JP2001200334A - 60 kilo class high tensile strength steel excellent in weldability and toughness - Google Patents

60 kilo class high tensile strength steel excellent in weldability and toughness

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Publication number
JP2001200334A
JP2001200334A JP2000008059A JP2000008059A JP2001200334A JP 2001200334 A JP2001200334 A JP 2001200334A JP 2000008059 A JP2000008059 A JP 2000008059A JP 2000008059 A JP2000008059 A JP 2000008059A JP 2001200334 A JP2001200334 A JP 2001200334A
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JP
Japan
Prior art keywords
steel
weldability
less
toughness
strength steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000008059A
Other languages
Japanese (ja)
Other versions
JP3747724B2 (en
Inventor
Minoru Suwa
稔 諏訪
Shinichi Suzuki
伸一 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
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Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Priority to JP2000008059A priority Critical patent/JP3747724B2/en
Publication of JP2001200334A publication Critical patent/JP2001200334A/en
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Publication of JP3747724B2 publication Critical patent/JP3747724B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To produce thick 60 kilo class steel excellent in low temperature toughness and weldability and to provide a method for producing the same. SOLUTION: This 60 kilo class high tensile strength steel excellent in weldability an toughness satisfies, by mass, P cm<=0.2% and Ceq (WES)<=0.42%, preferably has components containing, by mass, 0.04 to 0.09% C, 0.1 to 0.5% Si, 1.2 to 1.8% Mn, 0.1 to 0.5% Cr, 0.01 to 0.05% Nb, 0.002 to 0.07% sol.Al and 0.001 to 0.005% N, also satisfying 0.50<=Si+3Cr<=1.25%, and the balance iron with inevitable impurities as a steel composition and has a structure essentially consisting of bainite with a bainitic lath width of 2 μm or less, and in which filmy ferrite with a thickness of 0.1 to 5 μm is precipitated on the old austenitic grain boundaries in an occupancy ratio of 20% or more.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、建築、橋梁、水
圧鉄管、低温貯蔵タンク、圧力容器、ラインパイプ、船
舶及び海洋構造物等に用いられる60キロ級溶接構造用
鋼で、特に低温靭性に優れた鋼材の製造方法に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a 60-kg class welded structural steel used for construction, bridges, penstocks, low-temperature storage tanks, pressure vessels, line pipes, ships and marine structures, and particularly to low-temperature toughness. The present invention relates to a method for producing an excellent steel material.

【0002】[0002]

【従来の技術】建築、橋梁、水圧鉄管、低温貯蔵タン
ク、圧力容器、ラインパイプ、船舶及び海洋構造物等の
大型構造物が脆性破壊を生じた場合、経済、環境に及ぼ
す影響が大きいため、高度の安全性が求められている。
そのため、これらの構造物に使用される鋼材に対し低温
靭性が要求されることが多く、その要求水準は極寒地に
おける開発、構造物の大型化、及び信頼性要求水準の引
き上げなどにより年々厳しくなっている。また、比較的
低温靭性の確保が難しい厚肉材の需要が増加している。
2. Description of the Related Art When large-scale structures such as buildings, bridges, penstocks, low-temperature storage tanks, pressure vessels, line pipes, ships, and marine structures undergo brittle fracture, the impact on the economy and the environment is great. A high degree of safety is required.
For this reason, low-temperature toughness is often required for steel materials used in these structures, and the required level is becoming more stringent year after year due to development in extremely cold regions, enlargement of structures, and increase in reliability requirements. ing. In addition, there is an increasing demand for thick-walled materials in which it is relatively difficult to ensure low-temperature toughness.

【0003】鋼材の低温靭性を向上させる手段として、
従来よりNi含有量を増加させる方法が知られており、
液化天然ガス(LNG)の貯槽タンクにおいては、9%
Ni鋼が商業規模で使用されている。しかし、Ni量の
増加はコストを大幅に上昇させるため、LNG貯槽以外
の用途には多量の添加は難しい。
As means for improving the low temperature toughness of steel,
Conventionally, a method of increasing the Ni content has been known,
9% for liquefied natural gas (LNG) storage tanks
Ni steel is used on a commercial scale. However, since an increase in the amount of Ni greatly increases costs, it is difficult to add a large amount of Ni to uses other than the LNG storage tank.

【0004】一方、溶接施工性の観点からは、低温割れ
を防止するために行う予熱温度の低下が求められてお
り、近年、予熱フリーの鋼材の需要が急速に増加してい
る。予熱温度を下げるためには、Ceq(WES),P
cmを低減する必要があり、Cを低減することが最も有
効である。
[0004] On the other hand, from the viewpoint of welding workability, it is required to lower the preheating temperature for preventing low-temperature cracking, and in recent years, demand for preheating-free steel materials has been rapidly increasing. To lower the preheating temperature, Ceq (WES), P
cm needs to be reduced, and reducing C is most effective.

【0005】特にCを0.09%以下とした場合、予熱
フリー化が実現される。しかし、Cの低下は強度を低下
させるため、合金元素の添加が必須となるが、コスト的
な制約からNi等の靭性向上に有効な元素を添加しない
場合、上部ベイナイト組織、すなわち、ベイナイトラス
間にセメンタイトが析出した組織となり、優れた低温靭
性を得ることは極めて困難となる。
[0005] In particular, when C is set to 0.09% or less, preheating free is realized. However, since the decrease in C lowers the strength, it is necessary to add an alloying element. However, when an element effective for improving toughness such as Ni is not added due to cost constraints, the upper bainite structure, that is, the bainite lath And a structure in which cementite is precipitated, and it is extremely difficult to obtain excellent low-temperature toughness.

【0006】このような問題を解決する方法として、加
工熱処理により高靭化した570MPa級厚肉高張力鋼
板およびその製造方法が、特開平10−158778号
公報に開示されている。
As a method for solving such a problem, Japanese Patent Application Laid-Open No. H10-158778 discloses a 570 MPa class thick high-tensile steel sheet which has been toughened by thermomechanical treatment and a method for manufacturing the same.

【0007】本技術では、鋼板のフェライト体積率を1
0〜40%とすることにより、組織を分断し、靭性を向
上させることを意図している。しかし、フェライト体積
率が大きくなると降伏強さを確保することが困難であ
り、引張強さ60キロ級鋼に要求される440MPa以
上の降伏強さを厚肉鋼で満足することは困難である。
In the present technology, the ferrite volume ratio of a steel sheet is set to 1
By setting the content to 0 to 40%, it is intended to divide the structure and improve the toughness. However, when the ferrite volume ratio is increased, it is difficult to secure the yield strength, and it is difficult for the thick steel to satisfy the yield strength of 440 MPa or more required for a tensile strength steel of 60 kg.

【0008】また、その製造方法はオーステナイトの未
再結晶温度域で強圧下を加えるものであり、鋼板に異方
性が生じ、溶接部の超音波探傷試験において探傷不良を
生じる場合がある。
[0008] In addition, the manufacturing method is to apply a strong pressure in the non-recrystallization temperature range of austenite, which causes anisotropy in the steel sheet, and may cause defective inspection in an ultrasonic inspection test of a welded portion.

【0009】[0009]

【発明が解決しようとする課題】上述したように、溶接
施工性に優れた60キロ級厚肉鋼材に優れた低温靭性を
付与する技術は未だ完成されていない。本発明は、溶接
施工性に優れ、かつ優れた低温靭性を有する60キロ級
高張力鋼およびその製造方法を提供するものであり、具
体的には以下の性能を満足することを目的とする。降伏
強さ:440MPa以上、引張強さ:570〜610M
Pa級、板厚方向1/4位置でのvTs:−70℃以
下、溶接時の予熱:不要。
As described above, a technique for imparting excellent low-temperature toughness to a 60 kg-class thick steel material excellent in welding workability has not yet been completed. An object of the present invention is to provide a 60-kg class high-strength steel having excellent welding workability and excellent low-temperature toughness, and a method for producing the same. Specifically, an object of the present invention is to satisfy the following performance. Yield strength: 440MPa or more, tensile strength: 570-610M
Pa class, vTs at the 1/4 position in the thickness direction: -70 ° C or less, Preheating during welding: unnecessary.

【0010】[0010]

【課題を解決するための手段】本発明者らは上記課題の
達成に向けて鋭意検討を重ね、高価な合金元素を多量に
添加することなく、優れた溶接施工性と低温靭性を両立
させた鋼材およびその製造方法を完成するに至った。す
なわち、少ない合金元素の添加量で、強度を低下させる
ことなく低温靭性を向上させるため、金属組織を最適化
することを基本方針とし、光学顕微鏡レベル、さらには
電子顕微鏡レベルで検討を行い、以下の知見を得た。
Means for Solving the Problems The inventors of the present invention have made intensive studies to achieve the above object, and have achieved both excellent welding workability and low-temperature toughness without adding a large amount of expensive alloying elements. The steel and its manufacturing method have been completed. In other words, with the addition of a small amount of alloying elements, the basic policy is to optimize the metallographic structure in order to improve the low-temperature toughness without lowering the strength, and to study at the optical microscope level, and further, at the electron microscope level. Was obtained.

【0011】60キロ級の強度を確保するため必須とな
る上部ベイナイトを主体とする組織では、靭性を支配す
る亀裂の発生または伝播が旧オーステナイト粒界におい
て優先的に生じる。これを阻止するためには、粒界にフ
ェライトを析出させ、亀裂の発生または伝播する個所を
ベイナイトパケット境界とすることが有効である。
In a structure mainly composed of upper bainite, which is indispensable for securing a strength of 60 kg class, crack generation or propagation which governs toughness occurs preferentially at the former austenite grain boundary. In order to prevent this, it is effective to precipitate ferrite at the grain boundary and set a point where cracks are generated or propagated as a bainite packet boundary.

【0012】しかし、フェライトの体積分率が多くなり
すぎる場合は強度が低下し、60キロ級鋼としての降伏
強さおよび引張強さを満足することが出来ないため、フ
ェライト相の体積分率が少なくても、低温靭性を向上さ
せる組織形態が望ましく、旧オーステナイト粒界上に膜
状フェライトを析出させ、ベイナイト相をベイナイトラ
ス間隔をある一定値以下に細かくし、強化した組織が最
も強度の低下が少なくかつ低温靭性向上に有効である。
However, when the volume fraction of ferrite is too large, the strength is reduced, and the yield strength and tensile strength of a 60-kg class steel cannot be satisfied. At least, a microstructure that improves low-temperature toughness is desirable, and a film-like ferrite is precipitated on the prior austenite grain boundaries, and the bainite phase is refined to a bainite lath interval of a certain value or less, and the strengthened structure has the lowest strength. And is effective in improving low-temperature toughness.

【0013】本発明はこれらの知見をもとに更に検討を
加えてなされたものである。
The present invention has been made by further study based on these findings.

【0014】1. 質量%で、Pcm≦0.2%、Ce
q(WES)≦0.42%を満たし、ベイナイトラス幅
が2μm以下のベイナイトを主体とし、旧オーステナイ
ト粒界上に厚さ0.1〜5μmの膜状フェライトが20
%以上の占有率で析出した組織を有することを特徴とす
る溶接性および靭性に優れた60キロ級高張力鋼。
1. In mass%, Pcm ≦ 0.2%, Ce
q (WES) ≦ 0.42%, bainite having a bainite lath width of 2 μm or less as a main component, and a film-like ferrite having a thickness of 0.1 to 5 μm on an old austenite grain boundary.
A high-strength steel of 60 kg class having excellent weldability and toughness, characterized by having a structure precipitated at an occupancy of at least%.

【0015】但し、Pcm=C+Mn/20+Si/3
0+Cu/20+Ni/60+Cr/20+Mo/15
+V/10+5B,Ceq(WES)=C+Mn/6+
Si/24+Ni/40+Cr/5+Mo/4+V/1
4 2. 鋼組成として、質量%で、C:0.04〜0.0
9%、Si:0.1〜0.5%、Mn:1.2〜1.8
%、Cr:0.1〜0.5%、Nb:0.01〜0.0
5%、Sol.Al:0.002〜0.07%、N:
0.001〜0.005%を含有し、且つ0.50≦S
i+3Cr≦1.25%を満足する残部が実質的に鉄お
よび不可避不純物からなる1記載の溶接性および靭性に
優れた60キロ級高張力鋼。
However, Pcm = C + Mn / 20 + Si / 3
0 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15
+ V / 10 + 5B, Ceq (WES) = C + Mn / 6 +
Si / 24 + Ni / 40 + Cr / 5 + Mo / 4 + V / 1
4 2. As steel composition, in mass%, C: 0.04 to 0.0
9%, Si: 0.1 to 0.5%, Mn: 1.2 to 1.8
%, Cr: 0.1 to 0.5%, Nb: 0.01 to 0.0
5%, Sol. Al: 0.002 to 0.07%, N:
0.001 to 0.005%, and 0.50 ≦ S
60 kg high strength steel excellent in weldability and toughness according to 1 above, wherein the balance satisfying i + 3Cr ≦ 1.25% is substantially composed of iron and inevitable impurities.

【0016】3. 鋼組成として、更に質量%で、M
o:0.02〜0.3%、Cu:0.1〜0.6%の一
種又は二種を含有する2記載の溶接性および靭性に優れ
た60キロ級高張力鋼。
3. As a steel composition, M
3. A 60-kilometer high-strength steel excellent in weldability and toughness according to 2, which contains one or two kinds of o: 0.02 to 0.3% and Cu: 0.1 to 0.6%.

【0017】4. 鋼組成として、更に質量%で、N
i:0.1〜0.5%を含有する2又は3記載の溶接性
及び靭性に優れた60キロ級高張力鋼。
4. As a steel composition, in mass%, N
i: 60 kg class high strength steel excellent in weldability and toughness according to 2 or 3 containing 0.1 to 0.5%.

【0018】5. 鋼組成として、更に質量%で、V:
0.01〜0.08%を含有する2乃至4記載の何れか
に記載の溶接性及び靭性に優れた60キロ級高張力鋼。
5. As a steel composition, V:
The high strength steel of 60 kg class having excellent weldability and toughness according to any one of 2 to 4, containing 0.01 to 0.08%.

【0019】6. 鋼組成として、更に質量%で、T
i:0.005〜0.02%,Ca:0.001〜0.
004%の一種又は二種を含有する2乃至5記載の何れ
かに記載の溶接性及び靭性に優れた60キロ級高張力
鋼。
6. As steel composition, T
i: 0.005 to 0.02%, Ca: 0.001 to 0.
6. A 60 kg high strength steel excellent in weldability and toughness according to any one of 2 to 5 containing one or two kinds of 004%.

【0020】7. 鋼組成として、質量%で、B:0.
0002%以下とすることを特徴とする2乃至6記載の
何れかに記載の溶接性及び靭性に優れた60キロ級高張
力鋼。
[7] FIG. As a steel composition, B: 0.
The high strength steel of 60 kg class excellent in weldability and toughness according to any of items 2 to 6, wherein the steel content is not more than 0002%.

【0021】8. 鋼組成として、質量%で、P:0.
01%以下,S:0.002%以下とすることを特徴と
する2乃至7記載の何れかに記載の溶接性及び靭性に優
れた60キロ級高張力鋼。
8. As a steel composition, P: 0.
The high strength steel of 60 kg class excellent in weldability and toughness according to any one of 2 to 7, characterized in that the content is 0.01% or less and S: 0.002% or less.

【0022】9. 下記の工程を具備したことを特徴と
する溶接性及び靭性に優れた60キロ級高張力鋼の製造
方法。
9. A method for producing a 60 kg high strength steel excellent in weldability and toughness, comprising the following steps.

【0023】(1)2乃至8の何れかに記載の鋼組成を
有するスラブを1150℃以下に加熱する工程と、
(2)900〜1000℃の温度域でld/hm≧1.
0の圧延を1パス以上行う工程と、 但し、ld:投影接触弧長 ld=(R・(hi−ho))/2 hm:平均板厚 hm=(hi+2ho)/3 R:ロール半径、hi:圧延前の板厚、ho:圧延後の板厚 (3)Ar3以上900℃未満の温度域で累積圧下率1
0〜50%で圧延する工程と、(4)鋼材表面温度がA
r3以上から冷却を開始し、鋼材表面温度が200℃以
上の温度域で鋼材表面の冷却速度が40℃/秒以上とな
る冷却を実施し、鋼材平均温度が500℃以下において
冷却を停止する工程。
(1) a step of heating a slab having the steel composition according to any of 2 to 8 below 1150 ° C .;
(2) Id / hm ≧ 1 in a temperature range of 900 to 1000 ° C.
0: one or more passes, where ld: projected contact arc length ld = (R · (hi−ho)) / 2 hm: average plate thickness hm = (hi + 2ho) / 3 R: roll radius, hi : Sheet thickness before rolling, ho: Sheet thickness after rolling (3) Cumulative rolling reduction 1 in the temperature range of Ar3 or more and less than 900 ° C
A step of rolling at 0 to 50%, and (4) a steel material surface temperature of A
Step of starting cooling from r3 or more, performing cooling such that the cooling rate of the steel material surface becomes 40 ° C / sec or more in a temperature range where the steel material surface temperature is 200 ° C or more, and stopping cooling when the steel material average temperature is 500 ° C or less. .

【0024】[0024]

【発明の実施の形態】以下、本発明におけるミクロ組
織、成分組成、製造条件の限定理由について説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the reasons for limiting the microstructure, component composition, and manufacturing conditions in the present invention will be described.

【0025】1.ミクロ組織 本発明鋼のミクロ組織は、60キロ級の強度を確保する
ため、ベイナイト主体の組織とし、更に強度・靭性の観
点からベイナイトラス幅、旧オーステナイト粒界上にお
けるフェライトの析出状態を規定する。本発明では、ベ
イナイト主体の組織に、その作用,効果を失わない範囲
で、一部フェライト、パーライト等を含むことは差し支
えなく、また、ベイナイトとは上部ベイナイトを主体と
したベイナイトを意味するものとする。
1. Microstructure The microstructure of the steel of the present invention is a bainite-based structure in order to secure a strength of 60 kg class, and further defines the bainite lath width and the precipitation state of ferrite on the former austenite grain boundary from the viewpoint of strength and toughness. . In the present invention, the structure mainly composed of bainite may contain a part of ferrite, pearlite, etc. within a range that does not lose its function and effect, and bainite means bainite mainly composed of upper bainite. I do.

【0026】ベイナイトラス幅:2μm以下 低温靭性を向上させるため、粒界にフェライトを析出さ
せると、強度が低下する。溶接施工時の予熱を不要とす
るため合金添加量を低下したにも拘わらず、コスト的な
制約から、高価な合金元素を添加しない場合、厚肉鋼材
では60キロ級の強度が満足できないことも生じる。
Bainite lath width: 2 μm or less When ferrite is precipitated at grain boundaries in order to improve low-temperature toughness, strength decreases. Despite the fact that the amount of alloy addition was reduced to eliminate the need for preheating during welding work, due to cost constraints, if an expensive alloy element was not added, the strength of a 60-kilometer thick steel material could not be satisfied. Occurs.

【0027】そこで本発明では、ベイナイト相の強度に
影響を与えるベイナイトラス幅を調整し、ベイナイトの
下部組織を適正化する。ベイナイトラス幅は大きくなる
ほど、ベイナイトの強度は低下し、ラス幅が2μmを超
えると厚肉材の場合、60キロ級鋼としての強度が不足
するため、2μm以下とする。尚、ラスのサイズは靭性
に影響を与えないことを確認した。
Therefore, in the present invention, the bainite lath width, which affects the strength of the bainite phase, is adjusted to optimize the bainite lower structure. As the bainite lath width increases, the strength of the bainite decreases. If the lath width exceeds 2 μm, the thickness of a thick-walled material is insufficient for a 60-kilometer steel, and is set to 2 μm or less. It was confirmed that the size of the lath did not affect the toughness.

【0028】粒界フェライト:旧オーステナイト粒界上
で、厚さ0.1〜5μmの膜状に20%以上の占有率で
析出 ベイナイト組織を高靭化するため、旧オーステナイト粒
界上に膜状のフェライトを析出させる。旧オーステナイ
ト粒内に析出したフェライトもベイナイトの高靭化に有
効であるが、その効果は粒界上に比して小さいため、フ
ェライトの析出サイトは粒界上とする。
Grain-boundary ferrite: Precipitate in the form of a film having a thickness of 0.1 to 5 μm on the former austenite grain boundary at an occupation ratio of 20% or more. Of ferrite. Ferrite precipitated in prior austenite grains is also effective in increasing the toughness of bainite, but since the effect is smaller than on the grain boundaries, the ferrite precipitation sites are located on the grain boundaries.

【0029】また、ポリゴナルなフェライトが析出する
と強度の低下が大きくなるため、フェライトの析出形態
は膜状とし、その膜厚は厚さが5μmを超えると強度の
低下が大きく、0.1μm未満では高靭化の効果が明確
でないため、0.1〜5μmとする。さらにフェライト
の旧オーステナイト粒界上の占有率が、20%未満では
高靭化の効果が明確でないため、20%以上とする。
Further, since precipitation of polygonal ferrite causes a large decrease in strength, the precipitation form of ferrite is in the form of a film. When the thickness of the ferrite is more than 5 μm, the decrease in strength is large. Since the effect of toughening is not clear, the thickness is set to 0.1 to 5 μm. Furthermore, if the occupation ratio of ferrite on the former austenite grain boundary is less than 20%, the effect of toughening is not clear, so that it is set to 20% or more.

【0030】尚、粒界占有率は板厚方向に平行な断面を
光学顕微鏡または走査型電子顕微鏡で観察した際、ある
面積中に含まれる旧オーステナイト粒界の総長さに対す
る、旧オーステナイト粒界上に存在する膜状フェライト
の長さの和の割合とする。
The grain boundary occupancy is determined by observing a cross section parallel to the sheet thickness direction with an optical microscope or a scanning electron microscope, on the former austenite grain boundary relative to the total length of the former austenite grain boundary included in a certain area. Is the ratio of the sum of the lengths of the film-like ferrites present in the film.

【0031】2.成分組成 本発明では上述したミクロ組織により、60キロ級鋼と
しての強度を確保するが、溶接性等構造用鋼としての必
要な特性を付与するため、成分組成において以下の限定
を行う。
2. Component Composition In the present invention, the strength as a 60-kilometer steel is ensured by the microstructure described above. However, in order to impart necessary properties such as weldability to structural steel, the following limitations are imposed on the component composition.

【0032】Pcm:0.2%以下、Ceq(WE
S):0.42%以下 Pcmは溶接低温割れ性、Ceq(WES)は溶接熱影
響部の靭性の指標で、Pcmが0.2%を超えた場合、
予熱無しの溶接では低温割れが起こる可能性があり、C
eq(WES)が0.42%を超えた場合、大入熱溶接
の熱影響部靭性が著しく劣化するため、それぞれ、0.
2%以下、0.42%以下とする。
Pcm: 0.2% or less, Ceq (WE
S): 0.42% or less Pcm is weld cold cracking property, Ceq (WES) is an index of toughness of the weld heat affected zone, and when Pcm exceeds 0.2%,
Welding without preheating may cause low temperature cracking.
When eq (WES) exceeds 0.42%, the heat-affected zone toughness of large heat input welding is significantly deteriorated.
2% or less, 0.42% or less.

【0033】更に、本発明鋼として好ましい具体的な成
分組成は以下の通りである。
Further, the preferred specific composition of the steel of the present invention is as follows.

【0034】C:0.04%以上、0.09%以下 Cは所定の強度を確保するため添加する。0.04%未
満では厚肉材の場合、60キロ級の引張強度を確保する
ことが困難で、0.09%を超えると溶接施工性を阻害
するため、0.04%以上、0.09%以下とする。
C: 0.04% or more and 0.09% or less C is added to secure a predetermined strength. If it is less than 0.04%, it is difficult to secure a tensile strength of 60 kg class in the case of a thick material, and if it exceeds 0.09%, welding workability is impaired. % Or less.

【0035】Si:0.1%以上、0.5%以下 Siは強力なフェライト生成元素であり、旧オーステナ
イト粒界に膜状のフェライトを生成させるため添加す
る。0.1%未満ではその効果が十分でなく、0.5%
を超えると効果が飽和し、溶接熱影響部の靭性が著しく
劣化するため、0.1%以上、0.5%以下添加する。
Si: 0.1% or more and 0.5% or less Si is a strong ferrite-forming element, and is added to form a film-like ferrite at a prior austenite grain boundary. If less than 0.1%, the effect is not enough, and 0.5%
If the content exceeds 0.1%, the effect is saturated, and the toughness of the weld heat affected zone is significantly deteriorated.

【0036】Mn:1.2%以上、1.8%以下 Mnは所定の強度を確保するために添加する。1.2%
未満では厚肉材の場合、60キロ級の引張強度を確保す
ることが困難で、1.8%を超えると溶接熱影響部の靭
性が著しく劣化するため、1.2%以上、1.8%以下
とする。
Mn: 1.2% or more and 1.8% or less Mn is added to secure a predetermined strength. 1.2%
If the thickness is less than 60%, it is difficult to secure a tensile strength of 60 kg in the case of a thick material, and if it exceeds 1.8%, the toughness of the heat affected zone is significantly deteriorated. % Or less.

【0037】P:0.010%以下、S:0.002%
以下 P,Sは不純物であり、中央偏析を軽減し、板厚中央の
靭性および溶接性を向上させるため、Pは0.010%
以下、Sは0.002%以下とする。
P: 0.010% or less, S: 0.002%
Hereafter, P and S are impurities, and P is 0.010% in order to reduce central segregation and improve toughness and weldability at the center of the sheet thickness.
Hereinafter, S is set to 0.002% or less.

【0038】Cr:0.1%以上、0.5%以下 Crは強力なフェライト生成元素で、旧オーステナイト
粒界に膜状のフェライトを生成させるために添加する。
0.1%未満ではその効果が不十分で、0.5%を超え
ると焼入れ性が著しく高まり、膜状のフェライトの生成
が困難になるため、0.1%以上、0.5%以下添加す
る。
Cr: 0.1% or more and 0.5% or less Cr is a strong ferrite-forming element and is added to form a film-like ferrite at a prior austenite grain boundary.
If it is less than 0.1%, the effect is insufficient, and if it exceeds 0.5%, hardenability is remarkably increased, and it becomes difficult to form film-like ferrite. I do.

【0039】Nb:0.01%以上、0.05%以下 Nbは、圧延時のオーステナイトの再結晶を抑制し、オ
ーステナイト粒界を活性化させ、膜状フェライトの生成
を容易とする。また、Nb炭窒化物として析出し、強度
上昇に有効なため添加する。0.01%未満ではそれら
の効果が不十分で、0.05%を超えると著しいNb炭
窒化物の析出強化により靭性が劣化するため、0.01
%以上、0.05%以下添加する。
Nb: 0.01% or more and 0.05% or less Nb suppresses austenite recrystallization during rolling, activates austenite grain boundaries, and facilitates formation of film ferrite. Further, Nb is added as it precipitates as Nb carbonitride and is effective in increasing the strength. If it is less than 0.01%, these effects are insufficient, and if it exceeds 0.05%, the toughness deteriorates due to remarkable precipitation strengthening of Nb carbonitride.
% Or more and 0.05% or less.

【0040】sol.Al:0.002%以上、0.0
7%以下 Alは脱酸のため添加する。sol.Al量で、0.0
02%未満の場合その効果が十分でなく、0.07%を
超えて含有すると鋼材の表面疵が発生しやすくなるた
め、0.002%以上、0.07%以下添加する。
Sol. Al: 0.002% or more, 0.0
7% or less Al is added for deoxidation. sol. Al content is 0.0
If the content is less than 02%, the effect is not sufficient, and if the content exceeds 0.07%, the surface flaw of the steel material is apt to occur, so the content is added 0.002% or more and 0.07% or less.

【0041】N:0.001%以上、0.005%以下 Nは圧延加熱時、AlあるいはTiと結合し、AlN,
TiNを生成し、オーステナイトを微細化させる。0.
001%未満ではその効果が十分でなく、0.005%
を超えて含有すると靭性が劣化するため、0.001%
以上、0.005%以下とする。
N: not less than 0.001% and not more than 0.005% N is combined with Al or Ti at the time of rolling and heating, and AlN,
Generates TiN and refines austenite. 0.
If it is less than 001%, the effect is not sufficient, and 0.005%
If the content exceeds 0.001%, the toughness deteriorates.
At least 0.005%.

【0042】B:0.0002%以下 Bは本発明では不純物元素として扱う。冷却開始時、固
溶Bとして存在すると、旧オーステナイト粒界における
膜状フェライトの生成が抑制されるため、溶解原料の選
別などにより、0.0002%以下に規制する。
B: 0.0002% or less B is treated as an impurity element in the present invention. At the start of cooling, if it is present as solid solution B, the formation of film-like ferrite at the prior austenite grain boundaries is suppressed.

【0043】Si+3Cr:0.50%以上、1.25
%以下 本パラメータは上記成分範囲で構成される鋼の旧オース
テナイト粒界に膜状のフェライトを生成させるためのも
のであり、Si+3Crが0.50%未満ではその効果
が十分でなく、1.25%を超えると過度の焼入れ性に
より膜状のフェライトの生成が抑制されるため、0.5
0%以上、1.25%以下とする。
Si + 3Cr: 0.50% or more, 1.25
% Or less This parameter is for forming a film-like ferrite at the former austenite grain boundary of the steel composed of the above component range. When Si + 3Cr is less than 0.50%, the effect is not sufficient, and %, The formation of film-like ferrite is suppressed due to excessive hardenability.
0% or more and 1.25% or less.

【0044】基本成分組成は以上のとおりで、十分に本
発明の目的を達成できるが、更に特性を向上させる場
合、Mo,Cu,Ni,V,Ti,Caを添加させるこ
とができる。
Although the basic component composition is as described above, the object of the present invention can be sufficiently achieved. However, when the characteristics are further improved, Mo, Cu, Ni, V, Ti, and Ca can be added.

【0045】Mo:0.02%以上、0.3%以下、C
u:0.1%以上、0.6%以下の一種または二種 Moは強度を向上させ、特に厚肉材で有効なため、添加
する。0.02%未満ではその効果が十分でなく、0.
3%を超えると溶接性および溶接熱影響部の靭性が著し
く劣化するため、0.02%以上、0.3%以下とす
る。
Mo: 0.02% or more, 0.3% or less, C
u: One or more of 0.1% or more and 0.6% or less Mo is added because it improves the strength and is particularly effective for a thick material. If the content is less than 0.02%, the effect is not sufficient.
If it exceeds 3%, the weldability and the toughness of the heat affected zone are significantly deteriorated.

【0046】Cuは強度を向上させるため添加する。
0.1%未満ではその効果が十分でなく、0.6%を超
えて添加するとCu割れの懸念が高まるため、0.1%
以上、0.6%以下とする。
Cu is added to improve the strength.
If the content is less than 0.1%, the effect is not sufficient, and if the content is more than 0.6%, the possibility of Cu cracking increases.
At least 0.6%.

【0047】Ni:0.1%以上、0.5%以下 Niは靭性を向上させるため添加する。0.1%未満で
はその効果が十分でなく、0.5%を超えると鋼材コス
トの上昇が著しくなるため、0.1%以上、0.5%以
下とする。
Ni: 0.1% or more and 0.5% or less Ni is added to improve toughness. If it is less than 0.1%, the effect is not sufficient, and if it exceeds 0.5%, the cost of steel material increases significantly, so it is made 0.1% or more and 0.5% or less.

【0048】V:0.01%以上、0.08%以下 Vは炭化物として析出し、強度を向上させるため添加す
る。0.01%未満ではその効果が十分でなく、0.0
8%超えでは、著しいV炭化物の析出強化により靭性が
劣化するため、0.01%以上、0.08%以下とす
る。
V: 0.01% or more and 0.08% or less V precipitates as carbide and is added to improve the strength. If it is less than 0.01%, the effect is not sufficient, and
If it exceeds 8%, the toughness is deteriorated due to remarkable precipitation strengthening of V carbide, so that the content is made 0.01% or more and 0.08% or less.

【0049】Ti:0.005%以上、0.02%以
下、Ca:0.001%以上、0.004%以下の一種
または二種 Ti,Caは、母材靭性ならびに溶接熱影響部の靭性を
向上させるため添加する。Tiは圧延加熱時あるいは溶
接時、TiNを生成し、オーステナイト粒径を微細化す
るが、0.005%未満ではその効果が十分でなく、一
方、0.02%を超えて添加すると圧延時にTiNbの
複合炭化物が析出し、Nb炭窒化物の析出量が不足する
ようになり、強度が低下するため、0.005%以上、
0.02%以下とする。
One or two types of Ti: 0.005% or more and 0.02% or less, Ca: 0.001% or more and 0.004% or less Ti, Ca is the base material toughness and the toughness of the weld heat affected zone. Is added to improve the content. Ti generates TiN at the time of rolling heating or welding and refines austenite grain size. However, if the content is less than 0.005%, the effect is not sufficient. On the other hand, if added over 0.02%, TiNb is generated at the time of rolling. The precipitation of the complex carbide of Nb and the precipitation amount of Nb carbonitride becomes insufficient and the strength is reduced.
0.02% or less.

【0050】CaはCa硫酸化物として鋼中に存在し、
圧延加熱時あるいは溶接時にオーステナイト粒径を微細
化する。0.001%未満ではその効果が十分でなく、
0.004%を超えて添加すると多量のCa硫酸化物に
より清浄度を著しく劣化させるため、0.001%以
上、0.004%以下とする。
Ca is present in the steel as Ca sulfate oxide,
Austenite grain size is reduced during rolling or welding. If less than 0.001%, the effect is not enough,
If added in excess of 0.004%, the cleanliness will be significantly degraded by a large amount of Ca sulphate, so the content is made 0.001% or more and 0.004% or less.

【0051】3.製造条件 本発明のミクロ組織は、例えば、以下の工程を備えた製
造方法により達成される。各工程について説明する。
3. Manufacturing Conditions The microstructure of the present invention is achieved, for example, by a manufacturing method including the following steps. Each step will be described.

【0052】スラブを1150℃以下に加熱する工程 スラブ加熱温度は、1150℃を超えると、オーステナ
イト結晶粒が急激に粗大化し、その後の圧延によっても
細粒化が困難となり、低温靭性が劣化する場合があるた
め、1150℃以下とする。
Step of heating the slab to 1150 ° C. or less If the slab heating temperature exceeds 1150 ° C., the austenite crystal grains are rapidly coarsened, and it becomes difficult to reduce the grain size by subsequent rolling, and the low-temperature toughness deteriorates. Therefore, the temperature is set to 1150 ° C. or less.

【0053】900〜1000℃の温度域でld/hm
≧1.0の圧延を1パス以上行う工程 但し、ld:投影接触弧長 ld=(R・(hi−h
o))/2 hm:平均板厚 hm=(hi+2ho)/3 R:ロール半径、hi:圧延前の板厚、ho:圧延後の
板厚 オーステナイト粒径を微細化し、靭性を向上させるた
め、Nb含有鋼における再結晶温度の低温域である90
0〜1000℃において、ld/hm≧1.0を満たす
圧延を1パス以上行い、回復の早い温度域で板厚中央部
まで有効に加工歪を導入する。
Ld / hm in the temperature range of 900 to 1000 ° C.
Step of performing rolling of ≧ 1.0 for one or more passes, where ld: projected contact arc length ld = (R · (hi−h)
o)) / 2 hm: average sheet thickness hm = (hi + 2ho) / 3 R: roll radius, hi: sheet thickness before rolling, ho: sheet thickness after rolling In order to refine the austenite grain size and improve toughness, Nb-containing steel has a low recrystallization temperature range of 90.
At 0 to 1000 ° C., rolling satisfying ld / hm ≧ 1.0 is performed for one or more passes, and a working strain is effectively introduced to a central portion of the sheet thickness in a temperature range in which recovery is quick.

【0054】圧延温度は、900℃未満では再結晶が十
分でなく、1000℃を超えると再結晶粒が大きくなる
ため、900〜1000℃とする。ld/hmは、1.
0未満の場合、板厚中央部に再結晶を励起するのに十分
な加工歪みが加わらないため、1.0以上とする。
If the rolling temperature is less than 900 ° C., recrystallization is not sufficient, and if it exceeds 1000 ° C., the recrystallized grains become large. ld / hm is 1.
When the value is less than 0, a processing strain sufficient to excite recrystallization is not applied to the central portion of the sheet thickness, so that the value is set to 1.0 or more.

【0055】Ar3以上900℃未満の温度域で累積圧
下率10〜50%で圧延する工程靭性を向上させるた
め、Nb含有鋼の未再結晶温度域において累積圧下によ
り加工歪を蓄積し、フェライト変態を促進する。圧延温
度は、Ar3未満では冷却開始時にフェライト変態の進
行により焼入れ性が低下し、所定の強度が得られず、9
00℃以上では再結晶により、加工歪が蓄積されずフェ
ライト変態が不十分となるため、Ar3以上900℃未
満の温度域とする。
In order to improve the process toughness of rolling at a cumulative rolling reduction of 10 to 50% in a temperature range of Ar3 or more and less than 900 ° C., work strain is accumulated by cumulative rolling in a non-recrystallization temperature range of Nb-containing steel, and ferrite transformation is performed. To promote. If the rolling temperature is less than Ar3, the hardenability decreases due to the progress of ferrite transformation at the start of cooling, and the predetermined strength cannot be obtained.
If the temperature is higher than 00 ° C., the processing strain is not accumulated due to recrystallization, and the ferrite transformation becomes insufficient.

【0056】累積圧下率は、10%未満ではフェライト
変態が促進されず、50%を超えるとその効果が飽和
し、鋼材の異方性が急激に増大するため、10〜50%
とする。
If the cumulative rolling reduction is less than 10%, the ferrite transformation is not promoted, and if it exceeds 50%, the effect is saturated and the anisotropy of the steel material sharply increases.
And

【0057】鋼材表面温度がAr3以上から冷却を開始
し、鋼材表面温度が200℃以上の温度域で鋼材表面の
冷却速度が40℃/秒以上となる冷却を実施し、鋼材平
均温度が500℃以下において冷却を停止する工程。圧
延後の冷却は、所定の強度、靭性が得られる焼入れ性を
確保するため、鋼材表面温度をAr3以上とし、冷却開
始時の組織をオーステナイト単相とする。Ar3は例え
ば、Ar3=910−310C−80Mn−20Cu−
15Cr−55Ni−80Moとして求められる。
Cooling is started when the surface temperature of the steel material is Ar3 or higher, and cooling is performed so that the cooling rate of the surface of the steel material becomes 40 ° C / second or more in a temperature range where the steel material surface temperature is 200 ° C or more. A step of stopping cooling in the following. For cooling after rolling, the steel material surface temperature is set to Ar3 or higher and the structure at the start of cooling is a single austenitic phase in order to secure hardenability to obtain predetermined strength and toughness. Ar3 is, for example, Ar3 = 910-310C-80Mn-20Cu-
It is determined as 15Cr-55Ni-80Mo.

【0058】冷却速度は、所定の強度が得られるベイナ
イトラス幅とするため、40℃/秒以上とする。冷却速
度は、工業的な測定方法として、冷却開始時と冷却停止
時の鋼材表面温度の差を冷却時間で除して求めるが、冷
却停止が200℃以下の場合、鋼板表面温度と冷却水の
温度差が小さくなり、見かけ上冷却速度が急激に低下す
るため、冷却開始から鋼材表面温度が200℃の温度域
とする。
The cooling rate is set to 40 ° C./sec or more in order to obtain a bainite lath width at which a predetermined strength can be obtained. The cooling rate is obtained by dividing the difference between the steel surface temperature at the start of cooling and the surface temperature at the time of cooling stop by the cooling time as an industrial measurement method. Since the temperature difference becomes small and the apparent cooling rate sharply decreases, the steel material surface temperature is set to a temperature range of 200 ° C. from the start of cooling.

【0059】冷却停止が200℃超えの場合は、冷却開
始から該冷却停止の温度域とする。冷却は、冷却停止
後、所定の強度を有するベイナイト主体の組織に変態さ
せるため、鋼材平均温度500℃以下において停止す
る。この場合、鋼材平均温度は、冷却停止後鋼材の表面
が鋼材内部の潜熱により復熱した後の温度にほぼ等しい
ことから、鋼材表面の復熱温度で近似することができ
る。
When the cooling stop is higher than 200 ° C., the temperature range is from the start of cooling to the temperature range of the cooling stop. After the cooling is stopped, the cooling is stopped at an average steel material temperature of 500 ° C. or less in order to transform into a bainite-based structure having a predetermined strength. In this case, the average temperature of the steel material can be approximated by the reheat temperature of the surface of the steel material since the temperature of the steel material after cooling is stopped is substantially equal to the temperature after the surface of the steel material is regained by the latent heat inside the steel material.

【0060】[0060]

【実施例】表1に実施例に用いた供試鋼の成分を示す
(表示しない残部は実質的にFeおよび不可避不純物よ
りなる)。これらの化学成分を有する鋳片を加熱後、板
厚30〜100mmの鋼板に圧延、冷却した。表2に製
造条件、表3に鋼板の特性を示す。
EXAMPLES Table 1 shows the components of the test steels used in the examples (the remainder not shown consists essentially of Fe and unavoidable impurities). After heating the slabs having these chemical components, they were rolled into steel plates having a thickness of 30 to 100 mm and cooled. Table 2 shows the manufacturing conditions, and Table 3 shows the properties of the steel sheet.

【0061】ミクロ組織を、光学顕微鏡、走査型電子顕
微鏡、透過型電子顕微鏡により観察し、ベイナイトラス
幅とフェライトの析出状態を測定した。機械的特性とし
て、強度,靭性を求めた。引張試験は板厚1/4より採
取したJIS G14号(14Φ)試験片を用いた試験
とし、衝撃試験は、板厚1/4より長手方向が圧延方向
と直角となるように採取した2mmVノッチシャルピー
衝撃試験片(JIS4号標準試験片)を用いた試験とし
た。
The microstructure was observed with an optical microscope, a scanning electron microscope, and a transmission electron microscope, and the bainite lath width and the state of precipitation of ferrite were measured. Strength and toughness were determined as mechanical properties. The tensile test was a test using a JIS G14 (14Φ) test piece sampled from a 1/4 sheet thickness, and the impact test was a 2 mm V notch sampled so that the longitudinal direction was perpendicular to the rolling direction from a 1/4 sheet thickness. The test was performed using a Charpy impact test piece (JIS No. 4 standard test piece).

【0062】以下、実施例について詳細に説明する。表
1における鋼種A〜Hは請求項1〜8の何れかに記載の
成分組成を満足し、鋼種I,JはCeq(WES),P
cmの規定が本発明範囲外で、鋼種K,LはSi+3C
rが発明の範囲外で比較例となっている。表2,3にお
ける鋼番1〜13は鋼種A〜Hを用いた製造例で請求項
1〜11のいずれかに記載の発明の実施例となってい
る。vTsはー70℃以下で良好な低温靭性が得られて
いる。
Hereinafter, embodiments will be described in detail. Steel types A to H in Table 1 satisfy the component composition described in any of claims 1 to 8, and steel types I and J are Ceq (WES), P
cm is out of the range of the present invention, and steel types K and L are Si + 3C
r is a comparative example outside the scope of the invention. Steel numbers 1 to 13 in Tables 2 and 3 are production examples using steel types A to H, and are examples of the invention according to any one of claims 1 to 11. Good low temperature toughness is obtained at a vTs of -70 ° C or less.

【0063】鋼番14は加熱温度が高く、鋼番15は9
00〜1000℃での圧延を省略したため、vTsがー
70℃超えとなり靭性が低い。鋼番16は冷却速度が遅
く、ベイナイトラス幅が大きく、強度が低い。鋼番17
はオーステナイトの未再結晶温度域での圧延を省略した
ため、フェライト生成量が少なく、靭性に劣っている。
鋼番18は冷却速度が遅くベイナイトラス幅が大きく、
またフェライトも厚くなりすぎ、強度,靭性ともに劣っ
ている。
Steel No. 14 has a high heating temperature, and Steel No. 15 has a heating temperature of 9
Since the rolling at 00 to 1000 ° C. was omitted, vTs exceeded −70 ° C. and the toughness was low. Steel No. 16 has a low cooling rate, a large bainite lath width, and a low strength. Steel number 17
Since the rolling of austenite in the non-recrystallization temperature region was omitted, the amount of ferrite produced was small and the toughness was poor.
Steel No. 18 has a slow cooling rate and a large bainite lath width,
The ferrite is also too thick, and is inferior in both strength and toughness.

【0064】鋼番19はオーステナイト未再結晶域での
累積圧下が多すぎ、鋼板の異方性が大きくなっている。
鋼番20は冷却停止温度が高すぎたため、鋼番21は冷
却開始温度がAr3よりも低くなってしまったため、共
にフェライトが膜状でなくポリゴナルに析出したため、
強度が低い。鋼番22,23はCeq,Pcmが本発明
範囲外で、溶接性が劣化している。鋼番24,25はS
i+3Crの値が発明の範囲内でなく、フェライトの析
出が十分でなく靭性に劣っている。
In steel No. 19, the cumulative reduction in the austenite non-recrystallized region is too large, and the anisotropy of the steel plate is large.
Steel No. 20 had a too high cooling stop temperature, and Steel No. 21 had a cooling start temperature lower than Ar3.
Low strength. Ceq and Pcm of steel numbers 22 and 23 are out of the range of the present invention, and the weldability is deteriorated. Steel numbers 24 and 25 are S
The value of i + 3Cr is not within the range of the invention, and the precipitation of ferrite is not sufficient and the toughness is poor.

【0065】[0065]

【表1】 [Table 1]

【0066】[0066]

【表2】 [Table 2]

【0067】[0067]

【表3】 [Table 3]

【0068】[0068]

【表4】 [Table 4]

【0069】[0069]

【発明の効果】本発明によれば、高価な合金元素を用い
ずに、低温靭性及び、溶接性に優れた厚肉60キロ級鋼
とその製造方法の提供が可能で、産業上、その効果は極
めて大きい。
According to the present invention, it is possible to provide a thick 60-kg class steel excellent in low-temperature toughness and weldability without using expensive alloy elements and a method for producing the same. Is extremely large.

フロントページの続き Fターム(参考) 4K032 AA01 AA02 AA04 AA08 AA11 AA14 AA16 AA19 AA21 AA22 AA23 AA27 AA29 AA31 AA35 AA36 BA01 CA02 CC03 CC04 CD03 CF01 CF02 Continued on the front page F term (reference) 4K032 AA01 AA02 AA04 AA08 AA11 AA14 AA16 AA19 AA21 AA22 AA23 AA27 AA29 AA31 AA35 AA36 BA01 CA02 CC03 CC04 CD03 CF01 CF02

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 質量%で、Pcm≦0.2%、Ceq
(WES)≦0.42%を満たし、ベイナイトラス幅が
2μm以下のベイナイトを主体とし、旧オーステナイト
粒界上に厚さ0.1〜5μmの膜状フェライトが20%
以上の占有率で析出した組織を有することを特徴とする
溶接性および靭性に優れた60キロ級高張力鋼。但し、
Pcm=C+Mn/20+Si/30+Cu/20+N
i/60+Cr/20+Mo/15+V/10+5B,
Ceq(WES)=C+Mn/6+Si/24+Ni/
40+Cr/5+Mo/4+V/14
1. Pcm ≦ 0.2% by mass%, Ceq
(WES) ≦ 0.42%, bainite having a bainite lath width of 2 μm or less, and 20% of 0.1 to 5 μm thick film-like ferrite on the prior austenite grain boundary
A 60 kg high strength steel excellent in weldability and toughness characterized by having a structure precipitated at the above occupancy. However,
Pcm = C + Mn / 20 + Si / 30 + Cu / 20 + N
i / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B,
Ceq (WES) = C + Mn / 6 + Si / 24 + Ni /
40 + Cr / 5 + Mo / 4 + V / 14
【請求項2】 鋼組成として、質量%で、C:0.04
〜0.09%、Si:0.1〜0.5%、Mn:1.2
〜1.8%、Cr:0.1〜0.5%、Nb:0.01
〜0.05%、Sol.Al:0.002〜0.07
%、N:0.001〜0.005%を含有し、且つ0.
50≦Si+3Cr≦1.25%を満足する残部が実質
的に鉄および不可避不純物からなる請求項1記載の溶接
性および靭性に優れた60キロ級高張力鋼。
2. As a steel composition, C: 0.04 by mass%.
0.09%, Si: 0.1 to 0.5%, Mn: 1.2
To 1.8%, Cr: 0.1 to 0.5%, Nb: 0.01
~ 0.05%, Sol. Al: 0.002 to 0.07
%, N: 0.001 to 0.005%, and 0.1%.
The 60 kg class high tensile strength steel excellent in weldability and toughness according to claim 1, wherein the balance satisfying 50 ≦ Si + 3Cr ≦ 1.25% substantially consists of iron and inevitable impurities.
【請求項3】 鋼組成として、更に質量%で、Mo:
0.02〜0.3%、Cu:0.1〜0.6%の一種又
は二種を含有する請求項2記載の溶接性および靭性に優
れた60キロ級高張力鋼。
3. The steel composition further comprises Mo:
The high strength steel of 60 kg class having excellent weldability and toughness according to claim 2, containing one or two kinds of 0.02 to 0.3% and Cu: 0.1 to 0.6%.
【請求項4】 鋼組成として、更に質量%で、Ni:
0.1〜0.5%を含有する請求項2又は3記載の溶接
性及び靭性に優れた60キロ級高張力鋼。
4. The steel composition further includes Ni:
The 60 kg class high strength steel excellent in weldability and toughness according to claim 2 or 3 containing 0.1 to 0.5%.
【請求項5】 鋼組成として、更に質量%で、V:0.
01〜0.08%を含有する請求項2乃至4記載の何れ
かに記載の溶接性及び靭性に優れた60キロ級高張力
鋼。
5. The steel composition, in which V: 0.
The high strength steel of 60 kg class having excellent weldability and toughness according to any one of claims 2 to 4, containing 0.01 to 0.08%.
【請求項6】 鋼組成として、更に質量%で、Ti:
0.005〜0.02%,Ca:0.001〜0.00
4%の一種又は二種を含有する請求項2乃至5記載の何
れかに記載の溶接性及び靭性に優れた60キロ級高張力
鋼。
6. The steel composition further includes Ti:
0.005 to 0.02%, Ca: 0.001 to 0.00
The 60-kilometer high-strength steel excellent in weldability and toughness according to any one of claims 2 to 5, containing 1% or 2% of 4%.
【請求項7】 鋼組成として、質量%で、B:0.00
02%以下とすることを特徴とする請求項2乃至6記載
の何れかに記載の溶接性及び靭性に優れた60キロ級高
張力鋼。
7. The steel composition, in mass%, B: 0.00
The high-strength steel of 60 kg class excellent in weldability and toughness according to any one of claims 2 to 6, characterized in that the content is not more than 02%.
【請求項8】 鋼組成として、質量%で、P:0.01
%以下,S:0.002%以下とすることを特徴とする
請求項2乃至7記載の何れかに記載の溶接性及び靭性に
優れた60キロ級高張力鋼。
8. The steel composition, in mass%, P: 0.01
% Or less, S: 0.002% or less, 60 kg class high strength steel excellent in weldability and toughness according to any one of claims 2 to 7, characterized in that:
【請求項9】 下記の工程を具備したことを特徴とする
溶接性及び靭性に優れた60キロ級高張力鋼の製造方
法。 (1)請求項2乃至8の何れかに記載の鋼組成を有する
スラブを1150℃以下に加熱する工程と、(2)90
0〜1000℃の温度域でld/hm≧1.0の圧延を
1パス以上行う工程と、 但し、ld:投影接触弧長 ld=(R・(hi−ho))/2 hm:平均板厚 hm=(hi+2ho)/3 R:ロール半径、hi:圧延前の板厚、ho:圧延後の板厚 (3)Ar3以上900℃未満の温度域で累積圧下率1
0〜50%で圧延する工程と、(4)鋼材表面温度がA
r3以上から冷却を開始し、鋼材表面温度が200℃以
上の温度域で鋼材表面の冷却速度が40℃/秒以上とな
る冷却を実施し、鋼材平均温度が500℃以下において
冷却を停止する工程。
9. A method for producing a 60 kg high strength steel having excellent weldability and toughness, comprising the following steps. (1) a step of heating the slab having the steel composition according to claim 2 to 1150 ° C. or less;
A step of performing one or more passes of ld / hm ≧ 1.0 in a temperature range of 0 to 1000 ° C., where ld: projected contact arc length ld = (R · (hi−ho)) / 2 hm: average plate Thickness hm = (hi + 2ho) / 3 R: roll radius, hi: sheet thickness before rolling, ho: sheet thickness after rolling (3) Cumulative rolling reduction 1 in a temperature range of Ar3 or more and less than 900 ° C.
A step of rolling at 0 to 50%, and (4) a steel material surface temperature of A
Step of starting cooling from r3 or more, performing cooling such that the cooling rate of the steel material surface becomes 40 ° C / sec or more in a temperature range where the steel material surface temperature is 200 ° C or more, and stopping cooling when the steel material average temperature is 500 ° C or less. .
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