JP2001214074A - Resin composition and use thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a resin composition excellent in molding processability, flexibility and abrasion resistance, and to provide molded products and laminates each using the above resin composition. SOLUTION: This resin composition comprises (A) a thermoplastic resin, (B) an ethylene-vinyl ester copolymer resin composition comprising (b1) an ethylene-vinyl ester copolymer, (b2) inorganic microparticles <=10 μm in average size and (b3) a higher fatty acid salt <=10 μm in average particle size, and (C) an inorganic or organic filler. The other objective molded products and laminates each using the above resin composition are provided.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a resin composition comprising a thermoplastic resin (A), an ethylene-vinyl ester copolymer resin composition (B), and an inorganic or organic filler (C). The present invention relates to a resin composition having excellent moldability, flexibility, and abrasion resistance, and a molded article and a laminate using the same.

[0002]

2. Description of the Related Art Conventionally, flooring made of vinyl chloride resin has been frequently used for flooring of buildings and condominiums,
Many other products containing chlorine-containing resin are also used for building materials, etc.However, chlorine-containing resin products generate a large amount of smoke containing harmful hydrogen chloride gas at the time of fire, which has an adverse effect on the human body. And hinder evacuation and fire fighting. Also, because it contains a large amount of plasticizers and stabilizers, contamination by bleeding of plasticizers is seen,
There is also a problem of strong odor.

[0003] As a countermeasure, Japanese Patent Laid-Open No.
No. 45 discloses that calcium carbonate or a mixture of calcium carbonate and aluminum hydroxide is mixed with 100 parts by weight of a base resin obtained by mixing 70 to 30 parts by weight of polypropylene and 30 to 70 parts by weight of an ethylene-vinyl acetate copolymer. ~
Japanese Patent Laid-Open No. 9-317 discloses a floor material containing 300 parts by weight.
No. 142 discloses a floor material obtained by mixing 50 to 300 parts by weight of an inorganic filler with a mixed resin of 30 to 70 parts by weight of polyethylene and 70 to 30 parts by weight of an ethylene-vinyl acetate copolymer. JP-A-10-45962 discloses that 30 to 70 parts by weight of polyethylene, 70 to 30 parts by weight of an ethylene-vinyl acetate copolymer having a vinyl acetate content of 71 to 90% by weight, and 50 to 50 parts by weight of an inorganic filler. Floor materials mixed at a ratio of up to 300 parts by weight have been proposed.

[0004]

However, in the technology disclosed in the above publication, since the base resin such as polypropylene or polyethylene is a hard resin, it is attempted to impart flexibility by blending an ethylene-vinyl acetate copolymer. However, it is difficult to sufficiently satisfy the moldability, flexibility, and abrasion resistance by merely blending the ethylene-vinyl acetate copolymer, and further improvement is required.

In view of the above, an object of the present invention is to provide a resin composition having excellent moldability, flexibility and abrasion resistance, and a molded article and a laminate using the same. It is.

[0006]

[Means for Solving the Problems]
In view of the above circumstances, as a result of intensive studies, the thermoplastic resin (A), ethylene-vinyl ester copolymer (b
1), inorganic fine particles having an average particle diameter of 10 μm or less (b2)
And that the ethylene-vinyl ester copolymer resin composition (B) comprising the higher fatty acid salt (b3) having an average particle diameter of 10 μm or less and the resin composition comprising the inorganic or organic filler (C) meet the above object. Heading, the present invention has been completed.

In the present invention, the ethylene-vinyl ester copolymer (b1) is an ethylene-vinyl acetate copolymer, wherein the content of vinyl acetate in the copolymer is 40 to 95.
% By weight and the melt index (M
I) is 0.05 to 300 g / 10 min (190 ° C., 216
0 g load). The melt index (MI) in the present invention is a melt index (g / 10 minutes) measured under the condition of a load of 2160 g at 190 ° C., unless otherwise specified.

[0008]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail. The thermoplastic resin (A) used in the present invention includes:
There is no particular limitation, and examples thereof include polyolefin-based resins, polyamide-based resins, polyester-based resins, polyether-based resins, polyurethane-based resins, polycarbonate-based resins, acrylic-based resins, and polystyrene. Among them, polyolefin-based resins are preferably used. These may be used alone or in combination of two or more.

Examples of such polyolefin resins include various high-density, medium-density, and low-density homopolymers such as polyethylene, polypropylene, polybutene, and polypentene; ethylene-propylene copolymers; 2 to 2 carbon atoms such as 1-hexene
A copolymer with an α-olefin of about 0, an olefin-vinyl acetate copolymer having an olefin content of 90 mol% or more, such as ethylene or propylene, an olefin- (meth) acrylate copolymer, and a metal ion. One or two or more modified ionomer resins or the like, or those obtained by graft-modifying a homo- or copolymer of the above-mentioned polyolefin resin with an unsaturated carboxylic acid or the like can be used arbitrarily.

[0010] Among them, particularly, the density is 0.910
It is preferably a crystalline ethylene polymer having a 0.945 g / cm ³ and a melt index (MI) of 0.5 to 50 g / 10 min (according to JIS K 7210),
More preferred melt index (MI) is 0.5 to 2
0 g / 10 minutes (according to JIS K 7210).

The melt index (MI) is 0.5 g /
If the amount is less than 10 minutes, a large amount of a filler is added, and the fluidity is reduced. If the amount exceeds 50 g / 10 minutes, the melt tension is undesirably reduced.

The ethylene-vinyl ester copolymer resin composition (B) of the present invention comprises an ethylene-vinyl ester copolymer (b1), inorganic fine particles (b2) and a higher fatty acid salt (b3).

The ethylene-vinyl ester copolymer (b)
1) may be a copolymer of ethylene with a lower aliphatic vinyl carboxylate such as vinyl acetate, vinyl formate, vinyl propionate or vinyl butyrate, or a smaller amount thereof with an acrylate, methacrylate, or acrylic acid , Methacrylic acid, acrylonitrile, methacrylonitrile, styrene, vinyl stearate, carbon number 3
Copolymers obtained by copolymerizing other monomers such as the above-mentioned α-olefin, and the like can be mentioned. Among them, it is particularly preferable to use vinyl acetate as a vinyl ester.

When the ethylene-vinyl ester copolymer (b1) is an ethylene-vinyl acetate copolymer, the content of vinyl acetate in the copolymer is preferably 40 to 95% by weight, More preferably 50 to 90
%, Particularly preferably 50 to 85% by weight. When the content of vinyl acetate is less than 40% by weight, it becomes crystalline, and the compatibility with other resins is reduced. When the content exceeds 95% by weight, water resistance and heat resistance are lowered, which is not preferable.

The ethylene-vinyl acetate copolymer has a melt index (MI) of 0.05 to 300 g.
/ 10 minutes (190 ° C., 2160 g load), more preferably 0.05 to 250 g / 10 minutes (190 ° C., 2160 g load). The melt index (MI) is 0.05 g / 10 min (190 ° C.,
If it is less than 2160 g load), the fluidity is reduced, and 300
If it exceeds g / 10 minutes (at 190 ° C. and a load of 2160 g), it will not be sticky when blended with another resin.

The inorganic fine particles (b2) are not particularly limited, but need to have an average particle diameter of 10 μm or less, more preferably 8 μm or less. If the average particle size exceeds 10 μm, the effect of preventing the ethylene-vinyl ester copolymer from blocking cannot be obtained.

The inorganic fine particles (b2) used in the present invention
Specific examples of Ca, Mg, Zn, Al, Si, B
a, carbonates, hydroxides, oxides, etc., and any one or more of these are used. Among them, calcium carbonate, magnesium hydroxide, aluminum hydroxide, silicon oxide, talc and the like are preferably used.

The higher fatty acid salt (b3) is not particularly limited, but needs to have an average particle size of 10 μm or less. If the average particle size exceeds 10 μm, the effect of preventing the ethylene-vinyl ester copolymer from blocking cannot be obtained.

The higher fatty acid salt (b3) used in the present invention
As a specific example, C 8 to C 22 higher fatty acids
a, Zn, Mg, Al, Ba and the like, and any one or more of these are used. Among them, stearic acid, lauric acid, Ca salt of ricinoleic acid, Zn salt, Mg
Salts, Al salts, Ba salts and the like are preferably used.

The content of the inorganic fine particles (b2) and the higher fatty acid salt (b3) is 5 to 100 parts by weight based on 100 parts by weight of the ethylene-vinyl ester copolymer (b1). , More preferably 5 to 50 parts by weight, particularly preferably 1 to 50 parts by weight.
0 to 50 parts by weight, and the higher fatty acid salt (b3) is 0.1% by weight.
It is preferably from 10 to 10 parts by weight, more preferably from 0.1 to 5 parts by weight.

When the amount of the inorganic fine particles (b2) is less than 5 parts by weight, it is difficult to obtain the effect of preventing the ethylene-vinyl ester copolymer from being blocked. If the amount of the higher fatty acid salt is less than 0.1 part by weight, the effect of preventing the ethylene-vinyl ester copolymer from blocking is difficult to obtain. If the amount exceeds 10 parts by weight, bleeding out when blended with another resin is not preferred. As described above, by using the inorganic fine particles (b2) and the higher fatty acid salt (b3) together in a specific ratio, the effect can be obtained with a small amount of addition, and the effect cannot be obtained alone. It is.

The method for producing the ethylene-vinyl ester copolymer resin composition (B) of the present invention is not particularly limited, and the ethylene-vinyl ester polymer (b1), the inorganic fine particles (b2), the higher fatty acid salt ( It is possible to mix b3) all at once or mix any two components and then mix the remaining components.
It is preferable that the inorganic fine particles (b2) and the higher fatty acid salt (b3) are uniformly mixed with the vinyl ester copolymer (b1) particles and then dried.

As the ethylene-vinyl ester copolymer (b1) particles in a wet state, before or after the copolymer is precipitated from a non-solvent dispersion of the ethylene-vinyl ester copolymer (b1), It is preferable to wet with the non-solvent liquid before drying.

In the ethylene-vinyl ester copolymer (b1) particles in a wet state, the non-solvent liquid is 3 to 30% by weight based on the ethylene-vinyl ester copolymer (b1).
Preferably, the content is 3% by weight.
If the amount is less than the above, the ethylene-vinyl ester copolymer (b1) particles are blocked. If the amount exceeds 30% by weight, drying becomes difficult, which is not preferable.

As the dispersion of the ethylene-vinyl ester copolymer (b1) in the above-mentioned production method, the lower fatty acid vinyl ester and ethylene, or a small amount of an ethylenically unsaturated monomer copolymerizable therewith, are suspended. An aqueous dispersion obtained by copolymerization by a polymerization method or an emulsion polymerization method, or a block-like or pellet-like copolymer obtained by a solution of a copolymer obtained by a solution polymerization method or any other method. Any solution such as a dispersion obtained by emulsifying and dispersing a solution obtained by dissolving the copolymer in a non-solvent medium of the copolymer may be used.

In carrying out the above production method,
With respect to the non-solvent dispersion of the ethylene-vinyl ester copolymer (b1) obtained as described above or after depositing the copolymer (b1) in fine particles from the dispersion, the copolymer is obtained. (B1) Before the particles are dried, that is, while the copolymer (b1) particles are still sufficiently wetted by the non-solvent liquid, the inorganic fine particles (b2) and the higher fatty acid salt (b3) are mixed. After uniform mixing, the mixture is preferably dried.

The inorganic or organic filler (C) used in the present invention is not particularly limited. Examples of the inorganic filler include calcium carbonate, magnesium carbonate, magnesium hydroxide, aluminum hydroxide, zinc oxide, barium sulfate, and the like. Examples thereof include talc, clay, mica, and shirasu balloon, and may or may not be surface-treated. Examples of the organic filler include wood powder, fruit shell powder, pulp powder, vulcanized rubber powder and the like.

Thus, the thermoplastic resin (A), ethylene-
A resin composition comprising the vinyl ester copolymer resin composition (B) and the inorganic or organic filler (C) is obtained. In the present invention, the thermoplastic resin (A) is used in an amount of 50 to 99 parts by weight, preferably 70 to 95 parts by weight, 1 to 50 parts by weight, preferably 5 to 30 parts by weight of the ethylene-vinyl ester copolymer resin composition (B), and the inorganic or organic filler (C) to the thermoplastic resin (A) and With respect to 100 parts by weight of the total amount of the ethylene-vinyl ester copolymer resin composition (B),
It is preferable to contain not more than 600 parts by weight, preferably not more than 500 parts by weight.

If the content of the thermoplastic resin (A) is less than 50 parts by weight, and if the content of the ethylene-vinyl ester copolymer resin composition (B) exceeds 50 parts by weight, the surface is deteriorated by the ethylene-vinyl ester copolymer. When the content of the thermoplastic resin (A) exceeds 99 parts by weight and the content of the ethylene-vinyl ester copolymer resin composition (B) is less than 1 part by weight, the ethylene-vinyl ester copolymer The plasticizing effect of the polymer is undesirably reduced. If the content of the inorganic or organic filler (C) exceeds 600 parts by weight, the mechanical properties deteriorate, which is not preferable.

The method of compounding the resin composition of the present invention comprising (A) to (C) is not particularly limited, and (A) to (C) may be mixed at once or any two components may be mixed. After that, any of the remaining components may be sequentially blended or the like.

The mixing means (A) to (C) may be in any mode. For example, a method of mixing a thermoplastic resin (A), an ethylene-vinyl ester copolymer resin composition (B), and an inorganic or organic filler (C) with a Henschel mixer or a tumbler, an extruder, a pressure kneader, or the like. A method of melt-kneading and pelletizing, and the like.

In the present invention, the resin composition comprising the above (A) to (C) can be formed into a molded product, and the scrap generated when the resin composition is used for various uses can be contained in the resin composition. The resulting resin composition has an effect. The content ratio of scrap is 10 to 90% by weight, preferably 10 to 90% by weight.
It is about 50% by weight.

At the time of molding, if necessary, glass fiber,
Known additives such as reinforcing materials such as carbon fibers, low molecular weight polyethylene, low molecular weight polypropylene, paraffin, higher fatty acid amides, lubricants such as metal soaps, antioxidants, ultraviolet absorbers, antibacterial agents, inorganic and organic pigments, etc. May be blended in an appropriate amount.

As the melt molding method, any molding method such as calender molding, extrusion molding, injection molding, compression molding and the like can be adopted. Among them, the extrusion molding method is a T-die method,
Examples include a hollow molding method, a pipe extrusion method, a linear extrusion method, a profile die extrusion method, an inflation method, and a melt spun method.

The shape of the molded product obtained from the resin composition of the present invention is arbitrary, and not limited to films, sheets, tapes, bottles, tubes, tanks, hoses, pipes, filaments, extruded products with irregular cross-sections, etc. It is also important to form a laminate having at least one layer of a resin composition of the formula (1). When the laminate is laminated, the mating resin is a polyolefin resin, a polyamide resin such as EVOH, nylon-6, nylon-6,6, a vinylidene chloride, or the like. Resin, styrene resin, polyester resin, polycarbonate, vinyl chloride resin, acrylic resin, vinyl ester resin, polyester elastomer, polyurethane elastomer,
Thermoplastic resins such as chlorinated polyethylene and chlorinated polypropylene are exemplified.

In producing such a laminate, an adhesive resin can be used. As the adhesive resin, a known adhesive can be used. For example, a density of 0.1% modified with an unsaturated carboxylic acid or its anhydride can be used. 86 to 0.95 g /
cm ^{3 of} an ethylene-α-olefin copolymer is preferable, and can be obtained by copolymerizing or graft-modifying the same resin as the above polyolefin-based resin with an unsaturated carboxylic acid or an anhydride thereof. And a blend of an unmodified ethylene-α-olefin copolymer and an unsaturated carboxylic acid or anhydride thereof. Examples of the unsaturated carboxylic acid or its anhydride include maleic acid, maleic anhydride, fumaric acid, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, citraconic acid, hexahydrophthalic anhydride and the like. It is preferably used.

At this time, the amount of unsaturated carboxylic acid or anhydride contained in the ethylene-α-olefin copolymer is preferably 0.001 to 10% by weight, more preferably 0.01 to 5% by weight. is there. If the content is small, the adhesive strength is reduced, and if it is too large, a crosslinking reaction is caused and moldability is deteriorated, which is not preferable. It is also possible to mix such an adhesive resin in an adjacent layer.

The laminate of the present invention can be produced not only in the form of a sheet or a film, but also in the form of a pipe or a tube or a tank or the like by the above-mentioned coextrusion molding method, co-injection molding method, co-extrusion inflation molding method or blow molding method. The laminate can be formed into a container such as a bottle, and the laminate can be heated again to about 100 to 150 ° C. and stretched by a blow stretching method or the like.

Each layer of the laminate of the present invention (other than the resin composition layer of the present invention) is provided with an antioxidant, a lubricant, an antistatic agent, a plasticizer, a coloring agent for improving the moldability and physical properties. Agents, ultraviolet absorbers, antibacterial agents, inorganic / organic fillers, and the like can be added as long as the effects of the present invention are not impaired.

Thus, the resin composition of the present invention and molded articles and laminates using the same exhibit extremely excellent effects on moldability, flexibility, abrasion resistance and flame retardancy, and can be used for various applications. In particular, it is very useful as a building material application, an automobile application, and particularly as a flooring application.

[0041]

The present invention will be specifically described below with reference to examples. In the examples, “parts” and “%” mean on a weight basis unless otherwise specified.

Example 1 LLDPE (A1) (density 0.920 g / cm ³ , MI
= 1.0 g / 10 minutes (190 ° C, 2160 g load)), 80 parts of the ethylene-vinyl acetate copolymer resin composition (B1) prepared as described below, and calcium carbonate (C1) having a total amount of 200 parts. Further, 0.1 parts of low molecular weight polyethylene was used to form a sheet at 140 ° C. using two rolls having a diameter of 8 inches.

[Preparation of Ethylene-Vinyl Acetate Copolymer Resin Composition (B1)] Ethylene-vinyl acetate copolymer (b1) particles having a water content of 8.2% (vinyl acetate content: 60.4) %, Melt index (MI): 0.1
g / 10 minutes (190 ° C., 2160 g load)) and 100 parts of CaCO ₃ (b2) 25 having an average particle size of 5.0 μm.
Part, average particle diameter 5.6 μm Ca stearate (b3)
After sufficiently stirring and mixing 1.5 parts, the mixture was air-dried to prepare.

After the obtained sheet was further press-molded at 140 ° C., a test piece according to JIS K 63012 was prepared, and its tensile modulus (tensile condition: tensile speed: 50 mm / m)
in, temperature 20 ° C., humidity 65% RH). or,
Surface hardness of such sheet (measured with durometer D)
And abrasion resistance (wear amount was measured at a wear paper S-42, a load of 530 gf and 100 rotations according to JIS A 1453).

Example 2 In Example 1, the total amount of calcium carbonate (C1) was 4
The same procedure was performed except that the amount was changed to 50 parts, and evaluation was performed in the same manner as in Example 1.

Example 3 In Example 1, LLDPE (A1) (density 0.92
0 g / cm ³ , MI = 1.0 g / 10 min (190 ° C., 2
160 g load)), 30 parts of the ethylene-vinyl acetate copolymer resin composition (B2) prepared as follows,
And calcium carbonate (C1) was evaluated in the same manner as in Example 1 except that 0.1 part of low molecular weight polyethylene was further used so that the total amount was 450 parts.

[Ethylene-vinyl acetate copolymer resin composition
Preparation of Product (B2)] Etched wet 9.2% water
-Vinyl acetate copolymer (b1) particles (containing vinyl acetate)
Amount: 69.8%, melt index (MI): 58 g
/ 10 min (190 ° C, 2160g load) 100 parts
CaCO with an average particle size of 5.0 μm _Three(B2) 30 parts,
Ca (b3) stearic acid having an average particle size of 5.6 μm
After sufficiently stirring and mixing 5 parts, the mixture was air-dried to prepare.

Example 4 In Example 1, LLDPE (A2) (density 0.93
0 g / cm ³ , MI = 1.5 g / 10 min (190 ° C., 2
85 parts), 15 parts of the ethylene-vinyl acetate copolymer resin composition (B3) prepared as follows,
And calcium carbonate (C1) was evaluated in the same manner as in Example 1 except that 0.1 part of low molecular weight polyethylene was further used so that the total amount was 300 parts.

[Preparation of Ethylene-Vinyl Acetate Copolymer Resin Composition (B3)]
1) (vinyl acetate content: 70.3%, melt index (MI): 0.1 g / 10 min (190 ° C., 2160
g load)) 100 parts, CaC having an average particle size of 5.0 μm
28 parts of O ₃ (b2) and 1.3 parts of Ca (b3) stearate having an average particle diameter of 5.6 μm were sufficiently mixed by stirring.

Comparative Example 1 The procedure of Example 1 was repeated except that the ethylene-vinyl acetate copolymer resin composition (B1) was not used.

Comparative Example 2 The procedure of Example 2 was repeated except that the ethylene-vinyl acetate copolymer resin composition (B1) was not blended. However, when the rolls were kneaded, they were brittle and could not be formed into a sheet.

Comparative Example 3 In Example 2, maleic anhydride-modified LLD was used instead of the ethylene-vinyl acetate copolymer resin composition (B1).
The same procedure was performed except that the same amount of the adhesive resin made of PE was blended, and the evaluation was performed in the same manner as in Example 1. Table 1 shows the results of Examples and Comparative Examples.

[Table 1] Formability Workability Tensile modulus Surface hardness Abrasion resistance (MPa) (g) Example 1 Sheet formed 140 56 0.04４2 Sheet formed 290 56 0.07 〃3 Sheet was formed 180 52 0.07 ４4 Sheet was formed 310 53 0.05 Comparative Example 1 Sheet was formed 350 61 0.04 〃2 Sheet was not formed −−−−− − −−− 〃3 Sheet molding was completed 320 71 0.09

[0054]

The resin composition of the present invention comprises a thermoplastic resin (A), a specific ethylene-vinyl acetate copolymer resin composition (B) and an inorganic or organic filler (C). Therefore, it shows excellent effects on moldability, flexibility, and abrasion resistance.Also, even when incinerated as waste, it does not contain chlorine, so it is also environmentally friendly and can be used for various applications. Among them, it is very useful for building materials, automobiles, and especially flooring.

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[Procedure amendment]

[Submission Date] January 10, 2001 (2001.1.1)
0)

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] 0052

[Correction method] Change

[Correction contents]

Comparative Example 3 In Example 2, maleic anhydride-modified LLD was used instead of the ethylene-vinyl acetate copolymer resin composition (# 1).
The same procedure was performed except that the same amount of PE was blended, and the same evaluation as in Example 1 was performed. Table 1 shows the results of Examples and Comparative Examples.

Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat II (Reference) C08K 3/22 C08K 3/22 3/26 3/26 5/098 5/098 // (C08L 101/00 (C08L 101 / 00 23:08) 23:08) (C08L 101/00 (C08L 101/00 31:02) 31:02) F term (reference) 4F071 AA02 AA14 AA15X AA22 AA28X AA31 AA43 AA50 AA51 AA53 AA54 AB18 AB21 AC09 BA01 BB04 BB05 BB06 4F100 AA01A AG00H AH08A AK01B AK03 AK04A AK04J AK21A AK21J AK41 AK48 AK62G AK68A AK71A AL01A AL07G BA02 CA18A CA23A CB00 DE01A JA06A JB16A JL16 YY00A 4J002 AH003 BB031 BB042 BB051 BB061 BB062 BB071 BB121 BB151 BB171 BB231 BC031 BF012 BF032 BG001 BN051 CF001 CG001 CH001 CK001 CL001 DE076 DE078 DE086 DE096 DE106 DE108 DE116 DE148 DE236 DE238 DE246 DG048 DJ008 DJ038 DJ048 DJ058 EG017 EG037 EG047 FA086 FA087 FA108 FD013 FD018 GL00

Claims (8)

[Claims] 1. An ethylene comprising a thermoplastic resin (A), an ethylene-vinyl ester copolymer (b1), inorganic fine particles (b2) having an average particle diameter of 10 μm or less, and a higher fatty acid salt (b3) having an average particle diameter of 10 μm or less. -A resin composition comprising a vinyl ester copolymer resin composition (B) and an inorganic or organic filler (C). 2. The thermoplastic resin (A) is 50 to 99 parts by weight, the ethylene-vinyl ester copolymer resin composition (B) is 1 to 50 parts by weight, and the inorganic or organic filler (C) is a thermoplastic resin. 6 per 100 parts by weight of the total amount of (A) and the ethylene-vinyl ester copolymer resin composition (B)
2. The resin composition according to claim 1, comprising not more than 00 parts by weight. 3. The ethylene-vinyl ester copolymer resin composition (B) contains 5 parts of inorganic fine particles (b2) having an average particle diameter of 10 μm or less per 100 parts by weight of the ethylene-vinyl ester copolymer (b1). 0.1 to 100 parts by weight of a higher fatty acid salt (b3) having an average particle size of 10 μm or less.
3. The composition according to claim 1, which contains 0 parts by weight.
The resin composition as described in the above. 4. An ethylene-vinyl ester copolymer (b)
1) is an ethylene-vinyl acetate copolymer, wherein the content of vinyl acetate in the copolymer is 40 to 95% by weight,
And the melt index (MI) of the copolymer is 0.0
The resin composition according to any one of claims 1 to 3, wherein the resin composition has a pressure of 5 to 300 g / 10 minutes (190 ° C, 2160 g load). 5. An inorganic fine particle (b2) having an average particle diameter of 10 μm or less is at least one of Ca, Mg, Zn, Al, Si and Ba carbonates, hydroxides and oxides. The resin composition according to claim 1. 6. A higher fatty acid salt (b3) having an average particle diameter of 10 μm or less is a higher fatty acid having 8 to 22 carbon atoms, such as Ca, Zn,
The resin composition according to any one of claims 1 to 5, wherein the resin composition is at least one of Mg, Al, and Ba salts. 7. A molded product obtained by molding the resin composition according to claim 1 by any one of calender molding, extrusion molding, and injection molding. 8. A laminate comprising at least one layer comprising the resin composition according to claim 1.