JP2001058318A - Interior finish plate for building - Google Patents

Interior finish plate for building

Info

Publication number
JP2001058318A
JP2001058318A JP11271005A JP27100599A JP2001058318A JP 2001058318 A JP2001058318 A JP 2001058318A JP 11271005 A JP11271005 A JP 11271005A JP 27100599 A JP27100599 A JP 27100599A JP 2001058318 A JP2001058318 A JP 2001058318A
Authority
JP
Japan
Prior art keywords
diamond
zeolite
cut
area
plate material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11271005A
Other languages
Japanese (ja)
Inventor
Shinji Ishikawa
信司 石川
Yoshiyasu Ishiyama
慶泰 石山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KANTO ZEOLITE KK
Original Assignee
KANTO ZEOLITE KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KANTO ZEOLITE KK filed Critical KANTO ZEOLITE KK
Priority to JP11271005A priority Critical patent/JP2001058318A/en
Publication of JP2001058318A publication Critical patent/JP2001058318A/en
Pending legal-status Critical Current

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  • Processing Of Stones Or Stones Resemblance Materials (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain an interior finish plate for building which is fitted to the ceiling, wall, and floor of a closed habitable space, adsorbs/decomposes/ eliminates gaseous evaporated chemicals and odors, absorbs excess moisture, prevents the propagation of floating bacteria and molds, and maintains a safe, comfortable, hygienic habitable space over a long period. SOLUTION: A zeolite mineral which comprises crystalline zeolite and volcanic vitreous materials and has water resistance to prevent collapse by moisture absorption/water absorption, a specific surface area of at least 15 m/g, a base substitution capacity of meq/100 g and Mohs hardness of 4.8-5.8 is cut directly by a diamond particle blade having diamond particles 0.5-2.0 mm in diameter into pieces having at least 3 mm thickness and a required area to make a zeolite plate 3, which is dried to be 3.0% or below in water content. A coating layer coated with a binder made of cement, gypsum, diatomaceous earth, or clay containing substantially at least 0.1 wt.% of electromagnetic wave radiation ceramic fine powder which can excite water molecules is formed at least on one side of the plate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、中、高層集合住宅や戸
建住宅等密閉性の高い居住空間を、長期に亘って安全に
且快適で而も衛生的に保持しえる建築用内装板材に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an interior panel material for a building capable of maintaining a highly sealed living space, such as a middle-rise or high-rise apartment house or a detached house, safely and comfortably for a long period of time. About.

【0002】[0002]

【従来技術】我が国では経済成長とともに都市部への労
働移動が急速に高まり、これに伴い都市部では宅地供給
が逼迫し宅地の高騰が招来され、以来今日まで高値で推
移している。これがため都市部では土地の有効利用を図
るうえから、鉄骨鉄筋コンクリート構造による中高層集
合住宅が多量に建設供給され、更に戸建住宅においても
宅地の高騰に伴い都市近郊で狭少な面積で且多数に区画
された宅地の購入を余儀なくされ、この結果該狭少な宅
地に建蔽率いっぱいの建築がなされて却って密集林立し
た状態を呈している。
2. Description of the Related Art In Japan, labor movement to urban areas has rapidly increased along with economic growth. Residential land supply has become tight in urban areas, resulting in soaring residential land. For this reason, in order to effectively use land in urban areas, a large number of medium- and high-rise apartment buildings with steel reinforced concrete structures are constructed and supplied. As a result, the small residential land has been constructed with a high building coverage ratio, and is in a densely forested state.

【0003】ところで中、高層住宅においては、躯体が
鉄骨鉄筋コンクリート構造に加え、アルミサッシや鉄扉
等が用いられるため居住空間の密閉性が極めて高く、更
に戸建住宅においても近年では耐火性や耐震性はもとよ
り防音性や遮音性或いは省エネルギーのための断熱性等
が求められ、且戸建住宅では各戸毎に多彩なデザインや
設計が要請されること等からプレハブ工法やプレカット
工法による戸建住宅が積極的に採用されており、而もこ
れら戸建住宅もアルミサッシやアルミ開口扉を初めコン
クリートパネルやセラミックス外壁材、更には内装材に
も合板類やボード類等が使用されるために居住空間の密
閉性が著るしく高まっている。
[0003] In a middle-rise high-rise house, an aluminum sash or an iron door is used in addition to a steel-framed reinforced concrete structure, so that the airtightness of a living space is extremely high. Needless to say, sound insulation, sound insulation and heat insulation for energy saving are required, and in detached houses, various designs and designs are required for each house. These detached houses also use aluminum sashes and aluminum opening doors, concrete panels and ceramic outer wall materials, as well as plywood and boards for interior materials. Hermeticity is significantly increased.

【0004】加えてこれら密閉性の高い中、高層集合住
宅或いは戸建住宅の内装材には色彩感や自然感、豪華さ
や重厚感等居住者の多様な好みや価値感に合せて合成樹
脂板材や合板材、石膏ボード、クロスや合成樹脂或いは
紙素材の壁材或いは塗料等が、更には床材としても合成
樹脂タイルや合成繊維カーペット、合板材等が主に合成
樹脂接着剤等により施工されている。然るにこれら居住
空間は密閉性が高いため、使用経過とともに各種の建築
部材はもとより内装材の接着や塗着に係る接着剤や塗着
剤或いは内装材自体に含有されている化学物質例えばホ
ルムアルデヒド等の揮散ガスが居住空間内に揮散滞留
し、居住者の身体疾病を誘発する所謂ハウスシックが大
きな社会問題として提起されている。加えて居住空間の
密閉性の高まりに伴い生活臭もこもり易く且この生活臭
が内装材等に付着浸透して一段と不快な居住空間と化
し、更には居住空間内は空気の流通も悪く且水回り設備
等による多湿で而も年間を通して温暖なため細菌や黴菌
が繁殖し易く、かかる菌類の繁殖による異臭の発生はも
とよりダニ等の不快害虫の蛸集をも惹起せしめ、且これ
ら死菌類や不快害虫の死骸がアレルギー疾患の主たる原
因となる等極めて非衛生的居住空間での生活を余儀なく
されている。更にかかる居住空間では冬期乾燥時におけ
る僅かな加湿手段でも内壁面や窓ガラス等に結露が発生
し、建物の腐蝕劣化や菌類の繁殖を増長し、且夏期の多
湿時には湿気の除去のため膨大なエネルギーを用いて冷
房除湿を図らねばならない。
In addition, the interior materials of high-rise apartment houses or detached houses with high airtightness are made of synthetic resin plate materials in accordance with various tastes and values of residents, such as color, natural feeling, luxury and solid feeling. Plywood, gypsum board, cloth or synthetic resin or paper wall material or paint etc., and also as floor material, synthetic resin tile, synthetic fiber carpet, plywood material etc. are mainly constructed with synthetic resin adhesive etc. ing. However, since these living spaces have high sealing properties, as the use progresses, various building materials as well as adhesives and coatings for interior material adhesion and coating or chemical substances contained in the interior material itself, such as formaldehyde, etc. The so-called house-sick, in which the volatile gas is vaporized and stays in the living space, causing physical illness of the resident, has been raised as a major social problem. In addition, the living odor tends to be muffled with the increase in the airtightness of the living space, and the living odor adheres to and penetrates the interior materials, etc., and becomes a more uncomfortable living space. Bacteria and fungi are liable to propagate due to the humid and warm environment throughout the year due to the surrounding facilities. Pest carcasses are a major cause of allergic diseases, forcing them to live in extremely unsanitary living spaces. Further, in such a living space, even with a slight humidification method during the winter drying, dew condensation occurs on the inner wall surface and the window glass, and the corrosion deterioration of the building and the propagation of fungi increase. Energy must be used for cooling and dehumidification.

【0005】かかる問題に際して発明者は既に密閉性の
建物空間内における細菌や黴菌等の繁殖抑制と臭気の分
解消去を図るため、無機質素材にその粒径が30μm以
下で且その放射波長が2.7乃至3.2μmの近赤外線
領域並びに5.0乃至7.4μmの遠赤外線領域の電磁
波が黒体の放射率に対し少なくとも0.8以上の放射率
を有する電磁波放射セラミックス粉材を0.1%重量以
上の割合で配合のうえ、水と混練して所要形状に凝固成
形し、或いはこの凝固成形物を900℃以下の温度で焼
成させた抗菌消臭建材を先願として特願平9−3469
57号で開示している。
In view of such a problem, the inventor has already made inorganic materials having a particle size of 30 μm or less and a radiation wavelength of 2.about. Electromagnetic waves in the near infrared region of 7 to 3.2 μm and in the far infrared region of 5.0 to 7.4 μm have an electromagnetic radiation ceramic powder material having an emissivity of at least 0.8 or more with respect to the emissivity of the black body. % By weight or more, and kneaded with water to solidify and mold into a required shape, or to sinter the solidified molded product at a temperature of 900 ° C. or less. 3469
No. 57.

【0006】しかしながら該先願発明においても使用素
材がセメントの場合には凝固成形物が実用強度は保持す
るものの薄物の成形性に劣り、而も内装材の如く美感や
寸法精度が要求されるものには対処できず、更に石膏や
粘土等の素材では凝固成形に際しての乾燥に極めて長時
間を要するばかりか、乾燥に伴う歪みや変形の発生が多
く、而も焼成に際しても長時間に亘る加温勾配と焼成時
間を要し、且降温勾配の管理も厳格になさぬとクラック
の発生や損傷が多発し、而も内装材の如く幅広の製品に
は極めて大型の焼成炉が要請される等生産に際しての技
術面やコスト面で多くの問題を抱えている。加えて近年
ではゼオライト鉱石が多孔質で且塩基置換性も保持する
ことから、該ゼオライト鉱石を素材とした内装板材の試
みがなされているものの、通常ゼオライト鉱石はその組
成においてモンモリロナイトを主体とする粘土質分を多
量に含有するため吸湿や吸水に伴って該粘土質が吸水膨
潤化して自己崩壊するため、内装板材等には一旦微粉体
となしたるうえ加水して粘性と可塑性を付与せしめ、所
要の形状に凝固形成し、而して乾燥のうえ焼成成形せね
ばならず結局前記の如き実用生産に際しての問題に阻ま
れている。
However, in the prior application, when the material used is cement, the solidified molded product retains practical strength but is inferior in moldability of a thin material, and is required to have aesthetics and dimensional accuracy like interior materials. In addition, materials such as gypsum and clay not only take an extremely long time to dry during solidification and molding, but also generate a lot of distortion and deformation due to drying, and heating for a long time also during firing. Gradient and firing time are required, and if the temperature drop gradient is not strictly controlled, cracks are frequently generated and damaged, and extremely large firing furnaces are required for wide products such as interior materials. There are many problems in terms of technology and cost. In addition, in recent years, since zeolite ore is porous and retains base substitution properties, attempts have been made for interior plate materials using the zeolite ore as a raw material. However, zeolite ore is usually made of clay mainly composed of montmorillonite in its composition. Since the clay material absorbs water and swells due to moisture absorption and self-disintegrates as it contains a large amount of material, the interior plate material and the like once become a fine powder and then added with water to impart viscosity and plasticity, It must be solidified and formed into a desired shape, and then dried and fired, which is ultimately hampered by the problems in practical production as described above.

【0007】[0007]

【発明が解決しようとする課題】本発明はかかる問題に
鑑み鋭意研究を重ねた結果、極めて広範な地域で産出さ
れるゼオライト鉱石は、その産出鉱区により組成や性能
を著しく異にするものであることを初め、居住空間内の
化学揮散ガスや臭気を積極的に吸着し分解させるために
は、その比表面積が少なくとも15m/g以上の多孔
性で且塩基置換容量(meq/100g)が150mg
以上のものが好適であることや、多湿時における吸湿と
乾燥時における放湿所謂調湿性が発揮されること、並び
にその組成においてゼオライト結晶体と火山ガラス質分
とで構成されるものでは、吸湿や吸水に際しても自己崩
壊しない十分な耐水性が保持され、且そのモース硬度が
4.8乃至5.8程度の硬度のものは強靭性も高く特定
のダイヤモンド粒刃を使用することで、ゼオライト鉱石
を直接薄肉に且所要の面積を以って能率良く切断し生産
しえること、及び該ゼオライト鉱石にはセメント、石
膏、粘土或いは珪藻土等との接着性が極めて優れること
等を究明し本発明に至った。即ち本発明は密閉性の高い
居住空間に内装板材として簡便に施工しえ且化学揮散ガ
スや臭気を積極的に吸着分解させ而も居住空間内の過剰
な湿気を吸湿させ菌類の繁殖抑制若しくは防止を図り、
長期に亘って安全で快適且衛生的な居住空間を創出しえ
る建築用内装板材を安価に提供することにある。
SUMMARY OF THE INVENTION In view of the above problems, the present invention has been intensively studied, and as a result, the composition and performance of zeolite ore produced in an extremely wide area are significantly different depending on the production area. First, in order to positively adsorb and decompose the chemical volatile gas and odor in the living space, the specific surface area is at least 15 m 2 / g or more, and the base substitution capacity (meq / 100 g) is 150 mg.
The above-mentioned thing is preferable, and it is possible to exhibit the so-called humidity control of moisture absorption and drying during drying and moisture absorption at the time of high humidity, and the composition composed of the zeolite crystal and the volcanic glass material in the composition, And a Mohs hardness of about 4.8 to 5.8, which has high toughness and high specific toughness, can be obtained by using a specific diamond grain blade. The present invention has been investigated to be able to cut and produce the product directly into a thin wall and efficiently with a required area, and that the zeolite ore has extremely excellent adhesion to cement, gypsum, clay or diatomaceous earth. Reached. That is, the present invention can be easily constructed as an interior plate material in a highly enclosed living space, and actively absorbs and decomposes chemical volatile gases and odors, and also absorbs excessive moisture in the living space to suppress or prevent the growth of fungi. And
An object of the present invention is to provide an inexpensive architectural interior panel material that can create a safe, comfortable and hygienic living space for a long period of time.

【0008】[0008]

【課題を解決するための手段】上述の課題を解決するた
めに本発明が用いた技術的手段は、その組成がクリノプ
チロライト若しくはモルデナイトからなるゼオライト結
晶体と石英、長石、曹長石等のガラス質成分とからなる
耐水性を保持し、且その比表面積が少なくとも15m
/g以上及び塩基置換容量(meq/100g)が15
0mg以上で而もそのモース硬度が4.8乃至5.8の
ゼオライト鉱石を用いて、その直径が0.5乃至2.0
mmのダイヤモンド粒が植設されたダイヤモンド粒刃を
有するダイヤカッター、ダイヤ帯鋸、若しくはダイヤワ
イヤソーを用いて、注水冷却を施し且切断に伴う粉屑を
洗浄流出させながら、少なくともその厚さが3mm以上
で適宜面積のゼオライト板材を切断形成させたうえ、適
宜の乾燥手段によって残留水分率が3.0%以下となる
よう乾燥を施してなる建築用内装板材の構成に存するも
のである。加えて、建築用内装板材には、一方において
使用する居住者の多様な意匠上の好みや価値感が要請さ
れることから切断されて形成されるゼオライト板材の一
側面の切断に際しては、その直径の小さなダイヤモンド
粒が植設されたダイヤモンド粒刃のダイヤカッター、ダ
イヤ帯鋸、ダイヤワイヤソーを用いて切断面を比較的平
滑に切断形成し、且他側面の切断に際しては、その直径
の大きなダイヤモンド粒が植設されたダイヤモンド粒刃
のダイヤカッター、ダイヤ帯鋸若しくはダイヤワイヤソ
ーで切断することにより切断面を粗面状に切断形成させ
る構成、並びに切断形成されたゼオライト板材の一側面
を更に研磨して平滑性と艶を付与せしめる構成、及び切
断形成されたゼオライト板材をその温度が400乃至9
00℃の適宜温度で仮焼して、ゼオライト板材の全体色
調を乳白淡褐色に色調変化させる構成にある。
The technical means used by the present invention to solve the above-mentioned problems is that a zeolite crystal having a composition of clinoptilolite or mordenite and a quartz, feldspar, feldspar or the like are used. The water resistance of the vitreous component is maintained, and the specific surface area is at least 15 m 2.
/ G or more and the base substitution capacity (meq / 100 g) is 15
A zeolite ore having a Mohs hardness of 4.8 to 5.8 and a diameter of 0.5 to 2.0 is used.
Using a diamond cutter, diamond band saw, or diamond wire saw having a diamond grain blade with diamond grains of 1 mm, water-cooling is performed and at least its thickness is at least 3 mm while washing and flowing out the dust accompanying the cutting. In this case, a zeolite plate material having an appropriate area is cut and formed, and then dried by a suitable drying means so that the residual moisture content becomes 3.0% or less. In addition, since the interior paneling material for building is required to have a variety of design preferences and values of the occupants used on the one hand, when cutting one side of the zeolite plate material formed by cutting, The cutting surface is cut relatively smoothly using a diamond cutter, diamond band saw, or diamond wire saw with a diamond grain blade in which small diamond grains are implanted. A configuration in which the cut surface is cut and formed by cutting with a diamond cutter, diamond band saw or diamond wire saw with an implanted diamond grain blade, and one side of the cut and formed zeolite plate material is further polished for smoothness. And a zeolite plate cut and formed at a temperature of 400 to 9
It is configured to calcine at an appropriate temperature of 00 ° C. to change the overall color tone of the zeolite plate material to a milky white light brown color.

【0009】更に本発明では密閉性の高い居住空間内に
揮散滞留する化学揮散ガスやその空気中に拡散する臭気
ガスを長期に亘って安全に分解消去せしめ、且浮遊する
細菌や黴菌の繁殖を抑制防止するため、ゼオライト板材
の少なくとも一側面にその放射波長が2.7乃至3.2
μmの近赤外線領域及びその放射波長が5.0乃至7.
4μmの遠赤外線領域の電磁波を黒体の放射率に対し
0.8以上の放射率を以って放射しえる電磁波放射セラ
ミックス微粉体を、セメント、石膏、珪藻土若しくは粘
土をバインダーとして水と混合分散させたうえ、該電磁
波放射セラミックス微粉体がゼオライト板材の重量に対
して0.1%重量以上の割合で添着されるよう塗着乾燥
させた塗着層が形成されてなる構成に存する。
Further, according to the present invention, chemically volatile gas that stagnates and stays in a highly sealed living space and odor gas that diffuses in the air can be safely decomposed and eliminated over a long period of time, and the propagation of floating bacteria and fungi can be prevented. In order to prevent suppression, at least one side surface of the zeolite plate has an emission wavelength of 2.7 to 3.2.
The near-infrared region of μm and the radiation wavelength of 5.0 to 7.
Electromagnetic radiation ceramic fine powder that can emit 4μm electromagnetic wave in the far infrared region with an emissivity of 0.8 or more with respect to the emissivity of black body is mixed and dispersed with water using cement, gypsum, diatomaceous earth or clay as binder In addition, a coating layer is formed by coating and drying so that the electromagnetic radiation ceramic fine powder is applied at a rate of 0.1% by weight or more based on the weight of the zeolite plate material.

【0010】[0010]

【作用】上述の如き技術的手段を用いてなる本発明は以
下のような作用を有する。即ち使用するゼオライト鉱石
として、その組成がクリノプチロライト若しくはモルデ
ナイトからなる結晶体と石英や長石或いは曹長石等の火
山ガラス質分とからなるため、多量の吸湿や吸水に際し
ても膨潤崩壊せぬ耐水性を保持し、且劈開性が極めて小
さなため採掘時に所望の立方形状で採掘しえる。そして
このゼオライト鉱石は比表面積が少なくとも15m
g以上の多孔性と、且その塩基置換容量(meq/10
0g)が150mg以上の高い塩基置換性を有し、而も
モース硬度が4.8乃至5.8のものが使用されるた
め、その直径が0.5乃至2.0mmのダイヤモンド粒
が植設されたダイヤモンド粒刃を用いたダイヤカッタ
ー、ダイヤ帯鋸、ダイヤワイヤソーによりゼオライト鉱
石を直接に且その厚さが3mm程度の薄肉で適宜面積の
ゼオライト板材を均質な切断面を以って損傷させずに能
率的に切断ができる。更にダイヤモンド粒の直径の異な
るものを使用することで切断面の粗面化や緻密化を自在
に変化させることができ、且モース硬度が4.8乃至
5.8であるから切断面の研磨も容易で、而も研磨によ
り平滑性が高まり且艶も付与されるとともに天然石特有
の淡い流紋模様も現出され、且この切断されたゼオライ
ト板材を400乃至900℃の適宜温度で仮焼させるこ
とにより素材の基色たる乳白淡緑色を淡褐色に色調変化
もできる。加えてゼオライト板材自体セメント石膏、珪
藻土、粘土等と高い添着性を保持するものであるから、
施工に際してこれらによる下地処理で極めて簡便に施工
がなしえる。
The present invention using the above technical means has the following functions. That is, since the composition of the zeolite ore used is composed of a crystalline body composed of clinoptilolite or mordenite and a volcanic glass component such as quartz, feldspar, or feldspar, water resistance that does not swell and collapse even when absorbing a large amount of moisture or water. Since it retains its properties and its cleavage is extremely small, it can be mined in a desired cubic shape at the time of mining. And this zeolite ore has a specific surface area of at least 15 m 2 /
g of porosity and its base substitution capacity (meq / 10
0g) has a high base substitution property of 150 mg or more and also has a Mohs hardness of 4.8 to 5.8, so diamond grains having a diameter of 0.5 to 2.0 mm are implanted. Zeolite ore directly with a diamond cutter, diamond band saw, and diamond wire saw using a diamond grain blade, and without damaging the zeolite plate material having a small thickness of about 3 mm and an appropriate area with a uniform cut surface. Cutting can be performed efficiently. Furthermore, by using diamond grains having different diameters, it is possible to freely change the roughening and densification of the cut surface, and since the Mohs' hardness is 4.8 to 5.8, polishing of the cut surface is also possible. It is easy to apply, smoothness is enhanced by polishing, gloss is imparted, and a light ripple pattern peculiar to natural stone appears, and the cut zeolite plate is calcined at an appropriate temperature of 400 to 900 ° C. As a result, the color tone of the base color of the material, such as milky white and light green, can be changed to light brown. In addition, since the zeolite plate itself retains high impregnation with cement gypsum, diatomaceous earth, clay, etc.,
At the time of construction, the construction can be extremely easily performed by the base treatment.

【0011】そして居住空間の天井や壁或いは床に施工
される本発明は薄肉の板状のものであるから、化学揮散
ガスが揮散、滞留し若しくは臭気ガスが拡散し或いは湿
気を含む空気との接触面積が大きく、而も更に比表面積
の大きな多孔性で且高い塩基置換性を保持するため、化
学揮散ガスや臭気ガスが積極的に吸着され、且塩基置換
性により分解もさなれるとともに、過剰な湿気は一時的
に吸着され、湿度低下とともに放湿もなされる。更に本
発明の少なくとも一側面に電磁波放射セラミックス微粉
体の塗着層が形成される場合には、外部温度エネルギー
の吸収に伴い水分子を有効に励起させる電磁波が再放射
され空気中の水分子が励起されて一重項酸素、スーパー
オキシド、ヒドロキシラジカル、過酸化水素等反応性が
高く酸化分解力を有する活性酸素が励起発生及び基底衰
退を繰返すため、化学揮散ガスや臭気ガスの分解消去は
もとより、浮遊する細菌や黴菌の細胞内水分が変性さ
れ、生理機能が阻害される。そしてかかる塗着層は、セ
メント、石膏、珪藻土或いは粘土をバインダーとして塗
着されるものであるから、ガス吸着や吸湿放湿等ゼオラ
イト板材の性能に何等の支障も与えない。
Since the present invention, which is constructed on a ceiling, a wall, or a floor of a living space, is a thin plate, the chemical volatile gas is volatilized and stays there, or the odorous gas is diffused or the air containing moisture is mixed. It has a large contact area, and has a large specific surface area and is highly porous and retains a high base substitution property, so that the chemical volatile gas and odorous gas are positively adsorbed, and the base substitution property also prevents decomposition and prevents excess decomposition. Moisture is temporarily absorbed and released as the humidity decreases. Further, in the case where the coating layer of the electromagnetic wave radiating ceramic fine powder is formed on at least one side of the present invention, the electromagnetic wave which effectively excites the water molecule with the absorption of the external temperature energy is re-emitted, and the water molecule in the air is removed. When excited, singlet oxygen, superoxide, hydroxy radical, hydrogen peroxide, and other reactive oxygen having high reactivity and oxidative decomposition power repeat excitation generation and base decay, so that not only decomposition and elimination of chemical volatile gas and odor gas, The intracellular moisture of floating bacteria and fungi is denatured, and physiological functions are inhibited. And since such a coating layer is coated using cement, gypsum, diatomaceous earth or clay as a binder, it does not affect the performance of the zeolite plate material such as gas adsorption and moisture absorption / desorption.

【0012】[0012]

【実施例】以下に本発明実施例を図に基づき詳細に説明
すれば、図1はゼオライト板材の形成方法説明図、図2
はダイヤモンド粒刃の拡大説明図、図3は本発明の斜視
図であって、本発明に使用されるゼオライト鉱石1は使
用特性上より、その組成がクリノプチロライト若しくは
モルデナイトからなるゼオライト結晶体と、石英や長石
或いは曹長石などからなる火山ガラス質分とで形成さ
れ、長期に亘って多量の吸湿や吸水に晒されても自己崩
壊や基本物性の変化のない耐水性を保持することは当然
であり、且使用に際しては幅及び長さの大きなものも要
求されるから、比較的大型塊状のゼオライト鉱石1より
切断形成する必要上劈開性が小さなものが望まれ、これ
がためには組成中に粘土や石灰或いは他の鉱石類が混在
せぬものが好適で、更に実用使用に際しては密閉性の高
い居住空間内の化学揮散ガスや臭気ガスを積極的に吸着
せしむるうえで、その比表面積が少なくとも15m
g以上の多孔性で而も吸着された化学揮散ガスや臭気ガ
スを分解固定或いは分解消臭させるうえから、その塩基
置換容量(meq/100g)が少なくとも150mg
以上のものが選択される。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a view for explaining a method of forming a zeolite plate according to an embodiment of the present invention; FIG.
FIG. 3 is an enlarged explanatory view of a diamond grain blade, and FIG. 3 is a perspective view of the present invention. The zeolite ore 1 used in the present invention has a zeolite crystal composed of clinoptilolite or mordenite because of its usage characteristics. And a volcanic vitreous component composed of quartz, feldspar, or feldspar, etc., to maintain water resistance without self-disintegration or change in basic physical properties even when exposed to a large amount of moisture or water over a long period of time. Naturally, a large width and a long length are required for use. Therefore, it is necessary to cut and form a zeolite ore 1 having a relatively large mass and to have a small cleaving property. It is preferable that clay, lime or other ores are not mixed in.Moreover, in the case of practical use, it is necessary to positively adsorb the chemical volatile gas and odor gas in the highly sealed living space. A specific surface area of at least 15m 2 /
g or more of the volatile gas and odorous gas adsorbed and adsorbed and decomposed and fixed, and the base substitution capacity (meq / 100 g) is at least 150 mg.
The above are selected.

【0013】更に本発明はゼオライト鉱石1を直接所要
の厚さと面積に切断するもので、実用使用上においては
その厚さはせいぜい3乃至30mm程度の比較的薄肉の
ものであるから、一方においてはかかる薄肉で所要の面
積に切断する場合に、切断時の損傷や破損が発生せぬ程
度の硬度が必要となり、且他方においては多量に使用さ
れる内装材としての安定供給を図る上から能率的に切断
形成させる必要上、そのモース硬度において4.8乃至
5.8程度ものが好適である。従って、かかる条件を具
備するゼオライト鉱石1の具体例を示せば、緑色凝灰岩
の鉱区より採掘され、その真比重が略1.9乃至2.4
程度で且その平均的化学成分組成として酸化珪素68.
7%、酸化アルミニウム11.9%、酸化カリウム3.
5%、酸化ナトリウム2.6%、酸化カルシウム0.6
%、酸化鉄0.55%、酸化マグネシウム0.25%、
酸化マンガン0.06%、五酸化リン0.03%及びそ
の他強熱減量分5.8%重量割合のものが挙げられる。
Further, in the present invention, the zeolite ore 1 is directly cut to a required thickness and area. In practical use, the thickness is relatively thin at most about 3 to 30 mm. When cutting to a required area with such a thin wall, it is necessary to have a hardness that does not cause damage or breakage at the time of cutting, and on the other hand, to efficiently supply a large amount of interior material, Since it is necessary to cut and form it, its Mohs hardness is preferably about 4.8 to 5.8. Therefore, as a specific example of the zeolite ore 1 satisfying such conditions, it is mined from a green tuff mining area, and its true specific gravity is approximately 1.9 to 2.4.
Silicon oxide as its average chemical composition.
7%, aluminum oxide 11.9%, potassium oxide 3.
5%, sodium oxide 2.6%, calcium oxide 0.6
%, Iron oxide 0.55%, magnesium oxide 0.25%,
Manganese oxide 0.06%, phosphorus pentoxide 0.03% and other ignition loss 5.8% by weight.

【0014】かくして選択されたゼオライト鉱石1の切
断に際しては実用使用における軽量で施工作業の簡便さ
等より、その厚さは略3乃至30mm程度のものが要請
されるものであって、且そのモース硬度が4.8乃至
5.8であるから能率的な切断をなすうえで最高硬度の
ダイヤモンド粒刃2Aを有するダイヤカッター20やダ
イヤ帯鋸若しくはダイヤワイヤソー(図示せず)等の切
断装置2が用いられる。かかる場合において、ダイヤモ
ンド粒刃2Aは通常真鍮の如き加工性に富む金属素材か
らなる基材2Bの外面に所要の粒径のダイヤモンド粒2
Cが所要の密度を以って露出した状態に植設させてなる
ものでダイヤカッター20においてはその回転盤20A
の先端部に該ダイヤモンド粒刃2Aを装着固定させた構
成のものである。そして切断に際して肝要なことは、切
断により形成されるゼオライト板材3の表面3A及び裏
面3Bが切断面に相当するものであって、該切断面をそ
のままの状態で利用し若しくは更に研磨を施し一段と平
滑性や艶を付与せしめて利用する場合の如く、該切断面
を成可く緻密且平滑状に切断仕上げをする場合や、或い
は薄肉な切断の場合等では切断摩擦抵抗が大きく付加さ
れると切断面が粗雑となるばかりか、ゼオライト板材3
の損傷や破損を招来する結果となり、反面切断面を比較
的粗面に仕上げる場合や施工時のセメントやモルタル等
の下地面との添着性を高めるための凹凸切断面等の形成
には、ある程度の大きな切断摩擦抵抗の付加が望まし
い。これがため、切断面に緻密さや平滑さを必要とする
場合ではダイヤモンド粒刃2Aに植設されるダイヤモン
ド粒2Cの直径は0.5乃至1.0mm程度が好都合で
あり、且切断面が粗面若しくは凹凸を必要とする場合で
は、ダイヤモンド粒2Cの直径を1.0乃至2.0mm
程度の大きなものの使用が望まれる。加えて切断時には
ダイヤモンド粒刃2Aが高速に回転若しくは移動し大き
な摩擦熱が発性するため、常時加水による冷却とともに
切断に伴い発性する粉屑の洗浄流出を図ることも留意す
べきである。
When cutting the zeolite ore 1 thus selected, it is required to have a thickness of about 3 to 30 mm for practical use because of its light weight and simplicity of construction work. Since the hardness is 4.8 to 5.8, a cutting device 2 such as a diamond cutter 20, a diamond band saw or a diamond wire saw (not shown) having a diamond grain blade 2A of the highest hardness is used for efficient cutting. Can be In such a case, the diamond grain blade 2A usually has a diamond grain 2 having a required grain size on the outer surface of a base material 2B made of a metal material having a good workability such as brass.
C is planted in an exposed state with a required density.
The diamond grain blade 2A is mounted and fixed to the tip of the blade. What is essential for cutting is that the front surface 3A and the back surface 3B of the zeolite plate material 3 formed by cutting correspond to the cut surface, and the cut surface is used as it is or further polished to make it even smoother. In the case where the cut surface is cut and finished in a dense and smooth shape, as in the case where the cut surface is used with imparting properties and gloss, or in the case of thin cutting, when cutting friction resistance is greatly added, cutting is performed. Not only is the surface rough, but zeolite plate 3
This may result in damage or breakage of the surface, and on the other hand, when forming a relatively rough cut surface or forming uneven cut surfaces etc. to improve the adherence to the underlying ground such as cement or mortar during construction, It is desirable to add a large cutting frictional resistance. Therefore, when the cut surface needs to be dense and smooth, the diameter of the diamond grain 2C implanted on the diamond grain blade 2A is preferably about 0.5 to 1.0 mm, and the cut face is rough. Alternatively, when irregularities are required, the diameter of the diamond grains 2C is set to 1.0 to 2.0 mm.
It is desirable to use a large one. In addition, at the time of cutting, since the diamond grain blade 2A rotates or moves at a high speed and generates a large amount of frictional heat, it should also be noted that cooling by water is always performed and washing and outflow of dust generated along with the cutting is performed.

【0015】かくして所要の厚さに切断されたゼオライ
ト板材3は、所要の幅や長さに仕上げるためにその外縁
部が切断除去され、且加水に伴い吸水した水分の除去の
ため通常加熱乾燥が施されるもので、かかる乾燥手段に
よって残留水分を3%以下望ましくは1%以下となるよ
う、乾燥させることで本発明品4が形成される。かかる
場合に乾燥手段には特別な制約はないが、あまり高温度
での乾燥を施すと仮焼作用に伴う色調変化を生ずること
から、せいぜい180乃至200℃以下の乾燥温度に制
限すべきである。図4には表面3Aとなる切断面を緻密
且平滑に切断し、裏面3Bとなる切断面を粗面に切断形
成させた場合の本発明品4の断面説明図が示されてい
る。本発明品4は建築用内装板材として使用されるもの
であり、且内装材には多様な色彩やデザイン等も求めら
れる。これがため本発明品4においては図5に示す如
く、ゼオライト板材3の表面3Aを適宜の金属素材から
なるバフ材或いは研磨材で研磨を加えて平滑性とともに
艶を付与させるとともに、この表面3Aの平滑性と艶の
付与に伴ってゼオライト鉱石1特有の乳白淡緑の流紋模
様を現出させることが可能となり、更にはゼオライト板
材3を400乃至900℃の温度範囲における適宜温度
で仮焼させ組成成分中の強熱減量の焼去と酸化カリウム
や酸化ナトリウム或いは五酸化リン等の加熱変性に伴う
ゼオライト鉱石1の基色である乳白淡緑色を乳白淡褐色
に色調変化させることも提案されるもので、かかる場合
に仮焼温度が略450℃を超えると塩基置換性が次第に
損われることから、可成くは低温度域での仮焼が望まし
く、且900℃を超えると火山ガラス質分の熔融等基本
的物性に支障が及ぶので留意すべきである。
The zeolite plate material 3 thus cut to a required thickness has its outer edge cut and removed in order to finish it to a required width and length, and is usually heated and dried to remove water absorbed by the addition of water. The product 4 of the present invention is formed by drying such that the residual moisture is 3% or less, preferably 1% or less by such a drying means. In such a case, there is no particular limitation on the drying means, but if the drying is performed at an excessively high temperature, the color tone changes due to the calcining action. Therefore, the drying temperature should be limited to 180 to 200 ° C. or less. . FIG. 4 is an explanatory cross-sectional view of the product 4 of the present invention when the cut surface serving as the front surface 3A is cut densely and smoothly, and the cut surface serving as the back surface 3B is cut into a rough surface. The product 4 of the present invention is used as an interior plate for a building, and the interior material is required to have various colors and designs. For this reason, in the product 4 of the present invention, as shown in FIG. 5, the surface 3A of the zeolite plate 3 is polished with a buff material or an abrasive material made of an appropriate metal material to impart smoothness and gloss to the surface 3A. With the impartation of smoothness and luster, it is possible to produce a milky, pale green, flowing pattern peculiar to the zeolite ore 1. Further, the zeolite plate 3 is calcined at an appropriate temperature in a temperature range of 400 to 900 ° C. It is also proposed to change the color of milky pale green which is the basic color of zeolite ore 1 to milky pale brown due to the burning off of the ignition loss in the composition and the heat denaturation of potassium oxide, sodium oxide or phosphorus pentoxide. In such a case, if the calcination temperature exceeds about 450 ° C., the base substitution property is gradually impaired. Therefore, calcination in a low temperature range is desirable, and if it exceeds 900 ° C. Since the problem extends to melt such as a basic physical properties of the mountain glassy worth it should be noted.

【0016】図6は電磁波放射セラミックス微粉体の塗
着層が形成された本発明の説明図であって、本発明は密
閉性の高い居住空間の天井、壁若しくは床に張設し、化
学揮散ガスや臭気ガスを吸着し且分解固定や分解消去さ
せ、或いは過剰な湿気を吸湿させて細菌や黴菌の繁殖抑
制を図るために、その比表面積が少なくとも15m
g以上の多孔性で且塩基置換容量(meq/100g)
が150mg以上のゼオライト鉱石1を切断してゼオラ
イト板材3となしたるうえ使用するものであるが、本発
明の表面と接触する空気中に拡散されている化学揮散ガ
スや臭気ガスの吸着と分解固定や分解消去はなされるも
のの、密閉性の高い居住空間内は空気の流通も不十分で
あり、従って居住空間内に揮散する化学揮散ガスや拡散
する臭気ガス全体を短時に且効果的に分解固定させ若し
くは分解消去させるには未だ十分な手段とはなりえな
い。そこで本発明の少なくとも一側面に、外部温度エネ
ルギーを吸収のうえ水分子の共振波長とされるその波長
が2.7乃至3.2μmの近赤外線領域及びその波長が
5.0乃至7.4μmの遠赤外線領域の電磁波で且その
放射率が黒体の放射率に対し少なくとも0.8以上の放
射率を以って放射しえる電磁波放射セラミックス微粉体
40をゼオライト板材3の重量に対して実質的に0.1
%重量以上の割合で、且ゼオライト板材3との添着性を
有し、而も通気性や透湿性も有するセメント、石膏、珪
藻土若しくは粘土をバインダー40Aとして所要の厚さ
で塗着乾燥させた塗着層4Aを形成させる手段が提案さ
れる。
FIG. 6 is an explanatory view of the present invention in which a coating layer of a ceramic powder radiating electromagnetic waves is formed. The present invention is applied to a ceiling, a wall, or a floor of a highly sealed living space, and is chemically vaporized. In order to adsorb gas and odor gas and decompose and fix or decompose or remove excessive moisture, the specific surface area is at least 15 m 2 /
g or more and base substitution capacity (meq / 100g)
Is used to cut the zeolite ore 1 having a weight of 150 mg or more into a zeolite plate material 3 and adsorb and decompose the chemically volatilized gas and odor gas diffused in the air in contact with the surface of the present invention. Although it is fixed and disassembled and erased, the air inside the living space with high airtightness is insufficient, so the chemical volatile gas and the odorous gas that are volatilized in the living space are completely and quickly disassembled and fixed. It is not yet a sufficient means for dismantling or decomposing. Therefore, according to at least one aspect of the present invention, a near-infrared region having a wavelength of 2.7 to 3.2 μm, which absorbs external temperature energy and serves as a resonance wavelength of water molecules, and a wavelength of 5.0 to 7.4 μm, which is a wavelength of 5.0 to 7.4 μm. An electromagnetic wave radiating ceramic fine powder 40 capable of radiating an electromagnetic wave in the far-infrared region and having an emissivity of at least 0.8 or more with respect to the emissivity of a black body is substantially used for the weight of the zeolite plate 3. 0.1
% By weight of cement, gypsum, diatomaceous earth or clay, which has an adhesive property to the zeolite plate material 3 and also has air permeability and moisture permeability, as a binder 40A, and is dried at a required thickness. Means for forming the deposition layer 4A is proposed.

【0017】即ち水分子はその波長が2.7乃至3.2
μmの近赤外線領域と5.0乃至7.4μmの遠赤外線
領域に赤外線吸収所謂共振波長帯を有するものであるか
ら、該共振波長帯に適合する波長の電磁波放射をなすこ
とにより僅かな放射エネルギーによって化学揮散ガスが
揮散滞留し若しくは臭気ガスが拡散混在し或いは菌類が
浮遊する居住空間全体の空気中の水分子を有効に励起さ
せ、この励起により水分子が一重項酸素やスーパーオキ
シド、ヒドロキシラジカル或いは過酸化水素等の反応性
が高く酸化分解力を持つ活性酸素が創出され、且極めて
瞬時に該活性酸素が化学揮散ガスや臭気ガスと結合し分
解消去せしめ、更には菌類の細胞水を変性させてその生
理機能の阻害による繁殖防止が図られることとなる。か
かる場合において、使用しえる電磁波放射セラミックス
微粉体40はいくつかのものが提案されるが、具体例を
示せば酸化珪素50%、酸化アルミニウム26%に遷移
元素酸化物として酸化チタン11%、酸化マンガン8
%、酸化亜鉛5%の重量割合で配合のうえ略920乃至
960℃の温度で焼結させ、而してその電磁波放射表面
積率を大きく形成させるため微粉状所謂その粒径を略1
乃至10μm程度に粉砕させたものが挙げられる。そし
てゼオライト板材3の少なくとも一側面に形成される塗
着層4Aの形成方法としては噴霧による方法、塗着によ
る方法、ロールコーティング等多様な手段でなしえる
が、肝要なことは形成される塗着層4Aによりゼオライ
ト板材3の保持する多孔性や塩基置換性及び吸湿放湿性
を阻害させぬことであり、且長期に亘って強固に添着保
持されることである。これがためにはゼオライト板材3
と強固な添着性を有し且透気透水性を有するセメント、
石膏、珪藻土若しくは粘土をバインダー40Aとし、こ
れに電磁波放射セラミックス微粉体40と水とを適宜割
合に配合分散させて塗着手段に適した粘度の塗着液とし
て塗着させ乾燥させれば良い。この場合に留意すべきは
化学揮散ガスや臭気ガス等を分解消去せしめ、或いは菌
類の繁殖防止を図るうえからは、ゼオライト板材3の重
量に対して電磁波放射セラミックス微粉体40の塗着量
が実質的に0.1%重量割合以上で塗着させることにあ
る。
That is, water molecules have wavelengths of 2.7 to 3.2.
Since it has an infrared absorption so-called resonance wavelength band in a near-infrared region of μm and a far-infrared region of 5.0 to 7.4 μm, a small amount of radiant energy can be obtained by emitting electromagnetic waves having a wavelength suitable for the resonance wavelength band. This effectively excites water molecules in the air in the entire living space in which the chemical volatilized gas volatilizes and stays or the odor gas diffuses and mixes or the fungi float, and the water molecules are excited by singlet oxygen, superoxide, and hydroxyl radicals. Alternatively, active oxygen having a high reactivity such as hydrogen peroxide and oxidative decomposition power is created, and the active oxygen is combined with a chemical volatile gas or an odor gas instantaneously to decompose and eliminate, and further denatures fungal cell water. As a result, propagation is prevented by inhibiting the physiological function. In such a case, several types of electromagnetic radiation ceramic fine powders 40 that can be used are proposed, but specific examples include silicon oxide 50%, aluminum oxide 26%, titanium oxide 11% as a transition element oxide, oxide Manganese 8
% And zinc oxide at a weight ratio of 5%, and then sintered at a temperature of about 920 to 960 ° C., so as to increase the surface area ratio of electromagnetic wave radiation.
To about 10 μm. The coating layer 4A formed on at least one side surface of the zeolite plate 3 can be formed by various methods such as a spraying method, a coating method, and a roll coating method. The layer 4A does not impair the porosity, the base substitution property, and the moisture absorption / desorption property of the zeolite plate material 3, and is to be firmly attached and held for a long period of time. This is because zeolite plate 3
A cement having a strong adhering property and air permeability
Gypsum, diatomaceous earth, or clay may be used as the binder 40A, and the electromagnetic radiation ceramic fine powder 40 and water may be mixed and dispersed in an appropriate ratio, applied as a coating liquid having a viscosity suitable for the coating means, and dried. In this case, it should be noted that, in order to decompose and remove chemical volatile gas and odorous gas, or to prevent the propagation of fungi, the coating amount of the electromagnetic radiation ceramic fine powder 40 with respect to the weight of the zeolite plate 3 is substantially reduced. The purpose is to apply the coating at a weight ratio of 0.1% or more.

【0018】[0018]

【発明の効果】本発明は以上に述べたように、その組成
がクリノプチロライト若しくはモルデナイトからなるゼ
オライト結晶体と、石英や長石、曹長石等の火山ガラス
質分とからなり吸湿や吸水によっても崩壊せぬ耐水性
と、劈開性が極めて小さく而もその比表面積が少なくと
も15m/g以上で、且塩基置換容量(meq/10
0g)が150mg以上、及びモース硬度が4.8乃至
5.8のゼオライト鉱石を用いるため、所望の大きさの
ゼオライト鉱石塊として採掘しえるとともに、その直径
が0.5乃至2.0mmのダイヤモンド粒が植設された
ダイヤモンド粒刃を使用することで直接その厚さが3m
m以上のゼオライト板材として能率良く切断形成しえる
ため多量の生産と安価な提供が可能となるばかりか、板
状であるため居住空間の天井、壁、床等に適宜張設する
ことにより化学揮散ガスが揮散滞留し或いは臭気ガスが
拡散混在する居住空間内の空気との接触面積が大きく形
成され、従って比表面積の極めて大きな多孔性により、
これらが物理的に吸着され、且その高い塩基置換性によ
り化学的に分解固定若しくは分解消去がなされ、更に該
ゼオライト板材はゼオライト結晶体と多孔性とにより略
10乃至15%程度の吸湿及び放湿作用を有するため、
多湿化が回避され細菌や黴菌の繁殖が抑制され、而も体
感的に快適な居住空間が保持される。加えて本発明は1
000℃以上の耐火性とともに不燃であり、且多孔性に
より優れた断熱性と特に遮音性が高く、而もセメントや
モルタル等との添着性に優れるため、これらの下地処理
により簡便に施工がなしえるばかりか、切断時における
ダイヤモンド粒刃の使い分けによりその切断面所謂表面
若しくは裏面の粗密化や凹凸化、或いは研磨により平滑
性や艶の創出が容易になしえ、且ゼオライト鉱石特有の
乳白淡緑の流紋模様も現出しえ、しかも仮焼により色調
変化もなしえるため多様な色彩やデザインの内装材とし
て利用できる。更に本発明の少なくとも一側面に電磁波
放射セラミックス微粉体を用いた塗着層が形成された場
合には、その放射電磁波により居住空間内全体の水分子
が励起されて反応性が高く酸化分解力を有する活性酸素
が創出され、化学揮散ガスや臭気ガスの分解消去がなさ
れ、且浮遊する細菌、黴菌の生理機能も阻害されて繁殖
が防止され、而もかかる効果は温度エネルギーの存在に
より恒久的に発揮されることから、長期に亘って安全に
快適且衛生的な居住空間が保持できる等、極めて特長の
多い建築用内装板材といえる。
As described above, the present invention provides a zeolite crystal having a composition of clinoptilolite or mordenite and a volcanic glassy component such as quartz, feldspar, or feldspar, and the like. Water resistance that does not collapse, has extremely low cleavage properties, has a specific surface area of at least 15 m 2 / g, and has a base substitution capacity (meq / 10
0g) is 150 mg or more, and zeolite ore having a Mohs hardness of 4.8 to 5.8 is used, so that it can be mined as a zeolite ore block having a desired size and a diamond having a diameter of 0.5 to 2.0 mm. The thickness is 3m directly by using diamond grain blade with grain
m can be efficiently cut and formed as a zeolite plate material of m or more, which not only enables mass production and inexpensive provision, but also has a plate-like shape, which is chemically volatilized by being appropriately stretched on ceilings, walls, floors, etc. of living spaces. A large contact area with the air in the living space where the gas volatilizes and stays or the odor gas diffuses and mixes is formed, and therefore, due to the extremely large porosity of the specific surface area,
These are physically adsorbed and chemically decomposed and fixed or decomposed and erased due to their high base substitution. Further, the zeolite plate material absorbs and desorbs moisture by about 10 to 15% due to its zeolite crystal and porosity. To have an effect
The humidification is avoided, the growth of bacteria and fungi is suppressed, and a comfortable living space is maintained. In addition, the present invention
It is non-flammable with fire resistance of 000 ° C or higher, and has excellent heat insulation and excellent sound insulation due to its porosity. In addition, it is possible to easily create smoothness and gloss by polishing the surface or the back surface of the cut surface by making use of the diamond grain blade at the time of cutting. Can also be used as a decorative material, and the color tone can be changed by calcination, so it can be used as interior materials of various colors and designs. Further, in the case where a coating layer using a ceramic powder radiating electromagnetic waves is formed on at least one side of the present invention, water molecules in the entire living space are excited by the radiating electromagnetic waves, and the reactivity is high and the oxidative decomposition power is increased. Active oxygen is created, the chemical volatile gas and odorous gas are decomposed and eliminated, and the physiology of suspended bacteria and fungi is inhibited, and propagation is prevented. Such effects are permanently caused by the presence of temperature energy. Since it is exhibited, it can be said that it is an architectural interior plate material having extremely many features, such as a safe and comfortable living space that can be maintained safely over a long period of time.

【図面の簡単な説明】[Brief description of the drawings]

【図1】ゼオライト板材の形成方法説明図である。FIG. 1 is an explanatory diagram of a method for forming a zeolite plate material.

【図2】ダイヤモンド粒刃の拡大説明図である。FIG. 2 is an enlarged explanatory view of a diamond grain blade.

【図3】本発明の斜視図である。FIG. 3 is a perspective view of the present invention.

【図4】表裏面の粗密状態が異なる本発明の断面説明図
である。
FIG. 4 is an explanatory cross-sectional view of the present invention in which the density of the front and back surfaces is different.

【図5】表面が研磨された本発明の断面説明図である。FIG. 5 is an explanatory sectional view of the present invention whose surface is polished.

【図6】塗着層が形成された本発明の説明図である。FIG. 6 is an explanatory view of the present invention in which a coating layer is formed.

【符号の説明】[Explanation of symbols]

1 ゼオライト鉱石 2 切断装置 2A ダイヤモンド粒刃 2B 基材 2C ダイヤモンド粒 20 ダイヤカッター 20A 回転盤 3 ゼオライト板材 3A ゼオライト板材表面 3B ゼオライト板材裏面 4 本発明 4A 塗着層 40 電磁波放射セラミックス微粉体 40A バインダー DESCRIPTION OF SYMBOLS 1 Zeolite ore 2 Cutting device 2A Diamond grain blade 2B Base material 2C Diamond grain 20 Diamond cutter 20A Turntable 3 Zeolite plate material 3A Zeolite plate material surface 3B Zeolite plate material back surface 4 The present invention 4A Coating layer 40 Electromagnetic radiation ceramic fine powder 40A Binder

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 その組成がクリノプチロライトもしくは
モルデナイトからなるゼオライト結晶体と石英、長石、
曹長石等の火山ガラス質成分とからなり、耐水性と且そ
の比表面積が少なくとも15m/g以上、及び塩基置
換容量(meq/100g)が150mg以上で而もモ
ース高度が4.8乃至5.8のゼオライト鉱石を、その
直径が0.5乃至2.0mmのダイヤモンド粒が植設さ
れたダイヤモンド粒刃を有するダイヤカッター、ダイヤ
帯鋸若しくはダイヤワイヤソーを以って、注水冷却並び
に切断粉屑を洗出させながら少なくともその厚さが3m
m以上の適宜面積に切断してゼオライト板材となしたる
うえ残留水分率を3%以下に乾燥させてなることを特徴
とする建築用内装板材。
1. A zeolite crystal having a composition of clinoptilolite or mordenite and quartz, feldspar,
It is composed of a volcanic glassy component such as albite and has a water resistance and a specific surface area of at least 15 m 2 / g, a base substitution capacity (meq / 100 g) of 150 mg or more, and a Mohs altitude of 4.8 to 5 0.8 of the zeolite ore was cooled with a diamond cutter, diamond band saw or diamond wire saw having a diamond grain blade having diamond grains having a diameter of 0.5 to 2.0 mm implanted therein, and cooling and cutting dust were cut off. At least 3m thick while washing out
m. An interior board for building, which is cut into an appropriate area of at least m to form a zeolite board and dried to a residual moisture content of 3% or less.
【請求項2】 所要の厚さ及び面積で切断されたゼオラ
イト板材の一側面が直径の小さなダイヤモンド粒が植設
されたダイヤモンド粒刃を有するダイヤカッター、ダイ
ヤ帯鋸若しくはダイヤワイヤソーで切断され、且他側面
が直径の大きなダイヤモンド粒が植設されたダイヤモン
ド粒刃を有するダイヤカッター、ダイヤ帯鋸若しくはダ
イヤワイヤソーで切断されてなる請求項1記載の建築用
内装板材。
2. One side of a zeolite plate cut to a required thickness and area is cut by a diamond cutter, a diamond band saw or a diamond wire saw having a diamond grain blade on which diamond grains having a small diameter are implanted, and the like. 2. The interior panel material for building according to claim 1, wherein the side surface is cut by a diamond cutter, a diamond band saw or a diamond wire saw having a diamond grain blade on which diamond grains having a large diameter are implanted.
【請求項3】 所要の厚さと面積に切断されたゼオライ
ト板材の一側面が研磨され、平滑性と艶が付与せしめら
れてなる請求項1若しくは請求項2記載の建築用内装板
材。
3. The architectural interior plate material according to claim 1, wherein one side surface of the zeolite plate material cut to a required thickness and area is polished to impart smoothness and luster.
【請求項4】 所要の厚さ及び面積に切断されたゼオラ
イト板材を、その温度が400乃至900℃の適宜温度
で仮焼させて、乳白淡褐色の色調に変化させてなる請求
項1乃至請求項3記載の建築用内装板材。
4. A zeolite plate material cut to a required thickness and area is calcined at an appropriate temperature of 400 to 900 ° C. to change the color to a milky light brown color. Item 4. An interior board for building according to item 3.
【請求項5】 所要の厚さ及び面積に切断されたゼオラ
イト板材の少なくとも一側面に、その放射波長が2.7
乃至3.2μmの近赤外線及び5.0乃至7.4μmの
遠赤外線領域の電磁波を黒体の放射率に対し0.8以上
の放射率を以って放射しえる電磁波放射セラミックス微
粉体がセメント、石膏、珪藻土若しくは粘土をバインダ
ーとして水と共に混合分散させたうえ、適宜の厚さで且
ゼオライト板材の重量に対し該電磁波放射セラミックス
微粉体が実質的に0.1%重量以上の割合で添着される
よう塗着乾燥させた塗着層が形成されてなる請求項1乃
至請求項4記載の建築用内装板材。
5. A radiation material having a radiation wavelength of 2.7 on at least one side of a zeolite plate cut to a required thickness and area.
The ceramic fine powder which can radiate electromagnetic waves in the near-infrared region of 3 to 3.2 μm and in the far-infrared region of 5.0 to 7.4 μm with an emissivity of 0.8 or more with respect to the emissivity of the black body is cement. , Gypsum, diatomaceous earth or clay as a binder is mixed and dispersed with water, and the electromagnetic radiation ceramic fine powder having an appropriate thickness is attached to the zeolite plate material at a rate of substantially 0.1% by weight or more. The architectural interior board according to any one of claims 1 to 4, further comprising a coating layer which is coated and dried.
JP11271005A 1999-08-19 1999-08-19 Interior finish plate for building Pending JP2001058318A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11271005A JP2001058318A (en) 1999-08-19 1999-08-19 Interior finish plate for building

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11271005A JP2001058318A (en) 1999-08-19 1999-08-19 Interior finish plate for building

Publications (1)

Publication Number Publication Date
JP2001058318A true JP2001058318A (en) 2001-03-06

Family

ID=17494096

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11271005A Pending JP2001058318A (en) 1999-08-19 1999-08-19 Interior finish plate for building

Country Status (1)

Country Link
JP (1) JP2001058318A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005026465A3 (en) * 2003-09-12 2005-06-16 Knauf Gips Kg Construction material based on gypsum
JP2015199156A (en) * 2014-04-07 2015-11-12 渡邉 哲夫 Soft stone polishing method, soft stone-containing hard material polishing method, and molded article made of hard material manufactured by the methods
JP2016154860A (en) * 2015-02-25 2016-09-01 株式会社ケープラン Mold-resistant deodorant

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005026465A3 (en) * 2003-09-12 2005-06-16 Knauf Gips Kg Construction material based on gypsum
US7645527B2 (en) 2003-09-12 2010-01-12 Knauf Gips Kg Gypsum-based building material
JP2015199156A (en) * 2014-04-07 2015-11-12 渡邉 哲夫 Soft stone polishing method, soft stone-containing hard material polishing method, and molded article made of hard material manufactured by the methods
JP2016154860A (en) * 2015-02-25 2016-09-01 株式会社ケープラン Mold-resistant deodorant

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