JP2000332153A - Method for cleaning solder bump forming surface of wafer-level csp - Google Patents

Method for cleaning solder bump forming surface of wafer-level csp

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Publication number
JP2000332153A
JP2000332153A JP11143511A JP14351199A JP2000332153A JP 2000332153 A JP2000332153 A JP 2000332153A JP 11143511 A JP11143511 A JP 11143511A JP 14351199 A JP14351199 A JP 14351199A JP 2000332153 A JP2000332153 A JP 2000332153A
Authority
JP
Japan
Prior art keywords
wafer
solder bump
cleaning
forming surface
bump forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11143511A
Other languages
Japanese (ja)
Inventor
公夫 ▲土▼井
Kimio Doi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ENYA SYSTEM KK
Original Assignee
ENYA SYSTEM KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ENYA SYSTEM KK filed Critical ENYA SYSTEM KK
Priority to JP11143511A priority Critical patent/JP2000332153A/en
Publication of JP2000332153A publication Critical patent/JP2000332153A/en
Pending legal-status Critical Current

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  • Cleaning By Liquid Or Steam (AREA)

Abstract

PROBLEM TO BE SOLVED: To surely clean the solder bump forming surface of a wafer-level chip size (scale) package (CSP) which is formed in the level of a wafer. SOLUTION: After solder bumps are formed on a wafer 13 and the bumps are reflowed, the wafer 13 is held by a spin chuck and rotated. The solder bump forming surfaces 10 of the wafer 13 are heated by blowing steam upon the surfaces 10 from a nozzle 16. When the surfaces 10 are heated, the residues of flux 11, scattered solder 12, etc., become soft. Then the residues are washed away by jetting a washing solution upon the softened residues with a high pressure.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、半導体製造工程の
ICパッケ−ジプロセスであるチップサイズ(スケ−
ル)パッケ−ジ(CSP)の洗浄に係り、特に上記CS
Pプロセスをウエ−ハ上で行うようにしたウエ−ハレベ
ルCSPにおいて、ハンダバンプ形成後に、該形成面を
洗浄するウエ−ハレベルCSPのハンダバンプ形成面洗
浄方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a chip size (scale) which is an IC package process in a semiconductor manufacturing process.
L) In connection with the cleaning of the package (CSP),
The present invention relates to a method for cleaning a solder bump forming surface of a wafer level CSP, in which, after a solder bump is formed, the formation surface is cleaned in a wafer level CSP in which the P process is performed on the wafer.

【0002】[0002]

【従来の技術】携帯機器や小型高密度実装機器は、近年
ますます超小型化、超薄型化されてきており、それに伴
ってこれらの機器に使用される集積回路(IC)のパッ
ケ−ジも超小型化、超薄型化が要求されている。そのよ
うな要求に応じるICパッケ−ジプロセスとして、チッ
プサイズと同等あるいはわずかに大きい程度にパッケ−
ジする方法であるチップサイズ(スケ−ル)パッケ−ジ
(CSP)が知られている。さらに、このようなCSP
を行うプロセスとして、ウエ−ハ段階ですべてのCSP
加工を行い、その後にダイシングして個別のCSPを得
るようにしたウエ−ハレベルCSPが知られている。
2. Description of the Related Art In recent years, portable devices and small high-density mounting devices have been increasingly miniaturized and ultra-thin, and accordingly, integrated circuit (IC) packages used in these devices have been developed. Are also required to be ultra-small and ultra-thin. As an IC package process that meets such demands, a package that is equivalent to or slightly larger than the chip size is used.
A chip size (scale) package (CSP), which is a method of mounting, is known. Furthermore, such a CSP
As a process to perform all CSPs at the wafer stage
There is known a wafer level CSP in which processing is performed and then dicing is performed to obtain individual CSPs.

【0003】上記ウエ−ハレベルCSPにおいては、例
えばス−パ−CSPではウエ−ハレベルで多層配線によ
りAlパッドの再配置を行い、外部端子部にハンダ付け
可能なバンプを形成し、それを避けてウエ−ハ全面に保
護用の樹脂をコ−トし、ハンダバンプ形成後、ダイシン
グするようにしている。また、Ultra CPS (Flip ChipTe
chnologies社) は、ウエ−ハレベルで絶縁樹脂層を介し
てその上に電極の変換パタ−ンとハンダ付け可能な電極
パッドを形成し、その部分を残して保護用の樹脂層を形
成し、そこにハンダバンプを形成した後、ダイシングし
て個々のCSPとするプロセスで作られている。
In the above wafer level CSP, for example, in the super CSP, Al pads are rearranged by multilayer wiring at the wafer level, and bumps which can be soldered to external terminal portions are formed. A protective resin is coated on the entire surface of the wafer, and after the solder bumps are formed, dicing is performed. Ultra CPS (Flip ChipTe
(Chnologies) forms an electrode conversion pattern and an electrode pad that can be soldered on an insulating resin layer at the wafer level, and forms a protective resin layer except for that part. After forming solder bumps on the CSP, it is diced into individual CSPs.

【0004】上記ハンダバンプの形成は、直径0.3〜0.
5mm程度の、あるいは更に微細なハンダボ−ルをハンダ
付けして行うが、ハンダバンプ形成面には、ハンダ付け
する際のフラックス残さや数μ〜100μ程度の超微粒
子状のハンダ飛散物等が付着することがあるので、ハン
ダバンプ形成後に、ハンダボ−ル洗浄やフラックス洗浄
を行わなければならない。従来ハンダ付け後のフラック
ス洗浄としてはプリント基板における洗浄が知られてい
る。このプロセスでは、フロン、エタンその他の溶剤系
や水系の洗浄剤を用いた高圧噴流方法、液中ジェット方
式、気中ジェット方式、US(超音波)ディップ方式等
が使用されているが、ウエ−ハレベルCSPのフラック
ス洗浄等の場合、ハンダボ−ルの微細化と高密度化に伴
いエッジ部のフラックス残さや微細なハンダ飛散物がパ
ッケ−ジの保護樹脂層に固化して付着しているので、単
に上記洗浄方法を用いただけでは確実に洗浄することが
むずかしかった。
[0004] The formation of the solder bumps has a diameter of 0.3 to 0.3 mm.
The solder bump is soldered with a solder ball of about 5 mm or finer. However, a flux residue at the time of soldering and ultra-fine particles of about several μm to 100 μm are attached to the solder bump formation surface. Therefore, solder ball cleaning and flux cleaning must be performed after the formation of the solder bumps. Conventionally, cleaning of a printed circuit board is known as flux cleaning after soldering. In this process, a high-pressure jet method using a fluorocarbon, ethane or other solvent-based or water-based cleaning agent, a submerged jet system, an aerial jet system, a US (ultrasonic) dip system, or the like is used. In the case of flux cleaning of level CSP, as the solder ball becomes finer and denser, the flux residue at the edge and fine solder scattered matter are solidified and adhered to the protective resin layer of the package. Simply using the above-mentioned cleaning method has made it difficult to reliably clean.

【0005】[0005]

【発明が解決しようとする課題】本発明の解決課題は、
ウエ−ハレベルCSPにおいて、ハンダバンプ形成後、
該形成面に付着したフラックス残さやハンダ微粒子等の
残さ物を確実に洗浄できるようにしたウエ−ハレベルC
SPのハンダバンプ形成面洗浄方法を提供することであ
る。
The problem to be solved by the present invention is as follows.
In the wafer level CSP, after forming solder bumps,
Wafer level C, which is capable of reliably cleaning the residue such as flux residue and solder fine particles adhered to the formation surface.
An object of the present invention is to provide a method of cleaning a solder bump forming surface of SP.

【0006】[0006]

【課題を解決するための手段】本発明によれば、ウエ−
ハレベルCSPにおいて、ハンダバンプ形成後、形成面
に存する残さ物を軟化する程度に該ハンダバンプ形成面
を加熱し、上記ウエ−ハを回転させ上記加熱されたハン
ダバンプ形成面に洗浄液を噴射して洗浄することを特徴
とするウエ−ハレベルCSPのハンダバンプ形成面洗浄
方法が提供され、上記課題が解決される。
According to the present invention, a wafer is provided.
In the level CSP, after the solder bump is formed, the solder bump forming surface is heated to such an extent that the residue existing on the forming surface is softened, the wafer is rotated, and a cleaning liquid is sprayed onto the heated solder bump forming surface to perform cleaning. A method for cleaning a solder bump forming surface of a wafer level CSP is provided, which solves the above problem.

【0007】上記ハンダバンプ形成面の加熱方法として
は、水蒸気や洗浄剤蒸気等の蒸気を噴射したり、加温し
た洗浄液や温水を噴射したり、ハンダバンプ形成面の近
くにハロゲンランプ等のヒ−タ−を設けて加熱したり、
これらの各方法を適宜に組み合せたりでき、また好まし
くは上記加熱工程前に、加温された洗浄液中にウエ−ハ
を浸漬して前洗浄される。
The solder bump forming surface may be heated by spraying steam such as water vapor or a cleaning agent vapor, by spraying a heated cleaning solution or hot water, or by heating a heater such as a halogen lamp near the solder bump forming surface. -Heating,
These methods can be appropriately combined, and preferably, the wafer is pre-washed by immersing it in a heated washing solution before the heating step.

【0008】[0008]

【発明の実施の形態】図1は、CSPの一例を示し、I
Cチップ(1)内に多層配線されたAlパッド(2)・
・・は、Cu配線(3)、ビアポスト(4)を介してバ
リアメタル(5)に接続され、該バリアメタル(5)に
はハンダボ−ル(6)をハンダ付けしてハンダバンプを
形成してある。ICチップ(1)の裏面にはSiN
(7)、ポリイミド層(8)、封止樹脂層(9)が設け
られている。ウエ−ハレベルCSPにおいては、これら
の加工は、ウエ−ハ段階で行われ、最後にダイシングし
て個々のCSPを得る。
FIG. 1 shows an example of a CSP.
Al pad (2) multi-layered in C chip (1)
Is connected to a barrier metal (5) via a Cu wiring (3) and a via post (4), and a solder ball (6) is soldered to the barrier metal (5) to form a solder bump. is there. SiN on the back surface of the IC chip (1)
(7) A polyimide layer (8) and a sealing resin layer (9) are provided. In the wafer-level CSP, these processes are performed at the wafer stage, and are finally diced to obtain individual CSPs.

【0009】上記ハンダバンプを形成した形成面(10)に
は、例えば図2に示すように、ハンダボ−ル(6)のエ
ッジ部や周囲部にロジンを主成分とするフラックス残さ
(11)や超微粒子状のハンダ飛散物(12)等の残さ物が付着
しているので、上記ウエ−ハレベルCSPをリフロ−し
た後に下記するように洗浄する。
On the surface (10) on which the solder bumps are formed, as shown in FIG. 2, for example, a flux residue containing rosin as a main component is present at the edge and the periphery of the solder ball (6).
Since the residue such as (11) and the ultra-fine solder scattered matter (12) is adhered, the wafer level CSP is washed after reflowing as described below.

【0010】上記残さ物の洗浄は、図3に示すように、
ウエ−ハ(13)をスピンチャック(14)に保持して回転させ
ながら洗浄するスピン洗浄装置を用いるが、この工程に
よる洗浄効果を高めることができるよう前洗浄すること
が好ましい。該前洗浄は、ハンダボ−ル洗浄やフラック
ス洗浄に好適な洗浄液を収納した前洗浄槽(15)にウエ−
ハ(13)を浸漬し、該洗浄槽内で適宜液中噴流洗浄、超音
波洗浄等して洗浄する。なお、この際、該洗浄槽内の液
温を、例えば約60℃程度に加温しておくと、上記ハン
ダバンプ形成面に付着したフラックス残さは溶解した
り、膨潤しやすくなり、効果的に前洗浄することができ
る。その後、上記ウエ−ハはリンス洗浄等されて、スピ
ン洗浄部へ搬送される。
[0010] As shown in FIG.
A spin cleaning apparatus is used in which the wafer (13) is held by the spin chuck (14) and washed while rotating the wafer, and pre-washing is preferably performed so as to enhance the washing effect of this step. The pre-cleaning is carried out in a pre-cleaning tank (15) containing a cleaning solution suitable for solder ball cleaning and flux cleaning.
C. (13) is immersed and washed in the washing tank by jet washing in liquid or ultrasonic washing as appropriate. At this time, if the liquid temperature in the cleaning tank is heated to, for example, about 60 ° C., the flux residue attached to the solder bump forming surface is easily dissolved or swelled. Can be washed. Thereafter, the wafer is rinsed or the like and transported to a spin cleaning unit.

【0011】該スピン洗浄部において、ウエ−ハは約5
00rpm 程度で回転される。このとき、上記ウエ−ハ(1
3)の表面、少くとも上記ハンダバンプ形成面(10)は洗浄
液で洗浄するに際し、上記残さ物が軟化する程度に加熱
される。この加熱は、水蒸気、洗浄剤蒸気及びこれらを
混合した蒸気等の蒸気、好ましくは、温度約100〜1
10℃、圧力約0.1〜0.15MPa程度の水蒸気をノズ
ルから噴射することにより行われる。該ノズル(16)は、
ハンダバンプ形成面に蒸気粒子(17)を充分に吹きつける
ことができるようウエ−ハ(13)の表面に沿って直径方向
に揺動し、所望により噴射角を可変できるように構成さ
れ、スイングア−ム(図示略)等に複数個設けられてい
る。また、上記加熱は、加温水を噴射してもよく、この
加温水には洗浄液を含み若しくは洗浄液自体を加温水と
して用いてもよい。さらに、上記形成面(10)に近接して
ハロゲンランプ等のヒ−タ−(18)を設けたり、加温した
窒素ガス等の気体を吹き付けるようにしてもよい。
In the spin cleaning section, the wafer is about 5
It is rotated at about 00 rpm. At this time, the wafer (1
The surface of 3), at least the surface 10 on which the solder bumps are formed, is heated to such a degree that the residue is softened when being cleaned with a cleaning liquid. The heating is performed by using steam such as steam, cleaning agent steam and a mixture thereof, preferably at a temperature of about 100-1.
This is performed by injecting steam at a temperature of 10 ° C. and a pressure of about 0.1 to 0.15 MPa from a nozzle. The nozzle (16) is
It is configured to oscillate diametrically along the surface of the wafer (13) so that the vapor particles (17) can be sufficiently sprayed on the surface on which the solder bumps are formed, and the injection angle can be varied as desired. And a plurality of them (not shown). For the heating, warming water may be injected, and the warming water may include a cleaning liquid or the cleaning liquid itself may be used as the warming water. Further, a heater (18) such as a halogen lamp may be provided near the formation surface (10), or a gas such as a heated nitrogen gas may be blown.

【0012】上記加熱の程度は、残さ物の性状に応じて
適宜に設定され、例えば約60℃〜120℃程度にする
とよく、上記蒸気噴射等による加熱では軟化した残さ物
の一部は、噴射された蒸気粒子で吹き飛ばされる。ま
た、ノズルの角度を適宜変えたり、噴射幅を調整したり
することにより、ハンダボ−ルのエッジ部にも蒸気を確
実に供給でき、隅部のフラックス残さ等の残さ物も充分
に柔らかくできるとともに上記蒸気粒子によって除去す
ることができる。
[0012] The degree of the heating is appropriately set according to the properties of the residue, and may be, for example, about 60 ° C to about 120 ° C. Blown away by the vapor particles. In addition, by appropriately changing the angle of the nozzle or adjusting the injection width, the steam can be reliably supplied to the edge of the solder ball, and the residue such as the flux residue at the corner can be sufficiently softened. It can be removed by the vapor particles.

【0013】上記加熱によって残さ物を軟化させた後、
上記形成面(10)には高圧の洗浄液が噴射される。該洗浄
液の吐出圧力は、例えば約1MPa以上、好ましくは約
3〜7MPa程度である。このような洗浄液は、洗浄液
自体を高圧ポンプで所定圧まで加圧してもよいが、例え
ば図3に示すように、一方の流路(19)から洗浄液をノズ
ル(20)に供給し、他方の流路(21)から加圧エア等の加圧
気体を該ノズル(20)に供給し、二流体方式で加圧しても
よい。なお、上記洗浄液や加圧気体は、残さ物が形成面
(10)に付着しないように加温しておくとよく、例えば、
加圧エアを約60〜250℃程度に加温加圧し、ノズル
から噴出する洗浄液が洗浄に最適な温度、例えば約50
〜120℃程度に加温されるようにすることが好まし
い。この際、上記エアの流路に蒸気を供給するようにす
れば、形成面の加熱と洗浄を同時に行うこともできる。
また、上記蒸気噴射の際に、ハンダバンプ形成面(10)に
洗浄液を予め供給し、若しくは連続的に供給することに
より、該形成面の加熱と洗浄を一緒に行うこともでき
る。
After the residue is softened by the above heating,
A high-pressure cleaning liquid is sprayed on the forming surface (10). The discharge pressure of the cleaning liquid is, for example, about 1 MPa or more, and preferably about 3 to 7 MPa. Such a washing liquid may be pressurized to a predetermined pressure by a high-pressure pump, but for example, as shown in FIG. 3, the washing liquid is supplied from one flow path (19) to the nozzle (20) and the other is supplied to the nozzle (20). A pressurized gas such as pressurized air may be supplied to the nozzle (20) from the flow path (21) and pressurized by a two-fluid system. In addition, the above-mentioned cleaning liquid or pressurized gas is
It is good to heat so that it does not adhere to (10), for example,
The pressurized air is heated and pressurized to about 60 to 250 ° C., and the cleaning liquid ejected from the nozzle is heated to the optimum temperature for cleaning, for example, about 50 ° C.
It is preferable to heat to about 120 ° C. At this time, if steam is supplied to the air flow path, the formation surface can be heated and cleaned at the same time.
In addition, at the time of the steam injection, by supplying the cleaning liquid to the solder bump forming surface (10) in advance or continuously, the heating and cleaning of the forming surface can be performed together.

【0014】洗浄液による洗浄後、上記ウエ−ハは所望
により、例えばIPAジェット及び窒素ガスブロ−にウ
エ−ハのピスン、例えば約2000〜3000rpm を組
み合わせる等の乾燥手段により乾燥される。その後、該
ウエ−ハはダイシングされ、個々のCSPが得られる。
After washing with the washing solution, the wafer is optionally dried by a drying means such as combining an IPA jet and a nitrogen gas blow with a wafer pin, for example, at about 2000 to 3000 rpm. Thereafter, the wafer is diced to obtain individual CSPs.

【0015】[0015]

【発明の効果】本発明は上記のように構成され、ウエ−
ハレベルCSPにおいて、ハンダバンプ形成後、該ハン
ダバンプ形成面を加熱し、ウエ−ハを回転させて上記加
熱された形成面に洗浄液を噴射して洗浄するようにした
から、上記ハンダバンプ形成面にハンダボ−ルをハンダ
付けした際に、該形成面に付着したロジンを主成分とす
るフラックス残さや微粒子状のハンダ飛散物等の残さ物
は、上記加熱により軟化され、該加熱を蒸気噴射により
行うことにより一部は軟化と共に吹き飛ばされ、さら
に、このように軟化した残さ物に高圧の洗浄液が吹き当
てられるので、上記残さ物はハンダバンプ形成面から確
実に除去され、前洗浄槽にウエ−ハを浸漬させてから上
記洗浄処理を行うことにより、一層効率よく洗浄するこ
とができる。
The present invention is constructed as described above,
In the level CSP, after the solder bumps are formed, the surface on which the solder bumps are formed is heated, and the wafer is rotated to spray a cleaning liquid onto the heated formation surface to clean the solder bumps. When soldering is performed, the flux residue mainly composed of rosin adhered to the forming surface and the residue such as fine particle scattered solder are softened by the above-mentioned heating, and the heating is performed by steam injection. The part is blown off with softening, and furthermore, a high-pressure cleaning solution is sprayed on the softened residue, so that the residue is reliably removed from the solder bump forming surface, and the wafer is immersed in the pre-cleaning tank. By performing the above-described cleaning process, the cleaning can be performed more efficiently.

【図面の簡単な説明】[Brief description of the drawings]

【図1】CSPの構成の一例を示す説明図。FIG. 1 is an explanatory diagram showing an example of a configuration of a CSP.

【図2】ハンダバンプ形成面の説明図。FIG. 2 is an explanatory view of a solder bump forming surface.

【図3】洗浄工程を示す説明図。FIG. 3 is an explanatory view showing a cleaning step.

【符号の説明】[Explanation of symbols]

6 ハンダボ−ル 10 ハンダバンプ形成面 11 フラックス残さ 12 ハンダ飛散物 13 ウエ−ハ 14 スピンチャック 15 前洗浄槽 16,20 ノズル Reference Signs List 6 solder ball 10 solder bump forming surface 11 flux residue 12 solder scattered object 13 wafer 14 spin chuck 15 pre-cleaning tank 16, 20 nozzle

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 ウエ−ハレベルCSPにおいて、ハンダ
バンプ形成後、該ハンダバンプ形成面に存する残さ物を
軟化するよう該形成面を加熱し、上記ウエ−ハを回転さ
せ上記加熱されたハンダバンプ形成面に洗浄液を噴射し
て洗浄することを特徴とするウエ−ハレベルCSPのハ
ンダバンプ形成面洗浄方法。
In a wafer level CSP, after a solder bump is formed, the surface on which the solder bump is formed is heated so as to soften the residue on the surface, and the wafer is rotated so that a cleaning liquid is applied to the heated solder bump formation surface. A method for cleaning a solder bump forming surface of a wafer level CSP, comprising:
【請求項2】 上記ハンダバンプ形成面の加熱は、該形
成面に蒸気を噴射することにより行われる請求項1に記
載のウエ−ハレベルCSPのハンダバンプ形成面洗浄方
法。
2. The method for cleaning a solder bump forming surface of a wafer level CSP according to claim 1, wherein the heating of the solder bump forming surface is performed by injecting steam to the forming surface.
【請求項3】 上記ハンダバンプ形成面の加熱は、上記
洗浄液を加温して噴射することにより行われる請求項1
に記載のウエ−ハレベルCSPのハンダバンプ形成面洗
浄方法。
3. The heating of the solder bump forming surface is performed by heating and jetting the cleaning liquid.
3. The method for cleaning a surface for forming a solder bump of a wafer level CSP according to item 1.
【請求項4】 回転自在に支持された上記ウエ−ハの上
記ハンダバンプ形成面に近接してヒ−タ−を設けた請求
項1に記載のウエ−ハレベルCSPのハンダバンプ形成
面洗浄方法。
4. The method for cleaning a solder bump forming surface of a wafer level CSP according to claim 1, wherein a heater is provided close to the solder bump forming surface of the rotatably supported wafer.
【請求項5】 上記ウエ−ハは、ハンダバンプ形成面の
加熱工程前に、加温した洗浄液中に浸漬して前洗浄され
る請求項1ないし4のいずれかに記載のウエ−ハレベル
CSPのハンダバンプ形成面洗浄方法。
5. The solder bump of a wafer level CSP according to claim 1, wherein the wafer is pre-washed by immersing it in a heated cleaning solution before the step of heating the solder bump forming surface. Forming surface cleaning method.
JP11143511A 1999-05-24 1999-05-24 Method for cleaning solder bump forming surface of wafer-level csp Pending JP2000332153A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
JP2000332153A true JP2000332153A (en) 2000-11-30

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Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003007665A (en) * 2001-06-27 2003-01-10 Hitachi Ltd Method for manufacturing semiconductor device
JP2009212107A (en) * 2008-02-29 2009-09-17 Mitsubishi Electric Corp Method and device for removing residual dross
JP2013086090A (en) * 2011-10-24 2013-05-13 Tdk Corp Method and device for cleaning using steam

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003007665A (en) * 2001-06-27 2003-01-10 Hitachi Ltd Method for manufacturing semiconductor device
JP2009212107A (en) * 2008-02-29 2009-09-17 Mitsubishi Electric Corp Method and device for removing residual dross
JP2013086090A (en) * 2011-10-24 2013-05-13 Tdk Corp Method and device for cleaning using steam

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