JP2001039755A - Cement mortar composition for unevenness adjustment and method for executing application work of the same - Google Patents

Cement mortar composition for unevenness adjustment and method for executing application work of the same

Info

Publication number
JP2001039755A
JP2001039755A JP11212478A JP21247899A JP2001039755A JP 2001039755 A JP2001039755 A JP 2001039755A JP 11212478 A JP11212478 A JP 11212478A JP 21247899 A JP21247899 A JP 21247899A JP 2001039755 A JP2001039755 A JP 2001039755A
Authority
JP
Japan
Prior art keywords
cement
cement mortar
weight
composition
boards
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11212478A
Other languages
Japanese (ja)
Inventor
Masatoshi Nagahama
雅敏 長浜
Masaki Kobori
雅紀 小堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP11212478A priority Critical patent/JP2001039755A/en
Publication of JP2001039755A publication Critical patent/JP2001039755A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

Abstract

PROBLEM TO BE SOLVED: To obtain a cement mortar composition for unevenness adjustment, which is capable of attaining fireproof performance and sufficiently adjusting unevenness through thick application of the composition to cement boards, after joint filling treatment of the boards by using as components of the cement mortar composition, cement, an inorganic expanded aggregate having a specific particle size distribution, fiber and a polymer in specified compositional ratios, respectively. SOLUTION: This cement mortar composition is produced by blending 100 pts.wt. of cement, 10-60 pts.wt. of an inorganic expanded aggregate, 0.1-20 pts.wt. of fiber and 1-10 pts.wt. of a polymer together to obtain a blend, and if necessary, further adding heavy-weight aggregate, a dispersing agent, a thickener, a regulated setting agent, a shrinkage reducing agent, and the like, to the blend. The composition is used in an execution method that comprises sticking cement boards to a wooden or steel structure; after joint filling treatment of the boards, subjecting the treated boards to unevenness adjustment by applying cement mortar to the boards, and then performing finishing work of the boards with a finishing material. As the inorganic expanded aggregate, such aggregate which has <=5 mm particle size and contains 0.1-2 wt.% of a fraction remaining on a sieve having 2.36 mm opening size, 15-25 wt.% of a fraction remaining on a sieve having 1.18 mm opening size and <=50 wt.% of a fraction remaining on a sieve having 0.60 mm opening size, is preferred. The cement mortar composition is mixed with 25-55 pts.wt. of water on the basis of 100 pts.wt. of the composition and the resulting cement mortar can be applied to the boards so as to form a cement mortar coating layer having a >=4 mm thickness and hardened, by a single run of execution of the application work.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、木造や鉄骨造等に
セメントボードを張り付けたものを下地とする建築物の
壁構築用として好適な不陸調整用セメントモルタル組成
物及び該組成物の施工方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cement mortar composition for adjusting irregularities which is suitable for constructing a wall of a building having a cement board attached to a wooden structure or a steel frame structure or the like, and the construction of the composition. About the method.

【0002】[0002]

【従来の技術】先に、本発明者らは特願平11-100612号
において、一般住宅用の外装を含め建築物の壁構築用材
として、木造や不燃下地にサイディング材を張り付けた
ものを下地とし、そのサイディング材に下地調整材を塗
布するにあたり、目地補強用として使用する繊維ネット
の埋め込み、ひび割れ、目地部の不陸の調整などの課題
を解決することを目的とし、従来のセメントボードやA
LCなどのサイディング材用のセメントモルタルの持つ
性能および施工性を備えていることはもとより、従来の
セメントモルタルより高温時にドライアウトを起こすこ
とがない下地調整用セメントモルタル組成物及び該組成
物の施工方法を提案した。
2. Description of the Related Art The inventors of the present invention disclosed in Japanese Patent Application No. Hei 11-100612 a wooden siding or non-combustible siding material as a material for building walls including exteriors for general houses. In applying the base adjustment material to the siding material, the purpose was to solve problems such as embedding of fiber nets used for joint reinforcement, cracking, adjustment of unevenness of joints, etc. A
In addition to having the performance and workability of cement mortar for siding materials such as LC, the cement mortar composition for adjusting the groundwork that does not cause dryout at higher temperatures than conventional cement mortar, and the application of the composition A method was proposed.

【0003】しかし、特願平11-100612号の下地調整用
セメントモルタル組成物は、目地部の不陸調整は可能で
あるが、セメントボードが反り返っている場合や、セメ
ントボードの継ぎ目部分等に段差を生じている場合につ
いては不陸調整しにくいなどの問題点を有していた。ま
た施工においては、左官士の感覚で施工を行う場合が多
いため、施工時の塗布厚が規定の厚み以下となってしま
う場合もあり、施工時の塗布厚を管理することが難しい
という問題点があった。さらに、構造物に防火性能を付
与しようとすると、数回塗り重ねなければならず、工程
が煩雑になるという問題点があった。
[0003] However, the cement mortar composition for adjusting the foundation described in Japanese Patent Application No. 11-100612 can adjust the unevenness of joints, but can be used when the cement board is warped or at the seam of the cement board. When there is a step, there is a problem that it is difficult to adjust unevenness. In addition, in the case of construction, since the construction is often performed with the feeling of a plasterer, the application thickness at the time of construction may be less than the specified thickness, and it is difficult to control the application thickness at the time of construction. was there. Further, in order to impart fire-protection performance to a structure, it is necessary to apply the coating several times, resulting in a problem that the process becomes complicated.

【0004】また一般住宅用の外装を含め建築物の壁構
築用材として、サイティング材にセメント、骨材、ポリ
マーを混合したモルタルを塗布、硬化させることが知ら
れている(特公昭58−385882号)。さらに、一
般的に建築用として使用されるセメントモルタルとして
は、セメントに微細骨材、細骨材、繊維、ポリマー等を
配合してなるモルタル組成物を水等で混練りする下地調
整材やセメント、パーライト・珪砂などの無機質混和
材、有機質骨材・有機質繊維などの有機質混和材を配合
してなるモルタル組成物を水等で混練りする軽量セメン
トモルタルなどを、塗布し、硬化させるものも知られて
いる(1995建築仕上材ガイドブック 日本建築仕上
材工業会編集 平成7年4月20日発行)。
It is also known that a mortar obtained by mixing a cement, an aggregate and a polymer is applied to a siding material and cured as a material for building walls of a building including an exterior for a general house (Japanese Patent Publication No. 58-385882). issue). In addition, cement mortars generally used for construction include a mortar composition obtained by mixing fine aggregates, fine aggregates, fibers, polymers and the like with cement, and a base adjustment material or cement which is kneaded with water or the like. It is also known to apply and harden a lightweight cement mortar that kneads a mortar composition containing inorganic admixtures such as perlite and silica sand and organic admixtures such as organic aggregates and organic fibers with water. (1995 Architectural Finishing Material Guidebook, edited by the Japan Architectural Finishing Material Manufacturers Association, published on April 20, 1995).

【0005】しかしながら、前者はモルタルを厚く塗布
するために下塗り、上塗りと2度も塗布しなければなら
ないため、工程が多く効率が悪い。また後者の下地調整
材では、セメントボードに塗布してもひび割れが起き易
いことや目地部の不陸、さらにはボードの反り等による
不陸は調整し難いこと、更には防火性能を付与するため
に。また軽量セメントモルタルは、厚く塗布しなければ
ならないために数度に分け塗布する必要があるため効率
が悪いという問題があった。
However, in the former method, the mortar must be applied twice, that is, undercoating and overcoating in order to apply the mortar thickly. In addition, in the latter base adjustment material, even if it is applied to a cement board, it is easy to crack and unevenness of joints, and it is difficult to adjust unevenness due to warpage of the board, and furthermore, to impart fire protection performance To. In addition, the lightweight cement mortar has a problem that the efficiency is poor because it must be applied thickly and must be applied several times.

【0006】[0006]

【発明が解決しようとする課題】本発明は、一般住宅用
の外装を含め建築物の壁構築用材として、木造や鉄骨造
等にセメントボードを張り付けたものを下地とし、特願
平11-100612号に記載の目地処理を行ったセメントボー
ドに、セメントモルタルを塗布するにあたり、1回塗り
で4mm以上厚付け塗布ができ、セメントボードの継ぎ目
等に生じる段差の不陸調整をすることが可能で、特別な
工程を設けることなく施工時の塗布厚を4mm以上に管理
することができ、1回の塗布作業で構造物に防火性能を
付与することができる不陸調整用セメントモルタル組成
物を提供することにある。
SUMMARY OF THE INVENTION The present invention relates to a material for building walls, including exteriors for general houses, which is constructed by attaching a cement board to a wooden or steel structure or the like. When applying cement mortar to cement boards that have been subjected to the joint treatment described in No. 4, a single application can apply a thickness of 4 mm or more, making it possible to adjust the unevenness of the steps that occur at the joints of the cement boards, etc. Provide a cement mortar composition for uneven land adjustment that can control the coating thickness at the time of construction to 4 mm or more without providing a special process, and can provide fire protection performance to the structure with one coating operation Is to do.

【0007】[0007]

【課題を解決するための手段】本発明者らは、鋭意研究
を行った結果、セメントに粒径を規定した無機系発泡骨
材、繊維及びポリマーを特定量加えて混練し、得られた
不陸調整用セメントモルタル組成物を塗布し、硬化させ
ることにより、1回塗りで4mm以上厚付け塗布ができ、
セメントボードの継ぎ目等に発生する段差の不陸調整を
することが可能で、特別な工程を設けることなく施工時
の塗布厚を4mm以上に管理することができ、1回の塗布
作業で構造物に防火性能を付与することが可能な硬化体
が形成されることを見出し、本発明を完成した。
Means for Solving the Problems As a result of intensive studies, the present inventors have added a specific amount of inorganic foamed aggregate, fiber and polymer having a specified particle size to cement and kneaded the resulting mixture. By applying and curing the cement mortar composition for land adjustment, it can be applied with a thickness of 4 mm or more in one application,
It is possible to adjust the unevenness of the steps that occur at the joints of cement boards, etc., and it is possible to control the coating thickness at the time of construction to 4 mm or more without providing a special process, and to apply the structure to one application work The present inventors have found that a cured product capable of imparting fire-prevention performance is formed, and completed the present invention.

【0008】すなわち、本発明の第1の発明は「木造や
鉄骨造等にセメントボードを張り付けた後、目地処理を
行い、セメントモルタルで不陸調整し、仕上げ材にて仕
上げを行う施工方法に用いる不陸調整用セメントモルタ
ルであって、セメント100重量部、無機系発泡骨材1
0〜60重量部、繊維0.1〜20重量部およびポリマ
ー1〜10重量部の範囲に調節してなる下地調整用セメ
ントモルタル組成物。」を要旨とする。
[0008] That is, the first invention of the present invention relates to a construction method in which a cement board is attached to a wooden structure or a steel frame structure, joint processing is performed, unevenness is adjusted with a cement mortar, and finishing is performed with a finishing material. A cement mortar for adjusting irregularities to be used, which comprises 100 parts by weight of cement and inorganic foam aggregate 1
A cement mortar composition for adjusting a foundation, which is adjusted to a range of 0 to 60 parts by weight, 0.1 to 20 parts by weight of a fiber and 1 to 10 parts by weight of a polymer. ”.

【0009】本発明の第2の発明は「上記不陸調整用セ
メントモルタル組成物100重量部に対し、25〜55
重量部の水と混練して得られた混練物を目地処理を施し
たセメントボードに4mm以上塗布して硬化させることを
特徴とする不陸調整用セメントモルタル組成物の施工方
法。」を要旨とする。
The second invention of the present invention relates to "25 to 55 parts by weight based on 100 parts by weight of the cement mortar composition for adjusting unevenness.
A method for applying a cement mortar composition for adjusting unevenness, characterized in that a kneaded material obtained by kneading with parts by weight of water is applied to a cement board which has been subjected to joint treatment and is hardened by coating at least 4 mm. ”.

【0010】[0010]

【発明の実施の形態】本発明でいうセメントボードと
は、木片セメント板、珪酸カルシウム板(通称:ケイカ
ル板)や水硬性を有するセメントに骨材、必要に応じて
各種添加剤を添加したものを水と混練し、硬化させ、必
要に応じて繊維メッシュを埋め込み補強し板状に成形さ
せたもの、例えば三菱レイヨン社製「デラクリートセメ
ントボード」など、をいう。
BEST MODE FOR CARRYING OUT THE INVENTION The cement board referred to in the present invention is a wood chip cement board, a calcium silicate board (commonly referred to as a calcical board) or a cement having hydraulic properties, to which aggregates and various additives are added as required. Kneaded with water, cured, embedded and reinforced with a fiber mesh as required, and formed into a plate shape, for example, "Delacrete cement board" manufactured by Mitsubishi Rayon Co., Ltd.

【0011】本発明が対象とする不陸調整用セメントモ
ルタル組成物は、材料配合割合を所定の範囲に規定し
て、水硬性を有するセメント、これに特定の粒径や特定
量の無機系発泡骨材、特定量のポリマー、さらに特定量
の繊維、さらに必要に応じて用いられる硬化調節剤、寸
法安定剤、増粘剤など各種の添加剤から構成され、これ
に特定量の水を加え適宜のミキサーで混練して用いるこ
とができる。
[0011] The cement mortar composition for controlling irregularities, which is the object of the present invention, is a cement having hydraulic properties, in which a material mixing ratio is defined within a predetermined range, and a specific particle size and a specific amount of inorganic foam. It is composed of aggregate, specific amount of polymer, further specific amount of fiber, and various additives such as curing regulator, dimensional stabilizer, thickener, etc., which are used as needed, to which specific amount of water is added, and Kneaded with a mixer.

【0012】本発明で使用する水硬性を有するセメント
としては普通ポルトランドセメント、早強ポルトランド
セメント、中庸熱ポルトランドセメント、高炉セメン
ト、シリカセメント、フライアッシュセメント、アルミ
ナセメント、ジェットセメントなどの各種セメントを用
いることができる。
As the hydraulic cement used in the present invention, various cements such as ordinary Portland cement, early-strength Portland cement, moderately heated Portland cement, blast furnace cement, silica cement, fly ash cement, alumina cement and jet cement are used. be able to.

【0013】本発明で使用する無機系発泡骨材として
は、黒曜石、真珠岩、火成岩、バーミキュライト等の原
石を粒度調整した後、約1000℃で急激に焼成し、発
泡させたもので、これらの一種または二種以上を組み合
わせて用いることができる。無機系発泡骨材の粒径とし
ては5mm以下で、目開き2.36mmの篩上に残留するも
のの割合が0.1〜2重量%、目開き1.18mmの篩上
に残留するものの割合が15〜25重量%、および、目
開き0.60mmの篩上に残留するものの割合が50重量
%以下であることが良い。粒径が5mmを越えるもの、及
び目開き2.36mmの篩上に残留するものの割合が2重
量%を越えるものは、無機系発泡骨材が硬化体表面に凹
凸として現れ、硬化体の表面性が低下する。目開き2.
36mmの篩上に残留するものの割合が0.1重量%未満
では、1回の塗布厚が4mm以上とすることができず、施
工時の塗布厚の管理をすることが難しく、防火性能が得
られない。目開き0.60mmの篩上に残留するものの割
合が50重量%を越えるものは、作業性が低下する。無
機系発泡骨材の配合量は、その種類や組み合わせなどに
より若干異なるが、セメント100重量部に対し10〜
60重量部であることが良い。配合量が10重量部未満
では、セメント分が多くなりひび割れが起こり易くなる
と同時に、防火性能が得られない。また60重量部を超
えると骨材量が多すぎるために、作業性が著しく低下す
る。
The inorganic foam aggregate used in the present invention is obtained by adjusting the particle size of an ore such as obsidian, perlite, igneous rock, vermiculite, etc., and then rapidly baking it at about 1000 ° C. to form a foam. One type or a combination of two or more types can be used. The particle size of the inorganic foamed aggregate is 5 mm or less, and the ratio of those remaining on a sieve with an opening of 2.36 mm is 0.1 to 2% by weight, and the ratio of those remaining on a sieve with an opening of 1.18 mm is It is preferable that the proportion of the substance remaining on the sieve having a mesh size of 15 to 25% by weight and 0.60 mm is 50% by weight or less. When the particle size exceeds 5 mm and the ratio of the one remaining on the sieve with a mesh size of 2.36 mm exceeds 2% by weight, the inorganic foamed aggregate appears as irregularities on the surface of the cured product, and the surface property of the cured product is increased. Decrease. Openings2.
If the ratio of the residue on the 36 mm sieve is less than 0.1% by weight, the thickness of a single coating cannot be 4 mm or more, and it is difficult to control the coating thickness at the time of construction, and the fire prevention performance is obtained. I can't. If the ratio of the residue on the sieve having an opening of 0.60 mm exceeds 50% by weight, the workability is reduced. The amount of the inorganic foamed aggregate varies slightly depending on the type and combination of the inorganic foamed aggregate, but is 10 to 100 parts by weight of the cement.
Preferably, it is 60 parts by weight. If the compounding amount is less than 10 parts by weight, the amount of cement increases and cracks easily occur, and at the same time, fire prevention performance cannot be obtained. On the other hand, if it exceeds 60 parts by weight, the workability is remarkably reduced because the amount of aggregate is too large.

【0014】本発明で使用する繊維は、亀裂或いは割れ
を生じさせないために必要なものであり,耐アルカリガ
ラス繊維,炭素繊維、スチールファイバーなどの無機繊
維,ビニロン繊維,ナイロン繊維,ポリプロピレン繊維
などの有機繊維を一種或いは二種以上を組み合わせて用
いることが出来る。
The fibers used in the present invention are necessary to prevent cracks or cracks, and include inorganic fibers such as alkali-resistant glass fibers, carbon fibers, and steel fibers, vinylon fibers, nylon fibers, and polypropylene fibers. Organic fibers can be used alone or in combination of two or more.

【0015】繊維の配合量は、その種類や組み合わせな
どにより若干異なるが、セメント100重量部に対し
0.1〜20重量部、好ましくは、1〜10重量部、さ
らに好ましくは、3〜5重量部が良い。配合量が0.1
重量部未満では繊維を添加した効果はなく、亀裂や割れ
を生じ易い。また、20重量部を超えると繊維が表面に
露出し、表面性が悪くなるのと同時に、作業性も悪くな
る。また、繊維長は特に規定するものではないが、ひび
割れや表面性の関係から3〜18mmの範囲のものを用
いるのが好ましい。
The amount of the fiber varies slightly depending on the type and combination of the fibers, but is 0.1 to 20 parts by weight, preferably 1 to 10 parts by weight, more preferably 3 to 5 parts by weight based on 100 parts by weight of cement. Department is good. 0.1
If the amount is less than part by weight, the effect of adding the fiber is not obtained, and cracks and cracks are easily generated. If the amount exceeds 20 parts by weight, the fibers are exposed on the surface, and the surface properties are deteriorated, and the workability is also deteriorated. Although the fiber length is not particularly limited, it is preferable to use a fiber having a length in the range of 3 to 18 mm from the viewpoint of cracks and surface properties.

【0016】本発明で使用するポリマーは、エチレン酢
酸ビニル共重合物、アクリル酸或いはアクリル−スチレ
ン系共重合物、酢酸ビニル系、スチレン−ブタジエン系
共重合物、酢酸ビニル−バーサチック酸ビニル系共重合
物、酢酸ビニル−バーサチック酸ビニル−アクリル系共
重合物、酢酸ビニル−バーサチック酸ビニル−ラウリル
酸ビニル系共重合物等を例示でき、その形態はエマルシ
ョンでも再乳化型の粉末でも良い。また、ポリマーの種
類はエチレン酢酸ビニル共重合物が好ましく用いられ
る。ポリマーの配合量は、セメント重量部に対しポリマ
ー固形分濃度換算で1〜10重量部、好ましくは3〜7
重量部が良い。配合量が1重量部未満では、セメントボ
ードへの水の吸い込みが早く施工性に乏しい。また、1
0重量部を超えるとポリマー量が過剰となり、例えば鏝
抑えがし難い、粘度が上昇しベタ付く等、作業性が悪く
なる。
The polymer used in the present invention is ethylene-vinyl acetate copolymer, acrylic acid or acryl-styrene copolymer, vinyl acetate, styrene-butadiene copolymer, vinyl acetate-vinyl versatate copolymer. Products, vinyl acetate-vinyl versatate-acrylic copolymer, vinyl acetate-vinyl versatate-vinyl laurate copolymer, and the form thereof may be an emulsion or a re-emulsifying powder. As the type of the polymer, an ethylene-vinyl acetate copolymer is preferably used. The compounding amount of the polymer is 1 to 10 parts by weight, preferably 3 to 7 parts by weight in terms of the polymer solid content based on the cement weight part.
Good by weight. If the compounding amount is less than 1 part by weight, water is quickly sucked into the cement board and workability is poor. Also, 1
If the amount is more than 0 parts by weight, the amount of the polymer becomes excessive, for example, it is difficult to suppress the iron, and the workability is deteriorated, for example, the viscosity is increased and the solid is adhered.

【0017】本発明の不陸調整用セメントモルタル組成
物には、さらに珪砂、山砂、川砂、海砂等の重量骨材、
分散剤、増粘剤、凝結調整剤、収縮低減剤を必要に応じ
て加えてもよい。
The cement mortar composition for controlling unevenness of the present invention further comprises heavy aggregates such as silica sand, mountain sand, river sand, and sea sand.
A dispersant, a thickener, a setting regulator, and a shrinkage reducing agent may be added as needed.

【0018】本発明で使用可能である珪砂等の重量骨材
としては、粒度調整されているものや粒度分布を持って
いるもの、微粉化しているもの等を使用でき、その骨材
の粒径は無機発泡骨材と同等或いは細かいことが良い。
珪砂等の重量骨材の配合量としては、セメントに対し0
〜50重量部の範囲が良い。配合量が50重量部を超え
ると、下地に対する接着性が悪くなる傾向となる。
As the weight aggregate such as silica sand that can be used in the present invention, those having a controlled particle size, those having a particle size distribution, and those that have been pulverized can be used. Is preferably equal to or finer than the inorganic foamed aggregate.
The amount of heavy aggregate such as silica sand is 0
A good range is from 50 to 50 parts by weight. If the amount exceeds 50 parts by weight, the adhesiveness to the substrate tends to be poor.

【0019】本発明で使用可能である分散剤としては、
メラミンホルマリン縮合物スルホン酸塩、リグニンスル
ホン酸塩、β−ナフタレンスルホン酸アルデヒド縮合
物、ポリアルキルアリルスルホン酸塩、ポリカルボン酸
塩,アルキルナフタリンスルホン酸塩、アルキルナフタ
レンスルホン酸ホルマリン縮合物塩等が挙げられ、これ
らの一種または二種以上を組み合わせて用いることがで
きる。また上記化合物の塩の種類はナトリウム、カリウ
ム、カルシウムなどである。
The dispersants usable in the present invention include:
Melamine formalin condensate sulfonate, lignin sulfonate, β-naphthalene sulfonic acid aldehyde condensate, polyalkylallyl sulfonate, polycarboxylate, alkyl naphthalene sulfonate, alkyl naphthalene sulfonate formalin condensate, etc. And these can be used alone or in combination of two or more. The types of salts of the above compounds are sodium, potassium, calcium and the like.

【0020】本発明で使用可能である増粘剤は、本発明
の組成物の作業性や接着性を向上させる機能を有するも
のであり、メチルセルロース、エチルセルロース、ヒド
ロキシエチルセルロース、エチルヒドロキシメチルセル
ロース、エチルヒドロキシエチルセルロース、カルボキ
シメチルセルロースなどのセルロースエーテル類、ポリ
アクリルアミド、ポリエチレンオキサイド、ポリビニル
アルコール、カゼインなどの各種の水溶性高分子が挙げ
られ、これらの一種または二種以上を組み合わせて用い
ることができる。
The thickener which can be used in the present invention has a function of improving the workability and adhesiveness of the composition of the present invention, and includes methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, ethyl hydroxymethyl cellulose, ethyl hydroxyethyl cellulose. And various water-soluble polymers such as cellulose ethers such as carboxymethylcellulose, polyacrylamide, polyethylene oxide, polyvinyl alcohol, and casein. These can be used alone or in combination of two or more.

【0021】本発明で使用可能である凝結調整剤は、硬
化時間や作業できる時間のコントロールを行う機能を有
するものであり、アルミン酸ソーダ、炭酸ソーダ、珪酸
ソーダ、アルミン酸カルシウム類、カルシウムサルホア
ルミネート、硫酸カリウム、硫酸アルミニウム等の硬化
促進剤、また、クエン酸、クエン酸三ソーダ、糖類、乳
酸、アルコール類等の硬化遅延剤を各種用いることがで
きる。
The setting regulator which can be used in the present invention has a function of controlling the curing time and the workable time, and includes sodium aluminate, sodium carbonate, sodium silicate, calcium aluminate, calcium sulfoaluminum. Various hardening accelerators such as citrate, potassium sulfate, aluminum sulfate and the like, and various hardening retardants such as citric acid, trisodium citrate, sugars, lactic acid and alcohols can be used.

【0022】本発明で使用可能である収縮低減剤として
は、JIS A6202「コンクリート用膨張材」で規
定される物を使用でき、これらを一種または二種以上組
み合わせて用いることができる。
As the shrinkage reducing agent that can be used in the present invention, those specified in JIS A6202 “Expanding material for concrete” can be used, and these can be used alone or in combination of two or more.

【0023】次に、本発明の施工方法について説明す
る。
Next, the construction method of the present invention will be described.

【0024】本発明の施工方法においては、上記不陸調
整用セメントモルタル組成物100重量部当たり水を2
5〜55重量部、好ましくは30〜50重量部を添加し
て混練りし、得られた混練物をセメントボードに塗布す
ることができる。混練水が25重量部未満では、混練物
を均一な状態にできないか、均一にできても粘度が高く
作業性が悪くなる。また、55重量部を超えると、混練
水過剰となりひび割れが入り易く、さらに強度低下を招
くことがある。組成物に水を添加し混練する際の混練の
程度は均一に分散され、十分に水と馴染んでいればよい
が、粉末状のポリマーを使用した場合は2〜3分間混練
することが好ましい。混練にあってはハンドミキサー、
タライミキサー等のミキサー類を用いる或いは煉瓦鏝、
練りスコ等のいわゆる手練りで混練することができる。
In the construction method of the present invention, water is used in an amount of 2 parts by weight per 100 parts by weight of the cement mortar composition for adjusting unevenness.
5 to 55 parts by weight, preferably 30 to 50 parts by weight are added and kneaded, and the obtained kneaded material can be applied to a cement board. If the kneading water is less than 25 parts by weight, the kneaded material cannot be made uniform, or even if it can be made uniform, the viscosity is high and the workability deteriorates. On the other hand, when the amount exceeds 55 parts by weight, the kneading water becomes excessive and cracks are liable to occur, which may further reduce the strength. The degree of kneading when water is added to and kneaded with the composition may be uniform as long as it is well dispersed with water, but if a powdery polymer is used, kneading is preferably performed for 2 to 3 minutes. Hand mixer for kneading,
Use mixers such as Tarai mixer or brick iron,
Kneading can be performed by so-called hand kneading such as kneading.

【0025】こうして得られた混練物を目地処理を施し
たセメントボードに塗布する際の厚みは4mm以上が良
い。塗布厚が4mm未満では、セメントボードの継ぎ目部
分等の段差を調整することができないだけでなく、防火
性能が得られない。混練物の塗布にあたっては、鏝やヘ
ラなどを用いて塗布してもよく、混練物を吹き付け機等
で吹き付け塗装してもよい。また、上記セメントモルタ
ル混練物の塗布を行う際に、鏝やブラシ等でしごく工程
が入ることが好ましい。また、工程が一つ増えるために
煩雑とはなるが、本発明で規定しているポリマーを単独
や希釈、或いはセメントなどと混練りしプライマーとし
て塗布する工程を行うこともできる。さらに仕上げを行
う際は、鏝等の表面均し道具を用いて均し、硬化させる
ことが好ましい。
The thickness of the kneaded material thus obtained when applied to a cement board subjected to joint treatment is preferably 4 mm or more. If the coating thickness is less than 4 mm, not only the step at the seam portion of the cement board and the like cannot be adjusted, but also fire prevention performance cannot be obtained. In applying the kneaded material, the kneaded material may be applied using a trowel, a spatula, or the like, or the kneaded material may be applied by spraying with a spraying machine or the like. In addition, when the cement mortar kneaded material is applied, it is preferable that a squeezing step be performed with a trowel, a brush, or the like. In addition, although one step increases the complexity, the step of applying the polymer specified in the present invention alone, diluted, or kneaded with cement or the like and applied as a primer can also be performed. Further, when finishing, it is preferable to level and harden using a surface leveling tool such as a trowel.

【0026】[0026]

【実施例】以下に実施例、比較例を用いて本発明を更に
詳しく説明するが、本発明はその要旨を越えない限り、
以下の実施例に限定されるものでない。
The present invention will be described in more detail with reference to the following Examples and Comparative Examples.
It is not limited to the following embodiments.

【0027】なお、実施例において、セメントとして普
通ポルトランドセメントを用いた例を示すが、セメント
として早強ポルトランドセメント、中庸熱ポルトランド
セメント、高炉セメント、シリカセメント、フライアッ
シュセメント、アルミナセメント及びジェットセメント
の何れを用いても以下の実施例と同様、優れた不陸調整
用セメントモルタルとなる。また、実施例において下地
として、三菱レイヨン社製のセメントボードである「デ
ラクリートセメントボード」を用いた。
In the examples, an example in which ordinary Portland cement is used as the cement will be described. Whichever one is used, an excellent non-adjustment cement mortar can be obtained as in the following examples. In the examples, "Delacrete cement board" which is a cement board manufactured by Mitsubishi Rayon Co., Ltd. was used as a base.

【0028】実施例1〜10、比較例1〜18セメント
として普通ポルトランドセメントを用い、これと、無機
系発泡骨材、繊維及びポリマーをそれぞれ表1に示す量
配合した組成物に、表1に示す配合比で水を加えてJI
S R 5201に規定されるモルタルミキサーを用い
て3分間混練し、各種の混練物を得た。なお、エマルシ
ョンはエマルション原液を105℃で恒量となるまで乾
燥し、乾燥前後の重量から下記式で固形分濃度を算出し
て、その値からポリマー量及び水の量が表1の値となる
ようにエマルション及び添加する水の量を定めた。
Examples 1 to 10 and Comparative Examples 1 to 18 Table 1 shows a composition obtained by using ordinary Portland cement as the cement and blending the same with the inorganic foamed aggregate, fiber and polymer in the amounts shown in Table 1. Add water at the indicated mixing ratio and add JI
The mixture was kneaded for 3 minutes using a mortar mixer specified in SR5201 to obtain various kneaded materials. In addition, the emulsion was dried at 105 ° C. to a constant weight at 105 ° C., and the solid content concentration was calculated from the weight before and after the drying using the following formula, and the polymer amount and the water amount from the values were as shown in Table 1. The amounts of the emulsion and the water to be added were determined.

【0029】固形分濃度[wt%]={乾燥後重量/乾
燥前重量}×100
Solid content concentration [wt%] = {weight after drying / weight before drying} × 100

【0030】セメントボードに混練物を5mmの塗布厚と
なるように鏝で塗布した時の鏝作業性のうち、付着性を
評価した。 ○・・・セメントボードに塗布した際に、こぼれや剥が
れ落ちる等がなく良好なもの。 ×・・・セメントボードに塗布した際に、こぼれや剥が
れ落ちる等が生じたもの。
Among the workability of the iron when the kneaded material was applied to a cement board with a thickness of 5 mm using an iron, the adhesion was evaluated.・ ・ ・: Good without spilling or peeling when applied to cement board. C: Spills, peeling off, etc. occurred when applied to a cement board.

【0031】セメントボードに混練物を5mmの塗布厚と
なるように鏝で塗布した時の鏝作業性のうち、鏝伸びを
評価した。 ○・・・セメントボードに塗布した際に、混練物が均一
に伸び良好なもの。 ×・・・セメントボードに塗布した際に、混練物が均一
に伸びないもの。
Among the workability of the iron when the kneaded material was applied to the cement board with a thickness of 5 mm using an iron, the elongation of the iron was evaluated.・ ・ ・: The kneaded material spreads uniformly when applied to a cement board and has good quality. X: The kneaded material does not stretch uniformly when applied to a cement board.

【0032】セメントボードに混練物を5mmの塗布厚と
なるように鏝で塗布した時の鏝作業性のうち、鏝離れを
評価した。 ○・・・セメントボードに塗布した際に、混練物が鏝に
付着せず良好なもの。 ×・・・セメントボードに塗布した際に、混練物が鏝に
付着してしまうもの。
When the kneaded material was applied to a cement board with a trowel so as to have a coating thickness of 5 mm, the iron workability was evaluated as the trowel workability.・ ・ ・: Good when the kneaded material does not adhere to the iron when applied to a cement board. X: The kneaded material adheres to the iron when applied to the cement board.

【0033】セメントボードに混練物を鏝で塗布する際
の塗布厚を評価した。 ○・・・鏝で掃くように塗布しても1回で4mm以上塗布
可能で、塗布厚の管理が可能なもの。 ×・・・鏝で掃くように塗布しても1回で4mm以上塗布
できず、塗布厚の管理ができないもの。
The thickness of the kneaded material applied to the cement board with a trowel was evaluated. ○ ・ ・ ・ Applicable to apply 4mm or more at a time even if it is applied by sweeping with a trowel, and the coating thickness can be controlled. ×: The coating thickness cannot be controlled more than 4 mm at a time even if the coating is performed with a trowel so that the coating thickness cannot be controlled.

【0034】防火性能は、セメントボードに混練物を鏝
で塗布し、塗布厚を評価した供試体を硬化・養生し、J
IS A 1301に規定する防火2級加熱曲線に従い
加熱した。 ○・・・最高裏面温度が260℃以下のもの。 ×・・・最高裏面温度が260℃を越えるもの。
The fire prevention performance was measured by applying the kneaded material to a cement board with a trowel, curing and curing the test specimen having the evaluated coating thickness.
Heating was carried out according to a fire prevention class 2 heating curve specified in IS A 1301.・ ・ ・: The maximum back surface temperature is 260 ° C. or less. ×: The maximum back surface temperature exceeds 260 ° C.

【0035】硬化体評価の表面性はセメントボードに混
練物を5mmの塗布厚となるように鏝で塗布して鏝作業性
を評価した供試体を硬化・養生し、1日後及び28日後
の硬化体表面を目視で観察し評価した。 ○・・・亀裂・白華・剥がれがなく、繊維の飛び出しが
なく良好であるもの。 ×・・・亀裂・白華・剥がれ、繊維の飛び出しが生じて
いるもの。
The surface properties of the cured product evaluation were as follows. The kneaded material was applied to a cement board by a trowel so as to have a coating thickness of 5 mm, and the test pieces evaluated for trowel workability were cured and cured, and cured after 1 day and 28 days. The body surface was visually observed and evaluated.・ ・ ・: Good without cracks, efflorescence, peeling, and without fiber protrusion. ×: Cracks, efflorescence, peeling, and fibers jumping out.

【0036】総合評価として、何れの項目も○であるも
のを総合評価○、また何れかの項目に×があるものを総
合評価×とした。
As for the overall evaluation, those in which all items were ○ were evaluated as 総 合, and those in which any item was と し た were evaluated as ×.

【0037】[0037]

【表1】 [Table 1]

【0038】なお、表1において、無機系発泡骨材欄の
−は無添加、aは黒曜石系パーライトで粒径分布が表1
記載のとおりになるように調整したもの、太平洋セメン
ト社製、「アサノパーライト3号」、「アサノパーライ
ト4号」、「アサノパーライト5号」を混合して得た。
bは黒曜石系パーライトで粒径分布が表1記載のとおり
になるように調整したもの、芙蓉パーライト社製、「フ
ヨーライト0号」、「フヨーライト1号」、「フヨーラ
イト2号」、「フヨーライト7号」を混合して得た。を
示す。また、粒径欄は各目開きの篩上に残留する割合
(重量%)を記載した。
In Table 1, in the column of the inorganic foamed aggregate,-is not added, a is obsidian pearlite, and the particle size distribution is as shown in Table 1.
It was adjusted as described, and was obtained by mixing "Asano Perlite No. 3,""Asano Perlite No. 4," and "Asano Perlite No. 5" manufactured by Taiheiyo Cement Corporation.
b is obsidian pearlite adjusted to have a particle size distribution as shown in Table 1, manufactured by Fuyo Perlite Co., Ltd., "Fuyolite 0", "Fuyolite 1", "Fuyolite 2", "Fuyolite 7" Was mixed. Is shown. In the column of particle size, the ratio (% by weight) remaining on the sieve of each opening is described.

【0039】繊維欄において、−は無添加、Aはナイロ
ン繊維、Bはビニロン繊維、Cは耐アルカリガラス繊維
を示す。
In the fiber column,-indicates no addition, A indicates nylon fiber, B indicates vinylon fiber, and C indicates alkali-resistant glass fiber.

【0040】ポリマー欄において、−は無添加、Xはエ
チレン酢酸ビニル共重合系エマルションポリマーである
日本化成社製「NSハイフレックスHF−1000」、
Yは酢酸ビニル/ビニルバーサテート/アクリル酸共
重合系粉末ポリマーである日本エヌエスシー社製「エロ
テックスAP−200」、Zはスチレン/ブタジエン共
重合系ラテックスである武田薬品社製「クロスレンCM
X−02」 を示す。
In the polymer column,-represents no addition, and X represents "NS Hyflex HF-1000" manufactured by Nippon Kasei Co., Ltd., which is an ethylene-vinyl acetate copolymer emulsion polymer.
Y is "Erotex AP-200" manufactured by NSC, which is a vinyl acetate / vinyl versate / acrylic acid copolymer powder polymer; Z is "Crosslen CM" manufactured by Takeda Pharmaceutical Company, which is a styrene / butadiene copolymer latex.
X-02 ".

【0041】実施例1〜10は本発明の要件を満たす条
件で試験されたので、いずれも良好な塗布作業性能が得
られ、良い硬化体が得られた。比較例1は無機系発泡骨
材が添加さていないため、1回で4mm以上塗布すること
ができず、施工時の塗布厚の管理が難しいとともに防火
性能が得られず、硬化後の表面に亀裂が見られた。比較
例2は無機系発泡骨材が60重量部を越えているため、
下地に対する付着性が悪く、硬化後に亀裂、あるいは剥
がれを生じた。比較例3,4は無機系発泡骨材が目開き
2.36mmの篩上に残留するものの割合が0.1重量%
未満であるため、1回で4mm以上塗布することできず、
施工時の塗布厚の管理をすることが難しく、防火性能が
得られなくなる。さらに、比較例4では無機系発泡骨材
の粒径が目開き0.60mmの篩上に残留するものの割合
が50重量%以上であるため作業性が低下する。比較例
5は無機系発泡骨材の粒径が目開き2.36mmの篩上に
残留するものの割合が2重量%を越えているため、下地
に対する付着性が低下し、作業性が悪く、硬化体の表面
に凹凸を生じた。比較例6は繊維を添加しなかったため
に硬化体表面に亀裂が生じた。比較例7は繊維量が多い
ため、鏝作業性の下地への付着性及び鏝伸びが低下し、
かつ硬化体表面に繊維が飛び出し、表面性が低下する。
比較例8はポリマーを添加しなかったため、鏝作業性の
下地への付着性及び鏝伸びが低下し、かつ硬化体表面に
鏝むらを生じ、表面性が低下する。比較例9はポリマー
の添加量が10重量部を越えたため、混練物の粘度が上
昇し、鏝作業性のうち、鏝伸び、鏝離れが低下し、塗布
し難くなるとともに硬化体表面に鏝むらが生じた。比較
例10は混練水量が規定量より少ないために混練物が硬
くなり、作業性が悪く、さらに硬化体に凹凸が生じた。
比較例11は混練水量が規定量より多いために、1回で
4mm以上塗布し難く、施工時の塗布厚の管理が難しくな
るとともに防火性能が得られず、硬化体表面に白華・亀
裂を生じた。比較例12は無機系発泡骨材に粒径が5m
mを超えるものがあるために、硬化体表面に凹凸を生
じ、表面性が低下する。
Since Examples 1 to 10 were tested under the conditions satisfying the requirements of the present invention, good coating performance was obtained and good cured products were obtained. In Comparative Example 1, since no inorganic foamed aggregate was added, it was not possible to apply 4 mm or more at a time, it was difficult to control the applied thickness at the time of construction, fire prevention performance was not obtained, and the surface after curing was cracked. It was observed. In Comparative Example 2, since the inorganic foamed aggregate exceeded 60 parts by weight,
Poor adhesion to substrate, cracking or peeling after curing. In Comparative Examples 3 and 4, the percentage of the inorganic foamed aggregate remaining on the sieve having an opening of 2.36 mm was 0.1% by weight.
Less than 4mm at a time,
It is difficult to control the coating thickness at the time of construction, and fire prevention performance cannot be obtained. Further, in Comparative Example 4, the workability is reduced because the ratio of the inorganic foam aggregate remaining on the sieve having a mesh size of 0.60 mm is 50% by weight or more. In Comparative Example 5, the proportion of the inorganic foam aggregate remaining on a sieve having a mesh size of 2.36 mm was more than 2% by weight. Irregularities occurred on the surface of the body. In Comparative Example 6, cracks occurred on the surface of the cured product because no fiber was added. Comparative Example 7 has a large amount of fiber, so that the adhesion to the base and the elongation of the iron are reduced.
In addition, the fibers jump out to the surface of the cured product, and the surface property is reduced.
In Comparative Example 8, since no polymer was added, the workability of ironing to the substrate and the elongation of the iron decreased, and the surface of the cured product was reduced due to uneven iron. In Comparative Example 9, since the addition amount of the polymer exceeded 10 parts by weight, the viscosity of the kneaded material was increased, and among the iron workability, the elongation of the iron and the separation of the iron were reduced, and it became difficult to apply the iron. Occurred. In Comparative Example 10, since the amount of kneading water was smaller than the specified amount, the kneaded material became hard, the workability was poor, and the cured product had irregularities.
In Comparative Example 11, since the amount of the kneading water was larger than the specified amount, it was difficult to apply 4 mm or more at one time, it was difficult to control the coating thickness at the time of construction, and fire prevention performance was not obtained. occured. In Comparative Example 12, the inorganic foamed aggregate had a particle size of 5 m.
m, the surface of the cured product becomes uneven, and the surface properties are reduced.

【0042】[0042]

【発明の効果】本発明は、次の効果を奏する。セメント
ボードにセメントモルタル組成物を塗布しあるいは吹き
付け、表面を均す作業において、1回で4mm以上塗布す
ることが可能であるため、セメントボードが反り返って
いたり、継ぎ目部分等に生じた段差を調節することが可
能で、特別な工程を設けることなく施工時の塗布厚を管
理でき、防火性能が得られ、作業性を大幅に改善するこ
とができる。
The present invention has the following effects. Applying or spraying the cement mortar composition on the cement board to smooth the surface, it is possible to apply 4 mm or more at a time, so the cement board warps or adjusts the level difference at seams etc. It is possible to control the coating thickness at the time of construction without providing a special process, to obtain fire prevention performance, and to greatly improve workability.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C04B 26:02) ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification code FI theme coat ゛ (reference) C04B 26:02)

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 木造や鉄骨造等にセメントボードを張り
付けた後、目地処理を行い、セメントモルタルで不陸調
整し、仕上げ材にて仕上げを行う施工方法に用いる不陸
調整用セメントモルタルであって、セメント100重量
部、無機系発泡骨材10〜60重量部、繊維0.1〜2
0重量部およびポリマー1〜10重量部の範囲に調節し
てなる不陸調整用セメントモルタル組成物。
A cement mortar for adjusting land use which is used in a construction method in which a cement board is attached to a wooden structure, a steel frame structure or the like, then jointed, treated with cement mortar, and finished with a finishing material. 100 parts by weight of cement, 10 to 60 parts by weight of inorganic foam aggregate, 0.1 to 2 fibers
A cement mortar composition for adjusting unevenness, which is adjusted to a range of 0 part by weight and 1 to 10 parts by weight of a polymer.
【請求項2】 無機系発泡骨材が、粒径として5mm以下
であり、かつ、目開き2.36mmの篩上に残留するもの
の割合が0.1〜2重量%、目開き1.18mmの篩上に
残留するものの割合が15〜25重量%、および、目開
き0.60mmの篩上に残留するものの割合が50重量%
以下である請求項1記載の不陸調整用セメントモルタル
組成物。
2. An inorganic foamed aggregate having a particle size of 5 mm or less and a ratio of 0.1 to 2% by weight remaining on a sieve having a mesh size of 2.36 mm and a mesh size of 1.18 mm. The proportion of the substance remaining on the sieve is 15 to 25% by weight, and the proportion of the substance remaining on the sieve having an aperture of 0.60 mm is 50% by weight.
The cement mortar composition for uneven land adjustment according to claim 1, which is:
【請求項3】 不陸調整用セメントモルタル組成物10
0重量部に対して、25〜55重量部の水と混練して得
られた混練物を目地処理を施したセメントボードに4mm
以上塗布して硬化させることで防火性能を得ることを特
徴とする請求項1または2記載の不陸調整用セメントモ
ルタル組成物の施工方法。
3. A cement mortar composition for adjusting unevenness 10
A kneaded material obtained by kneading 25 to 55 parts by weight of water with respect to 0 parts by weight was added to a cement board having been subjected to joint treatment by 4 mm.
The method for applying a cement mortar composition for uneven land adjustment according to claim 1 or 2, wherein the composition is cured by applying and curing the composition.
JP11212478A 1999-07-27 1999-07-27 Cement mortar composition for unevenness adjustment and method for executing application work of the same Pending JP2001039755A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11212478A JP2001039755A (en) 1999-07-27 1999-07-27 Cement mortar composition for unevenness adjustment and method for executing application work of the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11212478A JP2001039755A (en) 1999-07-27 1999-07-27 Cement mortar composition for unevenness adjustment and method for executing application work of the same

Publications (1)

Publication Number Publication Date
JP2001039755A true JP2001039755A (en) 2001-02-13

Family

ID=16623320

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11212478A Pending JP2001039755A (en) 1999-07-27 1999-07-27 Cement mortar composition for unevenness adjustment and method for executing application work of the same

Country Status (1)

Country Link
JP (1) JP2001039755A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001261418A (en) * 2000-03-23 2001-09-26 Denki Kagaku Kogyo Kk Spraying material and construction method for spraying the same
JP2003055021A (en) * 2001-08-23 2003-02-26 Denki Kagaku Kogyo Kk Spraying material and spraying technique using the same
JP2007176740A (en) * 2005-12-28 2007-07-12 Taiheiyo Material Kk Thickening mortar
JP2019147900A (en) * 2018-02-28 2019-09-05 大和ハウス工業株式会社 One-pack ordinary temperature moisture curable sealant composition

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001261418A (en) * 2000-03-23 2001-09-26 Denki Kagaku Kogyo Kk Spraying material and construction method for spraying the same
JP4531188B2 (en) * 2000-03-23 2010-08-25 電気化学工業株式会社 Spraying method
JP2003055021A (en) * 2001-08-23 2003-02-26 Denki Kagaku Kogyo Kk Spraying material and spraying technique using the same
JP2007176740A (en) * 2005-12-28 2007-07-12 Taiheiyo Material Kk Thickening mortar
JP2019147900A (en) * 2018-02-28 2019-09-05 大和ハウス工業株式会社 One-pack ordinary temperature moisture curable sealant composition

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