JP2001163723A - Cosmetic - Google Patents

Cosmetic

Info

Publication number
JP2001163723A
JP2001163723A JP35279199A JP35279199A JP2001163723A JP 2001163723 A JP2001163723 A JP 2001163723A JP 35279199 A JP35279199 A JP 35279199A JP 35279199 A JP35279199 A JP 35279199A JP 2001163723 A JP2001163723 A JP 2001163723A
Authority
JP
Japan
Prior art keywords
pearl
acid
glycolic acid
cosmetics
cosmetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP35279199A
Other languages
Japanese (ja)
Other versions
JP4812150B2 (en
Inventor
Kiyosuke Ueda
清資 上田
Yoshio Koizumi
義夫 小泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mikimoto Pharmaceutical Co Ltd
Original Assignee
Mikimoto Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mikimoto Pharmaceutical Co Ltd filed Critical Mikimoto Pharmaceutical Co Ltd
Priority to JP35279199A priority Critical patent/JP4812150B2/en
Publication of JP2001163723A publication Critical patent/JP2001163723A/en
Application granted granted Critical
Publication of JP4812150B2 publication Critical patent/JP4812150B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a cosmetic maximally educing effectiveness of a pearl or a shell containing a nacre in addition to that of glycolic acid, improving effectiveness of firmness or bleaching of the skin, improving effects in an appearance when used to transparent or translucent cosmetics and further solving problems of precipitation, or the like, when used to transparent or translucent liquid cosmetics. SOLUTION: This cosmetic is obtained by formulating the pearl or the shell containing the nacre and the glycolic acid.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は真珠或いは真珠層を含ん
だ貝殻の有効性を最大に活用した化粧料である。また、
これを透明の化粧料に用いたときに外観的な美観も向上
する
BACKGROUND OF THE INVENTION The present invention is a cosmetic composition which makes the most of the effectiveness of a pearl or a shell containing a nacre. Also,
When this is used for transparent cosmetics, the external appearance is also improved.

【0002】[0002]

【従来の技術】真珠或いは真珠層を含んだ貝殻はすでに
化粧料の原料として利用されており、その有効性は広く
認知されている。また、グルコール酸も最近、角質柔軟
剤等として利用されている。
2. Description of the Related Art Pearls or shells containing nacres have already been used as raw materials for cosmetics, and their effectiveness has been widely recognized. Glucholic acid has also recently been used as a keratin softener and the like.

【0003】[0003]

【発明が解決しようとする課題】真珠或いは真珠層を含
んだ貝殻は不溶性のため、化粧料に配合しても溶解しな
いため、配合しても、皮膚内に浸透する量が少なく、せ
っかく配合しても効果が少なくなってしまう欠点があっ
た。この現象に対応すべく、微粉末化したりしているが
限度がある。また、粉末のままでは透明液体化粧料に配
合した場合、沈殿や凝集を起こす。
Since pearls or shells containing nacres are insoluble, they do not dissolve even when incorporated in cosmetics. Therefore, even if incorporated, the amount of permeation into the skin is small. However, there is a disadvantage that the effect is reduced. In order to cope with this phenomenon, the powder is pulverized, but there is a limit. Further, when the powder is used as it is in a transparent liquid cosmetic, precipitation or aggregation occurs.

【0004】[0004]

【課題を解決するための手段】上記の課題を解決するた
め、鋭意検討した結果、グルコール酸とともに配合する
ことがが本課題を解決するにはもっとも適切であること
が本発明者らによって見いだされた。真珠や貝殻は酸で
溶解することは当然知られているが、これは真珠或いは
真珠層にあるコンキオリンという蛋白質を利用するため
に原料段階で利用されるだけであり、本発明の考えとは
異なるものである。また、最近汎用されるαヒドロキシ
酸すべてが本発明に適用できるわけではなく、安全性、
有効性を保持したまま真珠或いは真珠層を含む貝殻を溶
解するにはグルコール酸が最適であった。勿論、他のα
ヒドロキシ酸を併用することは問題ないことは言うまで
もない。
Means for Solving the Problems As a result of diligent studies to solve the above-mentioned problems, the present inventors have found that it is most appropriate to mix them with glycolic acid to solve the problems. Was. It is naturally known that pearls and shells dissolve in acids, but this is only used at the raw material stage to utilize the protein pearl or nacre in concholin, which is different from the idea of the present invention. Things. Also, not all commonly used α-hydroxy acids can be applied to the present invention.
Glucocolic acid was the most suitable for dissolving pearls or shells containing nacres while retaining effectiveness. Of course, other α
It goes without saying that there is no problem in using a hydroxy acid in combination.

【0005】真珠を溶解することは有効性の向上という
大きな効果を発生させるが、さらに透明、或いは半透明
化粧料に用いると、外観上の有利点も生じまた、粘度の
低い液体系では沈殿などの問題点をも解決するという新
たな効果も発揮する。
[0005] Dissolving pearls has a great effect of improving the effectiveness, but when used in transparent or translucent cosmetics, there is an advantage in appearance, and in liquid systems with low viscosity, sedimentation etc. occurs. A new effect of solving the above problem is also exhibited.

【0006】真珠或いは真珠層を含んだ貝殻はアコヤガ
イ、カワシンジュガイ、クロチョウガイ、シナカラスガ
イ等の淡水産、海水産のものから選択すればよい。これ
らを、粉末化して利用する。粉末の程度は特に限定はな
いが、グルコール酸で溶解するときの攪拌時間などが変
化するため、経済的な範囲で粒子径は小さい方がよい。
The pearls or shells containing nacres may be selected from freshwater and marine products such as pearl oysters, pearl mussels, black mussels, and mussels. These are powdered and used. The degree of the powder is not particularly limited, but since the stirring time when dissolving with glycolic acid changes, the smaller the particle size, the better in the economic range.

【0007】グルコール酸はαヒドロキシ酸の一つです
でに化粧料に利用されている。市販の化粧料に利用でき
る品質のものであれば問題なく、他の物質との混合品を
利用することも勿論可能である。
[0007] Glucholic acid is one of α-hydroxy acids and is already used in cosmetics. There is no problem if it is of a quality that can be used for commercially available cosmetics, and it is of course possible to use a mixture with other substances.

【0008】真珠層とグルコール酸の比は0.5:9
9.5〜10:90好ましく、その合計の量は製剤中の
0.5%〜10%が好ましい。0.5%以下では有効性
が少なく、10%以上配合しても、ほとんどメリットが
でない。また、製剤のpHは3.0〜5.5望ましく、
pH3.0以下では刺激の問題があり、pH5.5以上
では溶解が完全に行われない場合がある。
The ratio of nacre to glycolic acid is 0.5: 9
9.5 to 10:90 is preferable, and the total amount is preferably 0.5% to 10% in the preparation. If the content is 0.5% or less, the effectiveness is low, and even if 10% or more is blended, there is almost no merit. In addition, the pH of the preparation is desirably 3.0 to 5.5,
At pH 3.0 or lower, there is a problem of irritation, and at pH 5.5 or higher, dissolution may not be completely performed.

【0009】製造方法は特に限定はなく、通常の化粧料
の作成方法に従えばよい。しかしながら、事前に真珠或
いは真珠層を含んだ貝殻とグルコール酸をよく混和して
溶解しておくことは有意義である。また、製造の途中で
pHが5.5を越えないようにグルコール酸の量や他の
pHを調整する成分を配合或いは配合の順を調整する。
[0009] The production method is not particularly limited, and may be in accordance with the usual method for producing cosmetics. However, it is significant to mix and dissolve the pearl or shell containing nacre and glycolic acid in advance. In addition, the amount of glycolic acid and other components for adjusting pH are blended or the order of blending is adjusted so that the pH does not exceed 5.5 during the production.

【0010】以上のように規定されたものはさまざまな
剤型に配合することができる。例えば、ローション類、
乳液類、クリーム類、軟膏類、パック類、入浴剤の形態
にすることができる。
[0010] Those defined above can be blended in various dosage forms. For example, lotions,
It can be in the form of emulsions, creams, ointments, packs, and bath preparations.

【0011】これら化粧料の剤型を処方化するために、
天然動植物油脂例えば、オリーブ油、ミンク油、ヒマシ
油、パーム油、牛脂、月見草油、ヤシ油、ヒマシ油、カ
カオ油、マカデミアナッツ油等;蝋例えば、ホホバ油、
ミツロウ、ラノリン、カルナウバロウ、キャンデリラロ
ウ等;高級アルコール例えば、ラウリルアルコール、ス
テアリルアルコール、セチルアルコール、オレイルアル
コール等;高級脂肪酸例えば、ラウリン酸、パルミチン
酸、ステアリン酸ィン、固形パラフィン、スクワラン、
ワセリン、セレシン、マイクロクリスタリンワックス
等;合成エステル油例えば、ブチルステアレート、ヘキ
シルラウレート、ジイソプロピルアジペート、ジイソプ
ロピルセバケート、ミリスチン酸オクチルドデシル、イ
ソプロピルミリステート、イソプロピルパルミテートイ
ソプロピルミリステート、セチルイソオクタノエート、
ジカプリン酸ネオペンチルグリコール;シリコーン誘導
体例えば、メチルシリコーン、メチルフェニルシリコー
ン等のシリコーン油
In order to formulate these cosmetic formulations,
Natural animal and vegetable oils and fats such as olive oil, mink oil, castor oil, palm oil, beef tallow, evening primrose oil, coconut oil, castor oil, cacao oil, macadamia nut oil and the like; waxes such as jojoba oil,
Beeswax, lanolin, carnauba wax, candelilla wax and the like; higher alcohols such as lauryl alcohol, stearyl alcohol, cetyl alcohol and oleyl alcohol; higher fatty acids such as lauric acid, palmitic acid, stearic acid, solid paraffin, squalane,
Vaseline, ceresin, microcrystalline wax and the like; synthetic ester oils such as butyl stearate, hexyl laurate, diisopropyl adipate, diisopropyl sebacate, octyl dodecyl myristate, isopropyl myristate, isopropyl palmitate isopropyl myristate, cetyl isooctanoate ,
Neopentyl glycol dicaprate; silicone derivatives such as silicone oils such as methyl silicone and methyl phenyl silicone

【0012】界面活性剤としては、アニオン性界面活性
剤例えば、アルキル硫酸塩、脂肪酸塩、アルキルリン酸
塩、ポリオキシエチレンアルキルエーテルのリン酸塩や
硫酸塩等;非イオン性界面活性剤例えば、グリセリン脂
肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エ
ステル、ポリオキシエチレンアルキルエーテル、ソルビ
タン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ
油、ポリグリセリン脂肪酸エステル等;両面活性剤例え
ば、アルキルベタイン、ホスホベタイン、ホスファチジ
ルコリン、ホスファチジルエタノールアミン、ホスファ
チジルセリン、ホスファチジルグリセロール、ホスファ
チジルイノシトール及びこれらのリゾ体の他、ホスホフ
ァチジン酸とその塩
Examples of the surfactant include anionic surfactants such as alkyl sulfates, fatty acid salts, alkyl phosphates, phosphates and sulfates of polyoxyethylene alkyl ethers; nonionic surfactants such as Glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, polyglycerin fatty acid ester, etc .; , Phosphatidylserine, phosphatidylglycerol, phosphatidylinositol and their lyso forms, as well as phosphatidic acid and its salts

【0013】多価アルコール例えば、エチレングリコー
ル、ジエチレングリコール、トリエチレングリコール、
それ以上のポリエチレングリコール類、プロピレングリ
コール、ジプロピレングリコール、それ以上のポリプロ
ピレングリコール類、1,3−ブチレングリコール、
1,4−ブチレングリコール等のブチレングリコール
類、グリセリン、ジグリセリン、それ以上のポリグリセ
リン類、ソルビトール、マンニトール、キシリトール、
マルチトール等の糖アルコール類、グリセリン類のエチ
レンオキシド(以下、EOと略記)、プロピレンオキシ
ド(以下、POと略記)付加物、糖アルコール類のE
O、PO付加物、ガラクトース、グルコース、フルクト
ース等の単糖類とそのEO、PO付加物、マルトース、
ラクトース等の多糖類とそのEO、PO付加物などの多
価アルコール
Polyhydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol,
More polyethylene glycols, propylene glycol, dipropylene glycol, more polypropylene glycols, 1,3-butylene glycol,
Butylene glycols such as 1,4-butylene glycol, glycerin, diglycerin, and more polyglycerins, sorbitol, mannitol, xylitol,
Sugar alcohols such as maltitol, ethylene oxide (hereinafter abbreviated as EO) of glycerin, propylene oxide (hereinafter abbreviated as PO) adduct, sugar alcohol E
O, PO adducts, monosaccharides such as galactose, glucose and fructose and their EO, PO adducts, maltose,
Polysaccharides such as lactose and polyhydric alcohols such as EO and PO adducts

【0014】薬剤としてトコフェロール、酢酸トコフェ
ロール、ビタミンC、アラントイン、胎盤抽出物、エラ
スチン、アルブチン、コラーゲン、トリクロサン、トリ
クロロカルバン、グリチルリチン酸ジカリウム、メチル
パラベン、ブチルパラベン
As drugs, tocopherol, tocopherol acetate, vitamin C, allantoin, placental extract, elastin, arbutin, collagen, triclosan, trichlorocarban, dipotassium glycyrrhizinate, methylparaben, butylparaben

【0015】これらの原料を組み合わせて必要な製剤を
得る。勿論グリコール酸以外のクエン酸,リンゴ酸,酒
石酸,乳酸等のαヒドロキシ酸の利用は有効である。以
下に実施例を記載するが、本発明はこれらの製造例及び
実施例によって何ら限定されるものではない。
The required preparation is obtained by combining these raw materials. Of course, the use of α-hydroxy acids such as citric acid, malic acid, tartaric acid and lactic acid other than glycolic acid is effective. Examples are described below, but the present invention is not limited by these Production Examples and Examples.

【0016】 (実施例1) ローション 重量部 オリーブ油 0.5 ポリオキシエチレン(20E.O.)ソルビタンモノステアレート 2.0 ポリオキシエチレン(60E.O.)硬化ヒマシ油 2.0 エタノール 10.0 1.0%ヒアルロン酸ナトリウム水溶液 1.0 1,3ブチレングリコール 5.0 真珠末(アコヤ貝真珠の微粉砕物) 0.1 グリコール酸 2.0 精製水 77.4Example 1 Lotion parts by weight olive oil 0.5 polyoxyethylene (20E.O.) sorbitan monostearate 2.0 polyoxyethylene (60E.O.) hydrogenated castor oil 2.0 ethanol 10.0 1.0% sodium hyaluronate aqueous solution 1.0 1,3 butylene glycol 5.0 Pearl powder (finely ground pearl pearl) 0.1 glycolic acid 2.0 Purified water 77.4

【0017】 (実施例2) クリーム 重量部 A スクワラン 20.0 オリーブ油 2.0 ミンク油 1.0 ホホバ油 5.0 ミツロウ 5.0 セトステアリルアルコール 2.0 グリセリンモノステアレート 1.0 ソルビタンモノステアレート 2.0 B 精製水 46.85 ポリオキシエチレン(20E.O.)ソルビタンモノステアレート 2.0 ポリオキシエチレン(60E.O.)硬化ヒマシ油 1.0 グリセリン 5.0 1.0%ヒアルロン酸ナトリウム水溶液 2.0 アコヤ貝殻の微粉砕物 0.05 グリコール酸 5.0 パラオキシ安息香酸メチル 0.1 AとBをそれぞれ計量し、70℃まで加温し、BにAを
攪拌しつつ徐々に加えたのち、ゆっくり攪拌しつつ30
℃まで冷却した。
(Example 2) Cream parts by weight A Squalane 20.0 Olive oil 2.0 Mink oil 1.0 Jojoba oil 5.0 Beeswax 5.0 Cetostearyl alcohol 2.0 Glycerin monostearate 1.0 Sorbitan monostea Rate 2.0 B Purified water 46.85 Polyoxyethylene (20E.O.) Sorbitan monostearate 2.0 Polyoxyethylene (60E.O.) Hydrogenated castor oil 1.0 Glycerin 5.0 1.0% Hyaluron Aqueous sodium acid solution 2.0 Finely pulverized pearl oyster shells 0.05 Glycolic acid 5.0 Methyl parahydroxybenzoate 0.1 A and B are each weighed, heated to 70 ° C, and gradually stirred into B while A is stirred. And then slowly agitate for 30 minutes.
Cooled to ° C.

【0018】(使用テスト)女性8名の顔面を左右に分
け、一方に、実施例のローションとクリームをセットに
して、他方には比較例のローションとクリームをセット
にして毎日、1回以上使用してもらって、3カ月後に、
美白、肌荒れ防止、肌のつや、クスミの改善及び肌のは
りについて評価した。なお、16名を2班にわけ、下記
表1に示される試料を使って試験した。
(Usage test) The face of eight women was divided into left and right sides, and the lotion and cream of the example were set on one side, and the lotion and cream of the comparative example were set on the other side. After three months,
Evaluation was made on whitening, prevention of rough skin, improvement of skin luster, blemishes, and skin abrasion. In addition, 16 persons were divided into two groups and tested using the samples shown in Table 1 below.

【0019】なお、比較例は以下に示す。 比較例1 実施例1よりグルコール酸を除き、他は実施例1と同様
に作成したもの 比較例2 実施例2よりグルコール酸を除き、他は実施例2と同様
に作成したもの 比較例3 実施例1より真珠末を除き、他は実施例1と同様に作成
したもの 比較例4 実施2よりアコヤ貝殻の微粉砕物を除き、他は実施例2
と同様に作成したもの
A comparative example is shown below. Comparative Example 1 A product prepared in the same manner as in Example 1 except for glycolic acid from Example 1 Comparative Example 2 A product prepared in the same manner as in Example 2 except for glycolic acid from Example 2 Comparative Example 3 Except for the pearl powder from Example 1, except that it was prepared in the same manner as in Example 1. Comparative Example 4 Except for the finely ground pearl oyster shell from Example 2, except for Example 2,
Created in the same way as

【0020】評価は、下記の評価基準により評価し、そ
の結果をまとめたのが下記の表2である。 (評価基準) 実施例の方が非常によい 3 実施例の方がかなりよい 2 実施例の方がややよい 1 差がない 0 比較例の方がややよい −1 比較例の方がかなりよい −2 比較例の方が非常によい −3
The evaluation was performed according to the following evaluation criteria, and the results are summarized in Table 2 below. (Evaluation criteria) Example is very good 3 Example is considerably better 2 Example is slightly better 1 No difference 0 Comparative example is slightly better -1 Comparative example is much better − 2 Comparative example is much better -3

【0021】 [0021]

【0022】[0022]

【効果】真珠或いは真珠層を含んだ貝殻とグルコール酸
を配合した化粧料はグルコール酸の有効性は勿論、真珠
或いは真珠層を含んだ貝殻の有効性を最大限に引き出
し、肌のはりや美白などの有効性が高まり、また、透
明、半透明の化粧料に用いると外観上の効果、透明、半
透明の液状の化粧料に用いれば、さらに沈殿などの問題
が解決された。
【Effects】 Cosmetics containing pearl or nacreous shells and glycolic acid have the best effect of cholesteric acid as well as pearls or nacreous shells. In addition, when used in transparent or translucent cosmetics, the effect on appearance is improved, and when used in transparent or translucent liquid cosmetics, problems such as precipitation are further solved.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】真珠或いは真珠層を含んだ貝殻とグルコー
ル酸を配合した化粧料
1. A cosmetic composition containing pearl or a shell containing nacre and glycolic acid.
JP35279199A 1999-12-13 1999-12-13 Cosmetics Expired - Fee Related JP4812150B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP35279199A JP4812150B2 (en) 1999-12-13 1999-12-13 Cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP35279199A JP4812150B2 (en) 1999-12-13 1999-12-13 Cosmetics

Publications (2)

Publication Number Publication Date
JP2001163723A true JP2001163723A (en) 2001-06-19
JP4812150B2 JP4812150B2 (en) 2011-11-09

Family

ID=18426473

Family Applications (1)

Application Number Title Priority Date Filing Date
JP35279199A Expired - Fee Related JP4812150B2 (en) 1999-12-13 1999-12-13 Cosmetics

Country Status (1)

Country Link
JP (1) JP4812150B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003081750A (en) * 2001-09-14 2003-03-19 Mikimoto Pharmaceut Co Ltd Cosmetic or food
JP2003300808A (en) * 2002-04-08 2003-10-21 Mikimoto Pharmaceut Co Ltd Skin care preparation
JP2003300822A (en) * 2002-04-08 2003-10-21 Mikimoto Pharmaceut Co Ltd Skin care preparation for external use
KR100718190B1 (en) 2005-12-27 2007-05-16 남종현 Skin whitening cosmetic composition, pack containing the same and preparation method thereof
JP2010095464A (en) * 2008-10-15 2010-04-30 Mikimoto Pharmaceut Co Ltd Skin external preparation and its manufacturing method
JP2011162469A (en) * 2010-02-08 2011-08-25 Mikimoto Pharmaceut Co Ltd Skin keratinization promoter
JP2014051440A (en) * 2012-09-05 2014-03-20 Mikimoto Pharmaceut Co Ltd Metallothionein production accelerator and antioxidant

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003081750A (en) * 2001-09-14 2003-03-19 Mikimoto Pharmaceut Co Ltd Cosmetic or food
JP2003300808A (en) * 2002-04-08 2003-10-21 Mikimoto Pharmaceut Co Ltd Skin care preparation
JP2003300822A (en) * 2002-04-08 2003-10-21 Mikimoto Pharmaceut Co Ltd Skin care preparation for external use
KR100718190B1 (en) 2005-12-27 2007-05-16 남종현 Skin whitening cosmetic composition, pack containing the same and preparation method thereof
JP2010095464A (en) * 2008-10-15 2010-04-30 Mikimoto Pharmaceut Co Ltd Skin external preparation and its manufacturing method
JP2011162469A (en) * 2010-02-08 2011-08-25 Mikimoto Pharmaceut Co Ltd Skin keratinization promoter
JP2014051440A (en) * 2012-09-05 2014-03-20 Mikimoto Pharmaceut Co Ltd Metallothionein production accelerator and antioxidant

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