inward of winding has active material layer non-formed portions 11c, 11d, to which a core body 11a is exposed with no active material layer 11b formed, provided on the inner face side of the core body 11a equivalent to one round at starting winding and on the outer face side of the core body 11a equivalent to one round at ending winding. The other electrode plate 12 located outward of the winding has active material layers 12b formed on the whole faces of both sides of a core body 12a having a length such that it terminates one-round shorter than one electrode plate 11. A pair of separators 3, 3 are set at lengths such that they terminate at the same position somewhat passing through the other electrode plate 12 where it terminates.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、正電極板と負電極
板とをこれらの間にセパレータを介在して積層した帯状
電極群を渦巻状に巻回した構成を有する、主としてリチ
ウム電池などの非水電解液電池に用いられる渦巻状電極
群およびそれを用いて構成した、主として角形の非水電
解液電池に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a structure in which a positive electrode plate and a negative electrode plate are laminated with a separator interposed therebetween and a band-like electrode group is spirally wound. The present invention relates to a spirally wound electrode group used for a non-aqueous electrolyte battery and a prismatic non-aqueous electrolyte battery formed using the spiral electrode group.

【0002】[0002]

【従来の技術】近年では、AV機器あるいはパソコンや
携帯形通信機器などの電気機器のポータブル化やコード
レス化が急速に促進されている。これら電気機器の駆動
用電源としては、従来においてニッケルカドミウム電池
やニッケル水素電池が主に用いられていたが、近年で
は、特に、急速充電が可能でエネルギ密度が高く、高い
安全性を有するリチウム電池に代表される非水電解液
(有機溶媒系電解液)電池が主流になりつつある。この
非水電解液電池では、高エネルギ密度や負荷特性に優れ
た密閉型とし、また、機器の薄型化に適し、各スペース
使用効果が高い角形とすることが促進されている。さら
に、これらの電池には、ポータブル形電気機器の高性能
化および高機能化が進むのに伴って、より高電圧および
高容量化のものが要望されており、このようなよう要求
を満たすために、正電極板と負電極板とをこれらの間に
セパレータを介在して積層した帯状電極群を渦巻状に巻
回してなる渦巻状電極群を用いて構成したものが広く一
般的に用いられている。
2. Description of the Related Art In recent years, portable and cordless electric devices such as AV devices, personal computers, and portable communication devices have been rapidly promoted. Conventionally, nickel cadmium batteries and nickel-metal hydride batteries have been mainly used as power sources for driving these electric devices. In recent years, however, lithium batteries which can be rapidly charged, have a high energy density, and have high safety have been used in recent years. Non-aqueous electrolyte (organic solvent-based electrolyte) batteries typified by (1) are becoming mainstream. In this non-aqueous electrolyte battery, it is promoted to be a sealed type having a high energy density and excellent load characteristics, and a square shape suitable for thinning of equipment and effective in using each space. Further, with the advancement of the performance and functions of portable electric devices, these batteries are required to have higher voltage and higher capacity. In general, a structure in which a positive electrode plate and a negative electrode plate are formed using a spiral electrode group formed by spirally winding a band-like electrode group in which a separator is interposed between the positive electrode plate and the negative electrode plate is widely used. ing.

【0003】さらに、上記の渦巻状電極群を用いる非水
電解液電池では、電池としての重量エネルギ密度および
体積エネルギ密度を共に大きくすることによって一層の
高容量化が促進されている。図3は、そのような高容量
化を図った角型電池に用いられている渦巻状電極群の構
成要素である正,負の電極板1,2および一対のセパレ
ータ3,3の巻回前の相対位置関係を示した切断側面図
である。同図において、正電極板1は、一般にアルミニ
ュウム箔からなる帯状の正極芯体1aの両面に、正極活
物質を塗着したのち圧延および乾燥されてなる正極活物
質層1bを形成して構成されている。負電極板2は、一
般に銅箔からなる帯状の負極芯体2aの両面に、負極活
物質を塗着したのち圧延および乾燥されてなる負極活物
質層2bを形成して構成されている。
Further, in a non-aqueous electrolyte battery using the above-mentioned spiral electrode group, a higher capacity is promoted by increasing both the weight energy density and the volume energy density of the battery. FIG. 3 shows before and after winding of positive and negative electrode plates 1 and 2 and a pair of separators 3 and 3, which are components of a spiral electrode group used in such a rectangular battery having a high capacity. FIG. 4 is a cut-away side view showing the relative positional relationship of FIG. In FIG. 1, a positive electrode plate 1 is formed by forming a positive electrode active material layer 1b formed by applying a positive electrode active material, rolling, and drying the both surfaces of a band-shaped positive electrode core 1a generally made of aluminum foil. ing. The negative electrode plate 2 is formed by forming a negative electrode active material layer 2b formed by applying a negative electrode active material, rolling and drying the negative electrode active material on both surfaces of a strip-shaped negative electrode core 2a generally made of copper foil.

【0004】上記両電極板1,2は、負電極板2が巻回
内方側に位置する配置でこれらの間にセパレータ3,3
を介在して積層した状態で、一対の巻芯4,4が両セパ
レータ3,3の各始端を両側から挟み込んで図示矢印方
向に回転することにより巻回されて、図4の角形電池の
横断面図に示すように、偏平な渦巻状電極群7とされた
のちに、電池ケース8内に挿入される。この渦巻状電極
群7は、電池ケース8内に注入される非水電解液(図示
せず)と共に電池の発電要素を構成する。
The two electrode plates 1 and 2 are arranged such that the negative electrode plate 2 is located on the inner side of the winding, and the separators 3 and 3 are interposed therebetween.
In a state in which the separators are interposed, the pair of cores 4, 4 are wound by sandwiching the respective start ends of the separators 3, 3 from both sides and rotating in the direction of the arrow shown in FIG. As shown in the plan view, after the flat spiral electrode group 7 is formed, it is inserted into the battery case 8. The spiral electrode group 7 constitutes a power generation element of the battery together with a non-aqueous electrolyte (not shown) injected into the battery case 8.

【0005】なお、図3において、R0 〜R11は、一対
の巻芯4,4が半回転する毎に巻回される長さ分の巻き
順を示している。一対の巻芯4,4は、巻回後の渦巻状
電極群7を巻芯4,4から取り出し易くすることを目的
として、僅かに位置をずらせて配置されており、この両
巻芯4,4が半回転するときに巻回される渦巻きの半周
分の長さR1 〜R11は両巻芯4,4の各々の外方側の端
部間の距離に相当する。また、図4は、渦巻状電極群7
の主として巻始め部分と巻終わり部分の構成を容易に理
解できるように模式的に図示したものであって、実際の
形態とはかなり相違している。例えば、巻き回数は図3
に対応させていなく、各電極板1,2およびセパレータ
3,3の各間は巻き締め状態とせずに離間して図示して
あり、渦巻状電極群7と電池ケース8との間は、図示の
便宜上、実際とは異なる大きな隙間になっている。
[0005] Incidentally, in FIG. 3, R 0 to R 11, a pair of the core 4, 4 indicates the winding order of the length component wound around every half turn. The pair of winding cores 4 and 4 are slightly displaced from each other for the purpose of facilitating removal of the spirally wound electrode group 7 from the winding cores 4 and 4. The lengths R 1 to R 11 corresponding to half the circumference of the spiral wound when the core 4 rotates a half turn correspond to the distance between the outer ends of the cores 4. FIG. 4 shows a spiral electrode group 7.
Are schematically illustrated so that the configuration of the winding start portion and the winding end portion can be easily understood, and it is considerably different from the actual form. For example, FIG.
The electrode plates 1 and 2 and the separators 3 and 3 are shown apart from each other without being tightened, and the space between the spiral electrode group 7 and the battery case 8 is not shown. For the sake of convenience, the gap is different from the actual one.

【0006】上記渦巻状電極群7は、電池としての重量
エネルギ密度および体積エネルギ密度を共に大きくする
ために、以下のような構成を設けている。すなわち、負
電極板2には、その巻始め側の一周相当部分の内面側に
負極活物質層2bが形成されずに負極芯体2aが露出し
た活物質未形成部2cが設けられ、正電極板1には、そ
の巻終わり側の一周相当部分の外面側に正極活物質層1
bが形成されずに正極芯体1aが露出した活物質未形成
部1cが設けられている。
The spiral electrode group 7 has the following configuration in order to increase both the weight energy density and the volume energy density of the battery. In other words, the negative electrode plate 2 is provided with an active material non-formed portion 2c in which the negative electrode core 2a is exposed without forming the negative electrode active material layer 2b on the inner surface of a portion corresponding to one round of the winding start side, and the positive electrode The plate 1 has a positive electrode active material layer 1 on the outer surface side of a portion corresponding to one round of the winding end side.
An active material non-formed portion 1c where the positive electrode core 1a is exposed without forming b is provided.

【0007】これは、図4から明らかなように、各活物
質未形成部1c,2cにセパレータ3を介して対向する
側に化学反応するための逆極性の活物質層2b,1bが
それぞれ存在しないことから、各活物質未形成部1c,
2cとした芯体1a,2aの部分に活物質層1b,2b
を形成しても、その活物質層1b,2bが充放電に何ら
関与しない不要なものとなるだけでなく、その不要な活
物質層の厚み分だけ発電要素が厚くなり、電池としての
重量エネルギ密度および体積エネルギ密度が減少するか
らである。これにより、この渦巻状電極群7は、一定容
積の電池ケース8に対し不要な活物質層を削除した分だ
け両電極板1,2の長さを長く、或いは活物質層1b,
2bを厚くして容量アップを図ることができる。
This is because, as is apparent from FIG. 4, active material layers 2b, 1b having opposite polarities for chemically reacting with the active material non-formed portions 1c, 2c are provided on the sides opposed to each other with the separator 3 interposed therebetween. Therefore, each active material unformed portion 1c,
The active material layers 1b and 2b are provided on the cores 1a and 2a, respectively.
Is formed, the active material layers 1b and 2b not only become unnecessary and do not participate in charge / discharge at all, but also the power generating element becomes thicker by the thickness of the unnecessary active material layer, and the weight energy as a battery is reduced. This is because the density and the volume energy density are reduced. As a result, the spiral electrode group 7 increases the lengths of the two electrode plates 1 and 2 by the amount of the unnecessary active material layer removed from the battery case 8 having a fixed volume, or the active material layer 1b,
By increasing the thickness of 2b, the capacity can be increased.

【0008】また、上記渦巻状電極群7では、負電極板
2における巻始め端より突出させた負極芯体2aに負極
リード10を取り付けるとともに、正電極板1における
巻終わり端より突出させた正極芯体1aに正極リード9
を取り付けている。これに対し以前の渦巻状電極群で
は、正極および負極の各活物質層の一部を削り落とした
部分にリードを取り付けたり、リードを活物質層に直接
かしめ加工して取り付けていたので、その取り付けられ
た正,負の各リードがこれらと逆極性の活物質層に対向
配置されて、その分だけ容量ダウンを招いていたが、こ
のような欠点は上記渦巻状電極群7において解消されて
いる。
In the spiral electrode group 7, the negative electrode lead 10 is attached to the negative electrode core 2a protruding from the winding start end of the negative electrode plate 2, and the positive electrode protruding from the winding end end of the positive electrode plate 1. Positive electrode lead 9 on core 1a
Is installed. On the other hand, in the previous spiral electrode group, the lead was attached to the part where each of the active material layers of the positive electrode and the negative electrode was cut off, or the lead was directly caulked to the active material layer and attached. The attached positive and negative leads are disposed opposite to the active material layers having the opposite polarities, and the capacitance is reduced by that amount. Such a disadvantage is solved in the spiral electrode group 7. I have.

【0009】さらに、以前では、セパレータを巻芯のス
リットに挿通させて2回程度空巻きしたのちに、正,負
の電極板を送り込んで渦巻状に巻回していたので、巻始
め部分においてセパレータの無駄な部分が存在してい
た。これに対し上記渦巻状電極群7では、これの巻回工
程の終わりに2枚のセパレータ3,3をテンションをか
けた状態で重ねて各々の同一位置をカッタで同時に切断
し、つぎの巻回工程において、2枚のセパレータ3,3
の各々の同一切断箇所を揃えた巻始め部分と負電極板2
における負極リード10を設けた負極芯体2aとを一対
の巻芯4,4で挟んで巻回しているので、巻始め部分で
のセパレータ3,3の無駄が低減されている。なお、2
枚のセパレータ3,3を同一位置で切断しているのは、
もし仮に異なる位置で切断すると、2枚のセパレータ
3,3の巻始め端が不揃いとなって巻芯4,4による巻
回作業が装置の構成上から非常に困難になるためであ
る。なお、正,負の電極板1,2は、巻回前に予め所定
の長さに切断されている。
Further, in the past, after the separator was inserted through the slit of the winding core and wound about twice, the positive and negative electrode plates were fed and spirally wound. There was a useless part. On the other hand, in the spiral electrode group 7, at the end of the winding step, the two separators 3 and 3 are overlapped with tension applied, and the same positions are simultaneously cut with a cutter, and the next winding is performed. In the process, two separators 3, 3
And the negative electrode plate 2 in which the same cut portions are aligned.
And the negative electrode core 2a provided with the negative electrode lead 10 is wound between the pair of winding cores 4 and 4, so that the waste of the separators 3 and 3 at the winding start portion is reduced. In addition, 2
The reason why the separators 3 and 3 are cut at the same position is that
If the cutting is performed at different positions, the winding start ends of the two separators 3 and 3 are not uniform, and the winding operation by the winding cores 4 and 4 becomes very difficult in view of the configuration of the apparatus. The positive and negative electrode plates 1 and 2 are cut into a predetermined length before winding.

【0010】[0010]

【発明が解決しようとする課題】ところで、上述の非水
電解液電池では、一般に、電池ケース8をアルミニウム
で形成するとともに電池の正極側として構成している。
このアルミニウムで電池ケース8を構成しているのは、
この種の電池の電池ケースの材料として以前から用いら
れていたステンレスが長期間の保存中にステンレス中の
鉄成分が鉄イオンとなって溶解し、この溶解反応が続く
と、一部に腐食孔があく欠点があるためである。これに
対しアルミニウムは、ステンレスに比較して溶解され難
いことから、腐食を防止することができ、しかも、比重
が小さいことから、軽量化に伴い電池としての重量エネ
ルギ密度の向上を図れる利点がある。また、正極芯体1
aの材料としてアルミニウムを用いているのは、軽量化
に伴って重量エネルギ密度の向上を図れるからである。
By the way, in the above-mentioned non-aqueous electrolyte battery, the battery case 8 is generally formed of aluminum and configured as the positive electrode side of the battery.
The battery case 8 is made of aluminum.
When stainless steel, which has been used as a material for the battery case of this type of battery for a long time, dissolves as iron ions in the stainless steel during long-term storage, and if this dissolution reaction continues, corrosion This is because there is a drawback. On the other hand, aluminum is less soluble than stainless steel, so that corrosion can be prevented, and the specific gravity is small, so that there is an advantage that the weight energy density as a battery can be improved with weight reduction. . In addition, the positive electrode core 1
The reason why aluminum is used as the material a is that the weight energy density can be improved as the weight is reduced.

【0011】したがって、上記渦巻状電極群7における
正電極板1の最外周に位置する活物質未形成部1cに露
出している正極芯体1aは、同金属で且つ同じ正極であ
る電池ケース8の内周面に接触しても何ら不都合が生じ
ないだけでなく、むしろ露出した正極芯体1aの1周分
を電池ケース8の内周面に接触させれば、正極端子部分
での接触面積が格段に大きなって良好な電気的接続を得
られるので、効率的な集電が可能となって放電特性を格
段に向上させることが可能となる。
Therefore, the positive electrode core 1a exposed in the active material non-formed portion 1c located at the outermost periphery of the positive electrode plate 1 in the spiral electrode group 7 is made of the same metal and the same positive electrode as the battery case 8 Not only does not cause any inconvenience even if it comes into contact with the inner peripheral surface of the battery case 8, but also makes one round of the exposed positive electrode core 1 a contact the inner peripheral surface of the battery case 8. Is remarkably large and a good electrical connection can be obtained, so that efficient current collection is possible and discharge characteristics can be remarkably improved.

【0012】しかしながら、上記渦巻状電極群7では、
上述のように2枚のセパレータ3,3の各終端を製造上
の関係から同一位置で切断する必要があるとともに、こ
の各セパレータ3,3における最外周の1周部分の間に
正電極板1が介在しているため、各セパレータ3,3の
終端を正電極板1の終端を過ぎた位置に止むなく設定し
なければならない。そのため、上記渦巻状電極群7を用
いた電池では、活物質未形成部1cの正極芯体1aを電
池ケース8の内周面に接触させられないだけでなく、外
側のセパレータ4における最外周の1周分以上が何の機
能をも果たさない全く不要なものになっており、このセ
パレータ4の無駄な不要部分3aの容積分だけ活物質層
1b,2bの量が減少することになり、電池としての体
積エネルギ密度が低くなっている。また、上記電池で
は、活物質未形成部1cの正極芯体1aを電池ケース8
の内周面に接触させることができず、正極リード9を封
口板(図示せず)にレーザ溶接することによって電気的
接続しているが、集電効率が悪いことから十分な放電特
性が得られない。
However, in the spiral electrode group 7,
As described above, it is necessary to cut each end of the two separators 3 at the same position from the viewpoint of manufacturing, and the positive electrode plate 1 is placed between the outermost peripheral portions of the separators 3. , The end of each of the separators 3 must be set to a position beyond the end of the positive electrode plate 1 without stopping. Therefore, in the battery using the spiral electrode group 7, not only the positive electrode core 1 a of the active material non-formed portion 1 c cannot be brought into contact with the inner peripheral surface of the battery case 8, but also the outermost peripheral portion of the outer separator 4. One or more rounds are completely unnecessary and do not perform any function, and the amount of the active material layers 1b and 2b is reduced by the volume of the useless unnecessary portion 3a of the separator 4. Has a low volume energy density. In the above battery, the positive electrode core 1a of the active material non-formed portion 1c is connected to the battery case 8
The positive electrode lead 9 is electrically connected to the sealing plate (not shown) by laser welding, but sufficient discharge characteristics are obtained due to poor current collection efficiency. I can't.

【0013】上記とは別に、正電極板における最外周の
1周分の正極活物質層を脱落させることによって露出し
た正極芯体を正極のアルミニウム製電池ケースの内周面
に接触させる構成を有する非水電解液電池が提案されて
いる(特開平6-163025号公報参照)。ところが、この非
水電解液電池では、円形に巻回した渦巻状電極群を偏平
形状に強制的に変形させながら角形または長円形の電池
ケースに挿入することにより、露出状態の正極芯体と電
池ケースの内周面とを、渦巻状電極群の円形に戻ろうと
する復元力で接触圧を高めた状態で電気的接続状態に接
触させる技術が単に示されているだけである。すなわ
ち、上記公報には、渦巻状電極群の体積エネルギ密度お
よび重量エネルギ密度を高める構成との具体的な関連は
何ら開示されていないことから、出来る限り容量アップ
を図った構成を備えた渦巻状電極群を用いながら放電特
性の向上を得ることの電池を具現化できない。
Apart from the above, the positive electrode core body exposed by dropping the outermost circumference of the positive electrode active material layer in the outermost circumference of the positive electrode plate is brought into contact with the inner peripheral surface of the aluminum battery case of the positive electrode. A non-aqueous electrolyte battery has been proposed (see JP-A-6-63025). However, in this non-aqueous electrolyte battery, the spirally wound spiral electrode group is inserted into a rectangular or oblong battery case while forcibly deforming it into a flat shape, so that the exposed positive electrode core and the battery are exposed. It merely discloses a technique in which the inner peripheral surface of the case is brought into electrical connection with a contact pressure increased by a restoring force for returning the spiral electrode group to a circular shape. That is, since the above-mentioned publication does not disclose any specific relationship with the configuration for increasing the volume energy density and the weight energy density of the spiral electrode group, the spiral configuration having the configuration for increasing the capacity as much as possible is not disclosed. It is not possible to realize a battery that can obtain improved discharge characteristics while using an electrode group.

【0014】そこで、本発明は、上記従来の課題に鑑み
てなされたもので、重量エネルギ密度および体積エネル
ギ密度の可及的な向上を図った電池用渦巻状電極群およ
びその電極群を用いて放電特性の向上を図れる構造とし
た電池を提供することを目的とするものである。
In view of the above, the present invention has been made in view of the above-mentioned conventional problems, and uses a spiral electrode group for a battery and a group of the spiral electrodes for a battery in which the weight energy density and the volume energy density are improved as much as possible. It is an object of the present invention to provide a battery having a structure capable of improving discharge characteristics.

【0015】[0015]

【課題を解決するための手段】上記目的を達成するため
に、本発明の電池用渦巻状電極群は、帯状の正極芯体の
両面に正極活物質層が形成された正電極板と、帯状の負
極芯体の両面に負極活物質層が形成された負電極板と
が、これらの間にセパレータを介在して渦巻状に巻回さ
れてなるものにおいて、巻回内方側に位置する一方の前
記電極板が、巻始めの少なくとも1周分の前記芯体に対
する内面側と巻終わりの少なくとも1周分の前記芯体に
対する外面側とに、前記活物質層が形成されずに前記芯
体が露出した活物質層未形成部が設けられ、巻回外方側
に位置する他方の前記電極板が、前記一方の電極板に対
し少なくとも1周分だけ短い位置に終端を有する長さに
設定された前記芯体の両面全体に前記活物質層が形成さ
れ、一対の前記セパレータが、前記他方の電極板の終端
とほぼ同じ同一位置に終端を有する互いに同一長さに設
定されていることを特徴としている。
In order to achieve the above object, a spiral electrode group for a battery according to the present invention comprises: a positive electrode plate having a positive electrode active material layer formed on both sides of a belt-like positive electrode core; A negative electrode plate in which a negative electrode active material layer is formed on both surfaces of the negative electrode core, and a negative electrode plate that is spirally wound with a separator interposed therebetween; Wherein the active material layer is not formed on the inner surface side of the core body for at least one round of the winding start and the outer surface side of the core body for at least one round of the winding end. Is provided with an active material layer unformed portion having an exposed portion, and the other electrode plate located on the outer side of the winding is set to a length having an end at a position shorter than the one electrode plate by at least one turn. The active material layer is formed on both surfaces of the core body thus formed, and a pair of the separators is formed. Over others, it is characterized in that it is set to one another the same length having an end at substantially the same the same position as the end of the other electrode plate.

【0016】この電池用渦巻状電極群では、一方の電極
板における二つの活物質未形成部との対向箇所に化学反
応するための他方の極の活物質層がそれぞれ存在しない
ので、充放電に何ら関与しない不要な活物質層を一切削
除した構成になっている。また、最外周の1周を一方の
電極板の活物質未形成部で形成しているから、電池ケー
スが一方の電極板と同極である場合には、活物質未形成
部において露出している一方の極の1周分の芯体を電池
ケースの内周面に接触させることができる。そのため、
他方の電極板および一対のセパレータは何れも一方の電
極板に対し約1周分だけ短くできるから、製造上の制約
から同一位置で切断する必要がある一対のセパレータ
は、一方の電極板に対し1周分だけ手前の同一位置を終
端に設定することが可能となる。その結果、両セパレー
タは従来と比較して合計で2周分を短縮することがで
き、そのセパレータを短くできる分だけ正,負両極の活
物質層の厚みまたは長さを大きく設定することができる
から、電池としての重量エネルギ密度および体積エネル
ギ密度の増大を図ることができる。
In this spiral electrode group for a battery, the active material layer of the other electrode for performing a chemical reaction does not exist in a portion of one electrode plate facing the two active material non-formed portions. The structure is such that unnecessary active material layers that are not involved at all are deleted at all. Further, since the outermost circumference is formed by the active material non-formed portion of one of the electrode plates, if the battery case has the same polarity as the one electrode plate, it is exposed in the active material non-formed portion. One core of one of the poles can be brought into contact with the inner peripheral surface of the battery case. for that reason,
Since both the other electrode plate and the pair of separators can be shortened by about one turn with respect to one electrode plate, a pair of separators that need to be cut at the same position due to manufacturing restrictions are It is possible to set the same position just before the end by one round as the end. As a result, both separators can be shortened by a total of two turns as compared with the conventional one, and the thickness or length of the positive and negative electrode active material layers can be set to be larger by the amount of the separator being shortened. Therefore, the weight energy density and the volume energy density of the battery can be increased.

【0017】上記発明における一方の電極板は、アルミ
ニウム製正極芯体を有する正電極板とすることが好まし
い。これにより、非水電解液電池において一般的に用い
られて正極を構成するアルミニウム製電池ケースに挿入
して、正極芯体を同金属で同一極の電池ケースの内周面
に接触させて極めて良好な電気的接続を得ることができ
る。また、正極芯体として一般的に用いられているアル
ミニウム箔は、強度が弱い上に伸びたり切断したりし易
いので、間欠的な正極活物質未形成部を形成することが
非常に困難であったが、共に1周分の同じ長さに設定さ
れた二つの正極活物質未形成部を正極芯体の互いに反対
側面における巻始め部分と巻終わり部分とに形成するの
で、この二つの正極活物質未形成部は、近年において確
立された新しい塗工技術である位相差塗工方式を活用し
て容易に形成することが可能となる。
In the above invention, it is preferable that the one electrode plate is a positive electrode plate having an aluminum positive electrode core. This makes it possible to insert the positive electrode core body into the same inner peripheral surface of the same-polarity battery case with the same metal as that of the non-aqueous electrolyte battery. Electrical connection can be obtained. In addition, since aluminum foil generally used as a positive electrode core has low strength and is easy to stretch or cut, it is very difficult to form an intermittent positive electrode active material-free portion. However, two positive electrode active material non-formed portions, each having the same length for one round, are formed at the winding start portion and the winding end portion on opposite sides of the positive electrode core body. The material-unformed portion can be easily formed by utilizing a retardation coating method, which is a new coating technology established in recent years.

【0018】また、本発明の電池は、上記発明に係る電
池用渦巻状電極群が一方の極を構成する電池ケース内に
挿入するとともに、最外周に位置する一方の電極板の活
物質未形成部における露出状態の少なくとも1周分の芯
体を前記電池ケースの内周面に接触させて構成されてい
ることを特徴としている。
In the battery according to the present invention, the spiral electrode group for a battery according to the present invention is inserted into a battery case forming one of the electrodes, and the active material is not formed on one of the electrode plates located at the outermost periphery. The battery is characterized in that at least one circumference of the exposed part of the core is brought into contact with the inner peripheral surface of the battery case.

【0019】この電池では、一方の電極板の1周分の芯
体と電池ケースの内周面とが互いに接触することによっ
て電気的接続のための大きな接触面積を確保しているの
で、良好な電気的接続が得られることから、電池内部で
生じた化学エネルギを電気エネルギとして効率良く集電
することができ、放電特性が格段に向上する。
In this battery, a large contact area for electrical connection is secured by contact between the core of one circumference of one of the electrode plates and the inner circumferential surface of the battery case. Since electrical connection is obtained, the chemical energy generated inside the battery can be efficiently collected as electric energy, and the discharge characteristics are significantly improved.

【0020】[0020]

【発明の実施の形態】以下、本発明の好ましい実施の形
態について図面を参照しながら説明する。図1は、本発
明の一実施の形態に係る渦巻状電極群13における各構
成要素である正,負の電極板11,12および一対のセ
パレータ3,3の巻回前の相対位置関係を示した切断側
面図であり、同図において、図3と同一若しくは同等の
ものには同一の符号を付してある。正電極板11は、ア
ルミニュウム箔からなる帯状の正極芯体11aの両面
に、正極活物質を塗着したのち圧延および乾燥されてな
る正極活物質層11bを形成して構成されており、負電
極板12は、銅箔からなる帯状の負極芯体12aの両面
に、負極活物質を塗着したのち圧延および乾燥されてな
る負極活物質層12bを形成して構成されている。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below with reference to the drawings. FIG. 1 shows a relative positional relationship before winding of positive and negative electrode plates 11 and 12 and a pair of separators 3 and 3, which are components of a spiral electrode group 13 according to an embodiment of the present invention. FIG. 4 is a cut-away side view in which the same or equivalent components as those in FIG. 3 are denoted by the same reference numerals. The positive electrode plate 11 is formed by forming a positive electrode active material layer 11b formed by applying a positive electrode active material on both sides of a strip-shaped positive electrode core 11a made of aluminum foil, and then rolling and drying. The plate 12 is formed by coating a negative electrode active material on both sides of a strip-shaped negative electrode core 12a made of copper foil, and then forming a negative electrode active material layer 12b formed by rolling and drying.

【0021】上記渦巻状電極群13は、電池の正極を構
成するアルミニウム製電池ケース8内に挿入するものを
例示してあり、電池ケース8と同極の正電極板11を負
電極板12に対し巻回内方側に配置している点において
図3と相違している。また、正電極板11には、巻始め
側の一周相当部分の内面側および巻終わり側の1周相当
部分の外面側に、正極活物質層11bが形成されずに正
極芯体11aが露出した活物質未形成部11c,11d
がそれぞれ設けられている。一方、負電極板12には、
活物質未形成部が設けられていない。また、負電極板1
2には、巻始め端より突出させた負極芯体12aに負極
リード10が取り付けられており、正電極板11には、
巻終わり端より突出させた正極芯体11aに正極リード
9が取り付けられている。
The spiral electrode group 13 is exemplified by one inserted into an aluminum battery case 8 constituting the positive electrode of the battery. The positive electrode plate 11 having the same polarity as the battery case 8 is connected to the negative electrode plate 12. On the other hand, it differs from FIG. 3 in that it is arranged on the inner side of the winding. In the positive electrode plate 11, the positive electrode core 11a was exposed without forming the positive electrode active material layer 11b on the inner surface side of a portion corresponding to one round on the winding start side and on the outer surface side of a portion corresponding to one round on the winding end side. Active material unformed portions 11c, 11d
Are provided respectively. On the other hand, the negative electrode plate 12
No active material-unformed portion is provided. Also, the negative electrode plate 1
2, a negative electrode lead 10 is attached to a negative electrode core 12a protruding from the winding start end.
The positive electrode lead 9 is attached to the positive electrode core 11a protruding from the winding end.

【0022】上記両電極板11,12は、これらの間に
セパレータ3を介在して積層された状態で、一対の巻芯
4,4が両セパレータ3,3の各々の巻始め端および負
電極板12の負極リード10が取り付けられた負極芯体
12a部分を挟み込んで図示矢印方向に回転することに
より巻回されて渦巻状電極群13とされたのちに、図2
の角形電池の横断面図に示すように、電池ケース8内に
挿入される。この渦巻状電極群13は、電池ケース8内
に注入される非水電解液(図示せず)と共に電池の発電
要素を構成する。
The two electrode plates 11 and 12 are laminated with a separator 3 interposed therebetween, and a pair of winding cores 4 and 4 are connected to the winding start end of each of the separators 3 and the negative electrode. After the negative electrode core 12a portion of the plate 12 to which the negative electrode lead 10 is attached is sandwiched and rotated in the direction indicated by the arrow in the drawing, the negative electrode core 12a is wound to form a spiral electrode group 13, and then, as shown in FIG.
Is inserted into the battery case 8 as shown in the cross-sectional view of the rectangular battery. The spiral electrode group 13 forms a power generating element of the battery together with a non-aqueous electrolyte (not shown) injected into the battery case 8.

【0023】なお、図1のR0 〜R13は、一対の巻芯
4,4が半回転する毎に巻回される渦巻状電極群13の
半周分の長さの巻き順を示している。一対の巻芯4,4
は、巻回後の渦巻状電極群13を巻芯4,4から取り出
し易くすることを目的として、僅かに位置をずらせて配
置されおり、この両巻芯4,4が半回転するときに巻回
される渦巻きの半周分の長さは両巻芯4,4の各々の外
方側の端部間の距離に相当する。この図1の巻き順R0
〜R13の長さは図3のR0 〜R13に対応して図示してあ
る。すなわち、上記渦巻状電極群13と図3に示した渦
巻状電極群7とは、共に同一容量の電池ケース8に挿入
するものである。
Note that R 0 to R 13 in FIG. 1 indicate the winding order of a length corresponding to a half circumference of the spiral electrode group 13 that is wound every time the pair of winding cores 4 and 4 makes a half turn. . A pair of cores 4, 4
Are arranged slightly shifted in order to make it easy to take out the spirally wound electrode group 13 from the winding cores 4, 4. The length of a half turn of the spiral to be turned corresponds to the distance between the outer ends of the respective winding cores 4 and 4. The winding order R 0 in FIG.
The length of the to R 13 is is shown in correspondence to the R 0 to R 13 in FIG. 3. That is, the spiral electrode group 13 and the spiral electrode group 7 shown in FIG. 3 are both inserted into the battery case 8 having the same capacity.

【0024】但し、図2は、主として渦巻状電極群13
の巻始め部分と巻終わり部分の構成を容易に理解できる
ように模式的に図示したものであって、実際の形態とは
かなり相違している。例えば、巻き回数は図1に対応さ
せていなく、各電極板11,12およびセパレータ3,
3の各間は巻き締め状態とせずに離間して図示してあ
り、渦巻状電極群13と電池ケース8と間は、図示の便
宜上、実際とは異なる大きな隙間になっている。したが
って、図2と図4とは、巻き回数などを比較できる図示
になっていない。
FIG. 2 mainly shows the spiral electrode group 13.
Are schematically illustrated so that the configuration of the winding start portion and the winding end portion can be easily understood, and are considerably different from the actual form. For example, the number of windings does not correspond to FIG.
3 are separated from each other without being wound, and the spiral electrode group 13 and the battery case 8 have a large gap different from the actual one for convenience of illustration. Therefore, FIG. 2 and FIG. 4 are not shown so that the number of windings and the like can be compared.

【0025】図2から明らかなように、上記渦巻状電極
群13では、正電極板11の各活物質未形成部11c,
11dが対向する側に化学反応するための負極活物質層
12bがそれぞれ存在しないので、充放電に何ら関与し
ない不要な正極活物質層11bを削減したことになる。
換言すると、上記渦巻状電極群13に設けられている
正,負極の各活物質層11b,12bは全て化学反応し
て充放電に関与できる構造になっている。
As apparent from FIG. 2, in the spiral electrode group 13, each active material non-formed portion 11 c of the positive electrode plate 11 is formed.
Since there is no negative electrode active material layer 12b for performing a chemical reaction on the side opposite to 11d, unnecessary positive electrode active material layers 11b that are not involved in charge / discharge at all are eliminated.
In other words, all of the positive and negative electrode active material layers 11b and 12b provided in the spiral electrode group 13 have a structure capable of participating in charge and discharge by a chemical reaction.

【0026】図1と図3との比較から明らかなように、
双方の渦巻状電極群7,13における正極活物質層1
b,11bおよび負極活物質層2b,12bは、正極芯
体1a,11aおよび負極芯体2a,12aの両面側を
合わせた長さの合計が何れも10周分の長さを有してお
り、長さにおいて同等である。また、上記渦巻状電極群
13の正極芯体11aは従来の渦巻状電極群7の正極芯
体1aに対し半周分長くなっているが、負極芯体12a
が従来の渦巻状電極群7の負極芯体2aよりも半周分短
くなっており、この点においても同等である。
As is clear from the comparison between FIG. 1 and FIG.
Positive electrode active material layer 1 in both spiral electrode groups 7 and 13
Each of b, 11b and the negative electrode active material layers 2b, 12b has a total length of 10 turns, which is the sum of the lengths of both sides of the positive electrode cores 1a, 11a and the negative electrode cores 2a, 12a. , In length. Further, the positive electrode core 11a of the spiral electrode group 13 is longer than the positive electrode core 1a of the conventional spiral electrode group 7 by half the circumference, but the negative electrode core 12a is longer.
Is shorter by half a circumference than the negative electrode core 2a of the conventional spiral electrode group 7, which is equivalent in this respect.

【0027】これに対し、上記渦巻状電極群13では、
最外周の1周(第11ターン目R11と第12ターン目R12
部分)を正電極板11の正極活物質未形成部11dで形
成しているから、この正極活物質未形成部11dにおい
て露出している正極芯体11aを同金属で同じ正極の電
池ケース8の内周面に接触させることができる。また、
負電極板12は第10ターン目R10で終わっている。した
がって、製造上から共に同一位置で切断する必要がある
両セパレータ3,3は、各々の第11ターン目R 11と第12
ターン目R12の部分が何れも不要となって、第10ターン
目R10を過ぎた時点の同一位置で共に切断されている。
これにより、図1と図3との比較から明らかなように、
両セパレータ3,3は従来の渦巻状電極群7と比較して
合計で2周分が短縮されていることになる。
On the other hand, in the spiral electrode group 13,
One round of outermost circumference (R on turn 11)11And turn 12 R12of
Part) is formed by the positive electrode active material non-formed portion 11d of the positive electrode plate 11.
Therefore, the positive electrode active material unformed portion 11d
The exposed positive electrode core 11a is made of the same metal and has the same positive electrode potential.
The inner peripheral surface of the pond case 8 can be brought into contact. Also,
The negative electrode plate 12 is in the 10th turn RTenEnds with did
Therefore, it is necessary to cut both at the same position from manufacturing
Both separators 3 and 3 are connected to each other in turn 11 R 11And the twelfth
Turn R12Is no longer required, and turn 10
Eye RTenAre cut off at the same position after passing through.
Thereby, as is clear from the comparison between FIG. 1 and FIG. 3,
The separators 3 and 3 are compared with the conventional spiral electrode group 7.
That is, two rounds are reduced in total.

【0028】したがって、上記渦巻状電極群13は、同
一容積の電池ケース8を用いる場合において、従来の渦
巻状電極群7に対し両セパレータ3,3の長さが合計で
2周分短くなった分だけ正,負両極の活物質層11b,
12bの厚みを大きくすることができるから、電池とし
ての体積エネルギ密度の増大を図ることができる。一
方、正,負両極の活物質層11b,12bを従来の渦巻
状電極群7と同一の厚みおよび長さに設定した場合に
は、両セパレータ3,3の長さが合計で2周分短くなる
分だけ渦巻状電極群13の厚みを小さくできるから、や
はり電池としての体積エネルギ密度の他に重量エネルギ
密度をも増大させることができる。
Therefore, when the battery case 8 having the same volume is used, the spiral electrode group 13 has a total length of the separators 3 and 3 shorter than that of the conventional spiral electrode group 7 by two turns. The positive and negative active material layers 11b by
Since the thickness of the battery 12b can be increased, the volume energy density of the battery can be increased. On the other hand, when the positive and negative electrode active material layers 11b and 12b are set to the same thickness and length as the conventional spiral electrode group 7, the length of both separators 3 and 3 is reduced by a total of two turns. Since the thickness of the spiral electrode group 13 can be reduced as much as possible, the weight energy density as well as the volume energy density of the battery can be increased.

【0029】また、上記渦巻状電極群13は製作面にお
いても大きな利点を備えている。すなわち、正極芯体1
1aとして一般的に用いられているアルミニウム箔は、
強度が弱い上に伸びたり切断したりし易いので、図3の
ような正極芯体1aの一面側に部分的に間欠する正極活
物質未形成部1cを形成することは、非常に困難であっ
て実用化の可能性に乏しい。これに対し、上記渦巻状電
極群13の正電極板11では、共に1周分の同じ長さに
設定された二つの正極活物質未形成部11c,11dが
正極芯体11aの互いに反対側面における巻始め部分と
巻終わり部分とに形成されている。したがって、二つの
正極活物質未形成部11c,11dは、近年においてロ
ールプレスの改良に伴い確立した新たな活物質塗工技術
である位相差塗工方式を活用して容易に形成することが
できる。
The spiral electrode group 13 also has a great advantage in terms of manufacturing. That is, the positive electrode core 1
Aluminum foil commonly used as 1a is:
It is very difficult to form a partially intermittent positive electrode active material-unformed portion 1c on one surface side of the positive electrode core 1a as shown in FIG. And the possibility of practical application is poor. On the other hand, in the positive electrode plate 11 of the spiral electrode group 13, the two positive electrode active material-free portions 11c and 11d each having the same length for one round are formed on the opposite side surfaces of the positive electrode core 11a. A winding start portion and a winding end portion are formed. Therefore, the two positive electrode active material non-formed portions 11c and 11d can be easily formed by utilizing the phase difference coating method, which is a new active material coating technology established in recent years with the improvement of the roll press. .

【0030】一方、上記渦巻状電極群13を用いた角形
電池では、最外周の1周を正電極板11の正極活物質未
形成部11dで形成しているとともに、この正極活物質
未形成部11dの外方側にセパレータ3が介在していな
いので、正極活物質未形成部11dにおいて露出してい
る正極芯体11aの1周分を正極の電池ケース8の内周
面に直接的に接触させて電気的接続を図ることができ
る。そのため、この角形電池は、正極リード9を封口板
にレーザ溶接で接続するのに加えて、1周分の正極芯体
11aと電池ケース8の内周面とが大きな接触面積で互
いに接触することによって良好な電気的接続を得られる
ので、電池内部で生じた化学エネルギを電気エネルギと
して効率良く集電することができ、放電特性が格段に向
上する。
On the other hand, in the prismatic battery using the spiral electrode group 13, one outermost circumference is formed by the positive electrode active material-free portion 11 d of the positive electrode plate 11, and the positive electrode active material-free portion is formed. Since the separator 3 is not interposed on the outer side of 11d, one round of the positive electrode core 11a exposed in the positive electrode active material non-formed portion 11d is directly in contact with the inner peripheral surface of the battery case 8 of the positive electrode. Thus, electrical connection can be achieved. Therefore, in this prismatic battery, in addition to connecting the positive electrode lead 9 to the sealing plate by laser welding, one round of the positive electrode core 11a and the inner peripheral surface of the battery case 8 come into contact with each other with a large contact area. As a result, good electrical connection can be obtained, so that the chemical energy generated inside the battery can be efficiently collected as electric energy, and the discharge characteristics are significantly improved.

【0031】なお、電池ケースが鉄製であって負極を構
成する場合には、図1における正電極板11と負電極板
12の各々の形状および配置を互いに入れ換えた構成と
すれば、上述と同様の効果を得ることができるのは言う
までもない。
When the battery case is made of iron and forms a negative electrode, the same configuration and arrangement as those of the positive electrode plate 11 and the negative electrode plate 12 in FIG. Needless to say, the effect can be obtained.

【0032】[0032]

【発明の効果】以上のように本発明の電池用渦巻状電極
群群によれば、巻回内方側に位置する電極板の巻始めの
1周分の内面側と巻終わりの1周分の外面側とに活物質
層未形成部を設けたので、充放電に何ら関与しない不要
な活物質層が一切存在しない。また、最外周の1周を一
方の電極板の活物質未形成部で形成できるので、製造上
の制約から同一位置で切断する必要がある一対のセパレ
ータを、一方の電極板に対し1周分だけ手前の同一位置
を終端に設定することが可能となり、両セパレータは従
来と比較して合計で2周分を短縮することができ、その
セパレータを短くできる分だけ正,負両極の活物質層の
厚みまたは長さを大きく設定することができるから、電
池としての重量エネルギ密度および体積エネルギ密度の
増大を図ることができる。
As described above, according to the spiral electrode group for a battery according to the present invention, the inner surface of the electrode plate located on the inner side of the winding for one turn and the end of the electrode plate for one turn at the end of the winding. Since no active material layer is formed on the outer surface side of the substrate, there is no unnecessary active material layer not involved in charge / discharge at all. In addition, since the outermost circumference can be formed by the active material-free portion of one electrode plate, a pair of separators that need to be cut at the same position due to manufacturing restrictions can be removed by one rotation relative to one electrode plate. It is possible to set the same position just before the end as the end, and both separators can be shortened by a total of two rounds compared to the conventional, and the positive and negative electrode active material layers can be shortened by the length of the separator. Since the thickness or the length of the battery can be set large, the weight energy density and the volume energy density of the battery can be increased.

【0033】また、本発明の電池によれば、一方の極の
1周分の芯体と電池ケースの内周面とが大きな接触面積
で互いに接触することによって良好な電気的接続を得ら
れるので、電池内部で生じた化学エネルギを電気エネル
ギとして効率良く集電することができ、放電特性が格段
に向上する。
Further, according to the battery of the present invention, a good electrical connection can be obtained because the core body for one round of one of the poles and the inner circumferential surface of the battery case come into contact with each other with a large contact area. In addition, the chemical energy generated inside the battery can be efficiently collected as electric energy, and the discharge characteristics are significantly improved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施の形態に係る電池用渦巻状電極
群における各構成要素の巻回前の相対位置関係を示した
切断側面図である。
FIG. 1 is a cut-away side view showing a relative positional relationship before winding of each component in a spiral electrode group for a battery according to an embodiment of the present invention.

【図2】同上渦巻状電極群を電池ケースに挿入した状態
を模式的に示した横断面図。
FIG. 2 is a cross-sectional view schematically showing a state in which the spiral electrode group is inserted into a battery case.

【図3】従来の角型電池の渦巻状電極群における各構成
要素の巻回前の相対位置関係を示した切断側面図であ
る。
FIG. 3 is a cross-sectional side view showing a relative positional relationship before winding each component in a spiral electrode group of a conventional rectangular battery.

【図4】同上渦巻状電極群を電池ケースに挿入した状態
を模式的に示した横断面図。
FIG. 4 is a cross-sectional view schematically showing a state where the spiral electrode group is inserted into a battery case.

【符号の説明】[Explanation of symbols]

3 セパレータ 8 電池ケース 11 正電極板(一方の電極板) 11a 正極芯体(一方の極の芯体) 11b 正極活物質層(一方の極の活物質層) 11c,11d 活物質未形成部 12 負電極板(他方の電極板) 12a 負極芯体(他方の極の芯体) 12b 負極活物質層(他方の極の活物質層) 13 渦巻状電極群 3 Separator 8 Battery case 11 Positive electrode plate (one electrode plate) 11a Positive electrode core (one electrode core) 11b Positive electrode active material layer (one electrode active material layer) 11c, 11d Active material unformed portion 12 Negative electrode plate (the other electrode plate) 12a Negative electrode core (the other electrode core) 12b Negative electrode active material layer (the other electrode active material layer) 13 Spiral electrode group

───────────────────────────────────────────────────── フロントページの続き (72)発明者 中ノ瀬 武治 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 Fターム(参考) 5H017 AA03 CC01 EE05 5H022 AA09 CC16 CC21 EE04 5H028 AA05 BB07 CC05 CC13 5H029 AJ03 BJ02 BJ14 CJ07 DJ05 DJ07  ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Takeharu Nakanose 1006 Kazuma Kadoma, Kazuma, Osaka Prefecture Matsushita Electric Industrial Co., Ltd.F-term (reference) BJ14 CJ07 DJ05 DJ07

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 帯状の正極芯体の両面に正極活物質層が
形成された正電極板と、帯状の負極芯体の両面に負極活
物質層が形成された負電極板とが、これらの間にセパレ
ータを介在して渦巻状に巻回されてなる電池用渦巻状電
極群において、 巻回内方側に位置する一方の前記電極板は、巻始めの少
なくとも1周分の前記芯体に対する内面側と巻終わりの
少なくとも1周分の前記芯体に対する外面側とに、前記
活物質層が形成されずに前記芯体が露出した活物質層未
形成部が設けられ、 巻回外方側に位置する他方の前記電極板は、前記一方の
電極板に対し少なくとも1周分だけ短い位置に終端を有
する長さに設定された前記芯体の両面全体に前記活物質
層が形成され、 一対の前記セパレータは、前記他方の電極板の終端とほ
ぼ同じ同一位置に終端を有する互いに同一長さに設定さ
れていることを特徴とする電池用渦巻状電極群。
A positive electrode plate having a positive electrode active material layer formed on both sides of a strip-shaped positive electrode core, and a negative electrode plate having a negative electrode active material layer formed on both surfaces of a strip-shaped negative electrode core, In a spirally wound electrode group for a battery, which is spirally wound with a separator interposed therebetween, one of the electrode plates located on the inner side of the spirally wound electrode is disposed on at least one round of the winding start with respect to the core body. An active material layer-free portion where the active material layer is not formed and the core material is exposed is provided on the inner surface side and the outer surface side of the core body for at least one round at the end of winding, and the winding outer side The active material layer is formed on both surfaces of the core body, which is set to have a length that has an end at a position shorter by at least one turn than the one electrode plate, and End of the separator at substantially the same position as the end of the other electrode plate A spiral electrode group for a battery, wherein the spiral electrode groups have the same length.
【請求項2】 一方の電極板は、アルミニウム製正極芯
体を有する正電極板である請求項1に記載の電池用渦巻
状電極群。
2. The spiral electrode group for a battery according to claim 1, wherein the one electrode plate is a positive electrode plate having an aluminum positive electrode core.
【請求項3】 請求項1または2に記載の電池用渦巻状
電極群が一方の極を構成する電池ケース内に挿入されて
いるとともに、最外周に位置する一方の電極板の活物質
未形成部における露出状態の少なくとも1周分の芯体が
前記電池ケースの内周面に接触されていることを特徴と
する電池。
3. The spirally wound electrode group for a battery according to claim 1 or 2 is inserted into a battery case constituting one of the electrodes, and the active material is not formed on one of the electrode plates located at the outermost periphery. A battery wherein at least one round of the exposed core of the portion is in contact with the inner peripheral surface of the battery case.
JP2000027693A 2000-02-04 2000-02-04 Battery spiral electrode group and battery using the same Expired - Fee Related JP3796087B2 (en)

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US20120196165A1 (en) * 2011-01-31 2012-08-02 Samsung Sdi Co., Ltd. Electrode assembly and secondary battery including electrode assembly
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004139800A (en) * 2002-10-16 2004-05-13 Dainippon Printing Co Ltd Nonaqueous electrolyte battery and its electrode plate
US7807292B2 (en) 2006-05-17 2010-10-05 Sony Corporation Secondary battery
US8168320B2 (en) 2006-05-17 2012-05-01 Sony Corporation Secondary battery
EP2348562A1 (en) * 2010-01-26 2011-07-27 SB LiMotive Co., Ltd. Electrode assembly, method of manufacturing electrode assembly, and secondary battery including electrode assembly
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US8450002B2 (en) 2010-01-26 2013-05-28 Samsung Sdi Co., Ltd. Electrode assembly including electrode having non-coated portion, method of manufacturing the same, and secondary battery including the same
WO2012042830A1 (en) * 2010-09-30 2012-04-05 パナソニック株式会社 Nonaqueous electrolyte secondary battery
CN102088082A (en) * 2010-12-28 2011-06-08 深圳市量能科技有限公司 Winding battery pole pack, preparation method of winding battery pole pack and battery comprising winding battery pole pack
US20120196165A1 (en) * 2011-01-31 2012-08-02 Samsung Sdi Co., Ltd. Electrode assembly and secondary battery including electrode assembly
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